CN110526583B - Gem binder for enamel colored porcelain decoration and application method thereof - Google Patents

Gem binder for enamel colored porcelain decoration and application method thereof Download PDF

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CN110526583B
CN110526583B CN201910889508.4A CN201910889508A CN110526583B CN 110526583 B CN110526583 B CN 110526583B CN 201910889508 A CN201910889508 A CN 201910889508A CN 110526583 B CN110526583 B CN 110526583B
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gem
binder
porcelain
sieving
porcelain body
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CN110526583A (en
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曹红燕
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Cao Hongyan
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/26Inlaying with ornamental structures, e.g. niello work, tarsia work
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/04Frit compositions, i.e. in a powdered or comminuted form containing zinc
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/24Fusion seal compositions being frit compositions having non-frit additions, i.e. for use as seals between dissimilar materials, e.g. glass and metal; Glass solders
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/003Joining burned ceramic articles with other burned ceramic articles or other articles by heating by means of an interlayer consisting of a combination of materials selected from glass, or ceramic material with metals, metal oxides or metal salts
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/10Glass interlayers, e.g. frit or flux

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Adornments (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

The invention relates to a gem binder for enamel color porcelain decoration and an application method thereof, wherein the binder comprises the following components in percentage by weight: 35-40% of potash feldspar, 15-20% of calcite, 5-10% of Suzhou soil, 25-30% of quartz, 5-10% of talcum, 5-10% of nepheline powder, 0-6% of transparent frit and 5% of quartz fiber, and the gem binder is obtained by mixing, ball milling, sieving, adding the quartz fiber and uniformly stirring. According to the invention, the gem is fixed on the surface of the porcelain body by using the binder, so that a decoration mode that the traditional enamel color is combined with the gem is created, the decoration effect of the traditional enamel color is greatly improved, and the porcelain has a wide market space.

Description

Gem binder for enamel colored porcelain decoration and application method thereof
Technical Field
The invention relates to the technical field of ceramics, in particular to a gem binder for enamel colored porcelain decoration and an application method thereof.
Background
The enamel color porcelain with a long history, which is called as 'color porcelain queen' and 'official ware in official ware', is evolved from cloisonne enamel, the cloisonne enamel is formed by applying enamel glaze on a copper body, and the enamel color porcelain is formed by applying the enamel glaze on a porcelain body and then firing, so the enamel color porcelain is also called 'porcelain body painting enamel', although the enamel color has the characteristics of exquisite porcelain, heavy color material, bright and beautiful color, exquisite painter and the like, the traditional enamel color decoration method can not meet the pursuit of people for high-quality life.
Disclosure of Invention
The invention aims to provide a healthy and environment-friendly gem binder for enamel colored porcelain decoration, which is stable in binding, low in cost and an application method thereof.
The technical scheme of the invention is as follows: the gem binder for enamel color porcelain decoration is characterized in that: the adhesive comprises the following components in percentage by weight: 35-40% of potash feldspar, 15-20% of calcite, 5-10% of Suzhou soil, 25-30% of quartz, 5-10% of talcum, 5-10% of nepheline powder, 0-6% of transparent frit and 5% of quartz fiber, and the gem binder is obtained by mixing, ball milling, sieving, adding the quartz fiber and uniformly stirring.
The transparent frit preferably comprises 3-6% by weight; the sieving process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The transparent frit is formed by mixing a transparent frit A and a transparent frit B according to the weight percentage of 0-100: 0-100.
The chemical composition percentage of the transparent frit A is as follows: SiO 22 34%、B2O3 12%、Al2O3 13%、Li2O12%, MgO 15% and ZnO 14% through the processes of proportioning, grinding, high-temperature melting, quenching, ball milling and sieving to obtain the transparent frit A.
The parameters of the high-temperature melting process are as follows: the heating rate is 5 ℃/min, the highest melting temperature is 1200 ℃, and the heat preservation time is 30 min; the screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The chemical composition percentage of the transparent frit B is as follows: SiO 22 26%、B2O3 28%、Al2O3 28%、Na2O 7%、CaO 8%、ZrO23 percent, and obtaining the transparent frit B through the working procedures of material preparation, grinding, high-temperature melting, quenching, ball milling and sieving.
The parameters of the high-temperature melting process are as follows: the heating rate is 5 ℃/min, the highest melting temperature is 1300 ℃, and the heat preservation time is 30 min; the screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The application method of the gem adhesive is characterized by comprising the following steps:
(1) selecting a high-quality porcelain body fired at 1260-1320 ℃, wherein the porcelain body comprises a body and a glaze layer;
(2) according to the decoration position of the gem on the enamel colored porcelain, mechanically drilling a hole on the surface of the porcelain body, wherein the depth of the hole is two thirds of the thickness of the porcelain body;
(3) carrying out enamel color pattern decoration on the surface of the porcelain body;
(4) uniformly mixing a gem binder, water and guar gum according to the weight ratio of 85:10:5, then filling the mixture into the hole drilled in the step (2), and installing the bottom of the gem in the hole;
(5) and putting the porcelain body decorated by the enamel color and provided with the precious stone into a kiln, firing at 1000-1100 ℃, and taking out of the kiln to obtain the enamel color decorated porcelain body with the precious stone.
And (4) filling the hole with the gem binder, the water and the guar gum in the step (4) to be one third of the volume of the hole.
And (4) the enamel color pattern decoration on the surface of the porcelain body in the step (3) is performed by hand drawing or decal paper.
The invention relates to a formula of a gem binder for decorating enamel colored porcelain and a formulation thought of a process, which comprises the following steps: mainly solves the problems that the bonding stability of the bonding agent to the jewel and the expansion coefficients of the bonding agent, the jewel, the porcelain body and the porcelain glaze layer are mutually matched.
Firstly, in order to improve the bonding performance of the bonding agent, the invention adopts the way that trivalent oxide, divalent oxide and boride are mutually matched in a material formula, quartz fiber is used in the material formula, and the grain fineness and the firing temperature of materials are strictly controlled in the preparation process, so that the material grains and the quartz fiber can be well mutually matched, the surface of the bottom of the gem is wrapped and bonded, and the stable bonding of the bonding agent and the gem is ensured;
secondly, in order to be suitable for different thermal expansion coefficients among the binding agent, various gems, porcelain body and porcelain body glaze layers, the invention adopts the composite transparent frit in the material formula, realizes the adjustment of the thermal expansion coefficient of the binding agent by adjusting the different proportions of the transparent frit A and the transparent frit B, and simultaneously particularly adjusts the Al in the binding agent2O3、SiO2、MgO、CaO、Ka2The content of O improves the elasticity of the adhesive and ensures the perfect adhesion of the adhesive and the gem;
thirdly, in order to improve the stability of the initial positioning of the gem on the surface of the porcelain body, the guar gum is additionally added when the binder is applied, and the position of the gem is initially fixed through the binding property of the guar gum mixed with water, so that the positioning of the gem on the porcelain body is ensured.
The invention relates to a method for decorating abundant enamel colored porcelain, which innovates a decoration mode of combining traditional enamel color and gem, realizes the fixation of gem on the surfaces of porcelain bodies with different shapes by utilizing the good bonding performance of the gem binder, greatly improves the decoration effect of the traditional enamel color, and has abundant sources, low price and no side effect on human body because most of the raw materials used by the gem binder are natural mineral raw materials, thereby having wide market space.
Detailed Description
To further illustrate the present invention and the technical means and effects thereof adopted to achieve the predetermined object, the present invention will be described in detail with reference to the preferred embodiments as follows:
example 1
The gem binder for enamel color porcelain decoration is characterized in that: the adhesive comprises the following components in percentage by weight: 36% of potash feldspar, 18% of calcite, 5% of Suzhou soil, 28% of quartz, 5% of talcum, 6% of nepheline powder, 0% of transparent frit and 5% of quartz fiber, and the gem binder is obtained by mixing, ball milling, sieving, adding the quartz fiber and uniformly stirring.
The gemstone is sapphire.
The screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The application method of the gem adhesive is characterized by comprising the following steps:
(1) selecting a high-quality porcelain body fired at 1280 ℃, wherein the porcelain body comprises a body and a glaze layer;
(2) according to the decoration position of the gem on the enamel colored porcelain, mechanically drilling a hole on the surface of the porcelain body, wherein the depth of the hole is two thirds of the thickness of the porcelain body;
(3) carrying out enamel color pattern decoration on the surface of the porcelain body;
(4) uniformly mixing a gem binder, water and guar gum according to the weight ratio of 85:10:5, then filling the mixture into the hole drilled in the step (2), and installing the bottom of the sapphire in the hole;
(5) the porcelain body decorated by the enamel color and provided with the gem is put into a kiln, fired at 1000 ℃, and taken out of the kiln to obtain the enamel color decorated porcelain body with the gem.
And (4) filling the hole with the gem binder, the water and the guar gum in the step (4) to be one third of the volume of the hole.
And (4) the enamel color pattern decoration on the surface of the porcelain body in the step (3) is hand-drawn.
Example 2
The gem binder for enamel color porcelain decoration is characterized in that: the adhesive comprises the following components in percentage by weight: 35% of potash feldspar, 15% of calcite, 8% of Suzhou soil, 25% of quartz, 7% of talcum, 5% of nepheline powder, 5% of transparent frit and 5% of quartz fiber, and the gem binder is obtained by mixing, ball milling, sieving, adding the quartz fiber and uniformly stirring.
The gemstone is a diamond.
The screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The transparent frit is formed by mixing a transparent frit A and a transparent frit B according to the weight percentage of 100: 0.
The chemical composition percentage of the transparent frit A is as follows: SiO 22 34%、B2O3 12%、Al2O3 13%、Li2O12%, MgO 15% and ZnO 14% through the processes of proportioning, grinding, high-temperature melting, quenching, ball milling and sieving to obtain the transparent frit A.
The parameters of the high-temperature melting process are as follows: the heating rate is 5 ℃/min, the highest melting temperature is 1200 ℃, and the heat preservation time is 30 min; the screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The application method of the gem adhesive is characterized by comprising the following steps:
(1) selecting a high-quality porcelain body fired at 1300 ℃, wherein the porcelain body comprises a body and a glaze layer;
(2) according to the decoration position of the gem on the enamel colored porcelain, mechanically drilling a hole on the surface of the porcelain body, wherein the depth of the hole is two thirds of the thickness of the porcelain body;
(3) carrying out enamel color pattern decoration on the surface of the porcelain body;
(4) uniformly mixing a gem binder, water and guar gum according to the weight ratio of 85:10:5, then filling the mixture into the hole drilled in the step (2), and installing the bottom of the gem in the hole;
(5) placing porcelain body decorated with enamel color and provided with gem in kiln, firing at 1020 deg.C, and discharging
Obtaining the enamel color decorative porcelain body with the gem.
And (4) filling the hole with the gem binder, the water and the guar gum in the step (4) to be one third of the volume of the hole.
And (4) the enamel color pattern decoration on the surface of the porcelain body in the step (3) is hand-drawn.
Example 3
The gem binder for enamel color porcelain decoration is characterized in that: the adhesive comprises the following components in percentage by weight: 35% of potash feldspar, 15% of calcite, 5% of Suzhou soil, 26% of quartz, 9% of talcum, 8% of nepheline powder, 2% of transparent frit and 5% of quartz fiber, and the gem binder is obtained by mixing, ball milling, sieving, adding the quartz fiber and uniformly stirring.
The gemstone is a spinel.
The screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The transparent frit is formed by mixing a transparent frit A and a transparent frit B according to the weight percentage of 20: 80.
The chemical composition percentage of the transparent frit A is as follows: SiO 22 34%、B2O3 12%、Al2O3 13%、Li2O12%, MgO 15% and ZnO 14% through the processes of proportioning, grinding, high-temperature melting, quenching, ball milling and sieving to obtain the transparent frit A.
The parameters of the high-temperature melting process are as follows: the heating rate is 5 ℃/min, the highest melting temperature is 1200 ℃, and the heat preservation time is 30 min; the screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The chemical composition percentage of the transparent frit B is as follows: SiO 22 26%、B2O3 28%、Al2O3 28%、Na2O 7%、CaO 8%、ZrO23 percent, and obtaining the transparent frit B through the working procedures of material preparation, grinding, high-temperature melting, quenching, ball milling and sieving.
The parameters of the high-temperature melting process are as follows: the heating rate is 5 ℃/min, the highest melting temperature is 1300 ℃, and the heat preservation time is 30 min; the screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The application method of the gem adhesive is characterized by comprising the following steps:
(1) selecting a high-quality porcelain body fired at 1280 ℃, wherein the porcelain body comprises a body and a glaze layer;
(2) according to the decoration position of the gem on the enamel colored porcelain, mechanically drilling a hole on the surface of the porcelain body, wherein the depth of the hole is two thirds of the thickness of the porcelain body;
(3) carrying out enamel color pattern decoration on the surface of the porcelain body;
(4) uniformly mixing a gem binder, water and guar gum according to the weight ratio of 85:10:5, then filling the mixture into the hole drilled in the step (2), and installing the bottom of the gem in the hole;
(5) placing porcelain body decorated with enamel color and provided with gem in kiln, firing at 1100 deg.C, and taking out of kiln
Obtaining the enamel color decorative porcelain body with the gem.
And (4) filling the hole with the gem binder, the water and the guar gum in the step (4) to be one third of the volume of the hole.
And (4) the enamel color pattern decoration on the surface of the porcelain body in the step (3) is realized by decal paper.
Example 4
The gem binder for enamel color porcelain decoration is characterized in that: the adhesive comprises the following components in percentage by weight: 38% of potash feldspar, 16% of calcite, 5% of Suzhou soil, 25% of quartz, 5% of talcum, 5% of nepheline powder, 6% of transparent frit and 5% of quartz fiber, and the gem binder is obtained by mixing, ball milling, sieving, adding the quartz fiber and uniformly stirring.
The gem is mozzarella.
The screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The transparent frit is formed by mixing a transparent frit A and a transparent frit B according to the weight percentage of 60: 40.
The chemical composition percentage of the transparent frit A is as follows: SiO 22 34%、B2O3 12%、Al2O3 13%、Li2O12%, MgO 15% and ZnO 14% through the processes of proportioning, grinding, high-temperature melting, quenching, ball milling and sieving to obtain the transparent frit A.
The parameters of the high-temperature melting process are as follows: the heating rate is 5 ℃/min, the highest melting temperature is 1200 ℃, and the heat preservation time is 30 min; the screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The chemical composition percentage of the transparent frit B is as follows: SiO 22 26%、B2O3 28%、Al2O3 28%、Na2O 7%、CaO 8%、ZrO23 percent of the raw materials are subjected to material mixing, grinding,And carrying out high-temperature melting, quenching, ball milling and sieving to obtain the transparent frit B.
The parameters of the high-temperature melting process are as follows: the heating rate is 5 ℃/min, the highest melting temperature is 1300 ℃, and the heat preservation time is 30 min; the screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The application method of the gem adhesive is characterized by comprising the following steps:
(1) selecting a high-quality porcelain body fired at 1290 ℃, wherein the porcelain body comprises a body and a glaze layer;
(2) mechanically drilling holes on the surface of the porcelain body according to the decoration position of the gem on the enamel colored porcelain;
(3) carrying out enamel color pattern decoration on the surface of the porcelain body;
(4) uniformly mixing a gem binder, water and guar gum according to the weight ratio of 85:10:5, then filling the mixture into the hole drilled in the step (2), and installing the bottom of the gem in the hole;
(5) the porcelain body decorated by the enamel color and provided with the gem is put into a kiln, fired at 1100 ℃, and taken out of the kiln to obtain the enamel color decorated porcelain body with the gem.
And (4) filling the hole with the gem binder, the water and the guar gum in the step (4) to be one third of the volume of the hole.
And (4) the enamel color pattern decoration on the surface of the porcelain body in the step (3) is hand-drawn.
Example 5
The gem binder for enamel color porcelain decoration is characterized in that: the adhesive comprises the following components in percentage by weight: 35% of potash feldspar, 16% of calcite, 6% of Suzhou soil, 25% of quartz, 7% of talcum, 6% of nepheline powder, 5% of transparent frit and 5% of quartz fiber, and the gem binder is obtained by mixing, ball milling, sieving, adding the quartz fiber and uniformly stirring.
The gemstone is rutile.
The screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The transparent frit is formed by mixing a transparent frit A and a transparent frit B according to the weight percentage of 0: 100.
The chemical composition percentage of the transparent frit B is as follows: SiO 22 26%、B2O3 28%、Al2O3 28%、Na2O 7%、CaO 8%、ZrO23 percent, and obtaining the transparent frit B through the working procedures of material preparation, grinding, high-temperature melting, quenching, ball milling and sieving.
The parameters of the high-temperature melting process are as follows: the heating rate is 5 ℃/min, the highest melting temperature is 1300 ℃, and the heat preservation time is 30 min; the screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
The application method of the gem adhesive is characterized by comprising the following steps:
(1) selecting a high-quality porcelain body fired at 1300 ℃, wherein the porcelain body comprises a body and a glaze layer;
(2) mechanically drilling holes on the surface of the porcelain body according to the decoration position of the gem on the enamel colored porcelain;
(3) carrying out enamel color pattern decoration on the surface of the porcelain body;
(4) uniformly mixing a gem binder, water and guar gum according to the weight ratio of 85:10:5, then filling the mixture into the hole drilled in the step (2), and installing the bottom of the gem in the hole;
(5) placing porcelain body decorated with enamel color and provided with gem into kiln, firing at 1050 deg.C, and discharging
Obtaining the enamel color decorative porcelain body with the gem.
And (4) filling the hole with the gem binder, the water and the guar gum in the step (4) to be one third of the volume of the hole.
And (4) the enamel color pattern decoration on the surface of the porcelain body in the step (3) is realized by decal paper.

Claims (6)

1. The gem binder for enamel color porcelain decoration is characterized in that: the adhesive comprises the following components in percentage by weight: 35-40% of potash feldspar, 15-20% of calcite, 5-10% of Suzhou soil, 25-30% of quartz, 5-10% of talcum, 5-10% of nepheline powder, 0-6% of transparent frit and 5% of quartz fiber, and the gem binder is obtained by mixing, ball milling, sieving, adding the quartz fiber and uniformly stirring;
the transparent frit comprises 3-6% by weight; the sieving process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue;
the application method of the gem binder comprises the following steps:
(1) selecting a high-quality porcelain body fired at 1260-1320 ℃, wherein the porcelain body comprises a body and a glaze layer;
(2) according to the decoration position of the gem on the enamel colored porcelain, mechanically drilling holes on the surface of the porcelain body, wherein the depth of the holes is two thirds of the thickness of the porcelain body;
(3) carrying out enamel color pattern decoration on the surface of the porcelain body;
(4) uniformly mixing a gem binder, water and guar gum according to the weight ratio of 85:10:5, then filling the mixture into the hole drilled in the step (2), and installing the bottom of the gem in the hole;
(5) and putting the porcelain body decorated by the enamel color and provided with the precious stone into a kiln, firing at 1000-1100 ℃, and taking out of the kiln to obtain the enamel color decorated porcelain body with the precious stone.
2. A gemstone bonding agent according to claim 1, wherein: the transparent frit is formed by mixing a transparent frit A and a transparent frit B according to the weight percentage of 0-100: 0-100.
3. A gemstone bonding agent according to claim 2, wherein: the chemical composition percentage of the transparent frit A is as follows: SiO 22 34%、B2O3 12%、Al2O3 13%、Li2O12%, MgO 15% and ZnO 14% through the processes of proportioning, grinding, high-temperature melting, quenching, ball milling and sieving to obtain transparent frit A;
the parameters of the high-temperature melting process are as follows: the heating rate is 5 ℃/min, the highest melting temperature is 1200 ℃, and the heat preservation time is 30 min; the screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
4. A gemstone bonding agent according to claim 2, wherein: the chemical composition percentage of the transparent frit B is as follows:SiO2 26%、B2O3 28%、Al2O3 28%、Na2O 7%、CaO 8%、ZrO23 percent, and obtaining transparent frit B through the working procedures of burdening, grinding, high-temperature melting, quenching, ball milling and sieving;
the parameters of the high-temperature melting process are as follows: the heating rate is 5 ℃/min, the highest melting temperature is 1300 ℃, and the heat preservation time is 30 min; the screening process comprises the following steps: sieving with 380 mesh sieve to obtain 0 residue.
5. A gemstone bonding agent according to claim 1, wherein: and (4) filling the hole with the gem binder, the water and the guar gum in the step (4) to be one third of the volume of the hole.
6. A gemstone bonding agent according to claim 1, wherein: and (4) the enamel color pattern decoration on the surface of the porcelain body in the step (3) is performed by hand drawing or decal paper.
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KR101857354B1 (en) * 2015-07-03 2018-05-11 영남대학교 산학협력단 Method for fabricating inlaid ceramics
CN105776872B (en) * 2016-03-17 2018-09-07 鹰牌陶瓷实业(河源)有限公司 A kind of coloured high transparency frit and preparation method thereof
CN106476117A (en) * 2016-10-10 2017-03-08 东莞华晶粉末冶金有限公司 A kind of method inlaying sapphire glass in zirconia ceramicss
CN107443992B (en) * 2017-08-11 2020-04-10 温州金瑞祥金银制品有限公司 Ceramic and silver inlaying and combining process

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