CN110408473A - A kind of preparation method of air conditioner cleaning agent - Google Patents
A kind of preparation method of air conditioner cleaning agent Download PDFInfo
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- CN110408473A CN110408473A CN201910505994.5A CN201910505994A CN110408473A CN 110408473 A CN110408473 A CN 110408473A CN 201910505994 A CN201910505994 A CN 201910505994A CN 110408473 A CN110408473 A CN 110408473A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
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- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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Abstract
The present invention relates to a kind of preparation methods of air conditioner cleaning agent, belong to cleaning air conditioner technical field.The present invention passes through using using mixture as base-material, lipid material therein is obtained by boiling and Steam explosion treatment, phenols, alcohols material, and utilize additive, under the action of the effect of auxiliary agent, part phenolic substances therein is set to carry out dehydrogenation polymerization, and pass through the adjustable peculiar smell generated in the process of cleaning of dehydrogenation polymerization, effectively it is attached to air-conditioning surface, form one layer of smell adjusting film, the ionic liquid being added simultaneously can make ion therein be dispersed in its surface well, when in use, cleaning agent rapid osmotic can be made to spread by the alcohol lipid material of extraction, and protective film can be effectively formed on its surface using microemulsion therein, smell can be effectively adjusted using polymer therein, increase the release of wherein anion by the attachment of ion, improve the treatment effect to wherein pollutant.
Description
Technical field
The present invention relates to a kind of preparation methods of air conditioner cleaning agent, belong to cleaning air conditioner technical field.
Background technique
In cleaning air conditioner industry, to the scale of air-conditioning system fan coil, air-conditioning box, blower fan group etc., oxide skin, rust staining,
When dust and bacterium carry out cleaning and sterilizing, generally single unit is operated, and is first cleaned, then scale removal, rear to sterilize.Existing cleaning agent
Can be single, cleaning can not be reached simultaneously, go the effect of dirt, antibacterial, disinfection, degerming.
In the prior art, Chinese patent CN101544930B discloses a kind of air conditioner fin cleaning agent and its preparation side
Method, the cleaning agent are mainly mixed by each component of following weight percent with water: nitric acid 10-15%, potassium chromate
0.5-0.8%, ethoxylated alkyl sulfate 0.5-0.8%, octyl phenol polyoxyethylene ether 0.1-0.5%, the half of water withdrawal,
Nitric acid is added, stirs evenly, obtains aqueous solution a；The other half water is taken, potassium chromate, ethoxylated alkyl sulfate, octyl are sequentially added
Phenol polyethenoxy ether is sufficiently stirred, and until solid particulate matter is dissolved, obtains aqueous solution b；The aqueous solution a stirred evenly is slow
Slowly be added in aqueous solution b, be stirred well to uniformly to get finished product, cleaning, energy-saving effect it is good and to equipment surface substantially
Corrosion-free influence；Chinese patent CN101492824 discloses a kind of air conditioner fin cleaning agent, the air conditioner fin cleaning agent each group
Divide and its mass parts ratio is as follows: 50% 3-5 parts of nitric acid, 75% 1-2 parts of citric acid, 65% 1-2 parts of oxalic acid, methenamine
6-24 parts, 10-45 parts of aniline, 3 parts of alkyl polyglycoside, 2-4 parts of alkyl polyoxyethylene ether, 1-3 parts of straight chain alkyl sulfonates, carboxyl fibre
Tie up 20-45 part of plain sodium and 3000 parts of water, when use only needs the cleaning that just can reach 99% or more in 1-2 minutes using spray clean
Degree；Chinese patent CN101475878 discloses a kind of air conditioner cleaning agent and cleaning method, and raw material contained by cleaning agent is lemon
Acid, inorganic weak acid, at least two in inorganic acid, nonionic surfactant or nonionic surfactant and anion table
Face activating agent compounding, oxo solvent, acid inhibitor, water surplus.Cleaning method is to dismantle motor and fan and remove individually clearly
It washes, cleaning agent is made into aqueous solution by 10~15%, and the air-conditioning of dismantle motor and fan is integrally hung in rinse bath, is soaked under room temperature
Bubble 30 minutes is opened ultrasonic cleaning 10-30 minutes, air-conditioning is integrally placed at rinsing bowl, with giant hydro-peening air-conditioning surface
And inside, 80 DEG C of hot-air seasonings, although the cleaning effect of these three detergents is preferable, preparation process is complicated and without antibacterial
Degerming disinfection efficacy.
Summary of the invention
The technical problems to be solved by the invention: the big, antibacterial for taste in current air conditioning for automobiles cleaning agent use process
Property difference problem, the present invention provides a kind of preparation methods of air conditioner cleaning agent.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of preparation method of air conditioner cleaning agent, the preparation method include the following steps:
(1) it takes mixture, water 1:5~8 in mass ratio to be mixed, heats, be cooled to room temperature, add water quality 30~40%
Dehydrated alcohol, stir evenly, carry out steam blasting, filtering, collect filtrate, decoloration, collect destainer；
(2) by destainer, mixed liquor, 3~5:8 is mixed by volume, is put into reactor, and destainer quality 40 is added
~45% additive and the auxiliary agent of destainer quality 15~18% heat up, stirring, collect stirring mixture；
(3) according to parts by weight, 100~150 parts of water, 40~50 parts of stirring mixtures, 16~19 parts of paraffin, 2~5 parts of additions are taken
Liquid, 3~6 parts of surfactants, 1~5 part of Ar ion mixing liquid and 0.8~1.8 part of lauric monoglyceride；
(4) water, stirring mixture, paraffin, annex solution are subjected to Hybrid Heating first, add surfactant, Ar ion mixing
Liquid and Glycerol Monolaurate are mixed, and pH is adjusted, and are concentrated under reduced pressure to get air conditioner cleaning agent.
Mixture is uniformly mixed in the step (1) for basyleaves, cork and orange peel 3~6:2 in mass ratio~4:7,
It dry, pulverize, collect pulverized particles to get mixture.
In the step (2) mixed liquor be ethanol solution, phosphate buffered saline solution 6~9:2 in mass ratio~4 mixing and
At.
Additive is isoamyl acetate in the step (2), isoeugenol 2:1~4 in mass ratio are mixed.
Auxiliary agent is chitosan in the step (2), agglutinin 4:1~2 in mass ratio are mixed.
The surfactant is dodecyl benzene sulfonic acid, any one in lauryl sodium sulfate.
The annex solution is to mix sodium acetate, ethanol solution 1:4~6 in mass ratio.
The Ar ion mixing liquid the preparation method comprises the following steps:
A. silicate fluoride solution, additive, calcium oxide 13:1~2:8 in mass ratio are subjected to ultrasonic vibration, are heated at 80~90 DEG C,
The water for adding 4~6 times of additive quality is warming up to 120~130 DEG C, heat preservation；
B. it after heat preservation, is cooled to room temperature, stands, discharge, filter, it is dry, dried object is collected, dried object is forged
It burns, crushes, sieving particle is collected in sieving, sieving particle, hydrochloric acid solution and auxiliary material 5:8~12:3 in mass ratio is mixed, i.e.,
Obtain Ar ion mixing liquid.
Additive is titanium tetrachloride in the step A, butyl titanate 7:3 in mass ratio is mixed.
Auxiliary particle is tourmaline powder in the step B.
The present invention is compared with other methods, and advantageous effects are:
The present invention by utilizing using mixture as base-material, by boiling and Steam explosion treatment acquisition lipid material therein,
Phenols, alcohols material, and part phenolic substances therein is taken off under the action of the effect of auxiliary agent using additive
Hydrogen polymerization, and by the adjustable peculiar smell generated in the process of cleaning of dehydrogenation polymerization, effectively it is attached to air-conditioning surface, shape
At one layer of smell adjusting film, secondly wherein the effect of auxiliary agent can increase antibacterial effect, then by utilizing surfactant pair
Paraffin acts on forming microemulsion, while the Ar ion mixing liquid being added can make ion therein be dispersed in its surface, In well
Cleaning agent rapid osmotic can be made to spread in use, passing through the alcohol lipid material extracted, remove dirt, while also had centainly
Antibacterial effect, and it can be effectively formed on its surface protective film using microemulsion therein, it can using polymer therein
Effectively to adjust smell, increase the release of wherein anion by the attachment of ion, improves the treatment effect to wherein pollutant.
Specific embodiment
Mixture is uniformly mixed for basyleaves, cork and orange peel 3~6:2 in mass ratio~4:7, dry, pulverize, and collects
Pulverized particles are to get mixture.
Mixed liquor is ethanol solution, pH is that 5.0 phosphate buffered saline solutions, 6~9:2~4 in mass ratio mix.
Additive is isoamyl acetate, isoeugenol 2:1~4 in mass ratio are mixed.
Auxiliary agent is chitosan, agglutinin 4:1~2 in mass ratio are mixed.
Surfactant is dodecyl benzene sulfonic acid, any one in lauryl sodium sulfate.
Annex solution is to mix sodium acetate, ethanol solution 1:4~6 in mass ratio.
Additive is titanium tetrachloride, butyl titanate 7:3 in mass ratio is mixed.
Auxiliary particle is tourmaline powder.
Ar ion mixing liquid the preparation method comprises the following steps:
A. silicate fluoride solution, additive, calcium oxide 13:1~2:8 in mass ratio are subjected to ultrasonic vibration 20min, at 80~90 DEG C
2h is heated, 4~6 times of additive quality of water is added, is warming up to 120~130 DEG C, keeps the temperature 3h；
B. it after heat preservation, is cooled to room temperature, stands 1h, discharge, filter, it is dry, dried object is collected, by dried object 600
DEG C carry out calcining 2h, crush, cross 500 meshes, collect sieving particle, will sieving particle, hydrochloric acid solution and auxiliary material in mass ratio
5:8~12:3 mixes to get Ar ion mixing liquid.
A kind of preparation method of air conditioner cleaning agent, the preparation method include the following steps:
(1) it takes mixture, water 1:5~8 in mass ratio to be mixed, in 100~105 DEG C of heating 2h, is cooled to room temperature, adds
The dehydrated alcohol of water quality 30~40%, stirs evenly, and carries out steam blasting, sets pressure as 1.6~1.9MPa, maintains pressure
80s is collected explosion object and is filtered, collected filtrate, decolourized using active carbon, collects destainer；
(2) by destainer, mixed liquor, 3~5:8 is mixed by volume, is put into reactor, and destainer quality 40 is added
~45% additive and the auxiliary agent of destainer quality 15~18% are warming up to 80~90 DEG C, stir 3h, and collection is stirred
Object；
(3) according to parts by weight, 100~150 parts of water, 40~50 parts of stirring mixtures, 16~19 parts of paraffin, 2~5 parts of additions are taken
Liquid, 3~6 parts of surfactants, 1~5 part of Ar ion mixing liquid and 0.8~1.8 part of lauric monoglyceride；
(4) water, stirring mixture, paraffin, annex solution are mixed first, in 70 DEG C of 2~4h of heating, adds surface-active
Agent, Ar ion mixing liquid and Glycerol Monolaurate are mixed, and mixing liquid is collected, and are adjusted pH to 6.5~7.0, are concentrated under reduced pressure into
The 70~80% of mixing liquid volume are to get air conditioner cleaning agent.
Embodiment 1
Mixture is uniformly mixed for basyleaves, cork and orange peel 6:4:7 in mass ratio, dry, pulverize, and collects pulverized particles,
Up to mixture.
Mixed liquor is ethanol solution, pH is that 5.0 phosphate buffered saline solutions 9:4 in mass ratio is mixed.
Additive is isoamyl acetate, isoeugenol 2:4 in mass ratio is mixed.
Auxiliary agent is chitosan, agglutinin 4:2 in mass ratio is mixed.
Surfactant is dodecyl benzene sulfonic acid.
Annex solution is to mix sodium acetate, ethanol solution 1:6 in mass ratio.
Additive is titanium tetrachloride, butyl titanate 7:3 in mass ratio is mixed.
Auxiliary particle is tourmaline powder.
Ar ion mixing liquid the preparation method comprises the following steps:
A. silicate fluoride solution, additive, calcium oxide 13:1:8 in mass ratio are subjected to ultrasonic vibration 20min, in 80 DEG C of heating 2h,
The water for adding 4 times of additive quality is warming up to 120 DEG C, keeps the temperature 3h；
B. it after heat preservation, is cooled to room temperature, stands 1h, discharge, filter, it is dry, dried object is collected, by dried object 600
DEG C carry out calcining 2h, crush, cross 500 meshes, collect sieving particle, will sieving particle, hydrochloric acid solution and auxiliary material in mass ratio
5:8:3 mixes to get Ar ion mixing liquid.
A kind of preparation method of air conditioner cleaning agent, the preparation method include the following steps:
(1) it takes mixture, water 1:8 in mass ratio to be mixed, in 105 DEG C of heating 2h, is cooled to room temperature, adds water quality
40% dehydrated alcohol, stirs evenly, and carries out steam blasting, sets pressure as 1.9MPa, maintains pressure 80s, collects explosion object
It is filtered, collects filtrate, decolourized using active carbon, collect destainer；
(2) by destainer, mixed liquor, 5:8 is mixed by volume, is put into reactor, and destainer quality 45% is added
The auxiliary agent of additive and destainer quality 18% is warming up to 90 DEG C, stirs 3h, collects stirring mixture；
(3) according to parts by weight, 150 parts of water, 50 parts of stirring mixtures, 19 parts of paraffin, 5 parts of annex solutions, 6 parts of surface-actives are taken
Agent, 5 parts of Ar ion mixing liquid and 1.8 parts of lauric monoglycerides；
(4) water, stirring mixture, paraffin, annex solution are mixed first, in 70 DEG C of heating 4h, add surfactant,
Ar ion mixing liquid and Glycerol Monolaurate are mixed, and mixing liquid is collected, and are adjusted pH to 7.0, are concentrated under reduced pressure into mixing liquid
The 80% of volume is to get air conditioner cleaning agent.
Embodiment 2
Mixture is uniformly mixed for basyleaves, cork and orange peel 5:3:7 in mass ratio, dry, pulverize, and collects pulverized particles,
Up to mixture.
Mixed liquor is ethanol solution, pH is that 5.0 phosphate buffered saline solutions 8:3 in mass ratio is mixed.
Additive is isoamyl acetate, isoeugenol 2:3 in mass ratio is mixed.
Auxiliary agent is chitosan, agglutinin 4:1.5 in mass ratio is mixed.
Surfactant is lauryl sodium sulfate.
Annex solution is to mix sodium acetate, ethanol solution 1:5 in mass ratio.
Additive is titanium tetrachloride, butyl titanate 7:3 in mass ratio is mixed.
Auxiliary particle is tourmaline powder.
Ar ion mixing liquid the preparation method comprises the following steps:
A. silicate fluoride solution, additive, calcium oxide 13:1.5:8 in mass ratio are subjected to ultrasonic vibration 20min, are heated at 85 DEG C
2h adds 5 times of additive quality of water, is warming up to 125 DEG C, keeps the temperature 3h；
B. it after heat preservation, is cooled to room temperature, stands 1h, discharge, filter, it is dry, dried object is collected, by dried object 600
DEG C carry out calcining 2h, crush, cross 500 meshes, collect sieving particle, will sieving particle, hydrochloric acid solution and auxiliary material in mass ratio
5:10:3 mixes to get Ar ion mixing liquid.
A kind of preparation method of air conditioner cleaning agent, the preparation method include the following steps:
(1) it takes mixture, water 1:7 in mass ratio to be mixed, in 103 DEG C of heating 2h, is cooled to room temperature, adds water quality
35% dehydrated alcohol, stirs evenly, and carries out steam blasting, sets pressure as 1.8MPa, maintains pressure 80s, collects explosion object
It is filtered, collects filtrate, decolourized using active carbon, collect destainer；
(2) by destainer, mixed liquor, 4:8 is mixed by volume, is put into reactor, and destainer quality 43% is added
The auxiliary agent of additive and destainer quality 16% is warming up to 85 DEG C, stirs 3h, collects stirring mixture；
(3) according to parts by weight, 130 parts of water, 45 parts of stirring mixtures, 18 parts of paraffin, 4 parts of annex solutions, 4 parts of surface-actives are taken
Agent, 3 parts of Ar ion mixing liquid and 1.2 parts of lauric monoglycerides；
(4) water, stirring mixture, paraffin, annex solution are mixed first, in 70 DEG C of heating 3h, add surfactant,
Ar ion mixing liquid and Glycerol Monolaurate are mixed, and mixing liquid is collected, and are adjusted pH to 6.5, are concentrated under reduced pressure into mixing liquid
The 70% of volume is to get air conditioner cleaning agent.
Embodiment 3
Mixture is uniformly mixed for basyleaves, cork and orange peel 3:2:7 in mass ratio, dry, pulverize, and collects pulverized particles,
Up to mixture.
Mixed liquor is ethanol solution, pH is that 5.0 phosphate buffered saline solutions 6:2 in mass ratio is mixed.
Additive is isoamyl acetate, isoeugenol 2:1 in mass ratio is mixed.
Auxiliary agent is chitosan, agglutinin 4:1 in mass ratio is mixed.
Surfactant is dodecyl benzene sulfonic acid.
Annex solution is to mix sodium acetate, ethanol solution 1:6 in mass ratio.
Additive is titanium tetrachloride, butyl titanate 7:3 in mass ratio is mixed.
Auxiliary particle is tourmaline powder.
Ar ion mixing liquid the preparation method comprises the following steps:
A. silicate fluoride solution, additive, calcium oxide 13:2:8 in mass ratio are subjected to ultrasonic vibration 20min, in 90 DEG C of heating 2h,
The water for adding 6 times of additive quality is warming up to 130 DEG C, keeps the temperature 3h；
B. it after heat preservation, is cooled to room temperature, stands 1h, discharge, filter, it is dry, dried object is collected, by dried object 600
DEG C carry out calcining 2h, crush, cross 500 meshes, collect sieving particle, will sieving particle, hydrochloric acid solution and auxiliary material in mass ratio
5:12:3 mixes to get Ar ion mixing liquid.
A kind of preparation method of air conditioner cleaning agent, the preparation method include the following steps:
(1) it takes mixture, water 1:5 in mass ratio to be mixed, in 100 DEG C of heating 2h, is cooled to room temperature, adds water quality
30% dehydrated alcohol, stirs evenly, and carries out steam blasting, sets pressure as 1.6MPa, maintains pressure 80s, collects explosion object
It is filtered, collects filtrate, decolourized using active carbon, collect destainer；
(2) by destainer, mixed liquor, 3:8 is mixed by volume, is put into reactor, and destainer quality 40% is added
The auxiliary agent of additive and destainer quality 15% is warming up to 80 DEG C, stirs 3h, collects stirring mixture；
(3) according to parts by weight, 100 parts of water, 40 parts of stirring mixtures, 16 parts of paraffin, 2 parts of annex solutions, 3 parts of surface-actives are taken
Agent, 1 part of Ar ion mixing liquid and 0.8 part of lauric monoglyceride；
(4) water, stirring mixture, paraffin, annex solution are mixed first, in 70 DEG C of heating 2h, add surfactant,
Ar ion mixing liquid and Glycerol Monolaurate are mixed, and mixing liquid is collected, and are adjusted pH to 6.5, are concentrated under reduced pressure into mixing liquid
The 70% of volume is to get air conditioner cleaning agent.
Comparative example 1
Mixture is uniformly mixed for basyleaves, cork and orange peel 5:3:7 in mass ratio, dry, pulverize, and collects pulverized particles,
Up to mixture.
Mixed liquor is ethanol solution, pH is that 5.0 phosphate buffered saline solutions 8:3 in mass ratio is mixed.
Additive is isoamyl acetate, isoeugenol 2:3 in mass ratio is mixed.
Auxiliary agent is chitosan, agglutinin 4:1.5 in mass ratio is mixed.
Surfactant is lauryl sodium sulfate.
Annex solution is to mix sodium acetate, ethanol solution 1:5 in mass ratio.
A kind of preparation method of air conditioner cleaning agent, the preparation method include the following steps:
(1) it takes mixture, water 1:7 in mass ratio to be mixed, in 103 DEG C of heating 2h, is cooled to room temperature, adds water quality
35% dehydrated alcohol, stirs evenly, and carries out steam blasting, sets pressure as 1.8MPa, maintains pressure 80s, collects explosion object
It is filtered, collects filtrate, decolourized using active carbon, collect destainer；
(2) by destainer, mixed liquor, 4:8 is mixed by volume, is put into reactor, and destainer quality 43% is added
The auxiliary agent of additive and destainer quality 16% is warming up to 85 DEG C, stirs 3h, collects stirring mixture；
(3) according to parts by weight, 130 parts of water, 45 parts of stirring mixtures, 18 parts of paraffin, 4 parts of annex solutions, 4 parts of surfactants are taken
And 1.2 parts of lauric monoglycerides；
(4) water, stirring mixture, paraffin, annex solution are mixed first, in 70 DEG C of heating 3h, adds surfactant
And Glycerol Monolaurate is mixed, and mixing liquid is collected, and is adjusted pH to 6.5, is concentrated under reduced pressure into the 70% of mixing liquid volume,
Up to air conditioner cleaning agent.
Comparative example 2: the air conditioner cleaning agent of Shanghai City company production.
The air conditioner cleaning agent that above-described embodiment is obtained with comparative example is detected, degerming performance detection: according to according to health
Portion's " disinfection technology standard " (version in 2002) tests；Corrosivity monitor: LY12 duralumin is used, according to " QB/T 2117-
1995 general water-base metal detergents " it is detected, obtain that the results are shown in Table 1.
Table 1:
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
| Escherichia coli/% | 99.9 | 99.8 | 99.8 | 932 | 83.2 |
| Staphylococcus aureus/% | 99.9 | 99.5 | 99.7 | 95.6 | 85.6 |
| Candida albicans/% | 99.9 | 99.3 | 99.6 | 94.6 | 89.2 |
| There is free from extraneous odour | Nothing | Nothing | Nothing | It is slight pungent | It is slight pungent |
| Corrosivity/mg | 0.1 | 0.3 | 0.2 | 0.8 | 1.8 |
In summary, air conditioner cleaning agent effect of the invention is more preferable as can be seen from Table 1, is worth of widely use, it is described above only
For preferred mode of the invention, it is not intended to limit the invention, it is all within the spirits and principles of the present invention, made any to repair
Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (10)
1. a kind of preparation method of air conditioner cleaning agent, which is characterized in that the preparation method includes the following steps:
(1) it takes mixture, water 1:5~8 in mass ratio to be mixed, heats, be cooled to room temperature, add water quality 30~40%
Dehydrated alcohol, stir evenly, carry out steam blasting, filtering, collect filtrate, decoloration, collect destainer；
(2) by destainer, mixed liquor, 3~5:8 is mixed by volume, is put into reactor, and destainer quality 40 is added
~45% additive and the auxiliary agent of destainer quality 15~18% heat up, stirring, collect stirring mixture；
(3) according to parts by weight, 100~150 parts of water, 40~50 parts of stirring mixtures, 16~19 parts of paraffin, 2~5 parts of additions are taken
Liquid, 3~6 parts of surfactants, 1~5 part of Ar ion mixing liquid and 0.8~1.8 part of lauric monoglyceride；
(4) first by water, stirring mixture, paraffin, annex solution carry out Hybrid Heating, add surfactant, ionic liquid and
Glycerol Monolaurate is mixed, and pH is adjusted, and is concentrated under reduced pressure to get air conditioner cleaning agent.
2. the preparation method of air conditioner cleaning agent according to claim 1, which is characterized in that mixture is in the step (1)
Basyleaves, cork and orange peel 3~6:2 in mass ratio~4:7 are uniformly mixed, and dry, pulverize, and collect pulverized particles to get mixed
Close object.
3. the preparation method of air conditioner cleaning agent according to claim 1, which is characterized in that mixed liquor is in the step (2)
Ethanol solution, phosphate buffered saline solution 6~9:2~4 in mass ratio mix.
4. the preparation method of air conditioner cleaning agent according to claim 1, which is characterized in that additive is in the step (2)
Isoamyl acetate, isoeugenol 2:1~4 in mass ratio are mixed.
5. the preparation method of air conditioner cleaning agent according to claim 1, which is characterized in that auxiliary agent is shell in the step (2)
Glycan, agglutinin 4:1~2 in mass ratio are mixed.
6. the preparation method of air conditioner cleaning agent according to claim 1, which is characterized in that the surfactant is dodecane
Any one in base benzene sulfonic acid, lauryl sodium sulfate.
7. the preparation method of air conditioner cleaning agent according to claim 1, which is characterized in that the annex solution be by sodium acetate,
Ethanol solution 1:4~6 in mass ratio mix.
8. the preparation method of air conditioner cleaning agent according to claim 1, which is characterized in that the preparation side of the Ar ion mixing liquid
Method are as follows:
A. silicate fluoride solution, additive, calcium oxide 13:1~2:8 in mass ratio are subjected to ultrasonic vibration, are heated at 80~90 DEG C,
The water for adding 4~6 times of additive quality is warming up to 120~130 DEG C, heat preservation；
B. it after heat preservation, is cooled to room temperature, stands, discharge, filter, it is dry, dried object is collected, dried object is forged
It burns, crushes, sieving particle is collected in sieving, sieving particle, hydrochloric acid solution and auxiliary material 5:8~12:3 in mass ratio is mixed, i.e.,
Obtain Ar ion mixing liquid.
9. the preparation method of air conditioner cleaning agent according to claim 8, which is characterized in that additive is four in the step A
Titanium chloride, butyl titanate 7:3 in mass ratio are mixed.
10. the preparation method of air conditioner cleaning agent according to claim 8, which is characterized in that auxiliary particle is in the step B
Tourmaline powder.
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Application publication date: 20191105 |