CN110437945A - Cleaning agent and preparation method thereof for wire-cloth - Google Patents
Cleaning agent and preparation method thereof for wire-cloth Download PDFInfo
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- CN110437945A CN110437945A CN201910719254.1A CN201910719254A CN110437945A CN 110437945 A CN110437945 A CN 110437945A CN 201910719254 A CN201910719254 A CN 201910719254A CN 110437945 A CN110437945 A CN 110437945A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
- C11D1/8255—Mixtures of compounds all of which are non-ionic containing a combination of compounds differently alcoxylised or with differently alkylated chains
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2089—Ether acids-salts thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- Engineering & Computer Science (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
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- Health & Medical Sciences (AREA)
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- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to the cleaning agents and preparation method thereof for wire-cloth, by weight, raw material is made of 4-7 parts of alcohol ether carboxylate, 4-6 parts of isomerous tridecanol polyoxyethylene ether, 3-5 parts of heterogeneous ten alcohol polyoxyethylene ether, 10-13 parts of octyl phenol polyoxyethylene ether, 3-6 parts of coconut oil diethanol amide, 5-9 parts of ammonium chloride, 2-5 parts of triethanolamine, 1-3 parts of Sodium Polyacrylate and 46-68 parts of water.Cleaning agent of the invention is alkalescent cleaning agent, does not have corrosiveness to polyester and polyamide material, use is safe and environment-friendly.By the introducing of the bleeding agents such as heterogeneous ten alcohol polyoxyethylene ether in the present invention, can promote to form net surface quickly cleaned agent wetting, and to forming net internal penetration, cleaning speed is substantially accelerated.The present invention increases activating component, and the ability of forming net cleaning agent washing inorganic foulants can be improved.
Description
Technical field
The present invention relates to the cleaning agents and preparation method thereof for wire-cloth, belong to pulp technology for making paper.
Background technique
With the high speed development of paper industry, the speed and breadth of paper machine are continuously improved, and yield is significantly reinforced.But
Modernization high-speed paper machine puts forward higher requirements working condition, especially becomes increasingly harsher to the requirement of wire-cloth.
It is produced in order to ensure paper machine optimizes, wire-cloth must keep good operating status, the cleaning of forming net is kept to seem outstanding
It is important.Meanwhile for extend as far as possible forming net service life, the cleaning of forming net is also critically important.
There are many different type product, leaning solvent, alkaline cleaner, acidity in the market for wire-cloth cleaning agent
Cleaning agent etc..Leaning solvent adds the organic solvents such as chloroform, and cleaning effect is fine, but has significant impact to environment, no
Meet environmental requirement, belongs to obsolete product.
Washing inorganic foulants are easy using acidic cleaner, majority, which is used for a long time, has corrosiveness to forming net raw material,
Forming net can be damaged.In common polyamide moulding net, polyamide is very sensitive to acid, and acidity is excessively high or acid residence time is too long all
Special hazard.Acid simultaneously to have an impact to environment, operator needs to put on the safeguard measures such as protective garment.
Alkaline paper-making forming net cleaning agent washs organic dirt such as pulp deposits object fine.Commercial available alkaline cleaning agent one
As using the strong basicities ingredient such as sodium hydroxide, after being handled, sewage side can be discharged.And alkaline cleaner is to inorganic dirt
Object cleaning is difficult.After general wire-cloth cleaning agent use, penetration is poor, and it is slow to penetrate into the forming net internal-response time.
Summary of the invention
In view of the deficiencies of the prior art, the present invention is provided to cleaning agents of wire-cloth and preparation method thereof, to mention
For the washability and detersive efficiency of cleaning agent.
In order to solve the above-mentioned technical problem, technical scheme is as follows:
For the cleaning agent of wire-cloth, by weight, raw material is by 4-7 parts of alcohol ether carboxylate, isomerous tridecanol
4-6 parts of polyoxyethylene ether, 3-5 parts of heterogeneous ten alcohol polyoxyethylene ether, 10-13 parts of octyl phenol polyoxyethylene ether, coconut oil diethanol
3-6 parts of amide, 5-9 parts of ammonium chloride, 2-5 parts of triethanolamine, 1-3 parts of Sodium Polyacrylate and 46-68 parts of water compositions.
Further, by weight, raw material is by 5-6 parts of alcohol ether carboxylate, isomerous tridecanol polyoxyethylene ether 4.5-
5.5 parts, 3.5-4.5 parts of heterogeneous ten alcohol polyoxyethylene ether, 11-12 parts of octyl phenol polyoxyethylene ether, coconut oil diethanol amide
3.5-5.5 part, 6-8 parts of ammonium chloride, 3-4 parts of triethanolamine, 1.5-2.5 parts of Sodium Polyacrylate and 48-65 parts of water compositions.
Further, the degree of polymerization of the isomerous tridecanol polyoxyethylene ether is 7-10, heterogeneous ten alcohol polyoxyethylene ether
The degree of polymerization is 5-9, and the degree of polymerization of octyl phenol polyoxyethylene ether is 8-12.
Further, the degree of polymerization of the isomerous tridecanol polyoxyethylene ether is 9.
Further, the degree of polymerization of the heterogeneous ten alcohol polyoxyethylene ether is 7.
Further, the degree of polymerization of the octyl phenol polyoxyethylene ether is 10.
The preparation method of cleaning agent as described above, which is characterized in that by water, octyl phenol polyoxyethylene ether, isomery 13
Alcohol polyoxyethylene ether and heterogeneous ten alcohol polyoxyethylene ether mixing, are warming up to 50-55 DEG C, after stirring 10-20min, add alcohol ether
Carboxylate, Sodium Polyacrylate and ammonium chloride continue to stir 5-15min, triethanolamine and coconut oil diethanol amide are then added,
Continue to stir 15-25min, obtains cleaning agent finished product.
Further, stirring rate 50-70r/min.
Further, deionized water, octyl phenol polyoxyethylene ether, isomerous tridecanol are sequentially added into clean reaction kettle
Polyoxyethylene ether and heterogeneous ten alcohol polyoxyethylene ether are warming up to 50-55 DEG C, stir 10-20min；Sequentially add alcohol ether carboxylate
Salt, Sodium Polyacrylate and ammonium chloride stir 5-15min, are eventually adding triethanolamine and coconut oil diethanol amide, stir 15-
25min obtains cleaning agent finished product.
Without acid and phosphate in cleaning agent of the invention, to molding net materials safety, corrosion-free effect.The chlorination of addition
Ammonium facilitates solution micella and becomes larger as activating component, and help forms layered liquid crystal, while improving system viscosity, increases pungent
The washability of base phenol polyethenoxy ether, isomerous tridecanol polyoxyethylene ether.With calcium carbonate etc. to the ability of inorganic foulants washing.
Heterogeneous ten alcohol polyoxyethylene ether promotes molding net surface quickly wetted, and to forming net internal penetration, it is slow to facilitate ammonium chloride
Forming net inorganic foulants in slow contact generate chemical reaction with the inorganic matter in mesh, the process of reaction have metathesis and
Decomposition exists simultaneously, and improves ammonium chloride and washs inorganic foulants ability.
The isomerous tridecanol polyoxyethylene ether that the degree of polymerization is 9, dissolves easily in water, in the isomerous tridecanol of degree of polymerization 7-10
Washing force is best in polyoxyethylene ether.The degree of polymerization is the base resistant wetting agent of the degree of polymerization 7 in the heterogeneous ten alcohol polyoxyethylene ether of 5-9
Most preferably.The octyl phenol polyoxyethylene ether degree of polymerization is 10, soluble easily in water, has good emulsification, wetting, diffusion, washing performance, together
When industrialize most common kind, cheap while reliable in quality.
In the present invention, triethanolamine can improve oily dirt, and the removal of especially nonpolar greasy dirt passes through raising simultaneously
Detergency ability can be improved in alkalinity, and has fabulous i.e. compatibility.And triethanolamine is alkalescent substance, it is environmentally friendly, no
Molding net materials are caused to corrode.
Heterogeneous ten alcohol polyoxyethylene ether is a kind of extraordinary bleeding agent, promotes molding net surface quickly to be formed by papermaking clear
Lotion wetting, and to forming net internal penetration, papermaking form cleaning agent can with forming net fast reaction, when can shorten washing
Between, chemical and forming net time of contact are reduced, while downtime can also be reduced, improves paper machine running rate.
Sodium Polyacrylate can reduce the redeposition (higher white retentivity) of dirt substance, reduce fibrous matter
Fouling；Meanwhile there is stronger sequestering power, facilitate the hardness bring side effect for offsetting water, enhances cleaning agent decontamination energy
Power enhances the performance of without phosphorus cleaning agent.
Cleaning agent of the invention is concentrated type product, and low concentration dilution uses.To the adherent deposit of dry net surface complexity
With good osmosis and cleaning action.The dry net of paper machine can effectively be cleaned when paper machine is shut down, improve dry net
Permeability, keep the clean manufacturing of Dryer Section of Paper Machine, extend the service life of the dry net of paper machine, reduced to the greatest extent because doing
The paper defects such as the broken end of page caused by dry portion's adherent deposit, stablize paper quality.
Cleaning agent of the invention is alkalescent cleaning agent, does not have a corrosiveness to polyester and polyamide material, use is safe,
Environmental protection.By the introducing of the bleeding agents such as heterogeneous ten alcohol polyoxyethylene ether in the present invention, molding net surface can be promoted quickly to be cleaned
Agent wetting, and to forming net internal penetration, it can be shortened scavenging period, cleaning speed is substantially accelerated.The present invention increases activating component,
The ability of forming net cleaning agent washing inorganic foulants can be improved.
Specific embodiment
The present invention is further illustrated combined with specific embodiments below, but the present invention is not limited in following implementation
Example.
Embodiment 1
To 1000L reaction kettle successively put into 550 kilograms of deionized water, octyl phenol polyoxyethylene ether (10, indicate the degree of polymerization,
Similarly hereinafter) 110 kilograms, (9) 60 kilograms and (7) 50 kilograms of heterogeneous ten alcohol polyoxyethylene ether of isomerous tridecanol polyoxyethylene ether, at this time
Agitator speed is warming up to 50-55 DEG C at 60r/min, stirs 15 minutes, keeps octyl phenol polyoxyethylene ether (10) all molten
Solution；40 kilograms of alcohol ether carboxylate, 20 kilograms of Sodium Polyacrylate and 80 kilograms of ammonium chloride are sequentially added, stirs 10 minutes, finally
50 kilograms and 40 kilograms of coconut oil diethanol amide of triethanolamine are added, is stirred 20 minutes.Product is detected, after detection is qualified
With filter filtering and discharging, cleaning agent is obtained, defoaming agent defoaming can be actually added into according to production.
Embodiment 2
535 kilograms of deionized water, (10) 100 kilograms of octyl phenol polyoxyethylene ether, isomery are successively put into 1000L reaction kettle
(9) 40 kilograms and (7) 40 kilograms of heterogeneous ten alcohol polyoxyethylene ether of tridecanol polyoxyethylene ether, agitator speed is in 50r/ at this time
Under min, it is warming up to 50-55 DEG C, is stirred 15 minutes, dissolves octyl phenol polyoxyethylene ether (10) all；Sequentially add alcohol ether
70 kilograms of carboxylate, 30 kilograms of Sodium Polyacrylate and 90 kilograms of ammonium chloride stir 10 minutes, are eventually adding 45 kilograms of triethanolamine
With 50 kilograms of coconut oil diethanol amide, stir 20 minutes.Product is detected, and uses filter filtering and discharging after detection is qualified.
Defoaming agent defoaming can be actually added into according to production.
Embodiment 3
560 kilograms of deionized water, (10) 130 kilograms of octyl phenol polyoxyethylene ether, isomery are successively put into 1000L reaction kettle
(9) 50 kilograms and (7) 45 kilograms of heterogeneous ten alcohol polyoxyethylene ether of tridecanol polyoxyethylene ether, agitator speed is in 70r/ at this time
Under min, it is warming up to 50-55 DEG C, is stirred 15 minutes, dissolves octyl phenol polyoxyethylene ether (10) all；Sequentially add alcohol ether
45 kilograms of carboxylate, 30 kilograms of Sodium Polyacrylate and 70 kilograms of ammonium chloride stir 10 minutes, are eventually adding 40 kilograms of triethanolamine
With 30 kilograms of coconut oil diethanol amide, stir 20 minutes.Product is detected, and uses filter filtering and discharging after detection is qualified.
Defoaming agent defoaming can be actually added into according to production.
Paraffin removal power detection method
Standard wax stone is dissolved into 90 degree of hot water, after mixing evenly, reference white is immersed and washs lining cloth, taken after two minutes
Out, it and air-dries.Cerecloth is cut to 5*5cm, is immersed in the working solution that stoste (corresponding cleaning agent) concentration is 5%, in 100 DEG C of temperature
Under the conditions of, oscillation washing 10 minutes, abundant cold water is cleaned, and the whiteness of cerecloth after measurement washing, whiteness value W is bigger, shows the table
Face activating agent paraffin removal ability is better.The paraffin removal power of the cleaning agent of embodiment 1-3 is detected according to the above method.
The results are shown in Table 1 for the cleaning agent correlation conventional detection of embodiment 1-3.
The cleaning agent conventional detection result table of 1 embodiment 1-3 of table
| Appearance | Smell | Product stability | Paraffin removal power | |
| Embodiment 1 | Light yellow viscous liquid | Slightly | It is not stratified without precipitate | 63.24 |
| Embodiment 2 | Light yellow viscous liquid | Slightly | It is not stratified without precipitate | 61.03 |
| Embodiment 3 | Light yellow viscous liquid | Slightly | It is not stratified without precipitate | 60.37 |
The detection of Hunan paper mill clean-in-place
Cleaning agent and soft water are made into dilution with 1:1000, the dry net of paper machine is cleaned.Dilution high pressure washing
Spray forming net, hydraulic pressure 1.5Mpa.
Existing adherent deposit is clean on paper machine, the inorganic foulants of especially difficult cleaning.Opposite Hunan papermaking simultaneously
Factory's existing product reduces downtime, improves paper machine running rate.And the cleaning of embodiment 1-3 is tried out in Hunan paper mill
During agent, resinous substances is greatly decreased in the redeposition of forming net, does not cause to corrode to molding net materials, also improvement forming net
Permeability, keep paper machine clean manufacturing.
Comparative example experiment
Comparative example 1: to 1000L reaction kettle successively put into 550 kilograms of deionized water, octyl phenol polyoxyethylene ether (10, indicate
The degree of polymerization, similarly hereinafter) 110 kilograms, (9) 60 kilograms of isomerous tridecanol polyoxyethylene ether and heterogeneous ten alcohol polyoxyethylene ether (7) 50 are public
Jin, agitator speed is warming up to 50-55 DEG C at 60r/min at this time, stirs 15 minutes, makes octyl phenol polyoxyethylene ether (10)
All dissolutions；40 kilograms of alcohol ether carboxylate, 20 kilograms of Sodium Polyacrylate are sequentially added, stirs 10 minutes, is eventually adding three second
It 50 kilograms and 40 kilograms of coconut oil diethanol amide of hydramine, stirs 20 minutes.Product is detected, and uses filter after detection is qualified
Filtering and discharging obtains cleaning agent, and defoaming agent defoaming can be actually added into according to production.
Comparative example 2: 535 kilograms of deionized water, octyl phenol polyoxyethylene ether (10) 100 are successively put into 1000L reaction kettle
Kilogram, (9) 40 kilograms of isomerous tridecanol polyoxyethylene ether and (7) 40 kilograms of heterogeneous ten alcohol polyoxyethylene ether, blender turns at this time
Speed is warming up to 50-55 DEG C at 50r/min, stirs 15 minutes, dissolves octyl phenol polyoxyethylene ether (10) all；Again successively
70 kilograms of alcohol ether carboxylate, 30 kilograms of Sodium Polyacrylate is added, stirs 10 minutes, is eventually adding 45 kilograms of triethanolamine and coconut
50 kilograms of oily diglycollic amide stirs 20 minutes.Product is detected, and uses filter filtering and discharging after detection is qualified.It can basis
Production is actually added into defoaming agent defoaming.
Comparative example 3: 560 kilograms of deionized water, octyl phenol polyoxyethylene ether (10) 130 are successively put into 1000L reaction kettle
Kilogram, (9) 50 kilograms of isomerous tridecanol polyoxyethylene ether and (7) 45 kilograms of heterogeneous ten alcohol polyoxyethylene ether, blender turns at this time
Speed is warming up to 50-55 DEG C at 70r/min, stirs 15 minutes, dissolves octyl phenol polyoxyethylene ether (10) all；Again successively
45 kilograms of alcohol ether carboxylate, 30 kilograms of Sodium Polyacrylate is added, stirs 10 minutes, is eventually adding 40 kilograms of triethanolamine and coconut
30 kilograms of oily diglycollic amide stirs 20 minutes.Product is detected, and uses filter filtering and discharging after detection is qualified.It can basis
Production is actually added into defoaming agent defoaming.
Embodiment cleaning agent and the cleaning agent of comparative example compare the cleaning effect of inorganic foulants
500ml pure water and 50ml forming net cleaning agent are added in clean 1000ml beaker, is placed on water-bath and keeps the temperature,
Keep temperature 45 C；Inorganic foulants coating (350mm*200mm polyamide screen cloth) is immersed in 1000ml beaker, impregnates 30 points
Clock；Screen cloth is finally taken out, is dried after rinsed clean.Repetition is done 80 times.Screen cloth will be dried, in micro- sem observation, dirt has residual
It is considered as unqualified.
The cleaning agent inorganic foulants wash result table of table 2 embodiment 1-3 and comparative example 1-3
| Screen cloth sample | Acceptance number | Qualification rate |
| Embodiment 1 | 72 | 90% |
| Comparative example 1 | 6 | 7.5% |
| Embodiment 2 | 69 | 85.25% |
| Comparative example 2 | 12 | 15% |
| Embodiment 3 | 65 | 81.25% |
| Comparative example 3 | 7 | 8.75% |
Comparative example 4: to 1000L reaction kettle successively put into 550 kilograms of deionized water, octyl phenol polyoxyethylene ether (10, indicate
The degree of polymerization, similarly hereinafter) 110 kilograms, (7) 50 kilograms of heterogeneous ten alcohol polyoxyethylene ether, agitator speed rises at 60r/min at this time
Temperature stirs 15 minutes to 50-55 DEG C, dissolves octyl phenol polyoxyethylene ether (10) all；Sequentially add alcohol ether carboxylate 40
Kilogram, 20 kilograms of Sodium Polyacrylate and 80 kilograms of ammonium chloride, stir 10 minutes, be eventually adding 50 kilograms of triethanolamine and coconut oil
It 40 kilograms of diglycollic amide, stirs 20 minutes.Product is detected, and is used filter filtering and discharging after detection is qualified, is cleaned
Agent can be actually added into defoaming agent defoaming according to production.
Comparative example 5: to 1000L reaction kettle successively put into 550 kilograms of deionized water, octyl phenol polyoxyethylene ether (10, indicate
The degree of polymerization, similarly hereinafter) 110 kilograms, agitator speed is warming up to 50-55 DEG C at 60r/min at this time, stir 15 minutes, make octyl
Phenol polyethenoxy ether (10) all dissolves；Sequentially add 40 kilograms of alcohol ether carboxylate, 20 kilograms of Sodium Polyacrylate and ammonium chloride
It 80 kilograms, stirs 10 minutes, is eventually adding 50 kilograms and 40 kilograms of coconut oil diethanol amide of triethanolamine, stirs 20 minutes.
Product is detected, and is used filter filtering and discharging after detection is qualified, is obtained cleaning agent, can be actually added into defoaming agent according to production and disappear
Bubble.
Comparative example 6: 550 kilograms of deionized water, isomerous tridecanol polyoxyethylene ether (9) are successively put into 1000L reaction kettle
60 kilograms, agitator speed is warming up to 50-55 DEG C at 60r/min at this time, stirs 15 minutes；Sequentially add alcohol ether carboxylate
40 kilograms of salt, 20 kilograms of Sodium Polyacrylate and 80 kilograms of ammonium chloride stir 10 minutes, are eventually adding 50 kilograms of triethanolamine and coconut palm
It 40 kilograms of seed oil diglycollic amide, stirs 20 minutes.Product is detected, and is used filter filtering and discharging after detection is qualified, is obtained
Cleaning agent can be actually added into defoaming agent defoaming according to production.
The cleaning agent paraffin removal power table of table 3 embodiment 1-3 and comparative example 4-6
| Paraffin removal power | |
| Embodiment 1 | 62.89 |
| Embodiment 2 | 61.21 |
| Embodiment 3 | 60.9 |
| Comparative example 4 | 53.21 |
| Comparative example 5 | 40.7 |
| Comparative example 6 | 49.28 |
The content that above-described embodiment illustrates should be understood as that these embodiments are only used for being illustrated more clearly that the present invention, without
For limiting the scope of the invention, after the present invention has been read, those skilled in the art are to various equivalent forms of the invention
Modification each fall within the application range as defined in the appended claims.
Claims (9)
1. being used for the cleaning agent of wire-cloth, which is characterized in that by weight, raw material is by 4-7 parts of alcohol ether carboxylate, different
4-6 parts of structure tridecanol polyoxyethylene ether, 3-5 parts of heterogeneous ten alcohol polyoxyethylene ether, 10-13 parts of octyl phenol polyoxyethylene ether, coconut
Oily diglycollic amide 3-6 parts, 5-9 parts of ammonium chloride, 2-5 parts of triethanolamine, 1-3 parts of Sodium Polyacrylate and 46-68 parts of water compositions.
2. cleaning agent according to claim 1, which is characterized in that by weight, raw material is by alcohol ether carboxylate 5-6
Part, 4.5-5.5 parts of isomerous tridecanol polyoxyethylene ether, 3.5-4.5 parts of heterogeneous ten alcohol polyoxyethylene ether, octyl phenol polyoxyethylene ether
11-12 parts, 3.5-5.5 parts of coconut oil diethanol amide, 6-8 parts of ammonium chloride, 3-4 parts of triethanolamine, Sodium Polyacrylate 1.5-2.5
Part and water 48-65 parts of composition.
3. cleaning agent according to claim 1 or 2, which is characterized in that the polymerization of the isomerous tridecanol polyoxyethylene ether
Degree is 7-10, and the degree of polymerization of heterogeneous ten alcohol polyoxyethylene ether is 5-9, and the degree of polymerization of octyl phenol polyoxyethylene ether is 8-12.
4. cleaning agent according to claim 3, which is characterized in that the degree of polymerization of the isomerous tridecanol polyoxyethylene ether is
9。
5. cleaning agent according to claim 3, which is characterized in that the degree of polymerization of the heterogeneous ten alcohol polyoxyethylene ether is 7.
6. cleaning agent according to claim 3, which is characterized in that the degree of polymerization of the octyl phenol polyoxyethylene ether is 10.
7. the preparation method of cleaning agent as claimed in any one of claims 1 to 6, which is characterized in that by water, octyl phenol polyoxy second
Alkene ether, isomerous tridecanol polyoxyethylene ether and heterogeneous ten alcohol polyoxyethylene ether mixing, are warming up to 50-55 DEG C, stir 10-20min
Afterwards, alcohol ether carboxylate, Sodium Polyacrylate and ammonium chloride are added, continues to stir 5-15min, triethanolamine and coconut is then added
Oily diglycollic amide continues to stir 15-25min, obtains cleaning agent finished product.
8. preparation method according to claim 7, which is characterized in that stirring rate 50-70r/min.
9. preparation method according to claim 7 or 8, which is characterized in that sequentially added into clean reaction kettle from
Sub- water, octyl phenol polyoxyethylene ether, isomerous tridecanol polyoxyethylene ether and heterogeneous ten alcohol polyoxyethylene ether, are warming up to 50-55 DEG C,
Stir 10-20min；Alcohol ether carboxylate, Sodium Polyacrylate and ammonium chloride are sequentially added, 5-15min is stirred, is eventually adding three second
Hydramine and coconut oil diethanol amide stir 15-25min, obtain cleaning agent finished product.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113025436A (en) * | 2021-02-07 | 2021-06-25 | 青州金昊工贸有限公司 | Novel emulsified polyester net cleaning agent |
| CN114933936A (en) * | 2022-06-27 | 2022-08-23 | 陕西师范大学 | Cleaning agent for removing oil stains on surfaces of paper cultural relics and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1313918A (en) * | 1998-07-28 | 2001-09-19 | 纳尔科化学公司 | Method of removing and preventing the buildup of contaminants in papermaking processes |
| CN102851144A (en) * | 2012-09-20 | 2013-01-02 | 长沙艾森设备维护技术有限公司 | Cleaning agent for papermaking felt |
| CN103525165A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Novel detergent for printing ink as well as preparation method thereof |
| CN104419542A (en) * | 2013-08-19 | 2015-03-18 | 天津市浩宇助剂有限公司 | Papermaking blanket cleaning agent |
-
2019
- 2019-08-06 CN CN201910719254.1A patent/CN110437945A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1313918A (en) * | 1998-07-28 | 2001-09-19 | 纳尔科化学公司 | Method of removing and preventing the buildup of contaminants in papermaking processes |
| CN102851144A (en) * | 2012-09-20 | 2013-01-02 | 长沙艾森设备维护技术有限公司 | Cleaning agent for papermaking felt |
| CN104419542A (en) * | 2013-08-19 | 2015-03-18 | 天津市浩宇助剂有限公司 | Papermaking blanket cleaning agent |
| CN103525165A (en) * | 2013-10-23 | 2014-01-22 | 合肥环照高分子材料厂 | Novel detergent for printing ink as well as preparation method thereof |
Non-Patent Citations (5)
| Title |
|---|
| 巢强国: "《日化产品检验技术》", 30 April 2014, 中国质检出版社 * |
| 李东光: "《实用洗涤剂生产技术手册》", 31 July 2001, 化学工业出版社 * |
| 范洪琼等: "《基础化学》", 31 August 2015, 重庆大学出版社 * |
| 钊华: "造纸毛毯及成形网的清洗和维护", 《湖北造纸》 * |
| 陈雪等: "异构醇醚型非离子表面活性剂特性研究", 《"闰土"杯第四届中国纺织印染助剂行业学术年会论文集》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113025436A (en) * | 2021-02-07 | 2021-06-25 | 青州金昊工贸有限公司 | Novel emulsified polyester net cleaning agent |
| CN114933936A (en) * | 2022-06-27 | 2022-08-23 | 陕西师范大学 | Cleaning agent for removing oil stains on surfaces of paper cultural relics and preparation method thereof |
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Application publication date: 20191112 |