CN110461151A - 溶剂型木材防腐剂组合物 - Google Patents
溶剂型木材防腐剂组合物 Download PDFInfo
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- CN110461151A CN110461151A CN201880020470.0A CN201880020470A CN110461151A CN 110461151 A CN110461151 A CN 110461151A CN 201880020470 A CN201880020470 A CN 201880020470A CN 110461151 A CN110461151 A CN 110461151A
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- oil
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- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims description 6
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- LQDARGUHUSPFNL-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)-3-(1,1,2,2-tetrafluoroethoxy)propyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(COC(F)(F)C(F)F)CN1C=NC=N1 LQDARGUHUSPFNL-UHFFFAOYSA-N 0.000 claims description 5
- ULCWZQJLFZEXCS-UHFFFAOYSA-N 1-[[2-(2,4-dichlorophenyl)-5-(2,2,2-trifluoroethoxy)oxolan-2-yl]methyl]-1,2,4-triazole Chemical compound O1C(OCC(F)(F)F)CCC1(C=1C(=CC(Cl)=CC=1)Cl)CN1N=CN=C1 ULCWZQJLFZEXCS-UHFFFAOYSA-N 0.000 claims description 5
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Classifications
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- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/003—Treating of wood not provided for in groups B27K1/00, B27K3/00 by using electromagnetic radiation or mechanical waves
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Abstract
本发明公开了木材防腐剂组合物,其包含在低芳族含量的溶剂载体中的颗粒铜化合物。颗粒铜分散体在该组合物中表现出优异的稳定性,并且用该组合物处理的木材免受木腐菌和白蚁的侵袭。本发明也涉及木材防腐剂组合物,其包含:(a.)可生物降解的有机溶剂载体,所述可生物降解的有机溶剂载体选自植物油、可再生资源油和生物柴油;(b.)粒径为约0.005微米至约10微米的金属化合物固体颗粒的分散体;(c.)有机杀生物剂;和(d.)分散剂;分散剂与金属化合物的比率为约1:500至约100:1(wt/wt)。本发明也涉及包含氟唑菌苯胺和溶剂载体的组合物。本发明也涉及使用该组合物处理木材的方法,以及用公开的组合物和方法处理的木材。
Description
本申请要求了2017年3月24日提交的美国临时申请序列号62/476,067的优先权,将其整个内容通过引用并入本申请。本申请引用的所有专利、印刷出版物和参考文献的整个内容都通过引用并入本申请。
技术领域
本发明涉及木材防腐剂组合物及使用该组合物用于保护木材和木材产品免受木腐菌、昆虫和白蚁生物侵袭的方法。
背景技术
木材防腐组合物用于保护木材和其它基于纤维素的材料例如纸、刨花板、纺织品、绳索等免受木材破坏生物(例如真菌和昆虫)的侵袭。常规的木材防腐组合物通常在溶剂载体中含有金属化合物、有机杀生物剂或金属化合物与有机杀生物剂这两者。用于木材防腐制剂的金属化合物的一些实例是铜、锌、锡、硼、氟的化合物。已用于木材防腐制剂的有机杀生物剂的一些实例包括杀虫剂、杀真菌剂、杀霉剂、除藻剂、杀细菌剂,其已直接溶解在含油载体中。这种化合物的实例为唑类、氨基甲酸酯类、异噻唑啉酮类、硫氰酸酯类、亚磺酰胺类、季鏻类化合物、季铵化合物、腈类、吡啶类等,以及这些化合物的协同混合物。
在有机溶剂载体中一起制备这种金属和有机化合物是合乎需要的,因为有机溶剂载体可赋予纤维素基质如木材防水性和尺寸稳定性,并且不会引起处理的木材或木料的溶胀。然而,尽管许多发明人付出了努力,但制备含有颗粒的固体分散体的有机载体防腐剂/杀生物剂系统是困难的或不可能的。迄今为止,金属化合物已经作为可溶性金属络合物加入到有机载体中,或者金属化合物溶解在有机载体中以增强它们在有机溶剂中的处理特性。例如,环烷酸铜(CuN),一种常见的溶剂型铜基防腐剂,其为与环烷酸络合并且溶解在烃溶剂中的铜离子溶液。另一实例为羟基喹啉铜木材防腐剂。羟基喹啉铜是一种溶于烃类溶剂中的8-喹啉铜(Cu8)络合物。CuN和Cu8木材防腐剂在2016年美国木材保护协会(AWPA)标准手册中分别列为P36-16和P37-11。
将金属化合物加入到有机载体中的另一技术为形成油包水乳液,其中金属化合物作为金属络合物溶解在水中,然后将水性金属络合物与乳化化合物混合,以制备油包水乳液。然而,由于乳液在高剪切混合下的敏感性或当制剂从储罐转移到处理罐时,在木材真空压力处理期间使用这些油包水乳液存在稳定性和相容性问题。
结果,仍然存在对制备在有机溶剂载体中含有金属化合物的稳定木材防腐剂组合物的未满足的需求。因此,通过在溶剂载体中使用分散的颗粒金属化合物(特别是铜化合物)的组合物来满足这种需求是本发明的目的之一。颗粒铜化合物例如碱式碳酸铜在存在于水性介质中时为有效的抵抗腐朽菌和白蚁的杀真菌剂,因为它们可以在水溶液中释放铜离子。
当颗粒铜化合物用于有机溶剂载体时,其释放离子铜的能力及其抵抗腐朽菌的效力是未知的。我们惊奇地发现,有机溶剂载体中的颗粒铜抵抗木腐菌也是有效的。
木材防腐剂制剂通常使用水作为载体来制备。然而,有机溶剂载体也用于许多防腐剂系统,例如轻质有机溶剂防腐剂(LOSP)处理、木榴油处理、五氯苯酚(PCP)处理或环烷酸铜(CuN)处理。2016年美国木材保护协会(AWPA)标准手册列出了几种标准化的有机溶剂系统,例如HAS-14、HSC-11、HSF-11、HSG-11和HSH-14,其用作木材防腐剂的载体。
这些溶剂例如LOSP溶剂或PCP/Cu-Nap/木馏油溶剂中的大多数由于芳族化合物的存在而具有强烈的气味。芳族化合物的存在不仅会产生强烈的气味,而且这还会引起工人暴露其中的担忧。结果,本发明的另一目的为通过在木材防腐剂制剂中使用替代性有机溶剂载体来克服与有机溶剂相关的气味和健康问题。此外,我们意外地发现,使用含有低芳族含量或基本上不含芳族含量的有机溶剂来制备本发明的颗粒铜制剂可以提高制剂的粒径和分散稳定性。
用包含在有机载体中的颗粒化合物的木材防腐剂制剂处理木材时经常遇到的另一问题称为“失效”或“沉降(fallout)”。许多时候,用这些制剂处理的木材在木材表面上将会留下残留物。残留物是由于颗粒化合物的附聚/聚集引起的,并且可以在处理的木材表面上看到。通过在木材上过滤颗粒化合物形成残留物,这是由颗粒化合物的附聚产生的。失效和沉降现象是不利的,因为附聚阻止颗粒化合物有效地渗透到木材中。表面沉积物如残留残留物对环境也有害,因为处理的木材在投入使用时会将残留物丧失到周围的地面或水中。这种物质的丧失导致对真菌腐烂和昆虫侵袭的抵抗力降低。本发明的发明人惊奇地发现,具有低芳族含量的有机载体与某些特定的颗粒铜化合物和分散剂的组合为用于处理木材的有效木材防腐制剂,并且不会导致失效或沉降现象。
本发明涉及稳定的木材防腐剂组合物,其包含在低芳族含量的有机溶剂载体中的颗粒铜化合物。令人惊奇地发现,本发明的颗粒铜组合物抵抗腐朽菌是有效的。此外,本发明的组合物具有低芳族含量和低气味。此外,本发明组合物的令人惊奇的方面为颗粒铜颗粒在低芳族含量的有机溶剂载体中具有优异的稳定性。这种优异的稳定性有利于使用本发明的木材防腐剂组合物对木材进行压力浸渍。
发明内容
本发明提供用于使木材防腐的组合物和方法。组合物包含颗粒金属化合物、具有低芳族含量或没有芳族含量的有机溶剂载体、和分散剂。令人惊奇地发现,颗粒金属化合物抵抗木腐菌是有效的。此外,颗粒分散制剂具有优异的保质期稳定性。本发明中公开的低芳族含量的溶剂通常是指芳族含量小于22%v/v、或优选小于8%v/v、小于5%v/v、小于1%v/v、小于0.1%v/v或基本上0.0%v/v的任何烃溶剂。
在某些实施方案中,本发明涉及处理木材或木材产品的方法,其包括使木材或木材产品与颗粒金属木材防腐剂组合物在低芳烃溶剂中接触的步骤。
在另一实施方案中,颗粒状防腐剂组合物可以进一步含有有机杀生物剂,例如三唑杀真菌剂或吡唑杀真菌剂。颗粒金属与有机杀生物剂的比率为约1:1至约500:1。
在某些实施方案中,本发明组合物中的金属化合物为微粉化铜化合物、低芳族含量的溶剂和分散剂。微粉化铜组合物可进一步包含三唑化合物。本发明的微粉化铜组合物的三唑包括但不限于氧环唑(azaconazole);糠菌唑(bromuconazole);环菌唑(cyproconazole);苄氯三唑醇(diclobutrazol);苯醚甲环唑(difenoconazole);烯唑醇(diniconazole);烯唑醇-M(diniconazole-M);氟环唑(epoxiconazole);乙环唑(etaconazole);腈苯唑(fenbuconazole);氟喹唑(fluquinconazole);氟硅唑(flusilazole);粉唑醇(flutriafol);呋菌唑(furconazole);呋醚唑(furconazole-cis);己唑醇(hexaconazole);亚胺唑(imibenconazole);种菌唑(ipconazole);ipfentrifluconazole;mefentrifluconazole;叶菌唑(metconazole);腈菌唑(myclobutanil);戊菌唑(penconazole);丙环唑(propiconazole);丙硫菌唑(prothioconazole);唑喹菌酮(quinconazole);硅氟唑(simeconazole);戊唑醇(tebuconazole);四氟醚唑(tetraconazole);三唑酮(triadimefon);三唑醇(triadimenol);灭菌唑(triticonazole);烯效唑(uniconazole);烯效唑-P(uniconazole-P)。
在某些实施方案中,本发明的木材防腐剂组合物包括金属化合物(其为微粉化铜化合物)、低芳族含量的溶剂和分散剂。微粉化铜组合物可进一步包含吡唑杀真菌剂。吡唑的实例包括但不限于苯丙烯氟菌唑(benzovindiflupyr);联苯吡菌胺(bixafen);胺苯吡菌酮(fenpyrazamine);氟唑菌酰胺(fluxapyroxad);呋吡菌胺(furametpyr);吡唑萘菌胺(isopyrazam);oxathiapiprolin;氟唑菌苯胺(penflufen);吡噻菌胺(penthiopyrad);氟唑菌酰羟胺(pydiflumetofen);吡唑醚菌酯(pyraclostrobin);唑胺菌酯(pyrametostrobin);唑菌酯(pyraoxystrobin);吡咪唑(rabenzazole);氟唑环菌胺(sedaxane)。在某些实施方案中,本发明的木材防腐剂组合物包含:(a.)可生物降解的有机溶剂载体,所述可生物降解的有机溶剂载体选自植物油、可再生资源油和生物柴油;(b.)粒径为约0.005微米至约10微米的金属化合物固体颗粒的分散体;(c.)有机杀生物剂;和(d.)分散剂;其中所述分散剂与所述金属化合物的比率为约1:500至约100:1(wt/wt)。
在某些实施方案中,本发明的木材防腐剂包含为植物油的有机溶剂,所述植物油选自:亚麻籽油、椰子油、玉米油、棉子油、橄榄油、棕榈油、低芥酸菜子油、棕榈仁油、花生油、菜子油、红花油、芝麻油、大豆油、葵花油、蓖麻油、桐油、罂粟籽油、斑鸠菊油(vernoniaoil)、杏仁油、山毛榉坚果油、巴西坚果油、初榨橄榄油、腰果油、榛子油、澳洲坚果油、蒙刚果油(mongongo nut oil)(或曼杰提树油(manketti oil))、胡桃油、松子油、阿月浑子油、核桃油、南瓜子油、巴卡斯果油(pracaxi oil)、葡萄子油、米糠油、烛果油和大麻子油。
在某些实施方案中,木材防腐剂组合物包含为可再生资源油和/或生物柴油的有机溶剂,所述可再生资源油和/或生物柴油选自基于妥尔油、植物油和动物脂肪的柴油,其中所述柴油由长链烷基(甲基、乙基或丙基)酯构成。
在某些实施方案中,本发明涉及使用本申请公开的组合物处理木材的方法,以及使用这种组合物和方法处理的木材。在某些实施方案中,本发明的组合物可以通过标准方法例如真空和/或压力方法浸渍到纤维素材料例如木材中。当这种组合物用于使木材防腐时,在使用过程中木材暴露于成分时金属成分的浸出最少。为了用于使木材和其它基于纤维素的材料防腐,金属化合物的粒径为约0.005微米至约25.0微米。
在某些实施方案中,本发明涉及木材防腐剂组合物,其包含:(a.)可生物降解的有机溶剂载体,所述可生物降解的有机溶剂载体选自植物油、可再生资源油和生物柴油;(b.)有效地使得用所述组合物处理的木材抵抗真菌腐烂的量的氟唑菌苯胺。
在某些实施方案中,本发明涉及处理木材产品以使得其抵抗真菌腐烂和尺寸稳定的方法,所述方法包括以下步骤:1)使所述木材与组合物接触,所述组合物包含:(a)具有低芳族含量的有机溶剂载体;和(b)氟唑菌苯胺;和2)干燥所述木材产品,其中使得所述处理的木材产品抵抗真菌腐烂和尺寸稳定。
在某些实施方案中,本发明涉及处理木材产品以使得其抵抗真菌腐烂和尺寸稳定的方法,所述方法包括以下步骤:1)使所述木材与组合物接触,所述组合物包含:(a)可生物降解的有机溶剂载体,所述可生物降解的有机溶剂载体选自植物油、可再生资源油和生物柴油;和(b)使得所述木材抵抗真菌腐烂的有效量的氟唑菌苯胺;和2)干燥所述木材产品,其中使得所述处理的木材产品抵抗真菌腐烂和尺寸稳定。
本发明的组合物可以通过标准方法真空和/或压力浸渍到纤维素材料例如木材中,以有效地保护材料免受真菌腐烂和昆虫侵袭。
具体实施方式
本申请公开用于保护纤维素材料、更特别是木材的木材防腐剂组合物。组合物包含金属化合物、具有低芳族的烃溶剂和分散剂。组合物赋予处理的木材对木腐菌、昆虫和白蚁的抗性。金属化合物可选自铜、锌、铁或银的化合物/络合物,优选的金属化合物为铜化合物。
铜化合物
通常,本发明的铜或铜化合物由以下物质(但不限于以下物质)制得:铜金属、氧化亚铜(铜(I)离子源)、氧化铜(铜(II)离子源)、氢氧化铜、碳酸铜、碱式碳酸铜、氯氧化铜、8-羟基喹啉铜、二甲基二硫代氨基甲酸铜、吡啶硫酮铜(copper omadine)、硼酸铜或碱式硼酸铜、铜残留物(铜金属副产品)或任何适宜的铜源。
本发明的木材防腐剂组合物包含颗粒分散体形式的铜化合物。颗粒铜的粒径为约0.005微米至约25微米。优选的粒径范围为约0.05微米至约5微米,最优选的粒径范围为约0.1微米至约1.0微米。平均粒径或均值粒径可以为约0.05微米至约1.0微米,优选的平均粒径为约0.08微米至约0.5微米,最优选的粒径为约0.1微米至约0.4微米。
研磨和研磨介质
适于木材处理的颗粒铜化合物可以通过湿球磨机用特定特性的研磨介质研磨来制备。研磨介质为陶瓷材料,例如锆氧化物、氧化锆、钇或镁稳定的氧化锆或密度大于3克/cm3、例如等于或大于3.8克/cm3、优选大于5.5克/cm3的任何其它类型的陶瓷材料。研磨介质的粒径可为50微米至1000微米,优选粒径为200微米至400微米。另外,不管原料的粒径如何,颗粒可在几分钟到至多几小时内破碎成可注入的大小。有利的是,所有用于木材处理的可注入制剂都应该进行湿磨,即使当“平均粒径”完全在认为可注入木材的范围内也是如此。
研磨介质(milling media),也称为研磨介质(grinding media)或研磨珠,为本发明的核心。研磨介质的选择明显不是常规优化的。该介质的使用允许先前在本领域中不可得到的平均粒径和窄的粒径分布,现有技术中的结果也不允许预测我们得到的预料不到的结果。
本发明的主要贡献为制备d50等于或小于约1微米的颗粒杀生物产品的方法,所述方法包括以下步骤:1)将固体金属或有机杀生物剂和包含表面活性剂的液体提供给研磨机;提供包含有效量的研磨珠的研磨介质,研磨珠的直径为约0.01mm至约0.8mm、优选约0.1mm至约0.7mm、更优选约0.1mm至约0.5mm,其中研磨珠的密度大于约2.5克/cm3、优选等于或大于3.5克/cm3、更优选等于或大于3.8克/cm3、最优选等于或大于5.5克/cm3,例如氧化锆珠的密度为约6克/cm3;和2)将材料进行高速湿磨,速度例如为300rpm至6000rpm、更优选1000rpm至4000rpm、例如约2000rpm至3600rpm,其中为实验室规模的球磨机提供研磨速度,持续足以得到平均体积粒径为约1微米或更小的产品的时间,例如约5分钟至300分钟、优选约10分钟至约240分钟、最优选约15分钟至约60分钟。低至5体积%的研磨介质需要在用于研磨一些材料的优选规格内,但是如果大于10重量%、优选大于25重量%、例如40重量%至100重量%的研磨材料在优选规格内,则获得较好的结果。对于在优选规格之外的研磨材料,有利地,该材料具有大于3克/cm3的密度和小于4mm的直径,例如1mm或2mm的氧化锆或硅酸锆研磨珠。
研磨介质有利地包含基于锆的材料或基本由基于锆的材料构成。优选的介质是氧化锆(密度约6g/cm3),其包括优选的变体,例如氧化钇稳定的四方氧化锆、氧化镁稳定的氧化锆和铈掺杂的氧化锆。对于一些杀生物剂,硅酸锆(密度为约3.8g/cm3)是有用的。然而,对于几种杀生物剂例如百菌清(chlorothalonil),在本发明的几个优选的实施方案中,硅酸锆将不能实现得到窄的亚微米范围的粒径所需的作用。在一个替代实施方案中,至少一部分研磨介质包括金属材料(例如钢)或基本由金属材料(例如钢)构成。研磨介质为具有如下密度的材料:大于约2.5g/cm3、优选至少约3.8g/cm3、更优选大于约5.5g/cm3、例如至少约6g/cm3。
并不需要所有的研磨介质都为优选的材料,所述材料例如具有优选的直径为0.1mm至0.8mm、优选0.1mm至0.7mm、更优选0.1mm至0.5mm并且具有优选的密度为等于或大于3.5克/cm3、优选大于或等于5.5克/cm3、更优选大于或等于6克/cm3。事实上,低至10%的这种介质将会提供有效的研磨。基于研磨机中的介质的总重量,优选的研磨介质的量可以为5%至100%、有利地为10%至100%、优选为25%至90%、例如约40%至80%。不在优选类别内的介质可以稍微较大,例如直径为1mm至4mm、优选直径为1mm至2mm并且也有利地具有等于或大于3.5kg/cm3的密度。
粒径
本申请所用的粒径可表示为“dxx”,其中“xx”为直径等于或小于dxx的所述组分的重量百分比(或替代地体积百分比)。例如,d50为这样的直径,其中50重量%的组分为直径等于或低于d50的颗粒,同时略低于50%的重量的组分存在于直径大于d50的颗粒中。粒径优选通过颗粒在流体中的斯托克斯定律沉降速度确定,例如使用由Horiba和Co.Ltd.出售的Model LA 700或CAPATM700、或由Micromeritics,Inc.制造的SedigraphTM5100T,其使用X射线检测和基于斯托克斯定律的尺寸计算,使尺寸降至约0.2微米。较小的尺寸优选地通过动态光散射方法、优选使用CoulterTM计数器确定。
在本发明的某些实施方案中,本发明木材防腐制剂中的固体颗粒的d95为小于约10微米;或小于约5微米;或小于约2微米;或小于约1微米;或小于约0.5微米;或小于约0.2微米;或小于约0.1微米。
在本发明的某些实施方案中,本发明木材防腐制剂中的固体颗粒的平均粒径为约20nm至约100nm;或约20nm至约200nm;或约20nm至约500nm;或约50nm至约200nm;或约50nm至约300nm;或约50nm至约500nm;或约100nm至约500nm。
处理的木材产品的铜含量
在某些实施方案中,使用本发明组合物处理的木材产品的铜(或其它金属,包括但不限于锌、铁或银)含量为小于约16Kg/m3;或小于约10Kg/m3;或小于约5Kg/m3;或小于约1Kg/m3。本申请所用的处理的木材中铜(或其它金属,包括但不限于锌、铁或银)的量为存在于木材中的元素铜(或其它金属,包括但不限于锌、铁或银)的量。
溶剂载体
本发明中公开的溶剂为低芳族含量的烃溶剂。作为石油衍生物的烃溶剂为通过蒸馏石油原油制备的相对少的一组产物。一般而言,通用烃溶剂为烃的复杂混合物并且含有脂族化合物,例如饱和或不饱和的直链、支链和/或环状烷烃、炔烃、链烷酸、环烷酸和一定水平的芳族组分。芳族化合物(例如烷基芳族化合物、苯和多核芳族化合物)在其它脂族烃溶剂中的存在将具有较不理想的特性,例如增加的气味或较大程度的人类健康问题。此外,芳族化合物的存在将改变烃溶剂性质的物理/化学性质,例如极性增加。本发明中,在组合物中使用低芳族烃溶剂。所述烃溶剂来自石油原油或来自合成工艺。我们惊奇地发现,除了使气味大大减少和健康问题减少之外,低芳族烃溶剂可促进铜化合物在研磨过程中的润湿/分散,并且保持在储存期间和真空/压力处理过程中的颗粒稳定性。
本发明中公开的烃溶剂通常具有小于约22%、或小于约15%、或小于约8%、或小于约1%的按重量计的芳族化合物,优选小于约0.1%的芳族化合物,更优选含有基本0%的芳族化合物。
低芳族烃溶剂的实例包括但不限于链烷烃饱和烷烃、不饱和烯烃以及不饱和炔烃(例如乙炔)。饱和烷烃包括支链或异烷烃(异链烷烃)、环烷烃、直链烷烃或正烷烃(己烷和庚烷)。不饱和烷烃(烯烃)包括支链或异烷烃、环烯烃(例如环己烯)、不饱和炔烃以及直链或正烯烃(例如乙烯、丙烯)。
本发明的低芳族烃溶剂的最小闪点为约20℃、或约30℃、或约40℃、或约60℃、或约80℃、或约100℃、或约120℃、或约140℃或更高。在其它实施方案中,本发明的低芳族烃溶剂的闪点可以为约20℃至约30℃、或约20℃至约40℃、或约20℃至约60℃、或约20℃至约80℃、或约20℃至约100℃、或约20℃至约120℃、或约20℃至约140℃。本申请所用的术语“闪点”是指在给定点燃源时挥发性物质的蒸气将点燃的最低温度。
本发明的低芳族烃溶剂的沸点范围为约40℃至约300℃、或约60℃至约95℃、或约130℃至约270℃、或约130℃至约185℃、或约140℃至约200℃、或约150℃至约190℃、或约180℃至约220℃、或约190℃至约250℃或约220℃至约270℃。
具有低芳族含量的商购可得烃溶剂的实例包括但不限于Exxsol D脱芳族烃流体和由ExxonMobil制造的Isopar异链烷烃流体,Shellsol D(脱芳族烃的)等级和由ShellChemicals制造的Shellsol OMS异链烷烃溶剂,由Neste制造的Nessol溶剂和由Resolute制造的MaxSolv。
Exxsol D溶剂的实例为Exxol D30、D155/170、D40、D180/200、D60、D80、D220/240、D100、D100S、D120、D140。这些溶剂的物理化学性质如下给出:
Exxsol溶剂
用于使木材防腐的可生物降解的有机溶剂载体
植物油
植物油一般是指从植物中提取的化合物。化合物主要是基于甘油三酯的,并且在室温以液体或脂肪蜡状或固态存在。在环境条件呈蜡状或固态的植物油也称为植物脂肪。另外,植物油含有饱和的以及不饱和碳-碳双键这两者。
不饱和植物油可以通过部分或完全氢化转化为较高熔点的油。氢化方法包括在催化剂(通常是基于镍的化合物)存在下在高温和高压用氢气喷射油。当每个碳-碳双键化学还原成单键时,两个氢原子各自与两个碳原子形成单键以增加其饱和度。油可以氢化以增加对酸败(氧化)的抵抗力或改变其物理特性。随着饱和度的增加,油的粘度和熔点增加。
植物油的非限制性实例为亚麻子油、椰子油、玉米油、棉子油、棕榈油、低芥酸菜子油、棕榈仁油、橄榄油、花生油、菜子油、红花油、芝麻油、大豆油、葵花油、蓖麻油、桐油、罂粟籽油、斑鸠菊油、杏仁油、山毛榉坚果油、巴西坚果油、初榨橄榄油、腰果油、榛子油、澳洲坚果油、蒙刚果油(或曼杰提树油)、胡桃油、松子油、阿月浑子油、核桃油、南瓜子油、巴卡斯果油、葡萄子油、米糠油、烛果油和大麻子油。
与植物油相似但与天然酯中发现的正常三个脂肪酸链相比具有四个脂肪酸链的合成四酯通过费歇尔酯化制备。四酯通常具有高的氧化稳定性并且已经用作发动机润滑剂。植物油用于制备可生物降解的有机溶剂载体。
可再生油源和生物柴油:可再生油(可再生资源油)源自脂肪酸和树脂的可持续和可再生来源,例如妥尔油(tall oil)。妥尔油,也称为“液体松香”或妥尔油(tallol),为作为木材制浆过程的副产品得到的黄黑色液体。妥尔油是硫酸盐法浆厂(Kraft mill)中的继木质素和半纤维素之后的第三大化学副产品;该过程的原油妥尔油产率为30-50千克/吨木浆,自20世纪30年代开始商业化生产。生物柴油是指基于植物油或动物脂肪的柴油,由长链烷基(甲基、乙基或丙基)酯构成。生物柴油通常通过使脂质(例如,植物油、大豆油、[1]动物脂肪(动物脂[2][3]))与醇发生化学反应产生脂肪酸酯来制备。
分散剂
本发明也包含溶剂型分散剂。优选的分散剂为具有颜料亲和基团的聚合物分散剂,所述颜料亲和基团例如羟基、羧酸基、磺酸酯基、胺官能团或季铵官能团。用于本发明的聚合物分散剂可以为在低芳族烃溶剂中可溶或至少部分可溶的共聚物。
共聚物分散剂的实例包括但不限于具有颜料亲和基团的共聚物、聚羧酸酯醚、改性聚丙烯酸酯、丙烯酸类聚合物乳液、改性丙烯酸类聚合物、聚羧酸聚合物及其盐、改性聚羧酸聚合物及其盐、脂肪酸改性的聚酯、脂族聚醚或改性脂族聚醚、聚醚磷酸酯、聚羧酸酯醚溶液、聚丙烯酸钠、聚甲基丙烯酸钠、改性聚醚或具有颜料亲和基团的聚酯、脂肪酸衍生物、聚氨酯共聚物或改性聚氨酯共聚物、丙烯酸/马来酸共聚物、聚乙烯吡咯烷酮或改性聚乙烯吡咯烷酮、改性马来酸酐/苯乙烯共聚物、木质素等。
商购可得溶剂型分散剂的实例包括但不限于Disperbyk分散剂系列,例如DISPERBYK 103、108、111、118、142、168、180、410、411、2008、2022、2055、2152、2155和2164;Tego分散剂系列,例如TEGO Disperse 1010、650、652、656、670、671、672、685、688、690和710;EFKA分散剂系列,例如EFKA 4008、4009、4010、4015、4020、4046、4047、4050、4055、4061、4063、4080、4300、4310、4320、4330、4340、4400、4401、4402、4403、4510、4530、4550、4570、4590、5010、5044、5054、5055、5063、5065、5066、5070、5071、5207、5210、5215、5220、5244、5744、6050、6230、6220、6225、1016、1101、1500、1501、1502、1503、6622、6700、6950、6043、6745、6780、6782、FA 4600、FA 4601、FA 4620、FA 4642、FA 4644、FA 4650、FA 4654、FA 4654EM、FA 4660、FA 4663、FA 4665和FA 4671;Solsperse系列,例如Solsperese 3000、5000S、8000、9000、11200、13300、13400、13650、13940、16000、17000、17940、18000、19000、21000和22000;来自Stepan Company的分散剂,例如Bio-softN1-3、Bio-soft N91-2.5、Bio-soft N-411、Makon NF-12和G-3300;AkzoNobel分散剂Phospholan PS 131。
稳定分散体
分散剂有助于颗粒分散并且防止颗粒聚集。亚微米尺寸的颗粒倾向于形成大得多的聚集体。本申请所用的聚集体为多个相似尺寸的颗粒的物理组合,通常通过范德华力或静电力聚集在一起。如果允许形成聚集体,则聚集体通常会老化成不能容易地注入的稳定聚集体,或可以为使聚集体可见的尺寸,从而产生非期望的颜色。在本发明的优选实施方案中,至少30重量%、优选至少60重量%、更优选至少90重量%的颗粒铜化合物(或金属化合物)的稳定分散体为单支化的(mono-disbursed),即不是聚集体形式。此外,固体颗粒在注入木材中时有利地不会趋于聚集。
因此,本申请所用的稳定分散体为金属化合物或铜化合物的粒径随时间推移而保持基本相同的分散体。
分散剂的确切用量水平取决于所用的铜化合物和特定的溶剂载体。但一般而言,分散剂与铜化合物的比率为约1:500至约100:1重量/重量(wt/wt)、或约1:100至约10:1wt/wt。优选的分散剂与铜化合物的比率为约1:20至约10:1(wt/wt),最优选的比率为约1:10至约1:1(wt/wt)。
其它杀生物剂和添加剂
目前用于确定处理的木材中防腐剂杀生物剂负载的AWPA方法为从防腐处理的木材样品中取样,然后进行化学分析以得到m/m%或wt/wt%,然后将其可以根据木材密度在数学上转换为另一种单位,pcf(磅每立方英尺)或kg/m3(千克每立方米)。AWPA方法M25-16(用于住宅和商业用途的防腐处理产品的质量控制和检验标准,其整个内容通过引用并入本申请)描述了进行保留分析的程序。
其它杀生物剂,例如杀真菌剂、杀细菌剂、杀白蚁剂和杀霉剂可包括在用于处理木材的本申请组合物中。其它杀生物剂的实例包括但不限于以下:
硼化合物。水溶性硼化合物的非限制性实例包括硼酸,硼酸钠,例如四硼酸钠十水合物、四硼酸钠五水合物和八硼酸二钠四水合物(DOT)、硼酸钾。水不溶性硼化合物的非限制性实例包括金属硼酸盐化合物,例如硼酸钙、硼酸盐硅酸盐、硅酸铝硼酸盐氢氧化物、硅酸盐硼酸盐氢氧化物氟化物、氢氧化物硅酸盐硼酸盐、硅酸钠硼酸盐、硅酸钙硼酸盐、硼酸铝、氧化硼、硼酸镁、硼酸铁、硼酸铜和硼酸锌(硼砂)。
季铵化合物。非限制性实例为:二癸基二甲基氯化铵;二癸基二甲基碳酸铵/碳酸氢铵;烷基二甲基苄基氯化铵;烷基二甲基苄基碳酸铵/碳酸氢铵;双十二烷基二甲基氯化铵;双十二烷基二甲基碳酸铵/碳酸氢铵;双十二烷基二甲基丙酸铵;N,N-二癸基-N-甲基-聚(氧基乙基)丙酸铵。
三唑或咪唑化合物。非限制性实例为1-[[2-(2,4-二氯苯基)-1,3-二氧戊环-2-基]甲基]-1H-1,2,4-三唑(氧环唑(azaconazole))、1-[(2RS,4RS:2RS,4SR)-4-溴-2-(2,4-二氯苯基)四氢糠基]-1H-1,2,4-三唑(糠菌唑(bromuconazole))、(2RS,3RS;2RS,3SR)-2-(4-氯苯基)-3-环丙基-1-(1H-1,2,4-三唑-1-基)丁-2-醇(环菌唑(cyproconazole))、(2RS,3RS)-1-(2,4-二氯苯基)-4,4-二甲基-2-(1H-1,2,4-三唑-1-基)戊-3-醇(苄氯三唑醇(diclobutrazol))、顺-反-3-氯-4-[4-甲基-2-(1H-1,2,4-三唑-1-基甲基)-1,3-二氧戊环-2-基]苯基4-氯苯基醚(苯醚甲环唑(difenoconazole))、(E)-(RS)-1-(2,4-二氯苯基)-4,4-二甲基-2-(1H-1,2,4-三唑-1-基)戊-1-烯-3-醇(烯唑醇(diniconazole))、(E)-(R)-1-(2,4-二氯苯基)-4,4-二甲基-2-(1H-1,2,4-三唑-1-基)戊-1-烯-3-醇(烯唑醇-M(diniconazole-M))、(2RS,3SR)-1-[3-(2-氯苯基)-2,3-环氧-2-(4-氟苯基)丙基]-1H-1,2,4-三唑(氟环唑(epoxiconazole))、(RS)-1-[2-(2,4-二氯苯基)-4-乙基-1,3-二氧戊环-2-基甲基]-1H-1,2,4-三唑(乙环唑(etaconazole))、(RS)-4-(4-氯苯基)-2-苯基-2-(1H-1,2,4-三唑-1-基甲基)丁腈(腈苯唑(fenbuconazole))、3-(2,4-二氯苯基)-6-氟-2-(1H-1,2,4-三唑-1-基)喹唑啉-4(3H)-酮(氟喹唑(fluquinconazole))、二(4-氟苯基)(甲基)(1H-1,2,4-三唑-1-基甲基)硅烷(氟硅唑(flusilazole))、(RS)-2,4′-二氟-α-(1H-1,2,4-三唑-1-基甲基)二苯甲醇(粉唑醇(flutriafol))、(2RS,5RS;2RS,5SR)-5-(2,4-二氯苯基)四氢-5-(1H-1,2,4-三唑-1-基甲基)-2-呋喃基2,2,2-三氟乙基醚(呋菌唑(furconazole))、(2RS,5RS)-5-(2,4-二氯苯基)四氢-5-(1H-1,2,4-三唑-1-基甲基)-2-呋喃基2,2,2-三氟乙基醚(呋醚唑(furconazole-cis))、(RS)-2-(2,4-二氯苯基)-1-(1H-1,2,4-三唑-1-基)己-2-醇(己唑醇(hexaconazole))、4-氯苄基(EZ)-N-(2,4-二氯苯基)-2-(1H-1,2,4-三唑-1-基)硫代乙酰胺酯(亚胺唑(imibenconazole))、(1RS,2SR,5RS;1RS,2SR,5SR)-2-(4-氯苄基)-5-异丙基-1-(1H-1,2,4-三唑-1-基甲基)环戊醇(种菌唑(ipconazole))、(1RS,5RS;1RS,5SR)-5-(4-氯苄基)-2,2-二甲基-1-(1H-1,2,4-三唑-1-基甲基)环戊醇(叶菌唑(metconazole))、(RS)-2-(4-氯苯基)-2-(1H-1,2,4-三唑-1-基甲基)己腈(腈菌唑(myclobutanil))、(RS)-1-(2,4-二氯-β-丙基苯乙基)-1H-1,2,4-三唑(戊菌唑(penconazole))、顺-反-1-[2-(2,4-二氯苯基)-4-丙基-1,3-二氧杂环-2-基甲基]-1H-1,2,4-三唑(丙环唑(propiconazole))、(RS)-2-[2-(1-氯环丙基)-3-(2-氯苯基)-2-羟基丙基]-2,4二氢-1,2,4-三唑-3-硫酮(丙硫菌唑(prothioconazole))、3-(2,4-二氯苯基)-2-(1H-1,2,4-三唑-1-基)-喹唑啉-4(3H)-酮(唑喹菌酮(quinconazole))、(RS)-2-(4-氟苯基)-1-(1H-1,2,4-三唑-1-基)-3-(三甲基甲硅烷基)丙-2-醇(硅氟唑(simeconazole))、(RS)-1-对氯苯基-4,4-二甲基-3-(1H-1,2,4-三唑-1-基甲基)戊-3-醇(戊唑醇(tebuconazole))、丙环唑(propiconazole)、(RS)-2-(2,4-二氯苯基)-3-(1H-1,2,4-三唑-1-基)丙基1,1,2,2-四氟乙基醚(四氟醚唑(tetraconazole))、(RS)-1-(4-氯苯氧基)-3,3-二甲基-1-(1H-1,2,4-三唑-1-基)丁-2-酮(三唑酮(triadimefon))、(1RS,2RS;1RS,2SR)-1-(4-氯苯氧基)-3,3-二甲基-1-(1H-1,2,4-三唑-1-基)丁-2-醇(三唑醇(triadimenol))、(RS)-(E)-5-(4-氯亚苄基)-2,2-二甲基-1-(1H-1,2,4-三唑-1-基甲基)环戊醇(灭菌唑(triticonazole))、(E)-(RS)-1-(4-氯苯基)-4,4-二甲基-2-(1H-1,2,4-三唑-1-基)戊-1-烯-3-醇(烯效唑(uniconazole))、(E)-(S)-1-(4-氯苯基)-4,4-二甲基-2-(1H-1,2,4-三唑-1-基)戊-1-烯-3-醇(烯效唑-P(uniconazole-P))、和2-(2,4-二氟苯基)-1-(1H-1,2,4-三唑-1-基)-3-三甲基甲硅烷基-2-丙醇。其它唑类化合物包括:吲唑磺菌胺(amisulbrom)、联苯三唑醇(bitertanol)、三氟苯唑(fluotrimazole)、叶锈特(triazbutil)、咪菌酮(climbazole)、clotrimazole、抑霉唑(imazalil)、恶咪唑(oxpoconazole)、咪鲜胺(prochloraz)、氟菌唑(triflumizole)、氧环唑(azaconazole)、硅氟唑(simeconazole)和己唑醇(hexaconazole)。
异噻唑酮化合物。非限制性实例为:甲基异噻唑啉酮;5-氯-2-甲基-4-异噻唑啉-3-酮、2-甲基-4-异噻唑啉-3-酮、2-正辛基-4-异噻唑啉-3-酮、4,5-二氯-2-正辛基-4-异噻唑啉-3-酮、2-乙基-4-异噻唑啉-3-酮、4,5-二氯-2-环己基-4-异噻唑啉-3-酮、5-氯-2-乙基-4-异噻唑啉-3-酮、2-辛基-3-异噻唑酮、5-氯-2-叔辛基-4-异噻唑啉-3-酮、1,2-苯并异噻唑啉-3-酮,优选5-氯-2-甲基-4-异噻唑啉-3-酮、2-甲基-4-异噻唑啉-3-酮、2-正辛基-4-异噻唑啉-3-酮、4,5-二氯-2-正辛基-4-异噻唑啉-3-酮、1,2-苯并异噻唑啉-3-酮等,更优选5-氯-2-甲基-4-异噻唑啉-3-酮、2-正辛基-4-异噻唑啉-3-酮、4,5-二氯-2-正辛基-4-异噻唑啉-3-酮、1,2-苯并异噻唑啉-3-酮、氯甲基异噻唑啉酮;4,5-二氯-2-正辛基-3(2H)-异噻唑酮;1,2-苯并异噻唑啉-3-酮。
拟除虫菊酯化合物包括:氟酯菊酯(acrinathrin)、丙烯除虫菊(allethrin)、反丙烯除虫菊(bioallethrin)、熏虫菊(barthrin)、氟氯菊酯(bifenthrin)、戊环苄呋菊酯(bioethanomethrin)、环戊烯菊酯(cyclethrin)、乙氰菊酯(cycloprothrin)、氟氯氰菊酯(cyfluthrin)、β-氟氯氰菊酯(beta-cyfluthrin)、(RS)氯氟氰菊酯(cyhalothrin)、γ-(RS)氯氟氰菊酯(ga mma-cyhalothrin)、λ-(RS)氯氟氰菊酯(lambda-cyhalothrin)、氯氰菊酯(cypermethrin)、α-氯氰菊酯(alpha-cypermethrin)、β-氯氰菊酯(beta-cypermethrin)、θ-氯氰菊酯(theta-cypermethrin)、ζ-氯氰菊酯(zeta-cypermethrin)、苯醚氰菊酯(cyphenothrin)、溴氰菊酯(deltamethrin)、四氟甲醚菊酯(dimefluthrin)、苄菊酯(dimethrin)、烯炔菊酯(empenthrin)、五氟苯菊酯(fenfluthrin)、吡氯氰菊酯(fenpirithrin)、甲氰菊酯(fenpropathrin)、杀灭菊酯(fenvalerate)、高氰戊菊酯(esfenvalerate)、氟氰戊菊酯(flucythrinate)、氟胺氰菊酯(fluvalinate)、氟胺氰菊酯(tau-fluvalinate)、糠醛菊酯(furethrin)、炔咪菊酯(imiprothrin)、甲氧苄氟菊酯(metofluthrin)、氯菊酯(permethrin)、生物氯菊酯(biopermethrin)、反氯菊酯(transpermethrin)、苯醚菊酯(phenothrin)、炔酮菊酯(prallethrin)、丙氟菊酯(profluthrin)、反灭虫菊(pyresmethrin)、灭虫菊(resmethrin)、右旋反灭虫菊酯(bioresmethrin)、右旋反灭虫菊酯(cismethrin)、七氟菊酯(tefluthrin)、环戊烯丙菊酯(terallethrin)、胺菊酯(tetramethrin)、四溴菊酯(tralomethrin)、四氟菊酯(transfluthrin)、醚菊酯(etofenprox)、氟苯苄醚(flufenprox)、卤醚菊酯(halfenprox)、protrifenbute、灭虫硅醚(silafluofen)。
其它杀生物剂包括:吡虫啉(imidachloprid);氟虫腈(fipronil);氟氯氰菊酯(cyfluthrin);氟氯菊酯(bifenthrin);氯菊酯(permethrin);氯氰菊酯(cypermethrin);和毒死蜱(chlorpyrifos)、丁基氨基甲酸碘代丙炔酯(iodopropynyl butylcarbamate)(IPBC);百菌清(chlorothalonil);2-(硫氰酸甲基巯基)苯并噻唑(2-(thiocyanatomethylthio)benzothiazole);烷氧基化二胺(alkoxylated diamines)和多菌灵(carbendazim)。
此外,在用于保护木材的组合物中可以包括其它添加剂,例如防水剂、抗风化剂、尺寸稳定剂或阻燃剂。防水剂的非限制性实例包括石蜡、烯烃蜡、石油蜡、巴西棕榈蜡、聚乙烯蜡、有机硅蜡、聚丙烯蜡、PTFE蜡和合成蜡。
氟唑菌苯胺:在某些实施方案中,本发明涉及包含氟唑菌苯胺的木材防腐剂组合物,用所述组合物处理木材的方法,和用所述组合物处理的木材。在某些实施方案中,木材用包含氟唑菌苯胺的所述组合物处理,所述木材产品中的氟唑菌苯胺的量为小于约0.25%重量/重量、或为约0.0001%至0.10%重量/重量、或为约0.001%至0.05%重量/重量、或为约0.005%至0.025%重量/重量。
抗风化剂的非限制性实例包括:颜料例如氧化锌、硫化锌、氧化铁、炭黑、二氧化钛;UV吸收剂例如羟基取代的二苯甲酮、羟基苯基苯并三氮唑(hydroxyphenylbenzotriazides)、取代的丙烯腈;UV稳定剂例如受阻胺光稳定剂(HALS);和抗氧化剂例如胺、咪唑或复合受阻酚醛树脂。
尺寸稳定剂的非限制性实例包括:蜡例如石蜡、烯烃蜡、石油蜡、巴西棕榈蜡、聚乙烯蜡、有机硅蜡、聚丙烯蜡、聚四氟乙烯蜡和合成蜡,和聚合物例如聚苯乙烯、聚乙烯、聚丙烯、聚氯乙烯、聚丙烯腈、聚乙酸乙烯酯、聚酯、丙烯酸类聚合物、聚酰胺、聚氨酯、线型酚醛树脂、甲阶酚醛树脂(phenolic resoles)、脲醛树脂、三聚氰胺甲醛树脂、环氧树脂、天然树脂如松香和松香酯、烃树脂、酮树脂、萜烯树脂、醇酸树脂、有机硅树脂和硅酸酯(silicate)树脂及其它水不溶性聚合物。
阻燃剂的非限制性实例为:金属氢氧化物,例如氢氧化铝和氢氧化镁;锑化合物,例如三氧化二锑、五氧化二锑和亚锑酸钙;锌化合物,例如锡酸锌、羟基锡酸锌、硼酸锌、硅酸锌、磷酸锌、氧化锌和氢氧化锌;基于磷的化合物如磷酸酯红磷磷酸三聚氰胺(phosphateesters red phosphorus melamine phosphate)、磷酸锌、磷酸钙、磷酸镁和磷酸乙二胺;硅酸盐化合物,例如硅酸钙、二氧化硅、硅酸镁和硅酸锌;卤代化合物,例如四溴双酚A;基于氮的化合物例如三聚氰胺及其盐、硼酸三聚氰胺和聚酰胺。
有机溶剂中的浓缩的铜的制备
在有机溶剂中制备浓缩的铜包括以下步骤:(1).将铜化合物与分散剂和溶剂预混合以形成液体浆料;(2).将浆料进料到预先填充有研磨介质的研磨机中;(3).研磨浆料并且监测粒径直到目标粒径规格。尽管用于制备浓缩的铜的优选溶剂为本申请中描述和公开的低芳族烃碳溶剂,但是其它溶剂也可用于制备浓缩的铜制剂。可以单独或作为混合物用于制备浓缩的铜制剂的其它有机溶剂的非限制性实例包括如下:
胺,例如:二甲胺、二乙胺、二异丙胺、二甲基乙胺、二正丁胺、单-2-乙基己胺、单戊胺、单乙胺70%、单异丙胺、无水的单正丁胺、三戊胺、三乙胺、三-正丁胺、二丁基氨基乙醇、二乙基氨基乙醇、二乙基氨基乙氧基乙醇、二异丙基氨基乙醇、二甲氨基-2P、混合的二甲基氨基-2-P 77%、无水的二甲基氨基乙醇、二甲基氨基乙氧基乙醇、乙基氨基乙醇、乙基氨基乙醇、混合的异丙基氨基乙醇、异丙基氨基乙醇、混合的甲基二乙醇胺、单甲基氨基乙醇、单正丙基氨基乙醇、正丁基氨基乙醇、正丁基二乙醇胺、正丁基二乙醇胺、光(photo)叔丁基氨基乙醇、叔丁基二乙醇胺、二乙醇胺、单乙醇胺、三乙醇胺、三乙醇胺85%/99%、二异丙醇胺、单异丙醇胺、三异丙醇胺、氨基乙基乙醇胺、氨基乙基哌嗪、二亚乙基三胺、乙二胺、哌嗪65%/无水、哌嗪、四亚乙基五胺、三亚乙基四胺、3-甲氧基丙胺、AMP.RTM.常规/95、环己胺、吗啉、Neutrol TE.RTM。
二醇,例如:一缩二乙二醇,一缩二丙二醇,乙二醇,甘油96%、99%,U.S.P.甘油,己二醇,Neol.RTM.新戊二醇(Neopentyiglycol),聚乙二醇,聚丙二醇,丙二醇Ind.,U.S.P.,三缩四乙二醇,二缩三乙二醇,二缩三丙二醇。
酮,例如:丙酮、环己酮、双丙酮、DIBK-二异丁基酮、异佛尔酮、MAK-甲基戊基酮、MEK-甲基乙基酮、MIAK-甲基异戊基酮、MIBK-甲基异丁基酮、MPK-甲基丙基酮。
酯,例如:乙酸戊酯、二元酯、乙酸乙酯、乙酸2-乙基己酯、丙酸乙酯、Exxate.RTM.乙酸酯、乙酸异丁酯、异丁酸异丁酯、乙酸异丙酯、乙酸正丁酯、丙酸正丁酯、丙酸正戊酯、乙酸正丙酯。
醇,例如:戊醇,苄醇,环己醇,变性乙醇,2-乙基己醇,Exxal 8.RTM.异辛醇,Exxal10.RTM.异癸醇,Exxal 13.RTM.十三烷醇,糠醇,异丁醇,99%无水异丙醇,甲醇,甲基戊醇(MIBC),正丁醇,正丙醇,Neodol.RTM.直链醇,仲丁醇,叔丁醇,四氢糠醇,十二醇酯(Texanol Ester Alcohol).RTM.,UCAR Filmer IBT.RTM。
卤化载体,例如:二氯甲烷,一氯苯,邻二氯苯,全氯乙烯,三氯乙烯,Vertrel.RTM.氢氟烃。
脂族载体,例如:庚烷,己烷,煤油,漆稀释剂(Lacquer Diluent),重质灯油,矿质油漆溶剂,正戊烷,OMS-无气味矿质油漆溶剂,橡胶溶剂,140溶剂,360溶剂,石脑油RTM.,VM&P。
芳族载体,例如:芳烃100,芳烃150,芳烃200,重芳烃溶剂,Panasol.RTM.,甲苯,二甲苯。
萜烯载体,例如:α-蒎烯,木材(Wood),双戊烯122.RTM.,D-柠檬烯,Herco.RTM.松油,Solvenol.RTM.,蒸汽蒸馏的松节油,Terpineol.RTM.,Yarmor.RTM.302,302-W松油。
其它载体,包括例如:矿物油,亚麻子油,橄榄油,植物油,乙酸甲氧基丙酯,异丙醇,蓖麻油,Arconate HP.RTM.碳酸亚丙酯,#2燃料油,Cypar.RTM.环烷烃溶剂,DMF--二甲基甲酰胺,甲酰胺,Exxprint.RTM.油墨用油/溶剂,糠醛,Isopar.RTM.异链烷烃溶剂,MTBE--甲基叔丁基醚,NMP--N-甲基吡咯烷酮,Norpar.RTM.正链烷烃溶剂,ProglydeDMM.RTM.乙二醇二醚,THF--四氢呋喃,Varsol.RTM.脂族溶剂。
低芳族烃溶剂载体中的铜处理溶液的制备
当制备处理木材或木产品的处理溶液时,用低芳族烃溶剂载体稀释如上制备的浓缩形式的溶剂型分散的铜化合物。最终处理溶液中的元素铜浓度可以为约0.05%wt/wt至约5.0%wt/wt。处理溶液中优选的元素铜浓度范围为约0.50%wt/wt至约3.0%wt/wt。
当将有机杀生物剂加入上述分散的铜处理溶液中时,如果杀生物剂易溶于处理溶液中,则可将有机杀生物剂直接加入处理溶液中。或者,可以将有机杀生物剂预先溶解在有机溶剂中,然后加入到分散的铜溶液中,其中用于溶解有机杀生物剂的有机溶剂与低芳族烃溶剂可相容或可混溶。上述部分中公开有机溶剂的非限制性实例。
处理和应用过程
本发明的木材防腐剂组合物可通过浸渍、刷涂、喷涂、真空和/或压力处理或本领域任何其它已知方法施加于木材。包含根据本发明的微粉化铜化合物的木材或木材产品可以通过真空和/或压力方法使本发明的组合物进入木材来制备。在一个优选的实施方案中,使用真空和/或压力技术浸渍根据本发明的木材,包括标准方法,例如“定量浸注”法("Empty Cell"process)、“改良的定量浸注”法(“Modified Full Cell”process)和“完全浸注”法("Full Cell"process),以及本领域技术人员公知的任何其它真空和/或压力方法。取决于所用的处理方法,处理的木材吸收的溶液为小于约600L/m3(升每立方米)、小于约500L/m3、小于约400L/m3、小于约300L/m3、小于约200L/m3、小于约100L/m3、小于约50L/m3或小于约10L/m3。
在另一个实施方案中,处理溶液可以通过微波或射频处理方法施加。在该方法中,首先使用射频或微波能量加热木质基材。加热的目标区域的温度可以为约40℃至约300℃、更优选约80℃至约100℃。加热后,立即使含有吡唑和异噻唑啉酮的液体制剂与基材接触。在施加组合物时,液体制剂的温度低于加热的目标区域的温度,组合物和加热的目标区域的温度之间的差异足以在施加组合物后降低基材中的压力。可以使用各种频率的无线电或微波能量。射频或微波能量的频率可以为约0.1MHz至约100MHz、优选约10MHz至约50MHz、更优选约20MHz至约40MHz。本领域技术人员可以容易地理解该范围之外的适当波长。取决于所使用的射频或加热持续时间,由处理的木材吸收的溶液通常为小于约600L/m3、小于约400L/m3、小于约300L/m3、小于约200L/m3、小于约100L/m3、小于约50L/m3或小于约10L/m3。
在某些实施方案中,本发明的组合物可通过外部涂布处理施加于木材表面。
在本发明的某些实施方案中,本发明的优点为用本发明的木材防腐剂组合物处理的木材产品在用本发明的木材防腐剂组合物处理后不需要随后的干燥。这种干燥步骤包括真空处理、加热、窑干和风干。
处理的木材产品
在本发明的某些实施方案中,本发明的处理的木材产品在触摸时没有油性质地。在本发明的某些实施方案中,处理的木材产品基本没有气味,例如化学气味。
在本发明的某些实施方案中,与未处理的木材产品或用包含水性载体或溶剂的木材防腐剂组合物处理的木材产品相比,本发明的处理的木材产品表现出增加的尺寸稳定性。术语“增加的尺寸稳定性”是指在用本发明的木材防腐剂组合物处理后,处理的木材产品在储存时的溶胀、干裂、分裂、翘曲或扭曲减少。
木材产品和种类
本发明的组合物可用作木材防腐剂以保护木材和/或木产品免受腐烂和白蚁侵袭,所述木材和/或木产品例如木材、木料、碎料板、层合板、单板层积材(LVL)、定向应变板(OSB)、电线杆、木桥(wood bridges)。木材种类的非限制性实例包括:南方松、辐射松、桉树、加勒比松、西黄松、红松、东部白松、欧洲赤松、短叶松、黑松、云杉松(Spruce-pine-fir)、花旗松、铁冷杉(hem fir)、东部铁杉、西部红雪松(western red cedar)、槭树、橡树。
本发明的组合物也可用于对使用中的木材例如电线杆和铁路枕木进行补充或补救处理。当用作补救防腐剂时,如果需要,组合物可以是糊状或油脂型制剂的形式,使得制剂具有粘合性质并且易于施加于所需位置。当制备糊状或油脂型制剂时,经常使用0.5重量%至约30重量%的金属粘土增稠剂,或这种增稠剂的混合物。金属粘土增稠剂包括诸如凹凸棒石粘土和海泡石粘土的纤维结构类型、诸如allophone的非晶体结构类型以及诸如蒙脱石和高岭土的混合层结构类型和上述层结构类型。金属粘土矿物的实例包括但不限于凹凸棒石、地开石、皂石、蒙脱石、珍珠陶土、高岭石、钙长石、埃洛石、准埃洛石、温石棉、利蛇纹石、蛇纹石、叶蛇纹石、贝得石、硅镁石、锂蒙脱石(hectonite)、smecnite、珍珠陶土和海泡石、蒙脱石、锌蒙脱石、硅镁石、绿脱石、皂石、锂蒙脱石、蛭石、smecnite、海泡石、珍珠陶土、伊利石、绢云母、海绿石-蒙脱石、玫瑰砷酸钙石-蒙脱石、有机皂土38(锂蒙脱石)和有机皂土34(膨润土)、绿泥石-蛭石、伊利石-蒙脱石、埃洛石-蒙脱石、高岭石-蒙脱石。用于本发明组合物中的粘土矿物也含有可交换的阳离子,包括但不限于铝离子、质子、钠离子、钾离子、钙离子、镁离子、锂离子等。在上述金属粘土矿物中,凹凸棒石、锂蒙脱石、膨润土、蒙脱石、锌蒙脱石、smecnite、硅镁石、贝得石、绿脱石、皂石、锂蒙脱石、蛭石、珍珠陶土和海泡石为本发明特别优选的。
实施例
以下实施例仅表示本发明的性质,不应解释为以任何方式限制本发明和所附权利要求的范围。实施例1-8说明浓缩的颗粒铜分散体在溶剂中的制备。实施例9-29说明溶剂型颗粒铜的处理溶液的制备和处理溶液在处理木材中的用途。
实施例1
将二百(200.0)克碱式碳酸铜加入到容纳132克的低芳族含量(<1.0%)溶剂和68克商购可得溶剂型分散/润湿剂的容器中。溶剂的闪点为约80℃。将混合物机械搅拌5分钟并且然后置于研磨机中。将混合物研磨约2小时,得到含有约50%碱式碳酸铜的稳定分散体,其中平均粒径为0.31微米。
实施例2
将二百(200.0)克碱式碳酸铜加入到容纳140克的低芳族含量(<0.1%)溶剂和60克商购可得溶剂型分散/润湿剂的容器中。溶剂的闪点为约60℃。将混合物机械搅拌5分钟并且然后置于研磨机中。将混合物研磨约2小时,得到含有约50%碱式碳酸铜的稳定分散体,其中平均粒径为0.34微米。
实施例3
将二百(200.0)克碱式碳酸铜加入到容纳140克的低芳族含量(<1.0%)溶剂和60克商购可得溶剂型分散/润湿剂的容器中。溶剂的闪点为约80℃。将混合物机械搅拌5分钟并且然后置于研磨机中。将混合物研磨约2小时,得到含有约50%碱式碳酸铜的稳定分散体,其中平均粒径为0.17微米。
实施例4
将二百(200.0)克碱式碳酸铜加入到容纳140克的低芳族含量(<0.1%)溶剂和60克商购可得溶剂型分散/润湿剂的容器中。溶剂的闪点为约80℃。将混合物机械搅拌5分钟并且然后置于研磨机中。将混合物研磨约2小时,得到含有约50%碱式碳酸铜的稳定分散体,其中平均粒径为0.34微米。
实施例5
将二百(200.0)克碱式碳酸铜加入到容纳170克的低芳族含量(<0.1%)溶剂和30克商购可得溶剂型分散/润湿剂的容器中。溶剂的闪点为约80℃。将混合物机械搅拌5分钟并且然后置于研磨机中。将混合物研磨约2小时,得到含有约50%碱式碳酸铜的稳定分散体,其中平均粒径为0.30微米。
实施例6
将二百(200.0)克碱式碳酸铜加入到容纳180克的低芳族含量(<0.1%)溶剂和20克商购可得溶剂型分散/润湿剂的容器中。溶剂的闪点为约80℃。将混合物机械搅拌5分钟并且然后置于研磨机中。将混合物研磨约2小时,得到含有约50%碱式碳酸铜的稳定分散体,其中平均粒径为0.33微米。
实施例7
将二百(200.0)克碱式碳酸铜加入到容纳140克的低芳族含量(<0.1%)溶剂和60克商购可得溶剂型分散/润湿剂的容器中。溶剂的闪点为约100℃。将混合物机械搅拌5分钟并且然后置于研磨机中。将混合物研磨约2小时,得到含有约50%碱式碳酸铜的稳定分散体,其中平均粒径为0.30微米。
实施例8
将二百(200.0)克碱式碳酸铜加入到容纳140克的低芳族含量(<1.0%)溶剂和60克商购可得溶剂型分散/润湿剂的容器中。溶剂的闪点为约100℃。将混合物机械搅拌5分钟并且然后置于研磨机中。将混合物然后研磨约2小时,得到含有约50%碱式碳酸铜的稳定分散体,其中平均粒径为0.20微米。
实施例9
防腐处理组合物如下制备:将124.20g由实施例4制备的分散体加入到3375.80g的闪点为约80℃的烃溶剂(<1.0%的芳族含量)中。所得流体含有约1.0%的按重量计的元素铜。然后将该流体使用完全浸注法用于处理1.5x 5.5x 10”南方松木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在120psi加压60分钟。将30”Hg的最终真空施加到木材上持续15分钟以除去残留液体。发现木材具有清晰的表面和可忽略的气味,并且处理溶液显示出良好的稳定性和稳定的粒径。
实施例10
防腐处理组合物如下制备:将124.20g由实施例4制备的分散体加入到3375.80g的闪点为约80℃的烃溶剂(<0.1%的芳族含量)中。所得流体含有约1.0%的按重量计的元素铜。然后将该流体使用完全浸注法用于处理1.5x 5.5x 12”南方松木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在120psi加压60分钟。将30”Hg的最终真空施加到木材上持续15分钟以除去残留液体。发现木材具有清晰的表面和可忽略的气味,并且处理溶液显示出良好的稳定性和稳定的粒径。将处理的木材沿横截面切割,然后用铜指示剂根据AWPA标准方法A72-12喷涂。发现铜穿透横截面。
实施例11
防腐处理组合物如下制备:将124.20g由实施例4制备的分散体加入到3375.80g的闪点为约100℃的烃溶剂(<1.0%的芳族含量)中。所得流体含有约1.0%的按重量计的元素铜。然后将该流体使用完全浸注法用于处理1.5x 5.5x 10”南方松木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在120psi加压60分钟。将30”Hg的最终真空施加到木材上持续15分钟以除去残留液体。发现木材具有清晰的表面和可忽略的气味,并且处理溶液显示出良好的稳定性和稳定的粒径。
实施例12
防腐处理组合物如下制备:将124.20g由实施例4制备的分散体加入到3375.80g的闪点为约100℃的烃溶剂(<0.1%的芳族含量)中。所得流体含有约1.0%的按重量计的元素铜。然后将该流体使用完全浸注法用于处理1.5x 5.5x 12”南方松木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在120psi加压60分钟。将30”Hg的最终真空施加到木材上持续15分钟以除去残留液体。发现木材具有清晰的表面和可忽略的气味,并且处理溶液显示出良好的稳定性和稳定的粒径。
实施例13
包含0.40%Cu和0.016%的戊唑醇的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的戊唑醇溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。发现处理的木桩具有清晰的表面。将木桩切割成19mm x 19mm x 450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例14
包含0.48%Cu和0.019%的戊唑醇的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的戊唑醇溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。发现处理的木桩具有清晰的表面。将木桩切割成19mm x 19mm x 450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例15
包含0.74%Cu和0.030%的戊唑醇的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的戊唑醇溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。发现处理的木桩具有清晰的表面。将木桩切割成19mm x 19mm x 450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例16
包含0.99%Cu和0.040%的戊唑醇的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的戊唑醇溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。发现处理的木桩具有清晰的表面。将木桩切割成19mm x 19mm x 450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例17
包含0.42%Cu和0.0084%的氟唑菌苯胺的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的氟唑菌苯胺溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。发现处理的木桩具有清晰的表面。将木桩切割成19mm x19mm x450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例18
包含0.42%Cu和0.0056%的氟唑菌苯胺的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的氟唑菌苯胺溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。发现处理的木桩具有清晰的表面。将木桩切割成19mm x19mm x450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例19
包含0.41%Cu和0.0041%的氟唑菌苯胺的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的氟唑菌苯胺溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。发现处理的木桩具有清晰的表面。将木桩切割成19mm x19mm x450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例20
包含0.42%Cu和0.0034%的氟唑菌苯胺的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的氟唑菌苯胺溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。发现处理的木桩具有清晰的表面。将木桩切割成19mm x19mm x450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例21
包含0.64%Cu和0.013%的氟唑菌苯胺的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的氟唑菌苯胺溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。发现处理的木桩具有清晰的表面。将木桩切割成19mm x 19mm x450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例22
包含0.65%Cu和0.0086%的氟唑菌苯胺的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的氟唑菌苯胺溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。发现处理的木桩具有清晰的表面。将木桩切割成19mm x19mm x450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例23
包含0.50%Cu和0.0050%的氟唑菌苯胺的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的氟唑菌苯胺溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。处理的木桩具有清晰的表面。将木桩切割成19mm x 19mm x450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例24
包含0.65%Cu和0.0052%的氟唑菌苯胺的防腐处理组合物如下制备:混合由实施例4制备的铜浓缩物和在闪点为约80℃的烃溶剂载体(<0.1%的芳族含量)中的氟唑菌苯胺溶液。将制备的处理流体使用完全浸注法用于处理测量为19mm x 19mm x 960mm的南方松边材木桩,其中将木材最初置于25-30”Hg的真空下持续15分钟,然后加入处理溶液。然后将系统在100psi加压30分钟。处理的木桩具有清晰的表面。将木桩切割成19mm x 19mm x450mm尺寸并且安装在两个室外测试场地,以进行抵抗真菌腐烂和白蚁的长期性能测试。
实施例25
包含2.5%Cu和0.10%的戊唑醇的防腐处理组合物如下制备:混合12.86%的铜浓缩物和在烃溶剂载体(丁醇)中的戊唑醇溶液,然后用白色溶剂油溶剂(芳族含量为<20%)稀释。将制备的处理流体用于使用双真空法处理测量为90mm x 22mm x 900mm的辐射松木板,其中将木材最初置于-60kPa的真空下1分钟,然后加入处理溶液。然后将该系统恢复到大气压2分钟,将溶液从处理容器中取出并且施加-85kPa的最终真空达10分钟。经处理的木材具有清晰的表面。铜斑试验显示所有穿透边材的穿透率,其中防腐剂吸收量为16-50L/m3。
实施例26
包含2.5%Cu和0.10%的戊唑醇的防腐处理组合物如下制备:混合12.86%的铜浓缩物和在烃溶剂载体(丁醇)中的戊唑醇溶液,然后用白色溶剂油溶剂(芳族含量为<20%,闪点40-42℃)稀释。将制备的处理流体使用真空和低压方法用于处理测量为90mm x 45mmx 900mm的辐射松样品,其中将木材最初置于-70kPa的真空下1分钟,然后加入处理溶液。然后将系统在50kPa加压2分钟。处理的木材具有清晰的表面。铜斑试验显示所有穿透边材的穿透率,其中防腐剂吸收量为20-60L/m3。
实施例27
包含2.95%Cu和0.12%的戊唑醇的防腐处理组合物如下制备:混合12.86%的铜浓缩物和在烃溶剂载体(丁醇)中的戊唑醇溶液,然后用D80溶剂(芳族含量为<1%和闪点>80℃)稀释。将制备的处理流体使用低压方法用于处理测量为12mm x 8mm x 900mm的辐射松层合板,其中将层合板最初浸入处理溶液中,施加30kPa的压力2分钟,除去溶液并且施加-85kPa的最终真空10分钟。处理的层合板具有清晰的表面。铜斑试验显示处理的木材满足AS/NZS1604.4的要求,其中吸收量为30-40L/m3。
实施例28
包含2.95%Cu和0.12%的戊唑醇的防腐处理组合物如下制备:混合12.86%的铜浓缩物和在烃溶剂载体(丁醇)中的戊唑醇溶液,然后用D40溶剂(芳族含量为<1%和闪点>40℃)稀释。将制备的处理流体使用低压方法用于处理测量为12mm x 8mm x 900mm的辐射松层合板,其中将层合板最初浸入处理溶液中,施加30kPa的压力2分钟,除去溶液并且施加-85kPa的最终真空10分钟。处理的层合板具有清晰的表面。铜斑试验显示处理的木材满足AS/NZS1604.4的要求,其中吸收量为60-80L/m3。
实施例29
包含2.95%Cu和0.12%的戊唑醇的防腐处理组合物如下制备:混合12.86%的铜浓缩物和在烃溶剂载体(丁醇)中的戊唑醇溶液,然后用白色溶剂油溶剂(芳族含量为<20%,闪点40-42℃)稀释。将制备的处理流体使用Rueping方法用于处理测量为90mm x45mm x 900mm的辐射松样品,其中施加50kPa的初始空气压力并且保持1分钟。然后将处理溶液泵入处理筒中同时保持压力,并且一旦充满,则将压力增加至110kPa并且持续2分钟。除去溶液,施加-85kPa的最终真空10分钟。处理的木材具有清晰的表面。铜斑试验显示处理的木材满足AS/NZS1604.1的要求,其中吸收量为20-40L/m3。
Claims (173)
1.一种木材防腐剂组合物,其包含:
a.具有低芳族含量的有机溶剂载体;
b.粒径为约0.005微米至约10微米的金属化合物固体颗粒的分散体;
c.有机杀生物剂;和
d.分散剂;
其中所述分散剂与所述金属化合物的比率为约1:500至约100:1(wt/wt)。
2.一种木材防腐剂组合物,其包含:
a.可生物降解的有机溶剂载体,所述可生物降解的有机溶剂载体选自植物油、可再生资源油和生物柴油;
b.粒径为约0.005微米至约10微米的金属化合物固体颗粒的分散体;
c.有机杀生物剂;和
d.分散剂;
其中所述分散剂与所述金属化合物的比率为约1:500至约100:1(wt/wt)。
3.根据权利要求2所述的木材防腐剂,其中所述有机溶剂为植物油,所述植物油选自亚麻籽油、椰子油、玉米油、棉子油、橄榄油、棕榈油、低芥酸菜子油、棕榈仁油、花生油、菜子油、红花油、芝麻油、大豆油、葵花油、蓖麻油、桐油、罂粟籽油、斑鸠菊油、杏仁油、山毛榉坚果油、巴西坚果油、初榨橄榄油、腰果油、榛子油、澳洲坚果油、蒙刚果油(或曼杰提树油)、胡桃油、松子油、阿月浑子油、核桃油、南瓜子油、巴卡斯果油、葡萄子油、米糠油、烛果油和大麻子油。
4.根据权利要求2所述的木材防腐剂,其中所述有机溶剂为可再生资源油和/或生物柴油。
5.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的d95为小于约10微米。
6.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的d95为小于约5微米。
7.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的d95为小于约2微米。
8.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的d95为小于约1微米。
9.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的d95为小于约0.5微米。
10.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的d95为小于约0.2微米。
11.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的d95为小于约0.1微米。
12.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的平均粒径为约20nm至约100nm。
13.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的平均粒径为约20nm至约200nm。
14.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的平均粒径为约20nm至约500nm。
15.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的平均粒径为约50nm至约200nm。
16.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的平均粒径为约50nm至约300nm。
17.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的平均粒径为约50nm至约500nm。
18.根据权利要求1或2所述的木材防腐剂组合物,其中所述固体颗粒的平均粒径为约100nm至约500nm。
19.根据权利要求1或2所述的木材防腐剂组合物,其中分散剂与金属化合物的比率为约1:100至约10:1(wt/wt)。
20.根据权利要求1或2所述的木材防腐剂组合物,其中分散剂与金属化合物的比率为约1:20至约10:1(wt/wt)。
21.根据权利要求1或2所述的木材防腐剂组合物,其中分散剂与金属化合物的比率为约1:10至约1:1(wt/wt)。
22.根据权利要求1或2所述的木材防腐剂组合物,其中所述有机溶剂载体包含的芳族含量为小于约22重量%。
23.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体包含的芳族含量为小于约15重量%。
24.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体包含的芳族含量为小于约8重量%。
25.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体包含的芳族含量为小于约1重量%。
26.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体包含的芳族含量为小于约0.1重量%。
27.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体基本不含芳族化合物。
28.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约20℃。
29.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约30℃。
30.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约40℃。
31.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约60℃。
32.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约80℃。
33.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约100℃。
34.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约120℃。
35.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约140℃。
36.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约40℃至约300℃。
37.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约60℃至约95℃。
38.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约130℃至约270℃。
39.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约130℃至约185℃。
40.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约140℃至约200℃。
41.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约150℃至约190℃。
42.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约180℃至约220℃。
43.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约190℃至约250℃。
44.根据权利要求1所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约220℃至约270℃。
45.根据权利要求1所述的木材防腐剂组合物,其中所述金属化合物为铜化合物。
46.根据权利要求45所述的木材防腐剂组合物,其中所述铜化合物选自铜金属、氧化亚铜、氧化铜、氢氧化铜、碳酸铜、碱式碳酸铜、氯氧化铜、8-羟基喹啉铜、二甲基二硫代氨基甲酸铜、吡啶硫酮铜、硼酸铜和碱式硼酸铜。
47.根据权利要求46所述的木材防腐剂组合物,其中铜浓度为约0.05%至约5.0%(wt/wt)。
48.根据权利要求46所述的木材防腐剂组合物,其中铜浓度为约0.5%至约3.0%(wt/wt)。
49.根据权利要求1或2所述的木材防腐剂组合物,其中所述有机杀生物剂为三唑或吡唑。
50.根据权利要求49所述的木材防腐剂组合物,其中所述三唑选自氧环唑、糠菌唑、环菌唑、苄氯三唑醇、苯醚甲环唑、烯唑醇、烯唑醇-M、氟环唑、乙环唑、腈苯唑、氟喹唑、氟硅唑、粉唑醇、呋菌唑、呋醚唑、己唑醇、亚胺唑、种菌唑、ipfentrifluconazole、mefentrifluconazole、叶菌唑、腈菌唑、戊菌唑、丙环唑、丙硫菌唑、唑喹菌酮、硅氟唑、戊唑醇、四氟醚唑、三唑酮、三唑醇、灭菌唑、烯效唑和烯效唑-P。
51.根据权利要求49所述的木材防腐剂组合物,其中所述吡唑选自苯丙烯氟菌唑、联苯吡菌胺、胺苯吡菌酮、氟唑菌酰胺、呋吡菌胺、吡唑萘菌胺、oxathiapiprolin、氟唑菌苯胺、吡噻菌胺、氟唑菌酰羟胺、吡唑醚菌酯、唑胺菌酯、唑菌酯、吡咪唑和氟唑环菌胺。
52.根据权利要求1或2所述的木材防腐剂组合物,其中所述杀生物剂选自杀真菌剂、杀细菌剂、杀白蚁剂和杀霉剂。
53.根据权利要求1或2所述的木材防腐剂组合物,其中所述组合物进一步包含选自着色剂、UV稳定剂、颜料和防水剂的添加剂。
54.一种处理木材产品的方法,所述方法包括使所述木材产品与组合物接触,所述组合物包含:
a.具有低芳族含量的有机溶剂载体;
b.粒径为约0.005微米至约10微米的金属化合物固体颗粒的分散体;
c.有机杀生物剂;和
d.分散剂;
其中所述分散剂与所述金属化合物的比率为约1:500至约100:1。
55.一种处理木材产品的方法,所述方法包括使所述木材产品与权利要求2所述的组合物接触。
56.一种处理木材产品的方法,所述方法包括使所述木材产品与权利要求3所述的组合物接触。
57.一种处理木材产品的方法,所述方法包括使所述木材产品与权利要求4所述的组合物接触。
58.根据权利要求54或55所述的方法,其中所述金属化合物为铜化合物。
59.根据权利要求58所述的方法,其中铜浓度为约0.05%至约5.0%(wt/wt)。
60.根据权利要求58所述的方法,其中铜浓度为约0.5%至约3.0%(wt/wt)。
61.根据权利要求54所述的方法,其中处理的木材产品中的溶液吸收量为小于约600L/m3。
62.根据权利要求54所述的方法,其中处理的木材产品中的溶液吸收量为小于约500L/m3。
63.根据权利要求54所述的方法,其中处理的木材产品中的溶液吸收量为小于约400L/m3。
64.根据权利要求54所述的方法,其中处理的木材产品中的溶液吸收量为小于约300L/m3。
65.根据权利要求54所述的方法,其中处理的木材产品中的溶液吸收量为小于约200L/m3。
66.根据权利要求54所述的方法,其中处理的木材产品中的溶液吸收量为小于约100L/m3。
67.根据权利要求54所述的方法,其中处理的木材产品中的溶液吸收量为小于约50L/m3。
68.根据权利要求54所述的方法,其中处理的木材产品中的溶液吸收量为小于约10L/m3。
69.根据权利要求54或55所述的方法,其中所述接触选自压力和/或真空处理、浸渍、喷涂、刷涂和微波处理。
70.根据权利要求54所述的方法,其中处理的木材产品的表面基本没有颗粒残留物。
71.根据权利要求54所述的方法,其中所述木材产品可在所述接触步骤后立即使用而无需进行干燥步骤。
72.根据权利要求71所述的方法,其中所述干燥步骤选自真空处理、加热、窑干和风干。
73.一种制备分散体的方法,所述方法包括以下步骤:
a.将具有低芳族含量的有机溶剂载体、金属化合物固体颗粒和分散剂组合;
b.将步骤(a)的混合物转移到预先填充有研磨介质的研磨机中;和
c.将步骤(a)的混合物研磨至约0.005微米至约10微米的粒径;
其中所述分散剂与所述金属化合物的比率为约1:500至约100:1。
74.根据权利要求73所述的方法,其中所述研磨介质的密度为至少约2.5g/cm3。
75.根据权利要求73所述的方法,其中所述研磨介质的密度为至少约3.8g/cm3。
76.根据权利要求73所述的方法,其中所述研磨介质的密度为至少约5.5g/cm3。
77.根据权利要求73所述的方法,其中所述研磨介质的密度为至少约6g/cm3。
78.根据权利要求73所述的方法,所述方法进一步包括将所述分散体用具有低芳族含量的有机溶剂载体稀释的步骤,其中所述芳族含量为小于约22重量%。
79.根据权利要求73所述的方法,所述方法进一步包括将所述分散体用具有低芳族含量的有机溶剂载体稀释的步骤,其中所述芳族含量为小于约15重量%。
80.根据权利要求73所述的方法,所述方法进一步包括将所述分散体用具有低芳族含量的有机溶剂载体稀释的步骤,其中所述芳族含量为小于约8重量%。
81.根据权利要求73所述的方法,所述方法进一步包括将所述分散体用具有低芳族含量的有机溶剂载体稀释的步骤,其中所述芳族含量为小于约1重量%。
82.根据权利要求73所述的方法,所述方法进一步包括将所述分散体用具有低芳族含量的有机溶剂载体稀释的步骤,其中所述芳族含量为小于约0.1重量%。
83.根据权利要求73所述的方法,所述方法进一步包括将所述分散体用具有低芳族含量的有机溶剂载体稀释的步骤,其中所述芳族含量为基本0重量%。
84.一种木材产品,其通过将所述木材产品用木材防腐剂组合物处理的方法制备,其中所述木材防腐剂组合物包含:
a.具有低芳族含量的有机溶剂载体;
b.大小为约0.005微米至约10微米的金属化合物固体颗粒的分散体;
c.有机杀生物剂;和
d.分散剂;
其中所述分散剂与所述金属化合物的比率为约1:500至约100:1(wt/wt)。
85.根据权利要求84所述的木材产品,其中所述木材产品基本无气味。
86.根据权利要求84所述的木材产品,其中与未处理的木材产品或用包含含水载体的木材防腐剂处理的木材产品相比,所述木材产品的尺寸稳定性增加。
87.根据权利要求86所述的木材产品,其中所述木材产品在储存期间基本没有溶胀、干裂、分裂、翘曲或扭曲。
88.根据权利要求84所述的木材产品,其中所述木材产品在所述木材产品表面上基本没有颗粒残留物。
89.根据权利要求84所述的木材产品,其中所述金属化合物为铜化合物。
90.根据权利要求84所述的木材产品,其中所述木材产品中的铜的量为小于约16Kg/m3。
91.根据权利要求84所述的木材产品,其中所述木材产品中的铜的量为小于约10Kg/m3。
92.根据权利要求84所述的木材产品,其中所述木材产品中的铜的量为小于约5Kg/m3。
93.根据权利要求84所述的木材产品,其中所述木材产品中的铜的量为小于约1Kg/m3。
94.一种木材防腐剂组合物,其包含:
a.具有低芳族含量的有机溶剂载体;和
b.有效地使得用所述组合物处理的木材抵抗真菌腐烂的量的氟唑菌苯胺。
95.根据权利要求94所述的木材防腐剂组合物,其中所述组合物基本不含铜化合物颗粒。
96.木材防腐剂组合物,其包含:
a.可生物降解的有机溶剂载体,所述可生物降解的有机溶剂载体选自植物油、可再生资源油和生物柴油;
b.有效地使得用所述组合物处理的木材抵抗真菌腐烂的量的氟唑菌苯胺。
97.根据权利要求96所述的木材防腐剂,其中所述有机溶剂为植物油,所述植物油选自亚麻籽油、椰子油、玉米油、棉子油、橄榄油、棕榈油、低芥酸菜子油、棕榈仁油、花生油、菜子油、红花油、芝麻油、大豆油、葵花油、蓖麻油、桐油、罂粟籽油、斑鸠菊油、杏仁油、山毛榉坚果油、巴西坚果油、初榨橄榄油、腰果油、榛子油、澳洲坚果油、蒙刚果油(或曼杰提树油)、胡桃油、松子油、阿月浑子油、核桃油、南瓜子油、巴卡斯果油、葡萄子油、米糠油、烛果油和大麻子油。
98.根据权利要求96所述的木材防腐剂,其中所述有机溶剂为可再生资源油和/或生物柴油。
99.根据权利要求96所述的木材防腐剂组合物,其中所述组合物基本不含铜化合物颗粒。
100.一种处理木材产品以使得其抵抗真菌腐烂和尺寸稳定的方法,所述方法包括以下步骤:
1)使所述木材与组合物接触,所述组合物包含:
a.具有低芳族含量的有机溶剂载体;和
b.氟唑菌苯胺;和
2)干燥所述木材产品,其中使得处理的木材产品抵抗真菌腐烂和尺寸稳定。
101.根据权利要求100所述的方法,其中所述组合物基本不含铜化合物颗粒。
102.一种处理木材产品以使得其抵抗真菌腐烂和尺寸稳定的方法,所述方法包括以下步骤:
1)使所述木材与组合物接触,所述组合物包含:
a.可生物降解的有机溶剂载体,所述可生物降解的有机溶剂载体选自植物油、可再生资源油和生物柴油;和
b.使得所述木材抵抗真菌腐烂的有效量的氟唑菌苯胺;和
2)干燥所述木材产品,其中使得处理的木材产品抵抗真菌腐烂和尺寸稳定。
103.根据权利要求102所述的方法,其中所述有机溶剂为植物油,所述植物油选自亚麻籽油、椰子油、玉米油、棉子油、橄榄油、棕榈油、低芥酸菜子油、棕榈仁油、花生油、菜子油、红花油、芝麻油、大豆油、葵花油、蓖麻油、桐油、罂粟籽油、斑鸠菊油、杏仁油、山毛榉坚果油、巴西坚果油、初榨橄榄油、腰果油、榛子油、澳洲坚果油、蒙刚果油(或曼杰提树油)、胡桃油、松子油、阿月浑子油、核桃油、南瓜子油、巴卡斯果油、葡萄子油、米糠油、烛果油和大麻子油。
104.根据权利要求102所述的方法,其中所述有机溶剂为可再生资源油和/或生物柴油。
105.根据权利要求102所述的方法,其中所述组合物基本不含铜化合物颗粒。
106.一种用根据权利要求94所述的组合物处理的木材产品。
107.一种用根据权利要求96所述的组合物处理的木材产品。
108.一种通过权利要求100所述的方法处理的木材产品。
109.一种通过权利要求102所述的方法处理的木材产品。
110.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体包含的芳族含量为小于约22重量%。
111.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体包含的芳族含量为小于约15重量%。
112.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体包含的芳族含量为小于约8重量%。
113.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体包含的芳族含量为小于约1重量%。
114.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体包含的芳族含量为小于约0.1重量%。
115.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体基本不含芳族化合物。
116.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约20℃。
117.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约30℃。
118.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约40℃。
119.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约60℃。
120.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约80℃。
121.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约100℃。
122.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约120℃。
123.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的最小闪点为约140℃。
124.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约40℃至约300℃。
125.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约60℃至约95℃。
126.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约130℃至约270℃。
127.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约130℃至约185℃。
128.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约140℃至约200℃。
129.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约150℃至约190℃。
130.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约180℃至约220℃。
131.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约190℃至约250℃。
132.根据权利要求94所述的木材防腐剂组合物,其中所述有机溶剂载体的沸点为约220℃至约270℃。
133.根据权利要求106所述的木材产品,其中所述木材产品中的氟唑菌苯胺的量为小于约0.25%重量/重量。
134.根据权利要求106所述的木材产品,其中所述木材产品中的氟唑菌苯胺的量为约0.0001%至0.10%重量/重量。
135.根据权利要求106所述的木材产品,其中所述木材产品中的氟唑菌苯胺的量为约0.001%至0.05%重量/重量。
136.根据权利要求106所述的木材产品,其中所述木材产品中的氟唑菌苯胺的量为约0.005%至0.025%重量/重量。
137.根据权利要求107所述的木材产品,其中所述木材产品中的氟唑菌苯胺的量为小于约0.25%重量/重量。
138.根据权利要求107所述的木材产品,其中所述木材产品中的氟唑菌苯胺的量为约0.0001%至0.10%重量/重量。
139.根据权利要求107所述的木材产品,其中所述木材产品中的氟唑菌苯胺的量为约0.001%至0.05%重量/重量。
140.根据权利要求107所述的木材产品,其中所述木材产品中的氟唑菌苯胺的量为约0.005%至0.025%重量/重量。
141.根据权利要求100所述的方法,其中所述有机溶剂载体包含的芳族含量为小于约22重量%。
142.根据权利要求100所述的方法,其中所述有机溶剂载体包含的芳族含量为小于约15重量%。
143.根据权利要求100所述的方法,其中所述有机溶剂载体包含的芳族含量为小于约8重量%。
144.根据权利要求100所述的方法,其中所述有机溶剂载体包含的芳族含量为小于约1重量%。
145.根据权利要求100所述的方法,其中所述有机溶剂载体包含的芳族含量为小于约0.1重量%。
146.根据权利要求100所述的方法,其中所述有机溶剂载体基本不含芳族化合物。
147.根据权利要求100所述的方法,其中所述有机溶剂载体的最小闪点为约20℃。
148.根据权利要求100所述的方法,其中所述有机溶剂载体的最小闪点为约30℃。
149.根据权利要求100所述的方法,其中所述有机溶剂载体的最小闪点为约40℃。
150.根据权利要求100所述的方法,其中所述有机溶剂载体的最小闪点为约60℃。
151.根据权利要求100所述的方法,其中所述有机溶剂载体的最小闪点为约80℃。
152.根据权利要求100所述的方法,其中所述有机溶剂载体的最小闪点为约100℃。
153.根据权利要求100所述的方法,其中所述有机溶剂载体的最小闪点为约120℃。
154.根据权利要求100所述的方法,其中所述有机溶剂载体的最小闪点为约140℃。
155.根据权利要求100所述的方法,其中所述有机溶剂载体的沸点为约40℃至约300℃。
156.根据权利要求100所述的方法,其中所述有机溶剂载体的沸点为约60℃至约95℃。
157.根据权利要求100所述的方法,其中所述有机溶剂载体的沸点为约130℃至约270℃。
158.根据权利要求100所述的方法,其中所述有机溶剂载体的沸点为约130℃至约185℃。
159.根据权利要求100所述的方法,其中所述有机溶剂载体的沸点为约140℃至约200℃。
160.根据权利要求100所述的方法,其中所述有机溶剂载体的沸点为约150℃至约190℃。
161.根据权利要求100所述的方法,其中所述有机溶剂载体的沸点为约180℃至约220℃。
162.根据权利要求100所述的方法,其中所述有机溶剂载体的沸点为约190℃至约250℃。
163.根据权利要求100所述的方法,其中所述有机溶剂载体的沸点为约220℃至约270℃。
164.根据权利要求100所述的方法,其中所述处理的木材产品中的氟唑菌苯胺的量为小于约0.25%重量/重量。
165.根据权利要求100所述的方法,其中所述处理的木材产品中的氟唑菌苯胺的量为约0.0001%至0.10%。
166.根据权利要求100所述的方法,其中所述处理的木材产品中的氟唑菌苯胺的量为约0.001重量/重量%至0.05重量/重量%。
167.根据权利要求100所述的方法,其中所述处理的木材产品中的氟唑菌苯胺的量为约0.005%至0.025%。
168.根据权利要求94或权利要求96所述的组合物,其进一步包含杀虫剂,所述杀虫剂选自新烟碱类杀虫剂、拟除虫菊酯杀虫剂、吡唑杀虫剂、氨基甲酸酯杀虫剂、二酰胺杀虫剂和醚菊酯醚杀虫剂。
169.根据权利要求168所述的组合物,其中所述杀虫剂选自吡虫啉、氟氯菊酯、氯菊酯、溴氰菊酯、氯氰菊酯、吡虫啉、氟虫腈、毒死蜱、醚菊酯和氯虫苯甲酰胺。
170.根据权利要求100或权利要求102所述的方法,其中所述组合物进一步包含杀虫剂,所述杀虫剂选自新烟碱类杀虫剂、拟除虫菊酯杀虫剂、吡唑杀虫剂、氨基甲酸酯杀虫剂、二酰胺杀虫剂和醚菊酯醚杀虫剂。
171.根据权利要求170所述的方法,其中所述杀虫剂选自吡虫啉、氟氯菊酯、氯菊酯、溴氰菊酯、氯氰菊酯、吡虫啉、氟虫腈、毒死蜱、醚菊酯和氯虫苯甲酰胺。
172.根据权利要求170所述的方法,其中所述处理的木材中的杀虫剂水平为约0.0001%至约0.1%重量/重量。
173.根据权利要求170所述的方法,其中所述处理的木材中的杀虫剂水平为约0.001%至约0.01%重量/重量。
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US20220264889A1 (en) * | 2019-08-07 | 2022-08-25 | Corning Incorporated | Biocidal dispersions for coating compositions |
US20210122923A1 (en) * | 2019-10-28 | 2021-04-29 | Polymer Synergies, LLC | Bio-Based Hydrophobic Formulations For Use in Engineered Wood Composites |
WO2022198054A1 (en) * | 2021-03-19 | 2022-09-22 | Arxada, LLC | Zinc and boron containing enhanced wood preservative |
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