CN110527227A - A kind of environmental protection froths glue and its preparation process - Google Patents
A kind of environmental protection froths glue and its preparation process Download PDFInfo
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- CN110527227A CN110527227A CN201910569041.5A CN201910569041A CN110527227A CN 110527227 A CN110527227 A CN 110527227A CN 201910569041 A CN201910569041 A CN 201910569041A CN 110527227 A CN110527227 A CN 110527227A
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- glue
- froths
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- plasticizer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L31/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid; Compositions of derivatives of such polymers
- C08L31/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C08L31/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A kind of environmental protection froths glue, including 60 ~ 80 parts of fluoropolymer resin, 15 ~ 30 parts of ethyl alcohol, 0.5 ~ 2 part of isopropanol, 1 ~ 4 part of plasticizer, 0.5 ~ 2 part of methyl acetate in terms of mass fraction.Ethyl alcohol, isopropanol dissolve fluoropolymer resin, without using toxic solvent as solvent, the safety of product is improved, plasticizer is environment-friendlyplasticizer plasticizer, non-phthalate, it is safe and non-toxic, meet the requirement of China and American-European countries's environmental protection, remove colloidal sol bubble, increases the soft and elastic of bubble glue, and it can assign elastomer good cold resistance, heat resistance, water resistance promote the glue adaptability asynchronous for environment that froths.
Description
Technical field
The present invention relates to the technical fields of glue, and in particular to a kind of environmental protection froths glue and its preparation process.
Background technique
Bubble glue is a kind of sticking colloid, is filled in hose, has a plastic suction pipe.In use, taking out one
Small bubble glue surrounds one end of plastic tube, and then with mouth in the other end featheriness of suction pipe, bubble glue can be expanded into user
One small bubble (tiny balloons).So bubble glue also known as blows wave ball glue or space balloon, main component is polyvinyl acetate
Ester.Polyvinyl acetate abbreviation PVAC is a kind of flexible synthetic polymer, polymerization through vinylacetate VAM preparation and
At being solid polymer, appearance colorless is transparent, odorless, flexible and plasticity.1912 by F. carats of special discoveries.To light and heat
Stablize, resistance to diluted acid and diluted alkaline, characteristic is that bonding force is strong.Dissolve in alcohols (methanol, ethyl alcohol, isopropanol, n-butanol etc.), ketone,
Esters, benzene class (aromatic hydrocarbon), chlorinated hydrocabon (carbon tetrachloride, trichloro ethylene, methylene chloride, chloroform) do not dissolve in fatty acid, water, height
Grade alcohol, aliphatic hydrocarbon, in carbon disulfide；Its purposes can be used as solid, coating, papermaking coating agent, weave and starch the raw material and bubble of agent
Bubble gum substrate；Industrially polyvinyl acetate resins mainly use in the form of an emulsion, are white " milky " liquid, a little remaining second
Vinyl acetate smell is not particularly suited for the use of toy range, and should be using poly-vinegar acid obtained after de- pure ethyl acetate technique
Vinyl acetate does not have the residual of ethyl acetate, more meets American-European, Japan and Korea S toy management requirements, and the children of China are used
When safety, it is more secure.It must be added to organic solvent with polyvinyl acetate production " bubble glue " and be at colloidal sol
Shape, the most frequently used is the organic solvents such as acetone, butanone, ethyl acetate, so bringing pungent smell.
Acetone, slight depressor of nerve centre, high concentration steam may cause headache, nausea, dizziness, drowsiness, movement not
Possible suck-back enters lung when coordinating obscure with spirit, stimulate eyes, eating or vomit, and being exposed under acetone will increase chlorinated solvent
Hepatotoxicity wind agitation, sucking will affect its reproductive capacity of mammal.
Butanone belongs to toxic solvent, has apparent injury for human respiratory tract mucosa and nerve center.Route of entry:
It sucks, eat, percutaneous absorbtion.Health hazard: irritant to eye, nose, larynx, mucous membrane.Long Term Contact can cause dermatitis.This product often with
Methyl-n-butyl ketone mixing application, can reinforce peripheral nerve disease phenomenon caused by methyl-n-butyl ketone, but individually contact butanone finds no mind around
Through sick phenomenon.
Ethyl acetate, to eye, nose, the irritating effect of throat.High concentration sucking can draw progressive anesthetic effect, acute edema with the lung involved
It is swollen, liver, renal damage.Continue largely to suck, respiratory paralysis can be caused.The person of wrongly taking can produce Nausea and vomiting, abdominal pain, diarrhea etc..There is cause
Quick effect causes bleeding gums because of nervus vasculairs obstacle；It can cause eczema-like dermatitis.Chronic Effect: Long Term Contact this product sometimes may be used
Cause the opacity of the cornea, secondary anemia, leukocytosis etc..
Three is all in chemicals whole world reconciliation system, under nuisance project, organic solvent poisoning prevention rules and specific
Chemical substance damage prevention standard, listed substance.Many benzene-like compounds, it is disabled.Acetone still generally appears in so far
In various product, such as the water that delusters.
The influence of common organic solvents harm to the human body physiology has following several:
Inhibit nervous system, generate nervous system disorders or cause neuritis etc., most organic solvents have this toxicity.Cause liver
Dirty intoxicating phenomenon causes to damage to liver function, and such solvent has benzene and its derivative etc..Influence kidney function, such solvent
Halide, benzene and its derivative, dihydric alcohol and its monoether class including hydro carbons etc..Marrow is destroyed, hematopoiesis function is influenced, it is such molten
Agent includes benzene and its derivative.Stimulate mucous membrane and skin, ether, benzene, acetone, halide of hydro carbons etc..
In addition, or inhibition toxic to microorganism can be generated during this kind of organic solvent is synthetically produced, it is difficult to point
The pernicious gas and waste water of solution, possible contaminated soil and underground water cause carrying capacity of environment, and increase human health risk.
In the addition of solvent components and product standard, each manufacturer of bubble glue industry are completely different: in order to reduce
The organic solvent of inexpensive high toxicity is added directly into product by cost, some dealers, and this kind of product has the strong of similar paint-like flavour
Strong pungent taste, similar seccotine.
However, the user of bubble glue this kind of product is mostly infants and children, indoors or outdoor all usable, child is blowing
When bubble, toxic component can be damaged schneiderian membrane with respiratory tract is entered, and for the child of allergic constitution
It is more likely to cause serious consequence, such as is short of breath, has a headache.Several years ago, once there is child's sucking or ate bubble glue by mistake, caused
It falls in a swoon, body rigidity, the symptoms such as stupor and twitch indicate that the nervous system of child has been damaged.
Synthesis is as described above, face toxicity and injury brought by organic solvent, for the safety and protection ring of user
Border, the solvent that then formula of the invention uses is predominantly ethyl alcohol, is nontoxic green to human health and environmentally friendly
Color solvent, to promote the safety and the feature of environmental protection of bubble glue product.Secondary isopropanol, the methyl acetate less for ratio etc. are molten
Agent, the Chemical Solvents to substitute the low-flashes such as acetone, butanone, ethyl acetate, strong solubility, high smell.Main function is to add
Strong dissolution fluoropolymer resin makes its extension film forming at can be uniform with thickness when balloon, can fast dry forming spherical shape, the present invention mention
This field goes out a kind of safer environmentally friendly bubble glue at present, to ensure the safety of user without anxiety and to the protectiveness of environment.
Summary of the invention
Goal of the invention of the invention is to overcome the problems, such as of the existing technology, provides a kind of highly-safe, nonhazardous
Froth glue.
Another goal of the invention of the invention is to overcome the problems, such as of the existing technology, provides a kind of highly-safe, nontoxic
The preparation process of the harmful glue that froths.
Technical solution of the present invention is as follows:
A kind of environmental protection froths glue, in terms of mass fraction including
60 ~ 80 parts of fluoropolymer resin,
15 ~ 30 parts of ethyl alcohol
0.5 ~ 2 part of isopropanol
1 ~ 4 part of plasticizer
0.5 ~ 2 part of methyl acetate.
Wherein, in terms of mass fraction including
72 parts of polyvinyl acetate,
21 parts of ethyl alcohol
1 part of isopropanol
2.5 parts of plasticizer
1 part of methyl acetate.
Wherein, fluoropolymer resin is polyvinyl butyral, polyvinyl acetate, vinylacetate-vinylalcohol butyral
One of copolymer or more than one mixture.
Wherein, the plasticizer be diethylene glycol dibenzoate, the double isobutyrates of 2.2.4- trimethyl 1.3- pentanediol its
One or both of mixture.
It wherein, further include antitack agent, antitack agent is 0.2 ~ 1 part.
Wherein, the antitack agent is one of silicone oil, fluorosilicon oil, vegetable oil, mineral oil or more than one mixture.
It wherein, further include fragrance, the fragrance is 0.2 ~ 1 part.
It wherein, further include pigment, the pigment is 0.5 ~ 2 part.
Wherein, the pigment includes haematochrome, uranidin and cyanine, and the haematochrome is RED53:1, the uranidin
For YELLOWPY-13, the cyanine is BLUE15:3.
A kind of environmental protection froths the preparation process of glue, and the ethyl alcohol and plasticizer being first added are added portionwise poly- in stirring
Polymer resin, resin to be polymerized are all dissolved into uniform paste, add pigment and antitack agent, obtain after mixing evenly
Finished product.
A kind of environmental protection froths glue, in terms of mass fraction including, 60 ~ 80 parts of fluoropolymer resin, 15 ~ 30 parts of ethyl alcohol, isopropanol
0.5 ~ 2 part, 1 ~ 4 part of plasticizer, 0.5 ~ 2 part of methyl acetate.
Ethyl alcohol, isopropanol dissolve fluoropolymer resin without using toxic solvent and improve the safety of product as solvent,
Plasticizer is environment-friendlyplasticizer plasticizer, non-phthalate, safe and non-toxic, meets the requirement of China and American-European countries's environmental protection, goes
Except colloidal sol bubble, increase the soft and elastic of bubble glue, and can assign elastomer good cold resistance, heat resistance, water resistance is promoted
The glue that froths adaptability asynchronous for environment.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, with reference to embodiments, to the present invention
It is further described into column.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.
Embodiment 1
A kind of environmental protection froths glue, including polyvinyl butyral 60g, ethyl alcohol 15g isopropanol 2g, plasticizer 4g, methyl acetate 2g.
Ethyl alcohol 15g, isopropanol 2g, diethylene glycol dibenzoate and 2.2.4- trimethyl 1.3- penta 2 are first added into closed agitator tank
Alcohol double isobutyrate mixture 4g, methyl acetate 2g, start blender, 60-180 turns of mixing speed/min is added portionwise poly-
Vinyl butyral 60g, after system becomes homogeneous paste, adding haematochrome is RED53 2g, silicone oil 0.5g, and stirring is equal
After even, lotion viscosity is ten thousand mPas of 15-25, and the experimental check qualification that frothed froths glue product to get red of the invention.
Embodiment 2
A kind of environmental protection froths glue, including polyvinyl acetate 72g, ethyl alcohol 21g, isopropanol 1g, plasticizer 2.5g, methyl acetate
1g.Ethyl alcohol 21g, isopropanol 1g are first added into closed agitator tank, diethylene glycol dibenzoate 2.5g starts blender, second
Polyvinyl acetate 72g is added portionwise in sour methyl esters 1g, 60-180 turns of mixing speed/min, becomes homogeneous paste to system
Afterwards, adding uranidin is YELLOWPY-13 2g, vegetable oil 2g, and after mixing evenly, lotion viscosity is ten thousand mPas of 15-25,
The experimental check qualification that frothed froths glue product to get yellow of the invention.
Embodiment 3
A kind of environmental protection froths glue, including 80 g of fluoropolymer resin, 30 g of ethyl alcohol, isopropanol 2 g, plasticizer 1g, methyl acetate
0.5g.The first addition ethyl alcohol 30g into closed agitator tank, 2 parts of isopropanol, the double isobutyrates of 2.2.4- trimethyl 1.3- pentanediol
1g, methyl acetate 0.5g start blender, and polyvinyl butyral, poly-vinegar is added portionwise in 60-180 turns of mixing speed/min
The mixture 60g of vinyl acetate and vinylacetate-vinylalcohol butyral copolymer, after system becomes homogeneous paste, then
Addition haematochrome is RED53 1g, fluorosilicon oil 0.5g, and after mixing evenly, lotion viscosity is ten thousand mPas of 15-25, and frothed experiment
It examines and qualified froths glue product to get red of the invention.
Embodiment 4
A kind of environmental protection froths glue, including 70 g of fluoropolymer resin, 20 g of ethyl alcohol, isopropanol 3 g, plasticizer 3g, methyl acetate 1g.
The first addition ethyl alcohol 20g into closed agitator tank, 3 parts of isopropanol, the double isobutyrate 3g of 2.2.4- trimethyl 1.3- pentanediol,
Methyl acetate 1g starts blender, and polyvinyl butyral 70g is added portionwise in 60-180 turns of mixing speed/min, to system at
After homogeneous paste, adding cyanine is BLUE15 2g, vegetable oil 2g, and after mixing evenly, lotion viscosity is 15-25 ten thousand
MPas, the experimental check qualification that frothed froth glue product to get blue of the invention.
Embodiment 5
A kind of environmental protection froths glue, including 70 g of fluoropolymer resin, 20 g of ethyl alcohol, isopropanol 3 g, plasticizer 3g, methyl acetate 1g.
Ethyl alcohol 20g is first added into closed agitator tank, starts blender, polyethylene is added portionwise in 60-180 turns of mixing speed/min
Butyral 70g, after system becomes homogeneous paste, adding cyanine is BLUE15 2g, fragrance 2g, vegetable oil 2g, stirring
After uniformly, lotion viscosity is ten thousand mPas of 15-25, and the experimental check qualification that frothed froths glue product to get blue of the invention.
Vegetable oil in the present embodiment can also be silicone oil, fluorosilicon oil, the mixture of mineral oil or silicone oil, fluorosilicon oil, mine
Object oil, vegetable oil, the mixture of any one combination of the above.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
In the technical scope disclosed by the present invention, any changes or substitutions that can be easily thought of by anyone skilled in the art,
It should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be with scope of protection of the claims
Subject to.
Claims (10)
- The glue 1. a kind of environmental protection froths, it is characterised in that: in terms of mass fraction including60 ~ 80 parts of fluoropolymer resin,15 ~ 30 parts of ethyl alcohol,0.5 ~ 2 part of isopropanol,1 ~ 4 part of plasticizer,0.5 ~ 2 part of methyl acetate.
- The glue 2. a kind of environmental protection according to claim 1 froths, it is characterised in that: in terms of mass fraction including70 ~ 75 parts of fluoropolymer resin,20 ~ 25 parts of ethyl alcohol,0.9 ~ 1.5 part of isopropanol,2 ~ 4 parts of plasticizer,0.9 ~ 1.5 part of methyl acetate.
- The glue 3. a kind of environmental protection according to claim 1 froths, it is characterised in that: fluoropolymer resin is polyvinyl alcohol contracting fourth Aldehyde, polyvinyl acetate, vinylacetate-vinylalcohol butyral one of copolymer or more than one mixture.
- The glue 4. a kind of environmental protection according to claim 1 froths, it is characterised in that: the plasticizer is diethylene glycol (DEG) dibenzoic acid The double isobutyrates of ester, 2.2.4- trimethyl 1.3- pentanediol are one such or two kinds of mixture.
- The glue 5. a kind of environmental protection according to claim froths, it is characterised in that: further include antitack agent, antitack agent is 0.2 ~ 1 Part.
- The glue 6. a kind of environmental protection according to claim 5 froths, it is characterised in that: the antitack agent is silicone oil, fluorosilicon oil, plant One of object oil, mineral oil or more than one mixture.
- The glue 7. a kind of environmental protection according to claim 1 froths, it is characterised in that: further include fragrance, the fragrance is 0.2 ~ 1 Part.
- The glue 8. a kind of environmental protection according to claim 1 froths, it is characterised in that: further include pigment, the pigment is 0.5 ~ 2 Part.
- The glue 9. a kind of environmental protection according to claim 4 froths, it is characterised in that: the pigment includes haematochrome, uranidin And cyanine, the haematochrome are RED53:1, the uranidin is YELLOWPY-13, and the cyanine is BLUE15:3.
- 10. a kind of frothed the preparation process of glue using environmental protection described in claim 1 to 9 any one, it is characterised in that: first plus The ethyl alcohol and plasticizer entered, fluoropolymer resin is added portionwise in stirring, and resin to be polymerized is all dissolved into uniformly Paste adds pigment and antitack agent, obtains finished product after mixing evenly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910569041.5A CN110527227A (en) | 2019-06-27 | 2019-06-27 | A kind of environmental protection froths glue and its preparation process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910569041.5A CN110527227A (en) | 2019-06-27 | 2019-06-27 | A kind of environmental protection froths glue and its preparation process |
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| Publication Number | Publication Date |
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| CN110527227A true CN110527227A (en) | 2019-12-03 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201910569041.5A Pending CN110527227A (en) | 2019-06-27 | 2019-06-27 | A kind of environmental protection froths glue and its preparation process |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114479329A (en) * | 2022-03-15 | 2022-05-13 | 广州欣东塑胶玩具有限公司 | Environment-friendly wave-blowing adhesive and preparation process thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN2611002Y (en) * | 2003-04-10 | 2004-04-14 | 李序光 | Tube for blowing to produce pawpaw |
| CN102795865A (en) * | 2011-05-25 | 2012-11-28 | 广州三则电子材料有限公司 | Environment-friendly bonding agent for ceramic sheet tape casting and preparation method of bonding agent |
| CN204973091U (en) * | 2015-10-06 | 2016-01-20 | 李雪坤 | Novel froth system for stage |
-
2019
- 2019-06-27 CN CN201910569041.5A patent/CN110527227A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2611002Y (en) * | 2003-04-10 | 2004-04-14 | 李序光 | Tube for blowing to produce pawpaw |
| CN102795865A (en) * | 2011-05-25 | 2012-11-28 | 广州三则电子材料有限公司 | Environment-friendly bonding agent for ceramic sheet tape casting and preparation method of bonding agent |
| CN204973091U (en) * | 2015-10-06 | 2016-01-20 | 李雪坤 | Novel froth system for stage |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114479329A (en) * | 2022-03-15 | 2022-05-13 | 广州欣东塑胶玩具有限公司 | Environment-friendly wave-blowing adhesive and preparation process thereof |
| CN114479329B (en) * | 2022-03-15 | 2022-09-20 | 广州欣东塑胶玩具有限公司 | Environment-friendly wave-blowing adhesive and preparation process thereof |
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