CN110468484A - A kind of environment-friendly plus material and its processing method - Google Patents
A kind of environment-friendly plus material and its processing method Download PDFInfo
- Publication number
- CN110468484A CN110468484A CN201910709309.0A CN201910709309A CN110468484A CN 110468484 A CN110468484 A CN 110468484A CN 201910709309 A CN201910709309 A CN 201910709309A CN 110468484 A CN110468484 A CN 110468484A
- Authority
- CN
- China
- Prior art keywords
- environment
- plus material
- friendly plus
- layer
- friendly
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/08—Melt spinning methods
- D01D5/088—Cooling filaments, threads or the like, leaving the spinnerettes
- D01D5/092—Cooling filaments, threads or the like, leaving the spinnerettes in shafts or chimneys
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
- D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
- D03D15/513—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads heat-resistant or fireproof
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Woven Fabrics (AREA)
Abstract
The present invention relates to a kind of environment-friendly plus material and its processing methods, which is characterized in that the LOI of environment-friendly plus material is 31~33%, environment-friendly plus material residual carbon content > 10% after 600 DEG C of high-temperature calcination 15min, and the UL-94 of environment-friendly plus material is V-0 grades.The present invention is raw material using regenerated polyester fiber, assigns fabric excellent reproducibility and environmental protection characteristic.
Description
Technical field
The present invention relates to fabric production technical fields, are a kind of environment-friendly plus material and its processing method specifically.
Background technique
China Patent Publication No. CN109972262A is related to a kind of production method of antibacterial environment-friendlyfabric fabric, including following
Step: (1) wool is dyed；(2) clear comb, then combing；(3) step (2) is added radiation protection by spinning process afterwards and spins
Wool yarn is made in yarn；(4) fine stainless steel wire yarn is made into after being mixed wool yarn and fine stainless steel wire by weaving process；(5) will
Fine stainless steel wire yarn carries out dyeing again then longitude and latitude and interweaves；Step (6) obtains antibacterial environment-friendlyfabric fabric by finishing technique afterwards；It is whole
Science and engineering skill is the following steps are included: A, singe；B, enzyme desizing；C, it washes；D, it dries；E, tentering；F, preshrunk；G, cloth-inspecting rolling, it is fixed
Type simultaneously examines textile fabric, by testing volume combination machine clot.This simple process is easy to operate.The finishing technique of textile fabric uses
Pure physical finishing technique, completely dispenses with chemical substance treatment, reduces pollution, is a kind of environmentally protective finishing technique.
China Patent Publication No. CN109605856A is related to a kind of antistatic environment-friendly plus material and preparation method thereof, including base fabric
The top of layer, fireprotection layer, antistatic layer, waterproof layer, heath care layer and air-permeable layer, the base cloth layer passes through environmental protection acrylic glue
It is connected with antistatic layer, and the top of antistatic layer is connected with fireprotection layer by environmental protection acrylic glue, the base cloth layer
Bottom is connected with waterproof layer by environmental protection acrylic glue, and the bottom of waterproof layer is connected with guarantor by environmental protection acrylic glue
Strong layer.Antistatic layer is connected to by environmental protection acrylic glue at the top of base cloth layer, can effectively improve this fabric prevent it is quiet
Electrical property, while fireprotection layer is connected to by environmental protection acrylic glue at the top of antistatic layer, it can avoid in hot environment
Under, antistatic layer is damaged, so that the antistatic effect of fabric is influenced, so that this fabric is having the same of antistatic effect
When, it may have ability resistant to high temperature.
China Patent Publication No. CN109457464A is related to a kind of production technology of environment-friendly type absorbing sweat hydrofuge fabric, including such as
Lower step: S1, fabric braiding: warp thread uses biomass graphene nylon fibre, and weft yarn uses polypropylene fiber in carding process fiber；S2, base
Cloth is singed；S3, fabric mercerising；S4, liquid ammonia finishing；S5, piece dyeing finishing；S6, drying and shaping.The ingredient of polypropylene fiber in carding process fiber is all
It is carbon and hydrogen, and both elements have affinity to the skin of people, not will cause any allergic reaction, and under illumination effect
Recurrence can be decomposed naturally, when burning simultaneously toxic gas will not be discharged as other synthetic fibers, dirt will not be caused to environment
Dye, is green ecological environment-friendly plus material truly.Biomass graphene fiber is with the stalks biomaterial such as corncob
The porous cellulose generated in refining process is raw material, and natural degradable, biomass graphene fiber is with graphene two-dimensional slice
Layer structure, the micropore between fabric is more, is conducive to steam and spreads, achievees the effect that absorbing sweat hydrofuge.
China Patent Publication No. CN109419066A is related to environmentally protective antimicrobial form gym suit, it includes garment body,
Be characterized in that: the garment body is by including successively outside to inside environment-friendly plus material layer and antibiotic layer, and environment-friendly plus material layer is by the first warp
It mutually being woven with the first weft, the first warp is by hemp, milk silk fiber and silk flock is blended forms, and first
Weft is formed by soybean fiber and Lyocell fibers are blended, and antibiotic layer is mutually woven by the second warp and the second weft, the
Two warps are by numb Sai Er fiber and Lyocell fibers are blended forms, and the second weft is blended by mint fibers and macromolecule bamboo charcoal fiber
It forms.Realize the environmentally protective and antibacterial effect of gym suit.
China Patent Publication No. CN108977932A is related to a kind of processing technology of novel fabric: (1) modified fibre: with
Blend spinning solvent: according to volume ratio 5:3 mixing DCM and DMF；Chitin is prepared according to weight ratio 2:0.5, tea polyphenols are formed
Mixture；Mixture is dissolved in blend spinning solvent, at room temperature after magnetic agitation 3h, temperature is reduced to 6-8 DEG C of cold place
10-30min is managed, room temperature is then restored, continues to stir 10-15h, stand for standby use；(2) electrostatic spinning.Obtain dumb light quality, antibacterial
The novel environment friendly fabric of excellent, and overcome the shortcomings that anti-microbial property declines to a great extent in soda bath and cotton blend
After can freer carry out pre-treatment, therefore have a vast market foreground.
China Patent Publication No. CN108866862A is related to a kind of high resiliency environment-friendly plus material printing system and its technique, equipment
Including dyestuff case, dye liquor guiding mechanism is set, liquid outlet is arranged in tail end, and dye liquor guiding mechanism is arranged first from front to back in case
Pressing mechanism, power mechanism and the second pressing mechanism；First and second pressing mechanisms alternately go up and down under power mechanism drive and squeeze
The dye liquor being padded in liquid guiding mechanism, dye liquor wash away fabric from liquid outlet outflow；Setting is ground between first and second pressing mechanisms
Grinding machine structure, grinding mechanism includes lower grinding assembly, upper grinding assembly and driving assembly, and coarse granule deposition of dye is in lower grinding assembly
On, the first pressing mechanism drives grinding assembly to be displaced downwardly to lower grinding assembly downwards, and drives driving assembly to move down to make
Grinding assembly is to the coarse granule dye abrasion on lower grinding assembly；The dyeing for solving fabric is bad, and the fabric for dyeing out is easy
Impurity is attached, lower leaf and the not high problem of dye utilization rate in dyestuff uniformity difference.
A kind of low-carbon environment-friendly fabric of China Patent Publication No. CN108754773A, the fabric warp use alginate fibre, latitude
Line uses cotton synthetic fibre fiber, and wherein the diameter of alginate fibre is 26.3 μm, fiber number 197.4dtex, and the diameter of cotton synthetic fibre fiber is
13.2 μm, fiber number 87.2dtex, be 17.2/cm through density, and weft density is 39.5/cm.This fabric seaweed Carbon fibe
Fabric, which is made, has heat preservation and health care double effects, is suitable for the clothes such as T-shirt, underwear, and wear wipes human body molecular mill for a long time produces
Pyrogenic reaction promotes body blood circulation, has the effect of a kind of heat storing and heat preserving.The socks that seaweed Carbon fibe is made into, which have, to be protected
Temperature, antibacterial and odor-resistant result.Due to raw material come from natural seaweed, fiber have good biocompatibility, degradable absorbability,
The specific functions such as biocompatibility are a kind of fabrics of low-carbon environment-friendly.
China Patent Publication No. CN108642648A is related to a kind of high conformal health-care environmental-protecting fabric and preparation method thereof, adopts
With the cop-cop-yarn for fabric quality percentage 56% be warp thread, 44% spun silk strand be weft yarn through warping, weaving process system
At；The cop-cop-yarn be adopted as fabric quality percentage 40% mixing covering yarn, 16% silk through in wool spinning technology
Doubling, double twisting, yarn steaming process be made；The mixing covering yarn is by the mercerising sheep to mix covering yarn mass percent 20%
Wool fibre, 25% aloe fibre, 25% silk fiber, 30% long-staple cotton fiber composition, wherein long-staple cotton fiber is mixed
Close the heart yarn of covering yarn.The textile fabric and its production method of offer, select have the aloe of environment-protecting health-care function, soft silk, cotton,
Wool etc. is raw material, and with silk and twist, spun silk interweaves, develop a series of flower pattern novelty, unique style, moisture absorption, it is ventilative, protect
The conformal health-care environmental-protecting fabric of height of skin.
China Patent Publication No. CN108642675A is related to a kind of environment-friendly plus material, it is characterised in that: the fabric is pure
Natural environmental-protective fabric, the fabric are interwoven by veil and filling, and the filling is mulberry silk fiber, and the veil includes following
Component according to parts by weight: zein fiber, pearl fiber and milk fibre mixed textile form, wherein the volume of three kinds of fibers
Percentage is 35%, 35% and 30%.Compared with prior art, fabric is environmentally protective, and skin-friendly is good, and durable antibacterial effect is right
Human body has preferable skin effect, is worthy to be popularized.
China Patent Publication No. CN108532328A is related to a kind of preparation process of tender skin environment-friendly plus material, including walks as follows
Rapid: S1 matches cloth；S2 cold dome: first rising to 26~29 DEG C for water temperature, be at the uniform velocity added in 5~10min chelating agent reaction 15~
20min, then Tea Saponin is at the uniform velocity added in 20~29min and reacts 45~60min, then degreaser reaction is added in 5~10min
5~8min banks up 24~26h；S3 continuous annealing dissipates volume；S4 cylinder moves back: being cooled to 26~29 DEG C after debatching, in 5~10min at the uniform velocity
Swelling agent is added and reacts 3~5min, then Tea Saponin is at the uniform velocity added in 20~29min and reacts 60~90min, it is warming up to 110~
120 DEG C, keep the temperature 45~60min；S5 dyeing；S6 reduction is washed；The preparation of S7 finished product.The application have environmental protection, low energy, low cost and
Dynamical advantage.
China Patent Publication No. CN108515739A is related to a kind of novel nano automatically cleaning environment-friendly plus material, including cleaning fabric
Ontology, the inside of the cleaning fabric ontology are equipped with multiple strip projected parts parts, and the strip projected parts part bilateral symmetry is distributed
And size dimension is unified, and multiple round bulge loops are equipped on the inside of the strip projected parts part, the circle bulge loop is equipped with multiple
And keep vertically being equally spaced, permeable portion, the ventilation part are symmetrically arranged at left and right sides of the cleaning fabric ontology
Multiple air holes are uniformly distributed on point；The cleaning fabric ontology include nanometer cleaning composite layer, bamboo fibre layer, antistatic backing,
Warming internal layer and carbon fiber layer, the bottom of the nanometer cleaning composite layer connect bamboo fibre layer, and the bottom of the bamboo fibre layer connects
Take over control electrostatic layer.This kind of equipment is integrally improved the functionality of cleaning fabric ontology, it is made to have antistatic, adsorbing contaminant, guarantor
Warm self-cleaning function, structure is simple, functional stronger.
China Patent Publication No. CN108185542A is related to a kind of environment-friendly plus material and efficiently completely cuts off ultraviolet light swimming suit, including waist
And chest, the waist are stitch-bonded to the two sides of chest, four corners of the chest are provided with opening, the waist and chest
Outside is equipped with film layer, and the middle part of the waist is laid with elasticity layer, and skin touching is equipped on the inside of the waist and chest
Layer is touched, uvioresistant layer and elastic layer are equipped in the middle part of the chest, the middle part interlocking of the opening has bandage, the chest
Interlocking has wardrobe-malfunction-proof cushion block between interior elastic layer and skin touch layer.This kind application design is rationally, easy to use, due to containing
Antiultraviolet fiber, therefore there is good ultraviolet-resistent property, since containing high-elastic spandex fibre, there is good elasticity and recovery,
It is provided simultaneously with good wearing comfort.Production technology is relatively simple, can be produced using common garment production equipment, beneficial
In the added value for promoting swimming suit.
China Patent Publication No. CN108070941A is related to a kind of preparation method of high-strength antibacterial environment-friendlyfabric fabric, is pressed by following
The raw material of weight ratio is blended: wherein polypropylene fiber in carding process fiber 45%, cotton fiber 35%, chitin fiber 10%, silver fiber 5%
And soybean fiber 5% carries out blended, obtains warp；By weight ratio take calamine fiber 55%, bamboo fibre 35% and
Milk protein fiber 10% carries out blended, obtains weft；High-strength antibacterial environment-friendlyfabric fabric provided by the present application, not only makes product antibacterial
Performance is good, protects skin, and it is strong to go back sucting wet air permeability, uses antibiotic finishing solution, further increases the antibacterial effect of fabric, contaminates
All natural vegetable dyeing agent is used during color, after fixation, even dyeing does not fade, simple process, color fast；
Fabric whole process provided by the present application is all made of natural material progress, and environmental protection is at low cost, and fabric Functional Design is novel, fabric
Class is high, and product comfort level is good, and added value is high.
China Patent Publication No. CN108049022A is related to a kind of production method of novel environment friendly fabric: (1) chitin is fine
The modification of dimension: it is equipped with blend spinning solvent: according to volume ratio 8:2 mixing DCM and DMF；According to weight ratio 1:0.3:0.02-
0.05:0.02 prepares chitin, tea polyphenols, soap cottonrose hibiscus carbohydrate gum, stachyose formation mixture；It is molten that mixture is dissolved in blend spinning
In agent, at room temperature after magnetic agitation 3h, temperature is reduced to 0-5 DEG C of cold treatment 30-50min, then restores room temperature, continues to stir
6-8h, stand for standby use；(2) electrostatic spinning.The application acquisition dumb light quality, the splendid novel environment friendly fabric of antibacterial effect, and
Overcome after the shortcomings that anti-microbial property declines to a great extent in soda bath and cotton blend can freer carry out pre-treatment, therefore
It has a vast market foreground.
China Patent Publication No. CN107805868A is related to a kind of Lyocell long filament environment-friendlyfabric fabric and its preparation side
Method, Lyocell long filament environment-friendlyfabric fabric warp thread and weft yarn are all made of the Lyocell long filament of 75D~150D, by loom make through
Yarn and weft yarn are interweaved and manufactured Lyocell long filament woven fabric.Preparation method, including the following steps: (1) it is former
Material is chosen；(2) batch warping；(3) silk is starched；(5) and axis；(6) leasing；(7) drawing-in；(8) looming weaving.With prior art phase
Than the fabric sense of touch that the application method prepares is submissive, and gloss is graceful, is not easy pilling, fastness is good, and it is wet to be adjustable skin
Degree and coolness.And spinning process is omitted, preparation cost is low, and it is high-efficient, there are significant energy conservation and consumption reduction effects.
China Patent Publication No. CN107538793A is related to antibacterial and mouldproof environment-friendly plus material, including environment-friendly plus material ontology (1), ring
The upper surface of friendly fabric ontology is provided with longitudinally arranged hollow out jacquard layer (2), the lower surface of environment-friendly plus material ontology (1) downwards according to
It is secondary to be provided with antistatic layer (5), fireprotection layer (6) and waterproof layer (7).The waterproof layer lower surface is compounded with backing layer, described
Backing layer, including successively compound PU film surface layer, flax fiber sandwich layer and ramee bottom.The application antibacterial and mouldproof.
China Patent Publication No. CN107538801A is related to a kind of feature-rich environment-friendly plus material, including environment-friendly plus material ontology
(1), the upper surface of environment-friendly plus material ontology is provided with longitudinally arranged hollow out jacquard layer (2), the lower surface of environment-friendly plus material ontology (1)
It is disposed with antistatic layer (5), fireprotection layer (6) and waterproof layer (7) downwards.The waterproof layer lower surface is compounded with lining
Layer, backing layer ontology, the warp thread and weft yarns made of the backing layer, including warp thread and weft yarns are on three three
Under plain weave structure, the backing layer body upper surface is equipped with jacquard layer, and jacquard layer upper surface is equipped with patch layer, on patch layer
Equipped with several patches, patch is mutually overlapped；The lower surface of backing layer ontology is equipped with air-permeable layer, and the lower surface of air-permeable layer is equipped with anti-
The lower surface of fire bed, fireprotection layer is equipped with photocatalyst coating.The application is feature-rich.
China Patent Publication No. CN107538820A is related to one kind, and elasticity is good, and color is high, the frivolous environment-friendly plus material of cloth, packet
It includes environment-friendly plus material ontology (1), the upper surface of environment-friendly plus material ontology is provided with longitudinally arranged hollow out jacquard layer (2), environment-friendly plus material
The lower surface of ontology (1) is disposed with downwards antistatic layer (5), fireprotection layer (6) and waterproof layer (7).Under the waterproof layer
Surface recombination has backing layer, and the backing layer, it includes base cloth layer, and the base cloth layer has first surface and second surface, institute
At least one surface of the first surface and second surface of base cloth layer is stated equipped with waterproof coating, the institutional framework of the base cloth layer
It for weighing structure, is formed by one group of warp thread and two groups of weft yarns, the warp thread is 150D polyester/rayon yarns, and the weft yarn is R3.5N
Polyester/rayon yarns+300D bright-polyester sticky net reeling.Elasticity is good by the application, and color is high, and cloth is frivolous.
China Patent Publication No. CN107538822A is related to a kind of dry and comfortable free from extraneous odour environment-friendly plus material, including environment-friendly plus material ontology
(1), the upper surface of environment-friendly plus material ontology is provided with longitudinally arranged hollow out jacquard layer (2), the lower surface of environment-friendly plus material ontology (1)
It is disposed with antistatic layer (5), fireprotection layer (6) and waterproof layer (7) downwards.The waterproof layer lower surface is compounded with lining
Layer, the backing layer, it includes backing layer ontology, and the backing layer ontology is interwoven by warp and weft, warp and weft
In be equipped with more covering yarns, the outer surface of the backing layer ontology is equipped with several protrusions, the covering yarn include inner core with
And it is coated on the surface layer outside inner core.The dry and comfortable free from extraneous odour of the application.
China Patent Publication No. CN107538825A is related to a kind of good environment-friendly plus material of expansion convergent force, including environment-friendly plus material sheet
Body (1), the upper surface of environment-friendly plus material ontology are provided with longitudinally arranged hollow out jacquard layer (2), the following table of environment-friendly plus material ontology (1)
It is disposed with antistatic layer (5), fireprotection layer (6) and waterproof layer (7) downwards.The waterproof layer lower surface is compounded with lining
Layer, the backing layer by 150D/48F plain loop and 32ST/A elongation sinker loop looped pile coil and 150D/96F drawing
Weaving method of the looped pile coil of long sinker loop by weft knitting, which is successively gone here and there, to be covered, and one layer of guarantor is attached on the double-colored backing layer
Warm medicament.It is good that the application expands convergent force.
China Patent Publication No. CN107538828A is related to a kind of fire-retardant, distinct environment-friendly plus material of level, including environment-friendly plus material
Ontology (1), the upper surface of environment-friendly plus material ontology are provided with longitudinally arranged hollow out jacquard layer (2), under environment-friendly plus material ontology (1)
Surface is disposed with downwards antistatic layer (5), fireprotection layer (6) and waterproof layer (7).The waterproof layer lower surface is compounded with lining
Inner layer, the backing layer, it includes base cloth layer, it includes base cloth layer, and the base cloth layer has first surface and second surface, institute
At least one surface of the first surface and second surface of base cloth layer is stated equipped with flame retardant coating, the base cloth layer and flame retardant coating it
Between be additionally provided with adhesive phase for base cloth layer and flame retardant coating to be bonded together, the base cloth layer is by single warps and double
Stock weft yarns form.
China Patent Publication No. CN107287731A is related to a kind of health-care environmental-protecting fabric, mutually woven by warp and weft and
At, the warp by mint fibers, Modal fiber and it is bamboo fiber blended form, the weft is fine by Modal fiber and peppermint
Dimension blending woven forms, mint fibers in the warp, and Modal fiber and bamboo fiber blended ratio are 1:2:2, the latitude
The blending rate of Modal fiber and mint fibers is 3:2 in line.A kind of health-care environmental-protecting fabric disclosed herein, fabric tool
There is smooth nice and cool, antistatic, antiultraviolet, antibacterial, wear-resisting, degradable, its health effect, which has, refreshes oneself, is eye-catching, is clear
The effects of cool, anti-inflammatory, skin makeup.
China Patent Publication No. CN107217494A is related to a kind of disc floret flocking environment-friendly plus material, including fabric body, described
Fabric body is equipped with disc floret layer in netted, in the upper surface of the fabric body, and lower surface is equipped with flocking layer, on the disc floret layer
Equipped with disc floret, the flocking layer is equipped with velvet flowers, and the fabric body is made of fabric, and the fabric includes pure wool organized layer
With wool tencel Hun Sha yarn organized layer, wool tencel Hun Sha yarn organized layer and pure wool organized layer respectively constitute fabric inner layer and
Outer layer passes through part connection between wool tencel Hun Sha yarn organized layer and pure wool organized layer.The disc floret of protrusion and velvet flowers enhancing
The stereovision of disc floret flocking environment-friendly plus material, and it is soft comfortable.The application was not only environmentally friendly, but also will not be damaged to wool
Wound.
China Patent Publication No. CN107139547A is related to a kind of positive and negative staggeredly jacquard weave environment-friendly plus material, including base fabric, base fabric
Tow sides be equipped with jacquard layer, jacquard layer includes several jacquard regions and non-jacquard region, the jacquard region and non-
Jacquard region is in blocky and is staggered, and the base fabric is made of fabric, and the fabric includes pure wool organized layer and wool
Tencel Hun Sha yarn organized layer, wool tencel Hun Sha yarn organized layer and pure wool organized layer respectively constitute the inner layer and outer layer of fabric,
Pass through part connection between wool tencel Hun Sha yarn organized layer and pure wool organized layer.Positive and negative the positive and negative of jacquard weave environment-friendly plus material of interlocking
Face is respectively provided with the jacquard region being interspersed and non-jacquard region, enhances the stereovision of fabric.The application was not only environmentally friendly, but also will not
Wool is damaged.
China Patent Publication No. CN106676735A is related to the production technology of colorful high-elastic environment-friendly plus material, and fabric is by 4~6
The network segment dye dacron thread of 150~200D/144F is weaved on the bodkin bullet towel single-side machine of 30 cun of 8~12G, fabric
Production process is as follows: weaving → cut open width → pre-setting → plucking → cropping → finished product sizing；Above-mentioned colorful high-elastic environmental protection
The step of production technology of fabric does not dye fabric reaches energy-saving ring so as to greatly reduce the discharge of pollutant
The purpose of guarantor；And the fabric of production technology production has colorful, high-elastic, moisture absorbing and sweat releasing, endures with all one's will crease-resistant performance, fabric color
Fastness can reach American Standard and require 3~4 grades.
A kind of environment-friendly plus material with catalysis formaldehyde function of China Patent Publication No. CN106515099A, it is characterised in that:
It is made of hydrophobic layer, functional layer, separation layer；Functional layer is between hydrophobic layer and separation layer；Hydrophobic layer is waterproof and breathable film layer；
Functional layer uniformly alternate is interwoven by the first fiber, the second fiber.The application, which has, has both that light shielding ability is strong, environmentally friendly degree
The advantages of good, durable ability is strong, waterproof, good permeability, good heat preservation performance.
A kind of jacquard weave fluff stripe environment-friendly plus material of China Patent Publication No. CN106418835A, it includes fabric body (1), face
Expect that the upper surface of ontology (1) is equipped with jacquard weave item (2) and fluff strip (3), lower surface equipped with tapetum (4), the jacquard weave item (2) and
Fluff strip (3) is alternatively arranged, and the upper surface of fluff strip (3) is equipped with ornament (5), and fabric body (1) is made of fabric, described to knit
Object includes pure wool organized layer and wool tencel Hun Sha yarn organized layer, and wool tencel Hun Sha yarn organized layer and pure wool organized layer divide
Not Gou Cheng fabric inner layer and outer layer, between wool tencel Hun Sha yarn organized layer and pure wool organized layer by part connection.It is convex
Fluff strip, jacquard weave item and the tapetum risen enhances the stereovision of jacquard weave fluff stripe environment-friendly plus material, while ornament is interspersed, and is dashed forward
Individual character is gone out.
A kind of environment-friendly plus material in men's style easy suit of China Patent Publication No. CN106360857A, belongs to textile technology
Technical field.It presses specific weight ratio by fiber yarns such as soft silk, kapok, wool, RTT, through spinning, woven fabric, dyeing, arrangement
Process is made.It is characterized in that their weight ratio be the soft silk 50~60%, kapok 10~20%, wool 5~10%,
RTT15~30%；The finished weight being made into is every Gram Mass between 130 grams~350 grams.The application has shape sense size
Stablize, memory effect is good, comfortable and easy to wear, pro-skin foster skin and the advantages that give the feeling for placing oneself in the midst of forest.
A kind of suede environment-friendly plus material with breathable fabric layer of China Patent Publication No. CN106333408A, it includes fabric
Ontology (1), the upper surface of fabric body (1) is equipped with tapetum (2), lower surface is equipped with jacquard layer (4), on the tapetum (2)
Equipped with fluff strip (3), jacquard layer (4) is fixed on the lower surface of fabric body (1), and the fabric body (1) is made of fabric, institute
Stating fabric includes pure wool organized layer and wool tencel Hun Sha yarn organized layer, wool tencel Hun Sha yarn organized layer and pure wool tissue
Layer respectively constitutes the inner layer and outer layer of fabric, is connected between wool tencel Hun Sha yarn organized layer and pure wool organized layer by part
It connects.The application is soft comfortable.
A kind of waterproof of China Patent Publication No. CN106113657A, the good environment-friendly plus material of air permeability effect, including environment-friendly plus material sheet
Body (1), the upper surface of environment-friendly plus material ontology are provided with longitudinally arranged hollow out jacquard layer (2), the following table of environment-friendly plus material ontology (1)
It is disposed with antistatic layer (5), fireprotection layer (6) and waterproof layer (7) downwards.The waterproof layer lower surface is compounded with lining
Layer, the lining layer surface are coated with fluorine monomer aqueous polyurethane coating layer.
China Patent Publication No. CN106113746A is a kind of fine and smooth, soft and have the sense environment-friendly plus material that hangs down, including environment-friendly plus material
Ontology (1), the upper surface of environment-friendly plus material ontology are provided with longitudinally arranged hollow out jacquard layer (2), under environment-friendly plus material ontology (1)
Surface is disposed with downwards antistatic layer (5), fireprotection layer (6) and waterproof layer (7).The waterproof layer lower surface is compounded with lining
Inner layer, the backing layer are made of the interlacing of warp thread one, warp thread two and weft yarn, and the warp thread one is 75D polyester-cotton blend composite filament,
Warp thread two is flaxen fiber, and the weft yarn is 32S cotton, and the warp thread one and warp thread two are alternately arranged.The application is fine and smooth, soft and have
It hangs down and feels.
A kind of good environment-friendly plus material of service performance of China Patent Publication No. CN106113757A, including environment-friendly plus material ontology (1),
The upper surface of environment-friendly plus material ontology is provided with longitudinally arranged hollow out jacquard layer (2), and the lower surface of environment-friendly plus material ontology (1) is downward
It is disposed with antistatic layer (5), fireprotection layer (6) and waterproof layer (7).The waterproof layer lower surface is compounded with backing layer, institute
It states backing layer to be weaved by weft, bombax cotton and ramee is respectively adopted in warp and weft, and wherein bombax cotton is straight
Diameter is 4.16 μm, and the diameter of ramee is 18.32 μm, is 16.9/cm through density, and weft density is 26.7/cm.The application
Service performance is good.
China Patent Publication No. CN106113755A one kind is elegant, undeformed environment-friendly plus material, including environment-friendly plus material ontology
(1), the upper surface of environment-friendly plus material ontology is provided with longitudinally arranged hollow out jacquard layer (2), the lower surface of environment-friendly plus material ontology (1)
It is disposed with antistatic layer (5), fireprotection layer (6) and waterproof layer (7) downwards.The waterproof layer lower surface is compounded with lining
Layer, the backing layer are successively combined from top to bottom by velvet layer, spongy layer and base cloth layer.
A kind of dry and comfortable comfortable environment-protection fabric of China Patent Publication No. CN106079602A, including environment-friendly plus material ontology (1), ring
The upper surface of friendly fabric ontology is provided with longitudinally arranged hollow out jacquard layer (2), the lower surface of environment-friendly plus material ontology (1) downwards according to
It is secondary to be provided with antistatic layer (5), fireprotection layer (6) and waterproof layer (7).The waterproof layer lower surface is compounded with backing layer, described
Backing layer, including successively compound pure cotton backing layer, bamboo charcoal fiber backing layer, the blended backing layer of soybean fiber/pure cotton fiber.This
Apply dry and comfortable comfortable.
China Patent Publication No. CN106079646A one kind has far infrared radiation function environment-friendly plus material, including environmentally friendly face
Expect ontology (1), the upper surface of environment-friendly plus material ontology is provided with longitudinally arranged hollow out jacquard layer (2), environment-friendly plus material ontology (1)
Lower surface is disposed with downwards antistatic layer (5), fireprotection layer (6) and waterproof layer (7).The waterproof layer lower surface is compounded with
Backing layer, the backing layer are interweaved by warp thread and weft yarn, and the warp thread and weft yarn are arranged in a mutually vertical manner, wherein institute
Stating warp thread is general fibre yarn, and the weft yarn is far infrared fiber yarn.The application has far infrared radiation function.
A kind of no electrostatic environment-protecting fabric of China Patent Publication No. CN106042495A, including environment-friendly plus material ontology (1), environmental protection
The upper surface of fabric body is provided with longitudinally arranged hollow out jacquard layer (2), and the lower surface of environment-friendly plus material ontology (1) is downwards successively
It is provided with antistatic layer (5), fireprotection layer (6) and waterproof layer (7).The waterproof layer lower surface is compounded with backing layer, the lining
Stamp is printed on inner layer, the backing layer is by the plain loop of 75D/36F and the looped pile coil for elongating sinker loop of 75D/144F
By weft knitting, successively string covers, and one layer of antistatic medicament is attached on the stamp backing layer.The application is without electrostatic.
A kind of good environment-friendly plus material of softness and comfort of China Patent Publication No. CN105965967A, including environment-friendly plus material sheet
Body (1), the upper surface of environment-friendly plus material ontology are provided with longitudinally arranged hollow out jacquard layer (2), the following table of environment-friendly plus material ontology (1)
It is disposed with antistatic layer (5), fireprotection layer (6) and waterproof layer (7) downwards.The waterproof layer lower surface is compounded with lining
Layer, the backing layer, comprising: backing layer ontology, PTFE film and protective film, the PTFE film are arranged in the backing layer ontology
On, the surface of the PTFE film is arranged in the protective film, for protecting the PTFE film.The application softness and comfort
It is good.
China Patent Publication No. CN105919198A moisture absorption environment-friendly plus material, innovative point are: by following mass percent
Raw material composition: flaxen fiber 12~20%, polyamide fibre 10~26%, teflon 2~5% and copper ammonia fiber 6~14%, color cotton and brocade
The blended internal layer as moisture absorption environment-friendly plus material of synthetic fibre, flaxen fiber and the blended interlayer as moisture absorption environment-friendly plus material of wool fibre, cuprammonium are fine
Dimension and the blended surface layer as moisture absorption environment-friendly plus material of teflon.This moisture absorption environment-friendly plus material of the application, fabric is light and comfortable, moisture absorption
Effect is good, using different raw materials is allowed in different positions, the effect of playing moisture absorption, drying and heat preservation；The product of the application makes
If no longer needing to wear with rear, can voluntarily degrade after a period of time, it is time saving and energy saving and environmentally friendly；This product production cost compared with
Low, simple production process improves production efficiency without increasing any processing step.
China Patent Publication No. CN105780264A is related to a kind of production method of environment-friendly plus material, it is characterised in that: it is adopted
With raw material are as follows: warp thread is the A yarn of full-dull polyester filament and the B yarn of polyester filament semi-dull；Weft yarn is that terylene semi-dull is long
The C yarn of silk, wherein being 13:5 through the example of matching to A yarn and B yarn；Its technique is warping technology, sizing technique and axis technique and weaving
Technology；Its organization design is to guarantee the fluffy feel and recovery of fabric using low-tension wefting insertion in weaving process, guarantees clothes
With the comfort of performance.Through adding 31/11 twill protrusion tissue to using plain weave, fabric is made using photo rotary process
Organization chart forms a basic organization unit by two warp thread ratio circulations, is made of always 342 basic organization units through item
Number, broadwise are 1 circulation by 24 weft yarns, are knitted into warp thread to Infinite Cyclic, are made into fabric fabric.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of environment-friendly plus material and its processing methods.
The purpose of the present invention is achieved through the following technical solutions:
A kind of environment-friendly plus material, which is characterized in that the LOI of the environment-friendly plus material is 31~33%, and environment-friendly plus material is at 600 DEG C
Residual carbon content > 10% after high-temperature calcination 15min, environment-friendly plus material UL-94 are V-0 grades.
A kind of processing method of environment-friendly plus material, the specific steps are that:
(1) preparation of high temperature flame-proof agent
With the miscellaneous -10- phosphine phenanthrene -10- oxa- (DOPO) of 9,10- dihydro-9-oxy and four pairs of benzaldehyde base ethylene for raw material, with chlorine
Change zinc is catalyst, and using the method for high-temperature fusion reaction, reaction temperature is 280~290 DEG C and obtains high temperature flame-proof agent；Its chemistry
Structural formula is as follows:
Specific preparation process is as follows:
Catalyst zinc chloride, DOPO and four pair of benzaldehyde base ethylene powder are subjected to mixed at high speed, are then then added to anti-
It answers in kettle, then carries out high-temperature heating reaction under nitrogen protection, then generate moisture content by collecting, control extent of reaction,
Ethylene glycol and dimethyl acetamide mixed solution are added after reaction at 160~180 DEG C after being discharged and reaching theory 99%
Under carry out dissolving unreacted DOPO and four pair of benzaldehyde base ethylene, then crystallisation by cooling obtains high temperature flame-proof agent powder, passes through
It is separated by filtration and is dried in vacuo 24 hours at 120 DEG C again, high temperature flame-proof agent is prepared；
The molar ratio of DOPO and four pair of benzaldehyde base ethylene is 1:0.95~1:1.05,
The mass ratio of the catalyst zinc chloride and DOPO is 1:50~1:100；
The mass ratio of ethylene glycol and dimethyl acetamide mixed solution and DOPO is 1:0.1~1:0.15；
In ethylene glycol and dimethyl acetamide mixed solution, the volume ratio of ethylene glycol and dimethyl acetamide is 1:1.
The high temperature flame-proof agent fusing point is 248~250 DEG C, phosphorus content 9.9wt%.
The reaction temperature of the high-temperature fusion reaction is 280~290 DEG C；
(2) preparation of environmental protection flame retardant fiber
Using chemical method waste and old polyester be prepared to benzene first acid dimethyl (DMT) and ethylene glycol as raw material, raw material warp
Ester exchange reaction, prepolymerization reaction obtain prepolymer, then the high temperature flame-proof agent that addition step (1) is prepared in prepolymer,
It carries out polycondensation reaction and environmental protection flame retardant polyester fondant is prepared in final polycondensation reaction, the spinning then added online using fused mass directly spinning
Silk carries out melt conveying spinning, and environmental protection flame retardant polyester fondant disperses through the mixing of static mixer and dynamic mixer, then through molten
Body distribution plate and spinning spinneret squeeze out to obtain spun filament, and spun filament oils through ring wind quenching, boundling, and drawing-off winding is prepared into
To environmental protection flame retardant fiber.
The molar ratio of the dimethyl terephthalate (DMT) and ethylene glycol is 1:1.05~1:1.35；
The molar ratio of the high temperature flame-proof agent and dimethyl terephthalate (DMT) is 1:0.03~1:0.11；
The transesterification temperature is 230~245 DEG C, and transesterification pressure is 0.15~0.2MPa, and the transesterification time is 2.0
~3.5h；The precondensation temperature be 255~265 DEG C, precondensation vacuum degree be 1~5kPa, the precondensation time be 45~
60min；The condensation temperature is 265~275 DEG C, and polycondensation vacuum degree is 1~2kPa, and the polycondensation time is 60~90min；It is described
Whole condensation temperature be 275~285 DEG C, the poly- vacuum degree of final minification be 100~200Pa, the final minification poly- time be 90~150min；
The fused mass directly spinning melt conveying temperature is 285~290 DEG C, and the spinning temperature of fused mass directly spinning is 275~285
DEG C, circular blow wind wind speed is 0.5m/min, and circular blow air temperature is 23~25 DEG C, and circular blow wind moisture is 40~45RH%, drafting multiple
It is 3.0~3.5 times, spinning speed is 4500~4800m/min.
(3) preparation of environment-friendly plus material
The environmental protection flame retardant fiber and regenerated polyester fiber being prepared using step (2) is raw materials, using the side of knitting and weaving
Environment-friendly plus material is prepared in method, and warp thread is environmental protection flame retardant fiber, and weft yarn is regenerated polyester fiber.
The warp thread of the environment-friendly plus material is environmental protection flame retardant fiber, and the number of warp thread is 150~200 needles/cm.
The weft yarn of the environment-friendly plus material is regenerated polyester fiber, and the number of weft yarn is 150~200 needles/cm.
The environment-friendly plus material with a thickness of 0.5~1.5mm, weaving speed is 600~800m/min.
The environment-friendly plus material is plain weave, a kind of in twill.
The grammes per square metre of the environment-friendly plus material is 80~350g/m2, and bursting strength is 700~1200N.
Compared with prior art, the positive effect of the present invention is:
It is raw material that the application, which utilizes the high temperature flame-proof agent with high temperature resistant and high degree of rigidity structure, by high temperature flame-proof agent
Excellent phenyl ring rigid structure and high phosphor-containing structure improves the excellent flame retardant property of fiber；Using through waste and old polyester fibrosis
The raw material that the dimethyl terephthalate (DMT) that alcoholysis method is prepared is environment-protection fiber is learned, by way of the modified addition of polycondensation,
Fire retardant resistant to high temperature is introduced into polyester matrix, and the ecological effect of environment-protection fiber, while high temperature flame-proof not only can be improved
Agent has melting temperature, can be evenly dispersed in polyester matrix, avoids conventional inorganic fire retardants and is difficult in polyester material
The problem of middle dispersion, causes fibre strength low, and its excellent organic benzene ring structure of heat-resistant fireproof agent and polyester matrix have
There is a good compatibility, and to impart itself material height-oriented in drafting process for rigid structure, to improve fibre
The intensity of dimension；And utilizing regenerated polyester fiber is raw material, assigns fabric excellent reproducibility and environmental protection characteristic.
Detailed description of the invention
The reaction equation schematic diagram of the heat-resistant fireproof agent of Fig. 1 the application；
Fig. 2 is the hydrogen nuclear magnetic resonance figure for the heat-resistant fireproof agent originally asked；
Specific embodiment
The specific embodiment of a kind of environment-friendly plus material of the present invention presented below and its processing method.
Embodiment 1
A kind of processing method of environment-friendly plus material, the specific steps are that:
(1) preparation of high temperature flame-proof agent
With the miscellaneous -10- phosphine phenanthrene -10- oxa- (DOPO) of 9,10- dihydro-9-oxy and four pairs of benzaldehyde base ethylene for raw material, with chlorine
Change zinc is catalyst, and using the method for high-temperature fusion reaction, reaction temperature is 280~290 DEG C and obtains high temperature flame-proof agent；Its chemistry
Structural formula is as follows:
Specific preparation process is as follows:
Catalyst zinc chloride, DOPO and four pair of benzaldehyde base ethylene powder are subjected to mixed at high speed, are then then added to anti-
It answers in kettle, then carries out high-temperature heating reaction under nitrogen protection, then generate moisture content by collecting, control extent of reaction,
Ethylene glycol and dimethyl acetamide mixed solution are added after reaction at 160~180 DEG C after being discharged and reaching theory 99%
Under carry out dissolving unreacted DOPO and four pair of benzaldehyde base ethylene, then crystallisation by cooling obtains high temperature flame-proof agent powder, passes through
It is separated by filtration and is dried in vacuo 24 hours at 120 DEG C again, high temperature flame-proof agent is prepared；Fig. 2 is the agent of the application heat-resistant fireproof
Hydrogen nuclear magnetic resonance map, wherein in map between 6.7~7.5ppm the corresponding characteristic absorption peak for phenyl ring in molecular structure
(a), and due to the multiple spliting structure that the hydrogen of phenyl ring and biphenyl structural occurs in benzene ring structure, while in map~
2.6ppm detects the characteristic absorption peak (b) of methylene, and there was only two groups of characteristic absorption peaks in map, and and be not detected
The characteristic absorption peak (~9.9ppm) of aldehyde group and the characteristic absorption peak (~3.6ppm) of P-H, therefore illustrate DOPO and 1,2,
3,4- react benzaldehyde base ethylene, generate related compound；It is found simultaneously by infrared spectrum in map
The middle miscellaneous 3090cm of discovery-1Under there are double bond characteristic absorption peaks, and in 1300~1400cm-1Nearby have found phenyl ring distinctive three
Group division peak, and in 960~1100cm cm-1The characteristic absorption peak of corresponding P-O and P=O, therefore illustrate to deposit in structure
In double bond structure, and the compound generated is related structure.
The molar ratio of DOPO and four pair of benzaldehyde base ethylene is 1:0.95；
The mass ratio of the catalyst zinc chloride and DOPO is 1:50；
The mass ratio of ethylene glycol and dimethyl acetamide mixed solution and DOPO is 1:0.1；
In ethylene glycol and dimethyl acetamide mixed solution, the volume ratio of ethylene glycol and dimethyl acetamide is 1:1.
The reaction temperature of the high-temperature fusion reaction is 280~290 DEG C；
(2) preparation of environmental protection flame retardant fiber
Using chemical method waste and old polyester be prepared to benzene first acid dimethyl (DMT) and ethylene glycol as raw material, raw material warp
Ester exchange reaction, prepolymerization reaction obtain prepolymer, then the high temperature flame-proof agent that addition step (1) is prepared in prepolymer,
It carries out polycondensation reaction and environmental protection flame retardant polyester fondant is prepared in final polycondensation reaction, the spinning then added online using fused mass directly spinning
Silk carries out melt conveying spinning, and environmental protection flame retardant polyester fondant disperses through the mixing of static mixer and dynamic mixer, then through molten
Body distribution plate and spinning spinneret squeeze out to obtain spun filament, and spun filament oils through ring wind quenching, boundling, and drawing-off winding is prepared into
To environmental protection flame retardant fiber.
The molar ratio of the dimethyl terephthalate (DMT) and ethylene glycol is 1:1.05；
The molar ratio of the high temperature flame-proof agent and dimethyl terephthalate (DMT) is 1:0.03；
The transesterification temperature is 230~245 DEG C, and transesterification pressure is 0.15~0.2MPa, and the transesterification time is 2.0
~3.5h；The precondensation temperature be 255~265 DEG C, precondensation vacuum degree be 1~5kPa, the precondensation time be 45~
60min；The condensation temperature is 265~275 DEG C, and polycondensation vacuum degree is 1~2kPa, and the polycondensation time is 60~90min；It is described
Whole condensation temperature be 275~285 DEG C, the poly- vacuum degree of final minification be 100~200Pa, the final minification poly- time be 90~150min；
The fused mass directly spinning melt conveying temperature is 285~290 DEG C, and the spinning temperature of fused mass directly spinning is 275~285
DEG C, circular blow wind wind speed is 0.5m/min, and circular blow air temperature is 23~25 DEG C, and circular blow wind moisture is 40~45RH%, drafting multiple
It is 3.0~3.5 times, spinning speed is 4500~4800m/min.
(3) preparation of environment-friendly plus material
The environmental protection flame retardant fiber and regenerated polyester fiber being prepared using step (2) is raw materials, using the side of knitting and weaving
Environment-friendly plus material is prepared in method, and warp thread is environmental protection flame retardant fiber, and weft yarn is regenerated polyester fiber.
The warp thread of the environment-friendly plus material is environmental protection flame retardant fiber, and the number of warp thread is 150 needles/cm.
The weft yarn of the environment-friendly plus material is regenerated polyester fiber, and the number of weft yarn is 150 needles/cm.
The environment-friendly plus material with a thickness of 0.5mm, weaving speed 600m/min.
The environment-friendly plus material is plain weave.
The grammes per square metre of the environment-friendly plus material is 80g/m2, bursting strength 700N.
Embodiment 2
A kind of processing method of environment-friendly plus material, the specific steps are that:
(1) preparation of high temperature flame-proof agent
With the miscellaneous -10- phosphine phenanthrene -10- oxa- (DOPO) of 9,10- dihydro-9-oxy and four pairs of benzaldehyde base ethylene for raw material, with chlorine
Change zinc is catalyst, and using the method for high-temperature fusion reaction, reaction temperature is 280~290 DEG C and obtains high temperature flame-proof agent；Its chemistry
Structural formula is as follows:
Specific preparation process is as follows:
Catalyst zinc chloride, DOPO and four pair of benzaldehyde base ethylene powder are subjected to mixed at high speed, are then then added to anti-
It answers in kettle, then carries out high-temperature heating reaction under nitrogen protection, then generate moisture content by collecting, control extent of reaction,
Ethylene glycol and dimethyl acetamide mixed solution are added after reaction at 160~180 DEG C after being discharged and reaching theory 99%
Under carry out dissolving unreacted DOPO and four pair of benzaldehyde base ethylene, then crystallisation by cooling obtains high temperature flame-proof agent powder, passes through
It is separated by filtration and is dried in vacuo 24 hours at 120 DEG C again, high temperature flame-proof agent is prepared；
The molar ratio of DOPO and four pair of benzaldehyde base ethylene is 1:1.05,
The mass ratio of the catalyst zinc chloride and DOPO is 1:100；
The mass ratio of ethylene glycol and dimethyl acetamide mixed solution and DOPO is 1:0.15；
In ethylene glycol and dimethyl acetamide mixed solution, the volume ratio of ethylene glycol and dimethyl acetamide is 1:1.
The high temperature flame-proof agent fusing point is 248~250 DEG C, phosphorus content 9.9wt%.
The reaction temperature of the high-temperature fusion reaction is 280~290 DEG C；
(2) preparation of environmental protection flame retardant fiber
Using chemical method waste and old polyester be prepared to benzene first acid dimethyl (DMT) and ethylene glycol as raw material, raw material warp
Ester exchange reaction, prepolymerization reaction obtain prepolymer, then the high temperature flame-proof agent that addition step (1) is prepared in prepolymer,
It carries out polycondensation reaction and environmental protection flame retardant polyester fondant is prepared in final polycondensation reaction, the spinning then added online using fused mass directly spinning
Silk carries out melt conveying spinning, and environmental protection flame retardant polyester fondant disperses through the mixing of static mixer and dynamic mixer, then through molten
Body distribution plate and spinning spinneret squeeze out to obtain spun filament, and spun filament oils through ring wind quenching, boundling, and drawing-off winding is prepared into
To environmental protection flame retardant fiber.
The molar ratio of the dimethyl terephthalate (DMT) and ethylene glycol is 1:1.35；
The molar ratio of the high temperature flame-proof agent and dimethyl terephthalate (DMT) is 1:0.11；
The transesterification temperature is 230~245 DEG C, and transesterification pressure is 0.15~0.2MPa, and the transesterification time is 2.0
~3.5h；The precondensation temperature be 255~265 DEG C, precondensation vacuum degree be 1~5kPa, the precondensation time be 45~
60min；The condensation temperature is 265~275 DEG C, and polycondensation vacuum degree is 1~2kPa, and the polycondensation time is 60~90min；It is described
Whole condensation temperature be 275~285 DEG C, the poly- vacuum degree of final minification be 100~200Pa, the final minification poly- time be 90~150min；
The fused mass directly spinning melt conveying temperature is 285~290 DEG C, and the spinning temperature of fused mass directly spinning is 275~285
DEG C, circular blow wind wind speed is 0.5m/min, and circular blow air temperature is 23~25 DEG C, and circular blow wind moisture is 40~45RH%, drafting multiple
It is 3.0~3.5 times, spinning speed is 4500~4800m/min.
(3) preparation of environment-friendly plus material
The environmental protection flame retardant fiber and regenerated polyester fiber being prepared using step (2) is raw materials, using the side of knitting and weaving
Environment-friendly plus material is prepared in method, and warp thread is environmental protection flame retardant fiber, and weft yarn is regenerated polyester fiber.
The warp thread of the environment-friendly plus material is environmental protection flame retardant fiber, and the number of warp thread is 200 needles/cm.
The weft yarn of the environment-friendly plus material is regenerated polyester fiber, and the number of weft yarn is 200 needles/cm.
The environment-friendly plus material with a thickness of 1.5mm, weaving speed 800m/min.
The environment-friendly plus material is twill.
The grammes per square metre of the environment-friendly plus material is 350g/m2, bursting strength 1200N.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
Member, without departing from the inventive concept of the premise, can also make several improvements and modifications, these improvements and modifications also should be regarded as
In protection scope of the present invention.
Claims (9)
1. a kind of environment-friendly plus material, which is characterized in that the LOI of environment-friendly plus material is 31~33%, and environment-friendly plus material is in 600 DEG C of high-temperature calcinations
Residual carbon content > 10% after 15min, the UL-94 of environment-friendly plus material are V-0 grades.
2. a kind of processing method of environment-friendly plus material as described in claim 1, which is characterized in that the specific steps are that:
(1) preparation of high temperature flame-proof agent
With the miscellaneous -10- phosphine phenanthrene -10- oxa- (DOPO) of 9,10- dihydro-9-oxy and four pairs of benzaldehyde base ethylene for raw material, with zinc chloride
For catalyst, the method reacted using high-temperature fusion, reaction temperature is 280~290 DEG C and obtains high temperature flame-proof agent；Its chemical structure
Formula is as follows:
(2) preparation of environmental protection flame retardant fiber
Using chemical method waste and old polyester be prepared to benzene first acid dimethyl (DMT) and ethylene glycol as raw material, raw material is handed over through ester
Change reaction, prepolymerization reaction obtains prepolymer, then the high temperature flame-proof agent that is prepared of step (1) is added in prepolymer, carry out
Environmental protection flame retardant polyester fondant is prepared in polycondensation reaction and final polycondensation reaction, the spinning then added online using fused mass directly spinning into
Row melt conveying spinning, environmental protection flame retardant polyester fondant disperse through the mixing of static mixer and dynamic mixer, then through melt point
Matching board and spinning spinneret squeeze out to obtain spun filament, and spun filament oils through ring wind quenching, boundling, and ring is prepared in drawing-off winding
Environment friendly flame-retardant fiber；
(3) preparation of environment-friendly plus material
The environmental protection flame retardant fiber and regenerated polyester fiber being prepared using step (2) is raw materials, using the method for knitting and weaving,
Environment-friendly plus material is prepared, warp thread is environmental protection flame retardant fiber, and weft yarn is regenerated polyester fiber.
3. a kind of processing method of environment-friendly plus material as claimed in claim 2, which is characterized in that the terephthalic acid (TPA) diformazan
The molar ratio of ester and ethylene glycol is 1:1.05~1:1.35.
4. a kind of processing method of environment-friendly plus material as claimed in claim 2, which is characterized in that the high temperature flame-proof agent with it is right
The molar ratio of rutgers is 1:0.03~1:0.11.
5. a kind of processing method of environment-friendly plus material as claimed in claim 2, which is characterized in that the transesterification temperature is
230~245 DEG C, transesterification pressure is 0.15~0.2MPa, and the transesterification time is 2.0~3.5h；The precondensation temperature is
255~265 DEG C, precondensation vacuum degree is 1~5kPa, and the precondensation time is 45~60min；The condensation temperature be 265~
275 DEG C, polycondensation vacuum degree is 1~2kPa, and the polycondensation time is 60~90min；The whole condensation temperature is 275~285 DEG C, eventually
Polycondensation vacuum degree is 100~200Pa, and the final minification poly- time is 90~150min.
6. a kind of processing method of environment-friendly plus material as claimed in claim 2, which is characterized in that the warp thread of the environment-friendly plus material
For environmental protection flame retardant fiber, and the number of warp thread is 150~200 needles/cm.
7. a kind of processing method of environment-friendly plus material as claimed in claim 2, which is characterized in that the weft yarn of the environment-friendly plus material
For regenerated polyester fiber, and the number of weft yarn is 150~200 needles/cm.
8. a kind of processing method of environment-friendly plus material as claimed in claim 2, which is characterized in that the thickness of the environment-friendly plus material
For 0.5~1.5mm, weaving speed is 600~800m/min.
9. a kind of processing method of environment-friendly plus material as claimed in claim 2, which is characterized in that the environment-friendly plus material is flat
It is a kind of in line, twill.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910692794 | 2019-07-30 | ||
| CN2019106927945 | 2019-07-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110468484A true CN110468484A (en) | 2019-11-19 |
| CN110468484B CN110468484B (en) | 2020-11-24 |
Family
ID=68509245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910709309.0A Active CN110468484B (en) | 2019-07-30 | 2019-08-02 | Environment-friendly fabric and processing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110468484B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11976390B2 (en) * | 2022-09-29 | 2024-05-07 | Sachin JHUNJHUNWALA | Woven textile fabric |
| US11982026B2 (en) * | 2022-09-29 | 2024-05-14 | Sachin JHUNJHUNWALA | Woven textile fabric |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002525449A (en) * | 1998-09-28 | 2002-08-13 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Flame resistant fabric |
| CN103328702A (en) * | 2010-11-17 | 2013-09-25 | Frx聚合物股份有限公司 | Phosphonate polymers, copolymers, and their respective oligomers as flame retardants for polyester fibers |
| KR101577171B1 (en) * | 2015-09-23 | 2015-12-11 | 주식회사 나노코 | Phosphorus Nitrogen Complex Reacted Type Resin Having Electro-Mechanical Properties And Composition Thereof |
| CN106350892A (en) * | 2016-08-24 | 2017-01-25 | 福建省百凯经编实业有限公司 | Anti-flaming tricot lace fabric and production method thereof |
| CN106518926A (en) * | 2016-11-09 | 2017-03-22 | 湖北大学 | Preparation method of water soluble benzoxazine resin containing DOPO |
| KR20170112568A (en) * | 2016-03-31 | 2017-10-12 | 도레이케미칼 주식회사 | Interior fiber, manufacturing method thereof, and blind including thereof |
| CN109763193A (en) * | 2018-12-26 | 2019-05-17 | 澳帕曼安全织带(昆山)有限公司 | The fire-retardant enhancing dacron thread of one kind, ribbon and preparation method |
-
2019
- 2019-08-02 CN CN201910709309.0A patent/CN110468484B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002525449A (en) * | 1998-09-28 | 2002-08-13 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | Flame resistant fabric |
| CN103328702A (en) * | 2010-11-17 | 2013-09-25 | Frx聚合物股份有限公司 | Phosphonate polymers, copolymers, and their respective oligomers as flame retardants for polyester fibers |
| KR101577171B1 (en) * | 2015-09-23 | 2015-12-11 | 주식회사 나노코 | Phosphorus Nitrogen Complex Reacted Type Resin Having Electro-Mechanical Properties And Composition Thereof |
| KR20170112568A (en) * | 2016-03-31 | 2017-10-12 | 도레이케미칼 주식회사 | Interior fiber, manufacturing method thereof, and blind including thereof |
| CN106350892A (en) * | 2016-08-24 | 2017-01-25 | 福建省百凯经编实业有限公司 | Anti-flaming tricot lace fabric and production method thereof |
| CN106518926A (en) * | 2016-11-09 | 2017-03-22 | 湖北大学 | Preparation method of water soluble benzoxazine resin containing DOPO |
| CN109763193A (en) * | 2018-12-26 | 2019-05-17 | 澳帕曼安全织带(昆山)有限公司 | The fire-retardant enhancing dacron thread of one kind, ribbon and preparation method |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11976390B2 (en) * | 2022-09-29 | 2024-05-07 | Sachin JHUNJHUNWALA | Woven textile fabric |
| US11982026B2 (en) * | 2022-09-29 | 2024-05-14 | Sachin JHUNJHUNWALA | Woven textile fabric |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110468484B (en) | 2020-11-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102383235B (en) | Ecological bacteriostatic breathable smooth tatting fabric | |
| CN108773132A (en) | A kind of warming napping composite material and its processing technology | |
| CN204265955U (en) | A kind of mercerising suede warp-knitted face fabric | |
| JP7433332B2 (en) | Yarn-dyed cotton polyester fabric, its manufacturing method, and use | |
| CN109501416A (en) | A kind of production technology of the super imitative cotton face fabric of moisture absorption waterproof and breathable elastic flame | |
| CN102416735B (en) | Hierarchical coating ultraviolet-resistant composite fabric | |
| CN106381595B (en) | A kind of air layer fabric and its method for weaving | |
| CN111005230B (en) | Sport cotton type fabric and production method thereof | |
| CN110468484A (en) | A kind of environment-friendly plus material and its processing method | |
| CN103541135A (en) | Light and thin thermal insulation knitting fabric and purpose thereof | |
| CN111172646A (en) | Twill woven cool fabric | |
| CN110965186A (en) | Multiple regenerated cellulose fiber functional fabric | |
| CN107630285A (en) | A kind of high-elastic woollen blanket of antibiotic health care type and its production technology | |
| CN110438578A (en) | A kind of color-changing face fabric and its production method | |
| CN101191273A (en) | Four sides elasticity chamois flannel | |
| CN106350892B (en) | Anti-flaming tricot lace fabric and production method thereof | |
| JP2004044059A (en) | Combined yarn and combined woven/knitted fabric | |
| CN110468463B (en) | High-end knitted fabric and processing method thereof | |
| CN105780284A (en) | Moisture-absorption and heat-generation warp-knitted fabric and processing method of moisture-absorption and heat-generation warp-knitted fabric | |
| CN110295444A (en) | A kind of antistatic, moisture absorbing and sweat releasing color knits the product design and production technology of interwoven fabric | |
| CN206204535U (en) | A kind of air layer fabric | |
| CN216891440U (en) | Filament hollow weft-knitted fabric | |
| CN211897256U (en) | Twill woven cool fabric | |
| CN211645522U (en) | Fine denier polyethylene super cool fabric and garment | |
| CN212472653U (en) | Spandex-free elastic fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |