CN110435270A - A kind of light-accumulated luminous film and its manufacturing method - Google Patents

A kind of light-accumulated luminous film and its manufacturing method Download PDF

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Publication number
CN110435270A
CN110435270A CN201910657750.9A CN201910657750A CN110435270A CN 110435270 A CN110435270 A CN 110435270A CN 201910657750 A CN201910657750 A CN 201910657750A CN 110435270 A CN110435270 A CN 110435270A
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CN
China
Prior art keywords
light
layer
luminous
emitting particles
dopp
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910657750.9A
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Chinese (zh)
Inventor
蔡浩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dongguan Anda Rare Earth Luminescent Materials Co Ltd
Original Assignee
Dongguan Anda Rare Earth Luminescent Materials Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dongguan Anda Rare Earth Luminescent Materials Co Ltd filed Critical Dongguan Anda Rare Earth Luminescent Materials Co Ltd
Priority to CN201910657750.9A priority Critical patent/CN110435270A/en
Publication of CN110435270A publication Critical patent/CN110435270A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29DPRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
    • B29D7/00Producing flat articles, e.g. films or sheets
    • B29D7/01Films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B23/00Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
    • B32B23/04Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose comprising such cellulosic plastic substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B23/00Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose
    • B32B23/12Layered products comprising a layer of cellulosic plastic substances, i.e. substances obtained by chemical modification of cellulose, e.g. cellulose ethers, cellulose esters, viscose next to a particulate layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/14Layered products comprising a layer of synthetic resin next to a particulate layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/12Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/06Interconnection of layers permitting easy separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0018Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
    • B29K2995/0035Fluorescent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/416Reflective

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Illuminated Signs And Luminous Advertising (AREA)

Abstract

The invention discloses a kind of light-accumulated luminous film and its manufacturing methods, including substrate, the substrate surface is equipped with light-emitting particles, and light-emitting particles are evenly arranged in substrate surface by adhesive bond and form light-accumulating luminous layer, the another side that the light-accumulating luminous layer is located at light-emitting particles is adhesive with laminating layer by composite layer, the light-emitting particles are clipped in substrate and laminating layer, the substrate, the light-accumulated luminous film layer of light-emitting particles and laminating layer composition layer structure, the light-accumulated luminous film layer is located at the surface coating of laminating layer or prints various colors and figure, form the colored prefabricated membrane that shines, the substrate is by adhesive, luminescent powder and Dopp carrier composition, the adhesive and luminescent powder are placed in Dopp carrier surface, light-accumulated luminous film of the invention shines after caning absorb light source under light illumination, different light sources issues different face The colourama of color, also becomes different colours at a temperature of different, warning effect highly significant improves the safety of trip, it may have beautiful effect.

Description

A kind of light-accumulated luminous film and its manufacturing method
Technical field
The present invention relates to the technical field that light-accumulating luminous film shines, specially a kind of light-accumulated luminous film and its manufacturing method.
Background technique
Light-accumulated luminous film is mainly used for guide plate, direction board, the delineator, protuberant guide post of various highways and railway, traffic, Place name sign, license plate, property plots garage safety sign, construction marker, billboard, scenery, clothing, cap, shoes, vehicle Deng.In the case where night or insufficient light, bright reflecting effect can effectively enhance the recognition capability of people, see mesh clearly Mark, arouses vigilance, to avoid accident, reduces casualties, reduces economic loss, it is indispensable to become road traffic Security guard has apparent social benefit.
But the storing capacity of existing light-accumulated luminous film is weaker, since storing capacity is weaker so that night does not receive for a long time Light irradiation, luminous intensity and time are all shorter, so that the effect reminded is poor, and existing light-accumulated luminous film figure is single, It is easy to appear aestheticly tired, aesthetics is reported to the leadship after accomplishing a task.
Summary of the invention
The purpose of the present invention is to provide a kind of light-accumulated luminous film and its manufacturing methods, existing in above-mentioned background technique to solve The storing capacity for the light-accumulated luminous film having is weaker, since storing capacity is weaker so that night does not receive light irradiation, hair for a long time Luminous intensity and time are all shorter, so that the effect reminded is poor, and existing light-accumulated luminous film figure is single, is easy to appear aesthetic The problem of fatigue, aesthetics is reported to the leadship after accomplishing a task.
To achieve the above object, the invention provides the following technical scheme: a kind of light-accumulated luminous film and its manufacturing method, including Substrate, the substrate surface are equipped with light-emitting particles and light-emitting particles and are evenly arranged in substrate surface shape by adhesive bond At light-accumulating luminous layer, the another side that the light-accumulating luminous layer is located at light-emitting particles is adhesive with laminating layer, the hair by composite layer Light particle is clipped in substrate and laminating layer, the light-accumulated luminous film layer of the substrate, light-emitting particles and laminating layer composition layer structure, The light-accumulated luminous film layer is located at the surface coating of laminating layer or prints various colors and figure, and it is prefabricated to form the colour that shines Film, the substrate are made of adhesive, luminescent powder and Dopp carrier, and the adhesive and luminescent powder are placed in Dopp carrier surface, Release layer and release layer are coated on the Dopp carrier using Dopp film, the bottom surface of the substrate is equipped with cellular anti- Light film.
Preferably, the Dopp film by carboxymethyl cellulose, polypropylene is resistance to, acid polyethylene powder, hydroxypropyl methyl fiber Element, hydroxyethylmethylcellulose, hydroxyethyl ethylenediamine and the aqueous rubber powder distilled water of dispersibility are composed.
Preferably, the light-emitting particles are by resin and zinc sulfide luminescent powder, and rare earth luminous powder makes to be formed, and light-emitting particles By capable of emitting coloured light of processing or colourama, and the glory or temperature that become different colours in the case where having illumination are not With when issue different colours.
Preferably, the composite layer is glued by two liquid type of polyurethane adhesive class and two synthesizing for liquid type of acrylic acid adhesive class Mixture is formed.
Preferably, one layer of glue-line that can turn is applied on the Dopp film, so that light-emitting particles are evenly distributed.
A kind of manufacturing method of light-accumulated luminous film, includes the following steps
S1, material prepare: preparing Dopp carrier, and in Dopp carrier coated thereon release layer;
S2, the light-accumulating luminous layer of production: keep the light-accumulated luminous object of its graininess i.e. light-emitting particles 2 logical by upper a layer of adhesive The method shed is crossed to accomplish to form light-accumulating luminous layer on the release film of Dopp carrier;
S3, the light-accumulated luminous film layer of production: fitting is adhesive with using composite layer on the surface of the light-emitting particles of light-accumulating luminous layer Layer is to form light-accumulated luminous film layer;
S4, the luminous colored prefabricated membrane of production: and then it is located at the surface coating or printing of laminating layer in light-accumulated luminous film layer Various colors and figure, the i.e. luminous and beautiful luminous colored prefabricated membrane of formation, and surface Dopp can print peelable.
The present invention provides a kind of light-accumulated luminous film and its manufacturing method, have it is following the utility model has the advantages that
(1) light-emitting particles by being sticked to the light storage synthesized on substrate and laminating layer hair by the present invention by environmental-protection type adhesive Light film layer, and the light-emitting particles of the light storage are by the capable of emitting multiple colored glories of specially treated.The surface of light-accumulated luminous layer is coated with Or various colors and figure are printed, beautiful light-accumulated luminous layer and picture on surface are formed, light-accumulated luminous film of the invention is in light It shines after absorbable light source under irradiation, different light sources issues the colourama of different colours, also becomes different face at a temperature of different Color, warning effect highly significant, improves the safety of trip, has equally also achieved the effect that beauty.
(2) light-emitting particles of the invention in illumination can extinction, become different colours, and after extinction can fluorescent lifetime it is long, Also variable color when temperature difference, light-accumulated luminous effect is good, and the security warning in night and dark can be improved, increase production Security warning and visual effect of the product to the mankind.
Detailed description of the invention
Fig. 1 is overall structure diagram of the invention.
In figure: 1, substrate;2, light-emitting particles;3, laminating layer;4, shine colored prefabricated membrane;5, reflective membrane.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description.
As shown in Figure 1, the present invention provides a kind of technical solution: a kind of light-accumulated luminous film and its manufacturing method, including substrate 1,1 surface of substrate is equipped with light-emitting particles 2 and light-emitting particles 2 and is evenly arranged in 1 surface shape of substrate by adhesive bond At light-accumulating luminous layer, the another side that the light-accumulating luminous layer is located at light-emitting particles 2 is adhesive with laminating layer 3 by composite layer, described Light-emitting particles 2 are clipped in substrate 1 and laminating layer 3, and the substrate 1, light-emitting particles 2 and laminating layer 3 form the light storage of layer structure Shine film layer, and the light-accumulated luminous film layer is located at the surface coating of laminating layer 3 or prints various colors and figure, is formed and is shone Colored prefabricated membrane 4, the substrate 1 are made of adhesive, luminescent powder and Dopp carrier, and the adhesive and luminescent powder are placed in Dopp Carrier surface is coated with release layer and release layer on the Dopp carrier using Dopp film, and the bottom surface of the substrate 1 is equipped with Cellular reflective membrane 5.
The Dopp film is by carboxymethyl cellulose, polypropylene is resistance to, acid polyethylene powder, hydroxypropyl methyl cellulose, hydroxyl second Ylmethyl cellulose, hydroxyethyl ethylenediamine and the aqueous rubber powder distilled water of dispersibility are composed, and can print peelable;The hair Light particle 2 is made to be formed by resin and zinc sulfide luminescent powder, rare earth luminous powder, and light-emitting particles 2 are by handling capable of emitting true qualities Light or colourama, and become to issue when the glory or temperature difference of different colours in the case where having illumination different Colour increases aesthetics;The composite layer is synthesized by two liquid type of polyurethane adhesive class and two liquid type of acrylic acid adhesive class Adhesive is formed, more environmentally-friendly.
One layer of glue-line that can turn is applied on the Dopp film, so that light-emitting particles 2 are evenly distributed.
It should be noted that a kind of manufacturing method of light-accumulated luminous film, includes the following steps
S1, material prepare: preparing Dopp carrier, and in Dopp carrier coated thereon release layer;
S2, the light-accumulating luminous layer of production: keep the light-accumulated luminous object of its graininess i.e. light-emitting particles 2 logical by upper a layer of adhesive The method shed is crossed to accomplish to form light-accumulating luminous layer on the release film of Dopp carrier;
S3, the light-accumulated luminous film layer of production: fitting is adhesive with using composite layer on the surface of the light-emitting particles 2 of light-accumulating luminous layer Layer 3 is to form light-accumulated luminous film layer;
S4, the luminous colored prefabricated membrane of production: and then it is located at the surface coating or printing of laminating layer 3 in light-accumulated luminous film layer Various colors and figure, the i.e. luminous and beautiful luminous colored prefabricated membrane 5 of formation, and surface Dopp can print peelable.
Light-emitting particles by being sticked to the light storage synthesized on substrate 1 and laminating layer 3 hair by the present invention by environmental-protection type adhesive Light film layer, and the light-emitting particles of the light storage are by the capable of emitting multiple colored glories of specially treated.The surface of light-accumulated luminous layer is coated with Or various colors and figure are printed, beautiful light-accumulated luminous layer and picture on surface are formed, light-accumulated luminous film of the invention is in light It shines after absorbable light source under irradiation, different light sources issues the colourama of different colours, also becomes different face at a temperature of different Color, warning effect highly significant, improves the safety of trip, has equally also achieved the effect that beauty.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

1. a kind of light-accumulated luminous film, including substrate (1), which is characterized in that substrate (1) surface is equipped with light-emitting particles (2), with And light-emitting particles (2) are evenly arranged in substrate (1) surface by adhesive bond and form light-accumulating luminous layer, it is described light-accumulating luminous The another side that layer is located at light-emitting particles (2) is adhesive with laminating layer (3) by composite layer, and the light-emitting particles (2) are clipped in substrate (1) In laminating layer (3), the substrate (1), light-emitting particles (2) and laminating layer (3) form the light-accumulated luminous film layer of layer structure, institute It states light-accumulated luminous film layer to be located at the surface coating of laminating layer (3) or print various colors and figure, it is prefabricated to form the colour that shines Film (4), the substrate (1) are made of adhesive, luminescent powder and Dopp carrier, and the adhesive and luminescent powder are placed in Dopp carrier Surface is coated with release layer and release layer on the Dopp carrier using Dopp film, and the bottom surface of the substrate (1) is equipped with bee The reflective membrane (5) of nest shape.
2. a kind of light-accumulated luminous film according to claim 1, it is characterised in that: the Dopp film by carboxymethyl cellulose, Polypropylene is resistance to, acid polyethylene powder, hydroxypropyl methyl cellulose, hydroxyethylmethylcellulose, hydroxyethyl ethylenediamine and dispersible The aqueous rubber powder distilled water of property is composed.
3. a kind of light-accumulated luminous film according to claim 1, it is characterised in that: the light-emitting particles (2) are by resin and sulphur Change zinc luminescent powder, rare earth luminous powder makes to be formed, and light-emitting particles (2) pass through capable of emitting coloured light of processing or colourama, and Become to issue different colours when the glory or temperature difference of different colours in the case where having illumination.
4. a kind of light-accumulated luminous film according to claim 1, it is characterised in that: the composite layer is by polyurethane adhesive class The composite adhesives of two liquid type of two liquid types and acrylic acid adhesive class are formed.
5. a kind of light-accumulated luminous film according to claim 1, it is characterised in that: apply one layer of glue that can turn on the Dopp film Layer, so that light-emitting particles (2) are evenly distributed.
6. a kind of a kind of manufacturing method of light-accumulated luminous film described in claim 1, it is characterised in that: include the following steps
S1, material prepare: preparing Dopp carrier, and in Dopp carrier coated thereon release layer;
S2, the light-accumulating luminous layer of production: pass through the light-accumulated luminous object of its graininess i.e. light-emitting particles (2) by upper a layer of adhesive The method shed accomplishes to form light-accumulating luminous layer on the release film of Dopp carrier;
S3, the light-accumulated luminous film layer of production: laminating layer is adhesive with using composite layer on the surface of the light-emitting particles (2) of light-accumulating luminous layer (3) to form light-accumulated luminous film layer;
S4, the luminous colored prefabricated membrane of production: and then be located at the surface coating of laminating layer (3) in light-accumulated luminous film layer or print each Kind color and figure, the i.e. luminous and beautiful luminous colour prefabricated membrane (4) of formation, and surface Dopp can print peelable.
CN201910657750.9A 2019-07-20 2019-07-20 A kind of light-accumulated luminous film and its manufacturing method Pending CN110435270A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910657750.9A CN110435270A (en) 2019-07-20 2019-07-20 A kind of light-accumulated luminous film and its manufacturing method

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Application Number Priority Date Filing Date Title
CN201910657750.9A CN110435270A (en) 2019-07-20 2019-07-20 A kind of light-accumulated luminous film and its manufacturing method

Publications (1)

Publication Number Publication Date
CN110435270A true CN110435270A (en) 2019-11-12

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1031606A (en) * 1987-05-15 1989-03-08 明尼苏达州采矿制造公司 Cellular high whiteness encapsulated retroreflective len with flexible frisket
KR20000066844A (en) * 1999-04-21 2000-11-15 김승열 Phosphorescent Safety Sign Board
CN104062698A (en) * 2014-03-20 2014-09-24 台州市万创夜光明工贸有限公司 Production method for high-intensity reflective films
CN104834038A (en) * 2015-05-29 2015-08-12 施盈吉 Reflecting and light emitting film and preparation method and application thereof
CN205071749U (en) * 2015-09-11 2016-03-09 江苏群跃新材料有限公司 Park plant is with luminous membrane of tombarthite
CN106483593A (en) * 2016-10-20 2017-03-08 福建新力元反光材料有限公司 A kind of self luminous reflective membrane and preparation method thereof
CN207663085U (en) * 2017-09-06 2018-07-27 方显峰 A kind of long afterglow Reflex Reflector with excitation light source
CN109212809A (en) * 2017-06-29 2019-01-15 江苏和成显示科技有限公司 A kind of PDLC film and its preparation method and application with noctilucent function

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1031606A (en) * 1987-05-15 1989-03-08 明尼苏达州采矿制造公司 Cellular high whiteness encapsulated retroreflective len with flexible frisket
KR20000066844A (en) * 1999-04-21 2000-11-15 김승열 Phosphorescent Safety Sign Board
CN104062698A (en) * 2014-03-20 2014-09-24 台州市万创夜光明工贸有限公司 Production method for high-intensity reflective films
CN104834038A (en) * 2015-05-29 2015-08-12 施盈吉 Reflecting and light emitting film and preparation method and application thereof
CN205071749U (en) * 2015-09-11 2016-03-09 江苏群跃新材料有限公司 Park plant is with luminous membrane of tombarthite
CN106483593A (en) * 2016-10-20 2017-03-08 福建新力元反光材料有限公司 A kind of self luminous reflective membrane and preparation method thereof
CN109212809A (en) * 2017-06-29 2019-01-15 江苏和成显示科技有限公司 A kind of PDLC film and its preparation method and application with noctilucent function
CN207663085U (en) * 2017-09-06 2018-07-27 方显峰 A kind of long afterglow Reflex Reflector with excitation light source

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Application publication date: 20191112

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