CN110461776A - 基于超临界水氧化的反应器、反应系统及含酚废水处理方法 - Google Patents

基于超临界水氧化的反应器、反应系统及含酚废水处理方法 Download PDF

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CN110461776A
CN110461776A CN201780053915.0A CN201780053915A CN110461776A CN 110461776 A CN110461776 A CN 110461776A CN 201780053915 A CN201780053915 A CN 201780053915A CN 110461776 A CN110461776 A CN 110461776A
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reactor
water
pipe
branch
wastewater
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CN110461776B (zh
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张凤鸣
苏闯建
陈久林
杨杰
贾翠杰
陈顺权
黄振飞
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Guangzhou Institute of Advanced Technology of CAS
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
    • B01J3/008—Processes carried out under supercritical conditions
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/02—Treatment of water, waste water, or sewage by heating
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/02—Treatment of water, waste water, or sewage by heating
    • C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/72—Treatment of water, waste water, or sewage by oxidation
    • C02F1/727—Treatment of water, waste water, or sewage by oxidation using pure oxygen or oxygen rich gas
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0053—Details of the reactor
    • B01J19/0073—Sealings
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00—Treatment of sludge; Devices therefor
    • C02F11/06—Treatment of sludge; Devices therefor by oxidation
    • C02F11/08—Wet air oxidation
    • C02F11/086—Wet air oxidation in the supercritical state
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/30—Organic compounds
    • C02F2101/34—Organic compounds containing oxygen
    • C02F2101/345—Phenols
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    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/002—Construction details of the apparatus
    • C02F2201/003—Coaxial constructions, e.g. a cartridge located coaxially within another
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/002—Construction details of the apparatus
    • C02F2201/004—Seals, connections
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00—Apparatus for treatment of water, waste water or sewage
    • C02F2201/002—Construction details of the apparatus
    • C02F2201/005—Valves
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00—Controlling or monitoring parameters in water treatment
    • C02F2209/02—Temperature
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00—General aspects of water treatment
    • C02F2301/06—Pressure conditions
    • C02F2301/066—Overpressure, high pressure
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
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  • Chemical Kinetics & Catalysis (AREA)
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Abstract

一种基于超临界水氧化的反应器，该反应器包括内壳和外壳；内壳同轴设置于外壳中；内壳分为上部圆柱和下部圆锥两部分；圆柱包括上段无孔管(1411)和下段直筒多孔管(1404)，圆锥为锥形多孔壁(1407)；外壳包括上部连接法兰、中部直筒承压壁(1403)和下部锥形承压壁(1409)；内壳的圆柱部分与直筒承压壁(1403)、连接法兰之间形成第一环隙；锥形多孔壁(1407)与锥形承压壁(1409)之间形成第二环隙；在第一环隙和第二环隙间设置有分隔环(1405)；直筒承压壁(1403)的上部设置有高温蒸发水注入管(1402)；锥形承压壁(1409)的上部设置有低温蒸发水注入管(1406)；锥形承压壁(1409)的底部设置有出口管(1408)；连接法兰上同轴设置有喷嘴管(1401)，且喷嘴管(1401)穿过内壳顶部中心。还公开了一种基于超临界水氧化的反应系统及一种含酚废水处理方法。

Description

PCT国内申请，说明书已公开。

Claims (18)

  1. PCT国内申请，权利要求书已公开。
CN201780053915.0A 2016-09-06 2017-09-05 基于超临界水氧化的反应器、反应系统及含酚废水处理方法 Active CN110461776B (zh)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114702159A (zh) * 2022-03-31 2022-07-05 深圳市华尔信环保科技有限公司 一种催化剂循环型超临界水氧化器及超临界水氧化系统
CN114735802A (zh) * 2022-03-31 2022-07-12 深圳市华尔信环保科技有限公司 一种纳米颗粒制备耦合有机废液降解的超临界水系统
CN114772775A (zh) * 2022-03-31 2022-07-22 深圳市华尔信环保科技有限公司 一种热量自供型超临界水制氢系统
CN114857598A (zh) * 2022-04-29 2022-08-05 西安交通大学 基于超临界水处理技术的氧化反应-余热回收一体化装置

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106219725B (zh) * 2016-09-06 2019-06-21 广州中国科学院先进技术研究所 一种超临界水氧化反应器
CN108217910A (zh) * 2018-04-01 2018-06-29 南通市华安超临界萃取有限公司 一种超临界流体水氧化废水处理装置
CN111417598B (zh) * 2018-08-07 2021-10-22 中国科学院深圳先进技术研究院 一种处理高盐高有机废水并回收能量的系统及方法
CN110642363B (zh) * 2019-10-22 2024-04-09 西安交通大学 一种分级强化有机物污染物降解的多功能超临界水反应器
CN111018087B (zh) * 2019-12-26 2021-11-30 一重集团大连工程技术有限公司 一种超临界水氧化系统反应器的内衬管及制备方法
CN111056616B (zh) * 2019-12-26 2022-07-22 一重集团大连工程技术有限公司 一种空气为氧化剂的超临界水氧化系统及启动方法
CN115605440A (zh) * 2020-03-23 2023-01-13 广州先进技术研究所（Cn） 处理高含固量有机废弃物的超临界水氧化反应器及其系统
CN111499072B (zh) * 2020-04-30 2023-08-25 克拉玛依九工环保技术有限公司 一种针对含盐废水中挥发酚的零排放处理系统及工艺
CN111620432A (zh) * 2020-06-12 2020-09-04 中国科学院上海应用物理研究所 一种旋风式超临界水氧化反应器
CN114772698B (zh) * 2022-03-31 2024-01-05 深圳市华尔信环保科技有限公司 一种有机废液超临界水氧化系统
CN114890384B (zh) * 2022-05-07 2023-09-26 深圳市沃尔奔达新能源股份有限公司 一种分布式能源供给系统
CN115180709B (zh) * 2022-07-06 2023-08-22 深圳市华尔信环保科技有限公司 一种采油废水处理及超临界多元热流体发生系统
CN115180708B (zh) * 2022-07-06 2023-08-22 深圳市华尔信环保科技有限公司 一种超临界水气化反应器及能量利用系统
CN115159757B (zh) * 2022-07-06 2023-07-25 深圳市华尔信环保科技有限公司 一种高盐有机废水超临界水气化反应系统

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101164912A (zh) * 2007-09-29 2008-04-23 山东大学 一种耐腐蚀防堵塞的超临界水氧化反应器
CN101555060A (zh) * 2009-05-20 2009-10-14 南京工业大学 一种超临界水氧化反应器
CN103951004A (zh) * 2014-04-29 2014-07-30 西安交通大学 基于超临界水热反应的含酚废水处理系统及方法
CN104445572A (zh) * 2014-12-05 2015-03-25 内蒙古天一环境技术有限公司 多层喷烧的蒸发壁式超临界水氧化反应器
US20150299015A1 (en) * 2012-04-23 2015-10-22 Xi'an Jiaotong University Method for controlling desalination and salt discharging in supercritical water oxidation system
CN105130080A (zh) * 2015-09-08 2015-12-09 广州中国科学院先进技术研究所 一种超临界水氧化处理高挥发性有机废水的系统与方法
CN106219725A (zh) * 2016-09-06 2016-12-14 广州中国科学院先进技术研究所 一种超临界水氧化反应器

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100484682B1 (ko) * 2002-12-24 2005-04-20 코오롱건설주식회사 폐액 산화 분해 장치 및 이를 이용한 폐액 산화 분해 시스템
CN102659232A (zh) * 2012-04-23 2012-09-12 西安交通大学 含盐废水处理用超临界析盐脱盐器
CN103708599B (zh) * 2012-09-29 2015-10-21 新奥科技发展有限公司 超临界水氧化反应装置和方法
EP2740529A1 (en) * 2012-12-07 2014-06-11 HYDROTHERMA Swiss Ecological Technologies SA Methods and equipment for hydrothermal processing and disposal of highly toxic substances, waste and metal powders
CN104671388B (zh) * 2015-01-28 2016-08-24 广州中国科学院先进技术研究所 一种以空气作为保护膜的超临界水氧化系统及反应工艺
CN105130081B (zh) * 2015-09-08 2017-11-10 广州中国科学院先进技术研究所 一种超临界水氧化处理低挥发性有机废水的系统与方法

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101164912A (zh) * 2007-09-29 2008-04-23 山东大学 一种耐腐蚀防堵塞的超临界水氧化反应器
CN101555060A (zh) * 2009-05-20 2009-10-14 南京工业大学 一种超临界水氧化反应器
US20150299015A1 (en) * 2012-04-23 2015-10-22 Xi'an Jiaotong University Method for controlling desalination and salt discharging in supercritical water oxidation system
CN103951004A (zh) * 2014-04-29 2014-07-30 西安交通大学 基于超临界水热反应的含酚废水处理系统及方法
CN104445572A (zh) * 2014-12-05 2015-03-25 内蒙古天一环境技术有限公司 多层喷烧的蒸发壁式超临界水氧化反应器
CN105130080A (zh) * 2015-09-08 2015-12-09 广州中国科学院先进技术研究所 一种超临界水氧化处理高挥发性有机废水的系统与方法
CN106219725A (zh) * 2016-09-06 2016-12-14 广州中国科学院先进技术研究所 一种超临界水氧化反应器

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
敬育民: "《环境监测常用检测检验数据手册 上》", 31 October 2003 *
祁鲁梁: "《水处理工艺与运行管理实用手册》", 31 May 2002 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114702159A (zh) * 2022-03-31 2022-07-05 深圳市华尔信环保科技有限公司 一种催化剂循环型超临界水氧化器及超临界水氧化系统
CN114735802A (zh) * 2022-03-31 2022-07-12 深圳市华尔信环保科技有限公司 一种纳米颗粒制备耦合有机废液降解的超临界水系统
CN114772775A (zh) * 2022-03-31 2022-07-22 深圳市华尔信环保科技有限公司 一种热量自供型超临界水制氢系统
CN114702159B (zh) * 2022-03-31 2023-04-18 深圳市华尔信环保科技有限公司 一种催化剂循环型超临界水氧化器及超临界水氧化系统
CN114735802B (zh) * 2022-03-31 2023-08-22 深圳市华尔信环保科技有限公司 一种纳米颗粒制备耦合有机废液降解的超临界水系统
CN114772775B (zh) * 2022-03-31 2024-02-09 深圳市华尔信环保科技有限公司 一种热量自供型超临界水制氢系统
CN114857598A (zh) * 2022-04-29 2022-08-05 西安交通大学 基于超临界水处理技术的氧化反应-余热回收一体化装置

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WO2018045951A1 (zh) 2018-03-15
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CN110461776B (zh) 2021-12-07
US20190248685A1 (en) 2019-08-15
US10457579B2 (en) 2019-10-29

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