CN106010361A - Modified plant adhesive - Google Patents
Modified plant adhesive Download PDFInfo
- Publication number
- CN106010361A CN106010361A CN201610334817.1A CN201610334817A CN106010361A CN 106010361 A CN106010361 A CN 106010361A CN 201610334817 A CN201610334817 A CN 201610334817A CN 106010361 A CN106010361 A CN 106010361A
- Authority
- CN
- China
- Prior art keywords
- adhesive
- plant adhesive
- improved plant
- sodium
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/04—Starch derivatives
- C09J103/10—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a modified plant adhesive. Against the shortcomings in existing plant adhesives, the modified plant adhesive is prepared from modified starch, urea formaldehyde resin, urea, sodium benzoate, urea, sodium hypochlorite, soya fatty acid, preservatives, caustic soda, thickening agent, crosslinking agent, emulsifier, catalyst and deionized water. Not only is the environmental protection and safety nature of the plant adhesive maintained, but also the original shortcomings are overcome, the modified plant adhesive is good in stability and quick in drying speed when used, and an adhesive film is high in damproof capability, good in mildew resistance and high in adhesion intensity and further has very high durability. The raw materials adopted are environmentally friendly and non-toxic, an intermediate in the preparation process does not harm the human health and environment, the greenness and environmental protection shortcomings of a conventional adhesive are overcome, and the modified plant adhesive is very high in practical value.
Description
Technical field
The present invention relates to a kind of adhesive, especially relate to a kind of improved plant adhesive.
Background technology
Vegetable adhesive belongs to natural glue, and raw material is easy to get, cheap, and natural environmental-protective is harmless,
Easy to use, production technology is simple, and the unstructuredness at materials such as fabric, timber, paper, leathers glueds joint
Application, the use of vegetable adhesive is essential, but existing vegetable adhesive also exists glue-joint strength
Relatively low, resistance to water and the poor problem of fungus resistance, thus greatly limit its range of application.
Accordingly, it would be desirable to a kind of new technology solves the problems referred to above.
Summary of the invention
Goal of the invention: in order to solve in the presence of prior art problem, the present invention proposes one to be had surely
Qualitative good, Yi Gan, glue-joint strength ability high, moisture resistance is strong, fungus resistance good and environmental sound, human-body safety
Improved plant adhesive.
Technical scheme: to achieve these objectives, the present invention takes techniques below scheme: a kind of improved plant adhesive,
Include the raw material of preparing of following components according to weight meter: modified starch 100-130 part, Lauxite 3-6 part,
Sodium benzoate 10-15 part, carbamide 8-12 part, sodium hypochlorite 3-6 part, soya bean fatty acid 3-6 part, preservative
1-2 part, Caustic soda 2-4 part, thickening agent 3-8 part, cross-linking agent 2-6 part, emulsifying agent 4-10 part, catalyst 0.5-1
Part, deionized water 100-150 part.
Further, described modified starch is Oxytarch and the mixture of esterification starch 3:1.
Further, the raw material of described Oxytarch is corn starch or potato starch.
Further, described preservative is formaldehyde.
Further, described thickening agent is bentonite.
Further, described cross-linking agent is zinc acetate and cumyl peroxide mass ratio is the mixture of 1:1.
Further, described emulsifying agent is sodium alkyl sulfonate emulsifying agent.
Further, described sodium alkyl sulfonate emulsifying agent is sodium alkyl sulfonate or sodium lauryl sulphate.
Further, described catalyst is benzoic acid or stannous octoate.
Beneficial effect: a kind of improved plant adhesive that the present invention provides, exists for existing vegetable adhesive
Defect, by modified starch, Lauxite, sodium benzoate, carbamide, sodium hypochlorite, soya bean fatty acid, anticorrosion
Agent, Caustic soda, thickening agent, cross-linking agent, emulsifying agent, catalyst and deionized water are prepared from, the present invention's
Improved plant adhesive, not only maintains the person's character of the Environmental Safety of vegetable adhesive itself, is more the improvement former
Defective, when having preferable stability and use, rate of drying is fast, and the moisture resistance ability of glued membrane is strong, fungus resistance
Good, glue-joint strength height, also has the strongest durability, and raw materials used all environment-protecting asepsis, in preparation process
Intermediate also will not endanger human health and environment, breaches the green environmental protection defect of tradition adhesive, has
The strongest practical value.
Detailed description of the invention
Embodiment 1:
A kind of improved plant adhesive, includes the raw material of preparing of following components according to weight meter: modified starch 100
Part, Lauxite 3 parts, sodium benzoate 10 parts, 8 parts of carbamide, sodium hypochlorite 3 parts, soya bean fatty acid 3
Part, preservative 1 part, 2 parts of Caustic soda, thickening agent 3 parts, cross-linking agent 2 parts, emulsifying agent 4 parts, catalyst
0.5 part, deionized water 100 parts.
Wherein, described modified starch is Oxytarch and the mixture of esterification starch 3:1；Described Oxytarch
Raw material is corn starch；Described preservative is formaldehyde；Described thickening agent is bentonite；Described cross-linking agent is acetic acid
Zinc and cumyl peroxide mass ratio are the mixture of 1:1；Described emulsifying agent is sodium alkyl sulfonate emulsifying agent；
Described sodium alkyl sulfonate emulsifying agent is sodium alkyl sulfonate；Described catalyst is benzoic acid.
Embodiment 2:
A kind of improved plant adhesive, includes the raw material of preparing of following components according to weight meter: modified starch 130
Part, Lauxite 6 parts, sodium benzoate 15 parts, 12 parts of carbamide, sodium hypochlorite 6 parts, soya bean fatty acid 6
Part, preservative 2 parts, 4 parts of Caustic soda, thickening agent 8 parts, cross-linking agent 6 parts, emulsifying agent 10 parts, catalyst
1 part, deionized water 150 parts.
Wherein, described modified starch is Oxytarch and the mixture of esterification starch 3:1；Described Oxytarch
Raw material is potato starch；Described preservative is formaldehyde；Described thickening agent is bentonite；Described cross-linking agent is acetic acid
Zinc and cumyl peroxide mass ratio are the mixture of 1:1；Described emulsifying agent is sodium alkyl sulfonate emulsifying agent；
Described sodium alkyl sulfonate emulsifying agent is sodium lauryl sulphate；Described catalyst is stannous octoate.
Embodiment 3:
A kind of improved plant adhesive, includes the raw material of preparing of following components according to weight meter: modified starch 115
Part, Lauxite 4 parts, sodium benzoate 13 parts, 10 parts of carbamide, sodium hypochlorite 4 parts, soya bean fatty acid 5
Part, preservative 1.5 parts, 3 parts of Caustic soda, thickening agent 6 parts, cross-linking agent 4 parts, emulsifying agent 7 parts, catalyst
0.8 part, deionized water 125 parts.
Wherein, described modified starch is Oxytarch and the mixture of esterification starch 3:1；Described Oxytarch
Raw material is corn starch；Described preservative is formaldehyde；Described thickening agent is bentonite；Described cross-linking agent is acetic acid
Zinc and cumyl peroxide mass ratio are the mixture of 1:1；Described emulsifying agent is sodium alkyl sulfonate emulsifying agent；
Described sodium alkyl sulfonate emulsifying agent is sodium alkyl sulfonate；Described catalyst is stannous octoate.
Use the tradition improved plant adhesive that is prepared from of glue method through product by the formula of embodiment 1-3
Performance test, result is as follows: outward appearance is slightly yellow thick liquid, and viscosity is 18-23Pa S, mobility 3-4cm,
It is superior to relevant criterion.
A kind of improved plant adhesive of above-described embodiment 1-3, more traditional vegetable adhesive, not only maintain
The person's character of the Environmental Safety of vegetable adhesive itself, is more the improvement native defect, have preferable stability,
And rate of drying is fast when using, the moisture resistance ability of glued membrane is strong, fungus resistance good, glue-joint strength is high, also has the strongest
Durability, and raw materials used all environment-protecting asepsis, the intermediate in preparation process also will not endanger human health and
Environment, breaches the green environmental protection defect of tradition adhesive, has the strongest practical value.
It should be pointed out that, for those skilled in the art, before without departing from the principle of the invention
Putting, it is also possible to make some improvement, these improvement also should be regarded as protection scope of the present invention.
Claims (9)
1. an improved plant adhesive, it is characterised in that include the raw material of preparing of following components according to weight meter:
Modified starch 100-130 part, Lauxite 3-6 part, sodium benzoate 10-15 part, carbamide 8-12 part, secondary chlorine
Acid sodium 3-6 part, soya bean fatty acid 3-6 part, preservative 1-2 part, Caustic soda 2-4 part, thickening agent 3-8 part,
Cross-linking agent 2-6 part, emulsifying agent 4-10 part, catalyst 0.5-1 part, deionized water 100-150 part.
Improved plant adhesive the most according to claim 1, it is characterised in that: described modified starch is
Oxytarch and the mixture of esterification starch 3:1.
Improved plant adhesive the most according to claim 2, it is characterised in that: described Oxytarch
Raw material is corn starch or potato starch.
Improved plant adhesive the most according to claim 1, it is characterised in that: described preservative is first
Aldehyde.
Improved plant adhesive the most according to claim 1, it is characterised in that: described thickening agent is swollen
Profit soil.
Improved plant adhesive the most according to claim 1, it is characterised in that: described cross-linking agent is vinegar
Acid zinc and cumyl peroxide mass ratio are the mixture of 1:1.
Improved plant adhesive the most according to claim 1, it is characterised in that: described emulsifying agent is alkane
Base sodium sulfonate emulsifying agent.
Improved plant adhesive the most according to claim 7, it is characterised in that: described sodium alkyl sulfonate
Emulsifying agent is sodium alkyl sulfonate or sodium lauryl sulphate.
Improved plant adhesive the most according to claim 1, it is characterised in that: described catalyst is benzene
Formic acid or stannous octoate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610334817.1A CN106010361A (en) | 2016-05-19 | 2016-05-19 | Modified plant adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610334817.1A CN106010361A (en) | 2016-05-19 | 2016-05-19 | Modified plant adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106010361A true CN106010361A (en) | 2016-10-12 |
Family
ID=57096253
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610334817.1A Pending CN106010361A (en) | 2016-05-19 | 2016-05-19 | Modified plant adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106010361A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109021860A (en) * | 2018-06-02 | 2018-12-18 | 安徽扬帆充气游乐设备制造有限公司 | A kind of environment water-resistant type inflatable boat adhesive |
| CN109181577A (en) * | 2018-09-25 | 2019-01-11 | 安溪县斯马拓科技发展有限公司 | A kind of mongolicum Turcz. with Modified Starch Adhesive preparation process |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079764A (en) * | 1992-06-06 | 1993-12-22 | 大竹县国营出口包装装璜厂 | Starch-resin adhesive and preparation method |
| CN103087651A (en) * | 2012-11-13 | 2013-05-08 | 陈晓 | Adhesive and preparation method thereof |
| CN103333635A (en) * | 2013-07-11 | 2013-10-02 | 张家港市鹿苑淀粉厂 | Corn starch adhesive and preparation method thereof |
| CN104327761A (en) * | 2014-11-12 | 2015-02-04 | 合肥东彩印刷科技有限公司 | Water-resistant quick-drying carton adhesive |
-
2016
- 2016-05-19 CN CN201610334817.1A patent/CN106010361A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1079764A (en) * | 1992-06-06 | 1993-12-22 | 大竹县国营出口包装装璜厂 | Starch-resin adhesive and preparation method |
| CN103087651A (en) * | 2012-11-13 | 2013-05-08 | 陈晓 | Adhesive and preparation method thereof |
| CN103333635A (en) * | 2013-07-11 | 2013-10-02 | 张家港市鹿苑淀粉厂 | Corn starch adhesive and preparation method thereof |
| CN104327761A (en) * | 2014-11-12 | 2015-02-04 | 合肥东彩印刷科技有限公司 | Water-resistant quick-drying carton adhesive |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109021860A (en) * | 2018-06-02 | 2018-12-18 | 安徽扬帆充气游乐设备制造有限公司 | A kind of environment water-resistant type inflatable boat adhesive |
| CN109181577A (en) * | 2018-09-25 | 2019-01-11 | 安溪县斯马拓科技发展有限公司 | A kind of mongolicum Turcz. with Modified Starch Adhesive preparation process |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161012 |
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| RJ01 | Rejection of invention patent application after publication |