CN110402136A - Oil-based cosmetic material - Google Patents
Oil-based cosmetic material Download PDFInfo
- Publication number
- CN110402136A CN110402136A CN201880016779.2A CN201880016779A CN110402136A CN 110402136 A CN110402136 A CN 110402136A CN 201880016779 A CN201880016779 A CN 201880016779A CN 110402136 A CN110402136 A CN 110402136A
- Authority
- CN
- China
- Prior art keywords
- oil
- ingredient
- red
- cosmetic material
- based cosmetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
- A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/08—Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/001—Preparations for care of the lips
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Problem of the present invention is that providing a kind of oil-based cosmetic material with bright-coloured appearance color and high-temperature stability and excellent gloss.The present invention provides a kind of oil-based cosmetic material, it passes through the specific content mass ratio containing (A) selected from a kind or 2 kinds No. 218 red, in red 223 and (B) alpha-olefin-vinylpyrrolidone copolymer ((A)/(B) is 2 or less), with bright-coloured appearance color, and high-temperature stability and excellent gloss.
Description
Technical field
The present invention relates to a kind of oil-based cosmetics with bright-coloured appearance color and high-temperature stability and excellent gloss
Expect and contain alpha-olefin-vinylpyrrolidone copolymer colour developing modifier.
Background technique
Oil-based cosmetic material is using oily mutually as the cosmetic preparation of continuous phase, excellent durability of making up, therefore is chiefly used in lipstick, lip
The cosmetic preparations such as coloured silk, blush, eye coloured silk.In addition, in recent years, the diversification of hobby property does not require nothing more than makeup persistence and gloss, also requires
The cosmetic preparation etc. of bright-coloured appearance color is presented, in order to realize chromatic colour, is widely used red No. 218 and waits dyestuffs.But
If only waiting dyestuffs containing red No. 218 in the oil-based cosmetic material using oil components as principal component, bright-coloured colour developing can't see.
Therefore, in order to which using the appearance color of dyestuff imparting oil-based cosmetic material, trial has adds other ingredients in oil-based cosmetic material.Example
Such as, it is known to technology (the Japan spy of sufficient appearance color is assigned by combination dextrin fatty acid ester, dipropylene glycol and dyestuff
Open 2004-175773 bulletin).Additionally, it is known that have through combination higher fatty acid metal salt and dyestuff realize it is bright-coloured outer
See technology (Japanese Unexamined Patent Publication 2016-132650 bulletin (No. 2017/319454 explanation of U.S. Patent Application Publication No. of color
Book)).
Summary of the invention
Subject to be solved by the invention
However, the stability under high temperature is poor in the technology of Japanese Unexamined Patent Publication 2004-175773 bulletin, in manufacture lipstick
Or whens lip gloss etc., if heating at high temperature (such as 100 DEG C or so), chromatic colour disappears sometimes.In addition, in Japanese Unexamined Patent Publication
In the technology of 2016-132650 bulletin (No. 2017/319454 specification of U.S. Patent Application Publication No.), although showing fresh
Gorgeous color, if but in order to improve the higher fatty acid metal salt for developing the color and being added the powder as the colour developing factor, exist sometimes
Satisfactory gloss can not be obtained in makeup film when cosmetic preparation to be coated on to skin.
Therefore, the issue of the present invention is to provide it is a kind of with bright-coloured appearance color and high-temperature stability (even if
Also bright-coloured appearance color is maintained after high-temperature heating) and makeup film excellent gloss oil-based cosmetic material.
Means for solving the problems
In view of such actual situation, present inventor has performed further investigations, as a result, it has been found that, by with specific content matter
Amount ratio (content mass ratio) ((A)/(B) be 2 or less) combination as (A) of the dyestuff of red system be selected from red 218 and
It a kind or 2 kinds in red No. 223 and in the structure with (B) alpha-olefin-vinylpyrrolidone copolymer of nitrogen-atoms, can
To obtain there is bright-coloured appearance color and the oil-based cosmetic material of high-temperature stability and excellent gloss, until completing this hair
Bright product.
That is, the present invention relates to
(1) a kind of oil-based cosmetic material contains ingredient below (A) and (B):
(A) a kind or 2 kinds in red No. 218 and red 223,
(B) alpha-olefin-vinylpyrrolidone copolymer,
Ingredient (A) is 2 or less relative to content mass ratio (A)/(B) of ingredient (B).
(2) the oil-based cosmetic material according to (1), wherein the carbon atom number of the alpha-olefin in ingredient (B) is 12~24.
(3) the oil-based cosmetic material according to (1) or (2), wherein ingredient (B) is hexadecene-vinyl pyrrolidone
Copolymer.
(4) the oil-based cosmetic material according to any one of (1)~(3), wherein above-mentioned (A)/(B) is 0.0001 or more
And 2 or less.
(5) the oil-based cosmetic material according to any one of (1)~(4), wherein the content of ingredient (A) is relative to makeup
Material is 0.1~1 mass %.
(6) a kind of colour developing modifier of the oily material containing dyestuff contains alpha-olefin-vinyl pyrrolidone copolymerization
Object, wherein dyestuff is a kind or 2 kinds in red No. 218 and red 223.
The present invention relates to a kind of colour developing modifiers, containing ingredient (A) selected from No. 218 red, a kind in red 223
Or 2 kinds and ingredient (B) alpha-olefin-vinylpyrrolidone copolymer.
Detailed description of the invention
After Fig. 1 is shown to the oiliness lip of embodiment 6 and comparative example 3 is coated on skin with cosmetic preparation, makeup is removed
The result that " dyeing difficulty " when material is evaluated.
Specific embodiment
Hereinafter, being illustrated to details of the invention.It should be noted that in this specification, "~" mean include
The range of numerical value before and after it.In addition, unless otherwise specified, the measurement of operation transitivity etc. room temperature (20~25 DEG C)/
It is carried out under conditions of 40~50%RH of relative humidity.
The present invention is a kind of oil-based cosmetic material, contains following component (A) and (B):
(A) a kind or 2 kinds in red 218, red 223,
(B) alpha-olefin-vinylpyrrolidone copolymer,
Ingredient (A) is 2 or less relative to content mass ratio (content mass ratio) (A)/(B) of ingredient (B).Oiliness of the invention
Cosmetic preparation has bright-coloured appearance color, and high-temperature stability and excellent gloss.
For example, in oiliness lip cosmetic preparation etc. (partly) solid shaped dosage forms, sometimes using by being heated up to 100 DEG C or so
And it is filled into the technique in container.In oil-based cosmetic material of the invention, even if cosmetic preparation is exposed to 100 DEG C or so of high temperature,
Also it is able to maintain that bright-coloured appearance color, i.e. high-temperature stability is excellent.
Although the detailed mechanism for playing said effect is still not clear, think to be bonded by ingredient (B) with ingredient (A) or instead
It answers, ingredient (A) brilliantly develops the color in cosmetic preparation.Moreover, because such bonding or reaction are also irreversible at high temperature, therefore
Think that bright-coloured appearance color can also be maintained even if after cosmetic preparation is heated to high temperature.In addition, passing through ingredient (A) and ingredient
(B) it is bonded or reacts, when being coated with cosmetic preparation on the skin, ingredient (A) is inhibited to be bonded with skin, the dyeing after removing cosmetic preparation
It is suppressed (referring to aftermentioned embodiment).In addition, since ingredient (B) is oiliness, therefore, it is considered that can be right after being coated with cosmetic preparation
Film of making up adds gloss.
Oil-based cosmetic material of the invention is preferably mutually to be set as the oil of finish or the oil components as oil-soluble compounds
The oil-based cosmetic material of continuous phase, from the viewpoint of it can play significantly effect of the invention, the content of water is preferably oiliness
0.5 mass % or less (0 mass % of lower limit) in cosmetic preparation, further preferably 0.1 mass % or less (0 mass % of lower limit), it is special
It You Xuanwei not 0 mass % (not aqueous).
Red 218 (tetrachloro-tetrabromfluorescein), red No. 223 (tetrabromo fluorescence of ingredient used in the present invention (A)
Element) be Material of Fluoran oil-soluble dyes one kind, be classified as tar colorant.It is the coloured silks such as lipstick since colour developing is red
Widely used colorant in adornment cosmetic preparation.As commercially available product, for example, can enumerate TPP is No. 218 red, TPP it is No. 223 red (with
On, the sixth of the twelve Earthly Branches in the last of the ten Heavenly stems is melted into Co. Ltd. system) etc., the one kind or two or more of these substances can be used.In these substances, do not limit especially
It is fixed, from light resistance superior viewpoint grade, more preferably using No. 218 red.
The content of ingredient used in the present invention (A) is not particularly limited, from colour developing, the excellent equal sight of transparency (transparent feel)
Point considers, relative to cosmetic preparation, preferably 0.0001~10 mass % (hereinafter referred to as " % "), more preferably 0.001~
5%, it is even more preferably 0.01~1%, particularly preferably 0.1~1%.
Alpha-olefin-vinylpyrrolidone copolymer of ingredient used in the present invention (B) refers to alpha-olefin and vinyl
The copolymer of pyrrolidones.
As alpha-olefin, from the aspect of further playing effect of the invention, preferably carbon atom number is 12~24, more excellent
Selecting carbon atom number is 14~22, and further preferred carbon atom number is 16~20.As alpha-olefin, pentadecane can be specifically enumerated
Alkene, hexadecene, heptadecene, octadecene, 19 carbenes or eicosylene.These alpha-olefins can be used alone,
It can be two or more.
Wherein, from the aspect of further playing effect of the invention, as alpha-olefin-vinyl pyrrolidone copolymerization
Object, preferably pentadecane alkene-vinylpyrrolidone copolymer, hexadecene-vinylpyrrolidone copolymer, 17 carbon
Alkene-vinylpyrrolidone copolymer, octadecene-vinylpyrrolidone copolymer, 19 carbenes-vinyl pyrrolidone
Copolymer or eicosylene-vinylpyrrolidone copolymer, more preferably hexadecene-vinylpyrrolidone copolymer
Or eicosylene-vinylpyrrolidone copolymer, further preferably hexadecene-vinylpyrrolidone copolymer.
It as the character of ingredient (B), is not particularly limited, is preferably liquid at 25 DEG C from viewpoints such as excellent gloss.
Here, liquid refers to the substance at 25 DEG C with mobility.More specifically, refer to the case where compound is tilted 45 °
Under, its shape can not be kept for 10 minutes or more, generate the variation of shape.As commercially available product, for example, ANTARON can be enumerated
V216, V220F (the above are ISP Amada Co., Ltd. systems) etc., can be used one kind or two or more.
The content of ingredient used in the present invention (B) is not particularly limited, excellent etc. from colour developing, gloss, high-temperature stability
Viewpoint is set out, and preferably 0.001~70%, more preferably 0.01~50%, it is even more preferably 0.1~30%, it is especially excellent
It is selected as 5~20%.
Ingredient (B) in the present invention relative to the content mass ratio of ingredient (A) be (A)/(B) (hreinafter referred to as (A)/
It (B)) is 2 or less.If (A)/(B) is greater than 2, it is unable to get satisfactory colour developing.In addition, from the viewpoint of colour developing,
(A)/(B) is preferably 0.0001 or more, and more preferably 0.001 or more, further preferably 0.002 or more.In turn, from colour developing
Viewpoint is set out, and (A)/(B) is preferably 1 hereinafter, from the viewpoint of gloss, and (A)/(B) is preferably 0.5 or less.From colour developing, high temperature
The viewpoints such as stability, transparency (transparent feel), excellent gloss are set out, preferably (A)/(B)=0.0001~2, more preferably
0.001~1, it is even more preferably 0.002~1, particularly preferably 0.005~1, most preferably 0.005~0.5.
The oil-based cosmetic material of present embodiment preferably comprises finish.As finish, fluid oil, solid oil, paste can be contained
The finish of shape or solid-like.
As fluid oil, specifically, can enumerate out Permethyl 99A, isohexadecane, light isoparaffins, atoleine,
Saualane, squalene, alpha-olefin low polymers, polybutene, liquid isoparaffin, heavy liquid isoparaffin, polyisobutene, hydrogenation
The hydro carbons such as polyisobutene, rape flower seed oil, avocado oil, almond oil, apricot kernel oil, sesame oil, orange-seed oil, olive oil, Kiwi berry
Seed oil, sesame oil, wheat-germ oil, rice germ oil, rice bran oil, safflower oil, sage oil, soybean oil, tea-seed oil, corn oil,
Rapeseed oil, evening primrose oil, Chinese toon oil, apricot kernel oil, palm oil, peanut oil, sunflower oil, grapeseed oil, white awns flower seed oil, fan change
Sesame oil, SIMMONDSIA CHINENSIS SEED OIL, macadimia nut oil, the vegetable and animals oils such as lavender oil, rose fruit seed oil, ermine oil；Three (2 ethyl hexanoic acids) are sweet
Grease, isononanoic acid isotridecyl ester, isononyl isononanoate, 2 ethyl hexanoic acid cetyl, isopropyl myristate, palmitinic acid are different
Propyl ester, palmitinic acid -2- ethylhexyl, myristic acid octyldodecyl, tricaprylin, three (caprylic capric) glycerol
Ester, two glyceryl isostearates, glyceryl isostearate, ten isostearic acids, ten glyceride (ten isostearic acid polyglycerol esters -10),
Didecyl acid propylene glycol, two capric acid neopentyl glycols, three polyglycerol stearates, two iso stearyl ester of malic acid, diethyl caproic acid are new
Pentanediol, pentaerythritol tetrastearate, four (2 ethyl hexanoic acid) pentaerythritol esters, five isostearic acid dipentaerythritol esters, carbon
Acid dialkyl ester, hexamethylene -1,4- dioctyl phthalate double ethoxydiglycols, dimer dilinoleic acid hydrogenated rosin condensation product, inclined benzene
The esters such as three sour tridecane base esters；The fatty acids such as oleic acid, isostearic acid；Oleyl alcohol, 2- octyldodecanol, 2- decyl alkane
The higher alcohols such as alcohol, isooctadecanol, 2- hexyl decyl alcohol；Dimethyl polysiloxane (dimethicone), the poly- silicon of methyl trimethoxy base
Oxygen alkane, methyl phenyl silicone, octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane, four silicon oxygen of tetramethyl tetrahydro ring
Alkane, tetramethyl tetraphenyl cyclotetrasiloxane, four fluoropropyl cyclotetrasiloxane of tetramethyl, five trifluoropropyl basic ring of pentamethyl, five silicon oxygen
Alkane, polyether-modified methyl polysiloxane, oil base modified methyl polysiloxanes, polyvinylpyrrolidone modified methyl polysiloxanes
Equal silicone oils；The fluorine systems finish class such as perfluoropolyether, perfluoro decane, perfluorooctane；Acetic acid lanolin, lanolin fatty acid isopropyl
The lanolin derivatives class such as ester, lanolin alcohol；The purple of the liquid such as Neo Heliopan AV, ethylhexyl salicylate
Ultraviolet absorbers etc..
It should be noted that fluid oil refers to (having mobility) oil at 25 DEG C for liquid.
As paste or the finish of solid-like, cocoa butter, shea butter, castor oil, rilanit special, hydrogenation can be enumerated
Coconut oil, vaseline, monostearate rilanit special, monohydroxy stearic acid rilanit special, hydroxy stearic acid cholesterol ester, two
Pentaerythritol fatty ester, N- lauroyl-Pidolidone-two (octyldodecyl/cholesteryl/docosyl) ester, N-
Lauroyl-Pidolidone-two (octyldodecyl/phytosterol base/behenyl base) ester, macadimia nut oil fatty acid phytosterin
The finish of the pastes such as ester, dimer dilinoleic acid (phytosterol base/iso stearyl/cetyl/stearyl/behenyl base) ester；Firmly
Resin acid, behenic acid, cetin, distearyl acid polyethylene glycol, San behenic acid glyceride, cholesterol, phytosterol, tristearin
The finish of the solid-likes such as base modified polyorganosiloxane, solidified oil, palm oil.
Finish can be used alone or two or more kinds may be used.
As the content of finish, considers dosage form, sense of touch etc. and suitably set, in oil-based cosmetic material, preferably 10~
99.9 quality %.
Oil-based cosmetic material of the invention can also not interfere effect of the invention other than above-mentioned ingredient (A) and (B)
Suitably containing ingredient, powder, surfactant, water soluble polymer used in usual cosmetic preparation in the range of fruit, to hydroxyl
Yl benzoic acid derivative, preservative, solid ultraviolet absorbing agent, moisturizer, antibacterial agent, fragrance, salt, antioxidant, pH
Regulator, chelating agent, freshener, anti-inflammatory agent, skin makeup ingredient (whitening agent, cell activator, pachylosis improver, blood
Recycle promotor, skin contraction agent, anti-grease bleeding etc.), vitamins, amino acids, nucleic acid, hormone, inclusion compound etc..
Powder used in the present invention, as long as usually powder used in cosmetic preparation, then not by spherical, plate
The especially limit such as the partial size of shape, the shapes such as needle-shaped or smoke-like, particle, pigment-level etc. or the particle structures such as porous, non-porous
It is fixed, a kind or 2 of inorganic particle class, bright property powder class, organic powder class, pigment powder class, composite granule class etc. can be used
Kind or more.
But there are following tendencies: by the powder big containing partial size, the gloss for film of making up is reduced, in addition, cosmetic preparation
Transparency or transparent feel reduce.Therefore, the content in the cosmetic preparation for the powder that average grain diameter is 1 μm or more is preferably 10% or less
(lower limit 0%), more preferably 5% or less (lower limit 0%), particularly preferably less than 1% (lower limit 0%).Here, average grain diameter can
To be calculated by the image observed using scanning electron microscope.
As above-mentioned inorganic particle class, can be used selected from titanium oxide, black oxidation titanium, Prussian blue, ultramarine, colcother,
Yellow iron oxide, black iron oxide, zinc oxide, aluminium oxide, silica, magnesia, zirconium oxide, magnesium carbonate, calcium carbonate, oxidation
Chromium, chromium hydroxide, carbon black, alumina silicate, magnesium silicate, aluminum magnesium silicate, mica, synthetic mica, sericite, talcum, kaolin, carbonization
It is one kind or two or more in silicon, barium sulfate, bentonite, montmorillonite and boron nitride etc..The change of inorganic particle class in the present invention
Content in makeup material is not particularly limited, from the viewpoints, preferably 10% or less such as gloss or transparency (transparent feel) is excellent
(lower limit 0%), more preferably 5% or less (lower limit 0%), particularly preferably less than 1% (lower limit 0%).
As above-mentioned bright property powder class, can be used selected from Bismuth Oxychloride, the mica of titanium oxide covering, iron oxide covering
Mica, the mica titanium of iron oxide covering, the mica titanium of organic pigment covering, titanium oxide covering glass powder and aluminium powder etc.
In it is one kind or two or more.Content in the cosmetic preparation of bright property powder class in the present invention is not particularly limited, from gloss or
The viewpoints such as transparency (transparent feel) is excellent are set out, preferably 30% or less (lower limit 0%), more preferably 15% or less (lower limit
0%), particularly preferably less than 10% (lower limit 0%).
As above-mentioned organic powder class, can be used selected from nylon powder, polymethylmethacrylate powder, acrylonitrile-
Methacrylic acid copolymer powder, vinylidene chloride-methacrylic acid copolymer powder, polyethylene powders, gather PET resin powder
Styrene powder, organopolysiloxane elastomers powder, polymethylsilsesquioxane powder, polyurethane powder, wool powder, silkworm
It is one kind or two or more in silk powder end, avicel cellulose powder and N- acyl-lysine powder etc..Organic powder in the present invention
Content in the cosmetic preparation of class is not particularly limited, from the viewpoints such as gloss or transparency (transparent feel) is excellent, preferably
30% or less (lower limit 0%), more preferably 15% or less (lower limit 0%), particularly preferably less than 10% (lower limit 0%).
In these powders, if further containing polyurethane powder, colour developing is further increased, therefore preferably.Polyurethane powder
The content at end is preferably 0.5~10%, more preferably 1~5% in cosmetic preparation.
Powder can be used one kind or two or more surface treating agent and implement surface treatment.As surface treatment, Ke Yiju
Silicone-treated, silylated processing, alkyl titanate processing, metallic soap processing, finish processing, fluorine compounds processing, phosphorus out
Lipid processing etc..
It as the shape of oil-based cosmetic material of the invention, is not particularly limited, solid-like, semi-solid, liquid can be enumerated
Shape, from the viewpoint of playing effect of the invention significantly, preferably liquid or semi-solid.
The manufacturing method of oil-based cosmetic material of the invention is not particularly limited, and can mix by ingredient (A) and ingredient (B)
After dispersion, arbitrary oil components are mixed into dispersion or heating mixes, later, equably by arbitrary powder or water composition etc.
It is flowed into container or mold after heating for dissolving and fills, cools down and obtain by mixing.As long as heating temperature when filling is changed
Makeup material can be filled in the temperature of container with mobility, be not particularly limited, and preferably 80 DEG C or more, preferably 85~
160℃.Even if cosmetic preparation is exposed to such high temperature, cosmetic preparation of the invention is also able to maintain that bright-coloured colour developing.
As oil-based cosmetic material of the invention, be not particularly limited, be suitable as lipstick, lip gloss, lip gloss, lip-stick,
The color make-ups cosmetic preparations such as clypeus, lipstick external coating, blush, eye color, the nail polish of substrate use.From can play significantly
From the perspective of effect of the invention, the lips cosmetic preparation such as particularly preferred lipstick, lip gloss.
Alternatively, it is also possible to a kind or 2 kinds and ingredient by ingredient (A) of the invention in red 218, red 223
(B) alpha-olefin-vinylpyrrolidone copolymer is used as colour developing modifier, is not particularly limited, other than cosmetic preparation,
It can also contain in coating, ink, bonding agent etc..
In turn, another way of the invention is a kind of colour developing modifier, is total containing alpha-olefin-vinyl pyrrolidone
The colour developing modifier of the oily material containing dyestuff of polymers, dyestuff are a kind or 2 in red No. 218 and red 223
Kind.Here, so-called colour developing improves, refer to such as chroma raising.About alpha-olefin-vinylpyrrolidone copolymer, red 218
Number and it is No. 223 red, as described above.Develop the color modifier preferably with containing colour developing modifier before oily material (a2+b2)(1/2)
It compares, (a after colour developing modifier addition2+b2)(1/2)Become larger, more preferably relative to containing the oily material before color developing agent
(a2+b2)(1/2), colour developing modifier addition after (a2+b2)(1/2)As 1.5 times or more, further preferably become 3 times or more.In
This, a value, b value use the value measured using the colour difference meter recorded in embodiment.Relative to oily material, alpha-olefin-vinyl
The additive amount of pyrrolidinone copolymer is preferably 0.001~70%, more preferably 0.01~50%, particularly preferably 0.1~
30%.
Embodiment
Hereinafter, enumerating embodiment explains the present invention in detail.In addition, these embodiments do not carry out any limit to the present invention
It is fixed.
Examples 1 to 5, Comparative Examples 1 and 2
The mixture of the composition shown in table 1, according to the degree of following evaluation criteria evaluation colour developing.It the results are shown in table 1.
It should be noted that ingredient (1)~(4) are uniformly mixed with three rollers, oil-based cosmetic material is obtained.
[table 1]
(colour developing (chroma))
Using transparent cuvette, using colour difference meter Sectro Color Meter SE7700, (Shimadzu is made under 25 DEG C of environment
Institute) sample obtained in Examples 1 to 5, Comparative Examples 1 and 2 is measured, according to obtained a value and b value, according to following evaluation criteria
It is evaluated.Show the result in table 1.
(evaluation criteria): (judgement)
30≤(a2+b2)(1/2): ◎
10<(a2+b2)(1/2)< 30: zero
(a2+b2)(1/2)≤ 10: ×
In addition, being carried out for " high-temperature stability " and " gloss " using following evaluation methods.Its result is also shown in table 1 together.
As shown in Table 1, it develops the color in Examples 1 to 5, in contrast, is unable to get in comparative example 1 and 2 adequately aobvious
Color.It should be noted that be unable to get satisfactory colour developing about comparative example 1 and 2, therefore " high-temperature stability " not into
Row evaluation.
Embodiment 6~11, comparative example 3~8
The oiliness lip cosmetic preparation (semi-solid gloss) of composition shown in table 2 is prepared according to following manufacturing methods.For obtaining
Oiliness lip cosmetic preparation, utilize following evaluation methods to carry out the " high-temperature stable of the degree of " colour developing ", heat tone
Property ", " dyeing difficulty ", " transparency " and coating of the appearance of cosmetic preparation when eliminating the cosmetic preparation for being coated on skin or skin
The evaluation of " gloss " of makeup film afterwards.Its result is also shown in table 2 together.In addition, about " colour developing ", using used in table 1
Method.
[table 2]
(manufacturing method) embodiment 6~11, comparative example 3~8
A. ingredient (1)~ingredient (8) is uniformly mixed.
B. ingredient (9)~ingredient (15) is uniformly mixed using three rollers.
C. B is heated to 90 DEG C, be filled into container, obtain oiliness lip cosmetic preparation.
(high-temperature stability)
After oiliness lip obtained in embodiment 6~11, comparative example 3~8 is heated to 110 DEG C with cosmetic preparation, transparent ratio is used
Color ware is measured, according to what is obtained using Sectro Color Meter SE7700 (Shimadzu Seisakusho Ltd.) under 25 DEG C of environment
A value and b value, are evaluated according to following evaluation criteria.
(evaluation criteria): (judgement)
30≤(a2+b2)(1/2): ◎
10<(a2+b2)(1/2)< 30: zero
(a2+b2)(1/2)≤ 10: ×
(dyeing difficulty)
Oiliness lip obtained in embodiment 6~11, comparative example 3~8 is coated on skin with cosmetic preparation, to the commercially available paper of utilization
Towel removes the dye levels after cosmetic preparation, carries out the evaluation based on professional judging panel according to following evaluation criteria.
(evaluation criteria)
After removing cosmetic preparation with paper handkerchief, do not dye: ◎
After removing cosmetic preparation with paper handkerchief, slightly dye: zero
After removing cosmetic preparation with paper handkerchief, it will be apparent that dyeing: ×
(transparency)
To oiliness lip cosmetic preparation obtained in embodiment 6~11, comparative example 3~8, the transparent colorimetric of optical length 1cm is used
Ware measures the absorbance of 650nm under 25 DEG C of environment using the extinction photometer UV-2500PC of society, Shimadzu Seisakusho Ltd., by
Absorbance in the wavelength region of 650nm is evaluated according to following evaluation criteria.
(evaluation criteria): (judgement)
95≤(absorbance): ◎
50 < (absorbance) < 95: zero
(absorbance)≤50: ×
(gloss)
To oiliness lip cosmetic preparation obtained in embodiment 6~11, comparative example 3~8, make based on 20 professional judging panels
With test, each one is evaluated as 5 grades to judging panel in following absolute evaluations, calculates it by the grade summing of judging panel crew and is averaged
Value, is determined according to following determinating references with 3 grades.Specifically, observing the shape of the makeup film after each sample is just coated with
State, the texture high to gloss are felt to evaluate.
<absolute evaluation standard>
(scoring): (evaluation)
4: feeling very excellent
3: feeling excellent
2: common
1: feeling slightly worse
0: feeling poor
<determinating reference>
(grade average): (judgement)
More than 3.5 points: ◎
2.5 points more than or lower than 3.5: zero
Lower than 2.5 points: ×
By the result of table 2 and Fig. 1 it is found that appearance color is brilliantly shown as the embodiment 6~11 for implementing product of the invention
Color is high-temperature stability or the oil-based cosmetic material for dyeing difficulty, transparency, excellent gloss.
On the other hand, the content mass ratio of the comparative example 3 without ingredient (B) and ingredient (A) and ingredient (B) is undesirable
Comparative example 4 is unable to get satisfactory colour developing.In addition, it is unable to get satisfactory colour developing about comparative example 3 and 4, because
This " high-temperature stability " is not evaluated.) substitute ingredient (B), containing hydroxyapatite, calcium carbonate, aluminium distearate, (two is hard
Resin acid AL) comparative example 5~7, transparency and gloss difference.In addition, substitute ingredient (B), the comparative example 8 containing DPG, are set as high
Wen Shi, appearance color disappear.
Embodiment 12~17, comparative example 9~14
The oiliness lip cosmetic preparation (solid-like) of composition shown in table 3 is prepared according to following manufacturing methods.To obtained oiliness mouth
Lip cosmetic preparation carries out the degree of " colour developing ", " high temperature of heat tone by evaluation method used in table 1 and table 2
Stability ", " gloss " for being coated on " the dyeing difficulty " when removing cosmetic preparation after skin or skin and the makeup film after coating
Evaluation.In addition, carrying out the evaluation of " transparent feel " of the appearance of cosmetic preparation using following evaluation methods.Its result is also shown in together
Table 3.
[table 3]
(manufacturing method) embodiment 12~17, comparative example 9~14
A. ingredient (1)~ingredient (9) is uniformly mixed.
B. ingredient (10)~ingredient (16) is uniformly mixed using three rollers.
C. B is heated to 110 DEG C, be filled into container, obtain oiliness lip cosmetic preparation.
(transparent feel)
For oiliness lip cosmetic preparation obtained in embodiment 12~17, comparative example 9~14, carry out based on 20 professional judging panels
Use test, each one is evaluated as 5 grades to judging panel in following absolute evaluations, calculates it by the grade summing of judging panel crew and puts down
Mean value is determined according to following determinating references with 3 grades.Specifically, the state of the appearance of each sample is observed, to transparent
The way of feeling of texture (transparent feel) evaluated.
<absolute evaluation standard>
(scoring): (evaluation)
4: having very much transparent feel
3: there is transparent feel
2: common
1: transparent feel is slightly worse
0: feeling that transparent feel is poor (hidden sense is strong)
<determinating reference>
(grade average): (judgement)
More than 3.5 points: ◎
2.5 points more than or lower than 3.5: zero
Lower than 2.5 points: ×
As shown in Table 3, the embodiment 12~17 as implementation product of the invention, appearance brilliantly develops the color, and is high temperature
Stability or the oil-based cosmetic material for dyeing difficulty, transparent feel, excellent gloss.
On the other hand, the content mass ratio of the comparative example 9 without containing ingredient (B) and ingredient (A) and ingredient (B) is not preferred
Comparative example 10, be unable to get satisfactory colour developing.Substitute ingredient (B) contains hydroxyapatite, calcium carbonate, distearyl acid
The comparative example 11~13 of AL, transparent feel and gloss difference.In addition, substitute ingredient (B), the comparative example 14 containing DPG was being manufactured
Appearance color disappears in journey.In addition, being unable to get satisfactory colour developing, therefore " high-temperature stable about comparative example 9,10,14
Property " do not evaluated.
Embodiment 18: nail polish
※ 17:NIKKOL refines avocado oil
※ 18:2-6-DI-TERT-BUTYL-CRESOL (Tokyo is melted into product society system)
※ 19:AEROSIL R976S (Japanese Aerosil society system, average grain diameter 7nm)
※ 20: micro glass METASHINE 1080RS (Japanese plate glass society system, 85 μm of average grain diameter).
(manufacturing method)
A. ingredient (1)~(7) are equably dissolved at 25 DEG C.
B. A is flowed directly into container of having a manicure, obtains nail polish.
Obtained nail polish all makes us full at colour developing, high-temperature stability, dyeing difficulty, transparency, all aspects of gloss
Meaning.Specifically, being ◎ in whole assessment items.In addition, (A)/(B)=0.0067.
Embodiment 19: solid-like cheek is red
※ 21:MULTIWAX W445 (SONNEBORN society system)
※ 22: purification candelila wax SR-3 (Japanese NATURAL PRODUCTS Co. Ltd. system)
※ 23:RISONOL 20SP (higher alcohol industry society system)
※ 24:SILICA MICRO BEAD BA-1 (waves catalyst chemical conversion Co. Ltd. system, 18 μm of average grain diameter day)
※ 25:HELIOS R300S (TOPY industry society system, 210 μm of average grain diameter).
(manufacturing method)
A. ingredient (1)~(8) are equably dissolved at 100 DEG C.
B. A is uniformly mixed using three rollers.
C. ingredient (9)~(10) are added in B, equably mix.
D. C is dissolved at 90 DEG C and is filled in resin ware and cools and solidifies, it is red to obtain solid-like cheek.
The red all aspects in colour developing, high-temperature stability, dyeing difficulty, transparent feel, gloss of obtained solid-like cheek all enable
People is satisfied.It is 〇 in transparent feel, gloss specifically, being ◎ in colour developing, high-temperature stability, dyeing difficulty.In addition,
(A)/(B)=0.0067.
Embodiment 20: solid-like lipstick
※ 26: amino acid system oleogel agent GP-1 (Ajincomoto Co., Inc's system)
※ 27: amino acid system oleogel agent EB-21 (Ajincomoto Co., Inc's system)
※ 28:NOMUCOAT HP-30 (Nisshin Oillio Group Ltd's system)
※ 29:Orgasol 2002D (Atofina Japan society system, 22 μm of average grain diameter)
※ 30: 7 μm of average grain diameter.
(manufacturing method)
A. ingredient (1)~(11) are equably dissolved at 150 DEG C.
B. A is uniformly mixed using three rollers.
C. ingredient (12)~(17) are added in B, equably mix
D. C melting is filled into mold and cooled down, obtain solid-like lipstick.
Obtained solid-like lipstick is all enabled at all aspects of colour developing, high-temperature stability, dyeing difficulty, transparent feel, gloss
People is satisfied.Specifically, being ◎ in whole assessment items.In addition, (A)/(B)=0.0125.
Claims (6)
1. a kind of oil-based cosmetic material contains ingredient below (A) and (B):
(A) a kind or 2 kinds in red No. 218 and red 223
(B) alpha-olefin-vinylpyrrolidone copolymer, content mass ratio (A)/(B) of the ingredient (A) relative to ingredient (B)
It is 2 or less.
2. oil-based cosmetic material according to claim 1, wherein the carbon atom number of the alpha-olefin in the ingredient (B) is 12
~24.
3. oil-based cosmetic material according to claim 1 or 2, wherein the ingredient (B) is hexadecene-vinyl pyrrole
Alkanone copolymer.
4. oil-based cosmetic material described in any one of claim 1 to 3, wherein (A)/(B) be 0.0001 or more and
2 or less.
5. oil-based cosmetic material according to any one of claims 1 to 4, wherein the content of the ingredient (A) is relative to change
Makeup material is 0.1~1 mass %.
6. a kind of colour developing modifier of the oily material containing dyestuff, containing alpha-olefin-vinylpyrrolidone copolymer,
In, the dyestuff is a kind or 2 kinds in red No. 218 and red 223.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2017090334 | 2017-04-28 | ||
| JP2017-090334 | 2017-04-28 | ||
| PCT/JP2018/017281 WO2018199314A1 (en) | 2017-04-28 | 2018-04-27 | Oily cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110402136A true CN110402136A (en) | 2019-11-01 |
| CN110402136B CN110402136B (en) | 2022-10-28 |
Family
ID=63919914
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201880016779.2A Active CN110402136B (en) | 2017-04-28 | 2018-04-27 | Oily cosmetic |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP7288849B2 (en) |
| KR (1) | KR102684988B1 (en) |
| CN (1) | CN110402136B (en) |
| TW (1) | TW201842898A (en) |
| WO (1) | WO2018199314A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7483686B2 (en) * | 2019-03-28 | 2024-05-15 | 株式会社コーセー | Oil-based cosmetics |
| JP7269064B2 (en) * | 2019-03-28 | 2023-05-08 | 株式会社コーセー | oily cosmetics |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06287109A (en) * | 1993-04-01 | 1994-10-11 | Kanebo Ltd | Oily composition for lip |
| CN1225260A (en) * | 1997-12-22 | 1999-08-11 | 莱雅公司 | Non-transfusion cosmetics composition contg. polymer particle dispersant and liposoluble polymer |
| JP2002363033A (en) * | 2001-06-06 | 2002-12-18 | Mikuni Color Ltd | Pigment dispersion for lipstick, method for lipstick composition production and lipstick composition |
| JP2008120687A (en) * | 2006-11-08 | 2008-05-29 | Shiseido Co Ltd | Coloring material for cosmetic and makeup cosmetic |
| US20080233064A1 (en) * | 2007-03-19 | 2008-09-25 | Tabakman Tatyana R | High shine, stick-shaped comsmetic products |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005194220A (en) | 2004-01-05 | 2005-07-21 | L'oreal Sa | COMPOSITION FOR EXTERNAL USE CONTAINING SEMICRYSTALLINE POLYMER AND POLYVINYLPYRROLIDONE-alpha-OLEFIN COPOLYMER, AND METHOD FOR PRODUCING THE COMPOSITION |
| JP2009114161A (en) | 2007-11-05 | 2009-05-28 | Assainir Inc | Transparent base material using gelling agent composition and cosmetic comprising the same |
| JP5657455B2 (en) | 2011-03-31 | 2015-01-21 | 株式会社ナリス化粧品 | Oily cosmetic base and oily cosmetic |
| JP6209052B2 (en) * | 2013-10-24 | 2017-10-04 | 株式会社コーセー | Lip cosmetics |
| TWI764956B (en) * | 2016-11-14 | 2022-05-21 | 日商高絲股份有限公司 | Cosmetics for oily makeup |
-
2018
- 2018-04-27 WO PCT/JP2018/017281 patent/WO2018199314A1/en active Application Filing
- 2018-04-27 KR KR1020197026005A patent/KR102684988B1/en active IP Right Grant
- 2018-04-27 JP JP2019514672A patent/JP7288849B2/en active Active
- 2018-04-27 CN CN201880016779.2A patent/CN110402136B/en active Active
- 2018-04-27 TW TW107114360A patent/TW201842898A/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06287109A (en) * | 1993-04-01 | 1994-10-11 | Kanebo Ltd | Oily composition for lip |
| CN1225260A (en) * | 1997-12-22 | 1999-08-11 | 莱雅公司 | Non-transfusion cosmetics composition contg. polymer particle dispersant and liposoluble polymer |
| JP2002363033A (en) * | 2001-06-06 | 2002-12-18 | Mikuni Color Ltd | Pigment dispersion for lipstick, method for lipstick composition production and lipstick composition |
| JP2008120687A (en) * | 2006-11-08 | 2008-05-29 | Shiseido Co Ltd | Coloring material for cosmetic and makeup cosmetic |
| US20080233064A1 (en) * | 2007-03-19 | 2008-09-25 | Tabakman Tatyana R | High shine, stick-shaped comsmetic products |
Also Published As
| Publication number | Publication date |
|---|---|
| JP7288849B2 (en) | 2023-06-08 |
| CN110402136B (en) | 2022-10-28 |
| KR20190139838A (en) | 2019-12-18 |
| JPWO2018199314A1 (en) | 2020-03-12 |
| TW201842898A (en) | 2018-12-16 |
| KR102684988B1 (en) | 2024-07-16 |
| WO2018199314A1 (en) | 2018-11-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6446414B2 (en) | Semi-permanent mascara composition | |
| JP4906040B2 (en) | Oily cosmetics | |
| AU2006247533B2 (en) | Long wearing glossy cosmetic composition | |
| US20170319454A1 (en) | Makeup cosmetic | |
| JP5657455B2 (en) | Oily cosmetic base and oily cosmetic | |
| CN104470489B (en) | Cosmetic composition including scattering filler and mother-of-pearl | |
| JP5080919B2 (en) | Liquid oily lip cosmetic | |
| WO2018088565A1 (en) | Oily makeup cosmetic | |
| CN110402136A (en) | Oil-based cosmetic material | |
| JP2011506296A (en) | Cosmetic composition comprising polyamide resin, glyceryl ester and nonpolar wax | |
| WO2012133293A1 (en) | Eyelash cosmetic | |
| JP4864414B2 (en) | Oily solid cosmetic | |
| JP2006241003A (en) | Oily solid cosmetic | |
| JP2006219486A (en) | Lip cosmetic | |
| TWI814774B (en) | Oil-based cosmetic and method for producing same | |
| US20180008527A1 (en) | Makeup cosmetic | |
| JP2008156245A (en) | Oil-based cosmetic | |
| JP2003261415A (en) | Oily cosmetic | |
| JP6334184B2 (en) | Oily solid cosmetic | |
| JP6231748B2 (en) | Oily solid cosmetic | |
| WO2012077639A1 (en) | Oil-in-water type eyelash cosmetic | |
| JP2007161590A (en) | Oily solid cosmetic | |
| KR100593526B1 (en) | Lip makeup composition | |
| JP2004175773A (en) | Solid cosmetic and method for producing the same | |
| WO2023180256A1 (en) | Composition comprising ethyl cellulose, a monoalcohol, a volatile hydrocarbon-based oil, a non-volatile alkane oil, a mono- or di-ester of a fatty acid and of polyglycerol and an ester oil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 40009056 Country of ref document: HK |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |