CN110511420A - A kind of manufacturing method of denim float stone - Google Patents

A kind of manufacturing method of denim float stone Download PDF

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Publication number
CN110511420A
CN110511420A CN201910922878.3A CN201910922878A CN110511420A CN 110511420 A CN110511420 A CN 110511420A CN 201910922878 A CN201910922878 A CN 201910922878A CN 110511420 A CN110511420 A CN 110511420A
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China
Prior art keywords
float stone
denim
manufacturing
preparation
taken
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Withdrawn
Application number
CN201910922878.3A
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Chinese (zh)
Inventor
虞波
余春珠
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University of Shaoxing
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University of Shaoxing
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Priority to CN201910922878.3A priority Critical patent/CN110511420A/en
Publication of CN110511420A publication Critical patent/CN110511420A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0066Use of inorganic compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102Azo-compounds
    • C08J9/103Azodicarbonamide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/04N2 releasing, ex azodicarbonamide or nitroso compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2311/00Characterised by the use of homopolymers or copolymers of chloroprene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2425/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2425/02Homopolymers or copolymers of hydrocarbons
    • C08J2425/04Homopolymers or copolymers of styrene
    • C08J2425/14Homopolymers or copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2463/00Characterised by the use of epoxy resins; Derivatives of epoxy resins

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

A kind of manufacturing method of denim float stone includes the following steps, (1) takes 2g silica gel bead and 12g neoprene adhesive, stirs evenly after mixing;(2) 10g epoxy adhesive or styrene-acrylic emulsion or pure-acrylic emulsion are taken, is added in the mixture of step (1) preparation, stirs evenly;(3) 0.5g plastics blowing agent is taken, is added in the mixture of step (2) preparation, stirs evenly;(4) it stands 2h and is fabricated to natural pumice shape after object to be mixed becomes soft elastomer;(5) after standing 0.5h, the preparation of denim float stone is completed, and the present invention provides the manufacturing methods that one kind can prepare the denim float stone of the float stone to reduce environmental pollution.

Description

A kind of manufacturing method of denim float stone
Technical field
The present invention relates to float stone technical field, specially a kind of manufacturing method of denim float stone.
Background technique
Denim is a kind of color through the thick count and high-density cotton fabric of white latitude, and for the dress ornament being thus processed into because comfortable and easy to wear, feel is rich It is rich, thick and solid, it fades uniformly, the unique style such as good and cheap and the fashionable whole world.Denim is the core of jeans final finishing The heart is directly related to the appearance, quality and value of clothes.The purpose of jeans washing is mainly to obtain soft feel, fresh Bright contrast, personalized appearance guarantee that clothes exist by washing the requirement that denim can also be made to reach washing shrinkage Dimensional stability in sale and wearing process.
Float stone can be added in jeans washing and carry out granite-wash, though it is new as usual, clean such as new spy that clothing can be made to obtain Special effect fruit.Granite-wash is the float stone using a certain size, and is carried out with the low water level that clothing is impregnated with completely, make float stone preferably with clothing Object contact friction, generate fade, fluffing, it is soft, imitate it is old and other effects.
Natural pumice is a kind of porous foam glass matter acidity volcano effusive rock, alkaline-resisting, acidproof, corrosion-resistant, can be floated on On the water surface.Float stone, since friction causes to be crushed, makes to contain a large amount of rubble in the textiles such as clothes after washing in water-washing process Mud, need to repeatedly be rinsed could remove, and the precipitation tank after washing needs continually to clear up.These situations make jean Dress washing process is complicated, and the consumption of float stone and water resource is big, while the slime water discharged is also to the water process in later period and environment Cause very big pressure.
Based on the above issues, this case is given birth to therefrom.
Summary of the invention
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides the denims that one kind can prepare the float stone to reduce environmental pollution The manufacturing method of float stone, solves the problems mentioned above in the background art.
(2) technical solution
In order to achieve the above object, the present invention is achieved by the following technical programs: a kind of manufacture of denim float stone Method includes the following steps,
(1) 2g silica gel bead and 12g neoprene adhesive are taken, is stirred evenly after mixing;
(2) 10g epoxy adhesive or styrene-acrylic emulsion or pure-acrylic emulsion are taken, is added in the mixture of step (1) preparation, stirring Uniformly;
(3) 0.5g plastics blowing agent is taken, is added in the mixture of step (2) preparation, stirs evenly;
(4) it stands 2h and is fabricated to natural pumice shape after object to be mixed becomes soft elastomer;
(5) after standing 0.5h, the preparation of denim float stone is completed.
Preferably, the silica gel bead is made of inorganic silica gel material.
Preferably, the neoprene adhesive is liquid non-solvent type neoprene adhesive.
Preferably, the epoxy adhesive is the weight that polyurethane prepolymer modified epoxy and curing agent press 2:1 Ratio is configured to.
Preferably, the plastics blowing agent AC foaming agent.
(3) beneficial effect
The present invention provides a kind of manufacturing method of denim float stone, have it is following the utility model has the advantages that
1, float stone effect prepared by the present invention and natural pumice are suitable, and solve natural pumice in jeans washing process The problem of consumption is big, and the slime water of discharge also causes very big pressure to the water process in later period and environment.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention.
A kind of manufacturing method of denim float stone, includes the following steps, (1) takes 2g silica gel bead and 12g neoprene Adhesive stirs evenly after mixing;(2) 10g epoxy adhesive or styrene-acrylic emulsion or pure-acrylic emulsion are taken, step (1) preparation is added Mixture in, stir evenly;(3) 0.5g plastics blowing agent is taken, is added in the mixture of step (2) preparation, stirs evenly; (4) it stands 2h and is fabricated to natural pumice shape after object to be mixed becomes soft elastomer;(5) after standing 0.5h, Niu Zaishui Float stone preparation is washed to complete.
Principle: washing step is to be placed in the float stone for being impregnated with chemical agent in rotating cylinder together with cowboy clothing trousers, and float stone is straight It connects and contacts, polishes with cowboy clothing trousers, utilize the chemistry of chemical agent and cowboy in the physical shock and float stone of float stone and cowboy Oxidation, makes clothing cloth reach colour fading, fluffing, softness, imitate old processing purpose, and natural pumice quality is light, and intensity is low, wear-resisting Property poor, quick abrasion a large amount of sandstone residual is had in clothes and rinse water after washing process, increase rinsing times and water money There is certain elasticity can reduce loss of the physical shock to float stone by the waste in source, permutite of the invention;Used material Material is inorganic silica gel good corrosion resistance, reduces loss of the washing chemical agent to float stone;Its density and natural pumice quite can generations For natural pumice;Wherein styrene-acrylic emulsion or pure-acrylic emulsion also have certain modification to product outside its main adhesive effect, It may make that product is more flexible, not easily broken blocking when rinsing, durability increases, and in sulfuric acid and acid bubble processing following table Face has certain hole and roughness, energy sorption chemical medicament, and clothing of polishing plays physical shock identical with natural pumice It acts on chemical oxidation, and is remained after chemically reacting without sandstone, reduce the waste of rinsing times and water resource.
Silica gel bead described in the present embodiment is made of inorganic silica gel material, specifically uses sodium metasilicate and sulfuric acid reaction, and It is made through a series of last handling processes such as aging, acid bubbles.
Neoprene adhesive described in the present embodiment is liquid non-solvent type neoprene adhesive.
Epoxy adhesive described in the present embodiment is the weight that polyurethane prepolymer modified epoxy and curing agent press 2:1 Ratio is configured to.
Plastics blowing agent AC foaming agent described in the present embodiment.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (5)

1. a kind of manufacturing method of denim float stone, it is characterised in that: include the following steps,
(1) 2g silica gel bead and 12g neoprene adhesive are taken, is stirred evenly after mixing;
(2) 10g epoxy adhesive or styrene-acrylic emulsion or pure-acrylic emulsion are taken, is added in the mixture of step (1) preparation, stirring is equal It is even;
(3) 0.5g plastics blowing agent is taken, is added in the mixture of step (2) preparation, stirs evenly;
(4) it stands 2h and is fabricated to natural pumice shape after object to be mixed becomes soft elastomer;
(5) after standing 0.5h, the preparation of denim float stone is completed.
2. a kind of manufacturing method of denim float stone according to claim 1, it is characterised in that: the silica gel bead by Inorganic silica gel material is made.
3. a kind of manufacturing method of denim float stone according to claim 1, it is characterised in that: the neoprene glue Stick is liquid non-solvent type neoprene adhesive.
4. a kind of manufacturing method of denim float stone according to claim 1, it is characterised in that: the Wear Characteristics of Epoxy Adhesive Agent is that polyurethane prepolymer modified epoxy and curing agent are configured to by the weight ratio of 2:1.
5. a kind of manufacturing method of denim float stone according to claim 1, it is characterised in that: described is plastic foamed Agent AC foaming agent.
CN201910922878.3A 2019-09-27 2019-09-27 A kind of manufacturing method of denim float stone Withdrawn CN110511420A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910922878.3A CN110511420A (en) 2019-09-27 2019-09-27 A kind of manufacturing method of denim float stone

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910922878.3A CN110511420A (en) 2019-09-27 2019-09-27 A kind of manufacturing method of denim float stone

Publications (1)

Publication Number Publication Date
CN110511420A true CN110511420A (en) 2019-11-29

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CN201910922878.3A Withdrawn CN110511420A (en) 2019-09-27 2019-09-27 A kind of manufacturing method of denim float stone

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111620598A (en) * 2020-06-17 2020-09-04 中山市诚力通通信科技有限公司 Artificial stone material and artificial stone processing technology
CN112092408A (en) * 2020-09-04 2020-12-18 中山市诚力通通信科技有限公司 Artificial stone processing technology
CN113698227A (en) * 2021-09-07 2021-11-26 中山市诚力通通信科技有限公司 Water washing stone and processing method for water washing stone

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111620598A (en) * 2020-06-17 2020-09-04 中山市诚力通通信科技有限公司 Artificial stone material and artificial stone processing technology
CN112092408A (en) * 2020-09-04 2020-12-18 中山市诚力通通信科技有限公司 Artificial stone processing technology
CN113698227A (en) * 2021-09-07 2021-11-26 中山市诚力通通信科技有限公司 Water washing stone and processing method for water washing stone

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Application publication date: 20191129

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