KR20190139838A - Oil-based cosmetics - Google Patents
Oil-based cosmetics Download PDFInfo
- Publication number
- KR20190139838A KR20190139838A KR1020197026005A KR20197026005A KR20190139838A KR 20190139838 A KR20190139838 A KR 20190139838A KR 1020197026005 A KR1020197026005 A KR 1020197026005A KR 20197026005 A KR20197026005 A KR 20197026005A KR 20190139838 A KR20190139838 A KR 20190139838A
- Authority
- KR
- South Korea
- Prior art keywords
- oil
- cosmetics
- component
- red
- color
- Prior art date
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 87
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/08—Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/001—Preparations for care of the lips
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
[과제] 본 발명은, 선명한 외관색을 지니면서도, 고온 안정성 및 윤기가 우수한 유성 화장료를 제공하는 것을 과제로 한다.
[해결 수단] 본 발명은, (A) 적색 218호, 적색 223호로부터 선택되는 1종 또는 2종과, (B) α-올레핀-비닐피롤리돈 공중합체를 특정한 함유 질량비율((A)/(B)가 2 이하)을 함유시킴으로써, 선명한 외관색을 지니면서도, 고온 안정성 및 윤기가 우수한 유성 화장료를 제공하는 것이다.[PROBLEMS] To provide an oily cosmetic having excellent vivid color and excellent in high temperature stability and gloss.
[Measures] The present invention provides a mass ratio of (A) one or two selected from red 218 and red 223, and (B) an α-olefin-vinylpyrrolidone copolymer. / (B) is 2 or less) to provide an oily cosmetic having a clear appearance color and excellent temperature stability and gloss.
Description
본 발명은, 선명한 외관색을 지니면서도, 고온 안정성 및 윤기가 우수한 유성 화장료 및, α-올레핀-비닐피롤리돈 공중합체를 함유한 발색 향상제에 관한 것이다.The present invention relates to an oily cosmetic having a clear appearance color and excellent in high temperature stability and gloss, and a color improving agent containing an α-olefin-vinylpyrrolidone copolymer.
유성 화장료란, 오일상을 연속상으로 하는 화장료이며, 화장 유지성이 우수하므로, 입술연지(口紅, 이하, "립스틱"이라 칭함), 립글로스, 볼연지, 아이컬러 등의 화장료에 많이 이용되고 있다. 또 최근에는, 기호성이 다양화되고, 화장 유지성이나 윤기뿐만 아니라, 선명한 외관색을 띠는 화장료 등이 요구되고 있고, 선명한 색을 구현하기 위해서, 적색 218호 등의 염료가 널리 이용되고 있다. 그러나, 유성 성분을 주성분으로 하는 유성 화장료에 적색 218호 등의 염료를 단지 함유한 것만으로는 선명한 발색이 보이지 않는다. 이 때문에, 염료에 의해서 유성 화장료의 외관색을 부여하기 위해서, 유성 화장료에 다른 성분을 첨가하는 시도가 이루어지고 있다. 예를 들면, 덱스트린 지방산 에스터, 다이프로필렌글리콜 및 염료를 조합시킴으로써, 충분한 외관색을 부여하는 기술이 알려져 있다(일본국 공개 특허 제2004-175773호 공보). 또, 고급 지방산 금속염과 염료를 조합시킴으로써, 선명한 외관색을 구현하는 기술이 알려져 있다(일본국 공개 특허 제2016-132650호 공보(미국 특허 출원 공개 제2017/319454호 명세서)).Oil-based cosmetics are cosmetics in which an oil phase is a continuous phase, and since cosmetics have excellent makeup retention property, they are frequently used in cosmetics such as lip balm (hereinafter referred to as "lipstick"), lip gloss, cheek lip balm, and eye color. Moreover, in recent years, palatability has diversified, cosmetic makeup etc. which have not only makeup retention property and gloss but a vivid exterior color are calculated | required, and dyes, such as red 218, are widely used to implement a vivid color. However, only the dyes, such as red No. 218, are contained in the oil-based cosmetics which contain an oil-based component as a main component, and vivid color development is not seen. For this reason, in order to provide the external appearance color of oily cosmetics with dye, the attempt to add another component to oily cosmetics is made. For example, the technique which gives sufficient external color by combining dextrin fatty acid ester, dipropylene glycol, and dye is known (Unexamined-Japanese-Patent No. 2004-175773). Moreover, the technique which implements a vivid external color by combining a higher fatty acid metal salt and dye is known (Unexamined-Japanese-Patent No. 2016-132650 (US Patent Application Publication No. 2017/319454 specification)).
그러나, 일본국 공개 특허 제2004-175773호 공보의 기술에서는, 고온에서의 안정성이 뒤떨어지고, 립스틱이나 립글로스 등을 제조할 때에, 고온(예를 들면 100℃ 전후)에서 가열하면 선명한 색이 사라져 버릴 경우가 있었다. 또, 일본국 공개 특허 제2016-132650호 공보(미국 특허 출원 공개 제2017/319454호 명세서)의 기술에서는, 선명한 색은 발현되지만, 발색을 향상시키기 위해서 발색인자인 분체의 고급지방산 금속염을 첨가해가면, 화장료를 피부에 도포했을 때의 화장막에 있어서, 만족스러운 윤기가 얻어지지 않을 경우가 있었다.However, in the technique of Japanese Patent Laid-Open No. 2004-175773, stability at high temperatures is inferior, and vivid colors disappear when heated at high temperatures (for example, around 100 ° C) when manufacturing lipsticks, lip gloss, and the like. There was a case. In addition, in the technique of Japanese Unexamined Patent Publication No. 2016-132650 (US Patent Application Publication No. 2017/319454), a vivid color is expressed, but in order to improve color development, a higher fatty acid metal salt of powder, which is a coloring factor, is added. In the cosmetic film at the time of applying a cosmetic to a mask, satisfactory gloss may not be obtained.
따라서 본 발명은, 선명한 외관색을 지니면서도, 고온 안정성(고온가열 후이더라도 선명한 외관색이 유지됨) 및 화장막의 윤기가 우수한 유성 화장료를 제공하는 것을 과제로 한다.Therefore, an object of the present invention is to provide an oily cosmetic having a clear appearance color and excellent in high temperature stability (a clear appearance color is maintained even after high temperature heating) and the glossiness of the makeup film.
이러한 실상에 비추어, 본 발명자들은 예의 검토한 결과, 적색계통의 염료인 (A) 적색 218호 및 적색 223호로부터 선택되는 1종 또는 2종과, 질소원자를 구조 중에 갖는 (B) α-올레핀-비닐피롤리돈 공중합체를 특정한 함유 질량 비율(함유 질량비)((A)/(B)가 2 이하)로 조합시킴으로써, 선명한 외관색을 지니면서도, 고온 안정성 및 윤기가 우수한 유성 화장료가 얻어지는 것을 찾아내어, 본 발명품을 완성시키기에 이르렀다.In view of the above facts, the present inventors have diligently studied, and as a result, one or two selected from red dyes (A) red 218 and red 223 and (B) alpha -olefins having nitrogen atoms in the structure By combining the vinylpyrrolidone copolymer with a specific content ratio (mass ratio) ((A) / (B) is 2 or less), an oily cosmetic having excellent vivid color and excellent temperature stability and gloss is obtained. It was found and completed the present invention.
즉, 본 발명은,That is, the present invention,
(1) 다음의 성분 (A) 및 (B):(1) the following components (A) and (B):
(A) 적색 218호 및 적색 223호로부터 선택되는 1종 또는 2종; 및(A) one or two selected from red 218 and red 223; And
(B) α-올레핀-비닐피롤리돈 공중합체(B) α-olefin-vinylpyrrolidone copolymer
를 함유하고, 성분 (B)에 대한 성분 (A)의 함유 질량비율 (A)/(B)가 2 이하인 유성 화장료에 관한 것이다.It is related with the oil-based cosmetics which contain and whose content mass ratio (A) / (B) of a component (A) with respect to a component (B) is two or less.
(2) 성분 (B)에 있어서의 α-올레핀이 탄소수 12 내지 24인, 상기 (1)에 기재된 유성 화장료이다.(2) The (alpha) -olefin in component (B) is an oil-based cosmetic as described in said (1) whose carbon number is 12-24.
(3) 성분 (B)가 헥사데센-비닐피롤리돈 공중합체인, 상기 (1) 또는 (2)에 기재된 유성 화장료에 관한 것이다.(3) Component (B) relates to the oil-based cosmetic according to the above (1) or (2), wherein the hexadecene-vinylpyrrolidone copolymer is used.
(4) 상기 (A)/(B)가 0.0001 이상 2 이하인, 상기 (1) 내지 (3) 중 어느 하나에 기재된 유성 화장료이다.(4) The oily cosmetic according to any one of the above (1) to (3), wherein (A) / (B) is 0.0001 or more and 2 or less.
(5) 성분 (A)의 함유량이 화장료에 대해서 0.1 내지 1질량%인, 상기 (1) 내지 (4) 중 어느 하나에 기재된 유성 화장료이다.(5) Content of component (A) is an oil-based cosmetic in any one of said (1)-(4) which is 0.1-1 mass% with respect to cosmetics.
(6) α-올레핀-비닐피롤리돈 공중합체를 함유하는, 염료를 포함하는 유성 재료의 발색 향상제이며, 염료는 적색 218호 및 적색 223호로부터 선택되는 1종 또는 2종인, 발색 향상제이다.(6) It is a color improving agent of the oil-based material containing dye containing the (alpha)-olefin-vinylpyrrolidone copolymer, and a dye is a color improving agent which is 1 type or 2 types chosen from red 218 and red 223.
성분 (A) 적색 218호, 적색 223호로부터 선택되는 1종 또는 2종 및 성분 (B) α-올레핀-비닐피롤리돈 공중합체를 함유하는 발색 향상제에 관한 것이다.It relates to a color improving agent containing one or two kinds selected from component (A) red 218 and red 223 and component (B) α-olefin-vinylpyrrolidone copolymer.
도 1은 실시예 6 및 비교예 3의 유성 입술용 화장료를 피부에 도포한 후, 화장료를 제거했을 때의 "염착(染着)되기 어려움"(이하, "염착 비감수성"이라 표기함)을 평가한 결과를 나타낸다.FIG. 1 shows "difficult to dye" when the cosmetics for oily lips of Examples 6 and Comparative Example 3 are applied to the skin, and hereinafter referred to as "non-dyeing". The evaluation result is shown.
본 발명의 상세에 대해서 이하에 설명한다. 또, 본 명세서에 있어서, "내지"는 그 전후의 수치를 포함하는 범위를 의미하는 것으로 한다. 또, 특기하지 않는 한, 조작 및 물성 등의 측정은 실온(20 내지 25℃)/상대습도 40 내지 50% RH의 조건에서 행한다.The detail of this invention is demonstrated below. In addition, in this specification, "-" shall mean the range containing the numerical value before and behind that. In addition, unless otherwise mentioned, operation, a measurement of a physical property, etc. are performed on the conditions of room temperature (20-25 degreeC) / relative humidity 40-50% RH.
본 발명은, 다음 성분 (A) 및 (B):The present invention provides the following components (A) and (B):
(A) 적색 218호, 적색 223호로부터 선택되는 1종 또는 2종; 및(A) one or two selected from red 218 and red 223; And
(B) α-올레핀-비닐피롤리돈 공중합체(B) α-olefin-vinylpyrrolidone copolymer
를 함유하고, 성분 (B)에 대한 성분 (A)의 함유 질량 비율(함유 질량비) (A)/(B)가 2 이하인 유성 화장료이다. 본 발명의 유성 화장료는, 선명한 외관색을 지니면서도, 고온 안정성 및 윤기가 우수한 것이다.It is an oil-based cosmetic which contains and is a content mass ratio (content mass ratio) (A) / (B) of a component (A) with respect to a component (B). The oily cosmetic of the present invention is excellent in high temperature stability and gloss while having a clear appearance color.
예를 들면, 유성 입술용 화장료 등의 (반)고체 형태의 제형에 있어서는, 100℃ 전후로 가온시킴으로써, 용기에 충전한다는 프로세스를 채용하는 경우가 있다. 본 발명의 유성 화장료에 있어서는, 100℃ 전후라는 고온에 화장료가 폭로되어도, 선명한 외관색을 유지할 수 있는, 즉, 고온 안정성이 우수하다.For example, in the form of (semi) solid form, such as an oily lip cosmetics, the process of filling into a container may be employ | adopted by heating to about 100 degreeC. In the oil-based cosmetic of the present invention, even when the cosmetic is exposed at a high temperature of around 100 ° C, a clear appearance color can be maintained, that is, excellent in high temperature stability.
상기 효과를 발휘하는 상세한 메커니즘은 불분명하지만, 성분 (B)가 성분 (A)와 결합 또는 반응함으로써, 성분 (A)가 화장료 중에서 선명하게 발색되게 되는 것으로 여겨진다. 그리고, 이러한 결합 또는 반응은 고온하에서도 불가역적이기 때문에, 화장료가 고온에서 가열된 후에도, 선명한 외관색이 유지되는 것으로 여겨진다. 또한, 성분 (A)가 성분 (B)와 결합 또는 반응함으로써, 피부 상에 화장료가 도포되었을 때에, 성분 (A)가 피부와 결합하는 것이 억제되어, 화장료를 제거한 후의 염착도 억제된다(후술하는 실시예 참조). 또한, 성분 (B)가 유성이기 때문에, 화장료를 도포한 후에 화장막에 윤기를 부가할 수 있는 것으로 여겨진다.Although the detailed mechanism for exerting the above effect is unclear, it is believed that the component (A) is vividly developed in the cosmetic by combining or reacting the component (B) with the component (A). And since such a bond or reaction is irreversible even at high temperature, it is believed that a vivid appearance color is maintained even after the cosmetic is heated at a high temperature. Moreover, when component (A) binds or reacts with component (B), when cosmetics are apply | coated on skin, it is suppressed that component (A) binds with skin, and also dyeing after removing cosmetics is also suppressed (to be described later) See example. In addition, since component (B) is oily, it is thought that gloss can be added to a makeup film after apply | coating cosmetics.
본 발명의 유성 화장료란, 유제나 유용성 화합물인 유성 성분의 오일상을 연속상으로 하는 유성 화장료인 것이 바람직하며, 본 발명의 효과를 현저하게 발휘할 수 있는 점에서, 물의 함유량은, 유성 화장료 중 0.5질량% 이하(하한 0질량%)인 것이 바람직하고, 0.1질량% 이하(하한 0질량%)인 것이 또한 바람직하며, 0질량%(물을 함유하지 않음)인 것이 특히 바람직하다.The oily cosmetic of the present invention is preferably an oily cosmetic comprising an oil phase of an oily component which is an oil agent or an oil-soluble compound in a continuous phase, and the water content is 0.5 in the oily cosmetics in that the effect of the present invention can be remarkably exhibited. It is preferable that it is mass% or less (lower limit 0 mass%), It is also preferable that it is 0.1 mass% or less (lower limit 0 mass%), It is especially preferable that it is 0 mass% (it does not contain water).
본 발명에 이용되는 성분 (A)의 적색 218호(테트라클로로테트라브로민플루오레세인), 적색 223호(테트라브로민플루오레세인)란, 플루오란계의 유용성 염료의 일종이며, 타르 색소로 분류된다. 적색을 발색하기 위해서, 립스틱 등의 메이크업 화장료에 널리 이용되고 있는 착색제이다. 시판품으로서는, 예를 들어, TPP 적색 218호, TPP 적색 223호(이상, 키시카세이(癸巳化成) 주식회사 제품) 등을 들 수 있고, 이들을 1종 또는 2종 이상 이용할 수 있다. 이들 중에서도, 특별히 한정되지 않지만, 내광성이 보다 우수한 점 등으로부터, 적색 218호를 이용하는 것이 보다 바람직하다.Red 218 (tetrachlorotetrabromine fluorescein) and red 223 (tetrabromine fluorescein) of the component (A) used for this invention are a kind of oil-soluble dye of a fluorane system, Are classified. In order to develop red color, it is a coloring agent widely used for makeup cosmetics, such as a lipstick. As a commercial item, TPP red 218, TPP red 223 (above, Kishikase Co., Ltd.) etc. are mentioned, for example, These can be used 1 type or 2 types or more. Although it does not specifically limit among these, It is more preferable to use red 218 from the point which is more excellent in light resistance.
본 발명에 이용되는 성분 (A)의 함유량은, 특별히 한정되지 않지만, 발색, 투명도(클리어감(クリア感))가 우수한 등의 관점에서, 화장료에 대해서, 0.0001 내지 10질량%(이하 단지 "%"라 기재함)인 것이 바람직하고, 0.001 내지 5%인 것이 보다 바람직하며, 0.01 내지 1%인 것이 또한 보다 바람직하고, 0.1 내지 1%인 것이 특히 바람직하다.Although content of the component (A) used for this invention is not specifically limited, From a viewpoint of being excellent in color development, transparency (clear feeling), 0.0001-10 mass% (hereinafter only "%) with respect to a cosmetics. Is preferably 0.001 to 5%, more preferably 0.01 to 1%, particularly preferably 0.1 to 1%.
본 발명에 이용되는 성분 (B)의 α-올레핀-비닐피롤리돈 공중합체란, α-올레핀과 비닐피롤리돈의 공중합체이다.The alpha-olefin-vinylpyrrolidone copolymer of the component (B) used for this invention is a copolymer of alpha-olefin and vinylpyrrolidone.
α-올레핀으로서는, 본 발명의 효과가 한층 발휘되는 것으로부터, 탄소수 12 내지 24인 것이 바람직하고, 탄소수 14 내지 22인 것이 보다 바람직하며, 탄소수 16 내지 20인 것이 더욱 바람직하다.As alpha-olefin, since the effect of this invention is exhibited further, it is preferable that it is C12-24, It is more preferable that it is C14-22, It is still more preferable that it is C16-20.
α-올레핀으로서는, 구체적으로는, 펜타데센, 헥사데센, 헵타데센, 옥타데센, 노나데센, 또는 에이코센을 들 수 있다. 이들 α-올레핀은 1종 단독이라도 2종 이상이어도 된다.Specific examples of the α-olefin include pentadecene, hexadecene, heptadecene, octadecene, nonadecene, or eicosene. These alpha -olefins may be used alone or in combination of two or more.
이들 중, 본 발명의 효과가 한층 발휘되는 것으로부터, α-올레핀-비닐피롤리돈 공중합체로서는, 펜타데센-비닐피롤리돈 공중합체, 헥사데센-비닐피롤리돈 공중합체, 헵타데센-비닐피롤리돈 공중합체, 옥타데센-비닐피롤리돈 공중합체, 노나데센-비닐피롤리돈 공중합체, 또는 에이코센-비닐피롤리돈 공중합체인 것이 바람직하고, 헥사데센-비닐피롤리돈 공중합체, 또는 에이코센-비닐피롤리돈 공중합체인 것이 보다 바람직하며, 헥사데센-비닐피롤리돈 공중합체인 것이 더욱 바람직하다.Among these, since the effect of this invention is exhibited further, as an alpha-olefin- vinylpyrrolidone copolymer, a pentadecene-vinylpyrrolidone copolymer, a hexadecene-vinylpyrrolidone copolymer, heptadecene-vinyl Pyrrolidone copolymer, octadecene-vinylpyrrolidone copolymer, nonadecene-vinylpyrrolidone copolymer, or eicosene-vinylpyrrolidone copolymer, hexadecene-vinylpyrrolidone copolymer, Or an eicosene-vinylpyrrolidone copolymer, more preferably a hexadecene-vinylpyrrolidone copolymer.
성분 (B)의 성상으로서는, 특별히 한정되지 않지만, 윤기가 우수한 등의 관점에서, 25℃에서 액상인 것이 바람직하다. 여기서, 액상이란, 25℃에서 유동성을 지니는 것을 가리킨다. 보다 구체적으로는, 화합물을 45° 기울인 경우, 그 형상을 10분 이상 유지할 수 없어, 형상의 변화를 일으키는 것을 지칭한다. 시판품으로서, 예를 들어, ANTARON V216, V220F(이상, 아이에스피재팬 주식회사 제품) 등을 들 수 있고, 1종 또는 2종 이상을 이용할 수 있다.Although it does not specifically limit as a property of a component (B), It is preferable that it is a liquid at 25 degreeC from a viewpoint of being excellent in glossiness. Here, a liquid state means having fluidity at 25 degreeC. More specifically, when the compound is tilted at 45 °, the shape cannot be maintained for 10 minutes or more, and refers to a change in shape. As a commercial item, ANTARON V216, V220F (above, ISSP Japan Co., Ltd.) etc. are mentioned, for example, 1 type, or 2 or more types can be used.
본 발명에 이용되는 성분 (B)의 함유량은, 특별히 한정되지 않지만, 발색, 윤기, 고온 안정성이 우수한 등의 관점에서, 0.001 내지 70%인 것이 바람직하고, 0.01 내지 50%인 것이 보다 바람직하며, 0.1 내지 30%인 것이 또한 보다 바람직하며, 5 내지 20%인 것이 특히 바람직하다.Although content of the component (B) used for this invention is not specifically limited, From a viewpoint of color development, gloss, and high temperature stability, etc., it is preferable that it is 0.001 to 70%, It is more preferable that it is 0.01 to 50%, It is more preferable that it is 0.1 to 30%, and it is especially preferable that it is 5 to 20%.
본 발명에 있어서의 성분 (A)에 대한 성분 (B)의 함유 질량비율인 (A)/(B)(이하, 단지 (A)/(B)라 칭함)는 2 이하이다. (A)/(B)가 2보다 크다면 만족스러운 발색이 얻어지지 않는다. 또, 발색의 관점에서, (A)/(B)가 0.0001 이상인 것이 바람직하고, 0.001 이상인 것이 보다 바람직하며, 0.002 이상인 것이 더욱 바람직하다. 또한, 발색의 관점에서, (A)/(B)가 1 이하인 것이 바람직하고, 윤기의 관점에서, (A)/(B)가 0.5 이하인 것이 바람직하다. 특별히 한정되지 않지만, 발색, 고온 안정성, 투명도(클리어감), 윤기가 우수한 등의 관점에서, (A)/(B)=0.0001 내지 2인 것이 바람직하고, 0.001 내지 1인 것이 보다 바람직하며, 0.002 내지 1인 것이 또한 보다 바람직하고, 0.005 내지 1인 것이 특히 바람직하며, 0.005 내지 0.5인 것이 가장 바람직하다.(A) / (B) (Hereinafter, only (A) / (B)) which is a content mass ratio of component (B) with respect to component (A) in this invention is two or less. If (A) / (B) is larger than 2, satisfactory color development cannot be obtained. Moreover, it is preferable that (A) / (B) is 0.0001 or more from a viewpoint of color development, It is more preferable that it is 0.001 or more, It is further more preferable that it is 0.002 or more. Moreover, it is preferable that (A) / (B) is 1 or less from a viewpoint of color development, and it is preferable that (A) / (B) is 0.5 or less from a viewpoint of glossiness. Although it does not specifically limit, From a viewpoint of color development, high temperature stability, transparency (clear feeling), glossiness, etc., it is preferable that it is (A) / (B) = 0.0001-2, It is more preferable that it is 0.001-1, 0.002 It is also more preferable that it is -1, It is especially preferable that it is 0.005-1, It is most preferable that it is 0.005-0.5.
본 실시형태의 유성 화장료는, 유제를 함유하는 것이 바람직하다. 유제로서는, 액상유, 고형유, 페이스트 형태 또는 고체 형태의 유제를 포함할 수 있다.It is preferable that the oil-based cosmetics of this embodiment contain an oil agent. The oily agent may include liquid oil, solid oil, paste or solid oil.
액상유로서는, 구체적으로는, 아이소도데칸, 아이소헥사데칸, 경질 아이소파라핀, 유동 파라핀, 스쿠왈란, 스쿠왈렌, α-올레핀 올리고머, 폴리부텐, 유동 아이소파라핀, 중질 유동 아이소파라핀, 폴리아이소부티렌, 수첨 폴리아이소부텐 등의 탄화수소류, 유채 종자유, 아보카도유, 아몬드유, 살구핵유, 들깨유, 오렌지유, 올리브유, 키위 종자유, 참깨유, 밀배아유, 쌀배아유, 쌀겨유, 잇꽃유, 세이지유, 대두유, 녹차씨유, 옥수수유, 유채씨유, 달맞이꽃유, 동백유, 살구씨유, 율무유, 땅콩유, 해바라기유, 포도씨유, 메도우폼유, 로즈메리유, 호호바유, 마카다미아 너트유, 라벤더유, 로즈힙(rose hip) 오일, 밍크오일 등의 동식물유; 트라이2-에틸헥산산글리세릴, 아이소노난산 아이소트라이데실, 아이소노난산 아이소노닐, 2-에틸헥산산 세틸, 미리스트산 아이소프로필, 팔미트산 아이소프로필, 팔미트산-2-에틸 헥실, 미리스트산 옥틸도데실, 트라이옥탄산 글리세릴, 트라이(카프릴·카프르산)글리세릴, 다이아이소스테아르산 글리세릴, 트라이아이소스테아르산 글리세릴, 데카아이소스테아르산 데카글리세릴(데카아이소스테아르산 폴리글리세릴-10), 다이카프르산 프로필렌글라이콜, 다이카프르산 네오펜틸글리콜, 트라이아이소스테아르산 폴리글리세릴, 말산 다이아이소스테아릴, 다이에틸헥산산 네오펜틸글리콜, 테트라 아이소스테아르산 펜타에리트리틸, 테트라2-에틸헥산산 펜타에리트리틸, 펜타아이소스테아르산 다이펜타에리트리틸, 탄산다이알킬, 사이클로헥산-1,4-다이카복실산 비스에톡시다이글리콜, 다이머 다이리놀레일 수첨로진 축합물, 트라이멜리트산 트라이데실 등의 에스터류; 올레산, 아이소스테아르산 등의 지방산류; 올레일알코올, 2-옥틸도데칸올, 2-데실테트라데칸올, 아이소스테아릴알코올, 2-헥실데칸올 등의 고급 알코올류; 다이메틸폴리실록산(다이메티콘), 메틸트라이메티콘, 메틸페닐폴리실록산, 옥타메틸사이클로테트라실록산, 데카메틸사이클로펜타실록산, 테트라메틸테트라하이드로젠 사이클로테트라실록산, 테트라메틸테트라페닐사이클로테트라실록산, 테트라메틸 테트라트라이플루오로프로필사이클로테트라실록산, 펜타메틸펜타트라이플루오로프로필사이클로펜타실록산, 폴리에터 변성 메틸폴리실록산, 올레일 변성 메틸폴리실록산, 폴리비닐피롤리돈 변성 메틸폴리실록산 등의 실리콘 오일류; 퍼플루오로폴리에터, 퍼플루오로데칸, 퍼플루오로옥탄 등의 불소계 유제류; 아세트산 라놀린, 라놀린 지방산 아이소프로필, 라놀린 알코올 등의 라놀린 유도체류; 파라메톡시신남산 2-에틸헥실, 살리실산 에틸헥실 등의 액상의 자외선흡수제 등을 들 수 있다.Specific examples of the liquid oil include isododecane, isohexadecane, light isoparaffin, liquid paraffin, squalane, squalene, α-olefin oligomer, polybutene, liquid isoparaffin, heavy liquid isoparaffin, and polyisobutyrene. Hydrocarbons such as hydrogenated polyisobutene, rapeseed seed oil, avocado oil, almond oil, apricot kernel oil, perilla oil, orange oil, olive oil, kiwi seed oil, sesame oil, wheat germ oil, rice germ oil, rice bran oil, safflower oil, Sage Oil, Soybean Oil, Green Tea Seed Oil, Corn Oil, Rape Seed Oil, Evening Primrose Oil, Camellia Oil, Apricot Seed Oil, Yulmu Oil, Peanut Oil, Sunflower Oil, Grapeseed Oil, Meadowfoam Oil, Rosemary Oil, Jojoba Oil, Macadamia Nut Oil Animal and vegetable oils such as lavender oil, rose hip oil and mink oil; Glyceryl tri2-ethylhexanoate, isotrinoyl isononate, isononyl isononanoate, 2-ethylhexanoate cetyl, isopropyl myristic acid, isopropyl palmitic acid, 2-ethylhexyl palmitate , Octyldodecyl myristic acid, glyceryl trioctanoate, glyceryl tri (capryl capric acid), glyceryl diisostearate, glyceryl triisostearate, decaglyceryl decaisostearate (decaiso) Stearic acid polyglyceryl-10), dicaproic propylene glycol, dicapric acid neopentylglycol, triisostearic acid polyglyceryl, diisostearyl malic acid neopentylglycol, tetra isopropyl Stearate pentaerythritol, tetra 2-ethylhexanoate pentaerythritol, pentaisostearic acid dipentaerythritol, dialkyl carbonate, cyclohexane-1,4-dica Esters such as bisethoxydiglycolic acid acid, dimer dilinoleyl hydrogenated condensate and trimellitic acid tridecyl; Fatty acids such as oleic acid and isostearic acid; Higher alcohols such as oleyl alcohol, 2-octyldodecanol, 2-decyl tetradecanol, isostearyl alcohol, and 2-hexyldecanol; Dimethylpolysiloxane (dimethicone), methyltrimethicone, methylphenylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, tetramethyltetrahydrocyclocyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane, tetramethyl tetratritri Silicone oils such as fluoropropylcyclotetrasiloxane, pentamethylpentatrifluoropropylcyclopentasiloxane, polyether-modified methylpolysiloxane, oleyl-modified methylpolysiloxane and polyvinylpyrrolidone-modified methylpolysiloxane; Fluorine emulsions such as perfluoropolyether, perfluorodecane and perfluorooctane; Lanolin derivatives such as lanolin acetate, lanolin fatty acid isopropyl and lanolin alcohols; Liquid ultraviolet absorbers, such as 2-ethylhexyl paramethoxy cinnamic acid and ethylhexyl salicylate, etc. are mentioned.
또, 액상유란 25℃에서 액상의 (유동성을 지니는) 오일을 가리킨다.In addition, liquid oil refers to liquid (having fluidity) oil at 25 degreeC.
페이스트 상태 또는 고체 형태의 유제로서는, 카카오 지방, 시어버터, 피마자유, 경화 피마자유, 경화 야자유, 바셀린, 모노스테아르산 경화 피마자유, 모노하이드록시스테아르산 경화 피마자유, 하이드록시스테아릴산 콜레스테릴, 다이펜타에리트리틸지방산 에스터, N-라우로일-L-글루탐산-다이(옥틸도데실/콜레스테릴/베헤닐), N-라우로일-L-글루탐산-다이(옥틸도데실/피토스테릴/베헤닐), 마카다미아 너트유 지방산 피토스테릴, 다이머 다이리놀레산(피토스테릴/아이소스테아릴/세틸/스테아릴/베헤닐) 등의 페이스트 형태의 유제; 스테아르산, 베헨산, 팔미트산 세틸, 다이스테아르산 폴리에틸렌 글라이콜, 트라이베헨산글리세릴, 콜레스테롤, 피토스테롤, 스테아릴 변성 폴리실록산, 경화유, 팜유 등의 고체 형태의 유제를 들 수 있다.Paste or solid emulsions include cacao fat, shea butter, castor oil, hardened castor oil, hardened palm oil, petrolatum, monostearic acid hardened castor oil, monohydroxystearic acid hardened castor oil, hydroxystearyl acid cholester Reel, dipentaerythrylfatty acid ester, N-lauroyl-L-glutamic acid-di (octyldodecyl / cholesteryl / behenyl), N-lauroyl-L-glutamic acid-di (octyldodecyl / Emulsions in the form of pastes such as phytosteryl / behenyl), macadamia nut oil fatty acid phytosteryl, dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl); Solid oils such as stearic acid, behenic acid, cetyl palmitate, polyethylene glycol distearate, glyceryl tribehenate, cholesterol, phytosterol, stearyl modified polysiloxane, hardened oil and palm oil.
유제는 1종 단독으로 이용해도 2종 이상 병용해도 된다.An oil agent may be used individually by 1 type, or may use 2 or more types together.
유제의 함유량으로서는, 제형, 감촉 등을 고려해서 적당히 설정되지만, 유성 화장료 중, 10 내지 99.9질량%인 것이 바람직하다.As content of an oil agent, although it sets suitably in consideration of a formulation, a touch, etc., it is preferable that it is 10-99.9 mass% in an oil-based cosmetic.
본 발명의 유성 화장료는, 상기 성분 (A) 및 (B) 이외에, 본 발명의 효과를 방해하지 않는 범위에서, 통상 화장료에 사용되는 성분, 분체, 계면활성제, 수용성고분자, 파라옥시벤조산 유도체, 방부제, 고형의 자외선흡수제, 보습제, 항균제, 향료, 염류, 산화 방지제, pH조정제, 킬레이트제, 청량제, 항염증제, 피부미용용 성분(미백제, 세포부활제, 피부거칠음 개선제, 혈행촉진제, 피부수렴제, 항지누제 등), 비타민류, 아미노산류, 핵산, 호르몬, 포접 화합물 등을 적당히 함유할 수 있다.Oily cosmetics of the present invention, in addition to the components (A) and (B), components, powders, surfactants, water-soluble polymers, paraoxybenzoic acid derivatives, and preservatives which are usually used in cosmetics within a range that does not interfere with the effects of the present invention. , UV absorbers, moisturizers, antibacterial agents, fragrances, salts, antioxidants, pH adjusters, chelating agents, refreshing agents, anti-inflammatory agents, skin care ingredients (whitening agents, cell-activating agents, skin roughness improving agents, blood stimulators, skin astringents, anti-gelatinizers) And the like), vitamins, amino acids, nucleic acids, hormones, clathrate compounds and the like.
본 발명에서 이용되는 분체로서는, 통상, 화장료에 이용되는 분체이면, 구 형상, 판 형상, 바늘 형상 등의 형상이나, 연무 형태, 미립자, 안료급 등의 입자 직경이나, 다공질, 무공질 등의 입자구조 등에 의해 특별히 한정되지 않고, 무기 분체류, 광휘성 분체류, 유기 분체류, 색소 분체류, 복합 분체류 등의 1종 또는 2종 이상을 사용할 수 있다.As a powder used by this invention, if it is a powder normally used for cosmetics, it will be spherical shape, plate shape, needle shape, etc. shape, mist form, particle size, such as fine particle, pigment grade, particle | grains, such as porous and nonporous It does not specifically limit by a structure etc., 1 type, or 2 or more types, such as inorganic powder, bright powder, organic powder, pigment powder, complex powder, can be used.
그러나, 입자 직경이 큰 분체를 함유함으로써, 화장막의 윤기가 저하되고, 또한, 화장료의 투명도나 클리어감이 저하하는 경향이 있다. 이 때문에, 평균 입자 직경이 1㎛ 이상인 분체의 화장료에 있어서의 함유량은, 10% 이하(하한 0%)인 것이 바람직하고, 5% 이하(하한 0%)인 것이 보다 바람직하며, 1% 미만(하한 0%)인 것이 특히 바람직하다. 여기서, 평균 입자 직경은 주사형 전자현미경에 의해 관찰한 화상으로부터 산출할 수 있다.However, by containing powder with a large particle diameter, the glossiness of a makeup film falls, and there exists a tendency for transparency and a clear feeling of a cosmetics to fall. For this reason, it is preferable that content in the cosmetics of powder whose average particle diameter is 1 micrometer or more is 10% or less (lower limit 0%), It is more preferable that it is 5% or less (lower limit 0%), and it is less than 1% ( The lower limit is 0%). Here, an average particle diameter can be computed from the image observed with the scanning electron microscope.
상기 무기 분체류로서는, 산화티타늄, 흑색 산화티타늄, 감청, 군청, 벵골라, 황색산화철, 흑색산화철, 산화아연, 산화알루미늄, 실리카, 산화마그네슘, 산화지르코늄, 탄산마그네슘, 탄산칼슘, 산화크롬, 수산화크롬, 카본블랙, 규산알루미늄, 규산마그네슘, 규산알루미늄마그네슘, 마이카, 합성 마이카, 세리사이트, 탤크, 카올린, 탄화규소, 황산바륨, 벤토나이트, 스멕타이트 및 질화붕소 등으로부터 선택되는 1종 또는 2종 이상을 이용할 수 있다. 본 발명에 있어서의 무기 분체류의 화장료에 있어서의 함유량은, 특별히 한정되지 않지만, 윤기나 투명도(클리어감)가 우수한 등의 관점에서, 10% 이하(하한 0%)인 것이 바람직하고, 5% 이하(하한 0%)인 것이 보다 바람직하며, 1% 미만(하한 0%)인 것이 특히 바람직하다.Examples of the inorganic powders include titanium oxide, black titanium oxide, blue wire, ultramarine blue, bengal, yellow iron oxide, black iron oxide, zinc oxide, aluminum oxide, silica, magnesium oxide, zirconium oxide, magnesium carbonate, calcium carbonate, chromium oxide, and hydroxide. One or two or more selected from chromium, carbon black, aluminum silicate, magnesium silicate, magnesium aluminum silicate, mica, synthetic mica, sericite, talc, kaolin, silicon carbide, barium sulfate, bentonite, smectite and boron nitride It is available. Although content in the cosmetics of the inorganic powders in this invention is not specifically limited, It is preferable that it is 10% or less (lower limit 0%) from a viewpoint of being excellent in luster and transparency (clear feeling), and 5% It is more preferable that it is below (lower limit 0%), and it is especially preferable that it is less than 1% (lower limit 0%).
상기 광휘성 분체류로서는, 옥시염화비스무트, 산화티타늄 피복 마이카, 산화철피복 마이카, 산화철피복 마이카 티타늄, 유기안료피복 마이카 티타늄, 산화 티타늄 피복 유리말 및 알루미늄 파우더 등으로부터 선택되는 1종 또는 2종 이상을 이용할 수 있다. 본 발명에 있어서의 광휘성 분체류의 화장료에 있어서의 함유량은, 특별히 한정되지 않지만, 윤기나 투명도(클리어감)가 우수한 등의 관점에서, 30% 이하(하한 0%)인 것이 바람직하고, 15% 이하(하한 0%)인 것이 보다 바람직하며, 10% 미만(하한 0%)인 것이 특히 바람직하다.Examples of the bright powder include one or two or more selected from bismuth oxychloride, titanium oxide coated mica, iron oxide coated mica, iron oxide coated mica titanium, organic pigment coated mica titanium, titanium oxide coated glass powder and aluminum powder. It is available. Although content in the cosmetics of the bright powders in this invention is not specifically limited, It is preferable that it is 30% or less (lower limit 0%) from a viewpoint of being excellent in glossiness and transparency (clear feeling), 15 It is more preferable that it is% or less (lower limit 0%), and it is especially preferable that it is less than 10% (lower limit 0%).
상기 유기 분체류로서는, 나일론 파우더, 폴리메틸메타크릴레이트 파우더, 아크릴로나이트릴-메타크릴산 공중합체 파우더, 염화비닐리덴-메타크릴산 공중합체 파우더, PET수지말, 폴리에틸렌 파우더, 폴리스타이렌 파우더, 오가노폴리실록산엘라스토머 파우더, 폴리메틸실세스퀴옥산 파우더, 폴리우레탄 파우더, 울 파우더, 실크 파우더, 결정 셀룰로스 파우더 및 N-아실리진 파우더 등으로부터 선택되는 1종 또는 2종 이상을 이용할 수 있다.Examples of the organic powders include nylon powder, polymethyl methacrylate powder, acrylonitrile-methacrylic acid copolymer powder, vinylidene chloride-methacrylic acid copolymer powder, PET resin powder, polyethylene powder, polystyrene powder, and organo 1 type, or 2 or more types chosen from a nopolysiloxane elastomer powder, a polymethylsilsesquioxane powder, a polyurethane powder, a wool powder, a silk powder, a crystalline cellulose powder, an N-acyl azine powder, etc. can be used.
본 발명에 있어서의 유기 분체류의 화장료에 있어서의 함유량은, 특별히 한정되지 않지만, 윤기나 투명도(클리어감)가 우수한 등의 관점에서, 30% 이하(하한 0%)인 것이 바람직하고, 15% 이하(하한 0%)인 것이 보다 바람직하며, 10% 미만 (하한 0%)인 것이 특히 바람직하다.Although content in the cosmetic of the organic powders in this invention is not specifically limited, It is preferable that it is 30% or less (lower limit 0%) from a viewpoint of being excellent in glossiness and transparency (clear feeling), and 15% It is more preferable that it is below (lower limit 0%), and it is especially preferable that it is less than 10% (lower limit 0%).
이들 분체 중에서도, 폴리우레탄 파우더를 더 함유하면, 더욱 출발색이 향상되므로 바람직하다. 폴리우레탄 파우더의 함유량은, 화장료 중, 0.5 내지 10%인 것이 바람직하고, 1 내지 5%인 것이 보다 바람직하다.Among these powders, further containing a polyurethane powder is preferable because the starting color is further improved. It is preferable that it is 0.5 to 10% in cosmetics, and, as for content of a polyurethane powder, it is more preferable that it is 1 to 5%.
분체는, 1종 또는 2종 이상의 표면처리제를 이용해서 표면 처리를 실시해도 된다. 표면처리로서는, 실리콘 처리, 실릴화 처리, 알킬티타네이트 처리, 금속비누 처리, 유제 처리, 불소화합물 처리, 인지질 처리 등을 들 수 있다.Powder may surface-treat using 1 type, or 2 or more types of surface treating agents. Examples of the surface treatment include silicon treatment, silylation treatment, alkyl titanate treatment, metal soap treatment, emulsion treatment, fluorine compound treatment, and phospholipid treatment.
본 발명의 유성 화장료의 형상으로서는, 특별히 한정되지 않지만, 고체 형태, 반고체 형태, 액상인 것을 들 수 있고, 본 발명의 효과가 현저하게 발휘되는 점에서 액상 또는 반고체 형태가 바람직하다.Although it does not specifically limit as a shape of the oil-based cosmetics of this invention, A solid form, a semisolid form, and a liquid form are mentioned, A liquid or semisolid form is preferable at the point which the effect of this invention is exhibited remarkably.
본 발명의 유성 화장료의 제조 방법은, 특별히 한정되는 것이 아니지만, 성분 (A)와 성분 (B)를 혼합 분산한 후, 임의의 유성 성분을 혼합 분산 또는 가열 혼합한 후에, 임의의 분체나 수성 성분 등을 균일하게 혼합하고, 이것을 용기 또는 몰드에 가열 용해 후에 유입시켜 충전하고, 냉각시켜서 얻을 수 있다. 충전 시의 가열 온도는, 화장료가 유동성을 지녀서 용기에 충전할 수 있게 되는 온도이면, 특별히 한정되지 않지만, 80℃ 이상인 것이 바람직하고, 85 내지 160℃인 것이 바람직하다. 이러한 고온에 화장료가 폭로되어도, 본 발명의 화장료는 선명한 발색을 유지할 수 있다.Although the manufacturing method of the oil-based cosmetics of this invention is not specifically limited, After mixing and disperse | distributing a component (A) and a component (B), after mixing and disperse | distributing or heat-mixing arbitrary oil components, arbitrary powders or aqueous components The mixture can be uniformly mixed, filled with a container or a mold after heating and dissolving, followed by cooling. The heating temperature at the time of filling is not particularly limited as long as the cosmetic material has fluidity and can be filled in the container. However, the heating temperature is preferably 80 ° C or higher, and preferably 85 to 160 ° C. Even if the cosmetic is exposed at such a high temperature, the cosmetic of the present invention can maintain vivid color development.
본 발명의 유성 화장료로서는, 특별히 한정되지 않지만, 립스틱, 립글로스, 립 트리트먼트, 립크림, 베이스용의 립베이스, 립스틱 오버코트, 볼연지, 아이컬러, 네일오일 등의 메이크업 화장료로서 사용하는 것이 바람직하다. 본 발명의 효과를 현저하게 발휘할 수 있는 점에서, 립스틱, 립글로스 등의 입술용 화장료가 특히 바람직하다.Although it does not specifically limit as an oil-based cosmetic of this invention, It is preferable to use it as makeup cosmetics, such as a lipstick, a lip gloss, a lip treatment, a lip cream, a lip base for bases, a lipstick overcoat, a ball oil, eye color, and nail oil. Since the effect of this invention can be exhibited remarkably, the cosmetics for lips, such as a lipstick and a lip gloss, are especially preferable.
또, 본 발명의 성분 (A) 적색 218호, 적색 223호로부터 선택되는 1종 또는 2종 및 성분 (B) α-올레핀-비닐피롤리돈 공중합체를 발색 향상제로서 이용할 수도 있고, 특별히 한정되지 않지만, 화장료 이외에도, 도료, 잉크, 접착제 등에도 함유시킬 수 있다.Moreover, 1 type (s) or 2 types (s) chosen from component (A) red 218, red 223 of this invention, and a component (B) alpha-olefin-vinylpyrrolidone copolymer can also be used as a color improving agent, and are not specifically limited. However, in addition to cosmetics, it can be contained in paints, inks, adhesives and the like.
또한, 본 발명의 다른 양상은, α-올레핀-비닐피롤리돈 공중합체를 함유하는, 염료를 포함하는 유성 재료의 발색 향상제로서, 염료는, 적색 218호 및 적색 223호로부터 선택되는 1종 또는 2종인, 발색 향상제이다. 여기서, 발색향상이란, 예를 들어, 채도가 향상되는 것을 가리킨다. α-올레핀-비닐피롤리돈 공중합체, 적색 218호, 및 적색 223호에 대해서는, 전술한 바와 같다. 발색 향상제는, 발색 향상제를 포함하기 전의 유성 재료의 (a2+b2)(1/2)보다도, 발색 향상제 첨가 후의 (a2+b2)(1/2)이 커지는 것이 바람직하고, 발색 향상제를 포함하기 전의 유성 재료의 (a2+b2)(1/2)에 대하여 발색 향상제 첨가 후의 (a2+b2)(1/2)이 1.5배 이상이 되는 것이 보다 바람직하며, 3배 이상이 되는 것이 더 바람직하다. 여기서, a값, b값은, 실시예에 기재된 색차계를 이용해서 측정된 값을 채용한다. 유성 재료에 대해서, α-올레핀-비닐피롤리돈 공중합체의 첨가량이 0.001 내지 70%인 것이 바람직하고, 0.01 내지 50%인 것이 보다 바람직하며, 0.1 내지 30%인 것이 특히 바람직하다.In addition, another aspect of the present invention is a color improving agent for an oil-based material containing a dye containing an α-olefin-vinylpyrrolidone copolymer, wherein the dye is one kind selected from red 218 and red 223 or It is two kinds, a color improving agent. Here, the color development means that the saturation is improved, for example. The alpha -olefin-vinylpyrrolidone copolymer, red 218, and red 223 are as described above. Color-improving agent, the oily material prior to include a color-improving agent (a 2 + b 2) ( 1/2) of all, after the color development-improving agent is added (a 2 + b 2) ( 1/2) is not preferred, and large color It is more preferable that (a 2 + b 2 ) (1/2) after the color development agent is 1.5 times or more with respect to (a 2 + b 2 ) (1/2) of the oily material before including the enhancer, 3 More preferably, it is more than twice. Here, a value and b value employ | adopt the value measured using the color difference meter described in the Example. The amount of the α-olefin-vinylpyrrolidone copolymer added to the oily material is preferably 0.001 to 70%, more preferably 0.01 to 50%, and particularly preferably 0.1 to 30%.
실시예Example
이하에 실시예를 들어서 본 발명을 상세히 설명한다. 또, 이들은 본 발명을 하등 한정하는 것은 아니다.An Example is given to the following and this invention is demonstrated to it in detail. In addition, these do not limit this invention at all.
실시예Example 1 내지 5, 1 to 5, 비교예Comparative example 1, 2 1, 2
표 1에 나타낸 조성의 혼합물에 관해서, 발색의 정도를 하기 평가 기준에 의해 평가했다. 그 결과를 표 1에 나타낸다. 또, 성분 (1) 내지 (4)를 3본(三本) 롤러로 균일 혼합하고, 유성 화장료를 얻었다.About the mixture of the composition shown in Table 1, the grade of color development was evaluated by the following evaluation criteria. The results are shown in Table 1. Moreover, component (1)-(4) was uniformly mixed with three rollers, and the oil-based cosmetics were obtained.
(발색(채도))(Color development (saturation))
실시예 1 내지 5, 비교예 1, 2에서 얻어진 것을, 투명 셀을 이용해서, 25℃ 환경하에 있어서, 색차계 Sectro Color Meter SE7700(시마즈세이사쿠쇼(島津製作所))으로 측정하여, 얻어진 a값 및 b값으로부터, 하기 평가 기준으로 평가를 행하였다.The a value obtained by measuring the thing obtained by Examples 1-5 and Comparative Examples 1 and 2 with the color difference meter Sectro Color Meter SE7700 (Shimazu Seisakusho) in 25 degreeC environment using a transparent cell. And it evaluated on the following evaluation criteria from b value.
결과를 표 1에 나타낸다.The results are shown in Table 1.
(평가 기준) : (판정)(Evaluation standard) : (Judgment)
30 ≤ (a2+b2)(1/2) : ◎30 ≤ (a2+ b2)(1/2) : ◎
10 < (a2+b2)(1/2) < 30 : ○10 <(a 2 + b 2 ) (1/2) <30: ○
(a2+b2)(1/2) ≤ 10 : ×(a 2 + b 2 ) (1/2) ≤ 10: ×
또한, "고온 안정성" 및 "윤기"에 대해서, 하기 평가 방법에 의해 행하였다. 그 결과도 아울러서 표 1에 나타낸다.In addition, "high temperature stability" and "glossiness" were performed by the following evaluation method. The results are also shown in Table 1.
표 1로부터 명확한 바와 같이, 실시예 1 내지 5에서는 발색한 것에 대해서, 비교예 1 및 2에서는 충분한 발색이 얻어지지 않았다. 또, 비교예 1 및 2에 관해서는, 만족스러운 발색이 얻어지지 않았기 때문에, "고온 안정성"은 평가하고 있지 않다.As is clear from Table 1, sufficient color development was not obtained in Comparative Examples 1 and 2, compared with those developed in Examples 1 to 5. In Comparative Examples 1 and 2, since satisfactory color development was not obtained, "high temperature stability" was not evaluated.
실시예Example 6 내지 11, 6 to 11, 비교예Comparative example 3 내지 8 3 to 8
표 2에 나타낸 조성의 유성 입술용 화장료(반고체 형태 글로스)를 하기 제조 방법에 따라서 조제했다. 얻어진 유성 입술용 화장료에 대해서, "발색"의 정도, 가열했을 때의 색의 "고온 안정성", 살갗이나 피부에 도포한 화장료를 제거했을 때의 "염착 비감수성", 화장료의 외관의 "투명도" 및 도포 후의 화장막의 "윤기"의 평가를 하기 평가 방법에 의해 행하였다. 그 결과도 아울러서 표 2에 나타낸다. 또, "발색"에 관해서는, 표 1에서 이용한 방법을 이용했다.The oily lip cosmetics (semi-solid gloss) of the composition shown in Table 2 were prepared according to the following manufacturing method. About the obtained oily lip cosmetics, the degree of "color development", "high temperature stability" of the color when heated, "dyeing insensitive" when removing the cosmetics applied to skin or skin, and "transparency" of the cosmetic appearance And evaluation of the "gloss" of the makeup film after application was performed by the following evaluation method. The results are also shown in Table 2. In addition, regarding the "color development", the method used in Table 1 was used.
(제조 방법): 실시예 6 내지 11, 비교예 3 내지 8(Manufacturing method): Examples 6-11, Comparative Examples 3-8
A. 성분 (1) 내지 (8)을 균일 혼합한다.A. The components (1) to (8) are mixed uniformly.
B. A와 성분 (9) 내지 (15)를 3본(三本) 롤러에서 균일 혼합한다.B. A and components (9) to (15) are homogeneously mixed in three rollers.
C. B를 90℃까지 가열하고, 용기에 충전하여, 유성 입술용 화장료를 얻었다.C. B was heated to 90 degreeC, it filled into the container, and obtained the oily lip cosmetics.
(고온 안정성)(High temperature stability)
실시예 6 내지 11, 비교예 3 내지 8에서 얻어진 유성 입술용 화장료를, 110℃로 가열한 후, 투명 셀을 이용하여, 25℃ 환경하에 있어서, Sectro Color Meter SE7700(시마즈세이사쿠쇼)으로 측정해서, 얻어진 a값 및 b값으로부터 하기 평가 기준으로 평가를 행하였다.The oily lip cosmetics obtained in Examples 6 to 11 and Comparative Examples 3 to 8 were heated to 110 ° C, and then measured with a Sectro Color Meter SE7700 (Shimazu Seisakusho) under a 25 ° C environment using a transparent cell. It evaluated by the following evaluation criteria from the obtained a value and b value.
(평가 기준) : (판정)(Evaluation standard) : (Judgment)
30 ≤ (a2+b2)(1/2) : ◎30 ≤ (a2+ b2)(1/2) : ◎
10 < (a2+b2)(1/2) < 30 : ○10 <(a 2 + b 2 ) (1/2) <30: ○
(a2+b2)(1/2) ≤ 10 : ×(a 2 + b 2 ) (1/2) ≤ 10: ×
(염착 비감수성)(Dye insensitivity)
실시예 6 내지 11, 비교예 3 내지 8에서 얻어진 유성 입술용 화장료를, 피부에 도포하고, 시판의 티슈 페이퍼로 화장료를 제거한 후의 염착 정도를, 하기 평가 기준으로 전문 패널에 의한 평가를 행하였다.The oil-based lip cosmetics obtained in Examples 6 to 11 and Comparative Examples 3 to 8 were applied to the skin, and the degree of dyeing after removing the cosmetics with commercial tissue paper was evaluated by a professional panel based on the following evaluation criteria.
(평가 기준) : (판정)(Evaluation standard) : (Judgment)
티슈 페이퍼로 화장료를 제거한 후, 염착되어 있지 않음 : ◎No dyeing after removing cosmetics with tissue paper : ◎
티슈 페이퍼로 화장료를 제거한 후, 다소 염착되어 있음 : ○After removing cosmetics with tissue paper, it is somewhat dyed : ○
티슈 페이퍼로 화장료를 제거한 후, 분명히 염착되어 있음 : ×After removing cosmetics with tissue paper, it is clearly dyed: ×
(투명도)(transparency)
실시예 6 내지 11, 비교예 3 내지 8에서 얻어진 유성 입술용 화장료를, 광로장 1㎝의 투명 셀을 이용하여, 25℃ 환경하에 있어서, 650㎚의 흡광도를 시마즈세이사쿠쇼사제의 흡광광도계 UV-2500PC로 측정해서, 650㎚의 파장영역에 있어서의 흡광도로부터, 하기 평가 기준으로 평가를 행하였다.Absorbance of 650 nm in a 25 ° C. environment using a transparent cell having an optical path length of 1 cm for the oily lip cosmetics obtained in Examples 6 to 11 and Comparative Examples 3 to 8, and an absorbance photometer UV manufactured by Shimadzu Corporation It measured by -2500 PC and evaluated on the following evaluation criteria from the absorbance in the wavelength region of 650 nm.
(평가 기준) : (판정)(Evaluation standard) : (Judgment)
95 ≤(흡광도) : ◎95 ≤ (absorbance) : ◎
50 < (흡광도) < 95 : ○50 <(absorbance) <95 : ○
(흡광도) ≤ 50 : ×(Absorbance) ≤ 50 : ×
(윤기)(burnish)
실시예 6 내지 11, 비교예 3 내지 8에서 얻어진 유성 입술용 화장료에 대해서, 전문 패널 20명에 의한 사용 테스트를 행하여, 패널 각 사람이 하기 절대 평가에서 5단계로 평가하고, 패널 전원의 평점합계로부터 그 평균치를 산출해서, 하기 판정 기준에 의해 3단계로 판정했다. 구체적으로는, 각 시료의 도포 직후의 화장막의 상태를 관찰하여, 윤기 높은 질감을 느낀 방식에 대해서 평가했다.The oily lip cosmetics obtained in Examples 6 to 11 and Comparative Examples 3 to 8 were subjected to a use test by 20 specialized panels, and each panel was evaluated in five stages by the following absolute evaluation. The average value was calculated from the above, and determined in three steps by the following criteria. Specifically, the state of the makeup film immediately after the application of each sample was observed, and the manner in which the glossy texture was felt was evaluated.
<절대평가기준><Absolute evaluation criteria>
(평점) : (평가)(grade) : (evaluation)
4 : 매우 우수하다고 느낌 4 : Feels very good
3 : 우수하다고 느낌 3 : Feels excellent
2 : 보통 2 : usually
1 : 다소 뒤떨어지고 있다고 느낌 One : I feel somewhat inferior
0 : 뒤떨어지고 있다고 느낌 0 : Feeling falling behind
<판정 기준><Judge criteria>
(평점평균치) : (판정)(Average score) : (Judgment)
3.5점 초과 : ◎3.5 points or more : ◎
2.5점 이상 3.5 미만 : ○2.5 points or more and less than 3.5 : ○
2.5점 미만 : ×Less than 2.5 : ×
표 2 및 도 1의 결과로부터 명확한 바와 같이, 본 발명의 실시물인 실시예 6 내지 11은, 외관이 선명하게 발색되고, 고온 안정성이나 염착 비감수성, 투명도, 윤기가 우수한 유성 화장료였다.As is clear from the results of Table 2 and Fig. 1, Examples 6 to 11, which are the examples of the present invention, were oil-based cosmetics that were vividly colored in appearance and were excellent in high temperature stability, dye non-sensitivity, transparency, and gloss.
한편, 성분 (B)를 함유하지 않는 비교예 3 및 성분 (A)와 성분 (B)의 함유 질량비율이 바람직하지 않은 비교예 4는 만족스러운 발색이 얻어지지 않았다. 또한, 비교예 3 및 4에 관해서는, 만족스러운 발색이 얻어지지 않았기 때문에, "고온 안정성"은 평가하고 있지 않다. 성분 (B) 대신에, 하이드록시아파타이트, 탄산칼슘, 다이스테아르산 알루미늄(다이스테아르산 AL)을 함유시킨 비교예 5 내지 7은, 투명도 및 윤기가 뒤떨어지는 것이었다. 또한, 성분 (B) 대신에, DPG를 함유시킨 비교예 8은, 고온으로 하면 외관색이 소실되어 버렸다.On the other hand, satisfactory color development was not obtained in Comparative Example 3 containing no component (B) and Comparative Example 4 in which the content mass ratio of component (A) and component (B) was not preferable. In Comparative Examples 3 and 4, since satisfactory color development was not obtained, "high temperature stability" was not evaluated. Instead of component (B), Comparative Examples 5 to 7 containing hydroxyapatite, calcium carbonate, and distearate aluminum (distearic acid AL) were inferior in transparency and gloss. In addition, in the comparative example 8 which contained DPG instead of component (B), when it made high temperature, the external appearance color disappeared.
실시예 12 내지 17, 비교예 9 내지 14Examples 12-17, Comparative Examples 9-14
표 3에 나타낸 조성의 유성 입술용 화장료(고체 형태)를 하기 제조 방법을 따라서 조제했다. 얻어진 유성 입술용 화장료에 대해서, 표 1 및 표 2에서 이용한 평가 방법에 의해, "발색"의 정도, 가열했을 때의 색의 "고온 안정성", 피부나 피부에 도포한 후에 화장료를 제거했을 때의 "염착 비감수성" 및 도포 후의 화장막의 "윤기"의 평가를 행하였다. 또한, 하기 평가 방법에 의해, 화장료의 외관의 "클리어감"의 평가를 행하였다. 그 결과도 아울러서 표 3에 나타낸다.The oily lip cosmetics (solid form) of the composition shown in Table 3 were prepared according to the following manufacturing methods. About the obtained oily-lip cosmetics, when the cosmetics were removed after apply | coating to the degree of "color development", the "high temperature stability" of the color when heated, and skin or skin by the evaluation method used in Table 1 and Table 2 "Dyeness-insensitive" and "gloss" of the makeup film after application were evaluated. Moreover, the "clear feeling" of the external appearance of the cosmetics was evaluated by the following evaluation method. The results are also shown in Table 3.
(제조 방법): 실시예 12 내지 17, 비교예 9 내지 14(Manufacturing method): Examples 12-17, Comparative Examples 9-14
A. 성분 (1) 내지 (9)를 균일 혼합한다.A. The components (1) to (9) are mixed uniformly.
B. A와 성분 (10) 내지 (16)을 3본 롤러에서 균일 혼합한다.B. A and components (10) to (16) are uniformly mixed in three rollers.
C. B를 110℃까지 가열하고, 용기에 충전하여, 유성 입술용 화장료를 얻었다.C. B was heated to 110 degreeC, it filled into the container, and obtained the oily lip cosmetics.
(클리어감)(Clear feeling)
실시예 12 내지 17, 비교예 9 내지 14에서 얻어진 유성 입술용 화장료에 대해서, 전문 패널 20명에 의한 사용 테스트를 행하여, 패널 각 사람이 하기 절대 평가에서 5단계로 평가하고, 패널 전원의 평점합계로부터 그 평균치를 산출하여, 하기 판정 기준에 의해 3단계로 판정했다. 구체적으로는, 각 시료의 외관의 상태를 관찰하고, 클리어한 질감(클리어감)을 느끼는 방식에 대해서 평가했다.The oily lip cosmetics obtained in Examples 12 to 17 and Comparative Examples 9 to 14 were subjected to a use test by 20 specialized panels, and each panel was evaluated in five steps by the following absolute evaluation, and the total ratings of the panel power supplies The average value was computed from and determined in three steps by the following criteria. Specifically, the state of the external appearance of each sample was observed, and the method of feeling the clear texture (clear feeling) was evaluated.
<절대평가기준><Absolute evaluation criteria>
(평점) : (평가)(grade) : (evaluation)
4 : 매우 클리어감이 있음 4 : There is a very clear feeling
3 : 클리어감이 있음 3 : There is a clear feeling
2 : 보통 2 : usually
1 : 다소 클리어감이 뒤떨어지고 있음 One : A feeling of clear is inferior
0 : 클리어감이 뒤떨어지고 있다(은폐감이 강하다)고 느낌 0 : A feeling of clearness is inferior (a feeling of concealment is strong)
<판정 기준><Judge criteria>
(평점평균치) : (판정)(Average score) : (Judgment)
3.5점 초과 : ◎More than 3.5 : ◎
2.5점 이상 3.5 미만 : ○2.5 points or more and less than 3.5 : ○
2.5점 미만 :×Less than 2.5 : ×
표 3의 결과로부터 명확한 바와 같이, 본 발명의 실시물인 실시예 12 내지 17은, 외관이 선명하게 발색되고, 고온 안정성이나 염착 비감수성, 클리어감, 윤기가 우수한 유성 화장료였다.As is clear from the results of Table 3, Examples 12 to 17 which are the examples of the present invention were oil-based cosmetics that were vividly colored in appearance and were excellent in high temperature stability, dyeing insensitivity, clear feeling, and gloss.
한편, 성분 (B)를 함유하지 않는 비교예 9 및 성분 (A)와 성분 (B)의 함유 질량비율이 바람직하지 않은 비교예 10은 만족스러운 발색이 얻어지지 않았다. 성분 (B) 대신에, 하이드록시아파타이트, 탄산칼슘, 다이스테아르산 AL을 함유시킨 비교예 11 내지 13은, 클리어감 및 윤기가 뒤떨어지는 것이었다. 또한, 성분 (B) 대신에, DPG를 함유시킨 비교예 14는, 제조 과정에서 외관색이 소실되어 버렸다. 또한, 비교예 9, 10, 14에 관해서는, 만족스러운 발색이 얻어지지 않았기 때문에, "고온 안정성"은 평가하고 있지 않다.On the other hand, satisfactory color development was not obtained in Comparative Example 9 containing no component (B) and Comparative Example 10 in which the content mass ratio of component (A) and component (B) was not preferable. Instead of component (B), Comparative Examples 11 to 13 containing hydroxyapatite, calcium carbonate, and distearic acid AL were inferior in clear feeling and gloss. In addition, in Comparative Example 14 containing DPG instead of component (B), the appearance color was lost in the manufacturing process. In Comparative Examples 9, 10 and 14, since satisfactory color development was not obtained, "high temperature stability" was not evaluated.
실시예 18: 네일오일Example 18 Nail Oil
(성분) (%)(ingredient) (%)
1. 아보카도유 ※17 501.Avocado oil ※ 17 50
2. 트라이에틸헥사노인(트라이2-에틸헥산산글리세릴) 잔량2. Triethylhexanoin (glyceryl tri2-ethylhexanoate) Remaining amount
3. (비닐피롤리돈/헥사데센)공중합체 ※4 153. (Vinylpyrrolidone / hexadecene) Copolymer * 4 15
4. 적색 218호 ※2 0.14. Red No. 218 * 2 0.1
5. 2,6-다이-tert-부틸-파라-크레졸 ※18 0.015. 2,6-Di-tert-butyl-para-cresol * 18 0.01
6. 다이메틸실릴화 실리카 ※19 106. Dimethylsilylated Silica * 19 10
7. 산화 티타늄 피복 유리말 ※20 0.017. Titanium oxide coated glass powder ※ 20 0.01
※17: NIKKOL 정제 아보카도유※ 17: NIKKOL refined avocado oil
※18: 2-6-다이-tert-부틸-크레졸(토쿄카세이힝(東京化成品)사 제품)* 18: 2-6-di-tert-butyl-cresol (manufactured by Tokyo Kasei Co., Ltd.)
※19: AEROSIL R976S(닛폰아에로실사 제품, 평균 입자 직경 7㎚)※ 19: AEROSIL R976S (Nippon Aerosil company make, average particle diameter 7nm)
※20: 마이크로글라스메타샤인1080RS(니혼이타가라스(日本板硝子)사 제품, 평균 입자 직경 85㎛).* 20: Micro glass meta shine 1080RS (made by Nippon Itagara Co., Ltd., the average particle diameter of 85 micrometers).
(제조 방법)(Production method)
A. 성분 (1) 내지 (7)을 25℃에서 균일하게 용해한다.A. The components (1) to (7) are dissolved uniformly at 25 ° C.
B. A를 매니큐어 용기에 직접 유입시켜, 네일오일을 얻었다.B. A was poured directly into the nail polish container to obtain nail oil.
얻어진 네일오일은, 발색, 고온 안정성, 염착 비감수성, 투명도, 윤기의 모든 점에서 만족스러운 것이었다. 구체적으로는, 모든 평가 항목에 있어서 ◎였다. 또한, (A)/(B)=0.0067이다.The obtained nail oil was satisfactory in all points of color development, high temperature stability, dye non-sensitivity, transparency and gloss. Specifically, it was ◎ in all evaluation items. Moreover, (A) / (B) = 0.0067.
실시예 19: 고체 형태 볼 연지Example 19: Solid Form Ball Roll
(성분) (%)(ingredient) (%)
1. 미세결정성 왁스 ※21 41.Microcrystalline Wax ※ 21 4
2. 칸데릴라 왁스 ※22 72. Candelilla Wax ※ 22 7
3. 트라이에틸헥사노인(트라이2-에틸헥산산글리세릴) 잔량3. Triethylhexanoin (glyceryl tri2-ethylhexanoate) Remaining amount
4. 트라이아이소스테아르산 폴리글리세릴-2 ※8 154. Triisostearic Acid Polyglyceryl-2 * 8 15
5. 옥틸도데칸올 ※23 105. Octyldodecanol ※ 23 10
6. (비닐피롤리돈/헥사데센)공중합체 ※4 156. (Vinylpyrrolidone / hexadecene) Copolymer * 4 15
7. 적색 218호 ※2 0.17. Red 218 * 2 0.1
8. 다이메틸실릴화 실리카 ※10 58. Dimethylsilylated Silica * 10 5
9. 무수 규산 ※24 89. Silic anhydride * 24 8
10. 산화티타늄 피복 합성 금운모 ※25 0.510. Titanium oxide coated synthetic mica ※ 25 0.5
11. 페녹시에탄올 ※11 0.311.Phenoxyethanol ※ 11 0.3
※21: MULTIWAX W445(SONNEBORN사 제품)※ 21: MULTIWAX W445 (product made by SONNEBORN company)
※22: 정제 칸데릴라 왁스 SR-3(일본 내츄럴프로덕츠사 제품)※ 22: Tablet candelilla wax SR-3 (product of Japan natural products company)
※23: 리소놀20SP(코큐알코올코교사 제품)※ 23: Resonol 20SP (product of Kokyu Alcohol Co., Ltd.)
※24: SILICA MICRO BEAD BA-1(닛키쇼쿠바이카세이주식회사(JGC Catalysts and Chemicals Ltd.) 제품, 평균 입자 직경 18㎛)※ 24: SILICA MICRO BEAD BA-1 (product of JGC Catalysts and Chemicals Ltd., average particle diameter 18㎛)
※25: HELIOS R300S(토피코교사(TOPY INDUSTRIES, LIMITED) 제품, 평균 입자 직경 210㎛).※ 25: HELIOS R300S (TOPY INDUSTRIES, LIMITED), the average particle diameter 210㎛.
(제조 방법)(Production method)
A. 성분 (1) 내지 (8)을 균일하게 100℃에서 용해시킨다.A. Components (1) to (8) are dissolved uniformly at 100 ° C.
B. A를 3본 롤러에서 균일 혼합한다.B. Mix A uniformly on three rollers.
C. B에 성분 (9) 내지 (10)을 가하고, 균일하게 혼합한다.C. Add components (9) to (10) to B and mix uniformly.
D. C를 수지접시에 90℃에서 용해 충전시키고 냉각 고형화시켜 고체 형태 볼 연지를 얻었다.D. C was dissolved and filled in a resin dish at 90 ° C. and cooled to solidification to obtain a solid ball softener.
얻어진 고체 형태 볼 연지는, 발색, 고온 안정성, 염착 비감수성, 클리어감, 윤기의 모든 점에서 만족스러운 것이었다. 구체적으로는, 발색, 고온 안정성, 염착 비감수성에 있어서 ◎이며, 클리어감, 윤기에 있어서 ○였다. 또한, (A)/(B)=0.0067이다.The obtained solid-form ball softener was satisfactory in all points of color development, high temperature stability, dye non-sensitivity, clear feeling, and gloss. Specifically, it was ◎ in color development, high temperature stability, and dyeing non-sensitivity, and ○ in clear feeling and gloss. Moreover, (A) / (B) = 0.0067.
실시예 20: 고형 립스틱Example 20 Solid Lipstick
(성분) (%)(ingredient) (%)
1. N-라우로일-L-글루탐산 다이뷰틸 아마이드 ※26 51.N-lauroyl-L-glutamic acid dibutyl amide ※ 26 5
2. N-에틸헥사노일-L-글루탐산 다이뷰틸 아마이드 ※27 32.N-ethylhexanoyl-L-glutamic acid dibutyl amide ※ 27 3
3. 트라이멜리트산 트라이트라이데실 ※9 303. Trimellitic acid tritridecyl ※ 9 30
4. (비닐피롤리돈/헥사데센)공중합체 ※4 154. (Vinylpyrrolidone / hexadecene) Copolymer * 4 15
5. (비닐피롤리돈/에이코센)공중합체 ※4' 15. (Vinylpyrrolidone / Eicosen) Copolymer * 4 ' One
6. 적색 218호 ※2 0.16. Red 218 * 2 0.1
7. 적색 223호 ※3 0.17. Red 223 * 3 0.1
8. 말산 다이아이소스테아릴 ※1 잔량8. Malic Acid Diisostearyl * 1 Remaining amount
9. 수첨폴리데센 ※28 109. Hydrogenated Polydecene ※ 28 10
10. 나일론 파우더 ※29 210. Nylon powder ※ 29 2
11. 폴리우레탄 파우더 ※30 311.Polyurethane Powder ※ 30 3
12. 다이프로필렌글리콜 0.312. Dipropylene Glycol 0.3
13. 1,2-펜탄다이올 0.313. 1,2-pentanediol 0.3
14. 2,6-다이-tert-부틸-파라-크레졸 0.0114. 2,6-di-tert-butyl-para-cresol 0.01
15. 아스타잔틴 0.000115. Astaxanthin 0.0001
16. 팔미트산 아스코르빌 0.000116. Palmitic acid Ascorbyl 0.0001
17. 니코틴 아마이드 117. Nicotine Amide One
※26: 아미노산계 오일 겔화제 GP-1(아지노모토 주식회사(Ajinomoto CO.JP) 제품)※ 26: Amino acid oil gelling agent GP-1 (product of Ajinomoto CO.JP)
※27: 아미노산계 오일 겔화제 EB-21(아지노모토 주식회사 제품)※ 27: Amino acid oil gelling agent EB-21 (product of Ajinomoto Corporation)
※28: 놈코트(ノムコ-ト) HP-30(닛신오일리오그룹주식회사(The Nisshin OilliO Group, Ltd.) 제품)※ 28: Nom-Coat HP-30 (product of The Nisshin OilliO Group, Ltd.)
※29: 오르가솔(Orgasol) 2002D(아토피나·재팬사(アトフィナ·ジャパン株式會社) 제품, 평균 입경 22㎛)* 29: Organasol 2002D (Atopina Japan company, average particle diameter 22㎛)
※30: 평균 입자 직경 7㎛.* 30: 7 micrometers of average particle diameters.
(제조 방법)(Production method)
A. 성분 (1) 내지 (11)을 균일하게 150℃에서 용해시킨다.A. The components (1) to (11) are dissolved uniformly at 150 ° C.
B. A를 3본 롤러에서 균일 혼합한다.B. Mix A uniformly on three rollers.
C. B에 성분 (12) 내지 (17)을 가하여, 균일하게 혼합한다C. Add components (12) to (17) to B and mix uniformly.
D. C를 금형에 용융 충전시키고 냉각시켜 고형 립스틱을 얻었다.D. C was melt filled into the mold and cooled to obtain a solid lipstick.
얻어진 고형 립스틱은, 발색, 고온 안정성, 염착 비감수성, 클리어감, 윤기의 모든 점에서 만족스러운 것이었다. 구체적으로는, 모든 평가 항목에 있어서 ◎였다. 또, (A)/(B)=0.0125이다.The obtained solid lipstick was satisfactory in all of color development, high temperature stability, dye non-sensitivity, clear feeling, and gloss. Specifically, it was ◎ in all evaluation items. Moreover, (A) / (B) = 0.0125.
Claims (6)
다음 성분 (A) 및 (B):
(A) 적색 218호 및 적색 223호로부터 선택되는 1종 또는 2종; 및
(B) α-올레핀-비닐피롤리돈 공중합체
를 함유하되, 성분 (B)에 대한 성분 (A)의 함유 질량비율 (A)/(B)가 2 이하인, 유성 화장료.As an oily cosmetic,
The following components (A) and (B):
(A) one or two selected from red 218 and red 223; And
(B) α-olefin-vinylpyrrolidone copolymer
An oil-based cosmetic product containing, wherein the content ratio (A) / (B) of the component (A) to the component (B) is 2 or less.
상기 염료는 적색 218호 및 적색 223호로부터 선택되는 1종 또는 2종인, 발색 향상제.As a color improving agent of the oil-containing material containing a dye containing the (alpha)-olefin-vinylpyrrolidone copolymer,
The dye is a color improving agent, which is one or two selected from red 218 and red 223.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JPJP-P-2017-090334 | 2017-04-28 | ||
| JP2017090334 | 2017-04-28 | ||
| PCT/JP2018/017281 WO2018199314A1 (en) | 2017-04-28 | 2018-04-27 | Oily cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20190139838A true KR20190139838A (en) | 2019-12-18 |
| KR102684988B1 KR102684988B1 (en) | 2024-07-16 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1020197026005A KR102684988B1 (en) | 2017-04-28 | 2018-04-27 | oil-based cosmetics |
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| JP (1) | JP7288849B2 (en) |
| KR (1) | KR102684988B1 (en) |
| CN (1) | CN110402136B (en) |
| TW (1) | TW201842898A (en) |
| WO (1) | WO2018199314A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20210145766A (en) * | 2019-03-28 | 2021-12-02 | 가부시키가이샤 코세 | oily cosmetics |
| JP7269064B2 (en) * | 2019-03-28 | 2023-05-08 | 株式会社コーセー | oily cosmetics |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06287109A (en) * | 1993-04-01 | 1994-10-11 | Kanebo Ltd | Oily composition for lip |
| KR19990063332A (en) * | 1997-12-22 | 1999-07-26 | 조지안느 플로 | Cosmetic composition comprising a dispersion of polymer particles in a liquid fatty phase and a fat-soluble polymer |
| JP2002363033A (en) * | 2001-06-06 | 2002-12-18 | Mikuni Color Ltd | Pigment dispersion for lipstick, method for lipstick composition production and lipstick composition |
| JP2008120687A (en) * | 2006-11-08 | 2008-05-29 | Shiseido Co Ltd | Coloring material for cosmetic and makeup cosmetic |
| KR20090122954A (en) * | 2007-03-19 | 2009-12-01 | 이엘씨 매니지먼트 엘엘씨 | High shine, stick-shaped cosmetic products |
| JP2015081256A (en) * | 2013-10-24 | 2015-04-27 | 株式会社コーセー | Lip cosmetics |
| KR102455854B1 (en) * | 2016-11-14 | 2022-10-18 | 가부시키가이샤 코세 | oily makeup cosmetics |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005194220A (en) | 2004-01-05 | 2005-07-21 | L'oreal Sa | COMPOSITION FOR EXTERNAL USE CONTAINING SEMICRYSTALLINE POLYMER AND POLYVINYLPYRROLIDONE-alpha-OLEFIN COPOLYMER, AND METHOD FOR PRODUCING THE COMPOSITION |
| JP2009114161A (en) | 2007-11-05 | 2009-05-28 | Assainir Inc | Transparent base material using gelling agent composition and cosmetic comprising the same |
| JP5657455B2 (en) | 2011-03-31 | 2015-01-21 | 株式会社ナリス化粧品 | Oily cosmetic base and oily cosmetic |
-
2018
- 2018-04-27 KR KR1020197026005A patent/KR102684988B1/en active IP Right Grant
- 2018-04-27 CN CN201880016779.2A patent/CN110402136B/en active Active
- 2018-04-27 JP JP2019514672A patent/JP7288849B2/en active Active
- 2018-04-27 WO PCT/JP2018/017281 patent/WO2018199314A1/en active Application Filing
- 2018-04-27 TW TW107114360A patent/TW201842898A/en unknown
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06287109A (en) * | 1993-04-01 | 1994-10-11 | Kanebo Ltd | Oily composition for lip |
| KR19990063332A (en) * | 1997-12-22 | 1999-07-26 | 조지안느 플로 | Cosmetic composition comprising a dispersion of polymer particles in a liquid fatty phase and a fat-soluble polymer |
| JP2002363033A (en) * | 2001-06-06 | 2002-12-18 | Mikuni Color Ltd | Pigment dispersion for lipstick, method for lipstick composition production and lipstick composition |
| JP2008120687A (en) * | 2006-11-08 | 2008-05-29 | Shiseido Co Ltd | Coloring material for cosmetic and makeup cosmetic |
| KR20090122954A (en) * | 2007-03-19 | 2009-12-01 | 이엘씨 매니지먼트 엘엘씨 | High shine, stick-shaped cosmetic products |
| JP2015081256A (en) * | 2013-10-24 | 2015-04-27 | 株式会社コーセー | Lip cosmetics |
| KR102455854B1 (en) * | 2016-11-14 | 2022-10-18 | 가부시키가이샤 코세 | oily makeup cosmetics |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110402136A (en) | 2019-11-01 |
| CN110402136B (en) | 2022-10-28 |
| JP7288849B2 (en) | 2023-06-08 |
| WO2018199314A1 (en) | 2018-11-01 |
| JPWO2018199314A1 (en) | 2020-03-12 |
| TW201842898A (en) | 2018-12-16 |
| KR102684988B1 (en) | 2024-07-16 |
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