CN110540346A - 处理酸洗磷化废水的方法 - Google Patents

处理酸洗磷化废水的方法 Download PDF

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CN110540346A
CN110540346A CN201910912915.2A CN201910912915A CN110540346A CN 110540346 A CN110540346 A CN 110540346A CN 201910912915 A CN201910912915 A CN 201910912915A CN 110540346 A CN110540346 A CN 110540346A
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wastewater
tank
acid pickling
treating acid
water
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马晴
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Jiangsu Zhongzhi Xinyu Environmental Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
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    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
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    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/12Treatment of sludge; Devices therefor by de-watering, drying or thickening
    • C02F11/121Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
    • C02F11/122Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering using filter presses
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
    • C02F2203/006Apparatus and plants for the biological treatment of water, waste water or sewage details of construction, e.g. specially adapted seals, modules, connections
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/06Controlling or monitoring parameters in water treatment pH
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
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    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N
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    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/04Flow arrangements
    • C02F2301/046Recirculation with an external loop
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C02F2303/06Sludge reduction, e.g. by lysis
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    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
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    • C02F3/02Aerobic processes
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    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/109Characterized by the shape

Abstract

发明涉及废水处理技术领域,尤其是处理酸洗磷化废水的方法。该方法的步骤为:a)将废水送入调节池内进行搅拌与预曝气处理;b)调节池内的废水流入中和池进行PH值调节;c)中和池内的废水流入曝气氧化池内进行内进行生化处理,曝气氧化池利用生物组合填料来去除废水的BOD并吸收废水里的磷;本发明通过中和池来调整废水PH值。通过曝气氧化池为废水去除BOD并去磷。通过混凝反应池捕捉废水中的有机物,降解废水COD。通过沉淀池将水与沉淀物分离。通过连续膜过滤系统将废水过滤为可再次利用的水。通过PH回调值调整水的PH值。本申请可以将废水处理为可再次利用的水,从而实现了水的循环利用。

Description

处理酸洗磷化废水的方法
技术领域
发明涉及废水处理技术领域,尤其是处理酸洗磷化废水的方法。
背景技术
现有的来自厂区的酸洗磷化废水需要进行处理。但是现有传统工艺的处理方法,只能将废水处理成排放达标的废水,而不能将废水处理为可再次利用的水。
发明内容
为了解决背景技术中描述的技术问题,发明提供了一种处理酸洗磷化废水的方法,通过中和池来调整废水PH值。通过曝气氧化池为废水去除BOD并去磷。通过混凝反应池捕捉废水中的有机物,降解废水COD。通过沉淀池将水与沉淀物分离。通过连续膜过滤系统将废水过滤为可再次利用的水。通过PH回调值调整水的PH值。本申请可以将废水处理为可再次利用的水,从而实现了水的循环利用。
本发明解决其技术问题所采用的技术方案是:
一种处理酸洗磷化废水的方法,该方法的步骤为:
a)将废水送入调节池内进行搅拌与预曝气处理;
b)调节池内的废水流入中和池进行PH值调节;
c)中和池内的废水流入曝气氧化池内进行内进行生化处理,曝气氧化池利用生物组合填料来去除废水的BOD并吸收废水里的磷;
d)将曝气氧化池内的废水送入混凝反应池内,通过在混凝反应池的废水内投入混凝剂和絮凝剂来捕捉废水内的不溶性有机物并降解废水COD;
e)混凝反应池内的废水流入沉淀池内分离成上清液和沉淀物,沉淀物排入污泥浓缩池,上清液流入连续膜过滤系统进行过滤,过滤后的上清液流入PH回调池内调整PH值后成为可再次利用的水;
f)污泥浓缩池内分离出的沉淀物通过板框压滤机进行脱水,而污泥浓缩池的溢流液与板框压滤机的滤液排至调节池内进行再处理。
具体地,步骤e)中,所述连续膜过滤系统是使用无机陶瓷膜为过滤膜管的装置。
具体地,步骤c)中,所述生物组合填料是由塑料圆环和纤维束组成,塑料圆环由外外圈与内圈组成,纤维束连接分布在塑料圆环的外圈,纤维束上附着有活性微生物,塑料圆环的内圈设有数个枝条。
具体地,所述纤维束为醛化纤维或涤纶丝。
具体地,步骤d)中,所述混凝剂为聚合氯化铝。
具体地,步骤d)中,所述絮凝剂为聚丙烯酰胺。
具体地,所述曝气氧化池与混凝反应池之间连接有提升泵。
具体地,所述中和池通过NaOH来调节废水的PH值。
具体地,所述PH回调池通过H2SO4来调节废水的PH值。
本发明的有益效果是:本发明提供了一种处理酸洗磷化废水的方法,通过中和池来调整废水PH值。通过曝气氧化池为废水去除BOD并去磷。通过混凝反应池捕捉废水中的有机物,降解废水COD。通过沉淀池将水与沉淀物分离。通过连续膜过滤系统将废水过滤为可再次利用的水。通过PH回调值调整水的PH值。本申请可以将废水处理为可再次利用的水,从而实现了水的循环利用。
附图说明
下面结合附图和实施例对发明进一步说明。
图1是本发明的框架示意图;
具体实施方式
现在结合附图对发明作进一步详细的说明。这些附图均为简化的示意图,仅以示意方式说明发明的基本结构,因此其仅显示与发明有关的构成。
图1是本发明的框架示意图。
如附图1所示,来自厂区生产废水进入调节池,同时鼓入空气对调节池内废水进行预曝气和搅拌,混合均质,有效削减冲击负荷,以起到对后续处理单元的保护作用,避免不溶性悬浮物池内堆积和发酵,还可吹脱氧化低分子有机物。。
随后废水自流至中和池,同时往中和池内投加NaOH药剂以调节废水的PH值。
中和池废水自流至曝气氧化池内进行生化处理,曝气氧化池内置放大量曝气管并挂满优质的生物组合填料。该生物组合填料是由塑料圆环和纤维束组成,塑料圆环由外外圈与内圈组成,纤维束连接分布在塑料圆环的外圈,纤维束上附着有活性微生物,塑料圆环的内圈设有数个枝条。枝条为雪花状。该雪花状枝条既能挂膜,又能有效切割气泡,提高氧的转移速率和利用率,使得水气生物膜能够得到充分交换,使水中的有机物得到高效处理。曝气气泡细密,氧转移效率高,在好氧条件下,活性微生物的硝化作用将NH3-N(NH4+)氧化为NO3-,去除BOD、吸收磷,处理后的废水则流入混凝反应池。
同时往混凝反应池内投加混凝剂PAC(聚合氯化铝)和絮凝剂PAM(聚丙烯酰胺)药剂,捕捉废水中的不溶解性有机物,降解废水COD。
混凝反应池内的废水流入沉淀池内,沉淀池将废水分离成上清液与沉淀物,沉淀物沉淀后由空去气提装置排入污泥浓缩池内。上清液自流入连续膜过滤系统的水箱内,利用水压压力,含小分子组分的渗透液沿与之垂直方向向外透过无机陶瓷膜的膜管管壁,含大分子组分的混浊浓缩液被膜管截留住,最后渗出膜管管壁的渗透液进入到PH回调池内,PH回调池内通过H2SO4调节渗透液的PH值,渗透液就成为可再利用的水。
污泥浓缩池内设曝气系统,利用微生物的内源呼吸减少沉淀物产生量,板框压滤机则对沉淀物进行减量化脱水,脱水后沉淀物定期外运处置。污泥浓缩池的溢流液及板框压滤机的滤液排至调节池进行再次处理。
以上述依据发明的理想实施例为启示,通过上述的说明内容,相关工作人员完全可以在不偏离本项发明技术思想的范围内,进行多样的变更以及修改。本项发明的技术性范围并不局限于说明书上的内容,必须要根据权利要求范围来确定其技术性范围。

Claims (9)

1.一种处理酸洗磷化废水的方法,其特征在于:该方法的步骤为:
a)将废水送入调节池内进行搅拌与预曝气处理;
b)调节池内的废水流入中和池进行PH值调节;
c)中和池内的废水流入曝气氧化池内进行内进行生化处理,曝气氧化池利用生物组合填料来去除废水的BOD并吸收废水里的磷;
d)将曝气氧化池内的废水送入混凝反应池内,通过在混凝反应池的废水内投入混凝剂和絮凝剂来捕捉废水内的不溶性有机物并降解废水COD;
e)混凝反应池内的废水流入沉淀池内分离成上清液和沉淀物,沉淀物排入污泥浓缩池,上清液流入连续膜过滤系统进行过滤,过滤后的上清液流入PH回调池内调整PH值后成为可再次利用的水;
f)污泥浓缩池内分离出的沉淀物通过板框压滤机进行脱水,而污泥浓缩池的溢流液与板框压滤机的滤液排至调节池内进行再处理。
2.根据权利要求1所述的处理酸洗磷化废水的方法,其特征在于:步骤e)中,所述连续膜过滤系统是使用无机陶瓷膜为过滤膜管的装置。
3.根据权利要求1所述的处理酸洗磷化废水的方法,其特征在于:步骤c)中,所述生物组合填料是由塑料圆环和纤维束组成,塑料圆环由外外圈与内圈组成,纤维束连接分布在塑料圆环的外圈,纤维束上附着有活性微生物,塑料圆环的内圈设有数个枝条。
4.根据权利要求3所述的处理酸洗磷化废水的方法,其特征在于:所述纤维束为醛化纤维或涤纶丝。
5.根据权利要求1所述的处理酸洗磷化废水的方法,其特征在于:步骤d)中,所述混凝剂为聚合氯化铝。
6.根据权利要求1所述的处理酸洗磷化废水的方法,其特征在于:步骤d)中,所述絮凝剂为聚丙烯酰胺。
7.根据权利要求1所述的处理酸洗磷化废水的方法,其特征在于:所述曝气氧化池与混凝反应池之间连接有提升泵。
8.根据权利要求1所述的处理酸洗磷化废水的方法,其特征在于:所述中和池通过NaOH来调节废水的PH值。
9.根据权利要求1所述的处理酸洗磷化废水的方法,其特征在于:所述PH回调池通过H2SO4来调节废水的PH值。
CN201910912915.2A 2019-09-25 2019-09-25 处理酸洗磷化废水的方法 Withdrawn CN110540346A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113387511A (zh) * 2021-06-17 2021-09-14 南京工大膜应用技术研究所有限公司 一种磷化废水零排放装置及工艺流程

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113387511A (zh) * 2021-06-17 2021-09-14 南京工大膜应用技术研究所有限公司 一种磷化废水零排放装置及工艺流程

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Application publication date: 20191206