CN110343402A - A kind of button and preparation method thereof with linen-cotton effect - Google Patents

A kind of button and preparation method thereof with linen-cotton effect Download PDF

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Publication number
CN110343402A
CN110343402A CN201910631840.0A CN201910631840A CN110343402A CN 110343402 A CN110343402 A CN 110343402A CN 201910631840 A CN201910631840 A CN 201910631840A CN 110343402 A CN110343402 A CN 110343402A
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China
Prior art keywords
button
filler
linen
agent
resin
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Granted
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CN201910631840.0A
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CN110343402B (en
Inventor
王雪雷
吴慧群
程茂
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Zhejiang Weixing Industrial Development Co Ltd
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Zhejiang Weixing Industrial Development Co Ltd
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    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B1/00—Buttons
    • A44B1/02—Buttons characterised by their material
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C08K7/26—Silicon- containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Coloring (AREA)

Abstract

The present invention provides a kind of button and preparation method thereof with linen-cotton effect.Button provided by the invention with linen-cotton effect, base slurry include: 85~100 parts of resin；1.0~15 parts of pretreated filler；0.5~10 part of diluent；0.1~0.5 part of defoaming agent；0.5~2.5 part of curing agent；0.5~2.0 part of promotor；The pretreated filler includes the pretreating agent of filler and cladding filler；Filler is selected from one or more of milk ferment, lignin, cellulose acetate, diatomite and kaolin；Pretreating agent is selected from Y-R-SiOX3One or more of；Wherein, Y is selected from amino, vinyl, epoxy group, cyano or methacryloxy；R is alkylidene；X is selected from chlorine atom, methoxyl group, ethyoxyl, methoxy ethoxy or acetoxyl group.Above-mentioned button surface has linen-cotton effect, and can satisfy the button Functional Requirement indispensable when using on clothes.

Description

A kind of button and preparation method thereof with linen-cotton effect
Technical field
The present invention relates to garment accessories technical field, in particular to a kind of button and its preparation side with linen-cotton effect Method.
Background technique
Button is a kind of common haberdashery, belongs to the fastener of clothes, is used primarily for the Chinese-style jacket with buttons down the front of connecting clothing, with The progress of living standard is developing progressively in addition to keeping original function as with more artistry and decorative representative.
Button by its material can be divided into natural class (such as true shellfish is buckled, coconut is buckled, bone is buckled), chemical (it is such as organic buckle, Resin button, ceramic button, plastic button etc.) and other material classes (such as imitation leather button, magnet button).With the development of the times, button from Material is all more and more abundant to shape, style and manufacture craft, and the needs of market diversification and the market competition of fierceness also require The button of fangle or material, such as the button etc. of imitative metal sense are constantly released in the industry.Button is the one big auxiliary of apparel industry Material is obtained by that will wrap resiniferous button slurry shaping forming.
Linen-cotton belongs in nature natural environmentally friendly material, its quality is slim and graceful, touch it is also very soft, it is prolonged resistance to With comfort is full；Also increasingly people is caused to cherish the memory of simultaneously, yearns for and pursue in nature true, kind, beautiful.This trend The condition of " naturally i.e. beautiful " is even developed to, the tidemark of linen-cotton style is exactly the physical feature that it is presented to people.
Linen-cotton material is during we live using more material, common upholstery in life, it is most of be also by What linen-cotton material was constituted, for example it is that raw material are made that sofa, mattress etc., which all have linen-cotton,.Meanwhile linen-cotton dress ornament is also Standby welcomed by the people, nowadays, linen-cotton dress ornament has returned to the sight of people again, has started one pseudo-classic fashion now Agitation possesses the linen-cotton dress ornament an of fashion, a kind of life attitudes just gradually loosened, lain fallow as people.Linen-cotton is taken The auxiliary material such as button etc. of decorations collocation linen-cotton texture can more promote dress ornament quality, but yet there are no about with linen-cotton effect The report of button product.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of button and preparation method thereof with linen-cotton effect.This hair The button surface of bright offer has linen-cotton effect, and is able to satisfy the washing of button, the dry-cleaning Functional Requirements such as color fastness and pulling force.
The present invention provides a kind of buttons with linen-cotton effect, and in terms of mass parts, the base slurry of the button includes Following components:
The pretreated filler includes the pretreating agent of filler and cladding filler；
The filler is selected from one or more of milk ferment, lignin, cellulose acetate, diatomite and kaolin；
The pretreating agent is selected from one or more of compound shown in formula (1):
Y-R-SiOX3Formula (1)；
Wherein, Y is selected from amino, vinyl, epoxy group, cyano or methacryloxy；
R is alkylidene；
X is selected from chlorine atom, methoxyl group, ethyoxyl, methoxy ethoxy or acetoxyl group.
Preferably, R is the alkylidene of C1~C4.
Preferably, the pretreating agent is selected from one or more of following compound:
NH2-(CH2)2-SiOCl3、NH2-(CH2)3-SiOCl3、CH2=CH- (CH2)2-SiO(OCH3)3、CH2=CH- (CH2)3-SiO(OCH3)3、
Preferably, the resin is selected from one of unsaturated-resin, epoxy resin, phenolic resin and Lauxite or several Kind.
Preferably, the curing agent is selected from one of methyl ethyl ketone peroxide, cyclohexanone peroxide, fatty amine and aromatic amine Or it is several.
Preferably, the promotor is cobalt naphthenate and/or cobalt iso-octoate.
Preferably, the defoaming agent is selected from polysiloxane defoaming agent, organic silicon defoamer, polyethers defoaming agent and advanced rouge One or more of fat alcohol defoaming agent；
The diluent is styrene and/or propylene oxide propylene ether.
Preferably, the dyestuff that the padding of the button is handled in dye solution used is selected from reactive dye, disperse dyes One or more of with acid dyes；
The reactive dye are selected from s-triazine type reactive dye, halogenated pyrimidine type reactive dye and double activated fundamental mode activity dye One or more of material；
The disperse dyes are selected from one of azo disperse dyes, ahthraquinone disperse dye and heterocyclic type disperse dyes Or it is several；
The acid dyes is selected from one or more of weak acid dye and neutral bath acid dyes.
The present invention also provides a kind of preparation method of button as described in the above technical scheme with linen-cotton effect, packets Include following steps:
A) resin, pretreated filler, diluent, defoaming agent, curing agent and promotor are mixed, obtains base slurry；
B) the base slurry curing is formed, obtains button blank；
C) the button blank is buckled, polishing treatment through system, obtains finished product button；
D) the finished product button is subjected to dyeing processing, obtains the button with linen-cotton effect.
Preferably, it is 80~100 DEG C that the temperature of the dyeing processing, which is temperature, bath raio 1: (30~50).
The present invention provides a kind of buttons with linen-cotton effect, and in terms of mass parts, the base slurry of the button includes Following components: 85~100 parts of resin；1.0~15 parts of pretreated filler；0.5~10 part of diluent；Defoaming agent 0.1~0.5 Part；0.5~2.5 part of curing agent；0.5~2.0 part of promotor；The pretreated filler includes the pre- place of filler and cladding filler Manage agent；The filler is selected from one or more of milk ferment, lignin, cellulose acetate, diatomite and kaolin；It is described pre- Inorganic agent is selected from one or more of compound shown in formula (1): Y-R-SiOX3Formula (1)；Wherein, Y is selected from amino, ethylene Base, epoxy group, cyano or methacryloxy；R is alkylidene；X is selected from chlorine atom, methoxyl group, ethyoxyl, methoxyl group ethoxy Base or acetoxyl group.The present invention coats specific filler using specific pretreated filler, using specific pretreating agent It is formed, by above-mentioned specific pretreated filler, in conjunction with other components, in button manufacture craft, is conducive to make button table Face generates linen-cotton effect, and can satisfy button prerequisite Functional Requirement when using on clothes, as Washing, Dry-cleaning color fastness and pulling force etc. are all satisfied standard requirements.
Test result shows that button provided by the invention has linen-cotton effect, and water-fastness, dry-cleaning, machine washing and steam scald Color fastness reaches 4 grades or more, and pulling force reaches 90N or more, meets the needs of physicochemical property.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this The embodiment of invention for those of ordinary skill in the art without creative efforts, can also basis The attached drawing of offer obtains other attached drawings.
Fig. 1 is the schematic diagram of 1 gained button of the embodiment of the present invention；
Fig. 2 is the schematic diagram of 2 gained button of the embodiment of the present invention；
Fig. 3 is the schematic diagram of 3 gained button of the embodiment of the present invention；
Fig. 4 is the schematic diagram of 4 gained button of the embodiment of the present invention；
Fig. 5 is the schematic diagram of 5 gained button of the embodiment of the present invention；
Fig. 6 is the schematic diagram of 6 gained button of the embodiment of the present invention；
Fig. 7 is the schematic diagram of 7 gained button of the embodiment of the present invention；
Fig. 8 is the schematic diagram of 8 gained button of the embodiment of the present invention.
Specific embodiment
The present invention provides a kind of buttons with linen-cotton effect, and in terms of mass parts, the base slurry of the button includes Following components:
The pretreated filler includes the pretreating agent of filler and cladding filler；
The filler is selected from one or more of milk ferment, lignin, cellulose acetate, diatomite and kaolin；
The pretreating agent is selected from one or more of compound shown in formula (1):
Y-R-SiOX3Formula (1)；
Wherein, Y is selected from amino, vinyl, epoxy group, cyano or methacryloxy；
R is alkylidene；
X is selected from chlorine atom, methoxyl group, ethyoxyl, methoxy ethoxy or acetoxyl group.
Include pretreated filler in base slurry used in button provided by the invention, resin, diluent, defoaming agent, consolidate Agent and promotor coat specific filler using specific pretreating agent wherein using specific pretreated filler It is formed, by above-mentioned specific pretreated filler, in conjunction with other components, in button manufacture craft, is conducive to make button table Face generates linen-cotton effect, and can satisfy button prerequisite Functional Requirement when using on clothes, as Washing, Dry-cleaning color fastness and pulling force etc. are all satisfied standard requirements.
In the present invention, the resin is the basis of button green body, and the present invention is not special to the type of the resin It is required that being knob base resin well known to those skilled in the art；In order to improve with the associativity of pretreated filler, reach more Good linen-cotton effect, in the present invention, the resin is preferably in unsaturated-resin, epoxy resin, phenolic resin and Lauxite One or more.In the present invention, the content of the resin is 85~100 mass parts, preferably 90~100 mass parts.
In the present invention, the pretreated filler includes the pretreating agent of filler and cladding filler.
Wherein, the filler is selected from one of milk ferment, lignin, cellulose acetate, diatomite and kaolin or several Kind.The present invention is not particularly limited the source of the filler, is general commercially available product.
Wherein, the pretreating agent is selected from one or more of compound shown in formula (1):
Y-R-SiOX3Formula (1)；
In above-mentioned formula (1):
Y is selected from amino, vinyl, epoxy group, cyano or methacryloxy；Preferably amino, vinyl, epoxy group Or methacryloxy；
R is alkylidene；The preferably alkylidene of C1~C4, the more preferably alkylidene of C1~C3；
X is selected from chlorine atom, methoxyl group, ethyoxyl, methoxy ethoxy or acetoxyl group；Preferably chlorine atom, methoxyl group, Ethyoxyl or methoxy ethoxy.
It is further preferred that the pretreating agent is selected from one or more of following compound:
NH2-(CH2)2-SiOCl3、NH2-(CH2)3-SiOCl3、CH2=CH- (CH2)2-SiO(OCH3)3、CH2=CH- (CH2)3-SiO(OCH3)3、
In the present invention, in the pretreated filler, the mass ratio of the pretreating agent of filler and cladding filler is preferably (5 ~20): (2~10).
In the present invention, the pretreated filler preferably obtains in the following manner: by the water-soluble of filler and pretreating agent Liquid mixes, is dry, obtains pretreated filler.Wherein, the mass concentration of the aqueous solution of the pretreating agent be preferably 2%~ 10%.The mass ratio of the aqueous solution of the filler and pretreating agent is preferably 5%~20%.It is preferably adjoint in the two mixed process Stirring, the rate of the stirring is preferably 10~50rpm；The time of the stirring is preferably 60~90min.In the present invention, institute Stating dry temperature is preferably 60~90 DEG C；The dry time is preferably 2~4 hours.Pretreated filler is obtained after drying, It is put into sealer and saves backup.The present invention pre-processes above-mentioned specific filler using specific pretreating agent, makes filler Surface forms specific active function groups, then cooperates other components, is conducive to button surface in the manufacture craft of button and is formed Linen-cotton effect, and can satisfy the Washing of button, the dry-cleaning Functional Requirements such as color fastness and pulling force.
In the present invention, on the basis of 85~100 mass parts of amount of resin, the dosage of the pretreated filler is 1.0~ 15 mass parts, preferably 5~15 mass parts.
In the present invention, the diluent is preferably styrene and/or propylene oxide propylene ether.In the present invention, used with resin On the basis of measuring 85~100 mass parts, the dosage of the diluent is 0.5~10 part, preferably 2~8 parts.
In the present invention, the type of the defoaming agent is not particularly limited, and is used for button to be well known to those skilled in the art The defoaming agent of blank；It is uniformly contacted between each component to improve in the whole knob base slurry system of the present invention, it is described in the present invention Defoaming agent is preferably in polysiloxane defoaming agent, organic silicon defoamer, polyethers defoaming agent and senior class fatty alcohols defoaming agent It is one or more of.In the present invention, on the basis of 85~100 mass parts of amount of resin, the dosage of the defoaming agent is 0.1~0.5 Part, preferably 0.2~0.4 part.
In the present invention, the curing agent is preferably in methyl ethyl ketone peroxide, cyclohexanone peroxide, fatty amine and aromatic amine It is one or more of.In the present invention, on the basis of 85~100 mass parts of amount of resin, the dosage of the curing agent is 0.5~2.5 Part, preferably 1.0~2.5 parts.
In the present invention, the promotor is preferably cobalt naphthenate and/or cobalt iso-octoate.In the present invention, with amount of resin 85 On the basis of~100 mass parts, the dosage of the promotor is 0.5~2.0 part, preferably 0.8~2.0 part.
In the present invention, it is preferably reactive dye, dispersion that the padding of the button, which handles the dyestuff in dye solution used, One or more of dyestuff and acid dyes.Wherein, the preferred s-triazine type reactive dye of the reactive dye, halogenated pyrimidine type One or more of reactive dye and double activated fundamental mode reactive dye；More preferably s-triazine type reactive dye.The dispersion Dyestuff is preferably one or more of azo disperse dyes, ahthraquinone disperse dye and heterocyclic type disperse dyes；More preferably For heterocyclic type disperse dyes.The acid dyes is preferably one or more of weak acid dye and neutral bath acid dyes； More preferably neutral bath acid dyes.It is dyed using the button that above-mentioned particular dye forms the above-mentioned base slurry of the present invention Processing, can obtain preferable linen-cotton effect, and meet Essential Performance Requirements.
In the present invention, it is preferred that the dye solution includes the component of following mass ratio:
Dyestuff 0.1%~5%；
Emulsifier 0.1%~5%；
Water surplus.
Wherein, consistent described in the dyestuff and above-mentioned technical proposal, details are not described herein.
The emulsifier is preferably fatty acid glycerine fat, sucrose ester, sorbose alcohol ester, soybean lecithin, lauric monoglyceride Ester, methyl glycol fatty acid ester, alkyl phenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, aliphatic amine polyoxyethylene ether, oleic acid polyoxy Vinyl acetate, polyoxyethylene stearic acid ester, polyoxylethylene abietate and to one of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt Or it is several；More preferably fatty acid glycerine fat, sorbose alcohol ester, lauric monoglyceride, alkyl phenol polyoxyethylene ether, fatty alcohol Polyoxyethylene ether, polyoxyethylene stearic acid ester and to one or more of methoxyl group fatty acyl amido benzene sulfonic acid sodium salt.
The present invention also provides a kind of preparation method of button as described in the above technical scheme with linen-cotton effect, packets Include following steps:
A) resin, pretreated filler, diluent, defoaming agent, curing agent and promotor are mixed, obtains base slurry；
B) the base slurry curing is formed, obtains button blank；
C) the button blank is buckled, polishing treatment through system, obtains finished product button；
D) the finished product button is subjected to dyeing processing, obtains the button with linen-cotton effect.
In the step a), the kind of the resin, pretreated filler, diluent, defoaming agent, curing agent and promotor Class, dosage and source etc. with it is consistent described in above-mentioned technical proposal, this is no longer going to repeat them.The mixed mode does not have It is specifically limited, raw material is mixed according to conventional mixing method well known to those skilled in the art.
In the step b), the curing molding is preferably centrifugal forming, compression molding or cast molding.
In the step c), the mode of the system button is not particularly limited, for conventional system well known to those skilled in the art Detain technique, such as punching press, cutting.The mode of the polishing treatment is not particularly limited, for known to those skilled in the art Conventional polishing mode.
Dyestuff or the dye solution and above-mentioned technical side in the step d), in dyeing processing dye solution used Consistent described in case, details are not described herein.In the present invention, the temperature of the dyeing processing is preferably 80~100 DEG C；Dyeing processing Time be preferably 40~120min.The bath raio of the dyeing processing is preferably 1: (30~50).To obtained in previous step Specific button carries out above-mentioned dyeing processing, is conducive to make button surface that preferable linen-cotton effect, and the various aspects of button be presented It can such as wash, dry-clean color fastness and pulling force is met the requirements.
Provided by the invention preparation method is simple, linen-cotton effect true to nature can be formed on resin button surface, together When, it can also meet the functional requirements of button, such as Washing, dry-cleaning color fastness and pulling force meet standard requirements.In addition, Provided by the invention preparation method is simple, reduces the experience dependence to technical staff, being capable of large-scale production；And it is above-mentioned Preparation method can be effectively reduced product defect rate, improves production efficiency, reduces wastage of material and cost of labor.
For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still It should be appreciated that these descriptions are only further explanation the features and advantages of the present invention, rather than to the claims in the present invention Limitation.
Embodiment 1
The preparation of 1.1 buttons
S1: 10% milk ferment filler is added into the pretreating agent aqueous solution of concentration 5%, stirs 80min under 10rpm Afterwards, drying 3 hours in 80 DEG C of baking ovens are placed in, pretreated filler is obtained；
Pretreating agent used are as follows: NH2-(CH2)2-SiOCl3。
S2: 15 parts of pretreated fillers are added in 90 parts of unsaturated-resins, and 10 parts of styrene diluent, defoaming is added 0.2 part of agent, 1.0 parts of cobalt naphthenate promotor are uniformly mixed, and add 1.5 parts of methyl ethyl ketone peroxide curing agent, rotation is poured into stirring In the centrifuge turned, makes mixed slurry in centrifuge radial distribution using centrifugal action, form to obtain in centrifuge surface cure Plate.Gained plate is successively passed through into punching press and obtains blank, then blank is cut on deduction processed to obtain required shape Blank finally polishes, and obtains finished product button.
S3: dyeing processing is carried out to gained finished product button, obtains button；
Dye solution used includes:
S-triazine type reactive dye 2%, emulsifier fatty acid glycerine fat 2%, water supplies 100%.
Dyeing temperature is 80 DEG C, and the time is 90 minutes, bath raio 1: 30.
The test of 1.2 buttons
(1) appearance of gained button is detected, as a result as shown in FIG. 1, FIG. 1 is 1 gained buttons of the embodiment of the present invention Schematic diagram.As can be seen that button surface has linen-cotton effect.
(2) physicochemical property test is carried out to gained button, the results show that aqueous color fastness >=4.0 grade of button, dry-clean color Fastness >=4.0 grade, color fastness >=4.0 grade of machine-washing, resistance to steam scald color fastness >=4.0 grade, reach standard GB/T3921.1 weaving The requirement that product are water-fastness, dry-clean and machine-wash color fastness.The pulling force > 90N of button.
(3) button is produced in batches according to above-mentioned preparation method, qualification rate is 100% as the result is shown.
Embodiment 2
The preparation of 1.1 buttons
S1: 15% milk ferment filler is added into the pretreating agent aqueous solution of concentration 10%, stirs 80min under 10rpm Afterwards, drying 3 hours in 80 DEG C of baking ovens are placed in, pretreated filler is obtained；
Pretreating agent used are as follows: NH2-(CH2)3-SiOCl3。
S2: 10 parts of pretreated fillers are added in 90 parts of epoxy resin, and propylene oxide propylene ether diluent 5 is added Part, 0.3 part of defoaming agent, 1.0 parts of cobalt iso-octoate promotor are uniformly mixed, 2.0 parts of fatty amine curing agent are added, by what is obtained Mixed slurry pours into plastic mold, and solidification obtains pre-setting body.The pre-setting body is successively passed through into punching press and obtains blank, then Blank is cut on deduction processed to obtain the blank of required shape, is finally polished, finished product button is obtained.
S3: dyeing processing is carried out to gained finished product button, the dye solution includes:
Heterocyclic type disperse dyes 5%, emulsifier sorbose alcohol ester 5%, water supplies 100%.
Dyeing temperature is 90 DEG C, and the time is 60 minutes, bath raio 1: 50.
The test of 1.2 buttons
(1) appearance of gained button is detected, as a result as shown in Fig. 2, Fig. 2 is 2 gained button of the embodiment of the present invention Schematic diagram.As can be seen that button surface has linen-cotton effect.
(2) physicochemical property test is carried out to gained button, the results show that aqueous color fastness >=4.0 grade of button, dry-clean color Fastness >=4.0 grade, color fastness >=4.0 grade of machine-washing, resistance to steam scald color fastness >=4.0 grade, reach standard GB/T3921.1 weaving The requirement that product are water-fastness, dry-clean and machine-wash color fastness.The pulling force > 90N of button.
(3) yield rate measurement is carried out according to the test method of embodiment 1, qualification rate is 100% as the result is shown.
Embodiment 3
The preparation of 1.1 buttons
S1: 5% lignin filler being added into the pretreating agent aqueous solution of concentration 2%, after stirring 80min under 20rpm, Drying 3 hours in 80 DEG C of baking ovens are placed in, pretreated filler is obtained；
Pretreating agent used are as follows: CH2=CH- (CH2)2-SiO(OCH3)3。
S2: 5 parts of pretreated fillers are added in 85 parts of phenolic resin, and be added 5 parts of propylene oxide propylene ether diluent, 0.3 part of defoaming agent, 1.0 parts of cobalt iso-octoate promotor are uniformly mixed, add 2.0 parts of aromatic amine curing agent, the mixing that will be obtained Slurry pours into plastic mold, and solidification obtains pre-setting body.The pre-setting body is successively passed through into punching press and obtains blank, then is being made Blank is cut on deduction to obtain the blank of required shape, is finally polished, finished product button is obtained.
S3: dyeing processing is carried out to gained finished product button, the dye solution includes:
Neutrality bath acid dyes 1%, emulsifier lauric monoglyceride 2%, water supplies 100%.
Dyeing temperature is 80 DEG C, and the time is 90 minutes, bath raio 1: 50.
The test of 1.2 buttons
(1) appearance of gained button is detected, as a result as shown in figure 3, Fig. 3 is 3 gained button of the embodiment of the present invention Schematic diagram.As can be seen that button surface has linen-cotton effect.
(2) physicochemical property test is carried out to gained button, the results show that aqueous color fastness >=4.0 grade of button, dry-clean color Fastness >=4.0 grade, color fastness >=4.0 grade of machine-washing, resistance to steam scald color fastness >=4.0 grade, reach standard GB/T3921.1 weaving The requirement that product are water-fastness, dry-clean and machine-wash color fastness.The pulling force > 90N of button.
(3) yield rate measurement is carried out according to the test method of embodiment 1, qualification rate is 100% as the result is shown.
Embodiment 4
The preparation of 1.1 buttons
S1: 10% cellulose acetate filler is added into the pretreating agent aqueous solution of concentration 5%, is stirred under 20rpm After 80min, drying 3 hours in 80 DEG C of baking ovens are placed in, pretreated filler is obtained；
Pretreating agent used are as follows: CH2=CH- (CH2)3-SiO(OCH3)3。
S2: 10 parts of pretreated fillers are added in 95 parts of Lauxites, and 6 parts of styrene diluent, defoaming agent is added 0.4 part, 1.0 parts of cobalt naphthenate promotor are uniformly mixed, and add 2.0 parts of cyclohexanone peroxide curing agent, rotation is poured into stirring Centrifuge in, make mixed slurry in centrifuge radial distribution using centrifugal action, form to obtain plate in centrifuge surface cure Material.Gained plate is successively passed through into punching press and obtains blank, then blank is cut on deduction processed to obtain the hair of required shape Base finally polishes, and obtains finished product button.
S3: dyeing processing is carried out to gained finished product button, the dye solution includes:
S-triazine type activity type dye 3%, emulsifier alkyl phenol polyoxyethylene ether 2%, water supplies 100%.
Dyeing temperature is 90 DEG C, and the time is 60 minutes, bath raio 1: 30.
The test of 1.2 buttons
(1) appearance of gained button is detected, as a result as shown in figure 4, Fig. 4 is 4 gained button of the embodiment of the present invention Schematic diagram.As can be seen that button surface has linen-cotton effect.
(2) physicochemical property test is carried out to gained button, the results show that aqueous color fastness >=4.0 grade of button, dry-clean color Fastness >=4.0 grade, color fastness >=4.0 grade of machine-washing, resistance to steam scald color fastness >=4.0 grade, reach standard GB/T3921.1 weaving The requirement that product are water-fastness, dry-clean and machine-wash color fastness.The pulling force > 90N of button.
(3) yield rate measurement being carried out according to the test method of embodiment 1 and carrying out yield rate measurement, qualification rate is as the result is shown 100%.
Embodiment 5
The preparation of 1.1 buttons
S1: 10% tripolite filling material being added into 5% pretreating agent aqueous solution of concentration, after stirring 80min under 20rpm, Drying 3 hours in 80 DEG C of baking ovens are placed in, pretreated filler is obtained；
Pretreating agent used are as follows:
S2: 15 parts of pretreated fillers are added in 100 parts of unsaturated-resins, and propylene oxide propylene ether diluent is added 8 parts, 0.4 part of defoaming agent, 1.0 parts of cobalt naphthenate promotor are uniformly mixed, add 2.0 parts of methyl ethyl ketone peroxide curing agent, stir It mixes in the centrifuge for pouring into rotation, makes mixed slurry in centrifuge radial distribution using centrifugal action, in centrifuge surface cure Molding obtains plate.Gained plate is successively passed through into punching press and obtains blank, then blank is cut on deduction processed to obtain institute The blank for needing shape, finally polishes, and obtains finished product button.
S3: dyeing processing is carried out to gained finished product button, the dye solution includes:
Heterocyclic type disperse dye 5%, emulsifier fatty alcohol polyoxyethylene ether 4%, water supplies 100%.
Dyeing temperature is 80 DEG C, and the time is 90 minutes, bath raio 1: 30.
The test of 1.2 buttons
(1) appearance of gained button is detected, as a result as shown in figure 5, Fig. 5 is 5 gained button of the embodiment of the present invention Schematic diagram.As can be seen that button surface has linen-cotton effect.
(2) physicochemical property test is carried out to gained button, the results show that aqueous color fastness >=4.0 grade of button, dry-clean color Fastness >=4.0 grade, color fastness >=4.0 grade of machine-washing, resistance to steam scald color fastness >=4.0 grade, reach standard GB/T3921.1 weaving The requirement that product are water-fastness, dry-clean and machine-wash color fastness.The pulling force > 90N of button.
(3) yield rate measurement is carried out according to the test method of embodiment 1, qualification rate is 100% as the result is shown.
Embodiment 6
The preparation of 1.1 buttons
S1: 15% kaolin clay filler being added into 10% pretreating agent aqueous solution of concentration, after stirring 80min under 30rpm, Drying 3 hours in 80 DEG C of baking ovens are placed in, pretreated filler is obtained；
Pretreating agent used are as follows:
S2: 5 parts of pretreated fillers are added in 90 parts of epoxy resin, and be added 5 parts of propylene oxide propylene ether diluent, 0.2 part of defoaming agent, 1.0 parts of cobalt naphthenate promotor are uniformly mixed, add 2.0 parts of cyclohexanone peroxide curing agent, stirring is fallen Enter in the centrifuge of rotation, makes mixed slurry in centrifuge radial distribution using centrifugal action, formed in centrifuge surface cure Obtain plate.Gained plate is successively passed through into punching press and obtains blank, then blank is cut on deduction processed to obtain required shape The blank of shape, finally polishes, and obtains finished product button.
S3: dyeing processing is carried out to gained finished product button, the dye solution includes:
Neutrality bathes acid type dye 0.5%, and emulsifier polyoxyethylene stearic acid ester 1%, water supplies 100%.
Dyeing temperature is 90 DEG C, and the time is 60 minutes, bath raio 1: 50.
The test of 1.2 buttons
(1) appearance of gained button is detected, as a result as shown in fig. 6, Fig. 6 is 6 gained button of the embodiment of the present invention Schematic diagram.As can be seen that button surface has linen-cotton effect.
(2) physicochemical property test is carried out to gained button, the results show that aqueous color fastness >=4.0 grade of button, dry-clean color Fastness >=4.0 grade, color fastness >=4.0 grade of machine-washing, resistance to steam scald color fastness >=4.0 grade, reach standard GB/T3921.1 weaving The requirement that product are water-fastness, dry-clean and machine-wash color fastness.The pulling force > 90N of button.
(3) yield rate measurement is carried out according to the test method of embodiment 1, qualification rate is 100% as the result is shown.
Embodiment 7
The preparation of 1.1 buttons
S1: 5% milk ferment filler is added into 8% pretreating agent aqueous solution of concentration and is set after stirring 80min under 30rpm It is 3 hours dry in 80 DEG C of baking ovens, obtain pretreated filler；
Pretreating agent used are as follows:
S2: 10 parts of pretreated fillers are added in 90 parts of phenolic resin, and 4 parts of styrene diluent, defoaming agent is added 0.2 part, 1.0 parts of cobalt iso-octoate promotor are uniformly mixed, and add 2.0 parts of methyl ethyl ketone peroxide curing agent, rotation is poured into stirring Centrifuge in, make mixed slurry in centrifuge radial distribution using centrifugal action, form to obtain plate in centrifuge surface cure Material.Gained plate is successively passed through into punching press and obtains blank, then blank is cut on deduction processed to obtain the hair of required shape Base finally polishes, and obtains finished product button.
S3: dyeing processing is carried out to gained finished product button, the dye solution includes:
S-triazine type activity type dye 1%, emulsifier to methoxyl group fatty acyl amido benzene sulfonic acid sodium salt 1%, supply by water 100%.
Dyeing temperature is 100 DEG C, and the time is 50 minutes, bath raio 1: 50.
The test of 1.2 buttons
(1) appearance of gained button is detected, as a result as shown in fig. 7, Fig. 7 is 7 gained button of the embodiment of the present invention Schematic diagram.As can be seen that button surface has linen-cotton effect.
(2) physicochemical property test is carried out to gained button, the results show that aqueous color fastness >=4.0 grade of button, dry-clean color Fastness >=4.0 grade, color fastness >=4.0 grade of machine-washing, resistance to steam scald color fastness >=4.0 grade, reach standard GB/T3921.1 weaving The requirement that product are water-fastness, dry-clean and machine-wash color fastness.The pulling force > 90N of button.
(3) yield rate measurement is carried out according to the test method of embodiment 1, qualification rate is 100% as the result is shown.
Embodiment 8
The preparation of 1.1 buttons
S1: 10% lignin filler being added into 6% pretreating agent aqueous solution of concentration, after stirring 80min under 30rpm, Drying 3 hours in 80 DEG C of baking ovens are placed in, pretreated filler is obtained；
Pretreating agent used are as follows:
S2: 15 parts of pretreated fillers are added in 100 parts of Lauxites, and 7 parts of styrene diluent, defoaming agent is added 0.3 part, 1.0 parts of cobalt iso-octoate promotor are uniformly mixed, and add 2.0 parts of methyl ethyl ketone peroxide curing agent, rotation is poured into stirring Centrifuge in, make mixed slurry in centrifuge radial distribution using centrifugal action, form to obtain plate in centrifuge surface cure Material.Gained plate is successively passed through into punching press and obtains blank, then blank is cut on deduction processed to obtain the hair of required shape Base finally polishes, and obtains finished product button.
S3: dyeing processing is carried out to gained finished product button, the dye solution includes:
Heterocyclic type disperse dye 2%, emulsifier fatty alcohol polyoxyethylene ether 1%, water supplies 100%.
Dyeing temperature is 100 DEG C, and the time is 50 minutes, bath raio 1: 50.
The test of 1.2 buttons
(1) appearance of gained button is detected, as a result as shown in figure 8, Fig. 8 is 8 gained button of the embodiment of the present invention Schematic diagram.As can be seen that button surface has linen-cotton effect.
(2) physicochemical property test is carried out to gained button, the results show that aqueous color fastness >=4.0 grade of button, dry-clean color Fastness >=4.0 grade, color fastness >=4.0 grade of machine-washing, resistance to steam scald color fastness >=4.0 grade, reach standard GB/T3921.1 weaving The requirement that product are water-fastness, dry-clean and machine-wash color fastness.The pulling force > 90N of button.
(3) yield rate measurement is carried out according to the test method of embodiment 1, qualification rate is 100% as the result is shown.
The above description of the embodiment is only used to help understand the method for the present invention and its core ideas.To these embodiments A variety of modifications will be readily apparent to those skilled in the art, the general principles defined herein can be with Without departing from the spirit or scope of the present invention, it realizes in other embodiments.Therefore, the present invention will not be limited In the embodiments shown herein, and it is to fit to widest model consistent with the principles and novel features disclosed in this article It encloses.

Claims (10)

1. a kind of button with linen-cotton effect, which is characterized in that in terms of mass parts, the base slurry of the button includes following Component:
The pretreated filler includes the pretreating agent of filler and cladding filler；
The filler is selected from one or more of milk ferment, lignin, cellulose acetate, diatomite and kaolin；
The pretreating agent is selected from one or more of compound shown in formula (1):
Y-R-SiOX3Formula (1)；
Wherein, Y is selected from amino, vinyl, epoxy group, cyano or methacryloxy；
R is alkylidene；
X is selected from chlorine atom, methoxyl group, ethyoxyl, methoxy ethoxy or acetoxyl group.
2. button according to claim 1, which is characterized in that R is the alkylidene of C1~C4.
3. button according to claim 1 or 2, which is characterized in that the pretreating agent in following compound one Kind is several:
NH2-(CH2)2-SiOCl3、NH2-(CH2)3-SiOCl3、CH2=CH- (CH2)2-SiO(OCH3)3、CH2=CH- (CH2)3- SiO(OCH3)3、
4. button according to claim 1, which is characterized in that the resin is selected from unsaturated-resin, epoxy resin, phenolic aldehyde One or more of resin and Lauxite.
5. button according to claim 1, which is characterized in that the curing agent is selected from methyl ethyl ketone peroxide, peroxidating ring One or more of hexanone, fatty amine and aromatic amine.
6. button according to claim 1, which is characterized in that the promotor is cobalt naphthenate and/or cobalt iso-octoate.
7. button according to claim 1, which is characterized in that the defoaming agent is selected from polysiloxane defoaming agent, organosilicon One or more of defoaming agent, polyethers defoaming agent and senior class fatty alcohols defoaming agent；
The diluent is styrene and/or propylene oxide propylene ether.
8. button according to claim 1, which is characterized in that the padding of the button is handled in dye solution used Dyestuff is selected from one or more of reactive dye, disperse dyes and acid dyes；
The reactive dye are in s-triazine type reactive dye, halogenated pyrimidine type reactive dye and double activated fundamental mode reactive dye One or more；
The disperse dyes are selected from one of azo disperse dyes, ahthraquinone disperse dye and heterocyclic type disperse dyes or several Kind；
The acid dyes is selected from one or more of weak acid dye and neutral bath acid dyes.
9. a kind of preparation method of the button according to any one of claims 1 to 8 with linen-cotton effect, which is characterized in that The following steps are included:
A) resin, pretreated filler, diluent, defoaming agent, curing agent and promotor are mixed, obtains base slurry；
B) the base slurry curing is formed, obtains button blank；
C) the button blank is buckled, polishing treatment through system, obtains finished product button；
D) the finished product button is subjected to dyeing processing, obtains the button with linen-cotton effect.
10. preparation method according to claim 9, which is characterized in that the temperature of the dyeing processing is 80~100 DEG C, Bath raio is 1: (30~50).
CN201910631840.0A 2019-07-12 2019-07-12 Button with cotton and hemp effect and preparation method thereof Active CN110343402B (en)

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CN111763468A (en) * 2020-06-24 2020-10-13 浙江伟星实业发展股份有限公司 Button with highlight paint and surface LOGO3D suspension effect and processing method thereof
CN114702781A (en) * 2022-03-29 2022-07-05 浙江新城钮扣饰品有限公司 High-strength flame-retardant button and process thereof

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Publication number Priority date Publication date Assignee Title
CN111763468A (en) * 2020-06-24 2020-10-13 浙江伟星实业发展股份有限公司 Button with highlight paint and surface LOGO3D suspension effect and processing method thereof
CN111763468B (en) * 2020-06-24 2021-11-12 浙江伟星实业发展股份有限公司 Button with highlight paint and surface LOGO3D suspension effect and processing method thereof
CN114702781A (en) * 2022-03-29 2022-07-05 浙江新城钮扣饰品有限公司 High-strength flame-retardant button and process thereof
CN114702781B (en) * 2022-03-29 2024-03-22 浙江新城钮扣饰品有限公司 High-strength flame-retardant button and process thereof

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