CN105131194A - Manmade beef bone button and preparing method thereof - Google Patents
Manmade beef bone button and preparing method thereof Download PDFInfo
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- CN105131194A CN105131194A CN201510643846.1A CN201510643846A CN105131194A CN 105131194 A CN105131194 A CN 105131194A CN 201510643846 A CN201510643846 A CN 201510643846A CN 105131194 A CN105131194 A CN 105131194A
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Abstract
The invention provides mixed sizing for preparing a manmade beef bone button. The mixed sizing comprises sizing A and sizing B. The sizing A comprises, by weight, 20-100 parts of unsaturated polyester resin, 5-50 parts of pigment, 0.2-2 parts of accelerant and 0.4-2 parts of initiator. The sizing B comprises, by weight, 800-1200 parts of unsaturated polyester resin, 1.0-8.0 parts of pigment, 5.0-50 parts of soluble fine granular packing, 5.0-80 parts of styrene, 2.0-20 parts of accelerant and 4.0-20 parts of initiator. The prepared manmade beef bone button is made of the unsaturated polyester resin material which is wide in source and low in price, the manmade beef bone button has the bone stripe texture and the bone age texture like natural beef bone buttons, and the stability is controllable after the button is dyed.
Description
Technical field
The invention belongs to garment production technical field, particularly relate to a kind of artificial ox bone button and preparation method thereof.
Background technology
Button is exactly fastener connected for the both sides hem on clothes, its initial effect is used to the left front of connecting clothing, now developing into gradually and have more artistry and ornamental except its original function of maintenance, is also the representative of the personalized and multifunction of dress ornament.
Button, by the classification of its material, can be divided into natural class, chemical and other materials, this wherein natural class button be divided into again bone to buckle (common are ox horn to buckle), shell button, coconut button, wood button, bamboo button, fruit button, shell button etc.In numerous natural class button, bone button, because conventional ox bone makes, is commonly called ox bone button, common are ox horn button etc.It is a kind of very ancient button, bone is from natural thing, the soft exquisiteness of striped, in rice white or creamy white under normal condition, there is the features such as natural soft color and luster, texture elegance and pseudo-classic sclerotin sense, all give out noble tempting breath from the inside to surface, and people again usually ox bone together with cultural contacts, so its characteristic can be shown in natural class button, set off the high-end quality of dress ornament, make ox bone button always like by masses.
Have the various features such as noble fashion just because of ox bone fastener, be the first-selection collocation of the especially high-end dress ornament of Clothing Industry always, the button that a lot of famous foreign brand and domestic high-grade clothing all adopt ox bone to make.But the material life requirement day by day improved along with people, expedite the emergence of the development in pluralism of dress ornament commodity, and then also driven the high demand of button industry and day by day fierce market competition, but the inherent defect of the natural ox bone button also development limiting natural ox bone button all the more.
First, though natural ox bone resource is not rare, but be difficult to collect, thus expensive; Secondly, natural ox bone color is single, the color of clothes though arrange in pairs or groups after the surface color of padding process reform ox bone button can be adopted, but there is larger drawback simultaneously, because natural ox bone exists individuality difference, and the bone that the stone age is different, its osteoporotic degree is different, so the button surface unity made with natural ox bone is poor.Again, the surface color of natural ox bone button can by dyeing or colouring of spraying paint, but due to individual difference, be easy to after dyeing occur aberration.After dyeing, the colour fastness of product also has a certain distance with domestic or international standard simultaneously, dry, Washing or press colour fastness and all can only reach 3.5 grades, and the staining that may there is different grades to high-grade clothing moves dye phenomenon.Therefore, the above-mentioned shortcoming of natural ox bone button all constrains development and the diversification application of ox bone button.
In view of this, how to find a kind of artificial imitative natural ox bone with natural ox bone button gloss and texture feature to buckle, can make up again the deficiency in above-mentioned natural ox bone material, be one of problem demanding prompt solution in button making field simultaneously always.
Summary of the invention
In view of this, the technical problem to be solved in the present invention is to provide a kind of artificial ox bone button and preparation method thereof, artificial imitative natural ox bone button prepared by method provided by the invention, there is preferably dry, Washing or flatiron colour fastness, also there is bone line texture and the stone age texture of natural ox bone button simultaneously.
The invention discloses a kind of mixed slurry for the manufacture of artificial ox bone button, it is characterized in that, comprising: slurry A and slurry B;
Described slurry A is:
Described slurry B is:
Preferably, the mass ratio of described slurry A and slurry B is 1:(10 ~ 50).
Preferably, described promotor is cobalt naphthenate and/or cobalt iso-octoate;
Described initiator is methylethyl ketone peroxide and/or cyclohexanone peroxide;
Described unsaturated polyester resin is adjacent benzene-type unsaturated polyester resin and/or metaphenylene unsaturated polyester resin.
Preferably, described solubility fine-grannular filler is one or more in wax powder, urea-formaldehyde moulding powder, microballon, young white sugar and meticulous salt.
The invention provides a kind of preparation method of artificial ox bone button, it is characterized in that, comprise the following steps:
A), after unsaturated polyester resin, colorant, promotor and initiator being mixed, base slurry A is obtained; The density of described base slurry A is 1.25 ~ 5g/mL;
After unsaturated polyester resin, mill base, solubility fine-grannular filler, promotor, vinylbenzene and initiator being mixed, obtain base slurry B; The viscosity of described base slurry B is 300 ~ 900mPas;
B) by above-mentioned steps A) the base slurry A that obtains and base slurry B after blank-making technology, obtain artificial ox bone button.
Preferably, in described blank-making technology, the gel time of described base slurry A is 3 ~ 7min;
The gel time of described base slurry B is 3 ~ 10min.
Preferably, described blank-making technology is centrifugal blank-making technology.
Preferably, described step B) be specially:
B1) by steps A) the base slurry B that obtains first is laid in whizzer inwall, carry out centrifugal solidification, when not solidifying completely, base slurry A being sprayed at above-mentioned not completely crued base slurry B surface, then after being cured, obtaining artificial ox bone button blank;
B2) artificial ox bone button blank above-mentioned steps obtained, after system buckles technique, obtains artificial ox bone button.
Preferably, described sprinkling is that wire is sprayed; The device of described sprinkling is air pressure spray gun.
Present invention also offers a kind of artificial ox bone button, it is characterized in that, obtained after preparation by unsaturated polyester resin, colorant and solubility fine-grannular filler.
The invention provides a kind of mixed slurry for the manufacture of artificial ox bone button, comprising: slurry A and slurry B; Described slurry A is the unsaturated polyester resin of 20 ~ 100 weight parts, the colorant of 5 ~ 50 weight parts, the promotor of 0.2 ~ 2 weight part, the initiator of 0.4 ~ 2 weight part; Described slurry B is the unsaturated polyester resin of 800 ~ 1200 weight parts, the mill base of 1.0 ~ 8.0 weight parts, the solubility fine-grannular filler of 5.0 ~ 50 weight parts, the vinylbenzene of 5.0 ~ 80 weight parts, the promotor of 2.0 ~ 20 weight parts, the initiator of 4.0 ~ 20 weight parts.Present invention also offers a kind of preparation method of artificial ox bone button, it is characterized in that, comprise the following steps, after first unsaturated polyester resin, colorant, promotor and initiator being mixed, obtain base slurry A; The density of described base slurry A is 1.25 ~ 5g/mL; After unsaturated polyester resin, mill base, solubility fine-grannular filler, promotor, vinylbenzene and initiator being mixed, obtain base slurry B; The viscosity of described base slurry B is 300 ~ 900mPas; Base slurry A above-mentioned steps obtained again and base slurry B, after blank-making technology, obtains artificial ox bone button.
Compared with prior art, present invention employs the mixed slurry comprising unsaturated polyester resin, colorant and solubility fine-grannular filler, by controlling viscosity and blank-making technology, finally obtaining artificial ox bone button, be i.e. artificial imitative natural ox bone resin button.Artificial ox bone button prepared by the present invention has selected wide material sources and cheap unsaturated polyester resin material, compensate for the deficiency on ox bone material source, also there is the bone line texture as natural ox bone button and stone age texture, and dyeing rear stability is controlled, effectively overcome natural ox bone due to the stone age different, osteoporotic degree is different and the unity that causes is poor and occur the problem of aberration after dyeing.In addition, artificial ox bone button prepared by the present invention has preferably dry, Washing or flatiron colour fastness, can reach the colour fastness testing standards such as GB, American Standard, Europe superscript.Experimental result shows, the surface effect of artificial ox bone button prepared by the present invention is similar to natural ox bone button, and colour fastness is more than 4 grades.
Accompanying drawing explanation
Fig. 1 is the outside drawing of artificial ox bone resin button prepared by embodiment 1;
Fig. 2 is the outside drawing of natural ox bone button;
Fig. 3 is the outside drawing after the dyeing of embodiment 2 preparation with the artificial ox bone button of imitative old effect.
Embodiment
In order to understand the present invention further, below in conjunction with embodiment, the preferred embodiments of the invention are described, but should be appreciated that these describe just as further illustrating the features and advantages of the present invention instead of the restriction to patent requirements of the present invention.
The all raw materials of the present invention, be not particularly limited its source, commercially buy or prepare according to ordinary method well known to those skilled in the art.
The all raw materials of the present invention, be not particularly limited its purity, the present invention preferably adopts analytical pure.
The invention discloses a kind of mixed slurry for the manufacture of artificial ox bone button, it is characterized in that, comprising: slurry A and slurry B;
Described slurry A is:
Described slurry B is:
In the slurry A of mixed slurry of the present invention, the add-on of described unsaturated polyester resin is preferably 20 ~ 100 weight parts, is more preferably 30 ~ 90 weight parts, is more preferably 40 ~ 80 weight parts, most preferably is 50 ~ 70 weight parts; The add-on of described colorant is preferably 5 ~ 50 weight parts, is more preferably 10 ~ 45 weight parts, is more preferably 15 ~ 40 weight parts, most preferably is 20 ~ 30 weight parts; The add-on of described promotor is preferably 0.2 ~ 2 weight part, is more preferably 0.4 ~ 1.7 weight part, is more preferably 0.5 ~ 1.5 weight part, most preferably is 0.8 ~ 1.2 weight part; The add-on of described initiator is preferably 0.4 ~ 2 weight part, is more preferably 0.5 ~ 1.7 weight part, is more preferably 0.7 ~ 1.5 weight part, most preferably is 1.0 ~ 1.2 weight parts.
In the slurry B of mixed slurry of the present invention, the add-on of described unsaturated polyester resin is preferably 800 ~ 1200 weight parts, is more preferably 850 ~ 1150 weight parts, is more preferably 900 ~ 1100 weight parts, most preferably is 950 ~ 1050 weight parts; The add-on of described mill base is preferably 1.0 ~ 8.0 weight parts, is more preferably 2.0 ~ 7.0 weight parts, be more preferably 3.0 ~ 6.0 weight parts, most preferably be 4.0 ~ 5.0 weight parts; The add-on of described solubility fine-grannular filler is preferably 5.0 ~ 50 weight parts, is more preferably 10 ~ 45 weight parts, is more preferably 20 ~ 40 weight parts, most preferably be 25 ~ 35 weight parts; Described cinnamic add-on is preferably 5.0 ~ 80 weight parts, is more preferably 10 ~ 70 weight parts, is more preferably 20 ~ 60 weight parts, most preferably is 30 ~ 50 weight parts; The add-on of described promotor is preferably 2.0 ~ 20 weight parts, is more preferably 4.0 ~ 17 weight parts, is more preferably 5.0 ~ 15 weight parts, most preferably is 8.0 ~ 12 weight parts; The add-on of described initiator is preferably 4.0 ~ 20 weight parts, is more preferably 5.0 ~ 17 weight parts, is more preferably 7.0 ~ 15 weight parts, most preferably is 10 ~ 12 weight parts.
The mass ratio of slurry A of the present invention and slurry B is preferably 1:(10 ~ 50), more preferably (15 ~ 45), more preferably (20 ~ 40), most preferably be (25 ~ 35).
Unsaturated polyester resin of the present invention is preferably adjacent benzene-type unsaturated polyester resin and/or metaphenylene unsaturated polyester resin, is more preferably adjacent benzene-type unsaturated polyester resin or metaphenylene unsaturated polyester resin, most preferably is adjacent benzene-type unsaturated polyester resin; Described promotor is preferably cobalt naphthenate and/or cobalt iso-octoate, is more preferably cobalt naphthenate or cobalt iso-octoate, most preferably is cobalt naphthenate; Described initiator is preferably methylethyl ketone peroxide and/or cyclohexanone peroxide, is more preferably methylethyl ketone peroxide or cyclohexanone peroxide, most preferably is methylethyl ketone peroxide.
The present invention does not have other to limit especially to described unsaturated polyester, with the unsaturated polyester resin for the production of button well known to those skilled in the art; The present invention is not particularly limited the kind of described colorant and quantity, with the colorant for the production of button well known to those skilled in the art, those skilled in the art can carry out selecting and arranging in pairs or groups according to practical condition, button appearance requirement and quality control, and the present invention is preferably titanium dioxide and hybrid pigment; The present invention is not particularly limited hybrid pigment, with pigment such as the redness for the production of button well known to those skilled in the art, blueness or black, those skilled in the art can carry out selecting and arranging in pairs or groups according to practical condition, button appearance requirement and quality control.The present invention is not particularly limited the kind of described mill base and quantity, with the mill base for the production of button well known to those skilled in the art, those skilled in the art can carry out selecting and arranging in pairs or groups according to practical condition, button appearance requirement and quality control; The present invention does not have other to limit especially to described solubility fine-grannular filler, with solubility fine-grannular filler well known to those skilled in the art, solubility fine-grannular filler of the present invention be preferably in wax powder, urea-formaldehyde moulding powder, microballon, young white sugar and meticulous salt one or more, be more preferably wax powder, microballon, young white sugar or meticulous salt, most preferably be wax powder, microballon or meticulous salt.
The present invention adopts solubility fine-grannular filler, be water-soluble particulate material, can dissolve in follow-up polishing water treating processes, button surface is made to form pore, and then after finished product button surface forms Os Bovis seu Bubali drying osteoporotic effect, again in conjunction with the mixed slurry of above-mentioned specific components collocation, finally obtain the meticulous linear striped as silk, the bone line texture of indistinct, soft, fine and smooth and orderly natural ox bone.
The invention provides a kind of preparation method of artificial ox bone button, it is characterized in that, comprise the following steps:
A), after unsaturated polyester resin, colorant, promotor and initiator being mixed, base slurry A is obtained; The density of described base slurry A is 1.25 ~ 5g/mL;
After unsaturated polyester resin, mill base, solubility fine-grannular filler, promotor, vinylbenzene and initiator being mixed, obtain base slurry B; The viscosity of described base slurry B is 300 ~ 900mPas;
B) by above-mentioned steps A) the base slurry A that obtains and base slurry B after blank-making technology, obtain artificial ox bone button.
In the above-mentioned preparation method of the present invention, raw materials used optimum principle and add-on and the optimum principle in aforementioned mixed slurry and add-on all consistent, this is no longer going to repeat them.
After first unsaturated polyester resin, colorant, promotor and initiator mix by the present invention, obtain base slurry A; After unsaturated polyester resin, mill base, solubility fine-grannular filler, promotor, vinylbenzene and initiator being mixed, obtain base slurry B.The density of described base slurry A is preferably 1.25 ~ 5g/mL, is more preferably 1.5 ~ 4.5g/mL, is more preferably 2.0 ~ 4.0g/mL, most preferably be 2.5 ~ 3.5g/mL; The viscosity of described base slurry B is preferably 300 ~ 900mPas, is more preferably 330 ~ 870mPas, is more preferably 350 ~ 850mPas, be more preferably 375 ~ 825mPas, most preferably be 420 ~ 780mPas.
The condition of the present invention to described mixing is not particularly limited, with the mixing condition preparing button blank well known to those skilled in the art; The mode of the present invention to described mixing is not particularly limited, and with hybrid mode well known to those skilled in the art, is preferably uniformly mixed; The equipment of the present invention to described mixing is not particularly limited, with mixing equipment well known to those skilled in the art; The order of addition(of ingredients) of the present invention to described mixing is not particularly limited, with the order of addition(of ingredients) preparing button blank well known to those skilled in the art.
The present invention is following to be illustrated the optimization that one-tenth component selections concrete in base slurry and proportioning are carried out, and described weight part all refers in base slurry, and each composition quality accounts for the per-cent of this base slurry total mass.
In base slurry B of the present invention, described cinnamic weight part is preferably 5.0 ~ 80 weight parts, is more preferably 10 ~ 70 weight parts; Be more preferably 15 ~ 60 weight parts, most preferably be 20 ~ 50 weight parts.
The present invention by regulating cinnamic ratio in base slurry B, and then controls viscosity number, the viscosity of base slurry B is preferably controlled within the specific limits, makes it in follow-up blank-making technology, can evenly tile and level is soft.The present invention is according to the colour match of natural ox bone that need copy and the thickness of level, the mill base of preferred distinct colors is mixed colours to slurry, the concrete color of the present invention to described mill base is not particularly limited, those skilled in the art can carry out selecting and proportioning according to practical condition, and the present invention is preferably according to the colour match of clothes or sample.
The base slurry A that above-mentioned steps obtains by the present invention and base slurry B, after blank-making technology, obtains artificial ox bone button.
In base slurry A and B of the present invention, described promotor is preferably cobalt naphthenate and/or cobalt iso-octoate separately, is more preferably cobalt naphthenate; The weight part of described cobalt naphthenate is preferably 2.0 ~ 20 separately, is more preferably 4.0 ~ 17 weight parts, is more preferably 5.0 ~ 15 weight parts, most preferably be 8.0 ~ 12 weight parts.
The present invention is by regulating the ratio of promotor in base slurry A and B, and then control the gel time of each base slurry in blank-making technology, the gel time of described base slurry A is preferably 3 ~ 7min, be more preferably 3.5min ~ 6.5min, be more preferably 4min ~ 6min, most preferably be 4.5min ~ 5.5min; The gel time of described base slurry B is 3 ~ 10min, is more preferably 4min ~ 9min, is more preferably 5min ~ 8min, most preferably be 6min ~ 7min.
Blank-making technology of the present invention is preferably centrifugal blank-making technology, and the present invention improves the similarity to natural ox bone, and preferably concrete blank-making technology carries out according to the following steps:
B1) base slurry B above-mentioned steps obtained first is laid in whizzer inwall, carry out centrifugal solidification, when not solidifying completely, base slurry A being sprayed at above-mentioned not completely crued base slurry B surface, then after being cured, obtaining artificial ox bone button blank;
B2) artificial ox bone button blank above-mentioned steps obtained, after system buckles technique, obtains artificial ox bone button.
The base slurry B that first above-mentioned steps obtains by the present invention is first laid in whizzer inwall, after tiling evenly, open whizzer and carry out centrifugal solidification, when base slurry B does not solidify completely, base slurry A is sprayed at above-mentioned not completely crued base slurry B surface, then after carrying out integrally curing, obtains artificial ox bone button blank; The rotating speed of the present invention to described whizzer is not particularly limited, with the rotating speed of whizzer in button blank-making technology well known to those skilled in the art, the rotating speed of whizzer of the present invention is preferably 60 ~ 180 turns/min, is more preferably 80 ~ 160 turns/min, most preferably is 100 ~ 150 turns/min.
Solidification of the present invention, the i.e. overall centrifugal solidification of base slurry, according to production particular case, is preferably divided into gel and after fixing two steps, the concept of the present invention to described gel and after fixing is not particularly limited, with the concept of resin gel well known to those skilled in the art and after fixing; After gel of the present invention refers to that base slurry adds initiator, by the process of liquid form to shaping colloidal state; After fixing of the present invention refers to that base slurry is by the process of shaping colloid form to hard solid state.
The not completely crued time of the present invention, namely it is the time of not gel completely, the present invention is not particularly limited the time to described not gel completely, those skilled in the art can carry out accommodation according to practical condition, button appearance requirement and specification of quality, the time of not gel completely of the present invention is preferably 2 ~ 8min, be more preferably 2 ~ 7min, most preferably be 3 ~ 6min.The present invention is not particularly limited the time to the centrifugal solidification of described entirety, those skilled in the art can carry out accommodation according to practical condition, button appearance requirement and specification of quality, the time of the centrifugal solidification of described entirety is preferably 2 ~ 10min, be more preferably 3 ~ 8min, most preferably be 4 ~ 7min.
The present invention, to described sprinkling, namely sprays, and the present invention is not particularly limited described sprinkling, and with spray pattern well known to those skilled in the art, the present invention is for improving appearance effect, and described sprinkling is preferably point-like and sprays; Pull into hachure under the influence of centrifugal force; The equipment of the present invention to described sprinkling is not particularly limited, and with spray appliance well known to those skilled in the art, the device of sprinkling of the present invention is preferably air pressure spray gun, is more preferably automatic air pressure spray gun; The present invention is not particularly limited conditions such as described air pressure spray gun pressure and feeding coals, and those skilled in the art can carry out accommodation according to practical condition, button appearance requirement and quality product.
The present invention is not when base slurry B solidifies completely, on stroke frame, base slurry A is evenly sprayed with automatic air pressure spray gun, make the base slurry A ejection in wire under pneumatic pressure, uniformly penetrating is in base slurry B, thus form the meticulous linear striped as silk, indistinctly, soft, fine and smooth, orderly, enable artificial imitative natural ox bone unsaturated polyester resin button of the present invention make the bone line texture of natural ox bone.
The artificial ox bone button blank that above-mentioned steps obtains by the present invention subsequently, after system buckles technique, obtains artificial ox bone button.
The present invention is not particularly limited described system button technique and follow-up production technique, and those skilled in the art can carry out accommodation according to the pattern of practical condition, quality product and button and other requirements.The present invention, after described base slurry A and B is solidified into sheet material on whizzer, reaches after 30-40 Pasteur until hardness and takes off plate from whizzer, be washed into the blank of required specification with clicking machine.Again after the system button treatment process such as overvulcanization, cutting, polishing, form finished synthetic's ox bone button.
The present invention is all not particularly limited the described relevant devices such as base, sclerosis, cutting or polishing that rush, above-mentioned processing unit in producing with button well known to those skilled in the art, the described base that rushes is preferably clicking machine, described cutting is preferably laser cutting machine, described cutting is preferably cutting machine, and described polishing is preferably water roll cast ray machine.
The present invention is the preferred artwork artificial ox bone button blank being cut into other shape also.
The present invention also provides a kind of artificial ox bone button, is obtained after preparation by unsaturated polyester resin, colorant and solubility fine-grannular filler.The present invention adopts unsaturated polyester resin, colorant and solubility fine-grannular filler to be main raw material, prepares after toning and blank-making technology.
The artificial ox bone button that the present invention obtains through above-mentioned steps, the present invention adopts solubility fine-grannular filler, dissolve in follow-up polishing water treating processes, button surface is made to form pore, and then after finished product button surface forms Os Bovis seu Bubali drying osteoporotic effect, further by controlling viscosity, density and gel time, especially the addition sequence in blank-making technology and joining day, again in conjunction with the mixed slurry of above-mentioned specific components collocation, finally obtain that there is the meticulous linear striped as silk, indistinctly, soft, fine and smooth and the orderly artificial ox bone button as natural ox bone bone line texture.
Artificial ox bone button prepared by the present invention has selected wide material sources and cheap unsaturated polyester resin material, compensate for the deficiency on ox bone material source, and dyeing rear stability is controlled, effectively overcome natural ox bone due to the stone age different, osteoporotic degree is different and the unity that causes is poor and occur the problem of aberration after dyeing.In addition, artificial ox bone button prepared by the present invention has preferably dry, Washing or flatiron colour fastness, can reach the colour fastness testing standards such as GB, American Standard, Europe superscript.
Colour fastness detection is carried out to the artificial ox bone resin button that the present invention obtains through above-mentioned steps, with reference to colour fastness testing standards such as GB, American Standard, Europe superscripts, with ISO105A02, ISO105C06, ISO105D01, ISO105X12, ISO105E04 and ISO105E01 for examination criteria.Experimental result shows, artificial ox bone button prepared by the present invention there is good colour fastness.
Again outward appearance comparison and detection is carried out to artificial ox bone button prepared by the present invention.Experimental result shows, artificial ox bone button prepared by the present invention has the surface effect close with natural ox bone button.
In order to understand the present invention further, be described artificial ox bone button provided by the invention and preparation method thereof below in conjunction with embodiment, protection scope of the present invention is not limited by the following examples.
Embodiment 1
First, after 50g unsaturated polyester resin, 25g titanium dioxide, 2g cobalt naphthenate and 2g methylethyl ketone peroxide being uniformly mixed, obtain the base slurry A that density is 3.65g/mL;
1000g unsaturated polyester resin, 0.5g are starched in vain, 0.02g Huang slurry, 0.01g palm fibre slurry, 40g solubility fine-grannular filler, 8g cobalt naphthenate be uniformly mixed, and add 40g vinylbenzene after being warming up to 30 DEG C, after adding 10g methylethyl ketone peroxide again, obtain the base slurry B that viscosity number is 638mPas;
Then, base slurry B above-mentioned steps obtained evenly is laid on whizzer inwall, opening centrifuge speed is after 60 turns/min, after 2 minutes, base slurry B is not waited to solidify completely, on stroke frame, base slurry A is repeatedly sprayed at the uniform velocity back and forth with automatic air pressure spray gun, base slurry A is progressively sprayed in wire under pneumatic pressure, uniformly penetrating is in base slurry B, complete after spraying and continue solidification 3 minutes, after slurry durometer tested for hardness reaches 30 degree, take off plate from whizzer, be washed into the blank of required specification with clicking machine.Again through the system such as sclerosis, cutting, the polishing button operation of subsequent handling, obtain artificial ox bone button.
Having prepared artificial imitative natural ox bone button to above-mentioned steps to observe, is the outside drawing of artificial ox bone button prepared by embodiment 1 see Fig. 1, Fig. 1.Be the outside drawing of natural ox bone button again see Fig. 2, Fig. 2.Contrasted from Fig. 1 and Fig. 2, artificial ox bone resin button prepared by aforesaid method of the present invention, there is the meticulous linear striped as silk, indistinct, soft, fine and smooth and orderly as natural ox bone bone line texture, and as osteoporotic effect after natural Os Bovis seu Bubali drying.
Carry out colour fastness detection to the artificial ox bone resin button that the present invention obtains through above-mentioned steps, with reference to aforementioned colour fastness testing standard, experimental result is see table 1, and table 1 is artificial button resin button colour fastness test result prepared by the embodiment of the present invention 1 ~ 3.
As can be seen from Table 1, artificial ox bone resin button prepared by the embodiment of the present invention 1 is in above-mentioned all standard detects, and colour fastness is all more than 4 grades.
Embodiment 2
First, after 50g unsaturated polyester resin, 20g colorant, 1.8g cobalt naphthenate and 1.8g methylethyl ketone peroxide being uniformly mixed, obtain the base slurry A that density is 3.26g/ml;
1000g unsaturated polyester resin, 0.5g are starched in vain, the blue slurry of the red slurry of 2g, 2g, 2g black wash, 40g solubility fine-grannular filler, 8g cobalt naphthenate be uniformly mixed, and add 50g vinylbenzene after being warming up to 30 DEG C, after adding 10g methylethyl ketone peroxide again, obtain the base slurry B that viscosity number is 553mPas.
Then, base slurry B above-mentioned steps obtained evenly is laid on whizzer inwall, opening centrifuge speed is after 120 turns/min, after 2 minutes, base slurry B is not waited to solidify completely, on stroke frame, base slurry A is repeatedly sprayed at the uniform velocity back and forth with automatic air pressure spray gun, base slurry A is progressively sprayed in wire under pneumatic pressure, uniformly penetrating is in base slurry B, complete after spraying and continue solidification 6 minutes, after slurry durometer tested for hardness reaches 40 degree, take off plate from whizzer, be washed into the blank of required specification with clicking machine.
By blank after the system such as sclerosis, cutting, the polishing button operation of subsequent handling, then obtain the artificial ox bone button with imitative old effect through dyeing, water mill.
Having prepared artificial imitative natural ox bone button to above-mentioned steps to observe, is the outside drawing after the dyeing of embodiment 2 preparation with the artificial ox bone button of imitative old effect see Fig. 3, Fig. 3.
Artificial ox bone resin button the present invention after the dyeing that above-mentioned steps obtains to imitative old effect carries out colour fastness detection, with reference to aforementioned colour fastness testing standard, experimental result is see table 1, and table 1 is artificial button resin button colour fastness test result prepared by the embodiment of the present invention 1 ~ 3.
As can be seen from Table 1, artificial ox bone resin button prepared by the embodiment of the present invention 2 is in above-mentioned all standard detects, and because of the dyed and water mill process in button surface, except dry-cleaning colour fastness except 3.5 grades, other colour fastness is all more than 4 grades.
Embodiment 3
First, after 50g unsaturated polyester resin, 20g titanium dioxide, 1.8g cobalt naphthenate and 2.0g methylethyl ketone peroxide being uniformly mixed, obtain the base slurry A that density is 3.20g/mL;
1000g unsaturated polyester resin, 0.5g are starched in vain, 0.02g Huang slurry, 0.01g palm fibre slurry, 40g solubility fine-grannular filler, 8g cobalt naphthenate be uniformly mixed, and add 20g vinylbenzene after being warming up to 30 DEG C, after adding 10g methylethyl ketone peroxide again, obtain the base slurry B that viscosity number is 780mPas;
Then, base slurry B above-mentioned steps obtained evenly is laid on whizzer inwall, opening centrifuge speed is after 60 turns/min, after 2 minutes, base slurry B is not waited to solidify completely, on stroke frame, base slurry A is repeatedly sprayed at the uniform velocity back and forth with automatic air pressure spray gun, base slurry A is progressively sprayed in wire under pneumatic pressure, uniformly penetrating is in base slurry B, complete after spraying and continue solidification 3 minutes, after slurry durometer tested for hardness reaches 35 degree, take off plate from whizzer, be washed into the blank of required specification with clicking machine.Again through the system such as sclerosis, cutting, the polishing button operation of subsequent handling, obtain artificial ox bone button.
Carry out colour fastness detection to the artificial ox bone resin button that the present invention obtains through above-mentioned steps, with reference to aforementioned colour fastness testing standard, experimental result is see table 1, and table 1 is artificial button resin button colour fastness test result prepared by the embodiment of the present invention 1 ~ 3.
As can be seen from Table 1, artificial ox bone resin button prepared by the embodiment of the present invention 3 is in above-mentioned all standard detects, and colour fastness is all more than 4 grades.
Artificial button resin button colour fastness test result prepared by table 1 embodiment of the present invention 1 ~ 3
Above artificial ox bone button of one provided by the present invention and preparation method thereof is described in detail.Apply a concrete example herein to set forth principle of the present invention and embodiment, the explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
Claims (10)
1. for the manufacture of a mixed slurry for artificial ox bone button, it is characterized in that, comprising: slurry A and slurry B;
Described slurry A is:
Described slurry B is:
2. mixed slurry according to claim 1, is characterized in that, the mass ratio of described slurry A and slurry B is 1:(10 ~ 50).
3. mixed slurry according to claim 1, is characterized in that, described promotor is cobalt naphthenate and/or cobalt iso-octoate;
Described initiator is methylethyl ketone peroxide and/or cyclohexanone peroxide;
Described unsaturated polyester resin is adjacent benzene-type unsaturated polyester resin and/or metaphenylene unsaturated polyester resin.
4. mixed slurry according to claim 1, is characterized in that, described solubility fine-grannular filler is one or more in wax powder, urea-formaldehyde moulding powder, microballon, young white sugar and meticulous salt.
5. a preparation method for artificial ox bone button, is characterized in that, comprise the following steps:
A), after unsaturated polyester resin, colorant, promotor and initiator being mixed, base slurry A is obtained; The density of described base slurry A is 1.25 ~ 5g/mL;
After unsaturated polyester resin, mill base, solubility fine-grannular filler, promotor, vinylbenzene and initiator being mixed, obtain base slurry B; The viscosity of described base slurry B is 300 ~ 900mPas;
B) by above-mentioned steps A) the base slurry A that obtains and base slurry B after blank-making technology, obtain artificial ox bone button.
6. preparation method according to claim 5, is characterized in that, in described blank-making technology, the gel time of described base slurry A is 3 ~ 7min;
The gel time of described base slurry B is 3 ~ 10min.
7. preparation method according to claim 5, is characterized in that, described blank-making technology is centrifugal blank-making technology.
8. preparation method according to claim 5, is characterized in that, described step B) be specially:
B1) by steps A) the base slurry B that obtains first is laid in whizzer inwall, carry out centrifugal solidification, when not solidifying completely, base slurry A being sprayed at above-mentioned not completely crued base slurry B surface, then after being cured, obtaining artificial ox bone button blank;
B2) artificial ox bone button blank above-mentioned steps obtained, after system buckles technique, obtains artificial ox bone button.
9. preparation method according to claim 8, is characterized in that, described sprinkling is that wire is sprayed; The device of described sprinkling is air pressure spray gun.
10. an artificial ox bone button, is characterized in that, is obtained after preparation by unsaturated polyester resin, colorant and solubility fine-grannular filler.
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| CN201510643846.1A CN105131194B (en) | 2015-09-30 | 2015-09-30 | A kind of artificial ox bone button and preparation method thereof |
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| CN201510643846.1A CN105131194B (en) | 2015-09-30 | 2015-09-30 | A kind of artificial ox bone button and preparation method thereof |
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| CN105131194B CN105131194B (en) | 2018-04-17 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106473326A (en) * | 2016-10-18 | 2017-03-08 | 大隅洋 | Lauxite button and preparation method thereof |
| CN107637923A (en) * | 2016-07-21 | 2018-01-30 | 浙江伟星实业发展股份有限公司 | A kind of fruit button and its preparation technology with crack effect |
| CN110754741A (en) * | 2019-11-01 | 2020-02-07 | 深圳联达钮扣有限公司 | Novel internally-carved button and corresponding manufacturing method and manufacturing equipment |
| CN113621224A (en) * | 2021-09-03 | 2021-11-09 | 嘉兴赵氏钮扣股份有限公司 | Adhesive and button waste recycling process with same |
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| US4292218A (en) * | 1978-12-29 | 1981-09-29 | Giovanni Corrado | Low viscosity unsaturated polyester resins |
| CN101953543A (en) * | 2010-09-06 | 2011-01-26 | 俞善锋 | Luminous button and production technology thereof |
| CN102389185A (en) * | 2011-07-27 | 2012-03-28 | 广东溢达纺织有限公司 | Unsaturated polyester resin button and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US4292218A (en) * | 1978-12-29 | 1981-09-29 | Giovanni Corrado | Low viscosity unsaturated polyester resins |
| CN101953543A (en) * | 2010-09-06 | 2011-01-26 | 俞善锋 | Luminous button and production technology thereof |
| CN102389185A (en) * | 2011-07-27 | 2012-03-28 | 广东溢达纺织有限公司 | Unsaturated polyester resin button and preparation method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107637923A (en) * | 2016-07-21 | 2018-01-30 | 浙江伟星实业发展股份有限公司 | A kind of fruit button and its preparation technology with crack effect |
| CN107637923B (en) * | 2016-07-21 | 2020-08-18 | 浙江伟星实业发展股份有限公司 | Fruit button with crack effect and preparation process thereof |
| CN106473326A (en) * | 2016-10-18 | 2017-03-08 | 大隅洋 | Lauxite button and preparation method thereof |
| CN106473326B (en) * | 2016-10-18 | 2019-08-13 | 大隅洋 | Lauxite button and preparation method thereof |
| CN110754741A (en) * | 2019-11-01 | 2020-02-07 | 深圳联达钮扣有限公司 | Novel internally-carved button and corresponding manufacturing method and manufacturing equipment |
| CN113621224A (en) * | 2021-09-03 | 2021-11-09 | 嘉兴赵氏钮扣股份有限公司 | Adhesive and button waste recycling process with same |
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| Publication number | Publication date |
|---|---|
| CN105131194B (en) | 2018-04-17 |
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