CN110436843A - Artificial porous volcanic rock slabstone of one kind and preparation method thereof - Google Patents
Artificial porous volcanic rock slabstone of one kind and preparation method thereof Download PDFInfo
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- CN110436843A CN110436843A CN201910802440.1A CN201910802440A CN110436843A CN 110436843 A CN110436843 A CN 110436843A CN 201910802440 A CN201910802440 A CN 201910802440A CN 110436843 A CN110436843 A CN 110436843A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/04—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by dissolving-out added substances
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2038—Resistance against physical degradation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/54—Substitutes for natural stone, artistic materials or the like
- C04B2111/542—Artificial natural stone
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
The present invention relates to artificial stone's technical fields, disclose artificial porous volcanic rock slabstone of one kind and preparation method thereof, each component including following parts by weight: 600~920 parts of 5~40 μm of average grain diameter of inorganic active powder；Partial size is not more than 900~1200 parts of sand of 4.75mm；36~90 parts of ice cube；14~20 parts of high performance additive；5~10 parts of pigment powder；0.01~0.05 part of retarder；10~20 parts of hydrophober；Water-cement ratio 0.2~0.25.The artificial porous volcanic rock slabstone of the present invention has the characteristics that effect is true to nature, water absorption rate is low, light weight, lovely luster, acid and alkali-resistance, corrosion-resistant, compression strength is greater than 100 megapascal, flexural strength is greater than 14 megapascal, good decorating effect, relative low price, solves the problems, such as that natural volcanic rock stone material mechanical property, endurance quality are bad；Raw material sources are extensively, it can be achieved that industrialized production, high production efficiency, the problem of it is limited to solve natural volcanic rock slabstone resource, higher cost；It can solve the problems, such as that color difference that natural volcanic rock slabstone has and color are not bright-coloured enough, improve the decorative effect of inorganic decorating board.
Description
Technical field
The present invention relates to artificial stone's technical fields, more particularly, to a kind of artificial porous volcanic rock slabstone and its system
Preparation Method.
Background technique
With the development of society, people have increasingly higher demands to the form of building or interior decoration.In metope
Perhaps floor decorative or the interior decoration watched for people are decorated, in order to embody different style, often uses day
Right granite, marble or ceramic tile are decorated.Using natural stone, resource is limited, higher cost, and processing is more difficult.
Therefore, more and more people are decorated using artificial stone, such as the artificial stone that artificial marble, microlite etc. are all types of.
For special porous stone, natural porous stone texture is numerous, different style, thus indoors decoration or other
In the ornament of same type, the use of porous stone is very extensive.But due to there are a large amount of holes so that bulk density it is relatively low,
Intensity decline.Therefore, physical performance index is less than normal marble standard；Due to simultaneously, there is also a large amount of textures, mud
The natural defects such as matter line, shale band, crackle, so that the performance uniformity of this material is very poor, and natural porous stone water absorption rate
Height, bacterium easy to breed goes mouldy, easy to pollute, and not easy cleaning after pollution influences its decorative effect.Such stone material belongs to carbonic acid
The limestone of salt structure, acid resistance is poor, and for the area of this kind of heavy contamination in Asia, acid-rain corrosion can be very serious, Geng Huijia
The destruction of fast stone material, so that the application of natural porous stone material is limited to.Since natural porous stone material is there are a series of defect,
Occurs artificial porous stone on the market, but hole is mostly made using special dies, mold during demoulding, is easy damage
Bad, production cost is higher, and it is not true to nature to imitate natural porous stone effect.
Chinese patent (publication number CN109279835A) discloses a kind of bionical cement and its system with orienting stephanoporate structure
Preparation Method, including slurry preparation, freezing casting, idiosome conserve three steps.The patent is prepared porous using freezing casting technology
Cement, intensity is low, complex process, pore size are not easy to control.Chinese patent (publication number CN103739306A) is open a kind of fixed
To the preparation method of porous special cement, the production of preparation, freezing green body including cement based sizing passes through freeze-drying legal system
Make four steps of maintenance of the porous biscuit of cement base and biscuit.The patent process is more, long flow path, complex process, low efficiency, consumption
Energy is big, is difficult to produce large-sized honeycombed cement.Chinese patent (publication number CN108911626A) discloses a kind of artificial Rome
Hole stone and preparation method thereof, the hole of the patent are realized by mold, higher cost.
For the above status, can develop a kind of with mechanical property is good, endurance quality is good, acid resistance is good, technique is simple
Single, pore size can control, be not required to that the artificial porous volcanic rock slabstone of hole can be realized by mold, widen porous stone material
Application range.
Summary of the invention
In view of this, the present invention is to overcome at least one described in the above-mentioned prior art insufficient, a kind of mechanical property is provided
The artificial porous volcanic rock slabstone good, water absorption rate is low, acid resistance is good, endurance quality is good, natural-like stone effect is true to nature.
In order to solve above-mentioned technical problem, the present invention is adopted the following technical solutions:
A kind of artificial porous volcanic rock slabstone, each component including following parts by weight:
600~920 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 900~1200 parts of sand of 4.75mm；
36~90 parts of ice cube；
14~20 parts of high performance additive；
5~10 parts of pigment powder；
0.01~0.05 part of retarder；
10~20 parts of hydrophober；
Water-cement ratio 0.2~0.25.
The present invention selects common material to prepare artificial porous volcanic rock slabstone, and raw material sources are extensively, it can be achieved that industry
The problem of metaplasia produces, high production efficiency, and it is limited to solve natural volcanic rock slabstone resource, higher cost；Select ice cube as shape
At the medium of hole, different hole can be formed, so that the slabstone being prepared is more nearly natural porous volcano
Rock panel, effect is more true to nature, and water absorption rate is low, light weight, lovely luster, acid and alkali-resistance, corrosion-resistant, compression strength are greater than 100,000,000
The features such as pa, flexural strength are greater than 14 megapascal, good decorating effect, relative low price, solve natural volcanic rock stone material mechanics
The problem that performance is bad, endurance quality is bad.
Preferably, the slabstone includes each component of following parts by weight:
680~840 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 975~1125 parts of sand of 4.75mm；
50~76 parts of ice cube；
16.5~18.5 parts of high performance additive；
6~9 parts of pigment powder；
0.02~0.04 part of retarder；
12.5~17.5 parts of hydrophober；
Water-cement ratio 0.21~0.24.
Most preferably, the slabstone includes each component of following parts by weight:
760 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1050 parts of sand of 4.75mm；
63 parts of ice cube；
17 parts of high performance additive；
7.5 parts of pigment powder；
0.03 part of retarder；
15 parts of hydrophober；
Water-cement ratio 0.225.
It is micro- that the inorganic active powder adds white silicon powder, miberal powder, glass based on 42.5 or more cement of strength grade
One or more of pearl, zeolite powder active powder；The sand is one of quartz sand, river sand, Machine-made Sand or multiple combinations；
The high performance additive is one of polycarboxylate water-reducer, early strength agent, defoaming agent or multiple combinations, rises subtract in the present invention
Few inorganic mixture water consumption, the consistency and early mechanics characteristics for improving artificial porous volcanic rock slabstone；The pigment powder is
The combination of inorganic pigment powder or inorganic pigment powder and organic pigment powder, pigment powder play pigmentation, and color in the present invention
Persistently, not fugitive color；The hydrophober is polysiloxanes or organosilicon, plays waterproof action in the present invention, improves slabstone
Waterproof performance, to improve the endurance quality of slabstone.
The ice cube plays the role of forming hole in the present invention, and ice cube is wrapped up with tinfoil, prevents porous volcanic rock
In hardening process, ice melting water penetrates into porous volcanic rock slabstone plate, to increase the water of porous volcanic rock slabstone
Glue ratio reduces the mechanical property and endurance quality of porous volcanic rock slabstone.
The thickness T of the slabstone1For 12~40mm, the hole in the slabstone be full impregnated hole or blind hole or full impregnated hole with not
The combination of open-work, the stone plate surface hole distributive law are 5~30%.
The partial size T of the ice cube2With thickness of stone slabs T1Unanimously, the hole is full impregnated hole；Or the partial size T of the ice cube2For
5~10mm, the hole are blind hole；Or the partial size T of the ice cube2For (T1- 5mm)~T1, the hole be full impregnated hole with it is impermeable
The combination in hole.
It is another object of the present invention to provide a kind of methods for preparing above-mentioned artificial porous volcanic rock slabstone, including under
State step:
S1. according to the ratio that retarder is soluble in water, obtain retarder aqueous solution；
S2. whole sand and pigment powder are premixed according to the ratio, obtains premix；
S3. it in the premix according to the ratio obtained whole inorganic active powders and hydrophober investment step S2, is uniformly mixing to obtain
Mixture；
S4. the obtained retarder aqueous solution of whole additives and step S1 is added to the mixture that step S3 is obtained according to the ratio
In, whole ice cubes are put into according to the ratio after being sufficiently stirred, are uniformly mixing to obtain inorganic mixture；
S5. the uniform spreading of inorganic mixture step S4 obtained carries out vibration compacting into mold, after first vacuum defoamation and obtains
Prefabricated board；
S6. step S5 is obtained prefabricated board room temperature overlay film carries out two-sided polishing after conserving 12~24 hours, then dry heating curing 30~
Single-sided polishing is carried out after 40 hours, and the slabstone is made.
The present invention first mixes sand and pigment premix with inorganic active powder again, and pigment powder can be made to be more uniformly distributed
In the inorganic mixture being grouped as to each group, guarantee slabstone color uniformity, reduces color difference.
Further, sand and pigment powder premix 2~4 minutes in step S2, are sufficiently mixed pigment powder with sand；In step S3
It is stirred 2~4 minutes after investment inorganic active powder and hydrophober, is sufficiently mixed pigment powder with powder, guarantee that slabstone color is equal
It is even consistent, reduce color difference；It is added after additive and retarder aqueous solution stir in step S4 and adds within 2~3 minutes ice cube and stir 3
~10 seconds.
Further, in step S5, spreading thickness is higher by 2~3mm of mold thickness, and vacuum defoamation and vibration are compressed on vacuum
Vibration carries out in room, and the time of vacuum defoamation is 30~60 seconds, and vacuum pressure is -0.07~-0.1 megapascal；Vibration compacting when
Between be 30~90 seconds, inorganic mixture surface apply pressure be 0.5~0.8 megapascal, vibration frequency be 45~60 hertz, increase people
The consistency of porous volcanic rock slabstone is made, guarantees artificial porous volcanic rock slabstone mechanical property and aesthetic effect.
Further, in step S6, artificial porous volcanic rock slabstone intensity reaches after room temperature overlay film conserves 12~24 hours
40% or more of design strength prevents artificial porous volcanic rock slabstone from crack in two-sided bruting process because intensity is inadequate；
The temperature of dry heating curing is 65~75 DEG C, accelerates the hydration rate of artificial porous volcanic rock slabstone, makes artificial porous volcanic rock
Plate abundant aquation in 30~40 hours, reaches design strength.
The present invention has the advantages that compared with prior art:
1, the artificial porous volcanic rock slabstone of the present invention has that effect is true to nature, water absorption rate is low, light weight, lovely luster, acid and alkali-resistance, resistance to
The features such as burn into compression strength is greater than 100 megapascal, flexural strength is greater than 14 megapascal, good decorating effect, relative low price,
Solve the problems, such as that natural volcanic rock stone material mechanical property is bad, endurance quality is bad；
2, the raw material sources of the artificial porous volcanic rock slabstone of the present invention are extensively, it can be achieved that industrialized production, high production efficiency, solution
The problem of natural volcanic rock slabstone resource of having determined is limited, higher cost；
3, the artificial porous volcanic rock slabstone of the present invention can solve color difference that natural volcanic rock slabstone has and color is not bright-coloured enough
The problem of, improve the decorative effect of inorganic decorating board.
Detailed description of the invention
Fig. 1 is the top view of the artificial porous volcanic rock slabstone of Examples 1 to 5 full impregnated.
Fig. 2 is the side view of the artificial porous volcanic rock slabstone of Examples 1 to 5 full impregnated.
Fig. 3 is the top view of the impermeable artificial porous volcanic rock slabstone of embodiment 6~10.
Fig. 4 is the side view of the impermeable artificial porous volcanic rock slabstone of embodiment 6~10.
Fig. 5 is the top view of the semi-transparent artificial porous volcanic rock slabstone of embodiment 11~15.
Fig. 6 is the side view of the semi-transparent artificial porous volcanic rock slabstone of embodiment 11~15.
Specific embodiment
Attached drawing only for illustration, is not considered as limiting the invention；In order to better illustrate this embodiment, attached
Scheme certain components to have omission, zoom in or out, does not represent the size of actual product；To those skilled in the art,
The omitting of some known structures and their instructions in the attached drawings are understandable；Described in attached drawing positional relationship for being only used for
Exemplary illustration is not considered as limiting the invention.Below by taking 20mm thickness slabstone as an example, in conjunction with specific embodiments to this hair
It is bright to be described in further details.
Embodiment 1
A kind of artificial porous volcanic rock slabstone of full impregnated, the slabstone with a thickness of 20mm, each component including following parts by weight:
600 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 900 parts of sand of 4.75mm；
36 parts of the ice cube of partial size 20mm；
14 parts of high performance additive；
5 parts of pigment powder；
0.01 part of retarder；
10 parts of hydrophober；
Water-cement ratio 0.2.
The inorganic active powder adds white silicon powder based on 42.5 or more cement of strength grade (can add white
One or more of silicon powder, miberal powder, glass microballoon, zeolite powder active powder)；The sand be quartz sand (can be quartz sand,
One of river sand, Machine-made Sand or multiple combinations)；The high performance additive is that polycarboxylate water-reducer (can be polycarboxylic acids to subtract
One of aqua, early strength agent, defoaming agent or multiple combinations)；The pigment powder is that inorganic pigment powder (is also possible to inorganic pigment
The combination of powder and organic pigment powder)；The hydrophober is polysiloxanes (being also possible to organosilicon).
Above-mentioned artificial porous volcanic rock slabstone is made according to the following steps:
S1. according to the ratio that retarder is soluble in water, obtain retarder aqueous solution；
S2. whole sand and pigment powder are premixed 2~4 minutes according to the ratio, obtains premix；
S3. it in the premix according to the ratio obtained whole inorganic active powders and hydrophober investment step S2, stirs 2~4 minutes,
Obtain mixture；
S4. the obtained retarder aqueous solution of whole additives and step S1 is added to the mixture that step S3 is obtained according to the ratio
In, it is sufficiently stirred after 2~3 minutes and according to the ratio puts into whole ice cubes, stir 3~10 seconds, obtain inorganic mixture；
S5. for the uniform spreading of inorganic mixture step S4 obtained into the mold with a thickness of 20mm, spreading thickness is higher by mold
2~3mm of thickness, together with mold immigration vacuum vibration room, the first vacuum defoamation 30 in the case where vacuum pressure is -0.07~-0.1 megapascal~
60 seconds, then apply 0.5~0.8 megapascal of pressure and the vibration compacting 30 under 45~60 hertz of vibration frequency on inorganic mixture surface
~90 seconds, obtain prefabricated board；
S6. the prefabricated board room temperature overlay film that step S5 is obtained carries out two-sided polishing after conserving 12~24 hours, then at 65~75 DEG C
Single-sided polishing is carried out after dry heating curing 30~40 hours, artificial porous volcanic rock slabstone is made.
Embodiment 2
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 1.The artificial porous fire
Mountain rock panel includes each component of following parts by weight:
920 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1200 parts of sand of 4.75mm；
90 parts of the ice cube of partial size 20mm；
20 parts of high performance additive；
10 parts of pigment powder；
0.05 part of retarder；
20 parts of hydrophober；
Water-cement ratio 0.25.
Embodiment 3
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 1.The artificial porous fire
Mountain rock panel includes each component of following parts by weight:
680 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 975 parts of sand of 4.75mm；
50 parts of the ice cube of partial size 20mm；
16.5 parts of high performance additive；
6 parts of pigment powder；
0.02 part of retarder；
12.5 parts of hydrophober；
Water-cement ratio 0.21.
Embodiment 4
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 1.The artificial porous fire
Mountain rock panel includes each component of following parts by weight:
840 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1125 parts of sand of 4.75mm；
76 parts of the ice cube of partial size 20mm；
18.5 parts of high performance additive；
9 parts of pigment powder；
0.04 part of retarder；
17.5 parts of hydrophober；
Water-cement ratio 0.24.
Embodiment 5
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 1.The artificial porous fire
Mountain rock panel includes each component of following parts by weight:
760 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1050 parts of sand of 4.75mm；
63 parts of the ice cube of partial size 20mm；
17 parts of high performance additive；
7.5 parts of pigment powder；
0.03 part of retarder；
15 parts of hydrophober；
Water-cement ratio 0.225.
Comparative example 1
Especially in addition to ice cube 100, other conditions are the same as embodiment 1.
Comparative example 2
Especially in addition to inorganic active powder 1000, other conditions are the same as embodiment 1.
Comparative example 3
Especially in addition to hydrophober 5, other conditions are the same as embodiment 1.
Comparative example 4
Other than not carrying out vacuum defoamation, other conditions are the same as embodiment 1.
Comparative example 5
Other than water-cement ratio 0.3, other conditions are the same as embodiment 1.
Porous volcanic rock slabstone artificial to full impregnated prepared by Examples 1 to 5, comparative example 1~5 be fabricated to standard specimen into
Row performance test, test result are as shown in table 1.
The artificial porous volcanic rock slabstone performance test results of 1 full impregnated of table
From the point of view of table 1,100 parts of 1 ice cube of comparative example is compared with embodiment 1, compressive strength, bending strength, shock resistance, not
Family name's hardness, wear-resisting property decline, anti-pollution characteristic essentially unchangedization, and water absorption rate improves；2 inorganic active powder 1000 of comparative example
Part, with embodiment 1 compare, compressive strength, bending strength, shock resistance, Mohs' hardness, wear-resisting property, anti-pollution characteristic under
Drop, water absorption rate improve；5 parts of 3 hydrophober of comparative example is compared with embodiment 1, compressive strength, bending strength, Mohs' hardness, wear-resisting
Performance slightly reduces, and shock resistance does not change substantially, and anti-pollution characteristic decline, water absorption rate improves；Comparative example 4 does not carry out very
Empty deaeration compares, compressive strength, bending strength, shock resistance, Mohs' hardness, wear-resisting property, anti-pollution characteristic with embodiment 1
Decline, water absorption rate improves；5 water-cement ratio 0.3 of comparative example compares, compressive strength, bending strength, impact resistance with embodiment 1
Energy, Mohs' hardness, wear-resisting property, anti-pollution characteristic decline, and water absorption rate improves.Through a large number of experiments, selected by the present invention
Ice cube, inorganic active powder, hydrophober, water-cement ratio are optimal；The cause of artificial porous volcanic rock slabstone can be improved in vacuum defoamation
Close property, to improve its mechanical property, hardness, anti-pollution characteristic, wear-resisting property.
Embodiment 6
A kind of impermeable artificial porous volcanic rock slabstone, in addition to ice cube partial size is 5~10mm, other conditions are the same as embodiment 1.
Embodiment 7
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 6.The artificial porous fire
Mountain rock panel includes each component of following parts by weight:
920 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1200 parts of sand of 4.75mm；
90 parts of the ice cube of 5~10mm of partial size；
20 parts of high performance additive；
10 parts of pigment powder；
0.05 part of retarder；
20 parts of hydrophober；
Water-cement ratio 0.25.
Embodiment 8
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 6.The artificial porous fire
Mountain rock panel includes each component of following parts by weight:
680 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 975 parts of sand of 4.75mm；
50 parts of the ice cube of 5~10mm of partial size；
16.5 parts of high performance additive；
6 parts of pigment powder；
0.02 part of retarder；
12.5 parts of hydrophober；
Water-cement ratio 0.21.
Embodiment 9
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 6.The artificial porous fire
Mountain rock panel includes each component of following parts by weight:
840 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1125 parts of sand of 4.75mm；
76 parts of the ice cube of 5~10mm of partial size；
18.5 parts of high performance additive；
9 parts of pigment powder；
0.04 part of retarder；
17.5 parts of hydrophober；
Water-cement ratio 0.24.
Embodiment 10
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 6.The artificial porous fire
Mountain rock panel includes each component of following parts by weight:
760 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1050 parts of sand of 4.75mm；
63 parts of the ice cube of 5~10mm of partial size；
17 parts of high performance additive；
7.5 parts of pigment powder；
0.03 part of retarder；
15 parts of hydrophober；
Water-cement ratio 0.225.
Comparative example 6
Especially in addition to ice cube 100, other conditions are the same as embodiment 6.
Comparative example 7
Especially in addition to inorganic active powder 1000, other conditions are the same as embodiment 6.
Comparative example 8
Especially in addition to hydrophober 5, other conditions are the same as embodiment 6.
Comparative example 9
Other than not carrying out vacuum defoamation, other conditions are the same as embodiment 6.
Comparative example 10
Other than water-cement ratio 0.3, other conditions are the same as embodiment 6.
Standard specimen is fabricated to impermeable artificial porous volcanic rock slabstone prepared by embodiment 6~10, comparative example 6~10
It is tested for the property, test result is as shown in table 2.
The impermeable artificial porous volcanic rock slabstone performance test results of table 2
From the point of view of table 2,100 parts of 6 ice cube of comparative example is compared with embodiment 6, compressive strength, bending strength, shock resistance, not
Family name's hardness, wear-resisting property decline, anti-pollution characteristic essentially unchangedization, and water absorption rate improves；7 inorganic active powder 1000 of comparative example
Part, with embodiment 6 compare, compressive strength, bending strength, shock resistance, Mohs' hardness, wear-resisting property, anti-pollution characteristic under
Drop, water absorption rate improve；5 parts of 8 hydrophober of comparative example is compared with embodiment 6, compressive strength, bending strength, Mohs' hardness, wear-resisting
Performance slightly reduces, and shock resistance does not change substantially, and anti-pollution characteristic decline, water absorption rate improves；Comparative example 9 does not carry out very
Empty deaeration compares, compressive strength, bending strength, shock resistance, Mohs' hardness, wear-resisting property, anti-pollution characteristic with embodiment 6
Decline, water absorption rate improves；10 water-cement ratio 0.3 of comparative example compares, compressive strength, bending strength, impact resistance with embodiment 6
Energy, Mohs' hardness, wear-resisting property, anti-pollution characteristic decline, and water absorption rate improves.Through a large number of experiments, selected by the present invention
Ice cube, inorganic active powder, hydrophober, water-cement ratio are optimal；The cause of artificial porous volcanic rock slabstone can be improved in vacuum defoamation
Close property, to improve its mechanical property, hardness, anti-pollution characteristic, wear-resisting property.
Embodiment 11
The combination that a kind of semi-transparent artificial porous volcanic rock slabstone, i.e. its hole are full impregnated hole and blind hole, except ice cube partial size is 15~
Outside 20mm, other conditions are the same as embodiment 1.
Embodiment 12
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 11.It is described artificial porous
Volcanic rock slabstone includes each component of following parts by weight:
920 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1200 parts of sand of 4.75mm；
90 parts of the ice cube of 15~20mm of partial size；
20 parts of high performance additive；
10 parts of pigment powder；
0.05 part of retarder；
20 parts of hydrophober；
Water-cement ratio 0.25.
Embodiment 13
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 11.It is described artificial porous
Volcanic rock slabstone includes each component of following parts by weight:
680 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 975 parts of sand of 4.75mm；
50 parts of the ice cube of 15~20mm of partial size；
16.5 parts of high performance additive；
6 parts of pigment powder；
0.02 part of retarder；
12.5 parts of hydrophober；
Water-cement ratio 0.21.
Embodiment 14
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 11.It is described artificial porous
Volcanic rock slabstone includes each component of following parts by weight:
840 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1125 parts of sand of 4.75mm；
76 parts of the ice cube of 15~20mm of partial size；
18.5 parts of high performance additive；
9 parts of pigment powder；
0.04 part of retarder；
17.5 parts of hydrophober；
Water-cement ratio 0.24.
Embodiment 15
The present embodiment is in addition to the formula of artificial porous volcanic rock slabstone is different, and other conditions are the same as embodiment 11.It is described artificial porous
Volcanic rock slabstone includes each component of following parts by weight:
760 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1050 parts of sand of 4.75mm；
63 parts of the ice cube of 15~20mm of partial size；
17 parts of high performance additive；
7.5 parts of pigment powder；
0.03 part of retarder；
15 parts of hydrophober；
Water-cement ratio 0.225.
Comparative example 11
Especially in addition to ice cube 100, other conditions are the same as embodiment 6.
Comparative example 12
Especially in addition to inorganic active powder 1000, other conditions are the same as embodiment 6.
Comparative example 13
Especially in addition to hydrophober 5, other conditions are the same as embodiment 6.
Comparative example 14
Other than not carrying out vacuum defoamation, other conditions are the same as embodiment 6.
Comparative example 15
Other than water-cement ratio 0.3, other conditions are the same as embodiment 6.
Standard examination is fabricated to semi-transparent artificial porous volcanic rock slabstone prepared by embodiment 11~15, comparative example 11~15
Part is tested for the property, and test result is as shown in table 3.
The semi-transparent artificial porous volcanic rock slabstone performance test results of table 3
From the point of view of table 3,100 parts of 11 ice cube of comparative example, with embodiment 11 compare, compressive strength, bending strength, shock resistance,
Mohs' hardness, wear-resisting property decline, anti-pollution characteristic essentially unchangedization, and water absorption rate improves；12 inorganic active powder of comparative example
It 1000 parts, is compared with embodiment 11, compressive strength, bending strength, shock resistance, Mohs' hardness, wear-resisting property, anti-pollution characteristic
Decline, water absorption rate improves；5 parts of 13 hydrophober of comparative example is compared with embodiment 11, and compressive strength, bending strength, Mohs are hard
Degree, wear-resisting property slightly reduce, and shock resistance does not change substantially, and anti-pollution characteristic decline, water absorption rate improves；Comparative example 14 does not have
Have carry out vacuum defoamation, with embodiment 11 compare, compressive strength, bending strength, shock resistance, Mohs' hardness, wear-resisting property,
Anti-pollution characteristic declines, and water absorption rate improves；15 water-cement ratio 0.3 of comparative example, with embodiment 11 compare, compressive strength, bending strength,
Shock resistance, Mohs' hardness, wear-resisting property, anti-pollution characteristic decline, and water absorption rate improves.By a large number of experiments, in the present invention
Selected ice cube, inorganic active powder, hydrophober, water-cement ratio are optimal；Artificial porous volcanic rock can be improved in vacuum defoamation
The compactness of slabstone, to improve its mechanical property, hardness, anti-pollution characteristic, wear-resisting property.
Obviously, the above embodiment of the present invention be only to clearly illustrate example of the present invention, and not be pair
The restriction of embodiments of the present invention.For those of ordinary skill in the art, may be used also on the basis of the above description
To make other variations or changes in different ways.There is no necessity and possibility to exhaust all the enbodiments.It is all this
Made any modifications, equivalent replacements, and improvements etc., should be included in the claims in the present invention within the spirit and principle of invention
Protection scope within.
Claims (10)
1. a kind of artificial porous volcanic rock slabstone, which is characterized in that each component including following parts by weight:
600~920 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 900~1200 parts of sand of 4.75mm；
36~90 parts of ice cube；
14~20 parts of high performance additive；
5~10 parts of pigment powder；
0.01~0.05 part of retarder；
10~20 parts of hydrophober；
Water-cement ratio 0.2~0.25.
2. artificial porous volcanic rock slabstone according to claim 1, which is characterized in that each group including following parts by weight
Point:
680~840 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 975~1125 parts of sand of 4.75mm；
50~76 parts of ice cube；
16.5~18.5 parts of high performance additive；
6~9 parts of pigment powder；
0.02~0.04 part of retarder；
12.5~17.5 parts of hydrophober；
Water-cement ratio 0.21~0.24.
3. artificial porous volcanic rock slabstone according to claim 2, which is characterized in that each group including following parts by weight
Point:
760 parts of 5~40 μm of average grain diameter of inorganic active powder；
Partial size is not more than 1050 parts of sand of 4.75mm；
63 parts of ice cube；
17 parts of high performance additive；
7.5 parts of pigment powder；
0.03 part of retarder；
15 parts of hydrophober；
Water-cement ratio 0.225.
4. described in any item artificial porous volcanic rock slabstones according to claim 1~3, which is characterized in that the inorganic active
Powder adds one of white silicon powder, miberal powder, glass microballoon, zeolite powder or several based on 42.5 or more cement of strength grade
Kind active powder, the sand are one of quartz sand, river sand, Machine-made Sand or multiple combinations, and the high performance additive is poly-
One of carboxylic acid water reducer, early strength agent, defoaming agent or multiple combinations, the pigment powder are inorganic pigment powder or inorganic pigment powder
With the combination of organic pigment powder, the hydrophober is polysiloxanes or organosilicon.
5. described in any item artificial porous volcanic rock slabstones according to claim 1~3, which is characterized in that the ice cube tin
Paper bag is wrapped up in.
6. described in any item artificial porous volcanic rock slabstones according to claim 1~3, which is characterized in that the thickness of the slabstone
Spend T1For 12~40mm, the hole in the slabstone is the combination in full impregnated hole or blind hole or full impregnated hole and blind hole.
7. artificial porous volcanic rock slabstone according to claim 6, which is characterized in that the partial size T of the ice cube2With slabstone
Thickness T1Unanimously, the hole is full impregnated hole；Or the partial size T of the ice cube2For 5~10mm, the hole is blind hole；Or institute
State the partial size T of ice cube2For (T1- 5mm)~T1, the hole is the combination in full impregnated hole and blind hole.
8. a kind of method for preparing any one of claim 1~7 artificial porous volcanic rock slabstone, which is characterized in that including
Following step:
S1. according to the ratio that retarder is soluble in water, obtain retarder aqueous solution；
S2. whole sand and pigment powder are premixed according to the ratio, obtains premix；
S3. it in the premix according to the ratio obtained whole inorganic active powders and hydrophober investment step S3, is uniformly mixing to obtain
Mixture；
S4. the obtained retarder aqueous solution of whole additives and step S1 is added to the mixture that step S4 is obtained according to the ratio
In, whole ice cubes are put into according to the ratio after being sufficiently stirred, are uniformly mixing to obtain inorganic mixture；
S5. the uniform spreading of inorganic mixture step S4 obtained carries out vibration compacting into mold, after first vacuum defoamation and obtains
Prefabricated board；
S6. step S5 is obtained prefabricated board room temperature overlay film carries out two-sided polishing after conserving 12~24 hours, then dry heating curing 30~
Single-sided polishing is carried out after 40 hours, and the slabstone is made.
9. the preparation method of artificial porous volcanic rock slabstone according to claim 8, which is characterized in that sand and face in step S2
Feed powder premixes 2~4 minutes；It is stirred 2~4 minutes after putting into inorganic active powder and hydrophober in step S3；It is added in step S4
It is stirred after additive and retarder aqueous solution and adds within 2~3 minutes ice cube stirring 3~10 seconds.
10. the preparation method of artificial porous volcanic rock slabstone according to claim 8, which is characterized in that in step S5, very
The time of empty deaeration is 30~60 seconds, and vacuum pressure is -0.07~-0.1 megapascal；The time of vibration compacting is 30~90 seconds, shake
Dynamic frequency is 45~60 hertz.
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