CN105401467A - High-efficiency emulsifying, dispersing and deoiling agent - Google Patents
High-efficiency emulsifying, dispersing and deoiling agent Download PDFInfo
- Publication number
- CN105401467A CN105401467A CN201510696586.4A CN201510696586A CN105401467A CN 105401467 A CN105401467 A CN 105401467A CN 201510696586 A CN201510696586 A CN 201510696586A CN 105401467 A CN105401467 A CN 105401467A
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- CN
- China
- Prior art keywords
- degreaser
- emulsion dispersion
- deoiling
- dispersing
- efficient emulsion
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
- D06P1/623—Aliphatic, aralophatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/655—Compounds containing ammonium groups
- D06P1/66—Compounds containing ammonium groups containing quaternary ammonium groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67316—Acids
Abstract
The invention relates to a high-efficiency emulsifying, dispersing and deoiling agent. The high-efficiency emulsifying, dispersing and deoiling agent comprises, by weight, sodium n-butyl oleate solfonate, an alkyl polyoxyethylene derivative, polyoxyethylene-polyoxypropylene block copolymer, sodium chlorite, polyacrylamide, fatty alcohol sulfate monoethanolamine, tannic acid, dioctyl sebacate, lauryl alcohol polyoxyethylene ether phosphate, ethanol and deionized water; and the lauryl alcohol polyoxyethylene ether phosphate is prepared through the steps of reacting fatty alcohol with ethylene oxide to generate lauryl alcohol polyoxyethylene ether, esterifying the lauryl alcohol polyoxyethylene ether and phosphoric pentoxide, and neutralizing. The high-efficiency emulsifying, dispersing and deoiling agent has extremely strong deoiling, emulsifying and after-tack preventing functions, and can be used in decontaminating and deoiling for environmentally friendly fabric dyeing.
Description
Technical field
The present invention relates to a kind of textile auxiliary, particularly the efficient emulsion dispersion degreaser of one.
Background technology
At dyeing, terylene, polyester-cotton blend, washing the knitted cloths such as ammonia, is adopt cylindrical machine to carry out knitting forming mostly.In recent years, woven processing producer is in order to weave cotton cloth more efficiently and reduce costs, and most of producer can increase the use of finish and finish inferior greatly, and this can bring very large difficulty to dyeing and printing process undoubtedly.Dye-works often can run into the problem of look flower, color dot and the oil mark deoiled not to the utmost.If employing secondary operations, after namely first kiering is deoiled in the basic conditions, then Colour Difference, the advantage done like this be deoil clean, to shelter disease few, shortcoming is that energy consumption is large, and the process time is long, and cost is high.For this reason, generally the dyeing that deoils is adopted at present.But dyeing (PH is 4-4.5) must use under meta-acid condition owing to deoiling, this makes dye-works more and more higher to the requirement with bath degreaser, not only require low-consuming, efficiency of deoiling is high, also want that decontamination is strong, whiteness is high, capillary effect is good, dyeing light is bright-coloured, also will possess certain level-dyeing property simultaneously, foam is low, cylinder is less poor and environment-protecting asepsis.
At present, domestic degreaser all also exists such-and-such shortcoming: general decontamination ability of deoiling is strong, and emulsifying ability is poor again; Or greasy dirt has got off, bad the returning again of emulsification has been stained with on casing wall, and then returns again to be stained with above cloth and produce oil mark.Therefore, need to develop and a kind ofly both there is excellent emulsifying ability, solubilising, the detergency of dispersion and greasy dirt prevent back being stained with function, the decontamination degreaser of the slow dye level-dyeing property under hot conditions can be taken into account again, also want environment-protecting asepsis.
Summary of the invention
The object of the invention is to overcome the problems referred to above, provide a kind of efficient emulsion dispersion degreaser, it has the extremely strong emulsification and prevent back being stained with function and textile dyeing decontamination for environmental protection is deoiled of deoiling.
To achieve these goals, the present invention adopts following technical scheme: a kind of efficient emulsion dispersion degreaser, with parts by weight, composed of the following components:
N butyl oleate sodium sulfonate 20-30
Alkyl polyoxyethylene derivative 15-18
Polyox-yethylene-polyoxypropylene block copolymer 12-16
Sodium chlorite 3-7
Polyacrylamide 2-8
Fatty alcohol sulfate single ethanol ammonium salt 0.5-3
Tannic acid 4-8
Di-n-octyl sebacate 10-20
Ethoxylated dodecyl alcohol phosphate 2-5
Ethanol 30-50
Deionized water 80-100;
Described ethoxylated dodecyl alcohol phosphate generates ethoxylated dodecyl alcohol by fatty alcohol and reacting ethylene oxide, then with phosphorus pentoxide esterification, neutralize and get final product.
Further, described efficient emulsion dispersion degreaser also comprises with the Macrogol 600 of parts by weight 15-20 part.
Further, described efficient emulsion dispersion degreaser in use dressing liquid pH value remain on 5-7 the best.
Beneficial effect: efficient emulsion dispersion degreaser of the present invention has the extremely strong emulsification and prevent back being stained with function of deoiling, particularly for a lot of spandex of some greasy dirts, terylene class stockinette, as coral fleece has, two-sided bullet, spandex fabric, spandex are many, and wire drawing oil on spandex is a lot, what have also contains silicone oil, can realize co-bathing dyeing by adding efficient emulsion dispersion degreaser of the present invention.
With polyster fibre, cotton fiber affinity interaction while that the present invention adopting detergent n butyl oleate sodium sulfonate to coordinate polyox-yethylene-polyoxypropylene block copolymer and di-n-octyl sebacate, phenyl ring under condition of heating rapidly and on polyster fibre, the occupy-place of carbon ester molecule chain bonding, by robbing an effect and strong hydrophilicity effect, greasy dirt molecule is forced down, this deoils to release dirty core.
The present invention adds non-ionic surface active agent ethoxylated dodecyl alcohol phosphate simultaneously preferably, and it is that emulsification deoils can the strongest raw material of function, and this non-ionic surface active agent is nontoxic without hormone effect, belongs to environment-friendly products; Simultaneously, it retains stronger detergency, still identical with polyoxyethylene nonylphenol ether, even better, be easy at high temperature combine with polyster fibre under the synergy of fatty alcohol sulfate single ethanol ammonium salt and be stained with crowded for soil molecules, improve detersive efficiency.
Detailed description of the invention
Below by embodiment, technical scheme of the present invention is described in further detail.
Embodiment one:
A kind of efficient emulsion dispersion degreaser, with parts by weight, composed of the following components:
N butyl oleate sodium sulfonate 20
Alkyl polyoxyethylene derivative 15
Polyox-yethylene-polyoxypropylene block copolymer 12
Sodium chlorite 3
Polyacrylamide 2
Fatty alcohol sulfate single ethanol ammonium salt 0.5
Tannic acid 4
Di-n-octyl sebacate 10
Ethoxylated dodecyl alcohol phosphate 2
Ethanol 30
Deionized water 80;
Described ethoxylated dodecyl alcohol phosphate generates ethoxylated dodecyl alcohol by fatty alcohol and reacting ethylene oxide, then with phosphorus pentoxide esterification, neutralize and get final product.Described efficient emulsion dispersion degreaser also comprises with the Macrogol 600 of parts by weight 15 parts.Described efficient emulsion dispersion degreaser in use dressing liquid pH value remains on 5-7 the best.
Embodiment two:
A kind of efficient emulsion dispersion degreaser, with parts by weight, composed of the following components:
N butyl oleate sodium sulfonate 30
Alkyl polyoxyethylene derivative 18
Polyox-yethylene-polyoxypropylene block copolymer 16
Sodium chlorite 7
Polyacrylamide 8
Fatty alcohol sulfate single ethanol ammonium salt 3
Tannic acid 8
Di-n-octyl sebacate 20
Ethoxylated dodecyl alcohol phosphate 5
Ethanol 50
Deionized water 100;
Described ethoxylated dodecyl alcohol phosphate generates ethoxylated dodecyl alcohol by fatty alcohol and reacting ethylene oxide, then with phosphorus pentoxide esterification, neutralize and get final product.Described efficient emulsion dispersion degreaser also comprises with the Macrogol 600 of parts by weight 20 parts.Described efficient emulsion dispersion degreaser in use dressing liquid pH value remains on 5-7 the best.
The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (3)
1. an efficient emulsion dispersion degreaser, is characterized in that, with parts by weight, composed of the following components:
N butyl oleate sodium sulfonate 20-30
Alkyl polyoxyethylene derivative 15-18
Polyox-yethylene-polyoxypropylene block copolymer 12-16
Sodium chlorite 3-7
Polyacrylamide 2-8
Fatty alcohol sulfate single ethanol ammonium salt 0.5-3
Tannic acid 4-8
Di-n-octyl sebacate 10-20
Ethoxylated dodecyl alcohol phosphate 2-5
Ethanol 30-50
Deionized water is about 80-100;
Described ethoxylated dodecyl alcohol phosphate generates ethoxylated dodecyl alcohol by fatty alcohol and reacting ethylene oxide, then with phosphorus pentoxide esterification, neutralize and get final product.
2. the efficient emulsion dispersion degreaser of one according to claim 1, is characterized in that, described efficient emulsion dispersion degreaser also comprises with the Macrogol 600 of parts by weight 15-20 part.
3. the efficient emulsion dispersion degreaser of the one according to claim 1 and 2, is characterized in that, described efficient emulsion dispersion degreaser in use dressing liquid pH value remains on 5-7 the best.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510696586.4A CN105401467A (en) | 2015-10-26 | 2015-10-26 | High-efficiency emulsifying, dispersing and deoiling agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510696586.4A CN105401467A (en) | 2015-10-26 | 2015-10-26 | High-efficiency emulsifying, dispersing and deoiling agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105401467A true CN105401467A (en) | 2016-03-16 |
Family
ID=55467201
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510696586.4A Pending CN105401467A (en) | 2015-10-26 | 2015-10-26 | High-efficiency emulsifying, dispersing and deoiling agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105401467A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105862170A (en) * | 2016-04-18 | 2016-08-17 | 温州泓呈祥科技有限公司 | Production method of spinning solution having memory function |
| CN108570360A (en) * | 2018-04-26 | 2018-09-25 | 浙江汉邦化工有限公司 | A kind of guarantor's color vividization unclogging agent |
| CN115073280A (en) * | 2022-08-02 | 2022-09-20 | 马鞍山同杰良生物材料有限公司 | Method for recovering high-optical-purity lactic acid from polylactic acid synthetic substrate |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59168187A (en) * | 1983-03-15 | 1984-09-21 | 三菱レイヨン株式会社 | Production of acrylic fiber excellent in stain removing property |
| CN1523095A (en) * | 2003-09-10 | 2004-08-25 | 清远市灵捷制造化工有限公司 | Thickening agent for liquid lotion and its preparation method and application |
| CN1730729A (en) * | 2005-06-16 | 2006-02-08 | 广州天至环保科技有限公司 | Biological degreasing agent used in metal processing pretreatment of oil removing and degreasing, and method for processing metal surface greasy dirt |
| CN101058781A (en) * | 2007-05-24 | 2007-10-24 | 朱思聪 | Low-temperature energy-saving emulsifier for industrial washing clothes |
-
2015
- 2015-10-26 CN CN201510696586.4A patent/CN105401467A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59168187A (en) * | 1983-03-15 | 1984-09-21 | 三菱レイヨン株式会社 | Production of acrylic fiber excellent in stain removing property |
| CN1523095A (en) * | 2003-09-10 | 2004-08-25 | 清远市灵捷制造化工有限公司 | Thickening agent for liquid lotion and its preparation method and application |
| CN1730729A (en) * | 2005-06-16 | 2006-02-08 | 广州天至环保科技有限公司 | Biological degreasing agent used in metal processing pretreatment of oil removing and degreasing, and method for processing metal surface greasy dirt |
| CN101058781A (en) * | 2007-05-24 | 2007-10-24 | 朱思聪 | Low-temperature energy-saving emulsifier for industrial washing clothes |
Non-Patent Citations (2)
| Title |
|---|
| 陈溥等: "《纺织染整助剂手册》", 31 August 1995, 中国轻工业出版社 * |
| 韩长日等: "《精细有机化工产品生产技术手册》", 31 May 2010, 中国石化出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105862170A (en) * | 2016-04-18 | 2016-08-17 | 温州泓呈祥科技有限公司 | Production method of spinning solution having memory function |
| CN105862170B (en) * | 2016-04-18 | 2018-08-17 | 南通市苏中纺织有限公司 | A kind of manufacturing method for the spinning solution having memory function |
| CN108570360A (en) * | 2018-04-26 | 2018-09-25 | 浙江汉邦化工有限公司 | A kind of guarantor's color vividization unclogging agent |
| CN108570360B (en) * | 2018-04-26 | 2021-12-17 | 浙江汉邦新材料股份有限公司 | Color-preserving brightening oil stain removing agent |
| CN115073280A (en) * | 2022-08-02 | 2022-09-20 | 马鞍山同杰良生物材料有限公司 | Method for recovering high-optical-purity lactic acid from polylactic acid synthetic substrate |
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Application publication date: 20160316 |