CN101381878A - Process for rapidly cleaning surface of nickel-coated billet cake - Google Patents

Process for rapidly cleaning surface of nickel-coated billet cake Download PDF

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Publication number
CN101381878A
CN101381878A CNA2008102015913A CN200810201591A CN101381878A CN 101381878 A CN101381878 A CN 101381878A CN A2008102015913 A CNA2008102015913 A CN A2008102015913A CN 200810201591 A CN200810201591 A CN 200810201591A CN 101381878 A CN101381878 A CN 101381878A
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China
Prior art keywords
cleaning
cake
nickel
clean
washing composition
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Application number
CNA2008102015913A
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Chinese (zh)
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CN101381878B (en
Inventor
史佳德
徐岷
崔培毅
徐兵
王振明
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Shanghai Mint Co ltd
China Banknote Printing and Minting Group Co Ltd
Original Assignee
SHANGHAI COINAGE CO Ltd
China Banknote Printing and Minting Corp
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Application filed by SHANGHAI COINAGE CO Ltd, China Banknote Printing and Minting Corp filed Critical SHANGHAI COINAGE CO Ltd
Priority to CN2008102015913A priority Critical patent/CN101381878B/en
Publication of CN101381878A publication Critical patent/CN101381878A/en
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Publication of CN101381878B publication Critical patent/CN101381878B/en
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Abstract

The invention discloses a process for quickly cleaning the surface of a nickel coated steel bollet. The process is characterized by comprising the following steps: putting the nickel coated steel billet in a cleaning agent consisting of a cleaning agent A, a cleaning agent B, alcohol, a WA dehydrating agent and water, wherein the cleaning agent A consists of sodium stearate, sodium oleate, polyoxyethylene nonyl phenyl ether, sodium silicate, borax and alkylolamide, and the cleaning agent B consists of trimeric sodium phosphate, AEO9, sodium alkyl benzene sulfonate and glauber salt; and producing a clean billet cake by rinsing by deionized water, blowing by compressed air and drying by hot air. The process replaces the prior acid cleaning process, can quickly remove oil stains and nickel scraps on the surface of the billet, so the clean surface of the billet can be directly stamped so as to improve the lustrousness and appearance quality of the surface of the billet, and further reduce the labor intensity and production cost.

Description

Process for rapidly cleaning surface of nickel-coated billet cake
Technical field
The present invention relates to coin manufacturing technology field, specifically a kind of process for rapidly cleaning surface of nickel-coated billet cake.
Background technology
At present, increase the base cake in the coin manufacturing and rolled word technology, in rolling the word production process, base cake edge is squeezed, and the metallic nickel plated layer of coin blank cake can come off on a small quantity, be subjected to secondary pollution in the base cake course of processing simultaneously, make base cake surface have a small amount of rubbish, nickel bits and greasy dirt, directly impress, then can cause the quality problems of the sticking nickel of impression as the base cake, existing manufacturing technique is rolling word after pickling, alkali cleaning and rinsing, to reach the purpose of base cake cleaning surfaces.Because acid cleaning process, equipment are more outmoded, there is potential safety hazard in operator's working strength, especially manual operation than higher during operation, the difficult control of processing parameter, cause quality product fluctuation bigger, and bronsted lowry acids and bases bronsted lowry all has corrosive nature to base cake surface, reduced the work-ing life of base cake, the base cake is after overpickling simultaneously, surface gloss reduces, and makes the base cake surface obfuscation behind the impression, influences base cake surface quality.
Summary of the invention
A kind of process for rapidly cleaning surface of nickel-coated billet cake of providing at the deficiencies in the prior art is provided, adopt the cleaning of soapless soap to replace former pickling technology, it can Rapid Cleaning remove rubbish, greasy dirt and the nickel bits on base cake surface, base cake cleaning surfaces can directly be impressed, glossiness, visual appearance and the work-ing life on base cake surface have been improved, it is convenient to have production of detergents, and cleaning is simple, greatly reduces labour intensity and production cost.
The concrete technical scheme that realizes the object of the invention is: a kind of process for rapidly cleaning surface of nickel-coated billet cake, characteristics are nickel-coated billet cake to be put in the washings clean, clean after rinsed with deionized water, pressurized air vibration are blown down, warm air drying becomes cleaning base cake, wherein: washings is mixed by washing composition A, washing composition B, alcohol, WA dewatering agent, water, is specifically undertaken by following step:
(1), preparation washings
A. press following component mixed preparing washing composition A, described substances in percentage by weight meter:
Sodium stearate: 14-18%
Sodium oleate: 14-18%
Polyoxyethylene nonylphenol ether: 13-17%
Water glass: 6-10%
Sodium sulfate: 10-14%
Yellow soda ash: 8-12%
Borax: 6-10%
Alkylol amide: 13-17%
B. press following component mixed preparing washing composition B, described substances in percentage by weight meter:
Tripoly phosphate sodium STPP: 35-45%
AEO 9[C 12Aliphatic alcohol polyethenoxy (9) ether]: 5-15%
Linear alkylbenzene sulphonic acid: 20-30%
Saltcake: 20-30%
C. getting above-mentioned washing composition A, washing composition B, 90% alcohol, WA dewatering agent, water Hybrid Heating, to become temperature be 60 ℃ washings, and its each weight percentages of components is: 2: 3: 40: 3: 2 * 10 4
(2), clean
Getting above-mentioned washings with nickel-coated billet cake, stainless shot is by weight percentage: put into the rinse bath of coin cleaning machine, clean 1~5 minute at 1: 2: 4;
(3), rinsing
Base cake after the cleaning was with 80 ℃ rinsed with deionized water 5~10 minutes;
(4), drying
The compressed air scavenging of base cake after the rinsing 2~6 minutes is then through hot-air dry 2~5 minutes.
The present invention has compared with prior art improved the glossiness of impression back coin, outward appearance more, bright and clean, attractive in appearance, and also improve greatly in work-ing life of coin.The present invention is by adjusting the concentration and the scavenging period of cleaning formulation, can also promote the use of the surface cleaning of the coin blank cake of other various materials, coin blank cake to different pollution levels carries out cleaning surfaces, be adapted to scale operation, it is good to have cleaning performance, cleaning speed is fast, cleans cost and the low advantage of labour intensity.
Description of drawings
Fig. 1 is a process flow sheet of the present invention
Embodiment
Embodiment 1
Consult accompanying drawing 1, nickel-coated billet cake put in the washings clean, clean after rinsed with deionized water, pressurized air vibration are blown down, warm air drying becomes cleaning base cake, wherein: washings is mixed by washing composition A, washing composition B, alcohol, WA dewatering agent, water, is specifically undertaken by following step:
(1), preparation washings
A. press following component mixed preparing washing composition A, described substances in percentage by weight meter:
Sodium stearate (content 〉=98%): 16%
Sodium oleate (content 〉=90%): 16%
Polyoxyethylene nonylphenol ether (content 〉=99%): 15%
Water glass (content 〉=99%): 8%
Sodium sulfate (content 〉=99%): 12%
Yellow soda ash (content 〉=99.1%): 10%
Borax (content 〉=99%): 8%
Alkylol amide (content 〉=92%): 15%
B. press following component mixed preparing washing composition B, described substances in percentage by weight meter:
Tripoly phosphate sodium STPP (content 〉=98.5%): 40%
AEO 9[C 12Aliphatic alcohol polyethenoxy (9) ether] (content 〉=99%): 10%
Linear alkylbenzene sulphonic acid (content 〉=96%): 25%
Saltcake (content 〉=95%): 25%
C. getting above-mentioned washing composition A:20g, washing composition B:30g, 90% alcohol 400ml, WA dewatering agent 30ml, water 200L Hybrid Heating, to become temperature be 60 ℃ washings.
Acting as of its main component of washing composition A: sodium stearate is an emulsifying agent, has the cleaning performance of low irritant gentleness; Sodium oleate is that the emulsifying agent wetting ability is stronger, and is soluble in water, and very strong cleaning force is also arranged, and can be used as emulsifying agent and uses; Polyoxyethylene nonylphenol ether has that a plurality of ether wetting abilities are very strong, soluble in water, and the emulsification dissemination is better, very strong cleansing power; Water glass is a cleaning additive, can make water softening, and throw out easily floats and removes, and the soil suspension effect is better, prevents that dirt from adhering to again; Sodium sulfate is cleaning additive, reduces the surface tension of scavenging solution and the interfacial tension between the profit, improves the solublization of scavenging solution; Yellow soda ash is cleaning additive, can make water softening; Borax: can play shock absorption to soda acid, but softening of water with the synergy such as tensio-active agent in the clean-out system, also can improve the free-flowing property of powdery clean-out system, prevents caking; Alkylol amide is a clean-out system, and decontamination, degreasing effect are good, and adding its washing effect in the prescription significantly increases.Clean-out system A has emulsifying property and dispersiveness preferably, and is better in solvability more than 60 ℃, but the soil suspension performance is relatively poor relatively to chelation of metal ion.
Acting as of its main component of washing composition B: tripoly phosphate sodium STPP is the inorganic surfaces promoting agent, the ability that stronger complexation of metal ions is arranged, generate soluble complexes with metal ion, can make the hard water deliquescing, has very strong shock absorption, the PH of washing composition is remained on than in the optimum range, solia particle there is stronger dispersion force, can prevent redeposition with the washing composition adapted, can significantly reduce surface tension of liquid or two-phase interface tension force, increase the perviousness of washing composition,, more increased the washing of oil-containing dirt is renderd a service to greasy emulsifying effect and to proteinic swelling and solublization; AEO 9[C 12Aliphatic alcohol polyethenoxy (9) ether] be nonionic surface active agent, have excellent biodegradability and low-temperature performance, be not subjected to the influence of the water hardness, scourability is good; Linear alkylbenzene sulphonic acid is soluble in water, has good detersive power, seepage force and foaming power, and comprehensive scourability is superior; Saltcake can reduce the surface tension of scavenging solution and the interfacial tension between the profit, improves the solublization of scavenging solution.Clean-out system B has remedied clean-out system A and has lacked the chelating of heavy metal ion and the defective of dispersive ability.
Alcohol can be accelerated the volatilization of base cake surface moisture content.
The WA dewatering agent can form one deck hydrophobic membrane at originally hydrophilic workpiece surface, can remove the moisture content of metallic surface rapidly, improves water stain that workpiece forms when drying, makes the workpiece purpose of dehydration rapidly thereby reach.
(2), clean
Above-mentioned washings is put into the rinse bath of coin cleaning machine with nickel-coated billet cake 400Kg, stainless shot 800Kg, cleaned 3 minutes, what its cleaning process was a washings to the base cake is wetting, makes dirt softening, loose, in addition in mechanical stirring, make stainless shot fully contact and rub, rely on the emulsifying effect of washing composition, disperse dirt base cake surface, form fine particle, and be suspended in equably in the washings, be dissolved in even in the washings, make dirt break away from the base cake fully.
(3), rinsing
Base cake after the cleaning relies on the flushing of clean current with 80 ℃ rinsed with deionized water 7 minutes, and the washings of dirt is washed away from the base cake.
(4), drying
The pressurized air of base cake after the above-mentioned rinsing in the vibrating machine of band air knife was blown down 6 minutes, then through dry 5 minutes of spiral hot air dryer the nickel-coated billet cake of cleaning, will clean the base cake and send the impression operation.
Cleaning of the present invention has replaced acid cleaning process of the prior art, it removes rubbish, greasy dirt and the nickel bits on base cake surface by the Rapid Cleaning of automatization, base cake cleaning surfaces can directly be impressed, improve work-ing life, surface luster and the surface quality of base cake, reduce labour intensity and production cost.

Claims (1)

1, a kind of process for rapidly cleaning surface of nickel-coated billet cake, it is characterized in that nickel-coated billet cake put in the washings and clean, clean after rinsed with deionized water, pressurized air vibration are blown down, warm air drying becomes cleaning base cake, wherein: washings is mixed by washing composition A, washing composition B, alcohol, WA dewatering agent, water, is specifically undertaken by following step:
(1), preparation washings
A. press following component mixed preparing washing composition A, described substances in percentage by weight meter:
Sodium stearate: 14-18%
Sodium oleate: 14-18%
Polyoxyethylene nonylphenol ether: 13-17%
Water glass: 6-10%
Sodium sulfate: 10-14%
Yellow soda ash: 8-12%
Borax: 6-10%
Alkylol amide: 13-17%
B. press following component mixed preparing washing composition B, described substances in percentage by weight meter:
Tripoly phosphate sodium STPP: 35-45%
AEO 9[C 12Aliphatic alcohol polyethenoxy (9) ether]: 5-15%
Linear alkylbenzene sulphonic acid: 20-30%
Saltcake: 20-30%
C. getting above-mentioned washing composition A, washing composition B, 90% alcohol, WA dewatering agent, water Hybrid Heating, to become temperature be 60 ℃ washings, and its each weight percentages of components is: 2: 3: 40: 3: 2 * 10 4
(2), clean
Getting above-mentioned washings with nickel-coated billet cake, stainless shot is by weight percentage: put into the rinse bath of coin cleaning machine, clean 1~5 minute at 1: 2: 4;
(3), rinsing
Base cake after the cleaning was with 80 ℃ rinsed with deionized water 5~10 minutes;
(4), drying
The compressed air scavenging of base cake after the rinsing 2~6 minutes is then through hot-air dry 2~5 minutes.
CN2008102015913A 2008-10-22 2008-10-22 Process for rapidly cleaning surface of nickel-coated billet cake Active CN101381878B (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN2008102015913A CN101381878B (en) 2008-10-22 2008-10-22 Process for rapidly cleaning surface of nickel-coated billet cake

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CN101381878A true CN101381878A (en) 2009-03-11
CN101381878B CN101381878B (en) 2010-06-09

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102312247A (en) * 2011-04-26 2012-01-11 东莞市安美润滑科技有限公司 General aqueous cleaning solution for non-ferrous metals
CN102776504A (en) * 2012-08-09 2012-11-14 贵州钢联金属制品有限公司 Drying-free steel wire dehydrating agent
CN103397338A (en) * 2010-06-25 2013-11-20 张红雨 Cleaning agent
CN105021768A (en) * 2014-04-15 2015-11-04 上海梅山钢铁股份有限公司 Steel plate high-temperature acid washing test apparatus and use method thereof
WO2018218426A1 (en) * 2017-05-27 2018-12-06 深圳市恒兆智科技有限公司 Oil remover, metal component, and oil removal treatment method therefor
CN111266353A (en) * 2018-12-04 2020-06-12 无锡飞云球业股份有限公司 Method for cleaning precision finished steel balls

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1025441C (en) * 1989-12-02 1994-07-13 山东大学 Purging medium for electronic industry and preparing process thereof
CN1105060A (en) * 1994-01-05 1995-07-12 刘春光 Multifunction cleaning agent
CN1242036C (en) * 2000-11-22 2006-02-15 上海白猫专用化学品有限公司 Metal polish-cleaning agent
CN100572518C (en) * 2005-08-31 2009-12-23 宜兴市弘育化工厂 High-permeability metal cleaning agent and preparation
CN101089167A (en) * 2006-06-16 2007-12-19 大连绿洲化工有限公司 Green high-concentration low-foam antirust metal detergent

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103397338A (en) * 2010-06-25 2013-11-20 张红雨 Cleaning agent
CN102312247A (en) * 2011-04-26 2012-01-11 东莞市安美润滑科技有限公司 General aqueous cleaning solution for non-ferrous metals
CN102312247B (en) * 2011-04-26 2013-06-12 东莞市安美润滑科技有限公司 General aqueous cleaning solution for non-ferrous metals
CN102776504A (en) * 2012-08-09 2012-11-14 贵州钢联金属制品有限公司 Drying-free steel wire dehydrating agent
CN105021768A (en) * 2014-04-15 2015-11-04 上海梅山钢铁股份有限公司 Steel plate high-temperature acid washing test apparatus and use method thereof
WO2018218426A1 (en) * 2017-05-27 2018-12-06 深圳市恒兆智科技有限公司 Oil remover, metal component, and oil removal treatment method therefor
CN110719971A (en) * 2017-05-27 2020-01-21 深圳市恒兆智科技有限公司 Oil removing agent, metal piece and oil removing treatment method of metal piece
CN111266353A (en) * 2018-12-04 2020-06-12 无锡飞云球业股份有限公司 Method for cleaning precision finished steel balls

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Address after: 100044 Beijing city Xicheng District Xizhimen Street No. 143 Kaixuan main building

Patentee after: China Banknote Printing and Minting Group Co.,Ltd.

Patentee after: SHANGHAI MINT Co.,Ltd.

Address before: 100044 Beijing city Xicheng District Xizhimen Street No. 143 Kaixuan main building

Patentee before: CHINA BANKNOTE PRINTING AND MINTING Corp.

Patentee before: SHANGHAI MINT Co.,Ltd.