CN109320875A - A kind of synthetic resin watt and its preparation process - Google Patents

A kind of synthetic resin watt and its preparation process Download PDF

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Publication number
CN109320875A
CN109320875A CN201811190612.6A CN201811190612A CN109320875A CN 109320875 A CN109320875 A CN 109320875A CN 201811190612 A CN201811190612 A CN 201811190612A CN 109320875 A CN109320875 A CN 109320875A
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CN
China
Prior art keywords
parts
synthetic resin
fire retardant
antioxidant
watt
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CN201811190612.6A
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Chinese (zh)
Inventor
周建新
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Hunan New Building Materials Co Ltd
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Hunan New Building Materials Co Ltd
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Priority to CN201811190612.6A priority Critical patent/CN109320875A/en
Publication of CN109320875A publication Critical patent/CN109320875A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The present invention relates to a kind of synthetic resin watt and its preparation processes, component including following parts by weight, 30-50 parts of polyvinyl chloride resin, 15-25 parts of neoprene, 10-20 parts of ceramic, 5-15 parts of flyash, 4-8 parts of calcium carbonate, 10-20 parts of epoxy resin glass powder, 3-5 parts of antioxidant, 1-3 parts of fire retardant.As an improvement, the antioxidant is antioxidant SONOX 1010.As an improvement, the fire retardant is silicone based flame retardant.The present invention overcomes prior art disadvantage, provides a kind of synthetic resin watt and its preparation process, and proportion is clear, and intensity is high, practical durable.

Description

A kind of synthetic resin watt and its preparation process
Technical field
The present invention relates to resin tile technical field, in particular to a kind of synthetic resin watt and its preparation processes.
Background technique
For a long time, people mostly concentrate in the understanding to watt material the understanding of roofing.As waterproof, heat preservation, Heat-insulated roofing, clay shingle are us using one of more, longer roofing of history, and still, such watt of needs disappear A large amount of clay is consumed, and in order to protect farmland, protect environment, energy saving, China gradually to limit, be even forbidden to use Clay shingle.More and more synthetic resin watt are applied in building, synthetic resin watt, are ground with high-new chemical Chemical Engineering Technology New Building Materials made of system have a variety of excellent spies such as light-weight, intensity is big, waterproof and dampproof, antiseptic fire-retardation, sound-insulating and heat-insulating Property, be generally applicable to development zone flat-changed-into-sloping, the market of farm produce, market, residential quarters, new countryside construction resident Deluxe villa, canopy, Awning, pseudo-classic architecture etc..
Existing synthetic resin watt is suitable in various environment and structure, but due in the process of production and this stature It phenomena such as the reason of material, and lead to situations such as usually will appear fracture during production, intensity is inadequate in use, will cause The product of production is unqualified, can not bring good economic benefit in this way, and can waste material, waste time, problem above Urgently improve.
Summary of the invention
The technical problem to be solved by the present invention is to overcome prior art disadvantage, provide a kind of synthetic resin watt and its preparation Technique, proportion is clear, and intensity is high, practical durable.
In order to solve the above technical problems, technical solution provided by the invention are as follows: a kind of synthetic resin watt, including following weight The component of number, 30-50 parts of polyvinyl chloride resin, 15-25 parts of neoprene, 10-20 parts of ceramic, 5-15 parts of flyash, calcium carbonate 4- 8 parts, 10-20 parts of epoxy resin glass powder, 3-5 parts of antioxidant, 1-3 parts of fire retardant.
As an improvement, include following parts by weight component, 40 parts of polyvinyl chloride resin, 20 parts of neoprene, 15 parts of ceramic, 10 parts of flyash, 6 parts of calcium carbonate, 15 parts of epoxy resin glass powder, 4 parts of antioxidant, 2 parts of fire retardant.
As an improvement, include following parts by weight component, 35 parts of polyvinyl chloride resin, 22 parts of neoprene, 18 parts of ceramic, 7 parts of flyash, 7 parts of calcium carbonate, 17 parts of epoxy resin glass powder, 4 parts of antioxidant, 2 parts of fire retardant.
As an improvement, the antioxidant is antioxidant SONOX 1010.
As an improvement, the fire retardant is silicone based flame retardant.
A kind of synthetic resin watt preparation process, specific steps are as follows:
S1, according to weight fraction ratio, polyvinyl chloride resin is put into pulverizer and is pulverized into powder, raw material A is obtained;
S2, according to weight fraction ratio, successively by neoprene, ceramic, flyash, calcium carbonate, epoxy resin glass powder, Antioxidant, fire retardant are put into batch mixer, are mixed 10-20 minutes, are obtained mixed material B;
S3, it mixed material B is put into heater is heated to 95-115 DEG C, heat 10-20 minutes;
S4, the mixed material B after heating is put into 100 DEG C of thermostatic chamber and is placed 5-10 minutes;
S5, the mixed material B after placement is placed again into blender, stirring cooling 10-14 minutes cools to 40-60 DEG C, obtains To mixing C;
S6, mixing C is put into extrusion in double screw extruder, is granulated;
S7, temperature are heated to 180-220 DEG C, and progress is hot-forming, and synthetic resin watt is obtained after cooling and demolding.
The present invention has the advantage that present invention employs silicone based flame retardants as fire retardant, this can be effectively prevented Resin tile is ignited, and improves the safety in resin tile production and use process;Raw material is done using ceramic, is improved The high temperature resistance of the resin tile, wear-resisting property, but also ensured that tile global density is little, reduce the negative of roof Load;Proportion is clear, and the Costco Wholesale that a variety of materials are added is not high, reduction production cost, the use of antioxidant, fire retardant, greatly Raising product quality, good impact resistance and quality of materials very light, anti-load-carrying ability are all very good, are suitable for It is widely used to promote.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments.
Embodiment 1
A kind of synthetic resin watt, the component including following parts by weight, 30 parts of polyvinyl chloride resin, 15 parts of neoprene, ceramic 10 parts, 5 parts of flyash, 4 parts of calcium carbonate, 10 parts of epoxy resin glass powder, 3 parts of antioxidant, 1 part of fire retardant.
The antioxidant is antioxidant SONOX 1010, and the fire retardant is silicone based flame retardant.
A kind of synthetic resin watt preparation process, specific steps are as follows:
S1, according to weight fraction ratio, polyvinyl chloride resin is put into pulverizer and is pulverized into powder, raw material A is obtained;
S2, according to weight fraction ratio, successively by neoprene, ceramic, flyash, calcium carbonate, epoxy resin glass powder, Antioxidant, fire retardant are put into batch mixer, are mixed 10 minutes, are obtained mixed material B;
S3, it mixed material B is put into heater is heated to 95 DEG C, heat 10 minutes;
S4, the mixed material B after heating is put into 100 DEG C of thermostatic chamber and is placed 5 minutes;
S5, the mixed material B after placement is placed again into blender, stirring cooling 10 minutes cools to 40 DEG C, obtains mixing C;
S6, mixing C is put into extrusion in double screw extruder, is granulated;
S7, temperature are heated to 180 DEG C, and progress is hot-forming, and synthetic resin watt is obtained after cooling and demolding.
Embodiment 2
A kind of synthetic resin watt, the component including following parts by weight, 50 parts of polyvinyl chloride resin, 25 parts of neoprene, ceramic 20 parts, 15 parts of flyash, 8 parts of calcium carbonate, 20 parts of epoxy resin glass powder, 5 parts of antioxidant, 3 parts of fire retardant.
The antioxidant is antioxidant SONOX 1010, and the fire retardant is silicone based flame retardant.
A kind of synthetic resin watt preparation process, specific steps are as follows:
S1, according to weight fraction ratio, polyvinyl chloride resin is put into pulverizer and is pulverized into powder, raw material A is obtained;
S2, according to weight fraction ratio, successively by neoprene, ceramic, flyash, calcium carbonate, epoxy resin glass powder, Antioxidant, fire retardant are put into batch mixer, are mixed 20 minutes, are obtained mixed material B;
S3, it mixed material B is put into heater is heated to 115 DEG C, heat 20 minutes;
S4, the mixed material B after heating is put into 100 DEG C of thermostatic chamber and is placed 10 minutes;
S5, the mixed material B after placement is placed again into blender, stirring cooling 14 minutes cools to 60 DEG C, obtains mixing C;
S6, mixing C is put into extrusion in double screw extruder, is granulated;
S7, temperature are heated to 220 DEG C, and progress is hot-forming, and synthetic resin watt is obtained after cooling and demolding.
Embodiment 3
A kind of synthetic resin watt, the component including following parts by weight, 40 parts of polyvinyl chloride resin, 20 parts of neoprene, ceramic 15 parts, 10 parts of flyash, 6 parts of calcium carbonate, 15 parts of epoxy resin glass powder, 4 parts of antioxidant, 2 parts of fire retardant.
The antioxidant is antioxidant SONOX 1010, and the fire retardant is silicone based flame retardant.
A kind of synthetic resin watt preparation process, specific steps are as follows:
S1, according to weight fraction ratio, polyvinyl chloride resin is put into pulverizer and is pulverized into powder, raw material A is obtained;
S2, according to weight fraction ratio, successively by neoprene, ceramic, flyash, calcium carbonate, epoxy resin glass powder, Antioxidant, fire retardant are put into batch mixer, are mixed 15 minutes, are obtained mixed material B;
S3, it mixed material B is put into heater is heated to 105 DEG C, heat 15 minutes;
S4, the mixed material B after heating is put into 100 DEG C of thermostatic chamber and is placed 8 minutes;
S5, the mixed material B after placement is placed again into blender, stirring cooling 12 minutes cools to 50 DEG C, obtains mixing C;
S6, mixing C is put into extrusion in double screw extruder, is granulated;
S7, temperature are heated to 200 DEG C, and progress is hot-forming, and synthetic resin watt is obtained after cooling and demolding.

Claims (6)

1. a kind of synthetic resin watt, it is characterised in that: the component including following parts by weight, 30-50 parts of polyvinyl chloride resin, neoprene 15-25 parts, 10-20 parts of ceramic, 5-15 parts of flyash, 4-8 parts of calcium carbonate, 10-20 parts of epoxy resin glass powder, antioxidant 3-5 parts, 1-3 parts of fire retardant.
2. a kind of synthetic resin watt according to claim 1, it is characterised in that: the component including following parts by weight, PVC 40 parts of resin, 20 parts of neoprene, 15 parts of ceramic, 10 parts of flyash, 6 parts of calcium carbonate, 15 parts of epoxy resin glass powder, antioxygen 4 parts of agent, 2 parts of fire retardant.
3. a kind of synthetic resin watt according to claim 1, it is characterised in that: the component including following parts by weight, PVC 35 parts of resin, 22 parts of neoprene, 18 parts of ceramic, 7 parts of flyash, 7 parts of calcium carbonate, 17 parts of epoxy resin glass powder, antioxygen 4 parts of agent, 2 parts of fire retardant.
4. a kind of synthetic resin watt according to claim 1, it is characterised in that: the antioxidant is antioxidant SONOX 1010。
5. a kind of synthetic resin watt according to claim 1, it is characterised in that: the fire retardant is that organic silicon is fire-retardant Agent.
6. a kind of synthetic resin watt preparation process described in any one of -5 claims according to claim 1, which is characterized in that tool Body step are as follows:
S1, according to weight fraction ratio, polyvinyl chloride resin is put into pulverizer and is pulverized into powder, raw material A is obtained;
S2, according to weight fraction ratio, successively by neoprene, ceramic, flyash, calcium carbonate, epoxy resin glass powder, antioxygen Agent, fire retardant are put into batch mixer, are mixed 10-20 minutes, are obtained mixed material B;
S3, it mixed material B is put into heater is heated to 95-115 DEG C, heat 10-20 minutes;
S4, the mixed material B after heating is put into 100 DEG C of thermostatic chamber and is placed 5-10 minutes;
S5, the mixed material B after placement is placed again into blender, stirring cooling 10-14 minutes cools to 40-60 DEG C, mixed Expect C;
S6, mixing C is put into extrusion in double screw extruder, is granulated;
S7, temperature are heated to 180-220 DEG C, and progress is hot-forming, and synthetic resin watt is obtained after cooling and demolding.
CN201811190612.6A 2018-10-12 2018-10-12 A kind of synthetic resin watt and its preparation process Pending CN109320875A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110938266A (en) * 2019-12-24 2020-03-31 龙吉松 Preparation method of PVC composite material
CN113845782A (en) * 2021-10-25 2021-12-28 怀化市新益全新型环保建材有限公司 Corrosion-resistant ancient-proof tile and manufacturing process thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103965567A (en) * 2014-05-04 2014-08-06 安徽正隆新材料有限公司 PVC (Polyvinyl Chloride) synthetic resin tile
CN104231501A (en) * 2014-09-30 2014-12-24 句容金猴机械研究所有限公司 Synthesized resin tile and preparing method thereof
CN107353585A (en) * 2016-05-09 2017-11-17 陈春来 New synthetic resin watt formula

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103965567A (en) * 2014-05-04 2014-08-06 安徽正隆新材料有限公司 PVC (Polyvinyl Chloride) synthetic resin tile
CN104231501A (en) * 2014-09-30 2014-12-24 句容金猴机械研究所有限公司 Synthesized resin tile and preparing method thereof
CN107353585A (en) * 2016-05-09 2017-11-17 陈春来 New synthetic resin watt formula

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110938266A (en) * 2019-12-24 2020-03-31 龙吉松 Preparation method of PVC composite material
CN113845782A (en) * 2021-10-25 2021-12-28 怀化市新益全新型环保建材有限公司 Corrosion-resistant ancient-proof tile and manufacturing process thereof

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Application publication date: 20190212

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