CN104829192B - Thermal-insulation energy-conservation material and its cement plate - Google Patents
Thermal-insulation energy-conservation material and its cement plate Download PDFInfo
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- CN104829192B CN104829192B CN201510171948.8A CN201510171948A CN104829192B CN 104829192 B CN104829192 B CN 104829192B CN 201510171948 A CN201510171948 A CN 201510171948A CN 104829192 B CN104829192 B CN 104829192B
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- 239000000463 material Substances 0.000 title claims abstract description 35
- 238000004134 energy conservation Methods 0.000 title claims abstract description 25
- 238000009413 insulation Methods 0.000 title claims abstract description 24
- 239000004568 cement Substances 0.000 title claims description 11
- 239000007822 coupling agent Substances 0.000 claims abstract description 27
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims abstract description 19
- 239000006260 foam Substances 0.000 claims abstract description 18
- YIBPLYRWHCQZEB-UHFFFAOYSA-N formaldehyde;propan-2-one Chemical class O=C.CC(C)=O YIBPLYRWHCQZEB-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229920002635 polyurethane Polymers 0.000 claims abstract description 13
- 239000004814 polyurethane Substances 0.000 claims abstract description 13
- 239000003381 stabilizer Substances 0.000 claims abstract description 13
- 239000011398 Portland cement Substances 0.000 claims abstract description 12
- 239000011324 bead Substances 0.000 claims abstract description 12
- 239000000919 ceramic Substances 0.000 claims abstract description 12
- 239000002270 dispersing agent Substances 0.000 claims abstract description 12
- 239000003822 epoxy resin Substances 0.000 claims abstract description 12
- 239000010881 fly ash Substances 0.000 claims abstract description 12
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052863 mullite Inorganic materials 0.000 claims abstract description 11
- 229940116351 sebacate Drugs 0.000 claims abstract description 8
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000000835 fiber Substances 0.000 claims abstract description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 60
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 52
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 25
- 235000010265 sodium sulphite Nutrition 0.000 claims description 17
- 238000010792 warming Methods 0.000 claims description 16
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 15
- 239000012965 benzophenone Substances 0.000 claims description 15
- -1 decanedioic acid Ester Chemical class 0.000 claims description 15
- URDCARMUOSMFFI-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(2-hydroxyethyl)amino]acetic acid Chemical compound OCCN(CC(O)=O)CCN(CC(O)=O)CC(O)=O URDCARMUOSMFFI-UHFFFAOYSA-N 0.000 claims description 13
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 11
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 10
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 8
- 229910000077 silane Inorganic materials 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000004872 foam stabilizing agent Substances 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 5
- FMRHJJZUHUTGKE-UHFFFAOYSA-N Ethylhexyl salicylate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1O FMRHJJZUHUTGKE-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical group OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 4
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 229960004889 salicylic acid Drugs 0.000 claims description 2
- 229920000305 Nylon 6,10 Polymers 0.000 claims 1
- 125000003916 ethylene diamine group Chemical group 0.000 claims 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N n-Decanedioic acid Natural products OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- 238000004321 preservation Methods 0.000 abstract description 2
- 230000005855 radiation Effects 0.000 abstract description 2
- CSUUDNFYSFENAE-UHFFFAOYSA-N (2-methoxyphenyl)-phenylmethanone Chemical compound COC1=CC=CC=C1C(=O)C1=CC=CC=C1 CSUUDNFYSFENAE-UHFFFAOYSA-N 0.000 abstract 1
- AHJKRLASYNVKDZ-UHFFFAOYSA-N DDD Chemical compound C=1C=C(Cl)C=CC=1C(C(Cl)Cl)C1=CC=C(Cl)C=C1 AHJKRLASYNVKDZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 125000005936 piperidyl group Chemical group 0.000 abstract 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 229960001860 salicylate Drugs 0.000 description 14
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 13
- 229960001484 edetic acid Drugs 0.000 description 13
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 11
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 7
- 239000012774 insulation material Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000007859 condensation product Substances 0.000 description 5
- 150000002576 ketones Chemical class 0.000 description 5
- OTEKOJQFKOIXMU-UHFFFAOYSA-N 1,4-bis(trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=C(C(Cl)(Cl)Cl)C=C1 OTEKOJQFKOIXMU-UHFFFAOYSA-N 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 150000003902 salicylic acid esters Chemical group 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000006277 sulfonation reaction Methods 0.000 description 2
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- WTBIAPVQQBCLFP-UHFFFAOYSA-N N.N.N.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O Chemical group N.N.N.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O.CC(O)=O WTBIAPVQQBCLFP-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical group [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The invention discloses a kind of thermal-insulation energy-conservation material, the energy-saving material raw material includes Portland cement, flyash, hydrogen peroxide, TDE, sulfonated acetone formaldehyde polycondensate, liquid-state epoxy resin dispersant, polyurethane, foam stabilizer, coupling agent, mullite fiber, ceramic fine bead, double (2,2,6,6, the piperidyl of tetramethyl 4) sebacate, the methoxy benzophenone of 2 hydroxyl 4, ultra-violet absorber, thermal and insulating performance is good, the 200kg/m of product dry density 1603, thermal conductivity factor at 0.05 0.08W/ (m*K), with good heat preservation and energy conservation effects；Fire protecting performance is good, and fire endurance is more than 3h, A grades of fire-protection standard is can reach, so that with good fire resistance；Sound insulation value is good, can greatly reduce noise effect；Excellent in durability, with anti-high and low-temp performance, the characteristics of corrosion-resistant, ultraviolet radiation resisting, good weatherability.
Description
Technical field
Field of material technology is built the present invention relates to one kind, more particularly to a kind of thermal-insulation energy-conservation material and its cement plate.
Background technology
The implementation of Building Energy Conservation Policy has promoted the development of wall heat insulation material.The organic foams such as polystyrene, polyurethane
Plastic, thermal-insulation material is widely used in wall thermal insulating, but such organic foam plastic insulation material easily burns, during burning
Fire spreading is rapid, and is produced with a large amount of poison gases and flue gas, and exceptional hardship is brought to rescue work of extinguishing fire, causes casualties
And property loss.The shortcomings of simultaneously also there is easily aging, poor dimensional stability in such insulation material.Protected compared to organic foam plastic
Adiabator, inorganic heat insulation material has that fire line is good, deformation coefficient is small, ageing resistace is strong, steady performance, so will
Foam cement insulation material is applied in wall thermal insulating, with extensive popularizing application prospect.Cement board be at present gradually
Rise a kind of external-wall heat-insulation material, it have it is non-aging, completely with the building same life-span, unit weight is light, thermal conductivity factor is low, resistance to
The fiery limit more than 3 hours, the advantages of will not produce toxic gas under high temperature or fire condition, but the shortcoming of foam cement version
It is also obvious that be exactly poor mechanical property, intensity is relatively low, fragility is larger, it is very easy to fracture, damaged, to transporting and constructed
Journey brings very big inconvenience.
The content of the invention
In view of this, it is an object of the invention to provide a kind of new thermal-insulation energy-conservation material and its cement plate, tool
Have the advantages that fire resisting, long service life, thermal conductivity factor it is small, it is environmentally friendly while, can overcome that its fragility is big, the problem of cracky again.
Thermal-insulation energy-conservation material of the invention, the energy-saving material raw material includes following components by weight：
100 parts, 20-30 parts flyash of Portland cement, 11-18 parts of hydrogen peroxide, 0.5-3 parts of TDE,
0.5-3 parts of sulfonated acetone formaldehyde polycondensate, 1-5 parts of liquid-state epoxy resin dispersant, 1-5 parts of polyurethane, 2-6 parts of foam stabilizer, 3-6
Part coupling agent, 6-12 parts of mullite fiber, ceramic fine bead 1-4 parts, 0.5-2 parts of double (2,2,6,6,-tetramethyl -4- piperidyl) last of the ten Heavenly stems
Two acid esters, 0.1-2 part ESCALOL 567,0.5-2 parts of ultra-violet absorber；
Further, the energy-saving material raw material includes following components by weight：
100 parts, 25 parts flyash of Portland cement, 15 parts of hydrogen peroxide, 2 parts of TDEs, 2 parts of sulfonated acetones
Formaldehyde condensation products, 2.5 parts of liquid-state epoxy resin dispersants, 3 parts of polyurethane, 4 parts of foam stabilizers, 5 parts of coupling agents, 10 parts of mullite fibres
Dimension, 3 parts of ceramic fine bead, 1.5 parts of double (2,2,6,6,-tetramethyl -4- piperidyl) sebacate, 1 part of 2- hydroxyl -4- methoxyl group two
Benzophenone, 1 part of ultra-violet absorber；
Further, the sulfonated acetone formaldehyde polycondensate is obtained by the following method：Sodium sulfite and water are mixed
50 DEG C are warming up to after being slowly added dropwise acetone at being afterwards 50 DEG C in temperature, 1h is incubated, is slowly added dropwise at being again then 70 DEG C in temperature
90 DEG C are warming up to after formaldehyde, 4h is incubated；
Further, the sulfurous acid, formaldehyde, the mol ratio of acetone are：N (sodium sulfite):N (formaldehyde):N (acetone)=
0.8:2.65:1；
Further, the foam stabilizer is in ethylenediamine tetra-acetic acid, diethyl triamine pentaacetic acid, N-hydroxyethyl-ethylenediamine triacetic acid
One or more mixtures；
Further, the coupling agent is the mixture of titanate coupling agent and silane coupler；
Further, the ultra-violet absorber be salicylate, benzophenone, BTA in one or more
Mixture.
Invention additionally discloses a kind of cement plate, it is made up of thermal-insulation energy-conservation material.
Beneficial effects of the present invention：Thermal-insulation energy-conservation material of the invention and its cement plate, thermal and insulating performance are good, produce
Product dry density 160-200kg/m3, thermal conductivity factor at 0.05-0.08W/ (m*K), with good heat preservation and energy conservation effects；Fire line
Can be good, fire endurance is more than 3h, A grades of fire-protection standard is can reach, so that with good fire resistance；Sound insulation value is good, can be significantly
Reduce noise effect；Excellent in durability, with anti-high and low-temp performance, the characteristics of corrosion-resistant, ultraviolet radiation resisting, good weatherability.
Specific embodiment
Thermal-insulation energy-conservation material of the invention, the energy-saving material raw material includes following components by weight：
100 parts, 20-30 parts flyash of Portland cement, 11-18 parts of hydrogen peroxide, 0.5-3 parts of TDE,
0.5-3 parts of sulfonated acetone formaldehyde polycondensate, 1-5 parts of liquid-state epoxy resin dispersant, 1-5 parts of polyurethane, 2-6 parts of foam stabilizer, 3-6
Part coupling agent, 6-12 parts of mullite fiber, ceramic fine bead 1-4 parts, 0.5-2 parts of double (2,2,6,6,-tetramethyl -4- piperidyl) last of the ten Heavenly stems
Two acid esters, 0.1-2 part ESCALOL 567,0.5-2 parts of ultra-violet absorber.
In the present embodiment, the energy-saving material raw material includes following components by weight：
100 parts, 25 parts flyash of Portland cement, 15 parts of hydrogen peroxide, 2 parts of TDEs, 2 parts of sulfonated acetones
Formaldehyde condensation products, 2.5 parts of liquid-state epoxy resin dispersants, 3 parts of polyurethane, 4 parts of foam stabilizers, 5 parts of coupling agents, 10 parts of mullite fibres
Dimension, 3 parts of ceramic fine bead, 1.5 parts of double (2,2,6,6,-tetramethyl -4- piperidyl) sebacate, 1 part of 2- hydroxyl -4- methoxyl group two
Benzophenone, 1 part of ultra-violet absorber；
In the present embodiment, the sulfonated acetone formaldehyde polycondensate is obtained by the following method：Sodium sulfite and water are mixed
50 DEG C are warming up to after being slowly added dropwise acetone at being 50 DEG C in temperature after stirring, 1h is incubated, it is slow at being again then 70 DEG C in temperature
90 DEG C are warming up to after formaldehyde is added dropwise, 4h is incubated.
In the present embodiment, the sulfurous acid, formaldehyde, the mol ratio of acetone are：N (sodium sulfite):N (formaldehyde):N (acetone)
=0.8:2.65:1.
In the present embodiment, the foam stabilizer is ethylenediamine tetra-acetic acid, diethyl triamine pentaacetic acid, N-hydroxyethyl-ethylenediamine triacetic acid
In one or more mixtures.
In the present embodiment, the coupling agent is the mixture of titanate coupling agent and silane coupler.
In the present embodiment, the ultra-violet absorber be salicylate, benzophenone, BTA in one or two
Thing mixed above.
Invention additionally discloses a kind of cement plate, it is made up of thermal-insulation energy-conservation material.
Below by specific embodiment, the present invention is further elaborated.
Embodiment one
In the present embodiment, the energy-saving material raw material includes following components by weight：
100 parts, 25 parts flyash of Portland cement, 15 parts of hydrogen peroxide, 2 parts of TDEs, 2 parts of sulfonated acetones
Formaldehyde condensation products, 2.5 parts of liquid-state epoxy resin dispersants, 3 parts of polyurethane, 4 parts of foam stabilizers, 5 parts of coupling agents, 10 parts of mullite fibres
Dimension, 3 parts of ceramic fine bead, 1.5 parts of double (2,2,6,6,-tetramethyl -4- piperidyl) sebacate, 1 part of 2- hydroxyl -4- methoxyl group two
Benzophenone, 1 part of ultra-violet absorber；
In the present embodiment, the sulfonated acetone formaldehyde polycondensate is obtained by the following method：Sodium sulfite and water are mixed
50 DEG C are warming up to after being slowly added dropwise acetone at being 50 DEG C in temperature after stirring, 1h is incubated, it is slow at being again then 70 DEG C in temperature
90 DEG C are warming up to after formaldehyde is added dropwise, 4h is incubated.
In the present embodiment, the sulfurous acid, formaldehyde, the mol ratio of acetone are：N (sodium sulfite):N (formaldehyde):N (acetone)
=0.8:2.65:1.
In the present embodiment, in the present embodiment, the foam stabilizer is ethylenediamine tetra-acetic acid, in the present embodiment, by the second two
Amine tetraacethyl part replace with diethyl triamine pentaacetic acid, N-hydroxyethyl-ethylenediamine triacetic acid according to equivalent weight in one kind, or by same
Ethylenediamine tetra-acetic acid and diethyl triamine pentaacetic acid, the mixture of N-hydroxyethyl-ethylenediamine triacetic acid are replaced with Deng weight portion, gained is produced
Moral character matter has no significant difference.
In the present embodiment, the coupling agent is the mixture of titanate coupling agent and silane coupler.
In the present embodiment, the ultra-violet absorber is salicylate, in the present embodiment, by the salicylate according to same
One kind in replacing with benzophenone, BTA Deng weight portion, or replace with salicylate and hexichol first by equivalent weight part
The mixture of ketone, BTA, products obtained therefrom property has no significant difference.
Embodiment two
The thermal-insulation energy-conservation material of the present embodiment, the energy-saving material raw material includes following components by weight：
100 parts, 20 parts flyash of Portland cement, 11 parts of hydrogen peroxide, 0.5 part of TDE, 0.5 part of sulfonation
Acetone-formaldehyde condensation polymer, 1 part of liquid-state epoxy resin dispersant, 1 part of polyurethane, 2 parts of foam stabilizers, 3 parts of coupling agents, 6 parts of mullites
Fiber, 1 part of ceramic fine bead, 0.5 pair of (2,2,6,6,-tetramethyl -4- piperidyl) sebacate, 0.1 part of 2- hydroxyl -4- methoxyl group
Benzophenone, 0.5 part of ultra-violet absorber.
In the present embodiment, the sulfonated acetone formaldehyde polycondensate is obtained by the following method：Sodium sulfite and water are mixed
50 DEG C are warming up to after being slowly added dropwise acetone at being 50 DEG C in temperature after stirring, 1h is incubated, it is slow at being again then 70 DEG C in temperature
90 DEG C are warming up to after formaldehyde is added dropwise, 4h is incubated.
In the present embodiment, the sulfurous acid, formaldehyde, the mol ratio of acetone are：N (sodium sulfite):N (formaldehyde):N (acetone)
=0.8:2.65:1.
In the present embodiment, in the present embodiment, the foam stabilizer is diethyl triamine pentaacetic acid, in the present embodiment, by the second two
Triamine pentaacetic acid part replace with ethylenediamine tetra-acetic acid, N-hydroxyethyl-ethylenediamine triacetic acid according to equivalent weight in one kind, or by same
Diethyl triamine pentaacetic acid and ethylenediamine tetra-acetic acid, the mixture of N-hydroxyethyl-ethylenediamine triacetic acid are replaced with Deng weight portion, gained is produced
Moral character matter has no significant difference.
In the present embodiment, the coupling agent is the mixture of titanate coupling agent and silane coupler.
In the present embodiment, the ultra-violet absorber is benzophenone, in the present embodiment, by the benzophenone according to same
One kind in replacing with salicylate, BTA Deng weight portion, or replace with benzophenone and salicylic acid by equivalent weight part
The mixture of ester, BTA, products obtained therefrom property has no significant difference.
Embodiment three
The thermal-insulation energy-conservation material of the present embodiment, the energy-saving material raw material includes following components by weight：
100 parts, 20-30 parts flyash of Portland cement, 11-18 parts of hydrogen peroxide, 0.5-3 parts of TDE,
0.5-3 parts of sulfonated acetone formaldehyde polycondensate, 1-5 parts of liquid-state epoxy resin dispersant, 1-5 parts of polyurethane, 2-6 parts of foam stabilizer, 3-6
Part coupling agent, 6-12 parts of mullite fiber, ceramic fine bead 1-4 parts, 0.5-2 parts of double (2,2,6,6,-tetramethyl -4- piperidyl) last of the ten Heavenly stems
Two acid esters, 0.1-2 part ESCALOL 567,0.5-2 parts of ultra-violet absorber.
In the present embodiment, the sulfonated acetone formaldehyde polycondensate is obtained by the following method：Sodium sulfite and water are mixed
50 DEG C are warming up to after being slowly added dropwise acetone at being 50 DEG C in temperature after stirring, 1h is incubated, it is slow at being again then 70 DEG C in temperature
90 DEG C are warming up to after formaldehyde is added dropwise, 4h is incubated.
In the present embodiment, the sulfurous acid, formaldehyde, the mol ratio of acetone are：N (sodium sulfite):N (formaldehyde):N (acetone)
=0.8:2.65:1.
In the present embodiment, in the present embodiment, the foam stabilizer is ethylenediamine tetra-acetic acid, in the present embodiment, by the second two
Amine tetraacethyl part replace with diethyl triamine pentaacetic acid, N-hydroxyethyl-ethylenediamine triacetic acid according to equivalent weight in one kind, or by same
Ethylenediamine tetra-acetic acid and diethyl triamine pentaacetic acid, the mixture of N-hydroxyethyl-ethylenediamine triacetic acid are replaced with Deng weight portion, gained is produced
Moral character matter has no significant difference.
In the present embodiment, the coupling agent is the mixture of titanate coupling agent and silane coupler.
In the present embodiment, the ultra-violet absorber is salicylate, in the present embodiment, by the salicylate according to same
One kind in replacing with benzophenone, BTA Deng weight portion, or replace with salicylate and hexichol first by equivalent weight part
The mixture of ketone, BTA, products obtained therefrom property has no significant difference.
Example IV
The thermal-insulation energy-conservation material of the present embodiment, the energy-saving material raw material includes following components by weight：
100 parts, 30 parts flyash of Portland cement, 18 parts of hydrogen peroxide, 3 parts of TDEs, 3 parts of sulfonated acetones
Formaldehyde condensation products, 5 parts of liquid-state epoxy resin dispersants, 5 parts of polyurethane, 6 parts of foam stabilizers, 6 parts of coupling agents, 12 parts of mullite fibres
Dimension, 4 parts of ceramic fine bead, 2 parts of double (2,2,6,6,-tetramethyl -4- piperidyl) sebacate, 2 parts of 2- hydroxyl -4- methoxyl group hexichol
Ketone, 2 parts of ultra-violet absorbers.
In the present embodiment, the sulfonated acetone formaldehyde polycondensate is obtained by the following method：Sodium sulfite and water are mixed
50 DEG C are warming up to after being slowly added dropwise acetone at being 50 DEG C in temperature after stirring, 1h is incubated, it is slow at being again then 70 DEG C in temperature
90 DEG C are warming up to after formaldehyde is added dropwise, 4h is incubated.
In the present embodiment, the sulfurous acid, formaldehyde, the mol ratio of acetone are：N (sodium sulfite):N (formaldehyde):N (acetone)
=0.8:2.65:1.
In the present embodiment, in the present embodiment, the foam stabilizer is N-hydroxyethyl-ethylenediamine triacetic acid, in the present embodiment, will
The ethylenediamine tetra-acetic acid replaces with the one kind in diethyl triamine pentaacetic acid, ethylenediamine tetra-acetic acid according to equivalent weight part, or by same
N-hydroxyethyl-ethylenediamine triacetic acid and diethyl triamine pentaacetic acid, the mixture of ethylenediamine tetra-acetic acid are replaced with Deng weight portion, gained is produced
Moral character matter has no significant difference.
In the present embodiment, the coupling agent is the mixture of titanate coupling agent and silane coupler.
In the present embodiment, the ultra-violet absorber is BTA, in the present embodiment, by the BTA according to same
One kind in replacing with benzophenone, salicylate Deng weight portion, or replace with BTA and hexichol first by equivalent weight part
The mixture of ketone, salicylate, products obtained therefrom property has no significant difference.
Embodiment five
The thermal-insulation energy-conservation material of the present embodiment, the energy-saving material raw material includes following components by weight：
100 parts, 20 parts flyash of Portland cement, 18 parts of hydrogen peroxide, 0.5 part of TDE, 3 parts of sulfonation third
Ketone formaldehyde condensation products, 1 part of liquid-state epoxy resin dispersant, 5 parts of polyurethane, 2 parts of foam stabilizers, 6 parts of coupling agents, 6 parts of mullite fibres
Dimension, 4 parts of ceramic fine bead, 0.5 part of double (2,2,6,6,-tetramethyl -4- piperidyl) sebacate, 2 parts of 2- hydroxyl -4- methoxyl groups two
Benzophenone, 0.5 part of ultra-violet absorber.
In the present embodiment, the sulfonated acetone formaldehyde polycondensate is obtained by the following method：Sodium sulfite and water are mixed
50 DEG C are warming up to after being slowly added dropwise acetone at being 50 DEG C in temperature after stirring, 1h is incubated, it is slow at being again then 70 DEG C in temperature
90 DEG C are warming up to after formaldehyde is added dropwise, 4h is incubated.
In the present embodiment, the sulfurous acid, formaldehyde, the mol ratio of acetone are：N (sodium sulfite):N (formaldehyde):N (acetone)
=0.8:2.65:1.
In the present embodiment, in the present embodiment, the foam stabilizer is ethylenediamine tetra-acetic acid, in the present embodiment, by the second two
Amine tetraacethyl part replace with diethyl triamine pentaacetic acid, N-hydroxyethyl-ethylenediamine triacetic acid according to equivalent weight in one kind, or by same
Ethylenediamine tetra-acetic acid and diethyl triamine pentaacetic acid, the mixture of N-hydroxyethyl-ethylenediamine triacetic acid are replaced with Deng weight portion, gained is produced
Moral character matter has no significant difference.
In the present embodiment, the coupling agent is the mixture of titanate coupling agent and silane coupler, the titanate esters idol
Connection agent is Di(dioctylpyrophosphato) ethylene titanate, two (octyl phenol APEO) phosphides, titanate esters idol
One or more mixtures in connection agent TMC-931, isopropyl three (dioctyl phosphoric acid acyloxy) titanate esters；The silane
Coupling agent is γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-(methacryloxypropyl) propyl trimethoxy silicane, N-
One or more mixtures in (aminoethyls of β mono-)-γ-aminopropyl front three (second) TMOS.
In the present embodiment, the ultra-violet absorber is salicylate, in the present embodiment, by the salicylate according to same
One kind in replacing with benzophenone, BTA Deng weight portion, or replace with salicylate and hexichol first by equivalent weight part
The mixture of ketone, BTA, products obtained therefrom property has no significant difference.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
Good embodiment has been described in detail to the present invention, it will be understood by those within the art that, can be to skill of the invention
Art scheme is modified or equivalent, and without deviating from the objective and scope of technical solution of the present invention, it all should cover at this
In the middle of the right of invention.
Claims (8)
1. a kind of thermal-insulation energy-conservation material, it is characterised in that：The energy-saving material raw material includes following components by weight：
100 parts, 20-30 parts flyash of Portland cement, 11-18 parts of hydrogen peroxide, 0.5-3 parts of TDE, 0.5-3
Part sulfonated acetone formaldehyde polycondensate, 1-5 parts of liquid-state epoxy resin dispersant, 1-5 parts of polyurethane, 2-6 parts of foam stabilizer, 3-6 parts of idol
Connection agent, 6-12 parts of mullite fiber, ceramic fine bead 1-4 parts, 0.5-2 parts of double (2,2,6,6,-tetramethyl -4- piperidyl) decanedioic acid
Ester, 0.1-2 part ESCALOL 567,0.5-2 parts of ultra-violet absorber.
2. thermal-insulation energy-conservation material according to claim 1, it is characterised in that：The energy-saving material raw material is by weight
Including following components：
100 parts, 25 parts flyash of Portland cement, 15 parts of hydrogen peroxide, 2 parts of TDEs, 2 parts of sulfonated acetone formaldehyde
Condensation polymer, 2.5 parts of liquid-state epoxy resin dispersants, 3 parts of polyurethane, 4 portions of foam stabilizers, 5 parts of coupling agents, 10 parts of mullite fibers,
3 parts of ceramic fine bead, 1.5 parts of double (2,2,6,6,-tetramethyl -4- piperidyl) sebacate, 1 part of 2- hydroxyl -4- methoxyl group hexichol
Ketone, 1 part of ultra-violet absorber.
3. thermal-insulation energy-conservation material according to claim 1, it is characterised in that：The sulfonated acetone formaldehyde polycondensate leads to
Following methods are crossed to be obtained：50 are warming up to after being slowly added dropwise acetone at being 50 DEG C in temperature after sodium sulfite and water are mixed
DEG C, 1h is incubated, 90 DEG C are warming up to after being slowly added dropwise formaldehyde at being again then 70 DEG C in temperature, it is incubated 4h.
4. thermal-insulation energy-conservation material according to claim 3, it is characterised in that：The sodium sulfite, formaldehyde, acetone
Mol ratio is：N (sodium sulfite):N (formaldehyde):N (acetone)=0.8:2.65:1.
5. thermal-insulation energy-conservation material according to claim 1, it is characterised in that：The foam stabilizer is ethylenediamine tetrem
One or more mixtures in acid, diethyl triamine pentaacetic acid, N-hydroxyethyl-ethylenediamine triacetic acid.
6. thermal-insulation energy-conservation material according to claim 1, it is characterised in that：The coupling agent is titanate coupling agent
With the mixture of silane coupler.
7. thermal-insulation energy-conservation material according to claim 1, it is characterised in that：The ultra-violet absorber is salicylic acid
One or more mixtures in ester, benzophenone, BTA.
8. a kind of cement plate, it is characterised in that：Thermal-insulation energy-conservation material system as described in claim 1-7 any claims
Into.
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| CN109280368A (en) * | 2018-09-20 | 2019-01-29 | 俞小峰 | A kind of highly effective flame-retardant acoustic material |
| CN114805935A (en) * | 2022-04-20 | 2022-07-29 | 江西永通科技股份有限公司 | Preparation method of composite ultraviolet absorbent |
| CN115196982B (en) * | 2022-08-05 | 2023-03-24 | 江苏华跃特种设备有限公司 | Boiler lining heat-insulating material and preparation method thereof |
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| CN103232208B (en) * | 2013-04-17 | 2014-12-17 | 徐州卧牛山新型防水材料有限公司 | Flame-retardant waterproof material and preparation method thereof |
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