CN106543751A - A kind of new plasticizer - Google Patents
A kind of new plasticizer Download PDFInfo
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- CN106543751A CN106543751A CN201611108659.4A CN201611108659A CN106543751A CN 106543751 A CN106543751 A CN 106543751A CN 201611108659 A CN201611108659 A CN 201611108659A CN 106543751 A CN106543751 A CN 106543751A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
- C08L93/04—Rosin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The present invention provides a kind of new plasticizer, it is related to additive technology field, including 2～8 parts of 33～45 parts of phthalic anhydride, 25～36 parts of 2 propyl enanthol, 10～22 parts of filler, 3～12 parts of phytosterol, 5～18 parts of palmitic acid, 12～25 parts of gum rosin, 7～16 parts of organic solvent, 9～20 parts of zinc stearate, 2～7 parts of glass fiber powder, 1～5 part of isopropanol, 3～9 parts of oxide and adhesive；The organic solvent includes perchloroethylene, ethylene glycol ether and triethanolamine, and the perchloroethylene, ethylene glycol ether and triethanolamine press 10～16：1～5：3～15 mass ratio composition.Usefulness of the present invention is that plasticization effect is good, and manufacture craft is simple, and with fabulous low temperature resistant and high temperature resistant function, tensile strength is high, good stability.
Description
Technical field
The present invention relates to additive technology field, especially a kind of new plasticizer.
Background technology
Plasticiser (plasticizer) is a kind of macromolecular material auxiliary agent, and the phthalate (PAEs in environmental estrogens
Phthalates), its species is various, and modal kind is DEHP (trade name DOP), DEHP chemical names phthalic acid two
(2- ethyl hexyls) ester, is a kind of colourless, liquid with no taste, is industrially widely used.Plasticiser, typically also referred to as plasticizer, plasticizer
It is the macromolecular material auxiliary agent being industrially widely used, adds this material in plastic processing, increases can its pliability
By force, it is easily worked, can be legal for industrial use.Plasticiser is large industrial goods, is widely used in all fields of national economy, bag
Include in the thousands of kinds of products such as plastics, rubber, adhesive, cellulose, resin, medicine equipment, cable.But used at present
There is mostly the phenomenon that the feature of environmental protection is poor, plasticization effect is bad and stability is undesirable in plasticiser, in high temperature or the ring of low temperature
Offensive gases are easily discharged under border, makes human body sensory uncomfortable, it is also possible to jeopardize health.
The content of the invention
Instant invention overcomes shortcoming of the prior art, there is provided a kind of new plasticizer, plasticization effect are good, manufacture craft letter
Single, with fabulous low temperature resistant and high temperature resistant function, tensile strength is high, good stability.
In order to solve above-mentioned technical problem, the present invention is achieved by the following technical solutions：
A kind of new plasticizer, including 33～45 parts of phthalic anhydride, 25～36 parts of 2- propyl enanthols, filler 10～22
Part, 3～12 parts of phytosterol, 5～18 parts of palmitic acid, 12～25 parts of gum rosin, 7～16 parts of organic solvent, zinc stearate 9～20
Part, 2～7 parts of glass fiber powder, 1～5 part of isopropanol, 3～9 parts of oxide and 2～8 parts of adhesive；
The organic solvent includes perchloroethylene, ethylene glycol ether and triethanolamine, the perchloroethylene, ethene second two
Alcohol ether and triethanolamine press 10～16：1～5：3～15 mass ratio composition；
The oxide includes cupric oxide, di-iron trioxide, aluminum oxide and silver oxide, the cupric oxide, di-iron trioxide,
Aluminum oxide and silver oxide press 3～11：3.6～6.8：4～15：7.8～15.6 mass ratio composition；
Described filler includes berl saddle, Ball-type packing, Pall ring filler and ladder ring packing, the berl saddle, ball
Shape filler, Pall ring filler and ladder ring packing press 1～8：3.5～7.5：5～13：7.2～18.7 mass ratio composition.
Further, a kind of 36～42 parts of described new plasticizer, including phthalic anhydride, 2- propyl enanthols 28～
31 parts, 15～20 parts of filler, 5～9 parts of phytosterol, 9～14 parts of palmitic acid, 16～20 parts of gum rosin, organic solvent 9～13
Part, 11～18 parts of zinc stearate, 4～6 parts of glass fiber powder, 2～4 parts of isopropanol, 4～7 parts of oxide and adhesive 3～6
Part；
The organic solvent includes perchloroethylene, ethylene glycol ether and triethanolamine, the perchloroethylene, ethene second two
Alcohol ether and triethanolamine press 13：3：9 mass ratio composition；
The oxide includes cupric oxide, di-iron trioxide, aluminum oxide and silver oxide, the cupric oxide, di-iron trioxide,
Aluminum oxide and silver oxide press 6：5：8：12 mass ratio composition；
Described filler includes berl saddle, Ball-type packing, Pall ring filler and ladder ring packing, the berl saddle, ball
Shape filler, Pall ring filler and ladder ring packing press 5：6：7：15 mass ratio composition.
Further, the preparation method of described adhesive is：(1) by polyurethane dibasic acid esters unsaturated-resin, expoxy propane benzene
Base ether, epoxy resin, zinc methacrylate, saccharin and hydroquinones, tertiary ethylene carbonate, allyl glycidyl ether and go
Ionized water presses 18：1：5：12：6：2：3：Stir after 30 mass ratio mixing；(2) material after stirring is poured into
In beaker, beaker is placed in the water of 40～60 DEG C of temperature, and manually constantly the material in beaker is stirred to thick；
(3) normal temperature is cooled, you can.
Compared with prior art, the invention has the beneficial effects as follows：
This plasticizer institute constituent is cheap, and preparation method is simple, is easily mastered, is conducive to large-scale promotion, together
When, the formula collocation of this plasticizer is reasonable, mutually coordinates, and makes the plasticizer made have fabulous cohesive and anti-aging
Property, long service life, it is not easy to rotten, during use, Volatilized smell is less, is adapted to most of places and uses.
Specific embodiment
Hereinafter the preferred embodiments of the present invention are illustrated, it will be appreciated that preferred embodiment described herein is only used
In the description and interpretation present invention, it is not intended to limit the present invention.
Embodiment 1
A kind of new plasticizer, including 45 parts of phthalic anhydride, 36 parts of 2- propyl enanthols, 22 parts of filler, phytosterol
12 parts, 18 parts of palmitic acid, 25 parts of gum rosin, 16 parts of organic solvent, 20 parts of zinc stearate, 7 parts of glass fiber powder, 5 parts of isopropanol,
8 parts of 9 parts of oxide and adhesive；
Organic solvent includes perchloroethylene, ethylene glycol ether and triethanolamine, perchloroethylene, ethylene glycol ether and three
Monoethanolamine presses 16：5：15 mass ratio composition；
Oxide includes cupric oxide, di-iron trioxide, aluminum oxide and silver oxide, cupric oxide, di-iron trioxide, aluminum oxide and
Silver oxide presses 11：6.8：15：15.6 mass ratio composition；
Filler includes berl saddle, Ball-type packing, Pall ring filler and ladder ring packing, berl saddle, Ball-type packing, Bao
That ring filler and ladder ring packing press 8：7.5：13：18.7 mass ratio composition.
Further, the preparation method of adhesive is：(1) by polyurethane dibasic acid esters unsaturated-resin, expoxy propane phenyl ether,
Epoxy resin, zinc methacrylate, saccharin and hydroquinones, tertiary ethylene carbonate, allyl glycidyl ether and deionization
Water presses 18：1：5：12：6：2：3：Stir after 30 mass ratio mixing；(2) material after stirring is poured into into beaker
In, beaker is placed in the water of 40～60 DEG C of temperature, and manually constantly the material in beaker is stirred to thick；(3)
Normal temperature is cooled, you can.
Embodiment 2
A kind of new plasticizer, including 33 parts of phthalic anhydride, 25 parts of 2- propyl enanthols, 10 parts of filler, phytosterol 3
Part, 5 parts of palmitic acid, 12 parts of gum rosin, 7 parts of organic solvent, 9 parts of zinc stearate, 2 parts of glass fiber powder, 1 part of isopropanol, oxidation
2 parts of 3 parts of thing and adhesive；
Organic solvent includes perchloroethylene, ethylene glycol ether and triethanolamine, perchloroethylene, ethylene glycol ether and three
Monoethanolamine presses 10：1：3 mass ratio composition；
Oxide includes cupric oxide, di-iron trioxide, aluminum oxide and silver oxide, cupric oxide, di-iron trioxide, aluminum oxide and
Silver oxide presses 3：3.6：4：7.8 mass ratio composition；
Filler includes berl saddle, Ball-type packing, Pall ring filler and ladder ring packing, berl saddle, Ball-type packing, Bao
That ring filler and ladder ring packing press 1：3.5：5：7.2～mass ratio composition.
Further, the preparation method of adhesive is：(1) by polyurethane dibasic acid esters unsaturated-resin, expoxy propane phenyl ether,
Epoxy resin, zinc methacrylate, saccharin and hydroquinones, tertiary ethylene carbonate, allyl glycidyl ether and deionization
Water presses 18：1：5：12：6：2：3：Stir after 30 mass ratio mixing；(2) material after stirring is poured into into beaker
In, beaker is placed in the water of 40 DEG C of temperature, and manually constantly the material in beaker is stirred to thick；(3) normal temperature
Cool, you can.
Embodiment 3
A kind of new plasticizer, including 38 parts of phthalic anhydride, 29 parts of 2- propyl enanthols, 16 parts of filler, phytosterol 7
Part, 11 parts of palmitic acid, 18 parts of gum rosin, 11 parts of organic solvent, 16 parts of zinc stearate, 5 parts of glass fiber powder, 3 parts of isopropanol, oxygen
4 parts of 6 parts of compound and adhesive；
Organic solvent includes perchloroethylene, ethylene glycol ether and triethanolamine, perchloroethylene, ethylene glycol ether and three
Monoethanolamine presses 13：4：8 mass ratio composition；
Oxide includes cupric oxide, di-iron trioxide, aluminum oxide and silver oxide, cupric oxide, di-iron trioxide, aluminum oxide and
Silver oxide presses 7：4.2：8：12 mass ratio composition；
Filler includes berl saddle, Ball-type packing, Pall ring filler and ladder ring packing, berl saddle, Ball-type packing, Bao
That ring filler and ladder ring packing press 5：4.2：8：11.2 mass ratio composition.
Further, the preparation method of adhesive is：(1) by polyurethane dibasic acid esters unsaturated-resin, expoxy propane phenyl ether,
Epoxy resin, zinc methacrylate, saccharin and hydroquinones, tertiary ethylene carbonate, allyl glycidyl ether and deionization
Water presses 18：1：5：12：6：2：3：Stir after 30 mass ratio mixing；(2) material after stirring is poured into into beaker
In, beaker is placed in the water of 50 DEG C of temperature, and manually constantly the material in beaker is stirred to thick；(3) normal temperature
Cool, you can.
The preparation method of new plasticizer of the present invention is directly by phthalic anhydride, 2- propyl enanthols, filler, plant
Sterol, palmitic acid, gum rosin, organic solvent, zinc stearate, glass fiber powder, isopropanol, oxide and adhesive are poured into instead
In answering kettle, stir, you can.
Phytosterol:With anti-aging, good endurance, it is unlikely to deteriorate and the features such as good penetrability；
Palmitic acid：Also known as palmitic acid is called, and it is a kind of saturated higher fatty acid, colourless, tasteless waxy solid, with anti-
Water function；
Zinc stearate：It is nontoxic, can be used as lubricant, accelerator and thickener etc.；
Glass fiber powder：Glass fiber powder has and improves product hardness, compression strength, wear-resistant and reduce shrinkage factor
Effect.
The plasticizer that embodiment 1 to 3 is made is sent to into the detection of reported in Tianhe district of Guangzhou chemical examination mechanism, it is as a result as follows：
| Detection project | Technical standard | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Outward appearance | Transparent, free from admixture | Transparent, free from admixture | Transparent, free from admixture | Transparent, free from admixture |
| Cadmium | Less than 100ppm | 54ppm | 92ppm | 77ppm |
| Aluminium alloy | Less than 4000ppm | 2954ppm | 3650ppm | 3190ppm |
| Mercury | Less than 4000ppm | 2534ppm | 3750ppm | 3215ppm |
| Cr VI | Less than 1000ppm | 430ppm | 880ppm | 560ppm |
| Nonvolatile matter | ≤2.0mg/100ml | 0.6 | 1.8 | 1.1 |
From the point of view of testing result, the plasticizer performance made using the present invention is good, safe and reliable, and volatilize particle
Concentration is low, meets environmental protection theory.
Finally it should be noted that：The preferred embodiments of the present invention are these are only, the present invention is not limited to, although
The present invention is described in detail with reference to embodiment, for a person skilled in the art, which still can be to aforementioned
Technical scheme described in each embodiment is modified, or equivalent is carried out to which part technical characteristic, but it is all
Within the spirit and principles in the present invention, any modification, equivalent substitution and improvements made etc. should be included in the protection of the present invention
Within the scope of.
Claims (3)
1. a kind of new plasticizer, it is characterised in that including 33～45 parts of phthalic anhydride, 25～36 parts of 2- propyl enanthols,
It is 10～22 parts of filler, 3～12 parts of phytosterol, 5～18 parts of palmitic acid, 12～25 parts of gum rosin, 7～16 parts of organic solvent, hard
2～8 parts of 9～20 parts of resin acid zinc, 2～7 parts of glass fiber powder, 1～5 part of isopropanol, 3～9 parts of oxide and adhesive；
The organic solvent includes perchloroethylene, ethylene glycol ether and triethanolamine, the perchloroethylene, ethylene glycol ether
10～16 are pressed with triethanolamine：1～5：3～15 mass ratio composition；
The oxide includes cupric oxide, di-iron trioxide, aluminum oxide and silver oxide, the cupric oxide, di-iron trioxide, oxidation
Aluminium and silver oxide press 3～11：3.6～6.8：4～15：7.8～15.6 mass ratio composition；
Described filler includes berl saddle, Ball-type packing, Pall ring filler and ladder ring packing, the berl saddle, spherical fills out
Material, Pall ring filler and ladder ring packing press 1～8：3.5～7.5：5～13：7.2～18.7 mass ratio composition.
2. a kind of new plasticizer according to claim 1, it is characterised in that including 36～42 parts of phthalic anhydride,
28～31 parts of 2- propyl enanthols, 15～20 parts of filler, 5～9 parts of phytosterol, 9～14 parts of palmitic acid, 16～20 parts of gum rosin,
9～13 parts of organic solvent, 11～18 parts of zinc stearate, 4～6 parts of glass fiber powder, 2～4 parts of isopropanol, 4～7 parts of oxide with
And 3～6 parts of adhesive；
The organic solvent includes perchloroethylene, ethylene glycol ether and triethanolamine, the perchloroethylene, ethylene glycol ether
13 are pressed with triethanolamine：3：9 mass ratio composition；
The oxide includes cupric oxide, di-iron trioxide, aluminum oxide and silver oxide, the cupric oxide, di-iron trioxide, oxidation
Aluminium and silver oxide press 6：5：8：12 mass ratio composition；
Described filler includes berl saddle, Ball-type packing, Pall ring filler and ladder ring packing, the berl saddle, spherical fills out
Material, Pall ring filler and ladder ring packing press 5：6：7：15 mass ratio composition.
3. a kind of new plasticizer according to claim 1 and 2, it is characterised in that the preparation method of described adhesive is：
(1) by polyurethane dibasic acid esters unsaturated-resin, expoxy propane phenyl ether, epoxy resin, zinc methacrylate, saccharin and to benzene two
Phenol, tertiary ethylene carbonate, allyl glycidyl ether and deionized water press 18：1：5：12：6：2：3：30 mass ratio mixing
After stir；(2) material after stirring is poured in beaker, beaker is placed in the water of 40～60 DEG C of temperature,
And manually constantly the material in beaker is stirred to thick；(3) normal temperature is cooled, you can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611108659.4A CN106543751A (en) | 2016-12-06 | 2016-12-06 | A kind of new plasticizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611108659.4A CN106543751A (en) | 2016-12-06 | 2016-12-06 | A kind of new plasticizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106543751A true CN106543751A (en) | 2017-03-29 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611108659.4A Pending CN106543751A (en) | 2016-12-06 | 2016-12-06 | A kind of new plasticizer |
Country Status (1)
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| CN (1) | CN106543751A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107739454A (en) * | 2017-10-27 | 2018-02-27 | 四川梅塞尔科技有限公司 | A kind of novel environment-friendlyplasticizer plasticizer |
Citations (4)
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|---|---|---|---|---|
| CN102531903A (en) * | 2011-06-08 | 2012-07-04 | 巢湖香枫塑胶助剂有限公司 | Preparation method and application of phthalic acid diester (2-propyl group heptanol) |
| CN105237803A (en) * | 2015-10-16 | 2016-01-13 | 江苏森禾化工科技有限公司 | Plasticizer |
| CN105348792A (en) * | 2015-12-11 | 2016-02-24 | 安徽律正科技信息服务有限公司 | Anti-aging plasticizer for wood plastic composite material |
| CN106117790A (en) * | 2016-07-07 | 2016-11-16 | 蚌埠海明压铸机有限公司 | A kind of high temperature resistant aging resistance modified plastic particles |
-
2016
- 2016-12-06 CN CN201611108659.4A patent/CN106543751A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102531903A (en) * | 2011-06-08 | 2012-07-04 | 巢湖香枫塑胶助剂有限公司 | Preparation method and application of phthalic acid diester (2-propyl group heptanol) |
| CN105237803A (en) * | 2015-10-16 | 2016-01-13 | 江苏森禾化工科技有限公司 | Plasticizer |
| CN105348792A (en) * | 2015-12-11 | 2016-02-24 | 安徽律正科技信息服务有限公司 | Anti-aging plasticizer for wood plastic composite material |
| CN106117790A (en) * | 2016-07-07 | 2016-11-16 | 蚌埠海明压铸机有限公司 | A kind of high temperature resistant aging resistance modified plastic particles |
Non-Patent Citations (4)
| Title |
|---|
| 中国化工学会橡胶专业委员会组织: "《橡胶助剂手册》", 30 April 2000, 化学工业出版社 * |
| 周祥兴等: "《塑料助剂应用速查手册》", 31 October 2010, 印刷出版社 * |
| 聂梅生等: "《水工业工程设计手册 水工业工程设备》", 31 March 2000, 中国建筑工业出版社 * |
| 胡凡启: "《塑料注塑工》", 31 December 2009, 中国水利水电出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107739454A (en) * | 2017-10-27 | 2018-02-27 | 四川梅塞尔科技有限公司 | A kind of novel environment-friendlyplasticizer plasticizer |
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Application publication date: 20170329 |