CN106497117A - A kind of environmental protection flame retardant Wood-plastic floor and preparation method thereof - Google Patents
A kind of environmental protection flame retardant Wood-plastic floor and preparation method thereof Download PDFInfo
- Publication number
- CN106497117A CN106497117A CN201611016491.4A CN201611016491A CN106497117A CN 106497117 A CN106497117 A CN 106497117A CN 201611016491 A CN201611016491 A CN 201611016491A CN 106497117 A CN106497117 A CN 106497117A
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- CN
- China
- Prior art keywords
- environmental protection
- flame retardant
- wheat straw
- master batch
- acetic acid
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of environmental protection flame retardant Wood-plastic floor, raw material is made up of following weight portion：Recycled plastic master batch 20～30, Wheat Straw 50～60, acetic acid 4～10, compatilizer 1～3, lubricant 2～4, antioxidant 0.4～0.8, UV absorbent 0.3～0.5, antifungus agent 0.4～0.6, red phosphorus 1.0～2.0, magnesium hydroxide 8～12, aluminium hydroxide 25～35, phosphate ester 2～4, pigment 2～4.The present invention soaks Wheat Straw powder using acetic acid, then mixes with recycled plastic master batch, and adds compatilizer; fully modified and promote bi-material to mix, the fire-retardant synchronization of organic-inorganic, it is ensured that flame retardant effect; and the interpolation of aluminium hydroxide, magnesium hydroxide improves product strength, and overall pliability is kept, the sheet material resistance to compression of preparation; shock resistance; wear-resisting, corrosion-resistant, antioxidation, anti-light photograph are fire-retardant; long service life, primary raw material environmental protection and energy saving.
Description
Technical field
The present invention relates to a kind of Wood-plastic floor, more particularly to a kind of environmental protection flame retardant Wood-plastic floor and preparation method thereof.
Background technology
In recent years, gradually deficient and " white pollution " of timber resources constantly deteriorates, and the protection of ecological environment is increasingly received
Arrive and pay attention to, the development of wood floors is faced with severe tests, and this provides wide market environment for the development of Wood-plastic floor, by
A kind of novel environment friendly based plate that is made using wood plastic composite in Wood-plastic floor, not only have timber processing characteristics and
The characteristics such as the water-fast of woodiness touch, also plastics, anti-corrosion, based on environmental protection, fashion attractive in appearance, fit up convenient the characteristics of, wood-plastic board
Progress in the finishing in outdoor park and house, but, existing Wood-plastic floor contradiction in intensity and toughness such as adds carbon
Sour calcium, causes product hard and urges, be unfavorable for transporting and install, and product has problems on fire protection flame retarding.
Wood floors to be substituted, it is desirable to which Wood-plastic floor is more environmentally friendly in raw material use, the floor that produces have resistance to compression, resistance to
Mill, pliability and intensity have both, and the characteristic with fire protection flame retarding, and existing Wood-plastic floor fails to meet above-mentioned requirements.
Content of the invention
In order to solve problem present in current techniques, it is an object of the invention to provide a kind of using salvage material and discarded
Thing production, environmental protection flame retardant Wood-plastic floor having both with resistance to compression, wear-resisting, pliability and intensity and preparation method thereof.
For reaching above-mentioned purpose, the technology used in the present invention means are：A kind of environmental protection flame retardant Wood-plastic floor, raw material by with
Lower weight portion composition：Recycled plastic master batch 20～30, Wheat Straw 50～60, acetic acid 4～10, compatilizer 1～3, lubricant 2～4,
Antioxidant 0.4～0.8, UV absorbent 0.3～0.5, antifungus agent 0.4～0.6, red phosphorus 1.0～2.0, magnesium hydroxide 8～
12nd, aluminium hydroxide 25～35, phosphate ester 2～4, pigment 2～4.
Further, the preparation method of the environmental protection flame retardant Wood-plastic floor, comprises the steps：
First, Wheat Straw is crushed, crosses 60～80 mesh sieves, add acetic acid mix homogeneously, stand 5～7d, then dry for standby；
2nd, the Wheat Straw powder after processed recycled plastic master batch with step one mixes, and adds compatilizer to stir；
3rd, lubricant, antioxidant, UV absorbent, antifungus agent, red phosphorus, hydrogen-oxygen are added in the mixed material of step 2
Change magnesium, aluminium hydroxide, phosphate ester, pigment, after stirring, send into pelletize in comminutor；
4th, the material after step 3 pelletize is sent into extruder, it is 145～210 DEG C to arrange extruder temperature, extrusion molding；
5th, the sheet material water-spraying control that step 4 is extruded.
The beneficial effects of the present invention is：Wheat Straw powder is soaked using acetic acid, is then mixed with recycled plastic master batch, and plus
Enter compatilizer, fully modified and promote bi-material to mix, magnesium hydroxide, aluminium hydroxide, red phosphorus, phosphate ester are hindered with organic-inorganic
Excessively heated axle is walked, it is ensured that flame retardant effect, and the interpolation of aluminium hydroxide, magnesium hydroxide improves product strength, and keeps overall flexible
Property, the final sheet material resistance to compression for preparing, shock resistance be wear-resisting, corrosion-resistant, and antioxidation, anti-light photograph are fire-retardant, long service life；Using return
Plastic master batch and Wheat Straw are received for primary raw material, environmental protection and energy saving.
Specific embodiment
Embodiment 1
A kind of environmental protection flame retardant Wood-plastic floor, raw material are made up of following weight portion：Recycled plastic master batch 20～30, Wheat Straw 50～
60th, acetic acid 4～10, compatilizer 1～3, lubricant 2～4, antioxidant 0.4～0.8, UV absorbent 0.3～0.5, antifungus agent
0.4～0.6, red phosphorus 1.0～2.0, magnesium hydroxide 8～12, aluminium hydroxide 25～35, phosphate ester 2～4, pigment 2～4.
Embodiment 2
The preparation method of the environmental protection flame retardant Wood-plastic floor, comprises the steps：
First, Wheat Straw is crushed, crosses 60～80 mesh sieves, add acetic acid mix homogeneously, stand 5～7d, then dry for standby；
2nd, the Wheat Straw powder after processed recycled plastic master batch with step one mixes, and adds compatilizer to stir；
3rd, lubricant, antioxidant, UV absorbent, antifungus agent, red phosphorus, hydrogen-oxygen are added in the mixed material of step 2
Change magnesium, aluminium hydroxide, phosphate ester, pigment, after stirring, send into pelletize in comminutor；
4th, the material after step 3 pelletize is sent into extruder, it is 145～210 DEG C to arrange extruder temperature, extrusion molding；
5th, the sheet material water-spraying control that step 4 is extruded.
For the sheet material that produces, the follow-up works such as sanding, embossing can be carried out according to the demand of client.
Embodiment 3
Used as the further restriction of embodiment 1, a kind of environmental protection flame retardant Wood-plastic floor, raw material are made up of following weight portion：Reclaim modeling
Material master batch 22, Wheat Straw 55, acetic acid 8, compatilizer 2, lubricant 3, antioxidant 0.6, UV absorbent 0.4, antifungus agent 0.5,
Red phosphorus 1.5, magnesium hydroxide 10, aluminium hydroxide 30, phosphate ester 3, pigment 3.
The present invention soaks Wheat Straw powder using acetic acid, then mixes with recycled plastic master batch, and adds compatilizer, fully changes
Property and promote bi-material mix, magnesium hydroxide, aluminium hydroxide, red phosphorus, phosphate ester are with the fire-retardant synchronization of organic-inorganic, it is ensured that fire-retardant
Effect, and the interpolation of aluminium hydroxide, magnesium hydroxide improves product strength, and overall pliability is kept, the final plate for preparing
Material resistance to compression, shock resistance are wear-resisting, corrosion-resistant, antioxidation, anti-light photograph, fire-retardant, long service life；Using recycled plastic master batch and wheat
Straw is primary raw material, environmental protection and energy saving.
Application embodiment is only intended to technical characteristic disclosed in the present application is described those skilled in the art are by simple
Carried out change is replaced, the scope protected by the application is still fallen within.
Claims (2)
1. a kind of environmental protection flame retardant Wood-plastic floor, raw material are made up of following weight portion：Recycled plastic master batch 20～30, Wheat Straw 50
～60, acetic acid 4～10, compatilizer 1～3, lubricant 2～4, antioxidant 0.4～0.8, UV absorbent 0.3～0.5, mould proof
Agent 0.4～0.6, red phosphorus 1.0～2.0, magnesium hydroxide 8～12, aluminium hydroxide 25～35, phosphate ester 2～4, pigment 2～4.
2. the preparation method of environmental protection flame retardant Wood-plastic floor according to claim 1, it is characterised in that comprise the steps：
First, Wheat Straw is crushed, crosses 60～80 mesh sieves, add acetic acid mix homogeneously, stand 5～7d, then dry for standby；
2nd, the Wheat Straw powder after processed recycled plastic master batch with step one mixes, and adds compatilizer to stir；
3rd, lubricant, antioxidant, UV absorbent, antifungus agent, red phosphorus, hydrogen-oxygen are added in the mixed material of step 2
Change magnesium, aluminium hydroxide, phosphate ester, pigment, after stirring, send into pelletize in comminutor；
4th, the material after step 3 pelletize is sent into extruder, it is 145～210 DEG C to arrange extruder temperature, extrusion molding；
5th, the sheet material water-spraying control that step 4 is extruded.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611016491.4A CN106497117A (en) | 2016-11-18 | 2016-11-18 | A kind of environmental protection flame retardant Wood-plastic floor and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611016491.4A CN106497117A (en) | 2016-11-18 | 2016-11-18 | A kind of environmental protection flame retardant Wood-plastic floor and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106497117A true CN106497117A (en) | 2017-03-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611016491.4A Pending CN106497117A (en) | 2016-11-18 | 2016-11-18 | A kind of environmental protection flame retardant Wood-plastic floor and preparation method thereof |
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| CN (1) | CN106497117A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106869352A (en) * | 2017-03-22 | 2017-06-20 | 合肥浦尔菲电线科技有限公司 | A kind of novel environment-friendly fire-proof plate |
| CN107227032A (en) * | 2017-06-13 | 2017-10-03 | 安徽淮宿建材有限公司 | A kind of fade resistant wood moulding roofing board |
| CN107418040A (en) * | 2017-06-13 | 2017-12-01 | 安徽淮宿建材有限公司 | A kind of high-wear-resistance and flame-retardant Wood-plastic floor |
| CN108727846A (en) * | 2018-05-14 | 2018-11-02 | 湖州统装饰材料有限公司 | A kind of manufacture craft of wood-plastic board |
Citations (3)
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| CN102690525A (en) * | 2012-05-29 | 2012-09-26 | 北京化工大学 | Wood-plastic composite material using sweet sorghum slag as enhanced phase and preparation method for wood-plastic composite material |
| DE102013011450A1 (en) * | 2013-07-10 | 2015-01-15 | PINUFORM GmbH & Co. KG | Wood plastic composite material |
| CN104927183A (en) * | 2014-03-18 | 2015-09-23 | 石大勇 | Method for producing building wood plastic template by using waste PP recycled material |
-
2016
- 2016-11-18 CN CN201611016491.4A patent/CN106497117A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102690525A (en) * | 2012-05-29 | 2012-09-26 | 北京化工大学 | Wood-plastic composite material using sweet sorghum slag as enhanced phase and preparation method for wood-plastic composite material |
| DE102013011450A1 (en) * | 2013-07-10 | 2015-01-15 | PINUFORM GmbH & Co. KG | Wood plastic composite material |
| CN104927183A (en) * | 2014-03-18 | 2015-09-23 | 石大勇 | Method for producing building wood plastic template by using waste PP recycled material |
Non-Patent Citations (1)
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| 王澜等: "提高木塑复合材料相容性的研究", 《上海塑料》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106869352A (en) * | 2017-03-22 | 2017-06-20 | 合肥浦尔菲电线科技有限公司 | A kind of novel environment-friendly fire-proof plate |
| CN107227032A (en) * | 2017-06-13 | 2017-10-03 | 安徽淮宿建材有限公司 | A kind of fade resistant wood moulding roofing board |
| CN107418040A (en) * | 2017-06-13 | 2017-12-01 | 安徽淮宿建材有限公司 | A kind of high-wear-resistance and flame-retardant Wood-plastic floor |
| CN108727846A (en) * | 2018-05-14 | 2018-11-02 | 湖州统装饰材料有限公司 | A kind of manufacture craft of wood-plastic board |
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Application publication date: 20170315 |
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