CN110408456A - 一种适合单机架可逆轧机生产高强钢产品用的冷轧轧制油 - Google Patents
一种适合单机架可逆轧机生产高强钢产品用的冷轧轧制油 Download PDFInfo
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- CN110408456A CN110408456A CN201810404487.8A CN201810404487A CN110408456A CN 110408456 A CN110408456 A CN 110408456A CN 201810404487 A CN201810404487 A CN 201810404487A CN 110408456 A CN110408456 A CN 110408456A
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- cold rolling
- emulsifier
- oil
- rolling oil
- strength steel
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- 239000010731 rolling oil Substances 0.000 title claims abstract description 43
- 238000005097 cold rolling Methods 0.000 title claims abstract description 31
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 30
- 239000010959 steel Substances 0.000 title claims abstract description 30
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 26
- 239000002199 base oil Substances 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 14
- 150000002148 esters Chemical class 0.000 claims abstract description 14
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 13
- 239000000194 fatty acid Substances 0.000 claims abstract description 13
- 229930195729 fatty acid Natural products 0.000 claims abstract description 13
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 13
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002253 acid Substances 0.000 claims abstract description 11
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 11
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 11
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 9
- 239000013556 antirust agent Substances 0.000 claims abstract description 9
- 239000010452 phosphate Substances 0.000 claims abstract description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 9
- 125000002091 cationic group Chemical group 0.000 claims abstract description 8
- 239000012875 nonionic emulsifier Substances 0.000 claims abstract description 7
- 239000000126 substance Substances 0.000 claims abstract description 5
- 150000004982 aromatic amines Chemical class 0.000 claims abstract description 3
- 238000005096 rolling process Methods 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 10
- 230000002441 reversible effect Effects 0.000 claims description 10
- -1 alkyl dimethyl benzyl ammonium chloride Chemical compound 0.000 claims description 6
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 6
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 claims description 6
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical group CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 4
- XQVWYOYUZDUNRW-UHFFFAOYSA-N N-Phenyl-1-naphthylamine Chemical compound C=1C=CC2=CC=CC=C2C=1NC1=CC=CC=C1 XQVWYOYUZDUNRW-UHFFFAOYSA-N 0.000 claims description 4
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 3
- PSBDWGZCVUAZQS-UHFFFAOYSA-N (dimethylsulfonio)acetate Chemical compound C[S+](C)CC([O-])=O PSBDWGZCVUAZQS-UHFFFAOYSA-N 0.000 claims description 3
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 3
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 3
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000005642 Oleic acid Substances 0.000 claims description 3
- 235000021314 Palmitic acid Nutrition 0.000 claims description 3
- 235000021355 Stearic acid Nutrition 0.000 claims description 3
- DFUONQUWPYWPGU-JZILDOMLSA-N [(2r)-3-hydroxy-2-[[3-hydroxy-2-(hydroxymethyl)propoxy]methoxymethyl]propyl] (e)-nonadec-9-enoate Chemical compound CCCCCCCCC\C=C\CCCCCCCC(=O)OC[C@H](CO)COCOCC(CO)CO DFUONQUWPYWPGU-JZILDOMLSA-N 0.000 claims description 3
- VURIDHCIBBJUDI-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO VURIDHCIBBJUDI-UHFFFAOYSA-N 0.000 claims description 3
- TXQVDVNAKHFQPP-UHFFFAOYSA-N [3-hydroxy-2,2-bis(hydroxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CO)(CO)CO TXQVDVNAKHFQPP-UHFFFAOYSA-N 0.000 claims description 3
- 125000001033 ether group Chemical group 0.000 claims description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 claims description 3
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 3
- 229940049964 oleate Drugs 0.000 claims description 3
- 239000008117 stearic acid Substances 0.000 claims description 3
- 229940117986 sulfobetaine Drugs 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000539 dimer Substances 0.000 claims description 2
- 150000002191 fatty alcohols Chemical group 0.000 claims description 2
- YVPOTNAPPSUMJX-UHFFFAOYSA-N octadecanoic acid;phosphoric acid Chemical group OP(O)(O)=O.CCCCCCCCCCCCCCCCCC(O)=O YVPOTNAPPSUMJX-UHFFFAOYSA-N 0.000 claims description 2
- 235000021313 oleic acid Nutrition 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 25
- 239000003921 oil Substances 0.000 abstract description 10
- 239000000779 smoke Substances 0.000 abstract description 3
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 239000007866 anti-wear additive Substances 0.000 abstract 1
- 230000007794 irritation Effects 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 235000019198 oils Nutrition 0.000 description 9
- 239000000839 emulsion Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000002480 mineral oil Substances 0.000 description 5
- 235000010446 mineral oil Nutrition 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- 150000003464 sulfur compounds Chemical class 0.000 description 3
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 229910000797 Ultra-high-strength steel Inorganic materials 0.000 description 2
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- IZWSFJTYBVKZNK-UHFFFAOYSA-N lauryl sulfobetaine Chemical compound CCCCCCCCCCCC[N+](C)(C)CCCS([O-])(=O)=O IZWSFJTYBVKZNK-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 2
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 2
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 239000010960 cold rolled steel Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009865 steel metallurgy Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/02—Hydroxy compounds
- C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
- C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
- C10M2207/2835—Esters of polyhydroxy compounds used as base material
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- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
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- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
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- C10M2215/064—Di- and triaryl amines
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
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- C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
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- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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Abstract
本发明涉及一种适合单机架可逆轧机生产高强钢产品用的冷轧轧制油，其组成按质量百分比包括：a)基础油A：季戊四醇与碳原子数在12‑18个之间的脂肪酸反应生成的酯类物质，30‑70％；b)基础油B：双季戊四醇与碳原子数在12‑18个之间的脂肪酸反应生成的酯类物质，5‑30％；c)基础油C：季戊四醇与二聚酸反应生成的酯类物质，5‑25％；d)乳化剂：非离子乳化剂及阳离子乳化剂的组合物，1‑4.5％；e)极压抗磨剂：磷酸酯，0.5‑6.5％；f)抗氧化剂：屏蔽酚类或芳胺型抗氧化剂，0.5‑1.5％；g)防锈剂：脂肪酸类物质，1‑2.5％。本发明所述的适合单机架可逆轧机生产高强钢产品用的冷轧轧制油具有满足高强钢生产所需的润滑性能，又具有显著减少生产时散发的油烟及刺激性异味的优点。
Description
技术领域
本发明涉及冷轧轧制技术领域，尤其是涉及一种高强钢在单机架冷轧生产用的轧制油产品。
背景技术
随着钢铁技术的发展，越来越多的钢铁冶金产品朝着高强化技术发展，现代最新的一代高强钢产品已经达到了1200-1500MPa的强度，由于钢种材料特性以及强度级别的大幅增加，对于这类钢种在传统热轧及冷连轧生产过程中均会遭遇到超过轧制设计极限难以生产的困难；因此，通常在冷轧机组会采用多辊(12辊，18辊或20辊)单机架轧机进行往复式多道次生产，出于生产效率的考虑，在单机架轧机的生产时最高轧制速度通常都会在700m/min以上，此时由于高强钢的极高强度特性，使得生产时板温会在150℃甚至170℃以上，而在冷轧生产时会喷射大量的乳化液进行冷却和润滑加工，此时乳化液中水分和油分会大量蒸发雾化成细颗粒，随着轧机顶部的抽风设备排出烟囱，在轧机的周围散发出具有刺激性的阵阵异味；同时，由于高温作用，乳化液被破坏，其中的轧制油常常会失效，导致生产出现了各种包括热划伤、带钢油斑等质量缺陷。
面对这一技术问题，在相关的技术领域进行检索查新，主要发现有如下的一些单机架冷轧轧制油优化技术：
CN1130780.3(一种冷轧薄钢板轧制油组合物)，此技术特点是采用加氢裂化矿物油作为主要的基础油用于生产，可以得到退火性能优良的冷轧薄板家用的轧制油，但由于其所用的矿物油在本技术所阐述的150-170℃的范围内会存在大量的挥发及受热裂化，因此轧制油会存在失效的风险，因此不宜用于本技术所述的单机架高强钢的生产。
CN201110362524.1(一种用于双机架可逆轧机的轧制油组合物)，提出了一种适合于可逆轧机的轧制油，其主要使用了比例高达70-95％多元醇酯类油性剂，以及壬基酚聚氧乙烯醚，大量的比例达0.1-10％硫醚类挤压抗磨剂，这类轧制油虽然可以提供优秀的润滑性，但是在150-170℃的高温下，乳化液会受热，而所用的硫醚添加剂具有极大的刺激性臭味，在生产时喷射到带钢上，瞬间产生的刺激性挥发烟会形成负面影响到机组操作人员的劳动环境。
CN101434886A(一种用于十二辊可逆轧机的轧制油组合物)，主要使用了60-70％的新戊基多元醇酯，14-28％的矿物油和1-5％硫化植物油和硫化动物油，此技术使用了一定量的矿物油和硫化物，也存在前面所述在150-170℃高温段的问题，即矿物油的大量挥发造成生产时轧制油消耗快，且会散发出硫化物的特殊刺激性臭味，对生产的员工造成负面的影响。
从上述的内容来看，对于单机架的可逆冷轧机，在生产高强钢的过程中，现有的冷轧轧制油均存在各种技术不足难于满足高强钢冷轧生产。
本发明提出一种优化的多辊单机架冷轧机组用的轧制油，即可满足单机架冷轧机生产超高强钢的生产需求，还可以显著控制生产时油烟和刺激性异味的散发，提升生产时操作工的工作舒适度。
发明内容
本发明针对单机架冷轧机生产超高强钢过程特点，本发明提供了一种适合单机架可逆轧机生产高强钢产品用的冷轧轧制油，其组成按质量百分比包括：
a)基础油A：季戊四醇与碳原子数在12-18个之间的脂肪酸反应生成的酯类物质，30-70％；
b)基础油B：双季戊四醇与碳原子数在12-18个之间的脂肪酸反应生成的酯类物质，5-30％；
c)基础油C：季戊四醇与二聚酸反应生成的酯类物质，5-25％；
d)乳化剂：非离子乳化剂及阳离子乳化剂的组合物，1-4.5％；
e)极压抗磨剂：磷酸酯，0.5-6.5％；
f)抗氧化剂：屏蔽酚类或芳胺型抗氧化剂，0.5-1.5％；
g)防锈剂：脂肪酸类物质，1-2.5％。
其中，
更进一步地，所述的基础油A为季戊四醇与碳原子数16-18个之间的脂肪酸反应生成的酯类产物，优选为季戊四醇棕榈酸酯、季戊四醇硬脂酸酯、季戊四醇油酸酯中的一种或多种的混合物；
更进一步地，所述的基础油B为双季戊四醇与碳原子数16-18个之间的脂肪酸反应生成的酯类产物，优选为双季戊四醇棕榈酸酯、双季戊四醇硬脂酸酯、双季戊四醇油酸酯中的一种或多种的混合物；
更进一步地，所述乳化剂为非离子乳化剂及阳离子乳化剂质量比3:7-7:3的组合物；
更进一步地，所述的非离子乳化剂优选为含聚氧乙烯醚结构的非离子高分子聚合物乳化剂，所述阳离子乳化剂优选为磺基甜菜碱系乳化剂及碳原子数在12-18个之间的烷基二甲基苄基氯化铵乳化剂中的一种或其混合物；所述含聚氧乙烯醚结构的非离子高分子聚合物乳化剂包括如辛基酚聚氧乙烯醚、聚氧乙烯聚氧丙烯嵌段聚合物、吐温85、吐温80等；所述磺基甜菜碱系乳化剂包括如十二烷基磺基甜菜碱等；所述烷基二甲基苄基氯化铵乳化剂包括如十二烷基二甲基苄基氯化铵、十八烷基二甲基苄基氯化铵等；
更进一步地，所述的极压抗磨剂为碳原子数在14-22个之间的脂肪醇酸性磷酸酯，如十八醇酸性磷酸酯、十四醇酸性磷酸酯等；
更进一步地，所述的抗氧化剂为2，6-二叔丁基对甲基苯酚或N-苯基-ɑ-萘胺；
更进一步地，所述的防锈剂为碳原子数在16-18之间的脂肪酸，如油酸、十六烷酸、硬脂酸等。
本发明所述的适合单机架可逆轧机生产高强钢产品用的冷轧轧制油的制备方法，可以为在常温下将其所含各组分直接混合均匀得到，也可以对混合物进行加热以促进溶解。
本发明所述的适合单机架可逆轧机生产高强钢产品用的冷轧轧制油具有满足高强钢生产所需的润滑性能，又具有显著减少生产时散发的油烟及刺激性异味的优点。
所述轧制油，可以有效提供高强钢轧制过程的润滑需求，也能避免单机架轧制高强钢时带钢极具发热所导致的轧制油挥发，并通过避免使用硫化合物使用控制了单机架轧制时轧制油挥发所产生的刺激味对工人操作引起的不便。同时，非离子高分子聚合乳化剂及阳离子乳化剂的使用可以使得乳化液非常稳定，且利于乳化液长期在高温环境下使用。
最终，由于本产品具有较高的润滑性和可靠性，因此在实际使用过程中具有非常简便且管理便利的优势，非常适合于各类单机架，尤其是轧制高强钢产品的单机架使用。
具体实施方式
实施例1
适合单机架可逆轧机生产高强钢产品用的冷轧轧制油，其组成按质量百分比包括：
基础油A：季戊四醇棕榈酸酯，65％；
基础油B：双季戊四醇棕榈酸酯，15％
基础油C：季戊四醇二聚酸酯，10％；
乳化剂：辛基酚聚氧乙烯醚，1％；十二烷基磺基甜菜碱，1％；
极压抗磨剂：十八醇酸性磷酸酯，5％；
抗氧化剂：2，6-二叔丁基对甲基苯酚，1.5％；
防锈剂：硬脂酸，1.5％。
实施例2
适合单机架可逆轧机生产高强钢产品用的冷轧轧制油，其组成按质量百分比包括：
基础油A：季戊四醇油酸酯，40％；
基础油B：双季戊四醇油酸酯，30％
基础油C：季戊四醇二聚酸酯，20％；
乳化剂：聚氧乙烯聚氧丙烯嵌段聚合物，1.5％；十二烷基二甲基苄基氯化铵，2.5％；
极压抗磨剂：十八醇酸性磷酸酯，3.5％；
抗氧化剂：2，6-二叔丁基对甲基苯酚，1.5％；
防锈剂:十六烷酸，1％。
实施例3
适合单机架可逆轧机生产高强钢产品用的冷轧轧制油，其组成按质量百分比包括：
基础油A：季戊四醇硬脂酸酯，55％；
基础油B：双季戊四醇硬脂酸酯，20％
基础油C：季戊四醇二聚酸酯，15％；
乳化剂：吐温-85，2％；十八烷基二甲基苄基氯化铵，1.2％；
极压抗磨剂：十四醇酸性磷酸酯，3％；
抗氧化剂：N-苯基-ɑ-萘胺，2.7％；
防锈剂:油酸，1.1％。
测试例1
将实施例1-3制得的冷轧轧制油送入实验室开展TGA热重试验分析测量，以了解轧制油在不同温度段下的热挥发失重效果，同时使用现有技术中的FZ/2015轧制油产品(日本大同化学株式会社提供)作为对比例，以评估轧制油的挥发性能，得到如下测量结果：
表1现有单机架使用轧制油产品与不同实施例的TGA试验
可以看见，采用原来的轧制油产品(对比例)，由于其设计的时候没有考虑高强钢产品在生产时极具发热的效果，因此在170-200℃的温度范围内，已经显著有油品挥发的损失产生，在300℃的温度下，14.39％质量百分比的轧制油挥发而损失。本发明所设计的实施例在170℃以下基本没有受热挥发的问题，在200℃的情况下仅不到0.4％的油品挥发，而在300℃时才会出现显著的油品的挥发，因此可以满足现场的高强钢生产的高温发热的轧制需求。
此外，由于本实施例所提到的产品不含有硫化合物，且在200℃的生产使用环境下，油品基本没有受热挥发到四周环境中的问题，所以，在实际的使用过程中不存在因为这两者在空气中挥发分散所产生的刺激性的油烟味，对现场操作工的劳动环境也较为有利。
测试例2
将上述的对比例及实施例1-3制得的产品，按照2.5％质量百分比的条件和水搅拌配置成乳化液，并维持在55℃的条件下喷射到带钢及轧辊上进行使用，并在某18辊单机架可逆轧机上轧制DP980材料的高强钢产品，按照如下的轧制规程进行生产：
表2轧制规程
| 轧辊直径/mm | 165 |
| 轧制前后张力范围/MPa | 30～180 |
| 轧辊粗糙度/μm | 1.0 |
| 各道次厚度变化/mm | 2.56/2.13/1.70/1.4/1.14 |
| 带钢宽度/mm | 1260 |
实际的使用后，得到如下的轧制力数据的采集，以说明效果对比：
表3实际生产的轧制力对比
从上面的使用后来看，在相同的生产情况下，使用本发明所得到的实施例在生产中的得到各道次的轧制力均小于原来的轧制油产品(对比例)，因此说明了本产品在润滑性上的改善。
本发明的实现原理简单，仅需对轧制润滑剂进行相关的调整，同时所使用的原料均可在市场上购买得到。同时，使用相关技术后，对于相应现场设备及轧制规程无需进行大规模变化，可以较为有效地控制单机架轧机轧制高强钢产品时的乳化液挥发，减少操作时工人感受到的刺激性异味，具有较高的实用价值。
Claims (10)
1.一种适合单机架可逆轧机生产高强钢产品用的冷轧轧制油，其特征在于，其组成按质量百分比包括：
a)基础油A：季戊四醇与碳原子数在12-18个之间的脂肪酸反应生成的酯类物质，30-70％；
b)基础油B：双季戊四醇与碳原子数在12-18个之间的脂肪酸反应生成的酯类物质，5-30％；
c)基础油C：季戊四醇与二聚酸反应生成的酯类物质，5-25％；
d)乳化剂：非离子乳化剂及阳离子乳化剂的组合物，1-4.5％；
e)极压抗磨剂：磷酸酯，0.5-6.5％；
f)抗氧化剂：屏蔽酚类或芳胺型抗氧化剂，0.5-1.5％；
g)防锈剂：脂肪酸类物质，1-2.5％。
2.根据权利要求1所述的冷轧轧制油，其特征在于：所述的基础油A为季戊四醇棕榈酸酯、季戊四醇硬脂酸酯、季戊四醇油酸酯中的一种或多种的混合物。
3.根据权利要求1所述的冷轧轧制油，其特征在于：所述的基础油B为双季戊四醇棕榈酸酯、双季戊四醇硬脂酸酯、双季戊四醇油酸酯中的一种或多种的混合物。
4.根据权利要求1所述的冷轧轧制油，其特征在于：所述乳化剂为非离子乳化剂及阳离子乳化剂质量比3:7-7:3的组合物。
5.根据权利要求4所述的冷轧轧制油，其特征在于：所述的非离子乳化剂为含聚氧乙烯醚结构的非离子高分子聚合物乳化剂，所述阳离子乳化剂为磺基甜菜碱系乳化剂及碳原子数在12-18个之间的烷基二甲基苄基氯化铵乳化剂中的一种或其混合物。
6.根据权利要求1所述的冷轧轧制油，其特征在于：所述的极压抗磨剂为碳原子数在14-22个之间的脂肪醇酸性磷酸酯。
7.根据权利要求6所述的冷轧轧制油，其特征在于：所述的极压抗磨剂选自十八醇酸性磷酸酯、十四醇酸性磷酸酯。
8.根据权利要求1所述的冷轧轧制油，其特征在于：所述的抗氧化剂为2，6-二叔丁基对甲基苯酚或N-苯基-ɑ-萘胺。
9.根据权利要求1所述的冷轧轧制油，其特征在于：所述的防锈剂为碳原子数在16-18之间的脂肪酸。
10.根据权利要求9所述的冷轧轧制油，其特征在于：所述的防锈剂选自油酸、十六烷酸、硬脂酸。
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| 欧风: "《合理润滑手册》", 31 May 1993, 石油工业出版社 * |
| 汪多仁: "《绿色增塑剂》", 31 October 2011, 科学技术文献出版社 * |
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