CN109337285A - A kind of fire-proof and thermal-insulation resin tile and preparation method thereof - Google Patents
A kind of fire-proof and thermal-insulation resin tile and preparation method thereof Download PDFInfo
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- CN109337285A CN109337285A CN201811190644.6A CN201811190644A CN109337285A CN 109337285 A CN109337285 A CN 109337285A CN 201811190644 A CN201811190644 A CN 201811190644A CN 109337285 A CN109337285 A CN 109337285A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of fire-proof and thermal-insulation resin tile, the raw material including following parts by weight: 100~160 parts of phenolic resin, 3-8 parts of sodium pyrophosphate, 10-30 parts of alumina fibre, 2-6 parts of iron oxide red, 4-10 parts of cobalt iso-octoate, 3-8 parts of neoprene, 5-10 parts of fire retardant, 20-30 parts of unsaturated polyester resin, 3-8 parts of stabilizer, 0.5~2 part of ultraviolet absorbing agent, 0.1~0.6 part of antioxidant.Resin tile of the invention has excellent fire retardant performance, sound insulation, waterproof, corrosion resistance, and the good mechanical performances such as impact strength, tensile strength are suitble to large-scale industrial production.
Description
Technical field
The present invention relates to resin tile fields, in particular to a kind of fire-proof and thermal-insulation resin tile and preparation method thereof.
Background technique
With quitting listing for modern native tile kilning piece, although cement tile cost is sufficiently minimized, lack enough weather resistances
(fracture often occurred is peeled off), becomes a great problem of puzzlement developer, especially uses in skyscraper, the peeling institute of tile
Bring harm has been not only the waterproof problem worried.With domestic extending old building (flat-changed-into-sloping) and the need of reducing energy consumption
It asks, synthetic resin watt comes into being, and synthetic resin watt is the New Building Materials developed using high-new chemical Chemical Engineering Technology,
It is the lightweight material of new generation that China vigorously advocates and promotes, with light-weight, intensity is big, waterproof and dampproof, antiseptic fire-retardation, sound insulation
A variety of good characteristics such as heat-insulated are generally applicable to the market of farm produce, market, residential quarters, new countryside construction resident Deluxe villa, rain
Paulin, awning, pseudo-classic architecture etc., the applicable environment construction of synthetic resin watt used at present is very extensive, but fire-proof and thermal-insulation
Performance is poor, is not suitable for large-scale production and utilizes.
Summary of the invention
The technical problem to be solved by the present invention is to overcome prior art disadvantage, provide a kind of with excellent fire protection flame retarding
Performance, sound insulation, waterproof, corrosion resistance, a kind of fire-proof and thermal-insulation resin tile of the good mechanical performances such as impact strength, tensile strength
And preparation method thereof.
In order to solve the above technical problems, technical solution provided by the invention are as follows: a kind of fire-proof and thermal-insulation resin tile, including it is following
The raw material of parts by weight: 100~160 parts of phenolic resin, 3-8 parts of sodium pyrophosphate, 10-30 parts of alumina fibre, iron oxide red 2-6
Part, 4-10 parts of cobalt iso-octoate, 3-8 parts of neoprene, 5-10 parts of fire retardant, 20-30 parts of unsaturated polyester resin, 3-8 parts of stabilizer,
0.5~2 part of ultraviolet absorbing agent, 0.1~0.6 part of antioxidant.
As an improvement, including the raw material of following parts by weight: 140 parts of phenolic resin, 5 parts of sodium pyrophosphate, alumina fibre 20
Part, 4 parts of iron oxide red, 5 parts of cobalt iso-octoate, 5 parts of neoprene, 7 parts of fire retardant, 24 parts of unsaturated polyester resin, 4 parts of stabilizer,
1.4 parts of ultraviolet absorbing agent, 0.4 part of antioxidant.
As an improvement, the fire retardant is antimony oxide, chlorinated paraffin, silica, tetrabromobisphenol A, tricresyl phosphate
One of rouge or a variety of combinations.
As an improvement, the unsaturated polyester resin is Bisphenol a unsaturated polyester resin, 182# unsaturated polyester (UP) tree
One of rouge, 191# unsaturated polyester resin or a variety of combinations.
As an improvement, the stabilizer is in dibasic lead phosphite, dibasic lead stearate and lead sulfate tribasic
One or more combinations.
As an improvement, the ultraviolet absorbing agent is phenyl salicylate, ultraviolet absorbent UV-531, ultraviolet radiation absorption
One of agent UVP-327, ultraviolet absorbing agent RMB, light stabilizer HPT or a variety of combinations.
As an improvement, the antioxidant is antioxidant 1010, in antioxidant 1076, antioxidant 164, antioxidant TPP
One or more combinations.
A kind of preparation method of fire-proof and thermal-insulation resin tile, comprising the following steps:
(1) phenolic resin, unsaturated polyester resin, chlorinated paraffin, sodium pyrophosphate and cobalt iso-octoate are put into proportion
In container, 10~20min is stirred under conditions of 50-70 DEG C, 200-300r/min, obtains mixture a；
(2) fire retardant is sent into pulverizer to crush, crosses 150-200 mesh and obtains fire-retardant particles b；
(3) mixture a, fire-retardant particles b are added in autoclave, add neoprene, iron oxide red, stabilizer,
Ultraviolet absorbing agent, antioxidant 100-110 DEG C of temperature, are placed on 105 DEG C of constant temperature after stirring 20-30min in pressure 2-3MPa
5-10min makes volatilization gas volatilize in room, naturally cools to 50-60 DEG C of formation reactant c；
(4) reactant c is put into injection molding machine, is molded at 180-200 DEG C, placed into die mould on tile-type mold and solidify
Obtain the resin tile.
The present invention has the advantage that
The toughness and service life for improving resin tile have had resin tile due to joined neoprene in resin
Ductility, can Resisting fractre, resisting breakage performance greatly improves, but due to selected high performance Bisphenol a unsaturated polyester resin,
182# unsaturated polyester resin, 191# unsaturated polyester resin and reasonable material mixture ratio and hierarchical structure arrangement, service life
It greatly improves, because joined cobalt iso-octoate, shortens the production time, be added to antimony oxide, chlorinated paraffin, dioxy
One of SiClx, tetrabromobisphenol A, tricresyl phosphate rouge or it is a variety of be used as fire retardant, improve the heat-insulating flame-retardant effect of product, product at
Moral character can be stablized, nontoxic, nonpollution environment, with short production cycle, at low cost, and tool weight bearing ability is most strong, fire-retardant fireproof, service life
It is long.
Specific embodiment
The present invention will be further described in detail below with reference to the embodiments.
Embodiment 1
A kind of fire-proof and thermal-insulation resin tile, the raw material including following parts by weight: 140 parts of phenolic resin, 5 parts of sodium pyrophosphate, oxygen
Change 20 parts of aluminum fiber, 4 parts of iron oxide red, 5 parts of cobalt iso-octoate, 5 parts of neoprene, 2 parts of antimony oxide, 3 parts of chlorinated paraffin, dioxy
2 parts of SiClx, 24 parts of Bisphenol a unsaturated polyester resin, 4 parts of dibasic lead phosphite, ultraviolet absorbing agent phenyl salicylate 1.4
Part, 0.4 part of antioxidant 1076.
A kind of preparation method of above-mentioned fire-proof and thermal-insulation resin tile, comprising the following steps:
(1) by phenolic resin, Bisphenol a unsaturated polyester resin, chlorinated paraffin, sodium pyrophosphate and cobalt iso-octoate press than
Example is put into container, is stirred 15min under conditions of 60 DEG C, 250r/min, is obtained mixture a；
(2) fire retardant antimony oxide, fire retardant chlorinated paraffin, fire retardant silica are sent into pulverizer and crushed, mistake
180 meshes obtain fire-retardant particles b；
(3) mixture a, fire-retardant particles b are added in autoclave, it is sub- adds neoprene, iron oxide red, dibasic
Lead phosphate, ultraviolet absorbing agent phenyl salicylate, antioxidant 1076 108 DEG C of temperature, are put in pressure 2.5MPa after stirring 28min
Setting the 8min in 105 DEG C of thermostatic chambers makes volatilization gas volatilize, and naturally cools to 55 DEG C of formation reactant c；
(4) reactant c is put into injection molding machine, is molded at 190 DEG C, placed into die mould on tile-type mold and solidify to obtain
The resin tile.
Embodiment 2
A kind of fire-proof and thermal-insulation resin tile, the raw material including following parts by weight: 150 parts of phenolic resin, 6 parts of sodium pyrophosphate, oxygen
Change 25 parts of aluminum fiber, 5 parts of iron oxide red, 8 parts of cobalt iso-octoate, 5 parts of neoprene, 4 parts of antimony oxide, 3 parts of tetrabromobisphenol A,
13 parts of 182# unsaturated polyester resin, 13 parts of 191# unsaturated polyester resin, 6 parts of dibasic lead stearate, light stabilizer
HPT1.6 parts, TPP0.2 parts of antioxidant.
A kind of preparation method of above-mentioned fire-proof and thermal-insulation resin tile, comprising the following steps:
(1) by phenolic resin, Bisphenol a unsaturated polyester resin, chlorinated paraffin, sodium pyrophosphate and cobalt iso-octoate press than
Example is put into container, is stirred 12min under conditions of 55 DEG C, 280r/min, is obtained mixture a；
(2) fire retardant antimony oxide, tetrabromobisphenol A are sent into pulverizer and crushed, cross 180 meshes and obtain fire-retardant particles
b；
(3) mixture a, fire-retardant particles b are added in autoclave, it is hard adds neoprene, iron oxide red, dibasic
Resin acid lead, light stabilizer HPT, antioxidant TPP 108 DEG C of temperature, are placed on 105 DEG C of perseverances after stirring 26min in pressure 2.8MPa
8min makes volatilization gas volatilize in greenhouse, naturally cools to 55 DEG C of formation reactant c；
(4) reactant c is put into injection molding machine, is molded at 190 DEG C, placed into die mould on tile-type mold and solidify to obtain
The resin tile.
Embodiment 3
A kind of fire-proof and thermal-insulation resin tile, the raw material including following parts by weight: 130 parts of phenolic resin, 4 parts of sodium pyrophosphate, oxygen
Change 15 parts of aluminum fiber, 3 parts of iron oxide red, 6 parts of cobalt iso-octoate, 5 parts of neoprene, 7 parts of tricresyl phosphate rouge, bisphenol A-type unsaturated polyester (UP)
25 parts of resin, 4 parts of dibasic lead stearate, 1.4 parts of ultraviolet absorbing agent UVP-327,164 0.2 parts of antioxidant.
A kind of preparation method of above-mentioned fire-proof and thermal-insulation resin tile, comprising the following steps:
(1) by phenolic resin, Bisphenol a unsaturated polyester resin, chlorinated paraffin, sodium pyrophosphate and cobalt iso-octoate press than
Example is put into container, is stirred 18min under conditions of 65 DEG C, 280r/min, is obtained mixture a；
(2) fire retardant tricresyl phosphate rouge is sent into pulverizer to crush, crosses 180 meshes and obtains fire-retardant particles b；
(3) mixture a, fire-retardant particles b are added in autoclave, it is hard adds neoprene, iron oxide red, dibasic
Resin acid lead, ultraviolet absorbing agent UVP-327, antioxidant 164 108 DEG C of temperature, are placed in pressure 2.8MPa after stirring 25min
8min makes volatilization gas volatilize in 105 DEG C of thermostatic chambers, naturally cools to 55 DEG C of formation reactant c；
(4) reactant c is put into injection molding machine, is molded at 190 DEG C, placed into die mould on tile-type mold and solidify to obtain
The resin tile.
Claims (8)
1. a kind of fire-proof and thermal-insulation resin tile, it is characterised in that: the raw material including following parts by weight: 100~160 parts of phenolic resin,
It is 3-8 parts of sodium pyrophosphate, 10-30 parts of alumina fibre, 2-6 parts of iron oxide red, 4-10 parts of cobalt iso-octoate, 3-8 parts of neoprene, fire-retardant
5-10 parts of agent, 20-30 parts of unsaturated polyester resin, 3-8 parts of stabilizer, 0.5~2 part of ultraviolet absorbing agent, antioxidant 0.1~
0.6 part.
2. a kind of fire-proof and thermal-insulation resin tile according to claim 1, it is characterised in that: the raw material including following parts by weight:
140 parts of phenolic resin, 5 parts of sodium pyrophosphate, 20 parts of alumina fibre, 4 parts of iron oxide red, 5 parts of cobalt iso-octoate, 5 parts of neoprene, resistance
Fire 7 parts of agent, 24 parts of unsaturated polyester resin, 4 parts of stabilizer, 1.4 parts of ultraviolet absorbing agent, 0.4 part of antioxidant.
3. a kind of fire-proof and thermal-insulation resin tile according to claim 1, it is characterised in that: the fire retardant is three oxidations two
One of antimony, chlorinated paraffin, silica, tetrabromobisphenol A, tricresyl phosphate rouge or a variety of combinations.
4. a kind of fire-proof and thermal-insulation resin tile according to claim 1, it is characterised in that: the unsaturated polyester resin is
One of Bisphenol a unsaturated polyester resin, 182# unsaturated polyester resin, 191# unsaturated polyester resin or a variety of groups
It closes.
5. a kind of fire-proof and thermal-insulation resin tile according to claim 1, it is characterised in that: the stabilizer is that dibasic is sub-
One of lead phosphate, dibasic lead stearate and lead sulfate tribasic or a variety of combinations.
6. a kind of fire-proof and thermal-insulation resin tile according to claim 1, it is characterised in that: the ultraviolet absorbing agent is water
Poplar acid phenenyl ester, ultraviolet absorbent UV-531, ultraviolet absorbing agent UVP-327, ultraviolet absorbing agent RMB, in light stabilizer HPT
One or more combinations.
7. a kind of fire-proof and thermal-insulation resin tile according to claim 1, it is characterised in that: the antioxidant is antioxidant
1010, one of antioxidant 1076, antioxidant 164, antioxidant TPP or a variety of combinations.
8. a kind of preparation method of fire-proof and thermal-insulation resin tile described in any one of -7 according to claim 1, it is characterised in that: packet
Include following steps:
(1) phenolic resin, unsaturated polyester resin, chlorinated paraffin, sodium pyrophosphate and cobalt iso-octoate are put into container in proportion
In, 10~20min is stirred under conditions of 50-70 DEG C, 200-300r/min, obtains mixture a；
(2) fire retardant is sent into pulverizer to crush, crosses 150-200 mesh and obtains fire-retardant particles b；
(3) mixture a, fire-retardant particles b are added in autoclave, add neoprene, iron oxide red, stabilizer, ultraviolet
Light absorbers, antioxidant 100-110 DEG C of temperature, are placed in 105 DEG C of thermostatic chambers in pressure 2-3MPa after stirring 20-30min
5-10min makes volatilization gas volatilize, and naturally cools to 50-60 DEG C of formation reactant c；
(4) reactant c is put into injection molding machine, is molded at 180-200 DEG C, placed into die mould on tile-type mold and solidify to obtain
The resin tile.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811190644.6A CN109337285A (en) | 2018-10-12 | 2018-10-12 | A kind of fire-proof and thermal-insulation resin tile and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811190644.6A CN109337285A (en) | 2018-10-12 | 2018-10-12 | A kind of fire-proof and thermal-insulation resin tile and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109337285A true CN109337285A (en) | 2019-02-15 |
Family
ID=65309453
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811190644.6A Pending CN109337285A (en) | 2018-10-12 | 2018-10-12 | A kind of fire-proof and thermal-insulation resin tile and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109337285A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112409721A (en) * | 2020-10-23 | 2021-02-26 | 湖南省建新建材有限公司 | Corrosion-resistant resin tile |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62290746A (en) * | 1986-06-09 | 1987-12-17 | Maruo Calcium Kk | Polyvinyl chloride resin tile |
| CN1195613A (en) * | 1998-05-15 | 1998-10-14 | 丁浩 | Multicolour flame-retardant resin tile |
| CN103304972A (en) * | 2013-06-28 | 2013-09-18 | 江苏海田技术有限公司 | High temperature-resistant resin composition |
| CN103602049A (en) * | 2013-10-30 | 2014-02-26 | 山东吉青化工有限公司 | Flame-retardant resin |
| CN107254137A (en) * | 2017-07-04 | 2017-10-17 | 合肥慧林建材有限公司 | A kind of fireproof resistance combustion resin watt and preparation method thereof |
-
2018
- 2018-10-12 CN CN201811190644.6A patent/CN109337285A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62290746A (en) * | 1986-06-09 | 1987-12-17 | Maruo Calcium Kk | Polyvinyl chloride resin tile |
| CN1195613A (en) * | 1998-05-15 | 1998-10-14 | 丁浩 | Multicolour flame-retardant resin tile |
| CN103304972A (en) * | 2013-06-28 | 2013-09-18 | 江苏海田技术有限公司 | High temperature-resistant resin composition |
| CN103602049A (en) * | 2013-10-30 | 2014-02-26 | 山东吉青化工有限公司 | Flame-retardant resin |
| CN107254137A (en) * | 2017-07-04 | 2017-10-17 | 合肥慧林建材有限公司 | A kind of fireproof resistance combustion resin watt and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112409721A (en) * | 2020-10-23 | 2021-02-26 | 湖南省建新建材有限公司 | Corrosion-resistant resin tile |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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Application publication date: 20190215 |