CN110655818A - Environment-friendly zipper softener and preparation method thereof - Google Patents
Environment-friendly zipper softener and preparation method thereof Download PDFInfo
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- CN110655818A CN110655818A CN201911003609.3A CN201911003609A CN110655818A CN 110655818 A CN110655818 A CN 110655818A CN 201911003609 A CN201911003609 A CN 201911003609A CN 110655818 A CN110655818 A CN 110655818A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/32—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing two or more of boron, silicon, phosphorus, selenium, tellurium or a metal
- C09K15/328—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing two or more of boron, silicon, phosphorus, selenium, tellurium or a metal containing boron, silicon, selenium or tellurium
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/16—Anti-static materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an environment-friendly zipper softener, which comprises the following components in percentage by mass: 1-5 parts of essence, 12-15 parts of higher fatty acid, 3.5-7 parts of emulsifier, 0.5-1 part of simethicone, 5-10 parts of nonionic surfactant, 0.3-0.8 part of bacteriostatic agent, 12-15 parts of ethanol and 78-85 parts of water; the invention also discloses a preparation method of the environment-friendly zipper softener; the zipper softener has the beneficial effects that firstly, the zipper softener adopts environment-friendly components, and part of the components have good biodegradability, so that the zipper softener cannot cause damage to clothes and human bodies after being used repeatedly and for a long time; secondly, the zipper softener has good softening effect, meanwhile, the components do not influence the quality of clothes, and the softening effect on the zipper, which can be achieved by a large amount of the clothes softener, can be achieved by using a small dosage; finally, the zipper softener disclosed by the invention adopts a nonionic surfactant, and has good antistatic capacity and yellowing resistance.
Description
Technical Field
The invention relates to the technical field of daily-use chemical industry, in particular to an ultraviolet-curable hydrophilic coating and a preparation method thereof.
Background
In daily clothes washing and wearing overshoot, due to fine fibers and material aging and dust accumulation caused by clothes or the external environment, the condition that the smoothness of the zipper is reduced after long-term use can be caused, and the zipper becomes old and has stiff hand feeling. Especially in dry seasons such as autumn and winter, the influence of dust accumulation on the hand feeling of the zipper is larger, and the wearing comfort of clothes is seriously influenced. Therefore, with the development of social life, people have higher and higher requirements on smoothness and comfort of the zipper, and the softener is produced at the same time.
However, no softener is used for the zipper at present, and if the zipper is not used well, the softener is often coated by using a clothes softener or a daily necessity softener, so that other problems are brought while the problem of smoothness of the zipper is solved. Firstly, the softener of the daily necessities often has toxic chemical components, is directly contacted with limbs or clothes and can slowly permeate into the skin of a human body to influence the body health; secondly, the softening effect of the fabric softener is inferior to that of a daily product softener, and the fabric softener is mainly used for improving the bulkiness and softness of the fabric and eliminating the static electricity effect, so that when the fabric softener is used on a zipper, the smooth effect of the zipper is not good, the dosage is increased, the fabric softener is wasted, and even the excessive fabric softener is contacted with the fabric, so that the comfort of the fabric is affected.
Disclosure of Invention
1. Technical problem to be solved
The technical problem to be solved by the invention is to provide an environment-friendly zipper softener and a preparation method thereof, which can improve the phenomena of zipper deterioration and stiff hand feeling, improve the smoothness of the zipper, and ensure that clothes and human bodies are not damaged in the using process by adopting environment-friendly components.
2. Technical scheme
In order to achieve the purpose, the technical scheme of the invention is as follows: an environment-friendly zipper softener comprises the following components in parts by mass: 1-5 parts of essence, 12-15 parts of higher fatty acid, 3.5-7 parts of emulsifier, 0.5-1 part of simethicone, 5-10 parts of nonionic surfactant, 0.3-0.8 part of bacteriostatic agent, 12-15 parts of ethanol and 78-85 parts of water.
Preferably, the emulsifier comprises the following components in percentage by mass: AEO-30.8-1.5 parts, AEO-52-4 parts and AEO-90.7-1.5 parts.
Preferably, the higher fatty acid comprises the following components in percentage by mass: 6-8 parts of saturated higher fatty acid and 6-7 parts of unsaturated higher fatty acid; wherein the saturated higher fatty acid is one or more of stearic acid, palmitic acid and lauric acid, and the unsaturated higher fatty acid is one or more of linoleic acid, oleic acid and olive oil.
Preferably, the nonionic surfactant is one or more of polyoxyethylene alkylamine, alkylphenol ethoxylate, polyoxyethylene fatty acid ester and polyvinyl alkylolamide.
Preferably, the bacteriostatic agent is a cationic bacteriostatic agent and is one or more of a quaternary ammonium salt bacteriostatic agent and a biguanide bacteriostatic agent.
Preferably, the quaternary ammonium salt bacteriostatic agent is one or more of benzalkonium chloride, didecyl dimethyl ammonium chloride and alkyl dimethyl benzyl ammonium chloride.
Preferably, the biguanide bacteriostat is one or more of chlorhexidine gluconate, chlorhexidine acetate and chlorhexidine hydrochloride.
The invention also discloses a preparation method of the environment-friendly zipper softener, which comprises the following steps:
step 1, adding the ethanol into a reaction kettle, heating while adding the higher fatty acid and the nonionic surfactant, uniformly stirring and fully dissolving to form a solution A;
step 2, adding the emulsifier into the solution A prepared in the step 1, stirring uniformly under a heating condition and fully dissolving to form a solution B;
step 3, adding the bacteriostatic agent, the dimethyl silicone oil and the essence into the solution B prepared in the step 2, and uniformly stirring and fully dissolving under a heating condition to form a solution C;
and 4, adding water into the solution C prepared in the step 3 while stirring, and standing under a heating condition to form the softener.
Preferably, the stirring temperature of the step 1 and the step 2 is 45 ℃.
Preferably, the stirring temperature in step 3 is 35 ℃.
Preferably, the solution in the step 4 is kept standing for 45 min.
3. Advantageous effects
In conclusion, the beneficial effects of the invention are as follows:
(1) the zipper softener disclosed by the invention adopts environment-friendly components, and part of the components have good biodegradability, so that the zipper softener can not cause damage to clothes and human bodies even if being used repeatedly and for a long time;
(2) the zipper softener has good softening effect, meanwhile, the components do not influence the quality of clothes, and the softening effect on the zipper, which can be achieved by a large amount of the clothes softener, can be achieved by using a small dosage;
(3) the zipper softener adopts the nonionic surfactant, and has good antistatic capability and yellowing resistance.
Detailed Description
The technical scheme of the invention is further explained by combining specific examples.
Example 1:
the components of the softener are as follows: an environment-friendly zipper softener comprises the following components in parts by mass: 2 parts of essence, 12 parts of higher fatty acid (a mixture of stearic acid, palmitic acid and oleic acid), 4 parts of emulsifier, 1 part of dimethyl silicone oil, 8 parts of nonionic surfactant (a mixture of polyoxyethylene alkylamine and alkylphenol polyoxyethylene ether), 0.5 part of bacteriostatic agent (a mixture of didecyl dimethyl ammonium chloride and alkyl dimethyl benzyl ammonium chloride), 15 parts of ethanol and 84 parts of water.
The preparation method comprises the following steps: firstly, adding the ethanol into a reaction kettle, heating while adding the higher fatty acid and the nonionic surfactant, stirring uniformly at 45 ℃ and fully dissolving to form a solution A; then, adding the emulsifier into the solution A prepared in the step 1, stirring uniformly at 45 ℃ and fully dissolving to form a solution B; secondly, adding the bacteriostatic agent, the dimethyl silicone oil and the essence into the solution B prepared in the step 2, stirring uniformly at 35 ℃ and fully dissolving to form a solution C; and finally, adding water into the solution C prepared in the step 3 while stirring, and standing for 60min under a heating condition to form the softener.
Example 2:
the components of the softener are as follows: an environment-friendly zipper softener comprises the following components in parts by mass: 5 parts of essence, 14 parts of higher fatty acid (a mixture of linoleic acid, oleic acid, palmitic acid and lauric acid), 5 parts of emulsifier, 0.5 part of simethicone, 10 parts of nonionic surfactant (a mixture of polyoxyethylene alkylamine, polyoxyethylene fatty acid ester and polyvinyl alkylolamide), 0.5 part of bacteriostatic agent (a mixture of chlorhexidine gluconate, chlorhexidine acetate, benzalkonium chloride and chlorhexidine acetate), 12 parts of ethanol and 79 parts of water.
The preparation method comprises the following steps: firstly, adding the ethanol into a reaction kettle, heating while adding the higher fatty acid and the nonionic surfactant, stirring uniformly at 45 ℃ and fully dissolving to form a solution A; then, adding the emulsifier into the solution A prepared in the step 1, stirring uniformly at 45 ℃ and fully dissolving to form a solution B; secondly, adding the bacteriostatic agent, the dimethyl silicone oil and the essence into the solution B prepared in the step 2, stirring uniformly at 35 ℃ and fully dissolving to form a solution C; and finally, adding water into the solution C prepared in the step 3 while stirring, and standing for 60min under a heating condition to form the softener.
The above description is only a preferred embodiment of the present invention, and not intended to limit the scope of the present invention, and all equivalent structural changes made by using the contents of the present specification, or any direct or indirect application attached to other related technical fields, are included in the scope of the present invention.
Claims (10)
1. The environment-friendly zipper softener is characterized by comprising the following components in parts by mass: 1-5 parts of essence, 12-15 parts of higher fatty acid, 3.5-7 parts of emulsifier, 0.5-1 part of simethicone, 5-10 parts of nonionic surfactant, 0.3-0.8 part of bacteriostatic agent, 12-15 parts of ethanol and 78-85 parts of water.
2. The environment-friendly zipper softener according to claim 1, wherein: the emulsifier comprises the following components in percentage by mass: AEO-30.8-1.5 parts, AEO-52-4 parts and AEO-90.7-1.5 parts.
3. The environment-friendly zipper softener according to claim 1, wherein: the higher fatty acid comprises the following components in percentage by mass: 6-8 parts of saturated higher fatty acid and 6-7 parts of unsaturated higher fatty acid; wherein the saturated higher fatty acid is one or more of stearic acid, palmitic acid and lauric acid, and the unsaturated higher fatty acid is one or more of linoleic acid, oleic acid and olive oil.
4. The environment-friendly zipper softener according to claim 1, wherein: the nonionic surfactant is one or more of polyoxyethylene alkylamine, alkylphenol polyoxyethylene, fatty acid polyoxyethylene ester and polyvinyl alkylolamide.
5. The environment-friendly zipper softener according to claim 1, wherein: the bacteriostatic agent is a cationic bacteriostatic agent and is one or more of quaternary ammonium salt bacteriostatic agent and biguanide bacteriostatic agent.
6. The environment-friendly zipper softener according to claim 5, wherein: the quaternary ammonium salt bacteriostatic agent is one or more of benzalkonium chloride, didecyl dimethyl ammonium chloride and alkyl dimethyl benzyl ammonium chloride.
7. The environment-friendly zipper softener according to claim 5, wherein: the biguanide bacteriostat is one or more of chlorhexidine gluconate, chlorhexidine acetate and chlorhexidine hydrochloride.
8. A preparation method of the environment-friendly zipper softener according to any one of claims 1 to 7, which is characterized by comprising the following steps:
step 1, adding the ethanol into a reaction kettle, heating while adding the higher fatty acid and the nonionic surfactant, uniformly stirring and fully dissolving to form a solution A;
step 2, adding the emulsifier into the solution A prepared in the step 1, stirring uniformly under a heating condition and fully dissolving to form a solution B;
step 3, adding the bacteriostatic agent, the dimethyl silicone oil and the essence into the solution B prepared in the step 2, and uniformly stirring and fully dissolving under a heating condition to form a solution C;
and 4, adding water into the solution C prepared in the step 3 while stirring, and standing under a heating condition to form the softener.
9. The method for preparing the environment-friendly zipper softener according to claim 8, characterized in that: the stirring temperature in the step 1 and the step 2 is 45 ℃.
10. The method for preparing the environment-friendly zipper softener according to claim 8, characterized in that: the stirring temperature in step 3 is 35 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911003609.3A CN110655818A (en) | 2019-10-22 | 2019-10-22 | Environment-friendly zipper softener and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911003609.3A CN110655818A (en) | 2019-10-22 | 2019-10-22 | Environment-friendly zipper softener and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN110655818A true CN110655818A (en) | 2020-01-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911003609.3A Pending CN110655818A (en) | 2019-10-22 | 2019-10-22 | Environment-friendly zipper softener and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87103029A (en) * | 1987-08-18 | 1988-02-24 | 东风电机厂 | Lubricant coating used in die casting |
| US8236167B2 (en) * | 2009-11-18 | 2012-08-07 | Liquifix | Lubricating oil |
| CN105331431A (en) * | 2015-11-18 | 2016-02-17 | 肖珍治 | Zipper lubricant |
| CN107740270A (en) * | 2017-09-30 | 2018-02-27 | 江苏新瑞贝科技股份有限公司 | A kind of environment-friendly antibacterial softener and preparation method thereof |
-
2019
- 2019-10-22 CN CN201911003609.3A patent/CN110655818A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN87103029A (en) * | 1987-08-18 | 1988-02-24 | 东风电机厂 | Lubricant coating used in die casting |
| US8236167B2 (en) * | 2009-11-18 | 2012-08-07 | Liquifix | Lubricating oil |
| CN105331431A (en) * | 2015-11-18 | 2016-02-17 | 肖珍治 | Zipper lubricant |
| CN107740270A (en) * | 2017-09-30 | 2018-02-27 | 江苏新瑞贝科技股份有限公司 | A kind of environment-friendly antibacterial softener and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 董国君等: "《表面活性剂化学》", 31 August 2009, 北京：北京理工大学出版社 * |
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