CN105131194B - A kind of artificial ox bone button and preparation method thereof - Google Patents
A kind of artificial ox bone button and preparation method thereof Download PDFInfo
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- CN105131194B CN105131194B CN201510643846.1A CN201510643846A CN105131194B CN 105131194 B CN105131194 B CN 105131194B CN 201510643846 A CN201510643846 A CN 201510643846A CN 105131194 B CN105131194 B CN 105131194B
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Abstract
The present invention provides a kind of mixed slurry for being used to manufacture artificial ox bone button, including：Slurry A and slurry B；The slurry A is the unsaturated polyester resin of 20~100 parts by weight, the colorant of 5~50 parts by weight, accelerating agent, the initiator of 0.4~2 parts by weight of 0.2~2 parts by weight；The slurry B is the unsaturated polyester resin of 800~1200 parts by weight, the mill base of 1.0~8.0 parts by weight, the soluble acinous filler of 5.0~50 parts by weight, the styrene of 5.0~80 parts by weight, accelerating agent, the initiator of 4.0~20 parts by weight of 2.0~20 parts by weight.Artificial ox bone button prepared by the present invention, which has been selected, to be derived from a wealth of sources and cheap unsaturated polyester resin material, also has bone line texture and stone age texture such as natural ox bone button, and dyeing rear stability is controllable.
Description
Technical field
The invention belongs to garment production technical field, more particularly to a kind of artificial ox bone button and preparation method thereof.
Background technology
Button is exactly to be used for the fastener that the both sides hem are connected on clothes, its initial effect is for connection to the door of clothes
The flap, gradually developed into and artistry and dicoration had more in addition to its original function is kept, and dress ornament it is personalized and
The representative of multifunction.
Button presses the classification of its material, can be divided into natural class, chemical and other materials, in natural class knob among these
Button is divided into bone button (common are ox horn button), shell button, coconut button, wood button, bamboo button, fruit button, shell button etc. again.
In numerous natural class buttons, bone button, because common ox bone makes, is commonly known as ox bone button, common are ox horn button etc..It
It is a kind of very ancient button, bone is to come from natural thing, the soft exquisiteness of striped, is in rice white or milk under normal condition
White, has the characteristics that the graceful and pseudo-classic sclerotin sense of natural soft color and luster, texture, all gives out from the inside to surface noble tempting
Breath, and people are again usually together with ox bone and cultural contacts, so can show its characteristic in natural class button,
Set off the high-end quality of dress ornament so that ox bone button is liked by masses always.
There are the various features such as noble fashion just because of ox bone fastener, be always the head of the especially high-end dress ornament of Clothing Industry
Choosing collocation, many famous foreign brands and domestic high-grade clothing all use button made of ox bone.Increasingly carried however as people
High material life requirement, has expedited the emergence of the development in pluralism of dress ornament commodity, so also driven button industry high demand and
Increasingly fierce market competition, but the development for limiting natural ox bone button of the inherent shortcoming of natural ox bone button also all the more.
First, though natural ox bone resource is not rare, it is difficult to collect, thus it is expensive；Secondly, natural ox
Bone color is single, though can use padding process reform ox bone button surface color after arrange in pairs or groups clothes color, at the same time
There are it is larger the drawbacks of, because there is individual sex differernce, and the bone that the stone age is different, the degree of its osteoporosis in natural ox bone
Difference, so button surface uniformity is poor made of natural ox bone.Again, the surface color of natural ox bone button can pass through
Dyeing or spray painting colouring, but due to individual difference, it is easy to aberration occur after dyeing.The color fastness of product and state after dyeing at the same time
Interior or international standard also has a certain distance, and dry, Washing or flatiron color fastness can only achieve 3.5 grades, and top grade is taken
Dress may move dye phenomenon there are different grades of staining.Therefore, the disadvantages mentioned above of natural ox bone button constrains ox bone button
Development and diversification application.
In view of this, a kind of artificial imitative natural ox bone with natural ox bone button gloss and texture feature how is found
Button, and the deficiency in above-mentioned natural ox bone material can be made up at the same time, it is always urgent problem to be solved in button production field
One of.
The content of the invention
In view of this, the technical problem to be solved in the present invention is to provide a kind of artificial ox bone button and preparation method thereof,
Prepared by method provided by the invention manually imitates natural ox bone button, has preferable dry, Washing or flatiron color fastness,
Also there is the bone line texture and stone age texture of natural ox bone button at the same time.
The invention discloses a kind of mixed slurry for being used to manufacture artificial ox bone button, it is characterised in that including：Slurry A
With slurry B；
The slurry A is：
The slurry B is：
Preferably, the mass ratio of the slurry A and slurry B are 1：(10~50).
Preferably, the accelerating agent is cobalt naphthenate and/or cobalt iso-octoate；
The initiator is methyl ethyl ketone peroxide and/or cyclohexanone peroxide；
The unsaturated polyester resin is m-phthalate unsaturated polyester resin and/or metaphenylene unsaturated polyester resin.
Preferably, the soluble acinous filler is one in wax powder, urea-formaldehyde moulding powder, microballon, young white sugar and fine salt
Kind is a variety of.
The present invention provides a kind of preparation method of artificial ox bone button, it is characterised in that comprises the following steps：
A after) being mixed unsaturated polyester resin, colorant, accelerating agent and initiator, base slurry A is obtained；The system
The density of base slurry A is 1.25~5g/mL；
Unsaturated polyester resin, mill base, soluble acinous filler, accelerating agent, styrene and initiator are mixed
Afterwards, base slurry B is obtained；The viscosity of the base slurry B is 300~900mPas；
B) by above-mentioned steps A) obtained base slurry A and base slurry B after blank-making technology, obtain artificial ox bone knob
Button.
Preferably, in the blank-making technology, the gel time of the base slurry A is 3~7min；
The gel time of the base slurry B is 3~10min.
Preferably, the blank-making technology is centrifugation blank-making technology.
Preferably, the step B) be specially：
B1) by step A) obtained base slurry B is first laid in centrifuge inner wall, centrifugation curing is carried out, completely not solid
During change, base slurry A is sprayed at the above-mentioned base slurry B surface not being fully cured, then artificial ox bone is obtained after being cured
Button blank；
B2 the artificial ox bone button blank that above-mentioned steps obtain) is obtained into artificial ox bone button after system buckles technique.
Preferably, the sprinkling is sprayed for wire；The device of the sprinkling is air pressure spray gun.
Present invention also offers a kind of artificial ox bone button, it is characterised in that by unsaturated polyester resin, colorant and solvable
Property acinous filler obtains after preparation.
The present invention provides a kind of mixed slurry for being used to manufacture artificial ox bone button, including：Slurry A and slurry B；It is described
Slurry A be the unsaturated polyester resin of 20~100 parts by weight, the colorant of 5~50 parts by weight, 0.2~2 parts by weight accelerating agent,
The initiator of 0.4~2 parts by weight；The slurry B is the unsaturated polyester resin of 800~1200 parts by weight, 1.0~8.0 weight
The mill base of part, the soluble acinous filler of 5.0~50 parts by weight, the styrene of 5.0~80 parts by weight, 2.0~20 parts by weight
Accelerating agent, the initiator of 4.0~20 parts by weight.Present invention also offers a kind of preparation method of artificial ox bone button, it is special
Sign is, comprises the following steps, and after first being mixed unsaturated polyester resin, colorant, accelerating agent and initiator, is made
Base slurry A；The density of the base slurry A is 1.25~5g/mL；Unsaturated polyester resin, mill base, soluble acinous are filled out
After material, accelerating agent, styrene and initiator are mixed, base slurry B is obtained；The viscosity of the base slurry B for 300~
900mPa·s；The base slurry A and base slurry B that above-mentioned steps are obtained again obtain artificial ox bone knob after blank-making technology
Button.
Compared with prior art, present invention employs including unsaturated polyester resin, colorant and soluble acinous filler
Mixed slurry, by controlling viscosity and blank-making technology, finally obtained artificial ox bone button, i.e., manually imitate natural ox bone resin
Button.Artificial ox bone button prepared by the present invention, which has been selected, to be derived from a wealth of sources and cheap unsaturated polyester resin material, more
The deficiency on ox bone material source has been mended, also there is the bone line texture and stone age texture such as natural ox bone button, and after dyeing
Stability is controllable, effectively overcomes natural ox bone since the stone age is different, the degree of osteoporosis it is different and caused by uniformity
There is the problem of aberration after poor and dyeing.In addition, artificial ox bone button prepared by the present invention has preferable dry, washing color
Fastness or flatiron color fastness, can reach the color fastness testing standard such as national standard, American Standard, Europe superscript.Test result indicates that prepared by the present invention
Artificial ox bone button surface effect it is similar to natural ox bone button, and color fastness is more than 4 grades.
Brief description of the drawings
Fig. 1 is the outside drawing of artificial ox bone resin button prepared by embodiment 1；
Fig. 2 is the outside drawing of natural ox bone button；
Fig. 3 is the outside drawing with the artificial ox bone button for imitating old effect after dyeing prepared by embodiment 2.
Embodiment
In order to further appreciate that the present invention, the preferred embodiments of the invention are described with reference to embodiment, but
It is it should be appreciated that these descriptions are simply for further explanation the features and advantages of the present invention rather than to patent requirements of the present invention
Limitation.
All raw materials of the present invention, are not particularly limited its source, commercially buying or according to people in the art
Known to member prepared by conventional method.
All raw materials of the present invention, are not particularly limited its purity, pure present invention preferably employs analyzing.
The invention discloses a kind of mixed slurry for being used to manufacture artificial ox bone button, it is characterised in that including：Slurry A
With slurry B；
The slurry A is：
The slurry B is：
In the slurry A of mixed slurry of the present invention, the addition of the unsaturated polyester resin is preferably 20~100 weights
Part, more preferably 30~90 parts by weight, more preferably 40~80 parts by weight are measured, is most preferably 50~70 parts by weight；The colorant
Addition be preferably 5~50 parts by weight, more preferably 10~45 parts by weight, more preferably 15~40 parts by weight, be most preferably
20~30 parts by weight；The addition of the accelerating agent is preferably 0.2~2 parts by weight, more preferably 0.4~1.7 parts by weight, more excellent
Elect 0.5~1.5 parts by weight as, be most preferably 0.8~1.2 parts by weight；The addition of the initiator is preferably 0.4~2 weight
Part, more preferably 0.5~1.7 parts by weight, more preferably 0.7~1.5 parts by weight, are most preferably 1.0~1.2 parts by weight.
In the slurry B of mixed slurry of the present invention, the addition of the unsaturated polyester resin is preferably 800~1200
Parts by weight, more preferably 850~1150 parts by weight, more preferably 900~1100 parts by weight, are most preferably 950~1050 weight
Part；The addition of the mill base is preferably 1.0~8.0 parts by weight, more preferably 2.0~7.0 parts by weight, more preferably 3.0~
6.0 parts by weight, are most preferably 4.0~5.0 parts by weight；The addition of the solubility acinous filler is preferably 5.0~50 weights
Part, more preferably 10~45 parts by weight, more preferably 20~40 parts by weight are measured, is most preferably 25~35 parts by weight；The benzene second
The addition of alkene is preferably 5.0~80 parts by weight, more preferably 10~70 parts by weight, more preferably 20~60 parts by weight, optimal
Elect 30~50 parts by weight as；The addition of the accelerating agent is preferably 2.0~20 parts by weight, more preferably 4.0~17 parts by weight,
More preferably 5.0~15 parts by weight, are most preferably 8.0~12 parts by weight；The addition of the initiator is preferably 4.0~20 weights
Part, more preferably 5.0~17 parts by weight, more preferably 7.0~15 parts by weight are measured, is most preferably 10~12 parts by weight.
The mass ratio of slurry A and slurry B of the present invention are preferably 1：(10~50), more preferably (15~45), more preferably
(20~40), are most preferably (25~35).
Unsaturated polyester resin of the present invention is preferably that m-phthalate unsaturated polyester resin and/or metaphenylene are unsaturated poly-
Ester resin, more preferably m-phthalate unsaturated polyester resin or metaphenylene unsaturated polyester resin, are most preferably adjacent benzene-type insatiable hunger
And polyester resin；The accelerating agent is preferably cobalt naphthenate and/or cobalt iso-octoate, is more preferably cobalt naphthenate or cobalt iso-octoate,
Most preferably cobalt naphthenate；The initiator is preferably methyl ethyl ketone peroxide and/or cyclohexanone peroxide, is more preferably peroxidating
Methyl ethyl ketone or cyclohexanone peroxide, are most preferably methyl ethyl ketone peroxide.
The present invention especially limits the unsaturated-resin without other, is used to produce with well known to those skilled in the art
The unsaturated polyester resin of button；The type and quantity of the colorant are not particularly limited in the present invention, with this area skill
It is used for the colorant for producing button known to art personnel, those skilled in the art can be according to outside practical condition, button
See requirement and quality control makes choice and arranges in pairs or groups, the present invention is preferably titanium dioxide and hybrid pigment；The present invention is to mixing face
Material is not particularly limited, with the pigment such as red, blueness or black well known to those skilled in the art for being used to produce button,
Those skilled in the art can make choice and arrange in pairs or groups according to practical condition, button appearance requirement and quality control.This
The type and quantity of the mill base are not particularly limited in invention, with the color well known to those skilled in the art for being used to produce button
Slurry, those skilled in the art can be made choice according to practical condition, button appearance requirement and quality control and
Collocation；The present invention especially limits the soluble acinous filler without other, with well known to those skilled in the art solvable
Property acinous filler, solubility acinous filler of the present invention is preferably wax powder, urea-formaldehyde moulding powder, microballon, young white sugar and essence
One or more in thin salt, more preferably wax powder, microballon, young white sugar or fine salt, are most preferably wax powder, microballon or essence
Thin salt.
The present invention, can be in follow-up throwing using soluble acinous filler, as water-soluble particulate material
Dissolved in light water treatment procedure, button surface is formed pore, and then form Os Bovis seu Bubali drying on finished product button surface
The effect of osteoporosis afterwards, the mixed slurry arranged in pairs or groups in conjunction with above-mentioned specific components, finally obtain the fine linear strips such as silk
Line, the bone line texture of indistinct, soft, fine and smooth and orderly natural ox bone.
The present invention provides a kind of preparation method of artificial ox bone button, it is characterised in that comprises the following steps：
A after) being mixed unsaturated polyester resin, colorant, accelerating agent and initiator, base slurry A is obtained；The system
The density of base slurry A is 1.25~5g/mL；
Unsaturated polyester resin, mill base, soluble acinous filler, accelerating agent, styrene and initiator are mixed
Afterwards, base slurry B is obtained；The viscosity of the base slurry B is 300~900mPas；
B) by above-mentioned steps A) obtained base slurry A and base slurry B after blank-making technology, obtain artificial ox bone knob
Button.
In the above-mentioned preparation method of the present invention, raw materials used optimum principle and addition with it is preferred in foregoing mixed slurry
Principle is consistent with addition, and this is no longer going to repeat them.
After the present invention is first mixed unsaturated polyester resin, colorant, accelerating agent and initiator, base slurry is obtained
A；After unsaturated polyester resin, mill base, soluble acinous filler, accelerating agent, styrene and initiator are mixed, obtain
Base slurry B.The density of the base slurry A is preferably 1.25~5g/mL, more preferably 1.5~4.5g/mL, more preferably
2.0~4.0g/mL, is most preferably 2.5~3.5g/mL；The viscosity of the base slurry B is preferably 300~900mPas, more
Preferably 330~870mPas, more preferably 350~850mPas, more preferably 375~825mPas, are most preferably
420~780mPas.
The condition of the mixing is not particularly limited in the present invention, and button blank is prepared with well known to those skilled in the art
Mixing condition；The mode of the mixing is not particularly limited in the present invention, with mixing well known to those skilled in the art
Mode, is preferably stirred；The equipment of the mixing is not particularly limited in the present invention, ripe with those skilled in the art
The mixing apparatus known；The charging sequence of the mixing is not particularly limited in the present invention, with known to those skilled in the art
The charging sequence for preparing button blank.
The optimization explanation specifically carried out in the following slurries to base of the present invention into component selections and proportioning, the parts by weight are equal
Refer in base slurry, each composition quality accounts for the percentage of the base slurry gross mass.
In base slurry B of the present invention, the parts by weight of the styrene are preferably 5.0~80 parts by weight, more preferably
10~70 parts by weight；More preferably 15~60 parts by weight, are most preferably 20~50 parts by weight.
The present invention controls viscosity number by adjusting the ratio of styrene in base slurry B, makes gluing for base slurry B
Degree be preferably controlled in a certain range so that its in follow-up blank-making technology, can evenly laid out and level it is soft.The present invention
According to the colour match of natural ox bone and the thickness of level that need to be copied, the mill base of preferably different colors adjusts slurry
The specific color of the mill base is not particularly limited in color, the present invention, and those skilled in the art can be according to actual production feelings
Condition makes choice and matches, colour match of the present invention preferably according to clothes or sample.
The base slurry A and base slurry B that the present invention obtains above-mentioned steps obtain artificial ox bone after blank-making technology
Button.
In base slurry A and B of the present invention, the accelerating agent is respectively preferably cobalt naphthenate and/or cobalt iso-octoate, more
Preferably cobalt naphthenate；The parts by weight of the cobalt naphthenate are respectively preferably 2.0~20, more preferably 4.0~17 parts by weight, more
Preferably 5.0~15 parts by weight, are most preferably 8.0~12 parts by weight.
The present invention controls each base slurry in blank-making technology by adjusting the ratio of accelerating agent in base slurry A and B
In gel time, the gel time of the base slurry A is preferably 3~7min, more preferably 3.5min~6.5min, it is more excellent
Elect 4min~6min as, be most preferably 4.5min~5.5min；The gel time of the base slurry B is 3~10min, more excellent
Elect 4min~9min as, more preferably 5min~8min, be most preferably 6min~7min.
Blank-making technology of the present invention is preferably to centrifuge blank-making technology, similarity of the present invention for raising to natural ox bone,
It is preferred that specific blank-making technology carries out according to the following steps：
B1 the base slurry B that above-mentioned steps obtain first) is laid in centrifuge inner wall, centrifugation curing is carried out, incomplete
During curing, base slurry A is sprayed at the above-mentioned base slurry B surface not being fully cured, then artificial ox is obtained after being cured
Bone button blank；
B2 the artificial ox bone button blank that above-mentioned steps obtain) is obtained into artificial ox bone button after system buckles technique.
The base slurry B that above-mentioned steps obtain first is laid in centrifuge inner wall by the present invention first, after tiling uniformly, is opened
Open centrifuge and carry out centrifugation curing, when base slurry B is not fully cured, base slurry A is sprayed at and above-mentioned is not fully cured
Base slurry B surface, then obtain artificial ox bone button blank after carrying out integrally curing；Rotating speed of the present invention to the centrifuge
It is not particularly limited, it is of the present invention with the rotating speed of centrifuge in button blank-making technology well known to those skilled in the art
The rotating speed of centrifuge is preferably 60~180 turns/min, more preferably 80~160 turns/min, is most preferably 100~150 turns/min.
Curing of the present invention, i.e. base slurry integrally centrifuge curing, according to production concrete condition, be preferably divided into gelatinization and
Two steps of solidify afterwards, the concept of the gelatinization and solidify afterwards is not particularly limited in the present invention, ripe with those skilled in the art
The resin gelatinization known and the concept of solidify afterwards；After gelatinization of the present invention refers to that base slurry adds initiator, by liquid
Process of the form to molding colloidal state；Solidify afterwards of the present invention refer to base slurry by molding colloid form to hard
Solid state process.
The time of the present invention not being fully cured, is the time of incomplete gelatinization, and the present invention is to the incomplete glue
The time of change is not particularly limited, and those skilled in the art can be according to practical condition, button appearance requirement and quality
It is required that carrying out accommodation, the time of incomplete gelatinization of the present invention is preferably 2~8min, more preferably 2~7min, most
Preferably 3~6min.The overall centrifugation cured time is not particularly limited in the present invention, and those skilled in the art can root
Accommodation, the overall centrifugation cured time are carried out according to practical condition, button appearance requirement and quality requirement
Preferably 2~10min, more preferably 3~8min, are most preferably 4~7min.
The present invention sprays, the sprinkling is not particularly limited in the present invention, with those skilled in the art the sprinkling
Well known spray pattern, for the present invention to improve appearance, the sprinkling is preferably point-like injection；In the effect of centrifugal force
Under pull into hachure；The equipment of the sprinkling is not particularly limited in the present invention, is set with sprinkling well known to those skilled in the art
Standby, the device of sprinkling of the present invention is preferably air pressure spray gun, more preferably automatic air pressure spray gun；The present invention is to the gas
The pressure condition such as spray gun pressure and feeding coal is not particularly limited, and those skilled in the art can be according to practical condition, button
Appearance requirement and product quality carry out accommodation.
The present invention when base slurry B is not fully cured, with automatic air pressure spray gun, uniformly starch on stroke frame by sprinkling base
Expect A, base slurry A is sprayed under pneumatic pressure in wire, uniformly penetrating is into base slurry B, so as to form the fine line such as silk
Property striped, it is indistinct, soft, fine and smooth, orderly, enable the present invention manually imitate natural ox bone unsaturated polyester resin button make
The bone line texture of natural ox bone.
The present invention obtains artificial ox bone then by the artificial ox bone button blank that above-mentioned steps obtain after system buckles technique
Button.
The system button technique and follow-up production technology is not particularly limited in the present invention, and those skilled in the art can be with
Accommodation is carried out according to practical condition, product quality and the pattern of button and other requirements.The present invention is in institute
State after base slurry A and B be solidified into plate on centrifuge, plate removed from centrifuge after hardness reaches 30-40 Pasteur,
The blank of specification needed for clicking machine is washed into.Again after the button treatment process processed such as overcure, cutting, polishing, finished synthetic is formed
Ox bone button.
The relevant devices such as base, hardening, cutting or polishing that rush are not particularly limited in the present invention, with art technology
Above-mentioned process equipment in button production known to personnel, the base that rushes is preferably clicking machine, and the cutting is preferably to swash
Light cutting machine, the cutting are preferably cutter, and the polishing is preferably water roll cast ray machine.
Artificial ox bone button blank is further preferably cut into other shapes of craftwork by the present invention.
The present invention also provides a kind of artificial ox bone button, by unsaturated polyester resin, colorant and soluble acinous filler
Obtained after preparation.The present invention uses unsaturated polyester resin, colorant and soluble acinous filler as main material, by toning
It is prepared with after blank-making technology.
The artificial ox bone button that the present invention is obtained by above-mentioned steps, the present invention is using soluble acinous filler, rear
Dissolved in continuous polishing water treatment procedure, button surface is formed pore, and then ox bone is formed on finished product button surface
The effect of osteoporosis after head is dry, further by controlling in viscosity, density and gel time, especially blank-making technology
Addition sequence and add the time, in conjunction with the mixed slurry of above-mentioned specific components collocation, finally obtain with fine such as silk
Linear striped is indistinct, soft, fine and smooth and orderly such as the artificial ox bone button of natural ox bone bone line texture.
Artificial ox bone button prepared by the present invention, which has been selected, to be derived from a wealth of sources and cheap unsaturated polyester resin material,
It compensate for the deficiency on ox bone material source, and it is controllable to dye rear stability, effectively overcome natural ox bone due to the stone age not
Together, the degree of osteoporosis it is different and caused by uniformity is poor and dyeing after there is the problem of aberration.In addition, present invention system
Standby artificial ox bone button has preferable dry, Washing or flatiron color fastness, can reach the colors such as national standard, American Standard, Europe superscript
Fastness testing standard.
The artificial ox bone resin button obtained to the present invention by above-mentioned steps carries out color fastness detection, with reference to national standard, U.S.
The color fastness testing standard such as mark, Europe superscript, with 105 105 C06 of A02, ISO of ISO, ISO 105D01, ISO 105 X12, ISO
105 E04 and 105 E01 of ISO are examination criteria.Test result indicates that the present invention prepare artificial ox bone button have compared with
Good color fastness.
Appearance contrasting detection is carried out to artificial ox bone button prepared by the present invention again.Test result indicates that prepared by the present invention
Artificial ox bone button have with natural ox bone button similar in surface effect.
For a further understanding of the present invention, with reference to embodiment to artificial ox bone button provided by the invention and its preparation
Method illustrates, and protection scope of the present invention is not limited by the following examples.
Embodiment 1
First, 50g unsaturated polyester resins, 25g titanium dioxides, 2g cobalt naphthenates and 2g methyl ethyl ketone peroxides are stirred
After mixing, the base slurry A that density is 3.65g/mL is obtained；
1000g unsaturated polyester resins, 0.5g are starched in vain, the yellow slurries of 0.02g, 0.01g palm fibres slurry, 40g solubility acinous are filled out
Material, 8g cobalt naphthenates are stirred mixing, and add 40g styrene after being warming up to 30 DEG C, add 10g methyl ethyl ketone peroxides
Afterwards, the base slurry B that viscosity number is 638mPas is obtained；
Then, base slurry B above-mentioned steps obtained is evenly laid out on centrifuge inner wall, opens centrifuge speed and is
After 60 turns/min, after 2 minutes, do not wait base slurry B be fully cured, with automatic air pressure spray gun on stroke frame at the uniform velocity back and forth
Base slurry A is sprayed, base slurry A is progressively sprayed in wire under pneumatic pressure, uniformly penetrating completes spray into base slurry B
Continue to cure 3 minutes after spilling, plate is removed from centrifuge after slurry reaches 30 degree with durometer test hardness, with punching
Base machine is washed into the blank of required specification.The button process processed such as the hardening Jing Guo subsequent handling, cutting, polishing again, obtains artificial ox bone
Button.
Above-mentioned steps are prepared with artificial imitative natural ox bone button to observe, referring to Fig. 1, Fig. 1 makes for embodiment 1
The outside drawing of standby artificial ox bone button.Referring back to Fig. 2, Fig. 2 is the outside drawing of natural ox bone button.Can by Fig. 1 and Fig. 2 contrasts
Know, artificial ox bone resin button prepared by the above method of the present invention that there is the fine linear striped such as silk, it is indistinct, soft, fine and smooth
It is and orderly such as natural ox bone bone line texture, and the effect such as osteoporosis after the drying of natural Os Bovis seu Bubali.
The artificial ox bone resin button obtained to the present invention by above-mentioned steps carries out color fastness detection, with reference to foregoing color jail
Testing standard is spent, for experimental result referring to table 1, table 1 is artificial button resin button color fastness prepared by the embodiment of the present invention 1~3
Test result.
As can be seen from Table 1, the artificial ox bone resin button that prepared by the embodiment of the present invention 1 is detected in above-mentioned all standard
In, color fastness is more than 4 grades.
Embodiment 2
First, 50g unsaturated polyester resins, 20g colorants, 1.8g cobalt naphthenates and 1.8g methyl ethyl ketone peroxides are stirred
After mixing mixing, the base slurry A that density is 3.26g/ml is obtained；
1000g unsaturated polyester resins, 0.5g are starched in vain, the red slurries of 2g, the blue slurries of 2g, 2g black wash, 40g solubility acinous are filled out
Material, 8g cobalt naphthenates are stirred mixing, and add 50g styrene after being warming up to 30 DEG C, add 10g methyl ethyl ketone peroxides
Afterwards, the base slurry B that viscosity number is 553mPas is obtained.
Then, base slurry B above-mentioned steps obtained is evenly laid out on centrifuge inner wall, opens centrifuge speed and is
After 120 turns/min, after 2 minutes, do not wait base slurry B be fully cured, with automatic air pressure spray gun on stroke frame it is at the uniform velocity anti-back and forth
Base slurry A is sprayed again, base slurry A is progressively sprayed in wire under pneumatic pressure, and uniformly penetrating is completed into base slurry B
Continue to cure 6 minutes after sprinkling, plate is removed from centrifuge after slurry reaches 40 degree with durometer test hardness, is used
Clicking machine is washed into the blank of required specification.
By blank after the button process processed such as the hardening, cutting, polishing of subsequent handling, then process dyeing, water mill are had
There is the artificial ox bone button of imitative old effect.
Above-mentioned steps are prepared with artificial imitative natural ox bone button to observe, referring to Fig. 3, Fig. 3 makes for embodiment 2
There is the outside drawing for the artificial ox bone button for imitating old effect after standby dyeing.
After the dyeing that above-mentioned steps obtain there is the artificial ox bone resin button for imitating old effect to carry out color the present invention
Fastness detects, and with reference to foregoing color fastness testing standard, for experimental result referring to table 1, table 1 is people prepared by the embodiment of the present invention 1~3
Make button resin button color fastness test result.
As can be seen from Table 1, the artificial ox bone resin button that prepared by the embodiment of the present invention 2 is detected in above-mentioned all standard
In, because button surface is dyed and water mill is handled, except dry-cleaning color fastness is in addition to 3.5 grades, other color fastness are more than 4 grades.
Embodiment 3
First, 50g unsaturated polyester resins, 20g titanium dioxides, 1.8g cobalt naphthenates and 2.0g methyl ethyl ketone peroxides are carried out
After being stirred, the base slurry A that density is 3.20g/mL is obtained；
1000g unsaturated polyester resins, 0.5g are starched in vain, the yellow slurries of 0.02g, 0.01g palm fibres slurry, 40g solubility acinous are filled out
Material, 8g cobalt naphthenates are stirred mixing, and add 20g styrene after being warming up to 30 DEG C, add 10g methyl ethyl ketone peroxides
Afterwards, the base slurry B that viscosity number is 780mPas is obtained；
Then, base slurry B above-mentioned steps obtained is evenly laid out on centrifuge inner wall, opens centrifuge speed and is
After 60 turns/min, after 2 minutes, do not wait base slurry B be fully cured, with automatic air pressure spray gun on stroke frame at the uniform velocity back and forth
Base slurry A is sprayed, base slurry A is progressively sprayed in wire under pneumatic pressure, uniformly penetrating completes spray into base slurry B
Continue to cure 3 minutes after spilling, plate is removed from centrifuge after slurry reaches 35 degree with durometer test hardness, with punching
Base machine is washed into the blank of required specification.The button process processed such as the hardening Jing Guo subsequent handling, cutting, polishing again, obtains artificial ox bone
Button.
The artificial ox bone resin button obtained to the present invention by above-mentioned steps carries out color fastness detection, with reference to foregoing color jail
Testing standard is spent, for experimental result referring to table 1, table 1 is artificial button resin button color fastness prepared by the embodiment of the present invention 1~3
Test result.
As can be seen from Table 1, the artificial ox bone resin button that prepared by the embodiment of the present invention 3 is detected in above-mentioned all standard
In, color fastness is more than 4 grades.
Artificial button resin button color fastness test result prepared by 1 embodiment of the present invention 1~3 of table
A kind of artificial ox bone button provided by the present invention and preparation method thereof is described in detail above.Herein
Apply a specific example to be set forth the principle of the present invention and embodiment, the explanation of above example is only intended to side
Assistant solves the method and its core concept of the present invention.It should be pointed out that for those skilled in the art, not
On the premise of departing from the principle of the invention, some improvement and modification can also be carried out to the present invention, these are improved and modification is also fallen into
In the protection domain of the claims in the present invention.
Claims (7)
- A kind of 1. mixed slurry for being used to manufacture artificial ox bone button, it is characterised in that including：Slurry A and slurry B；The slurry A is：The density of the base slurry A is 1.25~5g/mL；The slurry B is：The acinous filler is the one or more in wax powder, urea-formaldehyde moulding powder, young white sugar and fine salt；The viscosity of the base slurry B is 300~900mPas.
- 2. mixed slurry according to claim 1, it is characterised in that the mass ratio of the slurry A and slurry B are 1：(10 ~50).
- 3. mixed slurry according to claim 1, it is characterised in that the accelerating agent is cobalt naphthenate and/or isooctyl acid Cobalt；The initiator is methyl ethyl ketone peroxide and/or cyclohexanone peroxide；The unsaturated polyester resin is m-phthalate unsaturated polyester resin and/or metaphenylene unsaturated polyester resin.
- 4. a kind of mixed slurry using described in claims 1 to 3 any one prepares the method for artificial ox bone button, its feature It is, comprises the following steps：A after) being mixed unsaturated polyester resin, colorant, accelerating agent and initiator, base slurry A is obtained；The base slurry The density for expecting A is 1.25~5g/mL；After unsaturated polyester resin, mill base, acinous filler, accelerating agent, styrene and initiator are mixed, base is obtained Slurry B；The viscosity of the base slurry B is 300~900mPas；The acinous filler is the one or more in wax powder, urea-formaldehyde moulding powder, young white sugar and fine salt；B) by above-mentioned steps A) obtained base slurry A and base slurry B after blank-making technology, obtain artificial ox bone button；The blank-making technology is centrifugation blank-making technology.
- 5. preparation method according to claim 4, it is characterised in that in the blank-making technology, the glue of the base slurry A The change time is 3~7min；The gel time of the base slurry B is 3~10min.
- 6. preparation method according to claim 4, it is characterised in that the step B) be specially：B1) by step A) obtained base slurry B is first laid in centrifuge inner wall, centrifugation curing is carried out, when not being fully cured, Base slurry A is sprayed at the above-mentioned base slurry B surface not being fully cured, then artificial ox bone button base is obtained after being cured Material；B2 the artificial ox bone button blank that above-mentioned steps obtain) is obtained into artificial ox bone button after system buckles technique.
- 7. preparation method according to claim 6, it is characterised in that the sprinkling is sprayed for wire；The dress of the sprinkling It is set to air pressure spray gun.
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| CN201510643846.1A CN105131194B (en) | 2015-09-30 | 2015-09-30 | A kind of artificial ox bone button and preparation method thereof |
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| CN201510643846.1A CN105131194B (en) | 2015-09-30 | 2015-09-30 | A kind of artificial ox bone button and preparation method thereof |
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| CN105131194B true CN105131194B (en) | 2018-04-17 |
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| CN107637923B (en) * | 2016-07-21 | 2020-08-18 | 浙江伟星实业发展股份有限公司 | Fruit button with crack effect and preparation process thereof |
| CN106473326B (en) * | 2016-10-18 | 2019-08-13 | 大隅洋 | Lauxite button and preparation method thereof |
| CN110754741B (en) * | 2019-11-01 | 2022-06-14 | 深圳联达钮扣有限公司 | Manufacturing equipment for manufacturing novel internally-carved button and corresponding manufacturing method |
| CN113621224A (en) * | 2021-09-03 | 2021-11-09 | 嘉兴赵氏钮扣股份有限公司 | Adhesive and button waste recycling process with same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4292218A (en) * | 1978-12-29 | 1981-09-29 | Giovanni Corrado | Low viscosity unsaturated polyester resins |
| CN101953543A (en) * | 2010-09-06 | 2011-01-26 | 俞善锋 | Luminous button and production technology thereof |
| CN102389185A (en) * | 2011-07-27 | 2012-03-28 | 广东溢达纺织有限公司 | Unsaturated polyester resin button and preparation method thereof |
-
2015
- 2015-09-30 CN CN201510643846.1A patent/CN105131194B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4292218A (en) * | 1978-12-29 | 1981-09-29 | Giovanni Corrado | Low viscosity unsaturated polyester resins |
| CN101953543A (en) * | 2010-09-06 | 2011-01-26 | 俞善锋 | Luminous button and production technology thereof |
| CN102389185A (en) * | 2011-07-27 | 2012-03-28 | 广东溢达纺织有限公司 | Unsaturated polyester resin button and preparation method thereof |
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| CN105131194A (en) | 2015-12-09 |
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