CN110552202A - Scouring agent for wool-polyester blended fabric - Google Patents
Scouring agent for wool-polyester blended fabric Download PDFInfo
- Publication number
- CN110552202A CN110552202A CN201910699102.XA CN201910699102A CN110552202A CN 110552202 A CN110552202 A CN 110552202A CN 201910699102 A CN201910699102 A CN 201910699102A CN 110552202 A CN110552202 A CN 110552202A
- Authority
- CN
- China
- Prior art keywords
- wool
- blended fabric
- polyester blended
- scouring agent
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 23
- 229920000728 polyester Polymers 0.000 title claims abstract description 21
- 238000009991 scouring Methods 0.000 title claims abstract description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 27
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 108090000790 Enzymes Proteins 0.000 claims abstract description 19
- 102000004190 Enzymes Human genes 0.000 claims abstract description 19
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 ethoxy compound Chemical class 0.000 claims abstract description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 8
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims abstract description 8
- 229940088598 enzyme Drugs 0.000 claims description 18
- 101710121765 Endo-1,4-beta-xylanase Proteins 0.000 claims description 9
- 108010059820 Polygalacturonase Proteins 0.000 claims description 6
- 108010093305 exopolygalacturonase Proteins 0.000 claims description 6
- 108010059892 Cellulase Proteins 0.000 claims description 5
- 108010029541 Laccase Proteins 0.000 claims description 5
- 108091005804 Peptidases Proteins 0.000 claims description 5
- 229940106157 cellulase Drugs 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims description 5
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 4
- 102000035195 Peptidases Human genes 0.000 claims description 3
- 235000019833 protease Nutrition 0.000 claims description 3
- 239000004365 Protease Substances 0.000 claims description 2
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 2
- 235000019419 proteases Nutrition 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims 2
- 238000007670 refining Methods 0.000 abstract description 11
- 239000004753 textile Substances 0.000 abstract description 8
- 239000003513 alkali Substances 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 4
- 239000000835 fiber Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 108010084185 Cellulases Proteins 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 229940125810 compound 20 Drugs 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- General Chemical & Material Sciences (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
The invention relates to the technical field of textile auxiliary products, in particular to a textile scouring agent. The invention relates to a scouring agent for a wool-polyester blended fabric, which comprises the following components in percentage by mass: 20-30% of sulfonate of fatty acid methyl ester ethoxy compound, 5-10% of isomeric alcohol polyoxyethylene ether, 10-25% of sodium dodecyl benzene sulfonate, 5-10% of polyoxypropyl polyoxyethylene glyceryl ether, 2-20% of sodium hydroxide, 10-30% of hydrogen peroxide, 1-2% of ethyl acetate and 3-8% of bio-enzyme. The refining agent disclosed by the invention has high oil and wax removal performance, high alkali resistance, mild and efficient biological enzyme action, and can catalyze the reaction at normal temperature or low temperature, so that the energy consumption for refining the wool-polyester blended fabric is reduced, and the damage to the fabric is reduced.
Description
Technical Field
The invention relates to the technical field of textile auxiliary products, in particular to a textile scouring agent.
Background
The refining agent is the most commonly used auxiliary agent in the refining process of the textile before dyeing, and can effectively remove impurities and oil stains in the textile through the refining action, so that the refining agent is widely applied to the textile industry. The refining agent is a compound which is obtained by mixing various anionic and nonionic surfactants and proper additives according to a certain proportion and has the main washing effect and the synergistic effects of permeation, emulsification, dispersion, complexation and the like. The wool-polyester blended fabric is a fabric blended by wool and polyester fibers, takes wool as a main component, and is a textile blended by 65-67% of wool and 33-35% of polyester. The traditional refining agent has poor effect of removing fiber commensals on the wool-polyester blended fabric, is not beneficial to the printing and dyeing effect of the wool-polyester blended fabric, has complex component formula and higher cost, and is not beneficial to popularization and application.
Disclosure of Invention
The refining agent provided by the invention has a good oil and wax removing effect, and can still keep high oil and wax removing capability at high temperature and strong alkali.
In order to achieve the purpose, the scouring agent for the wool-polyester blended fabric, which is designed by the invention, comprises the following components in percentage by mass:
20-30% of sulfonate of fatty acid methyl ester ethoxy compound
5-10% of isomeric alcohol polyoxyethylene ether
10 to 25 percent of sodium dodecyl benzene sulfonate
5-10% of polyoxypropyl polyoxyethyl glycerol ether
2 to 20 percent of sodium hydroxide
10-30% of hydrogen peroxide
1-2% of ethyl acetate
3-8% of biological enzyme.
Preferably, the scouring agent for the wool-polyester blended fabric comprises the following components in percentage by mass:
Fatty acid methyl ester ethoxy compound sulfonate 25%
Isomeric alcohol polyoxyethylene ether 8%
Sodium dodecyl benzene sulfonate 20%
8% of polyoxypropyl polyoxyethylene glycerol ether
10 percent of sodium hydroxide
20 percent of hydrogen peroxide
2 percent of ethyl acetate
7% of biological enzyme.
Preferably, the biological enzymes include at least two of pectinase, cellulase, protease, xylanase and laccase.
As a further preference, the biological enzymes include pectinases, cellulases and xylanases.
As a further preference, the biological enzymes include proteinases, xylanases and laccases.
The fatty acid methyl ester ethoxy compound sulfonate contained in the formula of the refining agent has high oil and wax removing performance and high alkali resistance, and the sodium hydroxide has strong impurity removing capacity and can effectively remove nitrogen-containing impurities and pectin at high temperature and saponify fatty acid on fabrics. The method utilizes the cooperation of the biological enzyme and the surfactant to remove the fiber commensals on the wool-polyester blended fabric, the biological enzyme has mild and efficient action, can catalyze the reaction at normal temperature or lower temperature, has a pH environment close to neutral, is favorable for reducing the energy consumption for refining the wool-polyester blended fabric, saving energy, reducing the damage to the fabric, machines and equipment and being favorable for the safety of a working environment.
Detailed Description
example 1
The scouring agent for the wool-polyester blended fabric comprises the following components in percentage by mass:
Sulfonate of fatty acid methyl ester ethoxy compound 20%
Isomeric alcohol polyoxyethylene ether 10%
Sodium dodecyl benzene sulfonate 10%
Polyoxypropyl polyoxyethyl glyceryl ether 10%
20 percent of sodium hydroxide
20 percent of hydrogen peroxide
2 percent of ethyl acetate
8 percent of biological enzyme
The biological enzymes include pectinase, cellulase and xylanase.
Example 2
The scouring agent for the wool-polyester blended fabric comprises the following components in percentage by mass:
Fatty acid methyl ester ethoxylate sulfonate 30%
isomeric alcohol polyoxyethylene ether 5%
sodium dodecyl benzene sulfonate 20%
Polyoxypropyl polyoxyethyl glyceryl ether 5%
6 percent of sodium hydroxide
30 percent of hydrogen peroxide
Ethyl acetate 1%
3 percent of biological enzyme
The biological enzymes include pectinase, cellulase and xylanase.
Example 3
The scouring agent for the wool-polyester blended fabric comprises the following components in percentage by mass:
Fatty acid methyl ester ethoxy compound sulfonate 25%
isomeric alcohol polyoxyethylene ether 8%
Sodium dodecyl benzene sulfonate 20%
8% of polyoxypropyl polyoxyethylene glycerol ether
10 percent of sodium hydroxide
20 percent of hydrogen peroxide
2 percent of ethyl acetate
7 percent of biological enzyme
The biological enzymes include proteinases, xylanases, and laccases.
Claims (5)
1. A scouring agent for wool-polyester blended fabric is characterized in that: the composite material comprises the following components in percentage by mass:
20-30% of sulfonate of fatty acid methyl ester ethoxy compound
5-10% of isomeric alcohol polyoxyethylene ether
10 to 25 percent of sodium dodecyl benzene sulfonate
5-10% of polyoxypropyl polyoxyethyl glycerol ether
2 to 20 percent of sodium hydroxide
10-30% of hydrogen peroxide
1-2% of ethyl acetate
3-8% of biological enzyme.
2. The scouring agent for the wool-polyester blended fabric according to claim 1, which is characterized in that: the composite material comprises the following components in percentage by mass:
Fatty acid methyl ester ethoxy compound sulfonate 25%
Isomeric alcohol polyoxyethylene ether 8%
Sodium dodecyl benzene sulfonate 20%
8% of polyoxypropyl polyoxyethylene glycerol ether
10 percent of sodium hydroxide
20 percent of hydrogen peroxide
2 percent of ethyl acetate
7% of biological enzyme.
3. the scouring agent for the wool-polyester blended fabric according to claim 1 or 2, which is characterized in that: the biological enzyme comprises at least two of pectinase, cellulase, protease, xylanase and laccase.
4. The scouring agent for the wool-polyester blended fabric according to claim 3, which is characterized in that: the biological enzymes include pectinase, cellulase and xylanase.
5. The scouring agent for the wool-polyester blended fabric according to claim 3, which is characterized in that: the biological enzymes include proteinases, xylanases, and laccases.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910699102.XA CN110552202A (en) | 2019-07-31 | 2019-07-31 | Scouring agent for wool-polyester blended fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910699102.XA CN110552202A (en) | 2019-07-31 | 2019-07-31 | Scouring agent for wool-polyester blended fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110552202A true CN110552202A (en) | 2019-12-10 |
Family
ID=68736969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910699102.XA Pending CN110552202A (en) | 2019-07-31 | 2019-07-31 | Scouring agent for wool-polyester blended fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110552202A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114015425A (en) * | 2021-11-24 | 2022-02-08 | 克拉玛依新科澳石油天然气技术股份有限公司 | Oil well medium density emulsion paraffin remover and preparation and use method thereof |
-
2019
- 2019-07-31 CN CN201910699102.XA patent/CN110552202A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114015425A (en) * | 2021-11-24 | 2022-02-08 | 克拉玛依新科澳石油天然气技术股份有限公司 | Oil well medium density emulsion paraffin remover and preparation and use method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20191210 |
|
| WD01 | Invention patent application deemed withdrawn after publication |