CN110423422A - A kind of synthetic resin watt and its preparation process - Google Patents

A kind of synthetic resin watt and its preparation process Download PDF

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Publication number
CN110423422A
CN110423422A CN201910803439.0A CN201910803439A CN110423422A CN 110423422 A CN110423422 A CN 110423422A CN 201910803439 A CN201910803439 A CN 201910803439A CN 110423422 A CN110423422 A CN 110423422A
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Prior art keywords
parts
agent
synthetic resin
antioxidant
stabilizer
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CN201910803439.0A
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Chinese (zh)
Inventor
戴鹏辉
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Hunan Guhong Machinery Manufacturing Co Ltd
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Hunan Guhong Machinery Manufacturing Co Ltd
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Priority to CN201910803439.0A priority Critical patent/CN110423422A/en
Publication of CN110423422A publication Critical patent/CN110423422A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
    • E04D1/00—Roof covering by making use of tiles, slates, shingles, or other small roofing elements
    • E04D1/02—Grooved or vaulted roofing elements
    • E04D1/08—Grooved or vaulted roofing elements of plastics; of asphalt; of fibrous materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of synthetic resin watt, the raw material including following parts by weight: 40-60 parts of polyvinyl chloride resin, 40-50 parts of Corvic, 15-25 parts of ceramic, 10-12 parts of calcium carbonate, 10-20 parts of haloflex, 4-8 parts of ash wood, 10-20 parts of neoprene, be chopped alkali-free glass fiber 10-20 parts, 8-10 parts of stearic acid, 4-6 parts of solid-filling agent, 2-4 parts of antioxidant, 3-5 parts of dispersing agent, 3-5 parts of stabilizer, 2-4 parts of delustering agent, 2-4 parts of corrosion-resistant agent, 6-10 parts of fire retardant, 1-2 parts of pigment.The synthetic resin watt and its preparation process, the addition of chopped alkali-free glass fiber is so that be capable of forming network skeleton structure in resin tile, improve the service life of resin tile, ceramic can be improved the high temperature resistance of the resin tile, abrasion resistance, after putting into antioxidant, dispersing agent, stabilizer, delustering agent, corrosion-resistant agent, fire retardant again, so that the total quality of resin tile is greatly improved, strength high toughness is good, with corrosion resistant performance, practicability with higher.

Description

A kind of synthetic resin watt and its preparation process
Technical field
The invention belongs to synthetic tile technical fields, and in particular to a kind of synthetic resin watt and its preparation process.
Background technique
Synthetic resin watt is the New Building Materials developed with high-new chemical Chemical Engineering Technology, has light-weight, strong A variety of good characteristics such as big, waterproof and dampproof, antiseptic fire-retardation, sound-insulating and heat-insulating are spent, development zone flat-changed-into-sloping, agricultural trade city are generally applicable to Field, market, residential quarters, new countryside construction resident Deluxe villa, canopy, awning, pseudo-classic architecture etc..
The composition of raw materials that existing synthetic resin watt uses is fairly simple, causes the performance of synthetic resin watt that cannot break through The quality of sexual development, resin tile is general.
Summary of the invention
The object of the present invention is to provide a kind of synthetic resin watt and its preparation processes, to make up the deficiencies in the prior art.
To solve the above problems, the technical solution adopted by the present invention are as follows: a kind of synthetic resin watt, including following parts by weight Raw material: 40-60 parts of polyvinyl chloride resin, 40-50 parts of Corvic, 15-25 parts of ceramic, 10-12 parts of calcium carbonate, chlorination are poly- 10-20 parts of ethylene, 4-8 parts of ash wood, 10-20 parts of neoprene, alkali-free glass fiber 10-20 parts chopped, 8-10 parts of stearic acid, solid are filled out Fill 4-6 parts of agent, 2-4 parts of antioxidant, 3-5 parts of dispersing agent, 3-5 parts of stabilizer, 2-4 parts of delustering agent, 2-4 parts of corrosion-resistant agent, fire-retardant 6-10 parts of agent, 1-2 parts of pigment.
Preferably, the raw material including following parts by weight: 40 parts of polyvinyl chloride resin, 40 parts of Corvic, ceramic 15 Part, 10 parts of calcium carbonate, 10 parts of haloflex, 4 parts of ash wood, 10 parts of neoprene, be chopped 10 parts of alkali-free glass fiber, 8 parts of stearic acid, 4 parts of solid-filling agent, 2 parts of antioxidant, 3 parts of dispersing agent, 3 parts of stabilizer, 2 parts of delustering agent, 2 parts of corrosion-resistant agent, 6 parts of fire retardant, 1 part of pigment.
Preferably, the raw material including following parts by weight: 60 parts of polyvinyl chloride resin, 50 parts of Corvic, ceramic 25 Part, 12 parts of calcium carbonate, 20 parts of haloflex, 8 parts of ash wood, 20 parts of neoprene, be chopped 20 parts of alkali-free glass fiber, stearic acid 10 Part, 6 parts of solid-filling agent, 4 parts of antioxidant, 5 parts of dispersing agent, 5 parts of stabilizer, 4 parts of delustering agent, 4 parts of corrosion-resistant agent, fire retardant 10 Part, 2 parts of pigment.
Preferably, solid-filling agent is combination one such or a variety of in graphite, carbon black and alumina powder.
Preferably, antioxidant be antioxidant 1076, antioxidant SONOX1010, it is one such or a variety of in antioxidant TPP Combination.
Preferably, dispersing agent is hexenyl bis-stearamides.
Preferably, stabilizer is dibasic lead stearate stabilizer, dibasic lead phosphite stabilizer and tribasic sulfuric acid One of lead stabilizer.
Preferably, fire retardant is silicone based flame retardant or organic sebacic acid fire retardant.
A kind of preparation process of synthetic resin watt, comprising the following steps:
S1, it is put into pulverizer after mixing polyvinyl chloride resin, Corvic according to weight fraction ratio and is ground into powder It is granular, obtain material A；
S2, ceramic powder, calcium carbonate, haloflex, ash wood, neoprene, stearic acid are mixed according to weight fraction ratio After be put into flour mill shape of claying into power, obtain material B；
S3, material A obtained in step S1 is mixed with material B obtained in step S2 and is put into high speed mixer and is mixed Material then puts into the alkali-free glass fiber that is chopped, solid-filling agent, antioxidant, dispersing agent, stabilizer, delustering agent, corrosion-resistant agent, fire-retardant Agent, pigment obtain material C after mixing；
S4, material C obtained in step S3 is put into heating container and is heated, stirring drop is taken out after a period of time Temperature；
S5, the material C after cooling down in step S4 is put into extrusion in double screw extruder, is granulated, temperature is maintained at 180-220 DEG C, progress is hot-forming, and the synthetic resin watt is obtained after cooling and demolding.
Preferably, heating temperature is 90-100 DEG C, heating time 6-8min in step S4, and taking-up is cooled to 50-60 DEG C；
Expect that smashed powder material B can cross 200-300 mesh in the Central Plains step S2.
Technical effect and advantage of the invention: the synthetic resin watt and its preparation process, ash wood, calcium carbonate in raw material Cost is relatively low for equal material prices, reduces the manufacturing cost of the synthetic resin watt, while the addition for the alkali-free glass fiber that is chopped is so that tree It is capable of forming network skeleton structure in rouge watt, improves the service life of resin tile, while ceramic can be improved the resin tile High temperature resistance, abrasion resistance, then after putting into antioxidant, dispersing agent, stabilizer, delustering agent, corrosion-resistant agent, fire retardant, make The total quality for obtaining resin tile is greatly improved, and strength high toughness is good, has corrosion resistant performance, with higher practical Property.
Specific embodiment
Technical solution of the present invention is further elaborated below with reference to embodiment:
Embodiment 1
A kind of synthetic resin watt, the raw material including following parts by weight: 40 parts of polyvinyl chloride resin, 40 parts of Corvic, ceramics 15 parts of micro mist, 10 parts of calcium carbonate, 10 parts of haloflex, 4 parts of ash wood, 10 parts of neoprene, 10 parts of the alkali-free glass fiber that is chopped, tristearin It is 8 parts of acid, 4 parts of solid-filling agent, 2 parts of antioxidant, 3 parts of dispersing agent, 3 parts of stabilizer, 2 parts of delustering agent, 2 parts of corrosion-resistant agent, fire-retardant 6 parts of agent, 1 part of pigment.
Specifically, solid-filling agent is combination one such or a variety of in graphite, carbon black and alumina powder.
Specifically, antioxidant is antioxidant 1076, one such or a variety of in antioxidant SONOX1010, antioxidant TPP Combination.
Specifically, dispersing agent is hexenyl bis-stearamides.
Specifically, stabilizer is dibasic lead stearate stabilizer, dibasic lead phosphite stabilizer and tribasic sulfuric acid One of lead stabilizer.
Specifically, fire retardant is silicone based flame retardant or organic sebacic acid fire retardant.
The preparation process of the synthetic resin watt, comprising the following steps:
S1, it is put into pulverizer after mixing polyvinyl chloride resin, Corvic according to weight fraction ratio and is ground into powder It is granular, obtain material A；
S2, ceramic powder, calcium carbonate, haloflex, ash wood, neoprene, stearic acid are mixed according to weight fraction ratio After be put into flour mill shape of claying into power, obtain material B, material B can cross 200-300 mesh；
S3, material A obtained in step S1 is mixed with material B obtained in step S2 and is put into high speed mixer and is mixed Material then puts into the alkali-free glass fiber that is chopped, solid-filling agent, antioxidant, dispersing agent, stabilizer, delustering agent, corrosion-resistant agent, fire-retardant Agent, pigment obtain material C after mixing；
S4, material C obtained in step S3 is put into heating container and is heated, heating temperature is 90-100 DEG C, is added The hot time is 6-8min, and stirring is cooled to 50-60 DEG C after taking-up；
S5, the material C after cooling down in step S4 is put into extrusion in double screw extruder, is granulated, temperature is maintained at 180-220 DEG C, progress is hot-forming, and the synthetic resin watt is obtained after cooling and demolding.
Embodiment 2
A kind of synthetic resin watt, the raw material including following parts by weight:
60 parts of polyvinyl chloride resin, 50 parts of Corvic, 25 parts of ceramic, 12 parts of calcium carbonate, 20 parts of haloflex, 8 parts of ash wood, 20 parts of neoprene, 20 parts of the alkali-free glass fiber that is chopped, 10 parts of stearic acid, 6 parts of solid-filling agent, 4 parts of antioxidant, dispersion 5 parts of agent, 5 parts of stabilizer, 4 parts of delustering agent, 4 parts of corrosion-resistant agent, 10 parts of fire retardant, 2 parts of pigment.
Specifically, solid-filling agent is combination one such or a variety of in graphite, carbon black and alumina powder.
Specifically, antioxidant is antioxidant 1076, one such or a variety of in antioxidant SONOX1010, antioxidant TPP Combination.
Specifically, dispersing agent is hexenyl bis-stearamides.
Specifically, stabilizer is dibasic lead stearate stabilizer, dibasic lead phosphite stabilizer and tribasic sulfuric acid One of lead stabilizer.
Specifically, fire retardant is silicone based flame retardant or organic sebacic acid fire retardant.
The preparation process of the synthetic resin watt, comprising the following steps:
S1, it is put into pulverizer after mixing polyvinyl chloride resin, Corvic according to weight fraction ratio and is ground into powder It is granular, obtain material A；
S2, ceramic powder, calcium carbonate, haloflex, ash wood, neoprene, stearic acid are mixed according to weight fraction ratio After be put into flour mill shape of claying into power, obtain material B, material B can cross 200-300 mesh；
S3, material A obtained in step S1 is mixed with material B obtained in step S2 and is put into high speed mixer and is mixed Material then puts into the alkali-free glass fiber that is chopped, solid-filling agent, antioxidant, dispersing agent, stabilizer, delustering agent, corrosion-resistant agent, fire-retardant Agent, pigment obtain material C after mixing；
S4, material C obtained in step S3 is put into heating container and is heated, heating temperature is 90-100 DEG C, is added The hot time is 6-8min, and stirring is cooled to 50-60 DEG C after taking-up；
S5, the material C after cooling down in step S4 is put into extrusion in double screw extruder, is granulated, temperature is maintained at 180-220 DEG C, progress is hot-forming, and the synthetic resin watt is obtained after cooling and demolding.
Embodiment 3
A kind of synthetic resin watt, the raw material including following parts by weight:
50 parts of polyvinyl chloride resin, 45 parts of Corvic, 20 parts of ceramic, 11 parts of calcium carbonate, 15 parts of haloflex, 6 parts of ash wood, 15 parts of neoprene, 15 parts of the alkali-free glass fiber that is chopped, 9 parts of stearic acid, 5 parts of solid-filling agent, 3 parts of antioxidant, dispersion 4 parts of agent, 4 parts of stabilizer, 3 parts of delustering agent, 3 parts of corrosion-resistant agent, 8 parts of fire retardant, 2 parts of pigment.
Specifically, solid-filling agent is combination one such or a variety of in graphite, carbon black and alumina powder.
Specifically, antioxidant is antioxidant 1076, one such or a variety of in antioxidant SONOX1010, antioxidant TPP Combination.
Specifically, dispersing agent is hexenyl bis-stearamides.
Specifically, stabilizer is dibasic lead stearate stabilizer, dibasic lead phosphite stabilizer and tribasic sulfuric acid One of lead stabilizer.
Specifically, fire retardant is silicone based flame retardant or organic sebacic acid fire retardant.
The preparation process of the synthetic resin watt, comprising the following steps:
S1, it is put into pulverizer after mixing polyvinyl chloride resin, Corvic according to weight fraction ratio and is ground into powder It is granular, obtain material A；
S2, ceramic powder, calcium carbonate, haloflex, ash wood, neoprene, stearic acid are mixed according to weight fraction ratio After be put into flour mill shape of claying into power, obtain material B, material B can cross 200-300 mesh；
S3, material A obtained in step S1 is mixed with material B obtained in step S2 and is put into high speed mixer and is mixed Material then puts into the alkali-free glass fiber that is chopped, solid-filling agent, antioxidant, dispersing agent, stabilizer, delustering agent, corrosion-resistant agent, fire-retardant Agent, pigment obtain material C after mixing；
S4, material C obtained in step S3 is put into heating container and is heated, heating temperature is 90-100 DEG C, is added The hot time is 6-8min, and stirring is cooled to 50-60 DEG C after taking-up；
S5, the material C after cooling down in step S4 is put into extrusion in double screw extruder, is granulated, temperature is maintained at 180-220 DEG C, progress is hot-forming, and the synthetic resin watt is obtained after cooling and demolding.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features, All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (10)

1. a kind of synthetic resin watt, it is characterised in that: the raw material including following parts by weight: 40-60 parts of polyvinyl chloride resin, polyvinyl chloride 40-50 parts of resin, 15-25 parts of ceramic, 10-12 parts of calcium carbonate, 10-20 parts of haloflex, 4-8 parts of ash wood, neoprene 10-20 parts of glue, be chopped alkali-free glass fiber 10-20 parts, 8-10 parts of stearic acid, 4-6 parts of solid-filling agent, 2-4 parts of antioxidant, dispersing agent 3-5 parts, 3-5 parts of stabilizer, 2-4 parts of delustering agent, 2-4 parts of corrosion-resistant agent, 6-10 parts of fire retardant, 1-2 parts of pigment.
2. synthetic resin watt according to claim 1, it is characterised in that: the raw material including following parts by weight: polyvinyl chloride resin 40 Part, 40 parts of Corvic, 15 parts of ceramic, 10 parts of calcium carbonate, 10 parts of haloflex, 4 parts of ash wood, neoprene 10 Part, 8 parts of stearic acid, 4 parts of solid-filling agent, 2 parts of antioxidant, 3 parts of dispersing agent, 3 parts of stabilizer, disappears at 10 parts of the alkali-free glass fiber that is chopped 2 parts of photo etching, 2 parts of corrosion-resistant agent, 6 parts of fire retardant, 1 part of pigment.
3. synthetic resin watt according to claim 1, it is characterised in that: the raw material including following parts by weight: polyvinyl chloride resin 60 Part, 50 parts of Corvic, 25 parts of ceramic, 12 parts of calcium carbonate, 20 parts of haloflex, 8 parts of ash wood, neoprene 20 Part, 10 parts of stearic acid, 6 parts of solid-filling agent, 4 parts of antioxidant, 5 parts of dispersing agent, 5 parts of stabilizer, disappears at 20 parts of the alkali-free glass fiber that is chopped 4 parts of photo etching, 4 parts of corrosion-resistant agent, 10 parts of fire retardant, 2 parts of pigment.
4. synthetic resin watt according to claim 1, it is characterised in that: solid-filling agent is graphite, carbon black and aluminium oxide One such or a variety of combination in powder.
5. synthetic resin watt according to claim 1, it is characterised in that: antioxidant is antioxidant 1076, antioxidant One such or a variety of combination in SONOX1010, antioxidant TPP.
6. synthetic resin watt according to claim 5, it is characterised in that: dispersing agent is hexenyl bis-stearamides.
7. synthetic resin watt according to claim 5, it is characterised in that: stabilizer be dibasic lead stearate stabilizer, One of dibasic lead phosphite stabilizer and lead sulfate tribasic stabilizer.
8. synthetic resin watt according to claim 1, it is characterised in that: fire retardant is silicone based flame retardant or organic certain herbaceous plants with big flowers Diacid fire retardant.
9. a kind of preparation process of synthetic resin watt described in claim 1, it is characterised in that: the following steps are included:
S1, it is put into pulverizer after mixing polyvinyl chloride resin, Corvic according to weight fraction ratio and is ground into powder particle Shape obtains material A；
S2, it is put after mixing ceramic powder, calcium carbonate, haloflex, ash wood, neoprene, stearic acid according to weight fraction ratio Enter shape of claying into power in flour mill, obtains material B；
S3, material A obtained in step S1 is mixed with material B obtained in step S2 and is put into mixing in high speed mixer, Then put into be chopped alkali-free glass fiber, solid-filling agent, antioxidant, dispersing agent, stabilizer, delustering agent, corrosion-resistant agent, fire retardant, Pigment obtains material C after mixing；
S4, material C obtained in step S3 is put into heating container and is heated, stirring cooling is taken out after a period of time；
S5, the material C after cooling down in step S4 is put into extrusion in double screw extruder, is granulated, temperature is maintained at 180-220 DEG C, progress is hot-forming, and the synthetic resin watt is obtained after cooling and demolding.
10. the preparation process of synthetic resin watt according to claim 9, it is characterised in that: heating temperature is in step S4 90-100 DEG C, heating time 6-8min, taking-up is cooled to 50-60 DEG C；
Expect that smashed powder material B can cross 200-300 mesh in the Central Plains step S2.
CN201910803439.0A 2019-08-28 2019-08-28 A kind of synthetic resin watt and its preparation process Withdrawn CN110423422A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112409721A (en) * 2020-10-23 2021-02-26 湖南省建新建材有限公司 Corrosion-resistant resin tile
CN113845782A (en) * 2021-10-25 2021-12-28 怀化市新益全新型环保建材有限公司 Corrosion-resistant ancient-proof tile and manufacturing process thereof
CN113897074A (en) * 2021-10-25 2022-01-07 怀化市新益全新型环保建材有限公司 Formula and manufacturing method of high-surface-brightness ancient tile preventing
CN116199451A (en) * 2023-03-08 2023-06-02 深圳市石能纸业有限公司 Formula of special stone material for pipeline
CN116589804A (en) * 2023-05-19 2023-08-15 贵州电子科技职业学院 Modified synthetic resin tile and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112409721A (en) * 2020-10-23 2021-02-26 湖南省建新建材有限公司 Corrosion-resistant resin tile
CN113845782A (en) * 2021-10-25 2021-12-28 怀化市新益全新型环保建材有限公司 Corrosion-resistant ancient-proof tile and manufacturing process thereof
CN113897074A (en) * 2021-10-25 2022-01-07 怀化市新益全新型环保建材有限公司 Formula and manufacturing method of high-surface-brightness ancient tile preventing
CN116199451A (en) * 2023-03-08 2023-06-02 深圳市石能纸业有限公司 Formula of special stone material for pipeline
CN116589804A (en) * 2023-05-19 2023-08-15 贵州电子科技职业学院 Modified synthetic resin tile and preparation method thereof

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Application publication date: 20191108