CN107805803A - A kind of antioxidant toughening metal conditioner - Google Patents

A kind of antioxidant toughening metal conditioner Download PDF

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Publication number
CN107805803A
CN107805803A CN201711030625.2A CN201711030625A CN107805803A CN 107805803 A CN107805803 A CN 107805803A CN 201711030625 A CN201711030625 A CN 201711030625A CN 107805803 A CN107805803 A CN 107805803A
Authority
CN
China
Prior art keywords
parts
antioxidant
metal conditioner
aluminum oxide
toughening
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711030625.2A
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Chinese (zh)
Inventor
赵明汉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yangzhou Yixin Metal Surface Treatment Co Ltd
Original Assignee
Yangzhou Yixin Metal Surface Treatment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yangzhou Yixin Metal Surface Treatment Co Ltd filed Critical Yangzhou Yixin Metal Surface Treatment Co Ltd
Priority to CN201711030625.2A priority Critical patent/CN107805803A/en
Publication of CN107805803A publication Critical patent/CN107805803A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14Nitrogen-containing compounds
    • C23F11/149Heterocyclic compounds containing nitrogen as hetero atom

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Anti-Oxidant Or Stabilizer Compositions (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)

Abstract

A kind of antioxidant toughening metal conditioner, it is characterized in that, including each component of following parts by weight is prepared:4 12 parts of silk gum, 13 parts of boric acid, 25 parts of aluminum oxide, 26 parts of corrosion inhibiter, 10 15 parts of polyvinyl alcohol, 5 10 parts of deoxygenated ethanol, 28 parts of terephthalic acid (TPA), 29 parts of ammonium metavanadate, 25 parts of coalescents, 26 parts of laruyl alcohol, 23 parts of sodium acid carbonate, 13 parts of antioxidant.This metal conditioner uses chemically transformed film technique, in addition to the advantages that handling process and equipment is simple and convenient to operate, small investment benefit, can also avoid etching waste liquor from handling, and the metal conditioner helps to prevent ionic environment from polluting.

Description

A kind of antioxidant toughening metal conditioner
Technical field
The invention belongs to field of metal surface treatment technology, specifically, is related at a kind of antioxidant toughening metal surface Manage agent.
Background technology
Metal conditioner refers to the general name for the chemical agent that various processing are carried out to metal surface.Metal is at processing, place Different degrees of oxidation, corrosion etc. often occur during reason and use, reduces the use longevity of metal material or hardware Life, therefore, it is necessary to handle metal surface, increase its anti-oxidant, erosion-resisting ability, increase the service life.Application is The conventional technology of Treatment of Metal Surface, phosphatization can produce substantial amounts of phosphorus-containing wastewater in coating process, and need in strong acid or Carried out under strong alkaline condition, the health and environment to people cause greatly to endanger.Therefore, be badly in need of it is a kind of to environment without dirt Dye, the metal conditioner of human body health is not damaged.
The content of the invention
The present invention be directed to above-mentioned the deficiencies in the prior art, there is provided it is a kind of environment is not polluted, can be in metal surface shape Into organic film and the suitable metal conditioner of film adhesive force and antiseptic power.
The technical scheme is that:A kind of antioxidant toughening metal conditioner, it is characterized in that, including following weight The each component of part is prepared:Silk gum 4-12 parts, boric acid 1-3 parts, aluminum oxide 2-5 parts, corrosion inhibiter 2-6 parts, polyvinyl alcohol 10-15 Part, deoxygenated ethanol 5-10 parts, terephthalic acid (TPA) 2-8 parts, ammonium metavanadate 2-9 parts, coalescents 2-5 parts, laruyl alcohol 2-6 parts, carbon Sour hydrogen sodium 2-3 parts, antioxidant 1-3 parts.
The aluminum oxide is alumina in Nano level.
The corrosion inhibiter is made up of methyl benzotriazazole, sig water, antioxidant BHT, Tea Saponin.
The coalescents are lauryl alcohol ester.
The antioxidant is hydroquinones, neck benzenediol.
The present invention uses nano level aluminum oxide, and one layer of fine and close diaphragm can be formed in metal surface, effective anti- Only infringement of the external environment to metal.Water soluble polymer polyvinyl alcohol is mixed with silk gum, can be improved by boric acid modified The tensile strength and heat endurance of blend film, the inhibition alkali lye using methyl benzotriazazole as major ingredient is added, can to adsorb Film in metal surface is more uniform and stable, protects metal material from the corrosion of hazardous medium in air and water, plays more preferable Corrosion mitigating effect, antioxidant BHT can improve the inoxidizability of metal conditioner.
Antioxidant in the present invention can prevent and delay product oxidation deterioration, such as discoloration, peculiar smell, oxidative rancidity, capital Metal surface inorganic agent uses chemically transformed film technique, except handling process and equipment is simple and convenient to operate, small investment benefit etc. is excellent Point is outer, can also avoid etching waste liquor from handling, and the metal conditioner helps to prevent ionic environment from polluting.
Embodiment
Embodiment 1
A kind of antioxidant toughening metal conditioner, including each component of following parts by weight are prepared:Silk gum 4-12 parts, boron Sour 1-3 parts, aluminum oxide 2-5 parts, corrosion inhibiter 2-6 parts, polyvinyl alcohol 10-15 parts, deoxygenated ethanol 5-10 parts, terephthalic acid (TPA) 2-8 Part, ammonium metavanadate 2-9 parts, coalescents 2-5 parts, laruyl alcohol 2-6 parts, sodium acid carbonate 2-3 parts, antioxidant 1-3 parts.
Aluminum oxide is alumina in Nano level, and corrosion inhibiter is methyl benzotriazazole, sig water, antioxidant BHT, Tea Saponin system Into coalescents are lauryl alcohol ester, and antioxidant is hydroquinones, neck benzenediol.
Embodiment 2
A kind of antioxidant toughening metal conditioner, including each component of following parts by weight are prepared:12 parts of silk gum, boric acid 3 parts, 5 parts of aluminum oxide, 6 parts of corrosion inhibiter, 15 parts of polyvinyl alcohol, 10 parts of deoxygenated ethanol, 8 parts of terephthalic acid (TPA), 9 parts of ammonium metavanadate, 5 parts of coalescents, 6 parts of laruyl alcohol, 3 parts of sodium acid carbonate, 3 parts of antioxidant.
Aluminum oxide is alumina in Nano level, and corrosion inhibiter is methyl benzotriazazole, sig water, antioxidant BHT, Tea Saponin system Into coalescents are lauryl alcohol ester, and antioxidant is hydroquinones, neck benzenediol.
Embodiment 3
A kind of antioxidant toughening metal conditioner, including each component of following parts by weight are prepared:4 parts of silk gum, boric acid 1 Part, 2 parts of aluminum oxide, 2 parts of corrosion inhibiter, 10 parts of polyvinyl alcohol, 5 parts of deoxygenated ethanol, 2 parts of terephthalic acid (TPA), 2 parts of ammonium metavanadate, into 2 parts of film auxiliary agent, 2 parts of laruyl alcohol, 2 parts of sodium acid carbonate, 1 part of antioxidant.
Aluminum oxide is alumina in Nano level, and corrosion inhibiter is methyl benzotriazazole, sig water, antioxidant BHT, Tea Saponin system Into coalescents are lauryl alcohol ester, and antioxidant is hydroquinones, neck benzenediol.

Claims (5)

1. a kind of antioxidant toughening metal conditioner, it is characterized in that, including each component of following parts by weight is prepared:Silk It is glue 4-12 parts, boric acid 1-3 parts, aluminum oxide 2-5 parts, corrosion inhibiter 2-6 parts, polyvinyl alcohol 10-15 parts, deoxygenated ethanol 5-10 parts, right Phthalic acid 2-8 parts, ammonium metavanadate 2-9 parts, coalescents 2-5 parts, laruyl alcohol 2-6 parts, sodium acid carbonate 2-3 parts, antioxidant 1-3 parts.
2. a kind of antioxidant toughening metal conditioner according to claim 1, it is characterized in that, the aluminum oxide is to receive Meter level aluminum oxide.
3. a kind of antioxidant toughening metal conditioner according to claim 1, it is characterized in that, the corrosion inhibiter is first Base BTA, sig water, antioxidant BHT, Tea Saponin are made.
4. a kind of antioxidant toughening metal conditioner according to claim 1, it is characterized in that, the coalescents are Lauryl alcohol ester.
5. a kind of antioxidant toughening metal conditioner according to claim 1, it is characterized in that, the antioxidant is Hydroquinones, neck benzenediol.
CN201711030625.2A 2017-10-30 2017-10-30 A kind of antioxidant toughening metal conditioner Pending CN107805803A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711030625.2A CN107805803A (en) 2017-10-30 2017-10-30 A kind of antioxidant toughening metal conditioner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711030625.2A CN107805803A (en) 2017-10-30 2017-10-30 A kind of antioxidant toughening metal conditioner

Publications (1)

Publication Number Publication Date
CN107805803A true CN107805803A (en) 2018-03-16

Family

ID=61591624

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711030625.2A Pending CN107805803A (en) 2017-10-30 2017-10-30 A kind of antioxidant toughening metal conditioner

Country Status (1)

Country Link
CN (1) CN107805803A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108676387A (en) * 2018-04-27 2018-10-19 江苏恒加机械工程有限公司 A kind of metal surface treating liquid
CN108914105A (en) * 2018-07-19 2018-11-30 苏州瑞沁精密机械有限公司 A kind of die surface treatment fluid
CN109082666A (en) * 2018-08-17 2018-12-25 南京世界村汽车动力有限公司 A kind of engine surface antioxidant and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108676387A (en) * 2018-04-27 2018-10-19 江苏恒加机械工程有限公司 A kind of metal surface treating liquid
CN108914105A (en) * 2018-07-19 2018-11-30 苏州瑞沁精密机械有限公司 A kind of die surface treatment fluid
CN109082666A (en) * 2018-08-17 2018-12-25 南京世界村汽车动力有限公司 A kind of engine surface antioxidant and preparation method thereof

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Application publication date: 20180316

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