CN103602049A - Flame-retardant resin - Google Patents
Flame-retardant resin Download PDFInfo
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- CN103602049A CN103602049A CN201310547609.6A CN201310547609A CN103602049A CN 103602049 A CN103602049 A CN 103602049A CN 201310547609 A CN201310547609 A CN 201310547609A CN 103602049 A CN103602049 A CN 103602049A
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- flame
- retardant resin
- unsaturated polyester
- resin
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Abstract
The invention discloses flame-retardant resin, belonging to the technical field of high polymer materials. The technical scheme of the invention is as follows: the flame-retardant resin is composed of the following components in parts by weight: 25-60 parts of unsaturated polyester resin, 5-25 parts of glass wool, 2-10 parts of copper naphthenate, 1-5 parts of cobalt iso-octoate, 15-35 parts of calcium carbonate, 1-5 parts of talcum powder, 1-5 parts of polyvinyl fluoride, 6-14 parts of silicon dioxide, 2-12 parts of clay fiber, 2-12 parts of asbestos fiber, 2-10 parts of alumina cellucotton, and 2-6 parts of accelerant. Compared with the prior art, because the flame-retardant resin provided by the invention is low in viscosity and good in infiltrating property, the flame-retardant resin has a good penetration property to various fiber products; moreover, the flame-retardant resin is adjustable in viscosity and long in service life, therefore, the flame-retardant resin can be widely applied to processes of mechanical warping, casting, manual lay-up, mould pressing and the like, and has broad market values and huge market potential.
Description
Technical field
The present invention relates to technical field of polymer materials, relate in particular to a kind of flame-retarded resin.
Background technology
Along with the development of corrosion and protection and improving constantly of industrialization degree, the Application Areas of matrix material is also more and more wider, and applying working condition, medium become increasingly complex, and use temperature is also more and more higher, and market is also more and more higher to the requirement of its performance.
At present, both at home and abroad field adopts high-property resin composite material material more single, mainly take unsaturated polyester, vinyl ester resin, tough epoxy resin material as main, but the equal Shortcomings part in various degree of these materials.As unsaturated polyester, fragility is large, and use temperature is low, and bonding strength is low; Although vinyl ester resin has good toughness, bonding strength is good,, there is the shortcomings such as use temperature is low in the advantages such as toxicity is little after solidifying; Epoxy resin, although there is good toughness, bonding strength advantages of higher, but exist weathering resistance poor, easily efflorescence, viscosity is large, wettability is poor, under comparatively high temps, to bear compared with strong corrosive medium as poor compared with the ability of strong acid, alkali and solvent etc., curing system toxicity is large, the shortcomings such as curing cycle is long, post-treatment expense height.Therefore, traditional matrix material far can not meet the market requirement more and more higher to its performance.
Summary of the invention
The object of the invention is the deficiency existing for prior art, provide that a kind of heat-resistant fireproof, corrosion-resistant, high strength, performance of technical process are good, normal temperature solidified, nontoxicity, flame-retarded resin that bonding strength is high.
The object of the invention is to be achieved through the following technical solutions: a kind of flame-retarded resin, is grouped into by the one-tenth of following weight part: unsaturated polyester resin 25-60 part, glass wool 5-25 part, copper naphthenate 2-10 part, cobalt iso-octoate 1-5 part, calcium carbonate 15-35 part, talcum powder 1-5 part, fluorinated ethylene propylene 1-5 part, silicon-dioxide 6-14 part, carclazyte fiber 2-12 part, fibrous magnesium silicate 2-12 part, the cotton 2-10 part of sapphire whisker, promotor 2-6 part.
Preferably, its each component and weight part are: unsaturated polyester resin 30-45 part, glass wool 10-20 part, copper naphthenate 3-9 part, cobalt iso-octoate 2-4 part, calcium carbonate 20-30 part, talcum powder 2-4 part, fluorinated ethylene propylene 2-4 part, silicon-dioxide 8-12 part, carclazyte fiber 5-10 part, fibrous magnesium silicate 5-10 part, the cotton 3-9 part of sapphire whisker, promotor 3-5 part.
Preferably, its each component and weight part are: 35 parts of unsaturated polyester resins, 15 parts of glass wools, 6 parts of copper naphthenates, 3 parts of cobalt iso-octoates, 25 parts, calcium carbonate, 3 parts of talcum powder, 3 parts of fluorinated ethylene propylenes, 0 part of silica 1,8 parts of carclazyte fibers, 8 parts of fibrous magnesium silicates, cotton 6 parts of sapphire whisker, 4 parts of promotor.
The invention has the beneficial effects as follows: flame-retarded resin provided by the invention compared with prior art, there is heat-resistant fireproof, corrosion-resistant, high strength, performance of technical process good, normal temperature solidified, nontoxicity, bonding strength high, not only technical process is simple, with short production cycle, and in resin building-up process, make full use of the heat that chemical reaction produces, the energy-conservation energy and producing without the three wastes.Flame-retarded resin provided by the present invention is because viscosity is little, wettability is good, therefore various fibre products are had to good penetration, and viscosity is adjustable, can life cycle long, can be widely used in the techniques such as mechanical winding, casting, hand paste, mold pressing, there is marketable value and huge market potential widely.
Embodiment
For clearly demonstrating technical scheme of the present invention, below by several embodiment, the present invention will be further described.
1 one kinds of flame-retarded resins of embodiment, are grouped into by the one-tenth of following weight part: 25 parts of unsaturated polyester resins, 5 parts of glass wools, 2 parts of copper naphthenates, 1 part of cobalt iso-octoate, 15 parts, calcium carbonate, 1 part of talcum powder, 1 part of fluorinated ethylene propylene, 6 parts of silicon-dioxide, 2 parts of carclazyte fibers, 2 parts of fibrous magnesium silicates, cotton 2 parts of sapphire whisker, 2 parts of promotor.
2 one kinds of flame-retarded resins of embodiment, are grouped into by the one-tenth of following weight part: 60 parts of unsaturated polyester resins, 25 parts of glass wools, 10 parts of copper naphthenates, 5 parts of cobalt iso-octoates, 35 parts, calcium carbonate, 5 parts of talcum powder, 5 parts of fluorinated ethylene propylenes, 4 parts of silica 1s, 12 parts of carclazyte fibers, 12 parts of fibrous magnesium silicates, cotton 10 parts of sapphire whisker, 6 parts of promotor.
3 one kinds of flame-retarded resins of embodiment, are grouped into by the one-tenth of following weight part: 30 parts of unsaturated polyester resins, 10 parts of glass wools, 3 parts of copper naphthenates, 2 parts of cobalt iso-octoates, 20 parts, calcium carbonate, 2 parts of talcum powder, 2 parts of fluorinated ethylene propylenes, 8 parts of silicon-dioxide, 5 parts of carclazyte fibers, 5 parts of fibrous magnesium silicates, cotton 3 parts of sapphire whisker, 3 parts of promotor.
4 one kinds of flame-retarded resins of embodiment, are grouped into by the one-tenth of following weight part: 45 parts of unsaturated polyester resins, 20 parts of glass wools, 9 parts of copper naphthenates, 4 parts of cobalt iso-octoates, 30 parts, calcium carbonate, 4 parts of talcum powder, 4 parts of fluorinated ethylene propylenes, 2 parts of silica 1s, 10 parts of carclazyte fibers, 10 parts of fibrous magnesium silicates, cotton 9 parts of sapphire whisker, 5 parts of promotor.
5 one kinds of flame-retarded resins of embodiment, are grouped into by the one-tenth of following weight part: 35 parts of unsaturated polyester resins, 15 parts of glass wools, 6 parts of copper naphthenates, 3 parts of cobalt iso-octoates, 25 parts, calcium carbonate, 3 parts of talcum powder, 3 parts of fluorinated ethylene propylenes, 0 part of silica 1,8 parts of carclazyte fibers, 8 parts of fibrous magnesium silicates, cotton 6 parts of sapphire whisker, 4 parts of promotor.
Flame-retarded resin provided by the invention compared with prior art, there is heat-resistant fireproof, corrosion-resistant, high strength, performance of technical process good, normal temperature solidified, nontoxicity, bonding strength high, not only technical process is simple, with short production cycle, and in resin building-up process, make full use of the heat that chemical reaction produces, the energy-conservation energy and producing without the three wastes.Flame-retarded resin provided by the present invention is because viscosity is little, wettability is good, therefore various fibre products are had to good penetration, and viscosity is adjustable, can life cycle long, can be widely used in the techniques such as mechanical winding, casting, hand paste, mold pressing, there is marketable value and huge market potential widely.
Disclosed is above only a preferred embodiment of the present invention; but be not limited to the present invention; within the spirit and principles in the present invention all; the modification of doing, polish, be equal to replacement etc.; within all should being included in protection scope of the present invention; in addition, the present invention does not describe part in detail, is those skilled in the art of the present technique's known technology.
Claims (3)
1. a flame-retarded resin, it is characterized in that: the one-tenth by following weight part is grouped into unsaturated polyester resin 25-60 part, glass wool 5-25 part, copper naphthenate 2-10 part, cobalt iso-octoate 1-5 part, calcium carbonate 15-35 part, talcum powder 1-5 part, fluorinated ethylene propylene 1-5 part, silicon-dioxide 6-14 part, carclazyte fiber 2-12 part, fibrous magnesium silicate 2-12 part, the cotton 2-10 part of sapphire whisker, promotor 2-6 part.
2. a kind of flame-retarded resin according to claim 1, it is characterized in that: the one-tenth by following weight part is grouped into unsaturated polyester resin 30-45 part, glass wool 10-20 part, copper naphthenate 3-9 part, cobalt iso-octoate 2-4 part, calcium carbonate 20-30 part, talcum powder 2-4 part, fluorinated ethylene propylene 2-4 part, silicon-dioxide 8-12 part, carclazyte fiber 5-10 part, fibrous magnesium silicate 5-10 part, the cotton 3-9 part of sapphire whisker, promotor 3-5 part.
3. a kind of flame-retarded resin according to claim 1, it is characterized in that: the one-tenth by following weight part is grouped into 35 parts of unsaturated polyester resins, 15 parts of glass wools, 6 parts of copper naphthenates, 3 parts of cobalt iso-octoates, 25 parts, calcium carbonate, 3 parts of talcum powder, 3 parts of fluorinated ethylene propylenes, 0 part of silica 1,8 parts of carclazyte fibers, 8 parts of fibrous magnesium silicates, cotton 6 parts of sapphire whisker, 4 parts of promotor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310547609.6A CN103602049A (en) | 2013-10-30 | 2013-10-30 | Flame-retardant resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310547609.6A CN103602049A (en) | 2013-10-30 | 2013-10-30 | Flame-retardant resin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103602049A true CN103602049A (en) | 2014-02-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310547609.6A Pending CN103602049A (en) | 2013-10-30 | 2013-10-30 | Flame-retardant resin |
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| CN (1) | CN103602049A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647097A (en) * | 2016-04-12 | 2016-06-08 | 无锡南理工科技发展有限公司 | Flame-retardant resin |
| CN109135519A (en) * | 2018-07-09 | 2019-01-04 | 黄山市华圣新材料有限公司 | A kind of polyester resin for powdery paints and preparation method thereof and preparation facilities |
| CN109337285A (en) * | 2018-10-12 | 2019-02-15 | 湖南省建新建材有限公司 | A kind of fire-proof and thermal-insulation resin tile and preparation method thereof |
| CN110646903A (en) * | 2019-09-10 | 2020-01-03 | 安徽省通信产业服务有限公司 | Preparation method of reinforced heat-resistant optical cable material filler |
-
2013
- 2013-10-30 CN CN201310547609.6A patent/CN103602049A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105647097A (en) * | 2016-04-12 | 2016-06-08 | 无锡南理工科技发展有限公司 | Flame-retardant resin |
| CN109135519A (en) * | 2018-07-09 | 2019-01-04 | 黄山市华圣新材料有限公司 | A kind of polyester resin for powdery paints and preparation method thereof and preparation facilities |
| CN109135519B (en) * | 2018-07-09 | 2021-01-05 | 黄山市华圣新材料有限公司 | Polyester resin for powder coating and preparation method and preparation device thereof |
| CN109337285A (en) * | 2018-10-12 | 2019-02-15 | 湖南省建新建材有限公司 | A kind of fire-proof and thermal-insulation resin tile and preparation method thereof |
| CN110646903A (en) * | 2019-09-10 | 2020-01-03 | 安徽省通信产业服务有限公司 | Preparation method of reinforced heat-resistant optical cable material filler |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140226 |