CN110495466A - A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol - Google Patents
A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol Download PDFInfo
- Publication number
- CN110495466A CN110495466A CN201810484425.2A CN201810484425A CN110495466A CN 110495466 A CN110495466 A CN 110495466A CN 201810484425 A CN201810484425 A CN 201810484425A CN 110495466 A CN110495466 A CN 110495466A
- Authority
- CN
- China
- Prior art keywords
- biguanides
- azoles bacterium
- benzene sulfonate
- acyl azanol
- bacterium acyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
- A01N47/44—Guanidine; Derivatives thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal compositions of three octyl benzene sulfonate of fluorine-containing azoles bacterium acyl azanol and biguanides, it includes the effective component being made of fluorine azoles bacterium acyl azanol and three octyl benzene sulfonate of biguanides, the composition includes the effective component being made of fluorine azoles bacterium acyl azanol and three octyl benzene sulfonate of biguanides, and the mass ratio of three octyl benzene sulfonate of fluorine azoles bacterium acyl azanol and biguanides is 20:1~1:20.It is wherein added with suitable agricultural bactericidal agent aid, common disinfectant use in agriculture dosage form is made.The present invention has a higher control efficiency to crop fungal disease, and there are notable synergistic effects between two medicaments；Dosage can be reduced, ecological disruption and environmental pollution is effectively reduced, and crop yield and quality can be improved；Fluorine azoles bacterium acyl azanol and three octyl benzene sulfonate of biguanides belong to low toxicity in the present invention, and to people and animals, beneficial organism, Environmental security；Germ can be delayed to the drug resistance of single medicament.
Description
Technical field
The invention belongs to disinfectant use in agriculture fields, and in particular to a kind of fluorine azoles bacterium acyl azanol and three octyl benzene sulfonic acid of biguanides
The bactericidal composition of salt.
Background technique
Fusarium graminearum (Fusarium graminearum) caused by wheat scab be a kind of pole in Wheat Production
Have menace and propagated disease, widely distributed, Major Wheat planting area nearly all has generation in the world, in weather temperature
And moisten rainy area and be easier to cause to infect and spread between the time, wheat is infected and is extended not only serious after sprawling
The yield of wheat is influenced, and pathogen can excrete poison, such as deoxynivalenol, be difficult to clear up, it can be long-term
It remains in food chain, severe threat is come to the health care belt of humans and animals.In addition, in recent years with the change of tillage method,
By wheat root-rot Bipolaris sacchari (Bipolaris sorokiniana) caused by root rotof flax same serious, disease occurs
It can infect in seedling stage, be easier to occur in the case where rainwater is more, the later period causes dead ears, and complete stool is dead.Currently, in the market
Also lack the wheat breed that there is complete resistance to wheat scab, chemical agriculture is still relied primarily on to the prevention and control of wheat scab
The use of medicine and early prevention have reached prevention and control common recognition substantially between yangtse-huaihe region at present, that is, have seen colored laxative, 7 days laggard
Second of prevention and control of row.And Bipolaris sacchari can cause to infect in early stage, it is essential for being coated processing using seed coat agent
One of preventions, can utmostly mitigate seedling stage infects and forces down pathogen radix.Therefore, how more
On delay wheat scab drug resistance to generate and development, extend the service life of each component in bactericidal composition, while developing small
The effective prevention and control medicament and dosage form of wheat base rot disease and root rot realize economic, efficient, environmental protection, sustainable prevention and control,
As strategic project urgently to be resolved in wheat and Soybean production.
Fluorine azoles bacterium acyl azanol (Pydiflumetofen) category succinate dehydrogenase (succinate dehydrogenase,
SDHI new pyridine acid amide fungicides), its chemical name is 3-(difluoromethyls)-N- methoxyl group -1- methyl-N- [(RS) -
1- methyl -2-(2,4,6- trichlorophenyls) ethyl] pyrazole-4-carboxamide.Molecular formula is C16H16Cl3F2N3O2, boiling point is
557.9 DEG C ± 50.0 DEG C, density is 1.44 ± 0.1 g/cm3。
With wide spectrum, efficient feature, it is suitable for many crops, such as corn, granule cereal, soybean, peanut, rape
Seed, quinoa etc..In the product of all chemical types, fluorine azoles bacterium acyl azanol is to leaf spot and powdery mildew activity highest, to being difficult to
The disease of prevention and treatment, as disease caused by the pathogens such as botrytis (Botrytis spp.), sclerotinite and stick spore bacterium is efficient；Together
When the fungicide prevent and treat also breakthroughly on cereal by sickle-like bacteria (FusariumSpp. disease caused by), such as head blight.
Three octyl benzene sulfonate of biguanides (Iminoctadine trialbesilate) belongs to biguanides fungicide, chemical name
Referred to as 1 ', 1- imino group (octyl methylene) biguanides three (alkyl benzene sulfonate).The main lipoid biology by inhibiting germ
Synthesis, thus inhibit spore germination, germ tube elongation, the formation of attachment spore and mycelia,
Three octyl benzene sulfonate of biguanides is a kind of wide-spectrum bactericide, and local permeability is strong, can prevent powdery mildew, gray mold, climing
Blight and alternaria leaf spot of apple, citrus storage phase disease.
Summary of the invention
It is good that the present invention provides a kind of bactericidal effects, to wheat scab, root rotof flax control efficiency significant synergy
Composition.
The technical solution of the present invention is as follows:
A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol and three octyl benzene sulfonate of biguanides, it is characterised in that: the composition
Including the effective component being made of fluorine azoles bacterium acyl azanol and three octyl benzene sulfonate of biguanides, the fluorine azoles bacterium acyl azanol and double
The mass ratio of three octyl benzene sulfonate of guanidine is 20:1~1:20.
The bactericidal composition of the three octyl benzene sulfonate of fluorine azoles bacterium acyl azanol and biguanides, it is characterised in that: described
The mass ratio of three octyl benzene sulfonate of fluorine azoles bacterium acyl azanol and biguanides is 5:1~1:5.
The bactericidal composition of three octyl benzene sulfonate of the fluorine-containing azoles bacterium acyl azanol and biguanides, it is characterised in that: institute
Stating dosage form dosage form is suspending agent, wettable powder, micro-capsule suspension, water-dispersible granules, thermal fog or suspension seed-coating agent.It can
There are solvent, surfactant, emulsifier, wetting agent, dispersing agent, thickener, defoaming agent, antifreezing agent, stabilization with the auxiliary agent of selection
Each analog assistant such as agent, disintegrating agent, filler.
The present composition has good control efficiency for various crops diseases such as wheat scab, root rotof flaxes.
Remarkable result and advantage of the invention is:
Two classes are had to the fungicide of different structure type and discrepant mechanism of action, it is upper easy-to-use to be processed into production
Preparation, bioactivity is high, and total dosage decline on unit area, times for spraying reduces, reduces dispenser cost, delay cause of disease
Object drug resistance generates and development, extends the service life of each component in bactericidal composition, good to crop safety, to realize
Goal of the invention economic, efficiently, environmentally friendly.
Application of the bactericidal composition in prevention and treatment crop fungal disease.
Careful analysis is done to the sterilization idiocratic of three octyl benzene sulfonate of fluorine azoles bacterium acyl azanol and biguanides.Fluorine azoles is measured first
The EC of two single compound (hereinafter referred to as medicament) of bacterium acyl azanol and three octyl benzene sulfonate of biguanides50(drug safety refers to
Mark), according to the EC of two single medicaments50The portfolio ratio of two medicaments is set by Wadley method, and according to Wadley coefficient of synergism SR
Value.
Test objective object be cause wheat scab Fusarium graminearum (Fusarium graminearum), cause wheat
Root rot Bipolaris sacchari (Bipolaris sorokiniana), but not limited to this.Take fluorine azoles bacterium acyl azanol and biguanides three pungent
Alkylbenzene sulfonate is configured to need medical fluid plate, about 15 ml of every ware.It is produced in the punch of preculture colony edge sterilizing
The mycelia block of 5mm diameter, moves on to respectively on different culture medium plate, 25 DEG C of cultures.Test uses mycelia growth measurement method, by not
With processing production pastille culture medium, the mycelia block of 5mm diameter is produced in the punch of preculture colony edge sterilizing, is moved respectively
On the culture medium flat plate different to content of dispersion, colony diameter is measured using crossing method, is measured colony diameter (mm), by following
Formula calculates growth inhibition ratio:
Mycelial growth inhibition rate %=(1- chemicals treatment colony diameter -5/ compares colony diameter -5) × 100%
Mycelial growth inhibition rate is converted into and inhibits probit value (y), drug concentration is converted into log concentration (x), by log concentration
It is that ordinate makees toxicity regression straight line for abscissa, probit value, acquires three octyl benzene sulfonate of fluorine azoles bacterium acyl azanol and biguanides
Single dose and its mixture calculate EC to the virulence regression equation of germ50Value and correlation coefficient r value.
The interaction of mixture is evaluated according to Wadley method, calculation formula is as follows:
EC50(theoretical value)=(a+b)/(a/EC50a+ b/EC50B),
SR = EC50(theoretical value)/EC50(actual value).
Wherein a, b are each component content ratios in mixture, with the effect of SR value analysis mixture.SR≤0.5, then two kinds of medicines
Agent mixture has antagonism；SR=0.5~1.5, then two kinds of medicament mixtures have addition；SR >=1.5, then two kinds of medicaments are mixed
Equipped with synergistic effect.
Table 1, fluorine azoles bacterium acyl azanol and three octyl benzene sulfonate single dose of biguanides and its mixture survey Fusarium graminearum virulence
Determine result
As can be seen from the above table, the fluorine azoles bacterium acyl azanol of different proportion and three octyl benzene sulfonate composition of biguanides are to cereal sickle
The fungistatic effect of knife bacterium is different, and on the whole, ratio has synergistic effect in the range of 20:1 to 1:20.
Table 2, fluorine azoles bacterium acyl azanol and three octyl benzene sulfonate single dose of biguanides and its mixture are to wheat Bipolaris bacterium
Power measurement result
As can be seen from the above table, the fluorine azoles bacterium acyl azanol of different proportion and three octyl benzene sulfonate composition of biguanides are to Wheat flat
The fungistatic effect of the compacted spore bacterium of navel is different, and on the whole, ratio has synergistic effect in the range of 20:1 to 1:20.
Indoor synergy measurement result shows that the present invention has the fungal diseases such as wheat scab, root rotof flax
Higher growth inhibitory effect, there are notable synergistic effects between two components；Two components compound according to a certain percentage can reduce use
Dose is effectively reduced ecological disruption and environmental pollution, and can improve crop yield and quality；In the present invention fluorine azoles bacterium acyl azanol and
Three octyl benzene sulfonate of biguanides belongs to low toxicity, and to people and animals, beneficial organism, Environmental security；Germ can be delayed to list
The drug resistance of one medicament.
Specific embodiment
Below with reference to embodiment, the invention will be further described, but essence of the invention is not limited to following embodiments.
Embodiment 1
The preparation of 32% fluorine azoles bacterium acyl azanol biguanides, three octyl benzene sulfonate suspending agent, by mass percentage.
Fluorine azoles bacterium acyl azanol 16%, three octyl benzene sulfonate 16% of biguanides, calcium lignosulfonate 6%, alkylphenol-polyethenoxy
Base phosphate 4%, xanthan gum 0.1%, organic silicon defoamer 0.3%, water surplus.
Preparation method: according to formula, the above component being weighed in proportion, and ball mill ball milling 30min is added, and is filtered, and is pumped into
It is fully ground after dispersion tank high speed shear 3min through sand mill, solid component particle diameter is controlled within 2 μm, after grinding
It stirs evenly to get suspending agent product.
Embodiment 2
The preparation of 36% fluorine azoles bacterium acyl azanol biguanides, three octyl benzene sulfonate thermal fog, by mass percentage.
Fluorine azoles bacterium acyl azanol 18%, three octyl benzene sulfonate 18% of biguanides, No. 2 aromatic naphtha 20%, castor oil polyoxyethylene ether
4%, sodium dodecyl benzenylsulfonate 2%, xanthan gum 0.1%, urea 3%, propylene glycol 1%, attapulgite Ultramicro-powder 2%, poly dimethyl silicon
Oxygen alkane 0.1%, water surplus.
Preparation method: fluorine azoles bacterium acyl azanol, three octyl benzene sulfonate of biguanides, No. 2 aromatic naphtha are added in modulation kettle, temperature
Degree control at 60 DEG C, be stirred and dissolved into oil mutually keep the temperature it is spare；By castor oil polyoxyethylene ether, sodium dodecyl benzenylsulfonate, xanthan
Glue, urea, propylene glycol, attapulgite Ultramicro-powder, dimethyl silicone polymer, water etc. are added in modulation kettle, and temperature is controlled at 60 DEG C,
It is spare to be stirred and dissolved into water phase heat preservation；The oil of preparation is mutually introduced under the revolving speed of 3000 rpm to the water phase reserve liquid of preparation
In, after oil mutually add continue stir 30 min after, with low speed 200rpm stir 1h, filtering remove residue to get thermal fog product.
It is sufficiently shaken up when use, is blended into the smoke agents such as suitable diesel oil and crop is prevented and treated.
Embodiment 3
The preparation of 48% fluorine azoles bacterium acyl azanol biguanides, three octyl benzene sulfonate missible oil, by mass percentage.
Fluorine azoles bacterium acyl azanol 24%, three octyl benzene sulfonate 24% of biguanides, dimethylbenzene 20%, DMF 2%, anhydrous calcium salt
5%, tween (80) 5%, carbon tetrachloride surplus.
Preparation method: active component fluorine azoles bacterium acyl azanol is sufficiently dissolved in dimethylbenzene reaction kettle, A liquid is made；It will live
Three octyl benzene sulfonate of property component biguanides sufficiently dissolves in carbon tetrachloride and DMF reaction kettle, and B liquid is made, is keeping stirring
A liquid is mixed into B liquid under state, is stirred, anhydrous calcium salt and Tween 80 is added, is then contained with the adjustment of solvent carbon tetrachloride
Amount.
Embodiment 4
The preparation of 30% fluorine azoles bacterium acyl azanol biguanides, three octyl benzene sulfonate wettable powder, by mass percentage.
Fluorine azoles bacterium acyl azanol 25%, three octyl benzene sulfonate 5% of biguanides, sodium dodecyl benzenylsulfonate 2%, lignin sulfonic acid
Sodium 4%, white carbon black 7%, kaolin surplus/2, attapulgite surplus/2.
Preparation method: mixing machine is added by formula rate in the above component and carries out air-flow crushing after mixing, has been crushed
It is stirred at the rear a small amount of purified water of addition, wettable powder product can be obtained after drying.
Embodiment 5
The preparation of 50% fluorine azoles bacterium acyl azanol biguanides, three octyl benzene sulfonate water dispersible granules, by mass percentage.
Active component fluorine azoles bacterium acyl azanol 25%, three octyl benzene sulfonate 25% of active component biguanides, sodium lignin sulfonate
6%, polyvinyl alcohol 4%, ammonium sulfate 8%, white carbon black 10%, kaolin surplus.
Preparation method: mixing machine is added by formula rate in the above component and carries out air-flow crushing after mixing, has been crushed
It is stirred at the rear a small amount of purified water of addition, extrusion granulation can obtain water dispersible granules product after drying.
Embodiment 6
The preparation of 25% fluorine azoles bacterium acyl azanol biguanides, three octyl benzene sulfonate suspension seed-coating agent, by mass percentage.
Fluorine azoles bacterium acyl azanol 7.5%, three octyl benzene sulfonate 7.5% of biguanides, fulvic acid 2%, aliphatic acid polyethenoxy ether phosphorus
Acid esters 3%, polyvinyl acetate 3%, acid scarlet 0.01%, xanthan gum 0.2%, Kathon CG 0.3%, ethylene glycol 5%, water surplus.
Preparation method: according to formula, the above component being weighed in proportion, and ball mill ball milling 60min is added, and is filtered, and is pumped into
It is fully ground after dispersion tank high speed shear 3min through sand mill, solid component particle diameter is controlled within 2 μm, after grinding
It stirs evenly to get suspension seed-coating agent product.
Embodiment 7
The preparation of 16% fluorine azoles bacterium acyl azanol biguanides, three octyl benzene sulfonate microcapsule suspension seed-coating agent, by mass percentage.
Fluorine azoles bacterium acyl azanol 8%, three octyl benzene sulfonate 8% of biguanides, dimethylformamide 2%, two isocyanide of diphenyl methane
Acid esters 3%, fatty acid amide N methyl taurine salt 2%, ethylenediamine 0.5%, 1,3-PD 1.2%, sodium methylene bis-naphthalene sulfonate 2%,
Aluminium-magnesium silicate 3.2%, gum arabic 2%, polyvinyl alcohol 2%, polyacrylate 2.5%, permanent bordeaux 4%, water surplus.
Preparation method: by medicament dissolution in solvent, diphenylmethane diisocyanate vinegar is added and is uniformly mixing to obtain oily phase；
Emulsifier is added in water, adjuvant is uniformly mixing to obtain water phase；Water phase is added in oily phase, high speed homogenizing formation oil-in-water cream
Liquid；Under the conditions of 450 rpm speed, ethylenediamine is added and participates in interface polymerization reaction, reaction temperature rises to 55 DEG C, and 3h is kept to be solidified into
Capsule；Be added di-2-ethylhexylphosphine oxide tea sodium sulfonate, aluminium-magnesium silicate, permanent bordeaux, polyvinyl alcohol and polyacrylate, stir evenly be made it is micro-
Capsule suspension seed-coating agent.
The experiment of wheat scab field efficacy.
Comparison medicament selects 20% fluorine azoles bacterium acyl azanol suspending agent (comparison medicament 1), 40% biguanides, three octyl benzene sulfonate
Wettable powder (comparison medicament 2).It tests in being carried out in wheat paddock, is administered for the first time in wheat flowering initial stage, the after 3-5 days
Secondary application carries out Disease investigation after 20 days.It the results are shown in Table 3
Table 3, three octyl benzene sulfonate of fluorine azoles bacterium acyl azanol biguanides are to the control effect of wheat scab
Field experiment the result shows that, the compounded combination of three octyl benzene sulfonate of fluorine azoles bacterium acyl azanol biguanides is to wheat scab
Have it is preferable imitate, compared with single dose, whole control effect synergistic effect is obvious.According to field investigation, in test dose
In range, plant growth is normal, has no that plant generates drug damage and abnormal phenomena, to wheat safety.
Soya seeds are coated the experiment of prevention and control root rot field efficacy.
Experiment carries out seed pelleting processing using suspension seed-coating agent, and normal mechanical is broadcast after the wheat seeds after coating dry in the shade naturally
Kind, after planting 30 days progress Disease investigations.Prevention and treatment the results are shown in Table 4.
Control effect of 4 fluorine azoles bacterium acyl azanol biguanides of table, the three octyl benzene sulfonate to root rotof flax
Field experiment the result shows that, three octyl benzene sulfonate of fluorine azoles bacterium acyl azanol biguanides is formed by suspension seed-coating agent to small
Wheat root rot has preferable imitation, and whole control effect effect is obvious.According to field investigation, within the range of experimental dose, make
Object growth is normal, has no that plant generates drug damage and abnormal phenomena, to wheat safety.
The above list is only a few specific embodiments of the present invention for finally, it should also be noted that.Obviously, this hair
It is bright to be not limited to above embodiments, there can also be many variations.Those skilled in the art can be from disclosed by the invention interior same
All deformations for directly exporting or associating, are considered protection scope of the present invention.
Claims (3)
1. a kind of bactericidal composition of three octyl benzene sulfonate of fluorine-containing azoles bacterium acyl azanol and biguanides, it is characterised in that: the combination
Object includes the effective component being made of fluorine azoles bacterium acyl azanol and three octyl benzene sulfonate of biguanides, the fluorine azoles bacterium acyl azanol and
The mass ratio of three octyl benzene sulfonate of biguanides is 20:1~1:20.
2. the bactericidal composition of three octyl benzene sulfonate of fluorine azoles bacterium acyl azanol according to claim 1 and biguanides, special
Sign is: the mass ratio of three octyl benzene sulfonate of the fluorine azoles bacterium acyl azanol and biguanides is 5:1~1:5.
3. the bactericidal composition of three octyl benzene sulfonate of fluorine-containing azoles bacterium acyl azanol and biguanides according to claim 1,
Be characterized in that: the dosage form dosage form is suspending agent, missible oil, wettable powder, micro-capsule suspension, water-dispersible granules, hot mist
Agent or suspension seed-coating agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810484425.2A CN110495466A (en) | 2018-05-20 | 2018-05-20 | A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810484425.2A CN110495466A (en) | 2018-05-20 | 2018-05-20 | A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110495466A true CN110495466A (en) | 2019-11-26 |
Family
ID=68584936
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810484425.2A Pending CN110495466A (en) | 2018-05-20 | 2018-05-20 | A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110495466A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104486949A (en) * | 2012-07-26 | 2015-04-01 | 先正达参股股份有限公司 | Fungicidal compositions |
| CN109566642A (en) * | 2017-09-29 | 2019-04-05 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
-
2018
- 2018-05-20 CN CN201810484425.2A patent/CN110495466A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104486949A (en) * | 2012-07-26 | 2015-04-01 | 先正达参股股份有限公司 | Fungicidal compositions |
| CN109566642A (en) * | 2017-09-29 | 2019-04-05 | 江苏龙灯化学有限公司 | A kind of bactericidal composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102265837A (en) | Sterilizing composition containing thifluzamide and brassinolide | |
| CN102150659B (en) | Bactericide composition, preparation and application thereof | |
| CN101731223A (en) | Fungicide composition containing azoxystrobin and ethirimol, and application thereof | |
| CN104542585A (en) | Fungicide composition and application thereof | |
| CN102150671B (en) | Bactericide composition and preparation and application thereof | |
| CN104365611B (en) | A kind of bactericidal composition and application containing amisulbrom and mandipropamid | |
| CN105340915A (en) | Sterilization composition containing benziothiazolinone and Xinjunan acetate | |
| CN102228035B (en) | Herbicide composition containing bispyribacsodium and oxaziclomefone | |
| CN110495466A (en) | A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol | |
| CN105340914A (en) | Sterilization composition containing benziothiazolinone and bromothalonil | |
| CN101584335A (en) | Iprodione and azoxystrobin-containing antiseptic composition | |
| CN101584324A (en) | 2-cyano-3-amino-3-phenylancryic acetate and epoxiconazole-containing antiseptic composition | |
| CN105340894A (en) | Sterilization composition containing dithianon and bromothalonil | |
| CN104970021A (en) | Sterilization composition containing oxine-copper and xinjunan acetate | |
| CN104488894A (en) | Compound composition containing methanesulphonyl myclobutanil and fluopicolide and bactericide | |
| CN104488898B (en) | Containing methylsulfonyl bacterium azoles and the complex composition of Xinjunan acetate and antibacterial | |
| CN104488897A (en) | Compound composition containing methanesulphonyl myclobutanil and carbamic acid ester bactericide and preparation | |
| CN110495458A (en) | A kind of bactericidal composition containing three octyl benzene sulfonate of coumoxystrobin and biguanides | |
| CN105638686B (en) | A kind of combination sterilization composition containing tiger glue adipic acid copper | |
| CN104542626B (en) | A kind of containing methylsulfonyl bacterium azoles and the complex composition of CGA-173506 and preparation | |
| CN108812688A (en) | A kind of bactericidal composition containing Moroxydine Hydrochloride and Xinjunan acetate | |
| CN110495465A (en) | A kind of bactericidal composition containing three octyl benzene sulfonate and probenazole of biguanides | |
| CN110495467A (en) | A kind of bactericidal composition of 2-cyano-3-amino-3-phenylancryic acetate-containing and three octyl benzene sulfonate of biguanides | |
| CN110495462A (en) | A kind of bactericidal composition of fluorine-containing azoles bacterium acyl azanol and probenazole | |
| CN102150658A (en) | Bactericide composition and preparation and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20191126 |