CN110714232A - 一种高强度聚乙烯单丝的配方工艺 - Google Patents
一种高强度聚乙烯单丝的配方工艺 Download PDFInfo
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- CN110714232A CN110714232A CN201911021366.6A CN201911021366A CN110714232A CN 110714232 A CN110714232 A CN 110714232A CN 201911021366 A CN201911021366 A CN 201911021366A CN 110714232 A CN110714232 A CN 110714232A
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- polyethylene monofilament
- hyperbranched polyester
- strength polyethylene
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113638072A (zh) * | 2021-08-26 | 2021-11-12 | 福建省亚美工贸有限公司 | 长效防虫织物及其制作方法 |
CN114539708A (zh) * | 2022-03-01 | 2022-05-27 | 北京市建筑工程研究院有限责任公司 | 一种耐紫外应力拉索及其制备方法 |
CN115559010A (zh) * | 2022-01-06 | 2023-01-03 | 江苏锵尼玛新材料股份有限公司 | 一种环保型高比强度纤维材料的制备工艺及其应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1395588A (zh) * | 2000-01-21 | 2003-02-05 | 三井化学株式会社 | 烯烃嵌段共聚物,其制备方法和用途 |
US20140116703A1 (en) * | 2012-10-25 | 2014-05-01 | Halliburton Energy Services, Inc. | Wellbore Servicing Methods and Compositions Comprising Degradable Polymers |
CN108660535A (zh) * | 2018-06-08 | 2018-10-16 | 北京化工大学 | 改性超高分子量聚乙烯成纤专用料及其制备方法和熔融纺丝成纤方法 |
CN110204835A (zh) * | 2019-05-24 | 2019-09-06 | 武汉金发科技有限公司 | 一种增韧剂组合物与一种热塑性树脂复合材料及其制备方法 |
-
2019
- 2019-10-25 CN CN201911021366.6A patent/CN110714232B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1395588A (zh) * | 2000-01-21 | 2003-02-05 | 三井化学株式会社 | 烯烃嵌段共聚物,其制备方法和用途 |
US20140116703A1 (en) * | 2012-10-25 | 2014-05-01 | Halliburton Energy Services, Inc. | Wellbore Servicing Methods and Compositions Comprising Degradable Polymers |
CN108660535A (zh) * | 2018-06-08 | 2018-10-16 | 北京化工大学 | 改性超高分子量聚乙烯成纤专用料及其制备方法和熔融纺丝成纤方法 |
CN110204835A (zh) * | 2019-05-24 | 2019-09-06 | 武汉金发科技有限公司 | 一种增韧剂组合物与一种热塑性树脂复合材料及其制备方法 |
Non-Patent Citations (1)
Title |
---|
邓冰锋、黄从树等: "己内酯/乙交酯/丙交酯三元嵌段聚酯共聚物的合成与性能研究", 《己内酯/乙交酯/丙交酯三元嵌段聚酯共聚物的合成与性能研究》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113638072A (zh) * | 2021-08-26 | 2021-11-12 | 福建省亚美工贸有限公司 | 长效防虫织物及其制作方法 |
CN115559010A (zh) * | 2022-01-06 | 2023-01-03 | 江苏锵尼玛新材料股份有限公司 | 一种环保型高比强度纤维材料的制备工艺及其应用 |
CN115559010B (zh) * | 2022-01-06 | 2023-12-26 | 江苏锵尼玛新材料股份有限公司 | 一种环保型高比强度纤维材料的制备工艺及其应用 |
CN114539708A (zh) * | 2022-03-01 | 2022-05-27 | 北京市建筑工程研究院有限责任公司 | 一种耐紫外应力拉索及其制备方法 |
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