CN109206793A - A kind of PVC synthetic resin watt and preparation method thereof - Google Patents
A kind of PVC synthetic resin watt and preparation method thereof Download PDFInfo
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- CN109206793A CN109206793A CN201811190641.2A CN201811190641A CN109206793A CN 109206793 A CN109206793 A CN 109206793A CN 201811190641 A CN201811190641 A CN 201811190641A CN 109206793 A CN109206793 A CN 109206793A
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- synthetic resin
- pvc
- antioxidant
- stabilizer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/14—Solid materials, e.g. powdery or granular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of PVC synthetic resin watt, the raw material including following parts by weight: 50-60 parts of PVC resin powder, acrylate impact hit 30-40 parts of modifying agent, 25-40 parts of flyash, 20-25 parts of polyurethane, calcium carbonate 10-15,7-10 parts of atoleine, 3-5 parts of stabilizer, 4-10 parts of engineering plastics, 6-8 parts of solid-filling agent, 5-12 parts of antioxidant, fire retardant 4-10,3-5 parts of metallic soap, 1-2 parts of pigment.Resin tile of the invention is structurally reasonable, proportion is clear, good heat conductivity, light weight, anti-load-carrying ability are good.
Description
Technical field
The present invention relates to resin tile fields, in particular to a kind of PVC synthetic resin watt and preparation method thereof.
Background technique
For a long time, people mostly concentrate in the understanding to watt material the understanding of roofing, as waterproof, heat preservation,
Heat-insulated roofing, clay shingle are us using one of more, longer roofing of history, and still, such watt of needs disappear
A large amount of clay is consumed, and in order to protect farmland, protect environment, energy saving, China gradually to limit, be even forbidden to use
Clay shingle, ASA&PVC/PMMA/ABS/PETG/pet/PPE/pap vigorously advocate the light environment protection of new generation of country with popularization
Construction material comes into being, and the New Building Materials developed with high-new chemical Chemical Engineering Technology have light-weight, intensity
Greatly, a variety of good characteristics such as waterproof and dampproof, antiseptic fire-retardation, sound-insulating and heat-insulating, be generally applicable to development zone flat-changed-into-sloping, the market of farm produce,
Market, residential quarters, new countryside construction resident Deluxe villa, canopy, awning, pseudo-classic architecture etc., but due in production
Internal additives and lead to situations such as usually will appear fracture during production the reason of material itself in the process, meeting
Cause production product it is unqualified, good can not thus bring economic benefit, and material can be wasted, also can be to user
Bring hidden danger.
Summary of the invention
The technical problem to be solved by the present invention is to, overcome prior art disadvantage, provide it is a kind of it is structurally reasonable, proportion is clear,
The good a kind of PVC synthetic resin watt and preparation method thereof of good heat conductivity, light weight, anti-load-carrying ability.
In order to solve the above technical problems, technical solution provided by the invention are as follows: a kind of PVC synthetic resin watt, including it is following
The raw material of parts by weight: 50-60 parts of PVC resin powder, acrylate impact hit 30-40 parts of modifying agent, 25-40 parts of flyash, poly- ammonia
20-25 parts of ester, calcium carbonate 10-15,7-10 parts of atoleine, 3-5 parts of stabilizer, 4-10 parts of engineering plastics, solid-filling agent 6-8
Part, 5-12 parts of antioxidant, fire retardant 4-10,3-5 parts of metallic soap, 1-2 parts of pigment.
As an improvement, include following parts by weight raw material: 55 parts of PVC resin powder, acrylate impact hit 35 parts of modifying agent,
30 parts of flyash, 23 parts of polyurethane, calcium carbonate 12,7 parts of atoleine, 3 parts of stabilizer, 7 parts of engineering plastics, solid-filling agent 6
Part, 7 parts of antioxidant, fire retardant 6,4 parts of metallic soap, 1 part of pigment.
As an improvement, the stabilizer is dibasic lead phosphite stabilizer, dibasic lead stearate stabilizer and three
One such or a variety of combination in alkali sulfuric acid lead stabilizer.
As an improvement, the solid-filling agent is group one such or a variety of in graphite, carbon black and alumina powder
It closes.
As an improvement, the antioxidant is antioxidant 1076, one such or more in antioxidant 164, antioxidant TPP
The combination of kind.
As an improvement, the fire retardant is antimony oxide, one such or a variety of in chlorinated paraffin, silica
Combination.
As an improvement, the graft copolymer of the engineering plastics, that is, acrylate rubber like body and acrylonitrile, styrene.
A kind of PVC synthetic resin watt and preparation method thereof, it is characterised in that: the following steps are included:
(1) calcium carbonate, solid-filling agent, fire retardant and metallic soap are pressed and is mixed than part, be sent into pulverizer and crush, cross 150-
200 mesh obtain powder particle a.
(2) by powder particle a, PVC resin powder, flyash, stabilizer, polyurethane, calcium carbonate, atoleine, acrylic acid
Ester anti-impact modifier, antioxidant, pigment are put into batch mixer in order stirs 8-15min, obtains mixture b.
(3) by mixture b in 100-120 DEG C of container, 10- in 100 DEG C of thermostatic chambers is placed on after heating 15-22min
15min。
(4) natural cooling is cooled to 60-65 DEG C in stirring after taking out the material in thermostatic chamber.
(5) material after cooling is put into injection molding machine, 200-220 DEG C at a temperature of be molded, in the mistake of injection molding
Engineering plastics are added in journey, place into die mould on tile-type mold, cooling and solidifying obtains the resin tile.
The present invention has the advantage that
The proportion of material is very clear, and the Costco Wholesale of a variety of materials such as flyash, calcium carbonate being added is not high,
It not will cause too big financial burden, for materials such as solid-filling agent, stabilizers, can greatly improve the matter of resin tile
Amount, waterproofness, impact resistance and quality of materials very light, heating conduction, anti-load-carrying ability are all very good, pass through
Polyurethane and fire retardant is added, the mechanical strength, oxidation stability and fire resistance of resin tile are improved, to improve resin
Watt heat resistance, enhance heat insulation, avoid existing security risk when building uses, the pigment in addition added can be with
The color for arbitrarily adjusting resin tile as needed, meets consumer demand.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments.
Embodiment 1
A kind of PVC synthetic resin watt, the raw material including following parts by weight: 55 parts of PVC resin powder, acrylate impact click to change
35 parts of agent of property, 30 parts of flyash, 23 parts of polyurethane, calcium carbonate 12,7 parts of atoleine, 3 parts of dibasic lead phosphite stabilizer,
7 parts of engineering plastics, 6 parts of graphite, 7 parts of antioxidant 1076,6 parts of antimony oxide, 4 parts of metallic soap, 1 part of pigment.
Above-mentioned a kind of PVC synthetic resin watt and preparation method thereof, it is characterised in that: the following steps are included:
(1) calcium carbonate, graphite, antimony oxide and metallic soap are pressed and is mixed than part, be sent into pulverizer and crush, cross 160 mesh
Obtain powder particle a.
(2) by powder particle a, PVC resin powder, flyash, dibasic lead phosphite stabilizer, polyurethane, atoleine,
Acrylate impact, which hits modifying agent, antioxidant 1076, pigment and is put into batch mixer in order, stirs 11min, obtains mixture b.
(3) by mixture b in 110 DEG C of containers, 12min in 100 DEG C of thermostatic chambers is placed on after heating 18min.
(4) natural cooling is cooled to 62 DEG C in stirring after taking out the material in thermostatic chamber.
(5) material after cooling is put into injection molding machine, 210 DEG C at a temperature of be molded, during injection molding
Engineering plastics are added, place into die mould on tile-type mold, cooling and solidifying obtains the resin tile.
Embodiment 2
A kind of PVC synthetic resin watt, the raw material including following parts by weight: 58 parts of PVC resin powder, acrylate impact click to change
37 parts of agent of property, 35 parts of flyash, 23 parts of polyurethane, calcium carbonate 13,9 parts of atoleine, 5 parts of dibasic lead stearate stabilizer,
8 parts of engineering plastics, 4 parts of graphite, 3 parts of carbon black, 10 parts of antioxidant TPP, 5 parts of chlorinated paraffin, 4 parts of silica, 4 parts of metallic soap,
1.5 parts of pigment.
Above-mentioned a kind of PVC synthetic resin watt and preparation method thereof, it is characterised in that: the following steps are included:
(1) calcium carbonate, graphite, carbon black, chlorinated paraffin, silica and metallic soap are pressed and is mixed than part, be sent into pulverizer
It crushes, crosses 160 mesh and obtain powder particle a.
(2) by powder particle a, PVC resin powder, flyash, dibasic lead stearate stabilizer, polyurethane, atoleine,
Acrylate impact hits modifying agent, antioxidant TPP, pigment and is put into batch mixer stirs 14min in order, obtains mixture b.
(3) by mixture b in 120 DEG C of containers, 15min in 100 DEG C of thermostatic chambers is placed on after heating 20min.
(4) natural cooling is cooled to 65 DEG C in stirring after taking out the material in thermostatic chamber.
(5) material after cooling is put into injection molding machine, 220 DEG C at a temperature of be molded, during injection molding
Engineering plastics are added, place into die mould on tile-type mold, cooling and solidifying obtains the resin tile.
Embodiment 3
A kind of PVC synthetic resin watt, the raw material including following parts by weight: 52 parts of PVC resin powder, acrylate impact click to change
33 parts of agent of property, 29 parts of flyash, 21 parts of polyurethane, calcium carbonate 10,7 parts of atoleine, 5 parts of dibasic lead stearate stabilizer,
7 parts of engineering plastics, 6 parts of alumina powder, 8 parts of antioxidant TPP, 8 parts of silica, 4 parts of metallic soap, 1 part of pigment.
Above-mentioned a kind of PVC synthetic resin watt and preparation method thereof, it is characterised in that: the following steps are included:
(1) calcium carbonate, alumina powder, silica and metallic soap are pressed and is mixed than part, be sent into pulverizer and crush, cross 160
Mesh obtains powder particle a.
(2) by powder particle a, PVC resin powder, flyash, dibasic lead stearate stabilizer, polyurethane, atoleine,
Acrylate impact hits modifying agent, antioxidant TPP, pigment and is put into batch mixer stirs 10min in order, obtains mixture b.
(3) by mixture b in 105 DEG C of containers, 11min in 100 DEG C of thermostatic chambers is placed on after heating 16min.
(4) natural cooling is cooled to 60 DEG C in stirring after taking out the material in thermostatic chamber.
(5) material after cooling is put into injection molding machine, 208 DEG C at a temperature of be molded, during injection molding
Engineering plastics are added, place into die mould on tile-type mold, cooling and solidifying obtains the resin tile.
Claims (8)
1. a kind of PVC synthetic resin watt, it is characterised in that: the raw material including following parts by weight: 50-60 parts of PVC resin powder, propylene
30-40 parts of acid esters anti-impact modifier, 25-40 parts of flyash, 20-25 parts of polyurethane, calcium carbonate 10-15, atoleine 7-10
Part, 3-5 parts of stabilizer, 4-10 parts of engineering plastics, 6-8 parts of solid-filling agent, 5-12 parts of antioxidant, fire retardant 4-10, metallic soap
3-5 parts, 1-2 parts of pigment.
2. a kind of PVC synthetic resin watt according to claim 1, it is characterised in that: the raw material including following parts by weight:
55 parts of PVC resin powder, acrylate impact hit 35 parts of modifying agent, 30 parts of flyash, 23 parts of polyurethane, calcium carbonate 12, liquid stone
7 parts of wax, 3 parts of stabilizer, 7 parts of engineering plastics, 6 parts of solid-filling agent, 7 parts of antioxidant, fire retardant 6,4 parts of metallic soap, pigment 1
Part.
3. a kind of PVC synthetic resin watt according to claim 1, it is characterised in that: the stabilizer is that dibasic is sub-
One such or a variety of group in phosphoric acid lead stabilizer, dibasic lead stearate stabilizer and lead sulfate tribasic stabilizer
It closes.
4. a kind of PVC synthetic resin watt according to claim 1, it is characterised in that: the solid-filling agent be graphite,
One such or a variety of combination in carbon black and alumina powder.
5. a kind of PVC synthetic resin watt according to claim 1, it is characterised in that: the antioxidant is antioxidant
1076, antioxidant 164, combination one such or a variety of in antioxidant TPP.
6. a kind of PVC synthetic resin watt according to claim 1, it is characterised in that: the fire retardant is three oxidations two
Antimony, chlorinated paraffin, combination one such or a variety of in silica.
7. a kind of PVC synthetic resin watt according to claim 1, it is characterised in that: the engineering plastics, that is, acrylate
The graft copolymer of rubber like body and acrylonitrile, styrene.
8. a kind of PVC synthetic resin watt described in any one of -7 and preparation method thereof according to claim 1, it is characterised in that:
The following steps are included:
(1) calcium carbonate, solid-filling agent, fire retardant and metallic soap are pressed and is mixed than part, be sent into pulverizer and crush, cross 150-200
Mesh obtains powder particle a.
(2) powder particle a, PVC resin powder, flyash, stabilizer, polyurethane, calcium carbonate, atoleine, acrylate are resisted
Impact modifying agent, antioxidant, pigment are put into batch mixer in order stirs 8-15min, obtains mixture b.
(3) by mixture b in 100-120 DEG C of container, 10-15min in 100 DEG C of thermostatic chambers is placed on after heating 15-22min.
(4) natural cooling is cooled to 60-65 DEG C in stirring after taking out the material in thermostatic chamber.
(5) material after cooling is put into injection molding machine, 200-220 DEG C at a temperature of be molded, during injection molding
Engineering plastics are added, place into die mould on tile-type mold, cooling and solidifying obtains the resin tile.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811190641.2A CN109206793A (en) | 2018-10-12 | 2018-10-12 | A kind of PVC synthetic resin watt and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811190641.2A CN109206793A (en) | 2018-10-12 | 2018-10-12 | A kind of PVC synthetic resin watt and preparation method thereof |
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| CN109206793A true CN109206793A (en) | 2019-01-15 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109735092A (en) * | 2018-12-27 | 2019-05-10 | 耿佃勇 | Resin tile novel resin material and preparation method thereof |
| CN110938266A (en) * | 2019-12-24 | 2020-03-31 | 龙吉松 | Preparation method of PVC composite material |
| CN114230938A (en) * | 2021-11-12 | 2022-03-25 | 西安拓建仿古材料有限公司 | Corrosion-resistant flame-retardant polymer antique eave sealing plate and processing method thereof |
| WO2023000317A1 (en) * | 2021-07-23 | 2023-01-26 | 宁波先锋新材料股份有限公司 | Novel polyvinyl chloride plastic alloy tile and preparation method therefor |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62225546A (en) * | 1986-03-28 | 1987-10-03 | Dainippon Ink & Chem Inc | Vinyl chloride resin composition for vinyl tile |
| JPS6485244A (en) * | 1987-09-25 | 1989-03-30 | Dainippon Ink & Chemicals | Resin composition for polyvinyl chloride tile |
| CN103965567A (en) * | 2014-05-04 | 2014-08-06 | 安徽正隆新材料有限公司 | PVC (Polyvinyl Chloride) synthetic resin tile |
| CN104231501A (en) * | 2014-09-30 | 2014-12-24 | 句容金猴机械研究所有限公司 | Synthesized resin tile and preparing method thereof |
| CN108314861A (en) * | 2018-02-08 | 2018-07-24 | 佛山市高筑瓦业有限公司 | A kind of PVC thermal insulation tiles and preparation method thereof |
-
2018
- 2018-10-12 CN CN201811190641.2A patent/CN109206793A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62225546A (en) * | 1986-03-28 | 1987-10-03 | Dainippon Ink & Chem Inc | Vinyl chloride resin composition for vinyl tile |
| JPS6485244A (en) * | 1987-09-25 | 1989-03-30 | Dainippon Ink & Chemicals | Resin composition for polyvinyl chloride tile |
| CN103965567A (en) * | 2014-05-04 | 2014-08-06 | 安徽正隆新材料有限公司 | PVC (Polyvinyl Chloride) synthetic resin tile |
| CN104231501A (en) * | 2014-09-30 | 2014-12-24 | 句容金猴机械研究所有限公司 | Synthesized resin tile and preparing method thereof |
| CN108314861A (en) * | 2018-02-08 | 2018-07-24 | 佛山市高筑瓦业有限公司 | A kind of PVC thermal insulation tiles and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109735092A (en) * | 2018-12-27 | 2019-05-10 | 耿佃勇 | Resin tile novel resin material and preparation method thereof |
| CN110938266A (en) * | 2019-12-24 | 2020-03-31 | 龙吉松 | Preparation method of PVC composite material |
| WO2023000317A1 (en) * | 2021-07-23 | 2023-01-26 | 宁波先锋新材料股份有限公司 | Novel polyvinyl chloride plastic alloy tile and preparation method therefor |
| CN114230938A (en) * | 2021-11-12 | 2022-03-25 | 西安拓建仿古材料有限公司 | Corrosion-resistant flame-retardant polymer antique eave sealing plate and processing method thereof |
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