CN114717863B - Fabric, washing method thereof and worn leisure ready-made garment - Google Patents

Fabric, washing method thereof and worn leisure ready-made garment Download PDF

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Publication number
CN114717863B
CN114717863B CN202210543799.3A CN202210543799A CN114717863B CN 114717863 B CN114717863 B CN 114717863B CN 202210543799 A CN202210543799 A CN 202210543799A CN 114717863 B CN114717863 B CN 114717863B
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Prior art keywords
fabric
washing
solution
additive
auxiliary materials
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CN114717863A (en
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陈泓伍
易燕玲
张永超
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Guangdong Esquel Textiles Co Ltd
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Guangdong Esquel Textiles Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5221Polymers of unsaturated hydrocarbons, e.g. polystyrene polyalkylene
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525Polymers of unsaturated carboxylic acids or functional derivatives thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Detergent Compositions (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

The invention relates to a fabric washing method, which comprises the following steps: adsorbing the coloring solution by using washing water auxiliary materials; dry-frying and fixing the fabric to be treated by using the washing auxiliary materials adsorbed with the additive color solution; the washing auxiliary material comprises granular vinyl acetate-ethylene copolymer, the raw material of the additive solution comprises white thermosetting resin, the mass concentration of the white thermosetting resin in the additive solution is 10 g/L-600 g/L, and the ratio of the volume of the additive solution to the weight of the washing auxiliary material is (0.05-0.3) L/1 kg. The fabric washing method uses the washing auxiliary material as a carrier to firstly adsorb the coloring solution, and then uses the washing auxiliary material to dry-fry and fix the fabric to be treated, so that the white thermosetting resin is transferred to the surface of the fabric, thereby the fabric has the effect of overall whitening, is suitable for washing processes of various fabric fabrics, has little strong damage to the fabric, and has environmental protection and no pollution.

Description

Fabric, washing method thereof and worn leisure ready-made garment
Technical Field
The invention relates to the technical field of textile, in particular to a fabric, a washing method thereof and a worn leisure ready-made garment.
Background
With the global increase in the economic level of the world today, the demands of people for clothing, textiles, etc. are increasingly tending to be personalized and diversified. The significance of the clothing to people is also increasing, the clothing is no longer one way for our masks, and is one of important expression ways for modern people to pursue individuality and display themselves in trend. The worn leisure is a large class of personalized clothing, mainly products for fading the color of colored clothing, comprising the types of effects such as integral blushing, bone blushing and the like, wherein the integral blushing effect comprises integral uniform blushing, integral non-uniform blushing and the like.
The washing water of the old leisure ready-made clothes is mostly processed by adopting a processing principle of a fading mode, and particularly, the method mainly utilizes the stripping function of a strong oxidant or the friction and fading function of sand and stone to fade the colored ready-made clothes. Common fading washing water modes mainly comprise alkaline washing, acid washing, ozone stripping and the like. The alkaline washing, namely the alkaline water bath method garment fading washing process, needs a large amount of stripping agent and water in the fading washing process, has limitation under the current increasingly strict environmental protection production requirements, and is easy to generate the problems of staining, bone abrasion and the like for complex patterns such as cloth bumping, special auxiliary materials and the like. The acid washing is another traditional color stripping ready-made clothes washing process, and the process mainly comprises the steps of mixing a potassium permanganate solution with a certain concentration, sandy soil, stones and ready-made clothes in a machine for rolling friction, so that a large-area whitening effect is shown on the surface of the ready-made clothes. Compared with the alkaline stripping fading washing process, the washing process has the advantages of less water consumption, high stripping degree, more obvious blushing and residual old appearance, and better blushing effect especially on thick and heavy parts such as the bone position of the ready-made clothes. However, pickling has problems, such as that the diatomite carrier is a disposable consumable product, a large amount of solid waste is generated, and a large amount of dust is generated during production, which has adverse effects on workshop production environment and worker health. In addition, acid washing places a significant limitation on the dye and color, and does not produce a whitish wash appearance on any color and dye product. Ozone stripping is a non-aqueous environment-friendly fading washing technology, and the concentration and the treatment time of ozone gas can be adjusted to show different degrees of fading effects, but the stripping technology is non-selective stripping due to the gas circulation of ozone, so that the whole fading can be generally realized, and the personalized fading effect is difficult to realize.
In addition, the coating dyeing method of the ready-made clothes is another main mode for producing the residual leisure ready-made clothes in recent years, and the method mainly utilizes the characteristics of poor color fastness effect and easy elution and blushing of the coating dyeing so as to realize the technical effects of overall blushing and obvious bone position effect of the coating dyeing and blushing of the old clothes. However, the dyeing rate of the fading mode is low, and the color fastness is poor, so that a large amount of paint is required to be used in the paint dyeing process, the water pollution is large, and the production site is difficult to clean.
Thus, the conventional washing process of the worn casual garment has a certain technical limitation, and needs to be further improved.
Disclosure of Invention
Based on the above, the invention provides a novel fabric washing method which can enable the fabric to have an overall whitening effect and overcome the technical limitation of the traditional washing technology.
Further, the invention also provides a fabric and a residual casual garment produced by the fabric washing method.
The invention provides a fabric washing method, which comprises the following steps:
adsorbing the coloring solution by using washing water auxiliary materials;
dry-frying and fixing the fabric to be treated by using the washing auxiliary materials adsorbed with the additive color solution;
the washing auxiliary material comprises granular vinyl acetate-ethylene copolymer, the raw material of the additive solution comprises white thermosetting resin, the mass concentration of the white thermosetting resin in the additive solution is 10 g/L-600 g/L, and the ratio of the volume of the additive solution to the weight of the washing auxiliary material is (0.05-0.3) L/1 kg.
In one embodiment, the white thermosetting resin comprises an acrylic resin.
In one embodiment, the mass concentration of the white thermosetting resin in the additive solution is 100g/L to 500g/L; and/or
The ratio of the volume of the coloring solution to the weight of the washing auxiliary materials is (0.1-0.3) L to 1kg.
In one embodiment, the particle size of the washing auxiliary material is 0.2 cm-3 cm; and/or
The weight ratio of the washing auxiliary materials to the fabric to be treated is 1 (0.2-5).
In one embodiment, the raw materials of the additive color solution further comprise a catalyst, and the mass concentration of the catalyst in the additive color solution is 10 g/L-50 g/L.
In one embodiment, the catalyst comprises an aziridine crosslinking agent; and/or
The solvent of the additive color solution is water.
In one embodiment, the step of adsorbing the additive color solution using the wash water adjuvant comprises:
dividing the coloring solution into at least 3 batches, and sequentially mixing with the washing water auxiliary materials.
In one embodiment, the conditions of the dry-frying include: the rotating speed is 20 rpm-30 rpm, the time is 5 minutes-30 minutes, and the intermittent bidirectional rotation is performed; and/or
The conditions for fixation include: the drying temperature is 90-110 ℃ and the drying time is 50-70 minutes.
The invention also provides a fabric which has an overall whitening effect and is obtained by washing water by the fabric washing method according to any embodiment.
The invention also provides a piece of residual casual clothing which is processed by the fabric.
The fabric washing method uses washing auxiliary materials as carriers to firstly adsorb the coloring solution, and then carries out dry frying and color fixation treatment on the fabric to be treated, so that the white thermosetting resin is transferred to the surface of the fabric, thereby the fabric has the whole whitening effect.
Drawings
FIG. 1 is a photograph of a fabric obtained using the wash water process of example 1;
FIG. 2 is a photograph of a fabric obtained using the wash water process of example 2;
FIG. 3 is a photograph of a fabric obtained using the wash water process of example 3;
FIG. 4 is a photograph of fabric obtained using the wash water process of comparative example 1;
FIG. 5 is a photograph of the fabric obtained using the wash water process of comparative example 2.
Detailed Description
In order that the invention may be readily understood, a more complete description of the invention will be rendered by reference to the appended drawings. Preferred embodiments of the present invention are shown in the drawings. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used herein in the description of the invention is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. The term "and/or" as used herein includes any and all combinations of one or more of the associated listed items.
In the invention, the technical characteristics described in an open mode comprise a closed technical scheme composed of the listed characteristics and also comprise an open technical scheme comprising the listed characteristics.
An embodiment of the present invention provides a fabric. Further, the washing method of the fabric includes the following steps S110 and S120.
Step S110: and (5) absorbing the coloring solution by using a washing auxiliary material.
Wherein the washing auxiliary material comprises granular vinyl acetate-ethylene copolymer. The vinyl acetate-ethylene copolymer has larger specific surface area, better adsorption performance on the coloring solution, irregular appearance of the granular vinyl acetate-ethylene copolymer, and certain bouncing property, and when the granular vinyl acetate-ethylene copolymer is mixed with the fabric to be treated and is used for washing water in a washing machine, the vinyl acetate-ethylene copolymer serving as the washing water auxiliary material moves more freely in the washing machine and can be in 'punctiform' contact with the contact surface of the fabric to be treated, so that natural punctiform appearance patterns are formed on the surface of the fabric, and the natural punctiform appearance patterns enable the fabric to show the overall whitening effect. It is understood that the overall blushing effect referred to in the present embodiment includes an overall uniform blushing effect and an overall non-uniform blushing effect.
Further, the particle size of the washing auxiliary material is preferably 0.2 cm-3 cm. If the washing auxiliary material particles are too fine, washing auxiliary material remained in the washing machine after the washing process is finished is difficult to clean, and if the washing auxiliary material particles are too large, the washing effect is very uneven, and the overall whitening effect of the fabric is affected.
In this embodiment, an additive color is used to make the fabric have an overall whitening effect, and specifically, an additive color solution is used.
In a specific example, the raw materials of the additive color solution comprise white thermosetting resin, the white thermosetting resin is prepared into a solution to be absorbed by washing auxiliary materials, the white resin is transferred to the surface of the fabric along with the contact of the washing auxiliary materials and the fabric during washing, and the fabric is subjected to high-temperature fixation, so that the fabric has the overall whitening effect. Specifically, the white thermosetting resin includes an acrylic resin.
Further, the raw materials of the additive color solution can also comprise a catalyst, so that the white thermosetting resin can better react with the fabric under the action of the catalyst, the additive color fixation effect is firmer, and further, the improvement of color fastness is facilitated. In particular, the catalyst comprises an aziridine crosslinking agent.
It will be appreciated that the additive solution also includes a solvent. Specifically, the solvent of the additive color solution may be water which is commonly used, and further, soft water is preferable.
It will be appreciated that the additive solution needs to be formulated prior to use, and that a specific formulation method comprises the steps of:
the white thermosetting resin is mixed with the catalyst and the solvent.
It will be appreciated that the additive solution formed after mixing may also be filtered.
In a specific example, the mass concentration of the white thermosetting resin in the additive color solution is 10g/L to 600g/L. The mass concentration control of the white thermosetting resin can ensure that the fabric has a proper color adding effect, if the concentration is too low, the fabric cannot have an overall blushing effect, and if the concentration is too high, excessive color adding is easy to cause the fabric to be excessively white, and the fabric is hard and dry to feel and is difficult to soften. It is understood that the mass concentration of the white thermosetting resin in the additive color solution may be, for example, 10g/L, 30g/L, 50g/L, 90g/L, 100g/L, 120g/L, 140g/L, 180g/L, 200g/L, 210g/L, 250g/L, 280g/L, 300g/L, 320g/L, 3500g/L, 370g/L, 4000g/L, 410g/L, 450g/L, 480g/L, 500g/L, 550g/L, 600g/L, etc., without being limited thereto. Specifically, the mass concentration of the white thermosetting resin in the additive color solution is 100 g/L-500 g/L.
In a specific example, the mass concentration of the catalyst in the additive color solution is 10g/L to 50g/L. It will be appreciated that the mass concentration of the catalyst in the additive solution may be, for example, 10g/L, 20g/L, 30g/L, 40g/L, 50g/L, etc. Specifically, the mass concentration of the catalyst in the additive color solution is 40 g/L-50 g/L.
It will be appreciated that the ratio of the additive color solution to the wash water adjuvant in the blend formed in step S110 is also an important factor affecting the whitening effect of the fabric. In a specific example, the ratio of the volume of the additive color solution to the weight of the wash water adjunct is (0.05-0.3) L:1kg. In the range, the fabric can be ensured to have a good overall whitening effect, the excessive volume ratio of the coloring solution can cause the excessive liquid carrying rate of the washing auxiliary materials, the coloring solution can not be uniformly absorbed by the washing auxiliary materials, excessive heating solution can form obvious material drops on the surface of the washing auxiliary materials and the inner tank wall of the machine, and obvious water stain-like whitening defects can be formed on the surface of the fabric when the subsequent dry frying treatment is carried out; too low a volume ratio of heated solution may result in poor blushing. It will be appreciated that the ratio of the volume of additive colour solution to the weight of wash water adjunct may be, for example, 0.05L:1kg, 0.08L:1kg, 0.09L:1kg, 0.1L:1kg, 0.13L:1kg, 0.15L:1kg, 0.17L:1kg, 0.2L:1kg, 0.22L:1kg, 0.25L:1kg, 0.3L:1kg etc. Specifically, the ratio of the volume of the additive color solution to the weight of the washing auxiliary materials is (0.1-0.3) L to 1kg.
In a specific example, the step of adsorbing the additive color solution using the wash water adjuvant includes:
dividing the additive color solution into at least 3 batches, and sequentially mixing with the washing water auxiliary materials.
It can be appreciated that the additive color solution is divided into a plurality of batches of washing auxiliary materials for mixing, so that the adsorption effect of the washing auxiliary materials is more uniform, and more additive color solution can be adsorbed by the washing auxiliary materials as much as possible. Specifically, after the washing auxiliary material adsorbs the coloring solution, the liquid carrying rate of the washing auxiliary material in the saturated state is about 30%.
For example, in one example, the step of batch mixing may be: spraying 1/3 of the additive color solution onto the washing water auxiliary materials, and uniformly mixing; then spraying 1/2 of the rest color adding solution onto the washing water auxiliary materials, and uniformly mixing; and finally, spraying the rest coloring solution on the washing auxiliary materials, and uniformly mixing to finish the mixing. It will be appreciated that batch mixing may also be performed in other ways, not limited thereto.
It will be appreciated that step S110 described above is typically performed in a washer. Furthermore, a modified water washer is adopted, the inner container of the traditional water washer or roller dryer is usually provided with a plurality of drain holes for facilitating drainage, the drain holes can lead to loss of washing water auxiliary materials and coloring solution, and therefore, the drain holes of the inner container of the water washer can be sealed by plates such as a rubber plate or a steel plate. It will be appreciated that this step is not limited to being performed in a washer, but may be performed in other machines capable of performing the above steps.
It will be appreciated that step S110 may be performed in the modified washer, and after the additive color solution is sprayed onto the auxiliary washing materials, the modified washer may be operated to accelerate the mixing in order to uniformly mix the additive color solution and the auxiliary washing materials. In a specific example, the machine operating setting during mixing may be, for example, 20rpm to 30rpm, 30s to 5s, bi-directional rotation. It will be appreciated that other settings of the operating conditions of the machine at the time of mixing may also be made in connection with the actual situation, without being limited thereto.
It will be appreciated that in order to avoid that the water in the original modified washer influences the concentration of the additive color solution, the modified washer may be dried in advance before step S110. In one example of the present invention, a method of drying a modified washer is provided, and specifically, for example, clean and dry reuse cloth may be placed into the modified washer to allow the modified washer to operate for at least 20 minutes.
Step S120: and (3) dry-frying and color fixing the fabric to be treated by using the washing auxiliary material adsorbed with the coloring solution.
It can be appreciated that the addition amount of the fabric to be treated in the mixing of step S120 is closely related to the content of the washing auxiliary material and the additive color solution, and further, the addition amount of the fabric to be treated may be determined according to the content of the washing auxiliary material. In a specific example, the weight ratio of the washing auxiliary material to the fabric to be treated is 1 (0.2-5). After the fabric is subjected to dry frying and color fixing treatment within the weight range, the fabric can have a better overall whitening effect. It will be appreciated that the weight ratio of wash water adjunct to fabric to be treated may be, for example, 1:0.2, 1:0.6, 1:1, 1:1.2, 1:2, 1:2.5, 1:3, 1:3.8, 1:4.2, 1:4.5, 1:5, etc. Further, the weight ratio of the washing auxiliary materials to the fabrics to be treated is 1 (0.2-2).
In a specific example, the conditions of the dry-frying include: the rotating speed is 20 rpm-30 rpm, the time is 5 minutes-30 minutes, and the intermittent bidirectional rotation is realized. Intermittent bidirectional rotation herein refers to a period of time after each rotation and then a period of time after each rotation, and the rotation direction includes clockwise direction and anticlockwise direction, for example, 30s for each rotation and 5s for each rotation. It can be appreciated that the dry-frying time can be adjusted according to the preset blushing degree, and the longer the dry-frying time is, the more obvious the overall blushing degree is. Further, the rotation speed is 25rpm to 30rpm. Further, the rotation time is 5 minutes to 20 minutes. It will be appreciated that the dry-frying process may also be carried out in a modified washer.
It can be understood that before the fabric to be treated is treated, a layer of dry clean waste cloth can be paved on the surface of the washing water auxiliary material adsorbed with the coloring solution, so that the fabric to be treated can be effectively prevented from being directly contacted with the washing water auxiliary material in a static state before the dry frying treatment is started, and the fabric is prevented from generating defects.
In one specific example, the conditions for fixation include: the drying temperature is 90-110 ℃ and the drying time is 50-70 minutes. It is understood that the fixation treatment may be in-dryer treatment. It can be understood that the fabric after the dry-frying treatment can be taken out from the modified washing machine before the fixation treatment, the adhered residual washing auxiliary materials are removed, and then the fabric is put into a dryer for drying and fixation. It will be appreciated that this step is not limited to being performed in a dryer, but may be performed in other machines capable of accomplishing the above.
It will be appreciated that the method of washing the fabric may further comprise the step of washing the wash adjunct. Specifically, the washing step may be, for example, collecting the dried and fried washing auxiliary materials, placing the washing auxiliary materials in a conventional washing machine for washing with clear water, placing the washing auxiliary materials for standby after washing, and recycling the washing auxiliary materials. Further, the condition of washing with clean water may be, for example, washing at room temperature for 20 minutes to 60 minutes, dehydrating for 200 seconds to 300 seconds, and drying at 30 ℃ to 50 ℃ for 50 minutes to 70 minutes.
It will be appreciated that the fabric may also include steps of overdrying, drying, etc. after the fixing process.
It will be appreciated that the steps of overdrying, drying, etc. may be carried out by methods conventional in the art. After the fabric is washed by soft water, the floating color can be effectively removed, the hand feeling is improved, and the washing process is finished after drying.
By adopting the fabric washing method in the embodiment, the obtained fabric has the whole whitening effect, and the worn casual ready-made garment can be obtained after the fabric is processed.
Compared with the fading residual washing process in the traditional technology, the fabric washing method with the integral whitening effect has obvious advantages in the aspects of fabric quality, process environmental protection, industrial production and the like:
in the aspect of fabric quality, the strength loss of the fabric after washing process is not more than 5%, the appearance after home washing reaches 4 levels, and the color spectrum is more complete. The washing method provided by the invention does not need strong acid and alkali chemical treatment, does not have severe physical friction caused by diatom and pumice, and does not damage the strength of the fabric basically. The white thermosetting resin adopted in the raw materials of the additive solution has no limit on the dye type of the fabric, and can be suitable for processing technologies of fabrics with various colors, particularly medium and dark colors.
In the aspect of process environmental protection, the dry stir-frying and coloring process is a non-water bath processing mode, a large amount of industrial raw materials are not needed, water is less, sewage discharge is reduced, and the method is environment-friendly. And the used washing water auxiliary materials can be recycled, so that the raw materials are saved.
In the aspect of industrial production, the invention has less limiting conditions on production equipment, and can seal and reform the drain hole of the traditional water washing machine or roller dryer for production. The washing method provided by the invention has the advantages of no extra manual operation and no dust generation except conventional carrying, good production stability and high efficiency, and can meet the industrial mass production and supply.
The following are specific examples. In the following specific examples, all materials are commercially available unless otherwise specified.
Wherein, wash water auxiliary material: vinyl acetate-ethylene copolymer with particle size of 0.5 cm-1 cm, and the manufacturer is Guangzhou city-increasing simple plastic factory with small broken sponge; diatomite is manufactured by hong Kong Fenghua practice company in China, and the model is GR4000.
White thermosetting resin: the manufacturer is a building industry limited company, and the model is the regafinish spc;
catalyst: the manufacturer is established industry Co., ltd, and the model is CATAL LT.
Example 1
Step one: weighing washing water auxiliary materials:
3kg of washing auxiliary material vinyl acetate-ethylene copolymer is weighed, and the weight ratio of the washing auxiliary material to the fabric to be treated is 1:0.67.
Step two: preparing an additive color solution:
270g of white thermosetting resin and 45g of catalyst are weighed, poured into a chemical cup, soft water is added until the volume of the mixture reaches 0.9L, and the mixture is stirred for 5 minutes at room temperature, and filtered by a filter screen for later use. The mass concentration of the white thermosetting resin is 300g/L, and the mass concentration of the catalyst is 50g/L. The ratio of the volume of the coloring solution to the weight of the washing auxiliary materials is 0.3L to 1kg.
Step three: device pretreatment
And (3) putting 5kg of clean waste cloth into the modified washing machine, running for 20 minutes at room temperature, and taking out after the waste cloth is sufficiently dried in the machine.
Step four: forming a mixed material:
and (3) adding the washing auxiliary materials weighed in the step (I) into the modified washing machine, adding the coloring solution prepared in the step (II) into a spray can, and uniformly applying the coloring solution to the washing auxiliary materials in three batches. Firstly, spraying 1/3 of the total additive color solution, and running for 3 minutes at room temperature; spraying 1/2 of the rest additive color solution, and running for 3 minutes at room temperature; and finally, uniformly spraying the rest additive color solution, and operating for 6 minutes at room temperature to finish the mixing. The speed of the modified washer is set to 30rpm, and the washer is stopped for 5 seconds after being rotated forwards and backwards for 30 seconds.
Step five: adding the fabric to be treated:
and (3) paving a layer of tight waste cloth on the surface of the mixed material formed in the step (III), and then adding 2kg of fabric to be treated into the modified washing machine.
Step six: dry parching:
and (3) operating the modified washing machine with the fabric to be treated in the fifth step for 20 minutes at room temperature, wherein the rotating speed is 30rpm, and the washing machine is stopped for 5 seconds after rotating for 30 seconds.
Step seven: drying and fixing colors:
and D, taking out the dried and fried fabric in the step six from the modified washing machine, shaking off washing auxiliary materials adhered to the clothes, and then putting the clothes into a dryer for drying at 85 ℃ for 60 minutes.
Step eight: washing water auxiliary materials:
collecting the washed auxiliary materials shaken off in the step seven, filling the auxiliary materials with a mesh bag, washing the auxiliary materials in a conventional washing machine for 5 minutes at normal temperature by using clear water, dehydrating the auxiliary materials for 30 seconds, drying the auxiliary materials at 40 ℃ for 60 minutes, and standing the auxiliary materials for later use after the auxiliary materials are finished.
Step nine: too soft washing water:
and (3) placing the fabric subjected to the eight-color fixation treatment in a conventional washing machine for common soft washing, removing floating color and improving hand feeling. The process conditions of the excessively soft washing water are as follows:
step ten: and (3) drying:
and (3) drying the fabric subjected to the soft washing in the step nine at 80 ℃ for 45 minutes.
Example 2
The procedure of example 2 is substantially the same as in example 1, except that:
step two: the mass concentration of the white thermosetting resin is 500g/L.
Example 3
The procedure of example 3 is substantially the same as in example 1, except that:
step six: and (3) allowing the modified washing machine with the fabric to be treated added in the fifth step to run for 10 minutes at room temperature.
Example 4
The procedure of example 4 was essentially the same as in example 1, except that:
step two: the mass concentration of the white thermosetting resin is 360g/L, and the mass concentration of the catalyst is 50g/L. The ratio of the volume of the coloring solution to the weight of the washing auxiliary materials is 0.17L to 1kg.
Example 5
The procedure of example 5 is substantially the same as in example 1, except that:
step one: 1.5kg of washing auxiliary material vinyl acetate-ethylene copolymer is weighed, and the weight ratio of the washing auxiliary material to the fabric to be treated is 1:1.33.
Comparative example 1
The blue common reactive dye knitted fabric is adopted to carry out the traditional snowflake washing treatment. The method comprises the following specific steps: 10g/L of potassium permanganate aqueous solution is adopted to be mixed with diatomite serving as a washing water carrier (the diatomite carrying rate is 50%), the weight of the mixture of the diatomite and the potassium permanganate aqueous solution accounts for 60% of the weight of the fabric to be treated, and the fabric to be treated and the prepared diatomite potassium permanganate aqueous solution are placed in a modified washing machine and rotated at 20rpm for 40min. Stopping, cleaning the fabric out of the cylinder, and passing clear water. Then adopting 2g/L sodium metabisulfite aqueous solution to decompose potassium permanganate component, and cleaning; then 0.5g/L softener is added, and the machine is started for 20 minutes to carry out softening, dehydration and drying.
Comparative example 2
The procedure of comparative example 2 was substantially identical to comparative example 1, except that:
the rose knitted fabric is adopted, and the concentration of the used potassium permanganate solution is 20g/L.
Comparative example 3
The procedure of comparative example 3 was substantially the same as in example 1, except that:
step one: the adopted washing auxiliary material is diatomite.
Step two: the mass concentration of the white thermosetting resin is 100g/L, and the mass concentration of the catalyst is 10g/L. The ratio of the volume of the additive color solution to the weight of the washing auxiliary materials is 0.5L to 1kg.
Comparative example 4
The procedure of comparative example 4 was substantially the same as in example 1, except that:
step two: the ratio of the volume of the additive color solution to the weight of the washing auxiliary materials is 0.4L to 1kg.
Comparative example 5
The procedure of comparative example 5 was substantially the same as in example 1, except that:
step two: the mass concentration of the white thermosetting resin is 800g/L.
As shown in fig. 1 to 5, the fabrics of examples 1 to 3 after washing with water had an overall whitening effect, and the fabrics of comparative examples 1 to 2 after washing with water had a yellow color and an overall fading effect, and did not have an overall whitening effect.
The washing effects of examples 1 to 5 and comparative examples 1 to 5 are shown in Table 1 below.
Table 1 comparison of fabric wash water effect
Category(s) Effect of washing water
Example 1 The fabric has relatively uniform whitening effect
Example 2 The fabric exhibits a relatively uniform overall whitening effect, the degree of whitening being higher than in example 1
Example 3 The fabric exhibits an overall blushing effect with a slightly poorer blushing degree and uniformity than in example 1
Example 4 The fabric exhibits an overall blushing effect with a slightly poorer blushing degree and uniformity than in example 1
Example 5 The fabric exhibits an overall blushing effect with a slightly poorer blushing degree and uniformity than in example 1
Comparative example 1 The fabric has a slightly uneven whole fading effect, obvious fading and yellowing
Comparative example 2 The fabric has a slightly uneven whole fading effect, obvious fading and yellowing
Comparative example 3 The fabric has relatively uniform whitening effect on the whole, but has obvious dust residue
Comparative example 4 The fabric has an overall whitening effect, but has obvious water stain-like whitening defects
Comparative example 5 The fabric has relatively uniform whitening effect on the whole, but has very dry and hard hand feeling and is difficult to soften
The fabrics of examples 1 to 5 and comparative examples 1 to 5 were subjected to a color fastness test, and the test results are shown in table 2 below.
Table 2 fabric color fastness test results
The technical features of the above-described embodiments may be arbitrarily combined, and all possible combinations of the technical features in the above-described embodiments are not described for brevity of description, however, as long as there is no contradiction between the combinations of the technical features, they should be considered as the scope of the description.
The above examples illustrate only a few embodiments of the invention, which are described in detail and are not to be construed as limiting the scope of the invention. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention. Accordingly, the scope of protection of the present invention is to be determined by the appended claims.

Claims (10)

1. A fabric washing method, comprising the steps of:
adsorbing the coloring solution by using washing water auxiliary materials;
dry-frying and fixing the fabric to be treated by using the washing auxiliary materials adsorbed with the additive color solution;
the washing auxiliary material comprises granular vinyl acetate-ethylene copolymer, the raw material of the additive solution comprises white thermosetting resin, the mass concentration of the white thermosetting resin in the additive solution is 10 g/L-600 g/L, and the ratio of the volume of the additive solution to the weight of the washing auxiliary material is (0.05-0.3) L/1 kg.
2. The fabric washing method of claim 1, wherein the white thermosetting resin comprises an acrylic resin.
3. The fabric washing method according to claim 1, wherein the mass concentration of the white thermosetting resin in the additive solution is 100g/L to 500g/L; and/or
The ratio of the volume of the coloring solution to the weight of the washing auxiliary materials is (0.1-0.3) L to 1kg.
4. The fabric washing method according to claim 1, wherein the washing auxiliary material has a particle size of 0.2cm to 3cm; and/or
The weight ratio of the washing auxiliary materials to the fabric to be treated is 1 (0.2-5).
5. The fabric washing method according to any one of claims 1 to 4, wherein the raw material of the additive color solution further comprises a catalyst, and the mass concentration of the catalyst in the additive color solution is 10g/L to 50g/L.
6. The fabric washing method of claim 5, wherein the catalyst comprises an aziridine crosslinking agent; and/or
The solvent of the additive color solution is water.
7. The fabric washing method according to any one of claims 1 to 4, 6, wherein the step of adsorbing the color adding solution using the washing auxiliary material comprises:
dividing the coloring solution into at least 3 batches, and sequentially mixing with the washing water auxiliary materials.
8. The fabric washing method according to any one of claims 1 to 4 and 6, wherein the dry-frying conditions include: the rotating speed is 20 rpm-30 rpm, the time is 5 minutes-30 minutes, and the intermittent bidirectional rotation is performed; and/or
The conditions for fixation include: the drying temperature is 90-110 ℃ and the drying time is 50-70 minutes.
9. A fabric characterized by having an overall whitening effect, which is obtained by washing water processing by the fabric washing method according to any one of claims 1 to 8.
10. A casual garment worn by the user, characterized in that it is produced by processing the fabric according to claim 9.
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CN103952915A (en) * 2014-04-16 2014-07-30 广东溢达纺织有限公司 Vintage knitted fabric with surface whitening effect, finished garment and processing method of two
CN110273308A (en) * 2019-07-16 2019-09-24 广东溢达纺织有限公司 Wash water auxiliary agent, snowflake washing method and the fabric with snowflake wash water effect

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US4900323A (en) * 1987-11-05 1990-02-13 Ocean Wash, Inc. Chemical and method for bleaching textiles
WO1990015180A1 (en) * 1989-06-01 1990-12-13 Ocean Wash, Inc. A composition for bleaching textiles by dry tumbling
CN101008140A (en) * 2007-01-27 2007-08-01 常熟市虹桥砂洗有限公司 Aging method after dying of all-cotton knitting clothes
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