CN102096132A - Reflecting object and manufacturing method thereof - Google Patents
Reflecting object and manufacturing method thereof Download PDFInfo
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- CN102096132A CN102096132A CN2009102254567A CN200910225456A CN102096132A CN 102096132 A CN102096132 A CN 102096132A CN 2009102254567 A CN2009102254567 A CN 2009102254567A CN 200910225456 A CN200910225456 A CN 200910225456A CN 102096132 A CN102096132 A CN 102096132A
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- layer
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Abstract
The invention discloses a reflecting object and a manufacturing method thereof. The reflecting object has a laminated structure comprising an adhesive layer into which an optical element is embedded, a colored layer which does not contact the optical element, and a reflecting layer. The invention also relates to the manufacturing method of the reflecting object. The optical element is embedded into the adhesive layer and a smooth surface is formed on the adhesive layer, so that a smooth laminated structure can be formed through a small amount of adhesive and ink. The reflecting object is provided with a thin colored layer, so the reflecting layer in the reflecting object has good light transmitting and reflecting effects, and the reflecting effect of a finished product is better than that of the conventional reflecting object.
Description
Technical field
The present invention system is about a kind of reflective object and manufacture method thereof.
Background technology
Along with the progress in epoch, reflective object has developed the material that anti-cleaning, and it is in color and all existing many variations of pattern; General reflective object is used for the exterior trim of clothing, vest, cap, shoes or vehicle, and pedestrian and driving person are provided the safety in traffic, or as large-scale advertisement signboard, placard or traffic sign etc., reaches caution or reminding effect by reflective object.
In the manufacturing technology of known reflective object, how adhesive phase and nonferrous layer are made simultaneously, meaning promptly, bonding agent and printing ink are pre-mixed, coat together again and form a stratiform structure on the base material, form optical element and reflection horizon more in regular turn, prepared reflective object in such manufacture process, reach the smooth of this layer structure for asking, must use comparatively a large amount of bonding agents and printing ink (mostly to be the spheroid structure to fill and lead up optical element, beaded glass for example) out-of-flatness surface, its printing ink use amount mostly is 30g/m greatly
2More than, under the big situation of this printing ink use amount, hidden the optical element and the reflection horizon of its nexine, make printing opacity and light reflecting effect poor, and lower the reflecting effect of reflective object.
Reflective object also has another kind of known manufacture method, it is for separating manufacturing with adhesive phase and nonferrous layer, at first form an adhesive phase that is embedded with optical element, this bonding agent system is in order to fixing aforementioned optical element, the discharging of this optical element is to expose formula to the open air, meaning promptly only has part to be embedded in the bonding agent, then, form a nonferrous layer with printing ink in another surface of the optical element that is not coated with bonding agent again, in such manufacture method, because of optical element (mostly is the spheroid structure, beaded glass for example) non-with the printing ink surface of contact is the surface that many ball bumps are arranged for the plane, in manufacture process, must use relatively large printing ink, can make nonferrous layer form even and smooth surface, but this mode can hide the reflection horizon of its nexine because of ink usage greatly, make its printing opacity and light reflecting effect poor, and lowered the reflecting effect of reflective object.
Phase of the present invention sees through the manufacture method of adjusting reflective object, in the whole embedding adhesive phase of optical element, and utilize adhesive phase that optical element is filled and led up earlier earlier and form a plane, and make its surperficial nonferrous layer (printing ink) can reach even and smooth layer structure with less use amount, phase can reduce the covering for the reflection horizon, and increases the reflecting effect of reflective object.
Summary of the invention
Because the disappearance of prior art, fundamental purpose of the present invention is providing a kind of reflective object, optical element is embedded in the adhesive phase and do not contact with aforementioned optical element, and because of aforementioned optical element is whole the embedding in the adhesive phase, therefore, adhesive phase is an even curface, thus nonferrous layer can more slim formula in the surface of aforementioned adhesion agent layer, form an even and smooth thin layer, thereby reach better reflecting effect.
Another object of the present invention; a kind of reflective object is being provided; except that the feature of aforementioned reflective object; further comprise a base material (comprising release layer and release layer carrier); remove ground in order to lay as optical element; also can be as the protection that removes of finished product structure (being release base material), top layer without the reflective object of the present invention that uses is protected and keeps original reflective usefulness.
A further object of the present invention, tie up to the manufacture method that a kind of reflective object is provided, see through optical element is embedded in the adhesive phase, and adhesive phase formed a plane, make nonferrous layer promptly can be even curface with less use amount, and minimizing makes finished product that preferable reflecting effect be arranged for the covering in reflection horizon.
Another purpose of the present invention is to provide a kind of reflective object, the reflective object of the present invention is attached on the aforementioned reflective object, and then reaches the application target in each field.
For reaching above-mentioned purpose, the invention provides a kind of reflective object, it comprises following layer structure in regular turn: one is embedded with the adhesive phase of optical element; One nonferrous layer; An and reflection horizon; Aforementioned nonferrous layer does not contact with optical element.
The present invention provides a kind of reflective object in addition, and it comprises following layer structure in regular turn: a base material; One is embedded with the adhesive phase of optical element; One nonferrous layer; An and reflection horizon; Aforementioned nonferrous layer does not contact with aforementioned optical element.
Preferably, aforementioned reflective object can further comprise an associated layer, and it is the surface that is positioned at aforementioned reflection horizon, to be used to be attached at object surfaces.
The present invention provides a kind of manufacture method of reflective object again, and it comprises:
Get a base material;
One optical element is placed the surface of base material;
One bonding agent is coated optical element, and formation one is embedded with the adhesive phase of optical element;
One nonferrous layer is formed at the surface of adhesive phase;
One reflection horizon is formed at the surface of aforementioned nonferrous layer;
Nonferrous layer does not contact with optical element.
The present invention provides a kind of reflective object again, and it comprises the reflective object of the present invention.
Preferably, the material of aforementioned reflective object system comprises cloth, plastics, timber, metal or stone material.
Preferably, preceding method can further be formed at an associated layer surface in aforementioned reflection horizon.Preferably, aforementioned attaching series of strata make up formed polymkeric substance by monomer by: amido methyl formate, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its and are constituted, and are preferably polyurethane (PU glue).
Preferably, aforementioned substrates comprises release layer and release layer carrier, and wherein aforementioned release series of strata are between aforementioned release layer carrier and aforementioned adhesion agent layer.Preferably, aforementioned release series of strata are made of tygon, polypropylene, polybutylene, Polyvinylchloride, polyester or its combination.Preferably, aforementioned release layer carrier is that (poly (ethylene terephthalate) PET) constitutes by polyethylene terephthalate.
Preferably, aforementioned adhesion agent series of strata make up formed polymkeric substance by monomer by: amido methyl formate, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its and are constituted.
Preferably, aforementioned optical element is made of glass, pottery or synthetic resin.
Preferably, aforementioned coloured series of strata are made of polymkeric substance, printing ink or silane coupling agent.
Preferably, aforementioned reflection series of strata are made of metal or pearlescent material.Preferably, aforementioned metal system is made of aluminium, silver, tin or its combination.
Preferably, abovementioned steps (b) the bonding agent mode that coats aforementioned optical element comprises coating, applying, chemical deposition, impression or ink-jet.
As previously mentioned, in manufacture method of the present invention, see through optical element is embedded in the adhesive phase, and adhesive phase formed an even curface, and used a little binder and printing ink can reach smooth layer structure, so reflective object of the present invention can make the reflection horizon of its nexine that preferable printing opacity and reflecting effect be arranged because of having thin nonferrous layer, makes the reflecting effect of finished product better compared to traditional reflective object.
Description of drawings
Fig. 1 shows the layer structure synoptic diagram of the reflective object of the present invention;
Fig. 2 shows that the present invention has the layer structure synoptic diagram of the reflective object of base material;
Fig. 3 shows an enforcement aspect of reflective object of the present invention.
The main element symbol description:
1 adhesive phase
2 optical elements
3 nonferrous layers
4 reflection horizon
5 associated layers
6 base materials
61 release layers
62 release layer carriers
10 reflective objects
11 reflective objects
12 reflective objects
Embodiment
The layer structure of reflective object 10 of the present invention can be joined Fig. 1, and it comprises following layer structure in regular turn: one is embedded with the binder layer 1 of optical element 2; One nonferrous layer 3; An and reflection horizon 4; Described nonferrous layer 3 does not contact with described optical element 2.
The layer structure of another reflective object 11 of the present invention can be joined Fig. 2, and it comprises following layer structure in regular turn: a base material 6; One is embedded with the adhesive phase 1 of optical element 2; One nonferrous layer 3; An and reflection horizon 4; Nonferrous layer 3 does not contact with optical element 2.Base material 6 comprises release layer 61 and release layer carrier 62.
The manufacture method of reflective object 11 of the present invention, prepared finished product can be with reference to figure 2, and this method comprises:
(a) get a base material 6;
(b) optical element 2 is placed the surface of aforementioned substrates 6;
(c) bonding agent 1 is coated aforementioned optical element 2, formation one is embedded with the mixture layer 1 of optical element 2;
(d) nonferrous layer 3 is formed at the surface of adhesive phase 1;
(e) reflection horizon 4 is formed at the surface of aforementioned nonferrous layer 3;
Wherein, aforementioned nonferrous layer 3 does not contact with aforementioned optical element 2.
The reflective object 10 of the present invention or 11 can further comprise an associated layer 5, and manufacture method of the present invention also can further be formed at an associated layer 5 surface in aforementioned reflection horizon 4, this associated layer 5 is in order to aforementioned reflective object 10 or 11 is attached on the object, to reach the usefulness in various fields.Aforementioned associated layer 5 is made of polyurethane (PU glue).
The concrete enforcement of one of reflective object of the present invention aspect can be with reference to figure 3, and it is attached at a vest 12 with reflective object 10 of the present invention, makes this vest have reflecting effect.Reflective object 10 of the present invention or 11 can be pasted to the material surface of any kind of by associated layer 5, and the material of reflective object 12 promptly of the present invention can be, but is not limited to: cloth, plastics, timber, metal or stone material; In preferred embodiment, aforementioned material is a cloth.
In the reflective object 11 of the present invention, aforementioned substrates 6 comprises release layer 61 and release layer carrier 62, and wherein aforementioned release layer 61 is between aforementioned release layer carrier 62 and aforementioned adhesion agent layer 1; Wherein aforementioned substrates 6 is in order to the ground that optical element 2 lays in the manufacturing process being provided, optical element 2 is able to attached on the base material 6, more further coating adhesive to form smooth adhesive phase 1 surface and fixing optical element 2 by this.In the reflective object 11 of the present invention, release layer carrier 62 provides the effect of protection adhesive phase 1 and optical element 2 in addition, makes the surface of finished product not be subjected to external substance and corrodes and wear and tear, and keeps its good reflecting effect; The material of release layer carrier 62 for example but is not limited to: (poly (ethylene terephthalate) PET) constitutes polyethylene terephthalate.Release layer 61 of the present invention is in order to separate the usefulness of release layer carrier 62 and adhesive phase 1, release layer 61 is by for example, but be not limited to: tygon, polypropylene, polybutylene, Polyvinylchloride, polyester or its combination constitute, and in preferred embodiment, it is made of tygon.
Adhesive phase 1 of the present invention is in order to fixing and supporting optical component 2; It can be monomer and makes up formed polymkeric substance by: amido methyl formate, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its and constituted.
Optical element 2 of the present invention is in order to as light refraction, and preferable have a high refractive index transparent spheroid, and for example, but be not limited to: glass, pottery or synthetic resin constitute; In preferred embodiment, it is made of beaded glass; The particle diameter of aforementioned beaded glass is preferably 170～400 orders; And its refractive index is the beaded glass more than 1.925.
The material of nonferrous layer 3 of the present invention can absorb the light of specific wavelength, makes nonferrous layer 3 have solid color or more than one color.The composition material of nonferrous layer for example but is not limited to: polymkeric substance, printing ink or silane coupling agent; In preferred embodiment, it is made of printing ink; And the consumption of nonferrous layer of the present invention is 5～12g/m
2In preferred embodiment, its use amount is 10g/m
2
Incident light can be reflected in reflection horizon 4 of the present invention, and makes it enter optical element again, and it is for example formed, but is not limited to: metal or pearlescent material; Wherein aforementioned metal system is made of aluminium, silver, tin or its combination; In preferred embodiment, it is made of aluminium.
In the manufacture method of the present invention, the mode that step (b) bonding agent coats aforementioned optical element comprises coating, applying, chemical deposition, impression or ink-jet; In preferred embodiment, be to utilize coating method that bonding agent is coated aforementioned optical element.
The present invention is wire mark, ink-jet or embossing plate with the mode that nonferrous layer is formed at the surface of aforementioned adhesion agent layer; In preferred embodiment, it is to utilize ink-jetting style aforementioned nonferrous layer to be formed at the surface of aforementioned adhesion agent.
Embodiment 1: prepare reflective object of the present invention
The green reflective object of present embodiment is obtained through the following step:
(a) get a pet layer;
(b) PEF (PE) layer is attached at the surface of aforementioned pet layer with heating;
(c) a beaded glass cloth is put on the aforementioned PE layer, wherein aforementioned beaded glass particle diameter is 170～230 orders;
(d) bonding agent is coated the PE laminar surface that aforementioned row is equipped with beaded glass, and made binder coat aforementioned beaded glass fully to form a plane;
(e) green ink is formed a nonferrous layer with ink-jetting style on the surface of aforementioned adhesion agent layer, its ink usage is about 10g/m
2And
(f) form layer of aluminum in vacuum aluminum-coated mode in the surface of aforementioned nonferrous layer.
The structure of the prepared reflective object of present embodiment can be with reference to figure 2.Following examples are all used the manufacture method that is same as embodiment 1 and are made, and with the standard value of silver color reflecting properties as silver color, monochrome or colored standard value, to compare.
In the following test, monochromatic (comprising silver color, purple, coffee color, pink and green) reflective object is with 9cm
2(3cmx3cm) test, and the reflective object of polychrome is with 100cm for each area of measuring
2(10cmx10cm) test for each area of measuring.
Embodiment 2: the reflecting properties test of silvery reflection object of the present invention
Present embodiment uses the silvery reflection object to carry out the reflecting properties test, and its preparation method only printing ink is different with the green reflective object of embodiment 1, and other parts are all identical, and the silvery reflection object does not have any printing ink of use and can make.
This test is got above-mentioned silvery reflection object and is done the reflecting properties test, and it is the retroreflecting performance test that sees through Switzerland generic validation group (SGS) (Taiwan is for entrusting Taiwan check scientific ﹠ technical corporation), its result such as following table:
The reflecting properties table with test results of table 1, silvery reflection object of the present invention
By table 1 result as can be known, no matter silvery reflection object of the present invention is 12 ', 20 ', 1 ° or 1 ° 30 ' at observation angle, and angle of incidence of light is when being 5 °, 20 °, 30 ° or 40 °, and it all significantly is higher than standard value, shows that silvery reflection object of the present invention has the reflecting effect of excellence.
Embodiment 3: the reflecting properties test of color reflective object of the present invention
The color reflective object system of present embodiment makes with the manufacture method that is same as embodiment 1, is wherein constituted with colored ink except coloured series of strata, and other manufacture processes are all identical.Get color reflective object of the present invention and do the reflecting properties test, it is the reflecting properties test that sees through Switzerland generic validation group (SGS), its result such as following table:
The reflecting properties table with test results of table 2, color reflective object of the present invention:
By table 2 result as can be known, no matter color reflective object of the present invention is 12 ', 20 ', 1 ° or 1 ° 30 ' at observation angle, and angle of incidence of light is when being 5 °, 20 °, 30 ° or 40 °, and it shows that all apparently higher than the silver color standard value color reflective object of the present invention has good reflecting effect.
Embodiment 4: the reflecting properties test of the monochromatic reflective object of the present invention
The monochromatic reflective object of present embodiment is to make with the manufacture method that is same as embodiment 1, wherein except the printing ink of coloured series of strata with various solid colors, reaches the beaded glass particle diameter and varies in size, and other parts are all identical.Prepared reflective object is done the reflecting properties test; Table 3 is the reflecting properties test of the monochromatic reflective object of beaded glass particle diameter 170～230 purposes, and table 4 is the reflecting properties test of the monochromatic reflective object of beaded glass particle diameter 350～400 purposes; This test system sees through the test that juridical person's vehicle testing research centre (hereinafter to be referred as ARTC) is done, following each table of its result:
The reflecting properties table with test results of table 3, the monochromatic reflective object of the present invention
The reflecting properties table with test results of table 4, the monochromatic reflective object of the present invention
By the result of table 3 and table 4 as can be known, the monochromatic reflective object of the present invention is its beaded glass particle diameter size no matter, at observation angle is 12 ', 20 ', 1 ° or 1 ° 30 ', and angle of incidence of light is when being 5 °, 20 °, 30 ° or 40 °, it shows that all apparently higher than the silver color standard value the monochromatic reflective object of the present invention has good reflecting effect.
Embodiment 5: the reflecting properties test of the monochromatic reflective object of the present invention after different disposal
Present embodiment gets aforementioned green and the silvery reflection object carries out different disposal, tests its reflecting properties again, result such as following table 5, and wherein the standard value look reflective object that mines for silver can reach the minimum standard value of reflective function after various processing:
Table 5, the monochromatic reflective object of the present invention are through various processing back reflection The performance test results tables
By the result of last table 5 as can be known, no matter through abrasion, deflection, cold treatment, temperature variation processings, rainfall processing, washing or dry-cleaning etc., the present invention's reflective object of green and silvery reflection object all can be by the minimum standard values, and reach good reflective function.
In sum, the present invention adjusts manufacture process, optical element is embedded in the adhesive phase, utilize this adhesive phase elder generation optical element to be filled and led up and formed a plane, and make its surperficial nonferrous layer can reach even and smooth layer structure with less use amount, make the reflection horizon of its nexine that preferable printing opacity and reflecting effect be arranged because of nonferrous layer is thin, make the reflecting effect of finished product preferable.In addition, silver color, monochrome or the colored reflective effect test result by aforementioned manufacturing of the present invention learns that the reflective object of the present invention has good reflecting effect in fact.
Other implement aspect
Disclosed in this manual all features all may combine with additive method, disclosed each feature all may optionally be replaced with identical, equal or similar purpose feature in this instructions, therefore, except special notable attribute, the disclosed feature of this all instructionss only is an example in equal or the similar features.
Though the present invention discloses as above with preferred embodiment, so it is not in order to limiting the present invention, anyly is familiar with this skill person, without departing from the spirit and scope of the present invention, and when doing various changes and retouching.
Claims (26)
1. reflective object, it comprises following layer structure in regular turn:
One is embedded with the adhesive phase of optical element;
One nonferrous layer; And
One reflection horizon;
It is characterized in that: described nonferrous layer does not contact with described optical element.
2. reflective object, it comprises following layer structure in regular turn:
One base material;
One is embedded with the adhesive phase of optical element;
One nonferrous layer; And
One reflection horizon;
It is characterized in that: described nonferrous layer does not contact with described optical element.
3. object as claimed in claim 1 or 2 is characterized in that, further comprises an associated layer, and it is positioned at the surface in described reflection horizon, to be used to be attached to object surfaces.
4. object as claimed in claim 3, it is characterized in that described attaching series of strata make up formed polymkeric substance by monomer by: amido methyl formate, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its and constituted.
5. object as claimed in claim 2 is characterized in that, described base material comprises release layer and release layer carrier, and wherein said release series of strata are between described release layer carrier and described adhesive phase.
6. object as claimed in claim 5 is characterized in that, described release series of strata are made of tygon, polypropylene, polybutylene, Polyvinylchloride, polyester or its combination.
7. object as claimed in claim 5 is characterized in that, described release layer carrier is made of polyethylene terephthalate.
8. object as claimed in claim 1 or 2, it is characterized in that described bonding agent series of strata make up formed polymkeric substance by monomer by: amido methyl formate, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its and constituted.
9. object as claimed in claim 1 or 2 is characterized in that, described optical element is made of glass, pottery or synthetic resin.
10. object as claimed in claim 1 or 2 is characterized in that, described coloured series of strata are made of polymkeric substance, printing ink or silane coupling agent.
11. object as claimed in claim 1 or 2 is characterized in that, described reflection series of strata are made of metal or pearlescent material.
12. object as claimed in claim 11 is characterized in that, described metal is made of aluminium, silver, tin or its combination institute.
13. the manufacture method of a reflective object, it comprises:
(a) get a base material;
(b) optical element is placed the surface of described base material;
(c) bonding agent is coated described optical element, formation one is embedded with the adhesive phase of optical element;
(d) nonferrous layer is formed at the surface of described adhesive phase;
(e) reflection horizon is formed at the surface of described nonferrous layer;
It is characterized in that: described nonferrous layer does not contact with described optical element.
14. method as claimed in claim 13 is characterized in that, further an associated layer is formed at the surface in described reflection horizon.
15. method as claimed in claim 14, it is characterized in that described associated layer makes up formed polymkeric substance by monomer by: amido methyl formate, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its and constituted.
16. method as claimed in claim 13 is characterized in that, described base material comprises release layer and release layer carrier, and wherein said release series of strata are between described release layer carrier and described adhesive phase.
17., it is characterized in that described release layer is made of tygon, polypropylene, polybutylene, Polyvinylchloride, polyester or its combination as claim 16 a described method.
18., it is characterized in that described release layer carrier is made of polyethylene terephthalate as claim 16 a described method.
19. method as claimed in claim 13 is characterized in that, the mode that described step (b) bonding agent coats described optical element comprises coating, applying, chemical deposition, impression or ink-jet.
20. method as claimed in claim 13, it is characterized in that described bonding agent series of strata make up formed polymkeric substance by monomer by: amido methyl formate, ester, ether, epoxy, urea, carbonic ester, acrylate, acrylic acid, alkene, vinyl chloride, acid amides, alkyd or its and constituted.
21. method as claimed in claim 13 is characterized in that, described optical element is made of glass, pottery or synthetic resin.
22. method as claimed in claim 13 is characterized in that, described nonferrous layer is made of polymkeric substance, printing ink or silane coupling agent.
23. method as claimed in claim 13 is characterized in that, described reflection horizon is by metal or pearlescent material.
24. method as claimed in claim 13 is characterized in that, described metal is made of aluminium, silver, tin or its combination.
25. a reflective object, it comprises claim 1 or 2 described reflective objects.
26. reflective object as claimed in claim 25 is characterized in that, material comprises cloth, plastics, timber, metal or stone material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102254567A CN102096132A (en) | 2009-12-14 | 2009-12-14 | Reflecting object and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009102254567A CN102096132A (en) | 2009-12-14 | 2009-12-14 | Reflecting object and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102096132A true CN102096132A (en) | 2011-06-15 |
Family
ID=44129300
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009102254567A Pending CN102096132A (en) | 2009-12-14 | 2009-12-14 | Reflecting object and manufacturing method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104834038A (en) * | 2015-05-29 | 2015-08-12 | 施盈吉 | Reflecting and light emitting film and preparation method and application thereof |
| CN104842702A (en) * | 2015-05-29 | 2015-08-19 | 施盈吉 | Stereograph, preparation method and application of stereograph |
| TWI582470B (en) * | 2015-05-29 | 2017-05-11 | ying-ji Shi | Preparation of reflective light - emitting film |
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| US5169707A (en) * | 1991-05-08 | 1992-12-08 | Minnesota Mining And Manufacturing Company | Retroreflective security laminates with dual level verification |
| CN1350649A (en) * | 1999-06-17 | 2002-05-22 | 3M创新有限公司 | Retroreflective article having a colored layer containing a dye covalently bonded to a polymer |
| CN1441727A (en) * | 2000-07-10 | 2003-09-10 | 株式会社资生堂 | Forgery protective material |
| CN1504133A (en) * | 2002-12-04 | 2004-06-16 | Ykk株式会社 | Reflective slide fastener and reflective tape |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5169707A (en) * | 1991-05-08 | 1992-12-08 | Minnesota Mining And Manufacturing Company | Retroreflective security laminates with dual level verification |
| CN1350649A (en) * | 1999-06-17 | 2002-05-22 | 3M创新有限公司 | Retroreflective article having a colored layer containing a dye covalently bonded to a polymer |
| CN1441727A (en) * | 2000-07-10 | 2003-09-10 | 株式会社资生堂 | Forgery protective material |
| CN1504133A (en) * | 2002-12-04 | 2004-06-16 | Ykk株式会社 | Reflective slide fastener and reflective tape |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104834038A (en) * | 2015-05-29 | 2015-08-12 | 施盈吉 | Reflecting and light emitting film and preparation method and application thereof |
| CN104842702A (en) * | 2015-05-29 | 2015-08-19 | 施盈吉 | Stereograph, preparation method and application of stereograph |
| WO2016192207A1 (en) * | 2015-05-29 | 2016-12-08 | 施盈吉 | Stereograph, manufacturing method and use thereof |
| TWI582470B (en) * | 2015-05-29 | 2017-05-11 | ying-ji Shi | Preparation of reflective light - emitting film |
| CN104834038B (en) * | 2015-05-29 | 2018-10-02 | 施盈吉 | Reflective luminescent film, preparation method and its utilization |
| RU2700372C1 (en) * | 2015-05-29 | 2019-09-16 | Ин-Чи ШИХ | Reflecting luminous film, method for production and application thereof |
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Application publication date: 20110615 |