CN104834038A - Reflecting and light emitting film and preparation method and application thereof - Google Patents
Reflecting and light emitting film and preparation method and application thereof Download PDFInfo
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- CN104834038A CN104834038A CN201510288832.2A CN201510288832A CN104834038A CN 104834038 A CN104834038 A CN 104834038A CN 201510288832 A CN201510288832 A CN 201510288832A CN 104834038 A CN104834038 A CN 104834038A
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/08—Mirrors
- G02B5/0816—Multilayer mirrors, i.e. having two or more reflecting layers
- G02B5/085—Multilayer mirrors, i.e. having two or more reflecting layers at least one of the reflecting layers comprising metal
- G02B5/0858—Multilayer mirrors, i.e. having two or more reflecting layers at least one of the reflecting layers comprising metal the reflecting layers comprising a single metallic layer with one or more dielectric layers
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/02—Electroplating of selected surface areas
- C25D5/022—Electroplating of selected surface areas using masking means
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/02—Electroplating of selected surface areas
- C25D5/028—Electroplating of selected surface areas one side electroplating, e.g. substrate conveyed in a bath with inhibited background plating
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D7/00—Electroplating characterised by the article coated
- C25D7/08—Mirrors; Reflectors
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
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- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
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- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Laminated Bodies (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
- Optical Elements Other Than Lenses (AREA)
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Abstract
The invention discloses a reflecting and light emitting film and a preparation method and application thereof. The reflecting and light emitting film comprises a reflection layer and an attaching layer arranged successively, wherein the reflection layer is formed by adhering optical components via an adhesive, and the attaching layer is attached to the surface of a substrate. The optical components can reflect multi-color light after being electroplated; and the attaching layer is coated or printed with light-emitting powder and color or a first pattern to form a light emitting color layer, or the surface of the light emitting layer is coated or printed with the light-emitting powder and color or the first pattern to form the light emitting color layer. The reflecting and light emitting film can both reflect and absorb light during illumination, and can emit light after absorbing light, so that the film can emit light no matter there is illumination or not, the film can reflect multi-color light and generate an image variable effect with change of the illumination distance, brightness and observation angle, both the reflection and light emission effects are good, the prompting effect and safety level are improved, and the anti-counterfeiting and beauty performance are improved.
Description
Technical field
The present invention relates to the technical field of reflective lighting component, more particularly, relate to a kind of reflective luminescent film, preparation method and utilization thereof.
Background technology
Along with the progress in epoch, reflecting object has developed the material of resistance to cleaning, and it is in color and all existing many changes of pattern.General reflecting object is used for the exterior trim of clothing, vest, cap, shoes or vehicle, provides pedestrian and driving person the safety in traffic, or as large-scale advertisement signboard, placard or traffic sign etc., reaches warning or reminding effect by reflecting object.
For example, be 200910225456.7 at application number, name is called in the Chinese invention application of " reflecting object and manufacture method thereof ", it discloses described reflecting object and sequentially comprise following layer structure: a reflector layer being embedded with optical element, one nonferrous layer and a reflection horizon, wherein, optical element is embedded in reflector layer, and form an even curface by reflector layer, and used a small amount of bonding agent and ink can reach smooth layer structure, so this reflecting object can because having thinner nonferrous layer, thus improve printing opacity and the reflecting effect in the reflection horizon of its nexine.But this reflecting object still has the following disadvantages: 1, only just play reflection action when illumination, then inoperative when unglazed photograph, alarming effect is poor; 2, nonferrous layer can hide the reflection ray in reflection horizon, and its reflecting effect still has much room for improvement.
And be 201410261141.9 at application number, name is called in the Chinese invention application of " a kind of reflecting and luminous one PRINTED FABRIC and manufacturing process thereof ", it discloses and be provided with reflector layer successively from top to down on arbitrary surface of fabric body, fluorescence coating, silk-screen/mimeograph layer and bonding design layer, its effect presented under natural light and common fabric (ribbon or cloth etc.) indifference, but after the enough light sources of absorption, move on to dark place, ribbon (cloth) xylopyrography pattern sends voluntarily can visual light source, in addition can reflection source under there is light source irradiation at dark place, make the clear display of xylopyrography pattern, there is noctilucence and reflective effect, but the reflective membrane of this PRINTED FABRIC is made up of transparent reflecting glass Bead and substrate layer, can only reflected white-light light source, can not with lighting angle, the difference of Distance geometry brightness, produce the visual effect becoming figure.
Summary of the invention
The object of the invention is to overcome above-mentioned defect of the prior art, a kind of reflective luminescent film and its preparation method and reflective luminous object are provided, this reflective luminescent film both can reflective and extinction when illumination, again can be luminous thus improve alarming effect and security further after extinction, and reflective luminescent film can reflect colorful light, the color on binding film or the basis of pattern can produce with the difference of luminous range, brightness and observation angle and become figure effect.
For achieving the above object, a first aspect of the present invention provides a kind of reflective luminescent film, comprises the layer structure that next coming in order are arranged: one by the reflector layer of multiple optical element by bonding agent adhesion; One for being attached to the associated layer of surface of bottom material; Described associated layer be coated with or be printed on luminescent powder and color or the first pattern, forming a luminous color layer, or the surface of described reflector layer is coated with or is printed on luminescent powder and color or the first pattern, forms a luminous color layer.
Wherein, described optical element can directly be set to can reflect the optical element of colorful light through electroplating processes in advance, and it can make reflector layer reflect colorful light.As another kind of alternative way, described reflector layer also can be electroplate with the electrodeposited coating for making described optical element reflect colorful light, thus makes reflector layer reflect colorful light.
As preferably, described optical element is set to the reflecting beads be made up of glass, pottery or synthetic resin, and the material of described plating comprises for aluminium, silver, tin, chromium, zinc or its combination.
As preferably, the surface of described reflector layer is provided with strippable release carrier and a release layer, and described release layer is between described release layer carrier and described reflector layer.Wherein, described release carrier is set to PET film, and described release layer is made up of tygon, polypropylene, polybutylene, Polyvinylchloride, polyester or its combination.
As preferably, the polymkeric substance that described associated layer is formed by PU glue, TPU glue, bi-component acrylic, amidocarbonic acid methyl esters, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its combination formed, and the polymkeric substance that described bonding agent is formed by amidocarbonic acid methyl esters, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its combination formed.
As preferably, the surface of described reflector layer is coated with or is printed on the second pattern or color, forms at least one exterior color layer.
A second aspect of the present invention provides a kind of preparation method of reflective luminescent film, comprises the following steps:
(1) prepare a release carrier, described release carrier is provided with release layer;
(2) by bonding agent by advance through electroplating processes and the optical element that can reflect colorful light sticks to the surface of described release layer, form a reflector layer; Or, by bonding agent, optical element is sticked to the surface of described release layer, form a reflector layer, and at the electrodeposited coating of described reflector layer plating for making described optical element reflect colorful light;
(3) can be used in the bottom surface formation one of the bottom surface of described reflector layer or described electrodeposited coating the associated layer being attached to surface of bottom material;
(4) to be coated with on described associated layer or print luminescent powder and color or the first pattern, form a luminous color layer, or be coated with on the surface of the described reflector layer peeling off release carrier and release layer or print luminescent powder and color or the first pattern, form a luminous color layer.
As preferably, also comprise after step (4):
(5) when described associated layer is attached to ground surperficial, described release carrier and release layer are peeled off;
(6) be coated with on the surface of described reflector layer or print the second pattern or color, forming at least one exterior color layer.
A third aspect of the present invention provides a kind of reflective luminous object, comprise object body and the reflective luminescent film as described in technique scheme, described reflective luminescent film can with through weaving, being coated with, print, injection moulding, injection, drip the object body that the mode such as glue makes and connect and compose reflective luminous object.Wherein, described object body comprise the fabric of clothes, case, bag, cap, footwear, socks, umbrella, box, mark, label, paster, adhesive tape, raincoat, advertising signboard, placard, computer panel, TV screen, liquid crystal panel and the said goods, auxiliary material and zero, assembly etc., as the light tiles etc. of computer or television display (panel).Except can making above-mentioned various product, certainly, also can become other and become (business) product and accessory.
Compared with prior art, beneficial effect of the present invention is:
1, the reflector layer of reflective luminescent film of the present invention is embedded with the optical element with reflection action, be coated with in luminous color layer or be printed on luminescent powder and color or the first pattern, under there is light source irradiation at dark place, reflective luminescent film both can reflective and extinction, again can be luminous after extinction, making reflective luminescent film no matter can be luminous when whether there being illumination, improve alarming effect and security.
2, optical element of the present invention can reflect colorful light after electroplating processes, pattern or the color of luminous color layer can be seen before reflective luminescent film is reflective, both colorful light can be reflected during illumination, can produce with the difference of luminous range, brightness and observation angle again and become figure effect, certainly, also can be issued to the colorful reflecting effect of only surplus colorful light at certain lighting angle, its reflecting effect is good, adds false proof and aesthetic property.
3, to be coated with on the outside surface of reflector layer or when being printed on pattern or color, reflective luminescent film can when originally reflective and only surplus colorful light, display is coated with or the pattern of print or color, avoids the dullness sense of only surplus colorful light, increases aesthetics.
Accompanying drawing explanation
In order to be illustrated more clearly in the embodiment of the present invention or technical scheme of the prior art, be briefly described to the accompanying drawing used required in embodiment or description of the prior art below, apparently, accompanying drawing in the following describes is some embodiments of the present invention, for those of ordinary skill in the art, under the prerequisite not paying creative work, other accompanying drawing can also be obtained according to these accompanying drawings.
Fig. 1 is the sectional view of the reflective luminescent film that the embodiment of the present invention one provides;
Fig. 2 is the sectional view of the reflective luminescent film that the embodiment of the present invention two provides;
Fig. 3 is the sectional view of the reflective luminescent film that the embodiment of the present invention three provides;
Fig. 4 is the sectional view of the reflective luminescent film that the embodiment of the present invention four provides;
Fig. 5 is the sectional view of the reflective luminescent film that the embodiment of the present invention five provides.
Embodiment
For making the object of the embodiment of the present invention, technical scheme and advantage clearly, below in conjunction with the accompanying drawing in the embodiment of the present invention, technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Please refer to Fig. 1, embodiments of the invention one provide a kind of reflective luminescent film, and it comprises the layer structure that next coming in order are arranged: one by the reflector layer 2 of multiple optical element 1 by bonding agent adhesion; One for being attached to the associated layer 3 of surface of bottom material; One luminous color layer 4.To be described in detail to each Rotating fields below.
Specifically, described optical element can be set to the reflecting beads that is made up of glass, pottery or synthetic resin.In this enforcement, described optical element 1 is preferably set to reflecting glass Bead, the particle diameter of described reflecting glass Bead with 20 ~ 400 orders, refractive index be more than 1.5 beaded glass better.
In addition, described reflecting glass Bead needs in advance through electroplating processes, then is formed by bonding agent adhesion, and its electroplating metal material can be aluminium, silver, tin, chromium, zinc or its combination (containing compound).Wherein, described reflecting glass Bead needs the effect reaching reflection colorful light after electroplating processes, its objective is to make reflective luminescent film can produce change figure effect with the difference of lighting angle, Distance geometry brightness.
In reflector layer 2, the mode of the coated described optical element 1 of described bonding agent comprises coating, laminating or impression etc.Wherein, an even curface is formed after the adhesion of multiple optical element 1.The polymkeric substance that described bonding agent is formed by amidocarbonic acid methyl esters, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its combination formed.
In associated layer 3, the polymkeric substance that described associated layer 3 is formed by PU glue, TPU glue, bi-component acrylic, amidocarbonic acid methyl esters, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its combination formed.Can certainly be made up of other colloids, non-enforcement is limited.
Be coated with in described associated layer 3 or be printed on luminescent powder and color or the first pattern, thus forming luminous color layer 4.Wherein, the mode that color or pattern are formed at described associated layer 3 comprises computerized print, screen printing, ink-jet, embossing plate or other various mode of printings.Reflective luminescent film of the present invention by associated layer 3 by luminescent powder and color or design transfer to the material surface of any kind.
The preparation method of the reflective luminescent film of the embodiment of the present invention one, comprises the following steps:
(1) prepare a release carrier 5, described release carrier is provided with release layer 8;
(2) by bonding agent by advance through electroplating processes and the optical element 1 that can reflect colorful light sticks to the surface of described release layer 8, form a reflector layer 2;
(3) form one in the bottom surface of described reflector layer 2 and can be used for the associated layer 3 being attached to surface of bottom material;
(4) to be coated with in described associated layer 3 or print luminescent powder and color or the first pattern, to form a luminous color layer 4;
(5) when described associated layer 3 is attached to ground surperficial, described release carrier 5 and release layer 8 are peeled off.
Please refer to Fig. 2, embodiments of the invention two provide another kind of reflective luminescent film, and it comprises the layer structure that next coming in order are arranged: a luminous color layer 4, is by the reflector layer 2 of multiple optical element 1 by bonding agent adhesion; One for being attached to the associated layer 3 of surface of bottom material.The difference of the reflective luminescent film described in the embodiment of the present invention two and the reflective luminescent film described in above-described embodiment one is: be coated with on the surface of described reflector layer or be printed on luminescent powder and color or the first pattern, form described luminous color layer 4, this luminous color layer 4 is positioned at the outermost layer of reflective luminescent film.
Wherein, when being coated with on the surface of reflector layer 2 or being printed on color or the first pattern, reflective luminescent film can when originally reflective and only surplus colorful light, display is coated with or the color of print or the first pattern, avoids the dullness sense of only surplus colorful light, increases aesthetics.
The preparation method of the reflective luminescent film of the embodiment of the present invention two, comprises the following steps:
(1) prepare a release carrier 5, described release carrier is provided with release layer 8;
(2) by bonding agent by advance through electroplating processes and the optical element 1 that can reflect colorful light sticks to the surface of described release layer 8, form a reflector layer 2;
(3) form one in the bottom surface of described reflector layer 2 and can be used for the associated layer 3 being attached to surface of bottom material;
(4) when described associated layer 3 is attached to ground surperficial, described release carrier 5 and release layer 8 are peeled off;
(5) to be coated with on the surface of the described reflector layer 2 peeling off release carrier 5 and release layer 8 or print luminescent powder and color or the first pattern, to form a luminous color layer 4.
Please refer to Fig. 3, embodiments of the invention three provide another kind of reflective luminescent film, and it comprises the layer structure that next coming in order are arranged: a strippable release carrier 5; One release layer 8; One by the reflector layer 2 of multiple optical element 1 by bonding agent adhesion; One for being attached to the associated layer 3 of surface of bottom material; One luminous color layer 4.The difference of the reflective luminescent film described in the embodiment of the present invention three and the reflective luminescent film described in above-described embodiment one is: the surface of described reflector layer 2 is provided with strippable release carrier 5 and a release layer 8, and described release layer 8 is between described release layer carrier 5 and described reflector layer 2.Preferably, described release carrier 5 is set to PET film or other available carriers.Described release layer 8 is made up of tygon, polypropylene, polybutylene, Polyvinylchloride, polyester or its combination
Wherein, described release carrier 5 is equivalent to the base material that optical element 1 lays in manufacturing process, optical element 1 is attached on the release layer 8 of release carrier 5, more further coating adhesive to form smooth reflector layer 2 surface and fixing optical element 1 by this.
The preparation method of the reflective luminescent film of the embodiment of the present invention three, comprises the following steps:
(1) prepare a release carrier 5, described release carrier is provided with release layer 8;
(2) by bonding agent by advance through electroplating processes and the optical element 1 that can reflect colorful light sticks to the surface of described release layer 8, form a reflector layer 2;
(3) form one in the bottom surface of described reflector layer 2 and can be used for the associated layer 3 being attached to surface of bottom material;
(4) to be coated with in described associated layer 3 or print luminescent powder and color or the first pattern, to form a luminous color layer 4.
Please refer to Fig. 4, embodiments of the invention four provide another kind of reflective luminescent film, and it comprises the layer structure that next coming in order are arranged: an exterior color layer 6; One by the reflector layer 2 of multiple optical element 1 by bonding agent adhesion; One for being attached to the associated layer 3 of surface of bottom material; One luminous color layer 4.The difference of the reflective luminescent film described in the embodiment of the present invention four and the reflective luminescent film described in above-described embodiment one is: the surface of described reflector layer 2 is coated with or is printed on the second pattern or color, form exterior color layer 6, this exterior color layer 6 is positioned at the outermost layer of reflective luminescent film.
Wherein, when being again coated with on the surface of reflector layer 2 or being printed on color or pattern, reflective luminescent film can when originally reflective and only surplus colorful light, display is coated with or the color of print or the second pattern, avoids the dullness sense of only surplus colorful light, increases aesthetics.It should be noted that, exterior color layer 6 also can arrange multilayer, and exterior color layer 6 arranges more multilayer, and can protect the color of sublevel or more lower or pattern, the effect reduced wear is better.
The preparation method of the reflective luminescent film of the embodiment of the present invention four, comprises the following steps:
(1) prepare a release carrier 5, described release carrier is provided with release layer 8;
(2) by bonding agent by advance through electroplating processes and the optical element 1 that can reflect colorful light sticks to the surface of described release layer 8, form a reflector layer 2;
(3) form one in the bottom surface of described reflector layer 2 and can be used for the associated layer 3 being attached to surface of bottom material;
(4) to be coated with in described associated layer 3 or print luminescent powder and color or the first pattern, to form a luminous color layer 4;
(5) when described associated layer 3 is attached to ground surperficial, described release carrier 5 and release layer 8 are peeled off;
(6) be coated with on the surface of described reflector layer 2 of peeling off release carrier 5 and release layer 8 or print color or the second pattern, forming at least one exterior color layer 6.
Embodiment five
Please refer to Fig. 5, embodiments of the invention five provide another kind of reflective luminescent film, and it comprises the layer structure that next coming in order are arranged: one by the reflector layer 2 of multiple optical element 1 by bonding agent adhesion; One electrodeposited coating 7 being positioned at reflector layer 2 bottom surface; One for being attached to the associated layer 3 of surface of bottom material; One luminous color layer 4.The difference of the reflective luminescent film described in the embodiment of the present invention five and the reflective luminescent film described in above-described embodiment one is: described optical element 1 does not need in advance through electroplating processes, but after optical element 1 is become reflector layer 2 by bonding agent adhesion, then at the electrodeposited coating 7 of the bottom surface of reflector layer 2 plating for making described optical element reflect colorful light.
The preparation method of the reflective luminescent film of the embodiment of the present invention five, comprises the following steps:
(1) prepare a release carrier 5, described release carrier is provided with release layer 8;
(2) by bonding agent, optical element 1 is sticked to the surface of described release layer 8, form a reflector layer 2, and at the electrodeposited coating 7 of the bottom surface of described reflector layer 2 plating for making described optical element 1 reflect colorful light;
(3) form one in the bottom surface of described electrodeposited coating 7 and can be used for the associated layer 3 being attached to surface of bottom material;
(4) to be coated with on described associated layer 3 or print luminescent powder and color or the first pattern, to form a luminous color layer 4;
(5) when described associated layer 3 is attached to ground surperficial, described release carrier 5 and release layer 8 are peeled off.
Wherein, on the basis of the reflective luminescent film described in the embodiment of the present invention five, described luminous color layer 4 also can change the surface being arranged on described reflector layer 2 into.In addition, the surface of described reflector layer 2 also can be coated with or print the second pattern or color, forms at least one exterior color layer.It should be noted that, adopt different electro-plating methods, the position of electrodeposited coating 7 is also different, and described electrodeposited coating 7 also can be positioned at the end face of reflector layer 2, or is positioned at top, the face, two, the end of reflector layer 2, and non-the present embodiment is limited.
In the prior art, the optical element of reflective luminescent film is generally made up of transparent reflecting glass Bead, or aluminize on beads formed film, its can only under there is light source irradiation at dark place reflected white-light, the pattern on film can be seen before reflective luminescent film is reflective, pattern loss during illumination, but which angle viewing all can only see white light from.
And in an embodiment of the present invention, optical element can reflect colorful light after electroplating processes, the pattern of luminous color layer can be seen before reflective luminescent film is reflective, during illumination, along with the difference of the reflection of colorful light and luminous range, brightness and observation angle, have impact on the visual effect of human body viewing graphic pattern, therefore create change figure effect.Wherein, when under certain observation angle (as front) the colorful reflecting effect of only surplus colorful light can be reached.
In practice, reflective luminescent film of the present invention can with through weaving, being coated with, print, injection moulding, injection, drip the object body that the mode such as glue makes and connect and compose reflective luminous object, make it have colorful reflecting effect, illumination effect and change figure effect.Concrete, wherein, described object body comprise the fabric of clothes, case, bag, cap, footwear, socks, umbrella, box, mark, label, paster, adhesive tape, raincoat, advertising signboard, placard, computer panel, TV screen, liquid crystal panel and the said goods, auxiliary material and zero, assembly etc., as the light tiles etc. of computer or television display (panel).Except can making above-mentioned various product, certainly, also can become other and become (business) product and accessory.
In sum, reflective luminescent film of the present invention both can reflective and extinction when illumination, again can be luminous after extinction, make reflective luminescent film no matter can be luminous when whether there being illumination, thus improve alarming effect and security further, and can become figure effect along with the difference of the reflection of colorful light and luminous range, brightness and observation angle produces during illumination, reflecting effect is good, adds false proof and aesthetic property.
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from Spirit Essence of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.In addition, except the step of above-mentioned various preparation method, to pasting the variation of (glue) order of closing and each layer order and painting in the material of different layers and the change of different order, though the difference of brightness and the difference of pattern vividness may be caused, also in this claim of inventing.
Claims (10)
1. a reflective luminescent film, comprises the layer structure that next coming in order are arranged:
One by the reflector layer of multiple optical element by bonding agent adhesion;
One for being attached to the associated layer of surface of bottom material;
It is characterized in that, described optical element is can reflect the optical element of colorful light through electroplating processes in advance, described associated layer is coated with or is printed on luminescent powder and color or the first pattern, form a luminous color layer, or the surface of described reflector layer is coated with or is printed on luminescent powder and color or the first pattern, forms a luminous color layer;
Or, described reflector layer is electroplate with the electrodeposited coating for making described optical element reflect colorful light, described associated layer is coated with or is printed on luminescent powder and color or the first pattern, form a luminous color layer, or the surface of described reflector layer is coated with or is printed on luminescent powder and color or the first pattern, forms a luminous color layer.
2. reflective luminescent film according to claim 1, is characterized in that, described optical element is set to the reflecting beads be made up of glass, pottery or synthetic resin, and the material of described plating comprises for aluminium, silver, tin, chromium, zinc or its combination.
3. reflective luminescent film according to claim 1, is characterized in that, the surface of described reflector layer is provided with strippable release carrier and a release layer, and described release layer is between described release layer carrier and described reflector layer.
4. reflective luminescent film according to claim 3, is characterized in that, described release carrier is set to PET film, and described release layer is made up of tygon, polypropylene, polybutylene, Polyvinylchloride, polyester or its combination.
5. reflective luminescent film according to claim 1, it is characterized in that, the polymkeric substance that described associated layer is formed by PU glue, TPU glue, bi-component acrylic, amidocarbonic acid methyl esters, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its combination formed, and the polymkeric substance that described bonding agent is formed by amidocarbonic acid methyl esters, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its combination formed.
6. reflective luminescent film according to claim 1, is characterized in that, the surface of described reflector layer is coated with or is printed on the second pattern or color, forms at least one exterior color layer.
7. a preparation method for reflective luminescent film, is characterized in that, the method comprises the following steps:
(1) prepare a release carrier, described release carrier is provided with release layer;
(2) by bonding agent by advance through electroplating processes and the optical element that can reflect colorful light sticks to the surface of described release layer, form a reflector layer; Or, by bonding agent, optical element is sticked to the surface of described release layer, form a reflector layer, and at the electrodeposited coating of described reflector layer plating for making described optical element reflect colorful light;
(3) can be used in the bottom surface formation one of the bottom surface of described reflector layer or described electrodeposited coating the associated layer being attached to surface of bottom material;
(4) to be coated with on described associated layer or print luminescent powder and color or the first pattern, form a luminous color layer, or be coated with on the surface of the described reflector layer peeling off release carrier and release layer or print luminescent powder and color or the first pattern, form a luminous color layer.
8. the preparation method of reflective luminescent film according to claim 7, is characterized in that, also comprises after step (4):
(5) when described associated layer is attached to ground surperficial, described release carrier and release layer are peeled off;
(6) be coated with on the surface of described reflector layer or print the second pattern or color, forming at least one exterior color layer.
9. a reflective luminous object, is characterized in that, comprises object body and as the reflective luminescent film in claim 1 ~ 6 as described in any one, described reflective luminescent film is connected on the ground of described object body.
10. reflective luminous object according to claim 9, it is characterized in that, described object body comprises the light tiles of clothes, case, bag, cap, footwear, socks, umbrella, box, mark, label, paster, adhesive tape, raincoat, advertising signboard, placard, computer panel, TV screen, liquid crystal panel, computer or television display.
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510288832.2A CN104834038B (en) | 2015-05-29 | 2015-05-29 | Reflective luminescent film, preparation method and its utilization |
| RU2017145152A RU2700372C1 (en) | 2015-05-29 | 2015-08-17 | Reflecting luminous film, method for production and application thereof |
| US15/578,220 US20180149780A1 (en) | 2015-05-29 | 2015-08-17 | Reflective light-emitting film, preparation method and use thereof |
| MYPI2017704253A MY196079A (en) | 2015-05-29 | 2015-08-17 | Retroreflective Luminous Film, Preparation Method and use Thereof |
| JP2017557126A JP6830445B2 (en) | 2015-05-29 | 2015-08-17 | Light-reflecting light-emitting film, its manufacturing method and utilization |
| KR1020177032710A KR20170141715A (en) | 2015-05-29 | 2015-08-17 | Light reflecting film, manufacturing method and its operation |
| KR1020187035994A KR20180134433A (en) | 2015-05-29 | 2015-08-17 | Reflective light-emitting film, preparation method and use thereof |
| PCT/CN2015/087231 WO2016192206A1 (en) | 2015-05-29 | 2015-08-17 | Reflective light-emitting film, preparation method and use thereof |
| EP15893862.1A EP3306361A4 (en) | 2015-05-29 | 2015-08-17 | Reflective light-emitting film, preparation method and use thereof |
| TW104214338U TWM520641U (en) | 2015-05-29 | 2015-09-04 | Reflective light emitting film |
| TW104129268A TWI582470B (en) | 2015-05-29 | 2015-09-04 | Preparation of reflective light - emitting film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510288832.2A CN104834038B (en) | 2015-05-29 | 2015-05-29 | Reflective luminescent film, preparation method and its utilization |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104834038A true CN104834038A (en) | 2015-08-12 |
| CN104834038B CN104834038B (en) | 2018-10-02 |
Family
ID=53812033
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510288832.2A Active CN104834038B (en) | 2015-05-29 | 2015-05-29 | Reflective luminescent film, preparation method and its utilization |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20180149780A1 (en) |
| EP (1) | EP3306361A4 (en) |
| JP (1) | JP6830445B2 (en) |
| KR (2) | KR20170141715A (en) |
| CN (1) | CN104834038B (en) |
| MY (1) | MY196079A (en) |
| RU (1) | RU2700372C1 (en) |
| WO (1) | WO2016192206A1 (en) |
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| CN105334559A (en) * | 2015-12-09 | 2016-02-17 | 施盈吉 | High-brightness light-reflecting light-emitting film, making method and article of high-brightness light-reflecting light-emitting film |
| WO2016192206A1 (en) * | 2015-05-29 | 2016-12-08 | 施盈吉 | Reflective light-emitting film, preparation method and use thereof |
| CN107672238A (en) * | 2017-09-13 | 2018-02-09 | 国网山东省电力公司青岛供电公司 | A kind of phase color paster |
| TWI625556B (en) * | 2015-12-09 | 2018-06-01 | Shi ying ji | High-brightness reflective light-emitting film, preparation method and object thereof |
| CN110435270A (en) * | 2019-07-20 | 2019-11-12 | 东莞市安大稀土发光材料有限公司 | A kind of light-accumulated luminous film and its manufacturing method |
| CN111308595A (en) * | 2020-03-12 | 2020-06-19 | 东莞市三人行反光材料有限公司 | Monochromatic magic color light-reflecting bead-planting film |
| CN112406348A (en) * | 2020-11-12 | 2021-02-26 | 东莞市三人行反光材料有限公司 | Luminous transfer printing film |
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| CN109280507A (en) * | 2018-11-21 | 2019-01-29 | 江苏惠聪科技有限公司 | A kind of high reflectivity PVC warning adhesive tape |
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Also Published As
| Publication number | Publication date |
|---|---|
| JP2018517930A (en) | 2018-07-05 |
| WO2016192206A1 (en) | 2016-12-08 |
| KR20180134433A (en) | 2018-12-18 |
| EP3306361A4 (en) | 2019-02-06 |
| EP3306361A1 (en) | 2018-04-11 |
| CN104834038B (en) | 2018-10-02 |
| JP6830445B2 (en) | 2021-02-17 |
| MY196079A (en) | 2023-03-13 |
| RU2700372C1 (en) | 2019-09-16 |
| KR20170141715A (en) | 2017-12-26 |
| US20180149780A1 (en) | 2018-05-31 |
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