CN110520197A - silicone-free shampoo composition - Google Patents
silicone-free shampoo composition Download PDFInfo
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- CN110520197A CN110520197A CN201880013659.7A CN201880013659A CN110520197A CN 110520197 A CN110520197 A CN 110520197A CN 201880013659 A CN201880013659 A CN 201880013659A CN 110520197 A CN110520197 A CN 110520197A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/30—Characterized by the absence of a particular group of ingredients
- A61K2800/34—Free of silicones
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
Abstract
The present invention is in the field of cosmetics and relates to a silicone-free shampoo composition for human hair comprising at least one PPG-alkyl ether, at least one cationic conditioning polymer and at least one anionic, amphoteric and/or nonionic surfactant. The silicone-free shampoo compositions of the present invention allow for a significant improvement in the suppleness and/or combing of hair after use of the shampoo compositions. At the same time, the shampoo compositions of the invention allow for increased foam formation during the cleansing of the hair.
Description
Technical field
The invention belongs to cosmetic fields, and are related to for human hair without silicone hair-washing composition, the composition
Comprising at least one PPG- alkyl ether, at least one cationic conditioning polymer and at least one anion, both sexes and/or it is non-from
Sub- surfactant.
Background technique
Beautiful and attractive appearance is the expectation of many people.Define the main aspect of this positive appearance first is that head
The appearance of hair.For hair conditioning, consumer's usually a large amount of cosmetics of daily administration.It is produced in general, this is started from commercialization hair washing
Product clean hair.These hair washing products contain the surfactant that excessive dust or sebum are removed from hair.The surface-active
Agent is generally selected from anion, cation, both sexes and nonionic surfactant.In most cases, contain in hair-washing composition
There is anionic surfactant, because they promote formation of foam and ensure to effectively remove dirt, dust and/or sebum.
However, commercialization hair-washing composition generally also removes lipid and protein from hair and scalp, this is well known thing
It is real.This may cause dry scalp, or may be found that the structure of hair may become negatively affected, as a result the hair washing product
It is in hair under drying and fluffy and disorderly situation.As a result, hair is likely difficult to make in order after washing off the hair washing from hair
And/or it is difficult to comb.In addition, it is puckery and coarse usually to feel hair, such as when being slided with finger along hair, finger may be felt
Feel certain resistance.
In general, there are two types of the modes of the flexibility and cardability that improve hair.Firstly, can be applied after cleaning to hair
It is not required to the conditioning composition for rinsing or needing to rinse.It is living as surface that this composition usually only contains cationic surfactant
Property agent, the cationic surfactant is different from other surfaces activating agent, does not allow effective cleaning of hair.On the contrary, described
The hydrophilic end of cationic surfactant can be incorporated into the creatine of hair, and the cationic surfactant is hydrophobic
End can serve as the protective layer of hair.In addition, these conditioning compositions usually contain such as film forming polymer, moisturizer, water
Solve albumen and/or antistatic agent.However, being not required to rinse or the conditioner rinsed being needed to need second after cleaning hair consumption
When the step of.Therefore it provides a kind of composition of cleaning and conditioning hair simultaneously, will be desirable.
The flexibility of hair and the second way of cardability are improved, it can be by applying the hair washing group containing silicone component
Object is closed to realize.Silicone is outstanding conditioner, even if containing anion, both sexes and/or nonionic surfactant
In use, can also effectively be deposited on hair in hair-washing composition.Therefore, silicone provides improved compatibility, feeling, soft
The curly hair of softness and reduction.It is well known, however, that the fact be that silicone residue may accumulate on hair.As a result, these silicone are residual
Object is stayed to force down hair, this reduce hair volumes.Specifically, this is for fine and it is desirable that the consumer for gathering volume comes
Say the problem of being likely to become.Therefore, it is desirable to provide optionally without silicon-ketone composition, to hair offer conditioning effect and at the same time
Reduce the effect that silicone residue forces down hair.
It is generally found, no silicone hair-washing composition has the shortcomings that a large amount of.Specifically, those hair-washing compositions are usually in yin
Conditioning polymer is not allowed effectively to be deposited on hair in the presence of ionic surface active agent.As a consequence it is hardly possible to provide permission
Simultaneously clean hair and apply protectiveness conditioning layer without silicone hair-washing composition.In addition, usually existing without silicone hair-washing composition
Do not allow readily to arrange enough when combing wet hair after cleaning and/or the cardability of hair is adversely affected after cleaning.
In addition, many no silicone hair-washing compositions do not accumulate a large amount of foams when cleaning hair, wherein the foam-bubble formed is inadequate
It is small.
Summary of the invention
Therefore, the purpose of the present invention is to provide a kind of no silicone hair-washing composition, allow effectively cleaning hair and not
Show disadvantage discussed above.
2014077826 A1 of WO discloses a kind of cleaning compositions, contains anionic surfactant and alkoxylate
Alkyl ether.The document does not disclose the composition containing cationic conditioning polymer.Therefore, the document will not be professional
Technical staff guides the purpose of the present invention into.
Applicant is it has been found, surprisingly, that include at least one PPG- alkyl ether, at least one cationic conditioning polymer
Without silicone hair-washing composition allow to significantly improve conditioning at least one anion, both sexes and/or nonionic surfactant
Deposition of the polymer on hair.In addition, it has been found, surprisingly, that this no silicone hair-washing composition allows to wash described in use
The flexibility and/or cardability of hair are significantly improved after hair composition.Meanwhile hair-washing composition of the invention allows in cleaning head
Increase formation of foam during hair.
Hair-washing composition of the invention includes at least one PPG- alkyl ether as defined in formula (I)
Wherein i is the integer in 1 to 12 range, and j is the integer in 2 to 40 ranges.Term " PPG " indicates poly- the third two
Alcohol.
Preferred PPG- alkyl ether is determined by the i as the integer in 4 to 8 ranges and the j as the integer in 2 to 15 ranges
Justice.More preferably PPG-14 butyl ether.PPG-14 butyl ether is public by Dow Chemical at trade name UCON Fluid AP
Department's commercialization sale.
According to the present invention, the PPG- alkyl ether can with the total weight of composition of the invention be 0.05 weight % extremely
5 weight %, preferably 0.1 weight % to 4 weight %, more preferably 0.15 weight % to 3 weight % total concentration be present in institute
It states in composition.
In a preferred embodiment of the invention, PPG-14 butyl ether is contained only as PPG- alkyl ether.In these implementations
In mode, with the total weight of the composition, the total concentration of PPG-14 butyl ether in 0.05 weight % to 5 weight %, preferably
In the range of 0.1 weight % of ground to 4 weight %, more preferably 0.15 weight % to 3 weight %, and in the composition not
Containing other PPG- alkyl ethers.
Hair-washing composition of the invention includes at least one cationic conditioning polymer.In the sense of the invention, it states
" cationic polymer " refers to the polymer containing cation group and/or the group that can be ionized into cation group.
Since hair-washing composition of the invention is no silicon-ketone composition due to this, the cationic conditioning polymerization for including in the composition
Object does not include silicone atom.
According to the present invention, the cationic conditioning polymer is selected from:
(1) cation guar gum.This group of cationic conditioning polymer includes cationic guar derivative and hydrophobic changes
The cationic guar derivative of property.Preferred cationic guar derivative is cationic hydroxy (C1-C4)-alkyl-guar gum
Derivative such as hydroxyethyl trimethyl ammonium-guar gum or hydroxypropyl trimethyl ammonium-guar gum.Most preferably at CTFA
Claim known cationic guar derivative under guar gum trimethyl ammonium chloride.These products can be in trade name
It is obtained under JAGUAR C13 S, JAGUAR C 15 and JAGUAR C 17 from Solvay company.
(2) cationic cellulose.The example of cationic cellulose of the invention is selected from cationic cellulose copolymers, includes
The cellulose ether derivative of quaternary ammonium group or the cellulose derivative for being grafted with water soluble ammonium monomer.Specifically, preferably
Those include the epoxides replaced by hydroxy ethyl cellulose and trimethyl ammonium react the polymeric quaternary ammonium salts formed it is positive from
Subbundle element.For example, it is preferable to cationic cellulose in CTFA title polyquaternium -4, Polyquaternium-10 or Polyquaternium-67
It is lower known.Polyquaternium-10 can in trade name UCARE Polymer JR-400, Conditioner P10 orIt is commercially available under SC-240C Polymer.
(3) comprising at least one homopolymer and copolymer by formula (II)-(V) the polymeric chain component part defined:
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, alkyl or benzyl containing 1 to 18 carbon atom are indicated, wherein containing 1 to 6
The alkyl of carbon atom is preferred；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another, wherein selection methyl and/or second
Base is preferred；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably containing 2 or 3 carbon atoms, or indicates to contain
There is the hydroxy alkyl of 1 to 4 carbon atom；
A indicates halogen ion such as chloride ion or bromide ion, or such as methylsulphur of the anion from inorganic acid or organic acid
Acid radical anion.
According to the present invention, the copolymer comprising at least one monomeric unit stated hereinabove can also include following total
Polycondensation monomer, the comonomer are selected from acrylic or methacrylic acid, the ester of acrylic or methacrylic acid, acrylamide, first
Base acrylamide, on nitrogen by alkyl-substituted acrylamides and Methacrylamide, diacetone containing 1 to 4 carbon atom
Acrylamide, vinyl lactam such as caprolactam or vinyl pyrrolidone and/or vinyl esters.
The typical polymers of this group are for example by dithyl sulfate and vinyl pyrrolidone and dialkyl amido alkane
The polymer that the reaction of the copolymer of base acrylate or methacrylate is formed, such as by Ashland company in trade name
The substance sold under GAFQUAT.Typical instance name is GAFQUAT 755, GAFQUAT 755N or GAFQUAT 734.This
One group of other polymers are at trade name Copolymer 845 or Copolymer 937 it is known that they can also be from
Commercially available from Ashland company.Another example of this cationic conditioning polymer is polyquaternium -47, by Lubrizol public affairs
Department sells at trade name Merquat 2001Polymer.
(4) as being formed by the monomer mixture comprising methylvinyl imidazolium chloride and vinyl pyrrolidone
The copolymer of quaternary ammonium salt.The representative instance of these copolymers is by BASF AG in trade name Luviquat FC 905, Liviquat
FC 550 and Luviquat FC 370 is lower to be sold.
(5) it as the homopolymer of polymeric chain component part and is total to comprising the annular unit as defined in formula (VI) or (VII)
Polymers:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxyl alkane containing 1 to 5 carbon atom are indicated independently of one another
Base；And
B is anion, for example, halogen ion (bromide ion, chloride ion), acetate, borate, citrate, tartrate anion,
Bisulfate ion, bisulfite, sulfate radical or phosphate radical.
If wherein the structure of these annular units is characterized in that substituent R8And R9It indicates to contain 1 to 4 independently of one another
The alkyl of a carbon atom is then preferred.Typical cationic copolymer containing these annular units is in CTFA title poly- season
Ammonium salt -7 is lower it is known that it polymerize from acrylamide and dimethyl diallyl ammonium chloride.Polyquaternium -7 can be in various differences
Trade name under it is commercially available.The product Merquat 550Polymer that is particularly preferably sold by Lubrizol company and by BASF
The Salcare SC10 of company's sale.
The preferred homopolymer of structure stated hereinabove is lower it is known that it is dimethyl two in such as CTFA title polyquaternium -6
The polymeric quaternary ammonium salts of allyl ammonium chloride.Polyquaternium -6 can be in the trade name Merquat sold by Lubrizol company
It is commercially available under 100Polymer.
According to the present invention, cationic conditioning polymer listed above can be with the total weight of the hair-washing composition
0.001 weight % to 10 weight %, preferably 0.1 weight % are total to 5 weight %, more preferably 0.2 weight % to 2 weight %
Concentration is present in the composition.
It include that cationic conditioning polymer in hair-washing composition of the invention is preferably chosen from polyquaternium -4, poly- season
Ammonium salt -6, Polyquaternium-10, polyquaternium -47, Polyquaternium-67, hydroxypropyl guar gum trimethyl ammonium chloride
And/or guar gum trimethyl ammonium chloride.
Particularly preferably molecular weight (weight equal) be 1000 to 5000000, preferably 100000 to 3000000 and sun from
Charge of the electron density is at least cationic guar polymer of 0.5meq/g.
In the case where containing guar gum trimethyl ammonium chloride as cationic conditioning polymer, preferred pachyrhizus
The concentration of your glue trimethyl ammonium chloride is in the range of 0.05 weight % to 0.2 weight %.And in addition, containing
In the case that guar gum trimethyl ammonium chloride is as cationic conditioning polymer, preferably in the composition
Contain at least one selected from polyquaternium -4, polyquaternium -6, Polyquaternium-10, polyquaternium -47 and Polyquaternium-67
Cationic conditioning polymer.
According to the present invention, the anion, both sexes and/or nonionic surfactant can be with the gross weights of the composition
The total concentration that amount is calculated as 4 weight % to 40 weight % exists.
The anionic surfactant that can be suitble to used in hair-washing composition of the invention includes: to contain 8 to 30
The straight chain and branched chain fatty acid of a carbon atom；Formula R10-(OCH2-CH2)m-OSO3 -C+Alkylsurfuric acid compound and/or the poly- second of alkyl
Glycol ethers hydrosulphate, wherein R10Indicate that the linear chain or branched chain containing 8 to 24 carbon atoms, saturation or unsaturated alkyl, m indicate
Integer in 0 to 12 range, C indicate alkali metal, alkaline-earth metal, ammonium or alkanolamine ion；Containing 8 to 24 carbon atoms and include
The sulfonate of the unsaturated fatty acid of 1 to 6 double bond；Formula R11-O-(CH2-CH2O)n-CH2The ether carboxylic acid of-COOH, wherein R11It is
Linear chain or branched chain, saturation or unsaturated alkyl containing 8 to 30 carbon atoms, and x is the integer in 0 to 16 range；Acyl group
Isethionate, acyl taurine salt or acyl sarcosinates, it is each leisure acyl group in contain 8 to 24 carbon atoms；Containing 8 to
The alpha-alkene sulfonate of 24 carbon atoms；Sulfosuccinic acid monoalkyl and/or dioxane containing 8 to 24 carbon atoms in alkyl
Base ester, and the sulfosuccinic acid monoalkyl polyoxy second containing 8 to 24 carbon atoms and containing 1 to 6 oxygroup ethyl in alkyl
Base ester；The ester of tartaric acid or citric acid and the alcohol containing 8 to 22 carbon atoms, the alcohol are 2 to 15 oxireme and/or ring
The addition product of oxypropylene molecule；And/or the alkyl and/or alkenyl ether phosphate of formula (VIII):
Wherein R12Indicate the aliphatic group containing 8 to 30 carbon atoms, R13Indicate hydrogen atom, (OCH2-CH2)q-R12Group
Or D,
Wherein q indicates that the integer in 0 to 10 range, D indicate hydrogen, alkali metal, alkaline-earth metal or the quaternary ammonium containing 4 alkyl
Ion, the alkyl respectively contain 1 to 4 carbon atom independently of each other.
The anionic surfactant is preferably chosen from:
(1) formula R10-(OCH2-CH2)m-OSO3 -C+Alkylsurfuric acid compound and/or alkyl polyglycol ether hydrosulphate,
Middle R10Indicate that the linear chain or branched chain containing 8 to 24 carbon atoms, saturation or unsaturated alkyl, m indicate whole in 0 to 12 range
Number, C indicate alkali metal, alkaline-earth metal, ammonium or alkanolamine ion；With
(2) sulfonate of the unsaturated fatty acid containing 8 to 24 carbon atoms and comprising 1 to 6 double bond.
The suitable but non-limiting example of those preferred anionic surfactants is sodium laureth sulfate and laurel
Base sodium sulphate.
The concentration of anionic surfactant is preferably existed in the hair-washing composition with the total weight of the composition
In the range of 5 weight % to 30 weight %, more preferably 10 weight % to 20 weight %.
In order to provide hair-washing composition very sensitive for scalp and nonirritant, add with the gross weight of the composition
Meter total concentration is 0.5 weight % to 15 weight %, preferably 1 weight % to 5 weight %, more preferably 1.5 weight % to 4 weights
At least one amphoteric surfactant for measuring %, is beneficial.
The amphoteric surfactant is preferably chosen from alkyl amine oxide, alkyl betaine, alkyl amidopropyl betaine
Alkali, alkyl sulfo betaines (sulphonic acid betaine), alkyl glycine salt, alkyl carboxyl glycinate, alkyl both sexes acetate, alkane
Base both sexes propionate, alkyl both sexes glycinate, alkylamidopropyl group hydroxyl sulfoacid glycine betaine, acyl taurine salt and acyl group
Glutamate, wherein the alkyl and acyl group contain 8 to 19 carbon atoms.The representative instance of those groups includes lauryl oxidation
Amine, cocoyl dimethyl sulfopropyl betaine, lauryl betaine, Cocoamidopropyl betaine and cocounut oil acyl both sexes acetic acid
Sodium.Wherein, select Cocoamidopropyl betaine as most preferred amphoteric surfactant.
In addition, in order to support that clean-up performance, hair-washing composition of the invention can be containing with the total weights of the composition
Concentration is counted in 0.3 weight % to 15 weight %, preferably 0.5 weight % to 10 weight %, more preferably 1 weight % to 8 weights
Measure one or more nonionic surfactants within the scope of %.
The suitable example of nonionic surfactant be the linear chain or branched chain containing 8 to 18 carbon atoms aliphatic primary or
The condensation product of secondary alcohol or phenol and ethylene oxide, it includes 6 to 30 ethylene oxide groups.Other suitable non-ionic surfaces are living
Property agent includes list or dialkyl amide.Typical example is cocoyl list or diglycollic amide and cocoyl list isopropanol acyl
Amine.The nonionic surfactant for other groups that may be embodied in the hair-washing composition is alkyl poly glucoside or dehydration
The addition product of sorbitan fatty acid ester and ethylene oxide and sorbitan fatty ester such as polysorbate.Especially
Preferred nonionic surfactant be selected from fatty acid alkanol amides for example in such as CTFA title Cocamide MEA and
Known cocoyl list or diglycollic amide and/or alkyl glycosides under Cocamide DEA.
In first preferred embodiment, no silicone hair-washing composition of the invention includes with the gross weight of the composition
Meter:
A) 0.05 weight % to 5 weight %, preferably 0.1 weight % to 4 weight %, more preferably 0.15 weight % to 3
At least one PPG- alkyl ether as defined in formula (I) of weight %
Wherein i is the integer in 1 to 12 range, and j is the integer in 2 to 40 ranges；
B) at least one cationic conditioning polymer, is selected from:
(1) cation guar gum；
(2) cationic cellulose；
(3) homopolymer and copolymer comprising at least one polymeric chain component part defined by following formula (II)s-(V):
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably 2 or 3 carbon atoms, or contains 1 to 4
The hydroxy alkyl of carbon atom；
A indicates halogen ion or the anion from inorganic acid or organic acid；
(4) copolymer is by the monomer mixing comprising methylvinyl imidazolium chloride and vinyl pyrrolidone
The quaternary ammonium salt that object is formed；
(5) it as the homopolymer of polymeric chain component part and is total to comprising the annular unit as defined in formula (VI) or (VII)
Polymers:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxyl alkane containing 1 to 5 carbon atom are indicated independently of one another
Base；And
B is anion；And
C) at least one anionic surfactant.
In first embodiment, the particularly preferably described no silicone hair-washing composition includes with the composition
Total weight:
A) 0.05 weight % to 5 weight %, preferably 0.1 weight % to 4 weight %, more preferably 0.15 weight % to 3
The PPG-14 butyl ether of weight %；
B) 0.001 weight % to 10 weight %, preferably 0.1 weight % to 5 weight %, more preferably 0.2 weight % to 2
At least one cationic conditioning polymer of weight %, is selected from:
(1) cation guar gum；
(2) cationic cellulose；
(3) homopolymer and copolymer comprising at least one polymeric chain component part defined by following formula (II)s-(V):
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably 2 or 3 carbon atoms, or contains 1 to 4
The hydroxy alkyl of carbon atom；
A indicates halogen ion or the anion from inorganic acid or organic acid；
(4) copolymer is by the monomer mixing comprising methylvinyl imidazolium chloride and vinyl pyrrolidone
The quaternary ammonium salt that object is formed；
(5) it as the homopolymer of polymeric chain component part and is total to comprising the annular unit as defined in formula (VI) or (VII)
Polymers:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxyl alkane containing 1 to 5 carbon atom are indicated independently of one another
Base；And
B is anion；And
C) at least one anionic surfactant.
Most preferably without silicone hair-washing composition comprising with the composition in first embodiment of the invention
Total weight:
A) the PPG-14 butyl ether of 0.15 weight % to 3 weight %；
B) 0.2 weight % is selected at least one cationic conditioning polymer of 2 weight %
(1) cation guar gum；
(2) cationic cellulose；
(3) homopolymer and copolymer comprising at least one polymeric chain component part defined by following formula (II)s-(V):
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably 2 or 3 carbon atoms, or contains 1 to 4
The hydroxy alkyl of carbon atom；
A indicates halogen ion or the anion from inorganic acid or organic acid；
(4) copolymer is by the monomer mixing comprising methylvinyl imidazolium chloride and vinyl pyrrolidone
The quaternary ammonium salt that object is formed；
(5) it as the homopolymer of polymeric chain component part and is total to comprising the annular unit as defined in formula (VI) or (VII)
Polymers:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxyl alkane containing 1 to 5 carbon atom are indicated independently of one another
Base；And
B is anion；And
C) 5 weight % are selected at least one anionic surfactant of 30 weight %
(1) formula R10-(OCH2-CH2)m-OSO3 -C+Alkylsurfuric acid compound and/or alkyl polyglycol ether hydrosulphate,
Middle R10Indicate that the linear chain or branched chain containing 8 to 24 carbon atoms, saturation or unsaturated alkyl, m indicate whole in 0 to 12 range
Number, C indicate alkali metal, alkaline-earth metal, ammonium or alkanolamine ion；With
(2) sulfonate of the unsaturated fatty acid containing 8 to 24 carbon atoms and comprising 1 to 6 double bond.
In second preferred embodiment, no silicone hair-washing composition of the invention includes with the gross weight of the composition
Meter:
A) 0.05 weight % to 5 weight %, preferably 0.1 weight % is to 4 weight %, most preferably 0.15 weight % to 3
The PPG- alkyl ether that at least one of weight % is defined by formula (I)
Wherein i is the integer in 1 to 12 range, and j is the integer in 2 to 40 ranges；
B) at least one cation guar gum and at least one cationic cellulose；And
C) at least one anionic surfactant.
In this second embodiment, the particularly preferably described no silicone hair-washing composition includes with the composition
Total weight:
A) 0.05 weight % to 5 weight %, preferably 0.1 weight % to 4 weight %, more preferably 0.15 weight % to 3
The PPG-14- butyl ether of weight %；
B) at least one cation guar gum of 0.2 weight % to 2 weight % and at least one cationic cellulose；And
C) at least one anionic surfactant.
Most preferably without silicone hair-washing composition comprising with the composition in second embodiment of the invention
Total weight:
A) the PPG-14 butyl ether of 0.15 weight % to 3 weight %；
B) the guar gum trimethyl ammonium chloride and Polyquaternium-10 of 0.2 weight % to 2 weight %；And
C) 5 weight % are selected at least one anionic surfactant of 30 weight %:
(1) formula R10-(OCH2-CH2)m-OSO3 -C+Alkylsurfuric acid compound and/or alkyl polyglycol ether hydrosulphate,
Middle R10Indicate that the linear chain or branched chain containing 8 to 24 carbon atoms, saturation or unsaturated alkyl, m indicate whole in 0 to 12 range
Number, C indicate alkali metal, alkaline-earth metal, ammonium or alkanolamine ion；With
(2) sulfonate of the unsaturated fatty acid containing 8 to 24 carbon atoms and comprising 1 to 6 double bond.
In third preferred embodiment, no silicone hair-washing composition of the invention includes with the gross weight of the composition
Meter:
A) 0.05 weight % to 5 weight %, preferably 0.1 weight % to 4 weight %, more preferably 0.15 weight % to 3
The PPG- alkyl ether that at least one of weight % is defined by formula (I)
Wherein i is the integer in 1 to 12 range, and j is the integer in 2 to 40 ranges；
B) at least one cation guar gum and at least one are defined comprising at least one by following formula (II)s-(V) poly-
Close the cationic homopolymer or copolymer of chain component part:
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably 2 or 3 carbon atoms, or contains 1 to 4
The hydroxy alkyl of carbon atom；
A indicates halogen ion or the anion from inorganic acid or organic acid；And
C) at least one anionic surfactant.
In the third embodiment, the particularly preferably described no silicone hair-washing composition includes with the composition
Total weight:
A) 0.05 weight % to 5 weight %, preferably 0.1 weight % to 4 weight %, more preferably 0.15 weight % to 3
The PPG-14 butyl ether of weight %；
B) 0.001 weight % to 10 weight %, preferably 0.1 weight % to 5 weight %, more preferably 0.2 weight % to 2
A kind of cation guar gum of weight % and at least one polymerization chain group defined comprising at least one by following formula (II)s-(V)
At the cationic homopolymer or copolymer of part:
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably 2 or 3 carbon atoms, or contains 1 to 4
The hydroxy alkyl of carbon atom；
A indicates halogen ion or the anion from inorganic acid or organic acid；And
C) at least one anionic surfactant.
Most preferably without silicone hair-washing composition comprising with the combination in the third embodiment of the invention
The total weight of object:
A) the PPG-14 butyl ether of 0.15 weight % to 3 weight %；
B) a kind of cation guar gum of 0.2 weight % to 2 weight % and at least one include at least one by following formula
(II) cationic homopolymer or copolymer for the polymeric chain component part that-(V) is defined:
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably 2 or 3 carbon atoms, or contains 1 to 4
The hydroxy alkyl of carbon atom；
A indicates halogen ion or the anion from inorganic acid or organic acid；And
C) 5 weight % are selected at least one anionic surfactant of 30 weight %:
(1) formula R10-(OCH2-CH2)m-OSO3 -C+Alkylsurfuric acid compound and/or alkyl polyglycol ether hydrosulphate,
Middle R10Indicate that the linear chain or branched chain containing 8 to 24 carbon atoms, saturation or unsaturated alkyl, m indicate whole in 0 to 12 range
Number, C indicate alkali metal, alkaline-earth metal, ammonium or alkanolamine ion；With
(2) sulfonate of the unsaturated fatty acid containing 8 to 24 carbon atoms and comprising 1 to 6 double bond.
In the 4th preferred embodiment, no silicone hair-washing composition of the invention includes with the gross weight of the composition
Meter:
A) 0.05 weight % to 5 weight %, preferably 0.1 weight % to 4 weight %, more preferably 0.15 weight % to 3
The PPG- alkyl ether that at least one of weight % is defined by formula (I)
Wherein i is the integer in 1 to 12 range, and j is the integer in 2 to 40 ranges；
B) at least one cation guar gum and at least one are made comprising the annular unit as defined in formula (VI) or (VII)
For the homopolymer or copolymer of polymeric chain component part:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxyl alkane containing 1 to 5 carbon atom are indicated independently of one another
Base；And
B is anion；And
C) at least one anionic surfactant.
In the 4th embodiment, the particularly preferably described no silicone hair-washing composition includes with the composition
Total weight:
A) 0.05 weight % to 5 weight %, preferably 0.1 weight % to 4 weight %, more preferably 0.15 weight % to 3
The PPG-14 butyl ether of weight %；
B) 0.001 weight % to 10 weight %, preferably 0.1 weight % to 5 weight %, more preferably 0.2 weight % to 2
At least one cation guar gum and at least one of weight % includes the annular unit conduct as defined in formula (VI) or (VII)
The homopolymer or copolymer of polymeric chain component part:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxyl alkane containing 1 to 5 carbon atom are indicated independently of one another
Base；And
B is anion；And
C) at least one anionic surfactant.
Most preferably without silicone hair-washing composition comprising with the combination in the 4th embodiment of the invention
The total weight of object:
A) the PPG-14 butyl ether of 0.15 weight % to 3 weight %；
B) at least one cation guar gum of 0.2 weight % to 2 weight % and be selected from polyquaternium -6 and polyquaternium -
7 at least one cationic polymer；
C) 5 weight % are selected at least one anionic surfactant of 30 weight %
(1) formula R10-(OCH2-CH2)m-OSO3 -C+Alkylsurfuric acid compound and/or alkyl polyglycol ether hydrosulphate,
Middle R10Indicate that the linear chain or branched chain containing 8 to 24 carbon atoms, saturation or unsaturated alkyl, m indicate whole in 0 to 12 range
Number, C indicate alkali metal, alkaline-earth metal, ammonium or alkanolamine ion；With
(2) sulfonate of the unsaturated fatty acid containing 8 to 24 carbon atoms and comprising 1 to 6 double bond.
In the 5th preferred embodiment, no silicone hair-washing composition of the invention includes with the gross weight of the composition
Meter:
A) 0.05 weight % to 5 weight %, preferably 0.1 weight % to 4 weight %, more preferably 0.15 weight % to 3
The PPG- alkyl ether that at least one of weight % is defined by formula (I)
Wherein i is the integer in 1 to 12 range, and j is the integer in 2 to 40 ranges；
B) at least one cationic conditioning polymer, is selected from:
(1) cation guar gum；
(2) cationic cellulose；
(3) homopolymer and copolymer comprising at least one polymeric chain component part defined by following formula (II)s-(V):
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably 2 or 3 carbon atoms, or contains 1 to 4
The hydroxy alkyl of carbon atom；
A indicates halogen ion or the anion from inorganic acid or organic acid；
(4) copolymer is by the monomer mixing comprising methylvinyl imidazolium chloride and vinyl pyrrolidone
The quaternary ammonium salt that object is formed；
(5) it as the homopolymer of polymeric chain component part and is total to comprising the annular unit as defined in formula (VI) or (VII)
Polymers:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxyl alkane containing 1 to 5 carbon atom are indicated independently of one another
Base；And
B is anion；And
C) at least one anion, both sexes and/or the nonionic surfactant of 4 weight % to 40 weight %.
In the 5th embodiment, the particularly preferably described no silicone hair-washing composition includes with the composition
Total weight:
A) 0.05 weight % to 5 weight %, preferably 0.1 weight % to 4 weight %, more preferably 0.15 weight % to 3
The PPG-14 butyl ether of weight %；
B) 0.001 weight % to 10 weight %, preferably 0.1 weight % to 5 weight %, more preferably 0.2 weight % to 2
At least one cationic conditioning polymer of weight %, is selected from:
(1) cation guar gum；
(2) cationic cellulose；
(3) homopolymer and copolymer comprising at least one polymeric chain component part defined by following formula (II)s-(V):
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably 2 or 3 carbon atoms, or contains 1 to 4
The hydroxy alkyl of carbon atom；
A indicates halogen ion or the anion from inorganic acid or organic acid；
(4) copolymer is by the monomer mixing comprising methylvinyl imidazolium chloride and vinyl pyrrolidone
The quaternary ammonium salt that object is formed；
(5) it as the homopolymer of polymeric chain component part and is total to comprising the annular unit as defined in formula (VI) or (VII)
Polymers:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxyl alkane containing 1 to 5 carbon atom are indicated independently of one another
Base；And
B is anion；And
C) 4 weight % are at least one anion, both sexes and/or the nonionic surfactant of 40 weight %, wherein institute
State range of the concentration in 5 weight % to 30 weight %, more preferably 10 weight % to 20 weight % of anionic surfactant
It is interior.
Most preferably without silicone hair-washing composition comprising with the combination in the 5th embodiment of the invention
The total weight of object:
A) the PPG-14 butyl ether of 0.15 weight % to 3 weight %；
B) 0.2 weight % is selected at least one cationic conditioning polymer of 2 weight %:
(1) cation guar gum；
(2) cationic cellulose；
(3) homopolymer and copolymer comprising at least one polymeric chain component part defined by following formula (II)s-(V):
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably 2 or 3 carbon atoms, or contains 1 to 4
The hydroxy alkyl of carbon atom；
A indicates halogen ion or the anion from inorganic acid or organic acid；
(4) copolymer is by the monomer mixing comprising methylvinyl imidazolium chloride and vinyl pyrrolidone
The quaternary ammonium salt that object is formed；
(5) it as the homopolymer of polymeric chain component part and is total to comprising the annular unit as defined in formula (VI) or (VII)
Polymers:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxyl alkane containing 1 to 5 carbon atom are indicated independently of one another
Base；And
B is anion；And
C) at least one anion, both sexes and the nonionic surfactant of 4 weight % to 40 weight %, wherein the yin
The concentration of ionic surface active agent in the range of 5 weight % to 30 weight %, preferably 10 weight % to 20 weight %,
The concentration of the amphoteric surfactant 0.5 weight % to 15 weight %, preferably 1 weight % to 5 weight %,
In the range of more preferably 1.5 weight % to 4 weight %, and
The concentration of the nonionic surfactant is in 0.3 weight % to 15 weight %, preferably 0.5 weight % to 10 weights
In the range of amount %, more preferably 1 weight % to 8 weight %.
Hair-washing composition of the invention can also preferably include one or more cationic surfactants.It can be at this
The cationic surfactant being suitble to used in the hair-washing composition of invention is the quaternary ammonium salt defined by formula (IX):
Wherein R14And R15It indicates hydrogen atom or containing 1 to 4 carbon atom and is optionally replaced by one or more hydroxyls
Alkyl,
And wherein R16Indicate saturated or unsaturated branch or unbranched alkyl chain containing 8 to 24 carbon atoms,
Or R16Indicate R18CON(CH2)rGroup, wherein R18It is the saturated or unsaturated branch containing 7 to 21 carbon atoms
Chain or unbranched alkyl chain, and r is the integer in 1 to 4 range,
Or R16Indicate R19COO(CH2)sGroup, wherein R19Indicate saturated or unsaturated containing 7 to 21 carbon atoms
Branch or unbranched alkyl chain, and s is the integer in 1 to 4 range,
And wherein R17Indicate hydrogen atom or saturated or unsaturated branch or unbranched alkane containing 8 to 24 carbon atoms
Base chain,
Or R17Indicate R18CON(CH2)rOr R19COO(CH2)sGroup, wherein R18、R19, r and s have it is same as described above
Meaning,
And E is anion, preferably chloride ion or bromide ion.
The suitable but non-limiting example of cationic surfactant defined above is octyltrimethylammonium chloride, decyl
Trimethyl ammonium chloride, dodecyl trimethyl ammonium chloride, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, behenyl
Base trimethyl ammonium chloride, tetramethyl ammonium chloride, etamon chloride, cetyl pyridinium chloride, octyldimethyl benzyimag iesium chloride
Ammonium, decyl dimethyl benzyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, double dodecyl dimethyl ammonium chlorides and double
Octadecyldimethyl ammonium chloride.
The most preferred cationic surfactant for including in the present compositions is cetyl trimethyl ammonium chloride
And/or behenyl base trimethyl ammonium chloride.Cetyl trimethyl ammonium chloride can at trade name VARISOFT 300 from
Fa.Evonik Industries is obtained or in trade nameIt is obtained under A-CA from Fa.BASF.Behenyl base front three
Ammonium chloride can be in trade nameUnder AB commercially available from Fa.Kao Chemicals.
The cationic surfactant is preferably pressed with the total weight of the composition as 0.1 weight % to 5 weights
The concentration measured within the scope of %, more preferably 0.2 weight % to 3 weight % uses.
In addition, adding nonionic or amphoteric conditioning agent such as protein or polyprotein hydrolysate to the hair-washing composition
It is beneficial such as the collagen of the silk of hydrolysis, the wheat gluten of hydrolysis and/or hydrolysis.
The another kind of beneficial non-ionic conditioning agents that may be embodied in hair-washing composition of the invention are comprising 8 to 22
The fatty alcohol of carbon atom, preferably 14 to 18 carbon atoms.In those preferred fatty alcohols, linear saturation alcohol such as spermaceti
Alcohol, stearyl alcohol and/or its mixture are most preferred.
Cetanol can be in trade nameUnder 16 commercially available from BASF AG.Similarly, stearyl alcohol can be in commodity
NameIt is bought under 18 from BASF AG.The mixture of cetanol and stearyl alcohol can also be obtained from BASF AG.It is described
The trade name of mixture is referred to asO。
It is 0.01 weight % to 5 weight % that the fatty alcohol, which is preferably pressed with the total weight of the composition, more preferable
The total concentration of 0.1 weight % of ground to 2 weight % by comprising.
The another kind of non-ionic conditioning agents that may be embodied in hair-washing composition of the invention are water-soluble nonionic fibers
Plain polymer.
Term " water solubility " refer to it is solvable enough in water, at 25 DEG C at 1.0 weight % or higher concentration in water
The middle any material for forming solution transparent for naked eye.
Suitable water-soluble nonionic cellulosic polymer can be selected from methylcellulose, ethyl cellulose, ethoxy second
Base cellulose, methylethylcellulose, hydroxypropyl cellulose and/or hydroxypropyl methyl cellulose.
The water-soluble nonionic cellulosic polymer usually can be by with the total weight of hair-washing composition of the invention
It is present in the composition for the concentration within the scope of 0.01 to 2 weight %, preferably 0.02 to 0.5 weight %.
In the present compositions containing in the case where these water-soluble nonionic cellulosic polymers, this hair is being used
Feel that hair is especially smooth after bright hair-washing composition.
Composition of the invention can also include one or more rheology modifiers without cation group.These rheologies
Modifying agent can be selected from polyacrylic acid, the cross-linked polymer of acrylic or methacrylic acid, acrylic or methacrylic acid and dredge
The cross-linked copolymer of the copolymer of aqueous monomer, the copolymer containing carboxylic acid monomer and acrylate and acrylic acid and acrylate,
On condition that these polymer are free of cation group.Also the polymer with the acrylic acid of multifunctional reagent crosslinking can be used；It
Can be used as Carbopol 980,10 polymer of Carbopol Ultrez and Carbopol Aqua SF-1 polymer quotient
Purchase, and can be bought from Lubrizol company.Include the reality containing carboxylic acid monomer and the suitable copolymer of acrylate monomer
Example is 134 polymer of Carbopol and Pemulen TR-1, can also be obtained from Lubrizol company.In general, it is preferred that
Those are known rheology modified at CTFA title Carbomer and acrylate/C10-30 alkyl acrylate cross-linked polymer
Agent.
Preferred rheology modifier listed above can be with the total weight of composition of the invention for 0.1 weight % to 6
Weight %, preferably 0.5 weight % to 4 weight % concentration be present in the composition.
In order to further increase the opsonizing capacity of the hair-washing composition, the hair-washing composition can be additionally comprised with institute
The total weight total concentration for stating composition is 0.01 weight % to 5 weight %, is preferably 0.1 weight % to 4.5 weight % extremely
A few vegetable oil and/or fruit oil.The preferred vegetable oil or fruit oil that may include in the composition be walnut oil,
Bamboo oil, grape seed oil, apricot kernel oil, avocado oil, tea oil, soybean oil, sesame oil, sunflower oil, Chinese toon caul-fat, is shown in the moon persic oil
Careless oil, rice bran oil, palm-kernel oil, awns nut oil, creeping oxalis oil, Ji oil, coconut oil, (sweet tea) apricot kernel oil, macadimia nut oil, three-coloured amaranth
Seed oil, argan oil, olive oil, wheat-germ oil, pumpkin seed oil, hazelnut oil, high mallow oil, safflower oil, canola oil, camellia
Oil, jojoba oil, rambutan oil, cocoa butter, shea butter and/or these oily mixtures.
Furthermore, it is possible to composition addition citric acid of the invention or lactic acid to adjust pH value.If desired, also can wrap
It is adjusted containing sodium hydroxide for pH.The pH value of the composition is in the range of 3.0 to 6.9, preferably 3.5 to 6.5.
In addition, it is more than 50 weights that hair-washing composition of the invention, which may include with the total weight concentration of the composition,
Measure the water of %, preferably more than 65 weight %.
In order to provide visually attractive product, hair-washing composition of the invention can also include pearling agent such as two
Stearic acid second diester, C8-C30Fatty acid monoethylene glycol ester and/or pigments, mica with coating of titanium dioxide.
The preferred pearling agent that may be embodied in hair-washing composition of the invention is can be in trade name REWOPAL
The PEG-150 distearate that is obtained under 6000DS from Evonik Industries company and can be for example in trade nameFrom Clariant company and in trade name under PMSThe distearyl acid obtained under EGMS from BASF AG
Second diester.The pearling agent is preferably with the total weight of hair-washing composition of the invention for 0.01 weight % to 2 weight %, excellent
The concentration of 0.02 weight % of selection of land to 1 weight % includes in the composition.
The other active components that may be embodied in hair-washing composition of the invention are anti-dandruff activating agents.These anti-dandruffs
Activating agent can be with the total weight of the composition for 0.025 weight % to 7.5 weight %, preferably 0.05 weight % to 4
The amount of weight % uses.Suitable anti-dandruff activating agent can selected from piroctone olamine, Climbazole, zinc pyrithione,
Ketoconazole, sulphur, selenium sulfide, tar preparation, endecatylene acid derivative, burdock extract, poplar extract, stinging nettle are extracted
Object, English walnut shell extract, birch extract and/or Arnica extract.Particularly preferred anti-dandruff activating agent is selected from name monochloro
Miaow bar azoles, zinc pyrithione and piroctone olamine.
Hair-washing composition of the invention can also include one or more preservatives.Comprising in the present compositions
Suitable preservative is such as sodium benzoate, sodium salicylate, Phenoxyethanol, Sensiva SC50, methyl p-hydroxybenzoate, right
Nipagin A, benzyl alcohol, methylisothiazolinone, methylchloroisothiazandnone and/or DMDM hydantoin.Use benzene
Sodium formate and/or sodium salicylate are preferred.
If composition of the invention is loaded and is stored in tank, bottle, squeezing bottle, pump spray or aerosol can,
It is advantageous.
Other objects of the present invention are:
The purposes of hair-washing composition of the invention is used to clean hair and scalp.
The purposes of hair-washing composition of the invention is used to cationic conditioning polymer being deposited on hair.
The method for preparing hair-washing composition of the invention, wherein merging and stirring each component.
The method for cleaning human hair comprising apply composition of the invention and 5 seconds to 2 points after application to wet hair
The step of composition is washed off from hair with water in clock.
Without being bound by theory, the PPG- alkyl ether can be with the cationic conditioning polymer and/or a kind of yin
Ion, both sexes and/or nonionic surfactant interaction form compound with them, lead to the conditioning compound
Deposition on hair increases.Thus, it is possible to surprisingly improve the submissive of hair in the case where not using silicone component
Property and/or cardability.
When in entire this specification in use, term " hair " only refers to the human hair on scalp.
It has been found, surprisingly, that obtaining improved foam property after cleaning hair with composition of the invention.This
Outside, after being washed off hair-washing composition of the invention from hair with water, the cardability of hair is significantly improved.In addition, combing one's hair
When hair be easier to make and observe that conditioning polymer preferably deposits in order, do not use silicone in the case where improve hair
Coating.
Embodiment
The following examples but are not intending to by composition of the invention is illustrated and limit the invention to these embodiments.It is real
Applying the numerical value in example is with the weight percent of the total weight of prepared product.The composition is by merging all components and mixing
The mixture is closed and/or stirred to prepare.
Embodiment 1-8
Hair-washing composition
Com=comparative example, not according to the present invention
Inv=example, according to the present invention
Embodiment 9-16
Hair-washing composition
Com=comparative example, not according to the present invention
Inv=example, according to the present invention
In order to assess the property of composition Ex.2 of the invention compared with composition Ex.1 not of the invention, ground
Study carefully.The assessment is carried out by well-trained hairdresser, assesses the state and hair washing performance of hair.Test is black using Asian
The topknot of hair carries out.
Firstly, the composition after use, is assessed the amount of foam and the gas of foam in cleaning on wet hair
Steep size.In order to assess the amount of foam, hairdresser need the amount that the foam gathered in cleaning is determined in each test be it is high,
It is average or low.In order to assess bubble size, assessed as unit of the percentage of total bubble in hair washing occur big or middle and
The distribution of minute bubbles.
After washing off shampoo from hair with water, flexibility and cardability of the hair in combing are assessed by hairdresser.This
Outside, the hairdresser assesses the structure of wet topknot.For these three assessments, using from indicating bad 1 to indicating very
10 good scoring range
Finally, inquiring how they describe using the hair after hair-washing composition to hairdresser.They have following old
Selection between stating: feeling hair coarse, feels that hair is astringent, feels that hair is submissive, feels hair smooth texture and feels head
Hair has coating.What hairdresser can agree to according to them is set fourth as every kind of hair-washing composition distribution points.
All results are presented in the following table:
| Salon's test | Ex.1 | Ex.2 |
| Foam volume is high | 0 | 2 |
| Foam volume is average | 6 | 4 |
| Foam volume is low | 0 | 0 |
| ------------- | ||
| The ratio of air pocket | 9.17% | 14.17% |
| The ratio of middle bubble | 34.17% | 41.67% |
| The ratio of minute bubbles | 56.66% | 44.16% |
| ------------- | ||
| Flexibility (when combing one's hair) | 4.83 | 7.5 |
| Cardability | 4.0 | 7.33 |
| The hair structure of wet topknot | 4.17 | 5.83 |
| ------------- | ||
| Feel hair coarse | 3 | 0 |
| Feel that hair is astringent | 3 | 0 |
| Feel that hair is submissive | 0 | 3 |
| Feel hair smooth texture | 0 | 0 |
| Feel that hair has coating | 0 | 3 |
It is being presented in table in analysis as a result, discovery hair-washing composition of the invention forms larger amount of foam, and in addition,
The bubble size distribution of the foam is migrated to larger bubble.Even more outstanding is hair-washing composition of the invention in hair
Performance in terms of flexibility and cardability.For two kinds of parameters, discovery significant improvement.It moreover has been found that the structure of topknot
Improve.After the statement of hairdresser, it can be noted that after using hair-washing composition of the invention, the coating of hair is obtained,
Therefore feel that hair is submissive.Therefore, improved deposition is obtained.
Claims (38)
1. a kind of no silicone hair-washing composition, it includes:
A) at least one PPG- alkyl ether defined by formula (I)
Wherein i is 1 to 12 integer, and j is 2 to 40 integer；
B) at least one cationic conditioning polymer, is selected from:
(1) cation guar gum；
(2) cationic cellulose；
(3) homopolymer and copolymer comprising at least one polymeric chain component part defined by following formula (II)s-(V):
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, preferably 2 or 3 carbon atoms, or contains 1 to 4 carbon original
The hydroxy alkyl of son；
A indicates halogen ion or the anion from inorganic acid or organic acid；
(4) copolymer is by the monomer mixture shape comprising methylvinyl imidazolium chloride and vinyl pyrrolidone
At quaternary ammonium salt；
(5) include homopolymer and copolymer of the annular unit as defined in formula (VI) or (VII) as polymeric chain component part:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxy alkyl containing 1 to 5 carbon atom are indicated independently of one another；And
And
B is anion；And
C) at least one anion, both sexes and/or nonionic surfactant.
2. hair-washing composition according to claim 1, which is characterized in that described with the total weight of the composition
The total concentration of PPG- alkyl ether is 0.05 weight % to 5 weight %.
3. hair-washing composition according to claim 2, which is characterized in that described with the total weight of the composition
The total concentration of PPG- alkyl ether is 0.1 weight % to 4 weight %.
4. hair-washing composition according to claim 3, which is characterized in that described with the total weight of the composition
The total concentration of PPG- alkyl ether is 0.15 weight % to 3 weight %.
5. hair-washing composition according to any one of claims 1 to 4, which is characterized in that the PPG- alkyl ether is 4 by i
The integer that integer and j to 8 are 2 to 15 defines.
6. hair-washing composition according to claim 5, which is characterized in that the PPG- alkyl ether is PPG-14 butyl ether.
7. hair-washing composition according to any one of claims 1 to 6, which is characterized in that with the total weight of the composition
Meter, the total concentration of the cationic conditioning polymer are 0.001 weight % to 10 weight %.
8. hair-washing composition according to claim 7, which is characterized in that with the total weight of the composition, the sun
The total concentration of ion conditioning polymer is 0.1 weight % to 5 weight %.
9. hair-washing composition according to claim 8, which is characterized in that with the total weight of the composition, the sun
The total concentration of ion conditioning polymer is 0.2 weight % to 2 weight %.
10. hair-washing composition according to any one of claims 1 to 9, which is characterized in that the composition contains at least one
Kind cation guar gum.
11. hair-washing composition according to claim 10, which is characterized in that the cation guar gum is guar gum hydroxyl
Hydroxypropyltrimonium chloride.
12. hair-washing composition according to claim 11, which is characterized in that described with the total weight of the composition
The concentration of guar gum trimethyl ammonium chloride is 0.05 weight % to 0.2 weight %.
13. hair-washing composition according to claim 12, which is characterized in that in addition to the guar gum hydroxypropyl trimethyl
Except ammonium chloride, also containing at least one cationic conditioning polymer selected from the following in the composition: polyquaternium -4 gathers
Quaternary ammonium salt -6, Polyquaternium-10, polyquaternium -47 and Polyquaternium-67.
14. the hair-washing composition according to any of claims 1 to 10, which is characterized in that the composition contains at least
A kind of cationic cellulose.
15. according to claim 1 to 10 and 14 described in any item hair-washing compositions, which is characterized in that the composition contains
At least one homopolymer or copolymer, the homopolymer or copolymer include at least one polymeric chain defined by formula (II)-(V)
Component part:
Wherein
R1Indicate hydrogen atom or CH3Group；
R2、R3And R4It is identical or different, indicate alkyl or benzyl containing 1 to 18 carbon atom；
R5And R6Hydrogen atom or the alkyl containing 1 to 6 carbon atom are indicated independently of one another；
Z indicates the linear or branched alkyl group containing 1 to 6 carbon atom, or the hydroxy alkyl containing 1 to 4 carbon atom；
A indicates halogen ion or the anion from inorganic acid or organic acid；
16. according to claim 1 to 10 and 14 to 15 described in any item hair-washing compositions, which is characterized in that the composition
Containing at least one copolymer, the copolymer is by comprising methylvinyl imidazolium chloride and vinyl pyrrolidone
The quaternary ammonium salt that monomer mixture is formed.
17. according to claim 1 to 10 and 14 to 16 described in any item hair-washing compositions, which is characterized in that the composition
Containing at least one homopolymer and/or copolymer, the homopolymer and/or copolymer include to be defined by formula (VI) or (VII)
Annular unit as polymeric chain component part:
Wherein
K is 0 or 1；
L is 0 or 1；
On condition that the sum of k and l are always equal to 1；
R7Indicate hydrogen atom or methyl；
R8And R9The alkyl containing 1 to 22 carbon atom or the hydroxy alkyl containing 1 to 5 carbon atom are indicated independently of one another；And
And
B is anion.
18. according to claim 1 to 17 described in any item hair-washing compositions, which is characterized in that the cationic conditioning polymerization
Object is selected from: polyquaternium -4, polyquaternium -6, Polyquaternium-10, polyquaternium -47, Polyquaternium-67, hydroxypropyl Guar
Glue trimethyl ammonium chloride and/or guar gum trimethyl ammonium chloride.
19. according to claim 1 to 18 described in any item hair-washing compositions, which is characterized in that with the gross weight of the composition
Meter, the total concentration of the anion, both sexes and/or nonionic surfactant are 4 weight % to 40 weight %.
20. hair-washing composition according to claim 19, which is characterized in that described with the total weight of the composition
The concentration of anionic surfactant is 5 weight % to 30 weight %.
21. hair-washing composition according to claim 20, which is characterized in that described with the total weight of the composition
The concentration of anionic surfactant is 10 weight % to 20 weight %.
22. according to claim 1 to 21 described in any item hair-washing compositions, which is characterized in that the anion surface active
Agent is selected from:
A) formula R10-(OCH2-CH2)m-OSO3 -C+Alkylsurfuric acid compound and/or alkyl polyglycol ether hydrosulphate, wherein R10
Indicate that the linear chain or branched chain containing 8 to 24 carbon atoms, saturation or unsaturated alkyl, m indicate that 0 to 12 integer, C indicate alkali gold
Category, alkaline-earth metal, ammonium or alkanolamine ion；With
B) sulfonate of the unsaturated fatty acid containing 8 to 24 carbon atoms and comprising 1 to 6 double bond.
23. according to claim 1 to 22 described in any item hair-washing compositions, which is characterized in that with the gross weight of the composition
Meter, the concentration of the amphoteric surfactant are 0.5 weight % to 15 weight %.
24. hair-washing composition according to claim 23, which is characterized in that described with the total weight of the composition
The concentration of amphoteric surfactant is 1 weight % to 5 weight %.
25. hair-washing composition according to claim 24, which is characterized in that described with the total weight of the composition
The concentration of amphoteric surfactant is 1.5 weight % to 4 weight %.
26. according to claim 1 to 25 described in any item hair-washing compositions, which is characterized in that amphoteric surfactant is selected from:
Lauryl amine oxide, cocoyl dimethyl sulfopropyl betaine, lauryl betaine, Cocoamidopropyl betaine and/or coconut palm
Oleoyl both sexes sodium acetate.
27. according to claim 1 to 26 described in any item hair-washing compositions, which is characterized in that with the gross weight of the composition
Meter, the concentration of the nonionic surfactant are 0.3 weight % to 15 weight %.
28. hair-washing composition according to claim 27, which is characterized in that described with the total weight of the composition
The concentration of nonionic surfactant is 0.5 weight % to 10 weight %.
29. hair-washing composition according to claim 28, which is characterized in that described with the total weight of the composition
The concentration of nonionic surfactant is 1 weight % to 8 weight %.
30. according to claim 1 to 29 described in any item hair-washing compositions, which is characterized in that the non-ionic surface active
Agent is selected from fatty acid alkanol amides and/or alkyl glycosides.
31. according to claim 1 to 30 described in any item hair-washing compositions, which is characterized in that the composition also contain with
The total weight total concentration of the composition is the fatty alcohol comprising 8 to 22 carbon atoms of 0.01 weight % to 5 weight %.
32. according to claim 1 to 31 described in any item hair-washing compositions, which is characterized in that the composition also contain to
A kind of few water-soluble nonionic cellulosic polymer.
33. according to claim 1 to 32 described in any item hair-washing compositions, which is characterized in that the composition also contains one
Kind or a variety of rheology modifiers, the rheology modifier are selected from: polyacrylic acid, the cross-linked polymeric of acrylic or methacrylic acid
The copolymer of object, acrylic or methacrylic acid and hydrophobic monomer, copolymer and propylene containing carboxylic acid monomer and acrylate
The cross-linked copolymer of acid and acrylate, on condition that these polymer are free of cation group.
34. according to claim 1 to 33 described in any item hair-washing compositions, which is characterized in that the composition also include to
A few vegetable oil and/or fruit oil.
35. the purposes that the described in any item compositions of claims 1 to 34 are used to clean hair and scalp.
36. the described in any item compositions of claims 1 to 34 are used for the use being deposited on cationic conditioning polymer on hair
On the way.
37. the method for preparing the described in any item compositions of claims 1 to 34, wherein each component is merged
And it stirs.
38. a kind of method for cleaning human hair, the method includes applying the described in any item compositions of claims 1 to 34
For wet hair, and the composition is washed off from hair with water in 5 seconds to 2 minutes time after application.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2017/074528 WO2018152718A1 (en) | 2017-02-23 | 2017-02-23 | Silicone-free shampoo composition |
| CNPCT/CN2017/074528 | 2017-02-23 | ||
| PCT/EP2018/052984 WO2018153658A1 (en) | 2017-02-23 | 2018-02-07 | Silicone-free shampoo composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110520197A true CN110520197A (en) | 2019-11-29 |
Family
ID=61258189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201880013659.7A Pending CN110520197A (en) | 2017-02-23 | 2018-02-07 | silicone-free shampoo composition |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP3585487A1 (en) |
| CN (1) | CN110520197A (en) |
| WO (2) | WO2018152718A1 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102018217401A1 (en) * | 2018-10-11 | 2020-04-16 | Henkel Ag & Co. Kgaa | Cosmetic agent for the temporary deformation of keratin fibers with polymer combination II |
| DE102018222037A1 (en) * | 2018-12-18 | 2020-06-18 | Henkel Ag & Co. Kgaa | Composition and method for temporarily deforming keratin fibers |
| CN109864933A (en) * | 2019-04-20 | 2019-06-11 | 福建省梦娇兰日用化学品有限公司 | A kind of hair of children cleaning compositions of not silicate-containing oil and preparation method thereof |
| CN115569101B (en) * | 2022-10-26 | 2023-08-11 | 广东珍宝健康日用品科技有限公司 | Multifunctional shampoo |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005511649A (en) * | 2001-11-30 | 2005-04-28 | ザ プロクター アンド ギャンブル カンパニー | Shampoo containing alkyl ether |
| JP4856910B2 (en) * | 2005-08-08 | 2012-01-18 | 花王株式会社 | Aqueous hair cleanser |
| WO2007077668A1 (en) * | 2005-12-28 | 2007-07-12 | Kao Corporation | Skin or hair washing composition |
| JP5048947B2 (en) * | 2005-12-28 | 2012-10-17 | 花王株式会社 | Aqueous cleaning composition |
| DE102006011884A1 (en) * | 2006-03-13 | 2007-09-20 | Beiersdorf Ag | Silicone-free hair cleansing emulsion |
| JP5041894B2 (en) * | 2006-07-04 | 2012-10-03 | 花王株式会社 | Cleaning composition |
| JP4886505B2 (en) * | 2006-12-28 | 2012-02-29 | 花王株式会社 | Composition for cleaning agent |
| DE102008030131A1 (en) * | 2008-06-27 | 2009-12-31 | Beiersdorf Ag | Silicone-free conditioners for keratin fibers |
| JP5341029B2 (en) * | 2010-06-18 | 2013-11-13 | 花王株式会社 | Aqueous hair cleanser |
| MX352358B (en) | 2012-11-16 | 2017-11-22 | Colgate Palmolive Co | Cleansing composition with an alkoxylated alkyl ether. |
| CN104207966A (en) * | 2013-05-29 | 2014-12-17 | 拜尔斯道夫股份有限公司 | High-conditioning shampoo composition |
| CN105997567B (en) * | 2016-06-22 | 2019-03-05 | 广州好迪集团有限公司 | A kind of light shampoo of no silicone oil conditioning |
| CN106420407A (en) * | 2016-08-31 | 2017-02-22 | 福建省梦娇兰日用化学品有限公司 | Child silicone-oil-free shampoo with vegetable oil and fat replacing silicone oil |
-
2017
- 2017-02-23 WO PCT/CN2017/074528 patent/WO2018152718A1/en active Application Filing
-
2018
- 2018-02-07 CN CN201880013659.7A patent/CN110520197A/en active Pending
- 2018-02-07 EP EP18706660.0A patent/EP3585487A1/en active Pending
- 2018-02-07 WO PCT/EP2018/052984 patent/WO2018153658A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP3585487A1 (en) | 2020-01-01 |
| WO2018153658A1 (en) | 2018-08-30 |
| WO2018152718A1 (en) | 2018-08-30 |
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