CN104470489B - Cosmetic composition including scattering filler and mother-of-pearl - Google Patents
Cosmetic composition including scattering filler and mother-of-pearl Download PDFInfo
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- CN104470489B CN104470489B CN201280074785.6A CN201280074785A CN104470489B CN 104470489 B CN104470489 B CN 104470489B CN 201280074785 A CN201280074785 A CN 201280074785A CN 104470489 B CN104470489 B CN 104470489B
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/42—Colour properties
- A61K2800/43—Pigments; Dyes
- A61K2800/436—Interference pigments, e.g. Iridescent, Pearlescent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/65—Characterized by the composition of the particulate/core
- A61K2800/651—The particulate/core comprising inorganic material
Abstract
The present invention relates to a kind of cosmetic composition for nurse and/or make up keratin material, particularly facial skin, the following components being included in physiologically acceptable medium：(a) at least one scattering filler, particle size is less than 35 microns, preferably 2 microns to 35 microns, more preferable 11 microns to 17 microns, (b) at least at least one blue mother-of-pearl of red or pink mother-of-pearl and (c).
Description
Technical field
The present invention relates to the compositions for nursing and/or cosmetic skin, are especially intended to assign light and health shines
Effect.
Term " light " and " light effect " are understood to mean light reflection on the skin, diffusion and continuous according to the present invention
The feature of reflection.In fact, skin reflects the incident light of a part naturally." light effect " according to the present invention is so that increase this
Kind is reflected as possibility, this provides brighter and more luminous appearance for makeup.Composition according to the present invention can also be assigned
Give the illumination effect of health.
Statement " illumination effect of health " is understood to mean the natural colorants of skin, improves the Dull appearance (drop of the colour of skin
Low saturation or colored and anti-dim colour of skin effect).
Statement according to the present invention is understood to mean difference " for the composition for keratin material of nursing and/or make up "
In the composition of rinsing cleansing composition.
Particularly, they can be for the group of the skin, especially skin of face of nurse and/or make up face and/or body
Close object.
Background technology
Number centuries come, global consumer, particularly Asia consumer, are finding novel cosmetic to improve angle egg
The appearance of white material, especially skin, particularly appearance (visible and/or tactile inhomogeneities) and/or skin
The colour of skin, healthy shines, the external signal in health and youth.
In addition, for keratin material, especially skin tape carrys out bright and health illumination effect, it is necessary to hide skin
The shortcomings that upper, at the same by light scattering so as to skin tape come shine and simultaneously non-glittering appearance.
In the prior art it is well known that skin shortcoming and being made to hide using pigment in cosmetic composition
Skin bright.However, often in pore (pores) accumulated inside and improve it with strong light scattering and the granules of pigments absorbed
Visibility.The US2005163730 of Unilever describes silicone elastomer, ZnO nano pigment and scattering filler as TiO2 applies paving
The combination of mica or bismuth oxychloride.
Therefore, there is still a need for find new nursing and/or cosmetic product, particularly for the colour of skin, assign brightness effect and
Non- glittering, it does not mark uneven while covers shortcoming (dermatodyschroia, mark) or it assigns face homogeneous color,
Particularly face is natural and homogeneous color, advantageously, healthy illumination effect.
The content of the invention
It has been found by the present inventors that scattering filler, especially bismuth compound, with reference to mother-of-pearl, show extraordinary
Light reflection (refection) and makeup (making up) effect, meet the purpose of the present invention.
The hydrophilicity of scattering compound contributes to the present composition for the close nature of skin, and improves this hair
The adhesiveness of bright composition.
According to a kind of specific embodiment, cluster crystal structural scattering filler is used in the present invention.Due to scattering filler
Structure, composition thus become adherency and it is less transparent.Therefore, composition carrys out light scattering effect to skin tape, to assign hair
Light (glow) but non-glittering (shiny) appearance, and at the same time the shortcomings that covering skin.
Moreover, because the structure of above-mentioned scattering filler, composition of the invention can absorb the skin on skin after application
Fat (sebum).
In one aspect, the present invention is provided to the makeups of keratin material of nursing and/or make up, particularly facial skin
Product composition, the following components being included in physiologically acceptable medium：
(a) at least one scattering filler, particle size are less than 35 microns, and preferably 2 microns to 35 microns, more preferable 11 is micro-
Rice to 17 microns,
(b) at least red or pink mother-of-pearl and
(c) at least blue mother-of-pearl.
According to preferred embodiment, the present invention is provided to keratin material of nursing and/or make up, particularly face's skin
The cosmetic composition of skin, the following components being included in physiologically acceptable medium：
(a) at least one bismuth oxychloride, preferably cluster crystal form, particle size is less than 35 microns, and preferably 2 microns extremely
35 microns, more preferable 11 microns to 17 microns,
(b) at least red or pink mother-of-pearl and
(c) at least blue mother-of-pearl.
There is provided present invention as described above it is at least one scattering filler and mother-of-pearl between it is well balanced, to make this hair
Bright composition can bring the covering to skin shortcoming and the light and illumination effect to skin, especially skin of face.
According to the present invention, composition can be various forms of, particularly the shape of anhydrous composition, dispersion or lotion
Formula, especially such as water/oil or oil/water lotion or multiple emulsion.
The composition of the present invention is preferably lotion, particularly direct or inverted emulsion or anhydrous composition.
Preferably, said composition is lotion.
Lotion can have oil or water continuous phase.Such lotion can be, for example, inverse (W/O) lotion or direct (O/W)
Lotion or alternatively multiple emulsion (W/O/W or O/W/O).
According to another embodiment, composition of the invention further includes at least one other colorant, is selected from angle
Aberration colorant, photo-chromic colorant, fluorescer, optical brightener, color lake, organic pigment, composite pigment and its mixing
Object.
According to another specific embodiment, composition of the invention further includes at least one other filler.Root
According to another embodiment, composition of the invention further includes at least one organic UV sun-prevention components, be it is organic and/or
Inorganic UV sun-prevention components.
In yet another aspect, the present invention relates to nursing and/or the method for makeup keratin material, including to the keratin
Material, particularly to skin, using composition according to the present invention, if such as be administered to skin of face composition coating or
The form of the composition of dried layer, individually or with another combination of compositions (two step applications) use, institute according to the present invention
Composition is stated to be administered before or after the application of care composition or make-up composition such as foundation cream (foundation).
Particularly, to skin, particularly skin of face applying said compositions provide bright and health shine to the former
Effect.
The target of the present invention was also resided in cosmetic composition in the form of an emulsion such as including according to the definition of the present invention
At least one particle size be less than 35 microns, preferably 2 microns to 35 microns, more preferable 11 microns to 17 microns of scattering filler,
The combination of at least red or pink mother-of-pearl and at least blue mother-of-pearl is as improving the reagent of the brightness effect of the colour of skin
Purposes.
Specific embodiment
Scatter filler
Composition according to the present invention includes at least one scattering filler, and particle size is less than 35 microns, preferably 2 microns
It is to 35 microns and 11 microns to 17 microns more preferable.
Particle size is represented in the form of average volume diameter (D [0.5]).
Particularly, the refractive index for scattering filler is 1.6 to 2.5, preferably 1.7 to 2.3 and more preferable 1.7 to 2.2.
Particularly, scatter filler be selected from boron nitride, barium sulfate, bismuth oxychloride, aluminium oxide and based on titanium oxide with as talcum,
Mica, barium sulfate, boron nitride, bismuth oxychloride, aluminium oxide, mixed object substrate composite powder.
In special embodiment, scattering filler is bismuth oxychloride.
In preferred embodiments, scattering filler is cluster crystal bismuth oxychloride, and particle size is less than 35 microns, preferably 2
Micron is to 35 microns and 11 microns to 17 microns more preferable.
Cluster crystal bismuth oxychloride as referred in the present invention can scatter light, therefore help further to transfer to skin bright
(luminous) and shine (glow) effect, without glitter (shiny) appearance.
The example of commercial product as bismuth oxychloride, we can use following product：Ronaflair ESQ, are obtained
From Merck, Ronaflair LF -2000, obtained from Merck, Mearlite GLS and Mearlite LBU, obtained from BASF
Corporation, POL LO, obtained from George Uhe Company, Inc., Pearl I and II and Pearl Supreme
UVS, obtained from Presperse LLC, Pearl-Glo 1085, Pearl-Glo M 1098,1099 and of Pearl-Glo SF
Pearl-Glo SF UVR 1060, obtained from BASF Corporation.
As preferred bismuth oxychloride, we use following product：Ronaflair ESQ, obtained from Merck,
Ronaflair LF -2000, obtained from Merck, more preferable Ronaflair ESQ, obtained from Merck.
The content of at least one scattering filler as described above in the present compositions is 0.5 to 15wt%, preferably 1
To 10wt% and more preferable 2 to 5wt%, it is based on the total weight of the composition.
Mother-of-pearl
Term " mother-of-pearl ", which is appreciated that, refers to any type of flash of light or non-flash colored particles, especially by
Some mollusks generate or alternatively synthesize in its shell, have the color effect by optical interference.
Said composition includes at least red or pink mother-of-pearl and blue mother-of-pearl.
Red or pink mother-of-pearl is the mother-of-pearl with red or pink reflected colour.
Blue mother-of-pearl is the mother-of-pearl for having blue reflected color.
Mother-of-pearl may be selected from pearlescent pigment, such as apply the mica coated with iron oxide, apply the mica coated with bismuth oxychloride, coating
With titanium oxide or the mica of titanium dioxide, the mica coated with chromium oxide is applied, applies the mica coated with tin oxide, applies the cloud coated with SnO2
Mother applies the mica coated with BaSO4, applies the mica coated with organic dyestuff and the pearlescent pigment based on bismuth oxychloride.They may be used also
To be to be superimposed at least mica particles of the metal oxide of two pantostrats and/or toner in its surface.Preferably, it is precious
Pearl oyster is white in terms of its appearance, they are preferably formed by coating with the mica of at least titanium dioxide.
The example for the mother-of-pearl that can also be referred to includes applying coated with titanium oxide, iron oxide, natural pigment or bismuth oxychloride
Natural mica.
As preferred mother-of-pearl, we are using the mica applied coated with titanium oxide or titanium dioxide and apply coated with titanium dioxide
The mica of titanium and tin oxide.
In commercially available mother-of-pearl, it is mentioned that by BASF AG sell Timica, Flamenco and
Duochrome (mica-based) mother-of-pearl, the Timiron mother-of-pearls sold by MERCK companies are sold by Eckart companies
Prestige mica-based mother-of-pearls, below based on the mother-of-pearl of natural mica：Obtained from the Sunpearl of Sun Chemical companies,
Sunprizma obtained from the KTZ of Kobo companies and obtained from Sun Chemical companies, based on synthetic mica by Sun Chemical
Sunshine the and Sunprizma mother-of-pearls and the Timiron sold based on synthetic mica by MERCK companies that company sells
Synwhite mother-of-pearls.
Mother-of-pearl can more particularly have pink, red, bronze, orange, blueness, brown, golden and/or coppery
Color or reflective.
As the example for the mother-of-pearl that can be used in the context of the present invention, it can be mentioned that the treasure of pink-color
Pearl oyster, especially by BASF AG with Brilliant gold 212G (Timica), Gold 222C (Cloisonne),
Sparkle gold's (Timica), Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne)
Title sale；Bronze mother-of-pearl, especially by MERCK companies with Bronze fine (17384) (Colorona) and
The title of Bronze (17353) (Colorona) and by BASF AG with the title pin of Super bronze (Cloisonne)
It sells；Orange mother-of-pearl, especially by BASF AG with Orange 363C (Cloisonne) and Orange MCR 101
(Cosmica) title and by MERCK companies with Passion orange (Colorona) and Matte orange (17449)
(Microna) title sale；Red mother-of-pearl, especially by BASF AG with Summit Red 30D's (Flamenco)
Title sale；Blue mother-of-pearl is especially sold by MERCK companies with the title of Silk Blue (Timiron)；It is filbert
Mother-of-pearl, especially by BASF AG with Nuantique copper 340XB (Cloisonne) and Brown CL4509
(Chromalite) title sale；Mother-of-pearl with light coppery, especially by BASF AG with Copper 340A
(Timica) title sale；With pink mother-of-pearl, especially by MERCK companies with Sienna fine (17386)
(Colorona) title sale；Pale red mother-of-pearl with weak golden, especially by BASF AG with Sunstone G012
(Gemtone) title sale；Pink mother-of-pearl, especially by BASF AG with Tan opale G005's (Gemtone)
Title sale；Black mother-of-pearl with weak golden, especially by BASF AG with 240 AB of Nu antique bronze
(Timica) title sale；Blue mother-of-pearl, especially by MERCK companies with Matte blue (17433) (Microna)
Title sale；White pearl with light silver color is female, is especially sold by MERCK companies with the title of Xirona Silver
's；With golden-green pink-orange mother-of-pearl, especially by MERCK companies with the title pin of Indian summer (Xirona)
Sell and its mixture.
As the example of red or pink mother-of-pearl, we can use the mother-of-pearl of pink color, especially by
BASF AG is with Brilliant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold
(Timica), the title of Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne) are sold；It is red
Color mother-of-pearl is especially sold by BASF AG with the title of Summit Red 30D (Flamenco)；With pink treasure
Pearl oyster is especially sold by MERCK companies with the title of Sienna fine (17386) (Colorona)；With weak golden
Pale red mother-of-pearl is especially sold by BASF AG with the title of Sunstone G012 (Gemtone)；Pink pearl
Mother is especially sold by BASF AG with the title of Tan opale G005 (Gemtone)；With its mixture.
As preferred red or pink mother-of-pearl, we using red mother-of-pearl, especially by BASF AG with
The title sale of Summit Red 30D (Flamenco).
As the example of blue mother-of-pearl, we can use blue mother-of-pearl, especially by MERCK companies with Silk
The title sale of Blue (Timiron)；Blue mother-of-pearl, especially by MERCK companies with Matte blue (17433)
(Microna) title sale；With its mixture.
As preferred blue mother-of-pearl, we are using blue mother-of-pearl, especially by MERCK companies with Silk Blue
(Timiron) title sale.
In general, the content of mother-of-pearl in the present compositions for 1 to 10wt%, preferably 2 to 8wt% and more preferable 3 to
6wt% is based on the total weight of the composition.
In general, the content of red or pink mother-of-pearl in the present compositions is 1 to 10wt%, preferably 2 to 8wt%
With more preferable 3 to 6wt%, it is based on the total weight of the composition.
In general, the content of blue mother-of-pearl in the present compositions is 0.1 to 1wt%, preferably 0.2 to 0.5wt%, press
The gross weight meter of composition.
Purpose to realize the present invention, at least one scattering filler and at least red or pink mother-of-pearl
Weight ratio is about 20:1 to about 1:20, preferably from about 5:1 to about 1:5.
The weight ratio of at least red or pink mother-of-pearl and at least blue mother-of-pearl is about 10:1 to about 1:
10, preferably from about 5:1 to about 1:3.
In special embodiment, it is more than 80%, by the coloured particle of the composition to scatter filler and mother-of-pearl
The weight meter of the total amount of (colored particles), particularly, more than 90%, more than 95%, more than 98%, by the composition
Coloured particle (colored particles) total amount weight meter.
Galenic (Galenic) form
The present invention relates to cosmetic composition, especially emulsion types, can be for angle egg of nursing and/or make up
White material, the particularly form of the composition of skin or the form of sun-proof (sun protection) composition.
Then it can be colourless or low color value form, optionally comprising cosmetic or dermatological active agent.Then it can be used
Keratin material is acted on, particularly the nursing of skin or makeup foundation (base).
The composition of the present invention can also be for keratin material of making up, and be particularly used for the colored product of cosmetic skin
Form, be such as particularly applied to the foundation cream (foundation) of face or neck, hide far product (concealer), flesh correction
Substance (complexion corrector), light color missible oil (tinted cream) or body make-up composition.
Particularly, composition of the invention is low color value form, foundation (base) of preferably making up.
Composition according to the present invention can be various forms of, the particularly shape of anhydrous composition, dispersion or lotion
Formula, especially such as water/oil or oil/water lotion or multiple emulsion.
The composition of the present invention is preferably lotion, particularly direct or inverted emulsion or anhydrous composition.
Preferably, it is lotion.
Dispersion can be made into water phase or oil phase is made.
Lotion can have oil or water continuous phase.Such lotion can be, for example, inverse (W/O) lotion or direct (O/W)
Lotion or alternatively multiple emulsion (W/O/W or O/W/O).
In the case of lotion, direct (O/W) lotion is preferred.
Particularly, the form of composition according to the present invention can be oil-in-water (O/W) lotion, Water-In-Oil (W/O) lotion,
Or multiple emulsion, preferably oil-in-water (O/W) lotion.
Composition according to the present invention can be formed foundation (base) composition or nursing and/or make-up composition or
Person is below another makeup and/or care composition or the composition applied above, so as to by skin in a manner of touching on a small quantity
Color is unified.
It, will advantageously in the case that composition according to the present invention is nursing and/or makeup foundation (base) wherein
Undyed or dye very much, this allows to fill out using scattering according to the present invention in the foundation (base) low degree
Material and the combination of mother-of-pearl.This nursing and/or makeup foundation (base) can be applied to entire face, then application nursing
Composition and/or make-up composition.According to another embodiment, the nursing of a certain layer or make-up composition (foundation cream are being applied
(foundation)) before (under) or application a certain layer nursing or make-up composition (foundation cream (foundation)) afterwards (on),
The nursing and/or makeup foundation (base) are used in a manner of touching and making up.
According to a kind of special embodiment, the composition (in touches) in a manner of touching is applied to show
Go out the face area of defect of skin；This application can before the subsequent application of foundation cream (foundation) or followed by.
According to another special embodiment, can be applied around eyes so as to ocular blast or on lip,
It applies to give curve shape on Cupid's bow (cupid's bow).
According to a kind of special embodiment, the composition is applied on such people, and the skin of the people has
The heterogeneity of visible and/or tactile inhomogeneities and/or the colour of skin.
A kind of special embodiment according to the present invention, the composition are applied to have on the people of Oily.
Another special embodiment according to the present invention, the composition are applied to have aged skin or into barks
On the people of skin.
Another special embodiment according to the present invention, the composition are applied to the people with Asian skin
On.
Physiologically acceptable medium
In addition to compound pointed before, composition according to the present invention includes physiologically acceptable medium.
Term " physiologically acceptable medium " is intended to indicate such medium, particularly suitable for by according to the present invention group
It closes object and is administered to skin.
Physiologically acceptable medium typically be adapted to thereon by application composition carrier property and be adapted to it
Form packaged by middle composition.
The composition of the present invention can be dispersion or lotion.
Dispersion can be made into water phase or oil phase is made.
Lotion can have oil or water continuous phase.Such lotion can be, for example, inverse (W/O) lotion or direct (O/W)
Lotion or alternatively multiple emulsion (W/O/W or O/W/O).
In the case of lotion, direct (O/W) lotion is preferred.
Water phase
Composition according to the present invention can include water phase.
Water mutually includes water.It can be flowers water such as corn flower water and/or mineral water such as Vittel to be suitable for the invention water
Water, Lucas water or La Roche Posay water and/or spring.
Water can also mutually include the organic solvent (at room temperature: 25 DEG C) that can mix of water, such as comprising 2 to 6 carbon atoms
Monohydric alcohol, such as ethyl alcohol or isopropanol；Polyalcohol, especially comprising 2 to 20 carbon atoms, preferably comprise 2 to 10 carbon atoms and
Preferentially comprising 2 to 6 carbon atoms, such as glycerine, propylene glycol, butanediol, pentanediol, hexylene glycol, dipropylene glycol or diethylene glycol (DEG)；
Glycol ethers (especially comprising 3 to 16 carbon atoms) such as propylene glycol, dipropylene glycol, tripropylene glycol (C1-C4) alkyl ether, one, two
Or triethylene glycol (C1-C4) alkyl ether and its mixture.
Water can also mutually include stabilizer, such as sodium chloride, magnesium dichloride or magnesium sulfate.
Water can also mutually include any water-soluble or water dispersible compound mutually compatible with water, for example, gelling agent,
Film forming polymer, thickener or surfactant and its mixture.
Particularly, composition of the invention can include water phase, and content is 1wt% to 80wt%, and especially 5wt% is extremely
50wt%, particularly 10wt% to 45wt%, compared with the total weight of composition.
Fatty phase
Cosmetic composition according to the present invention can include at least one liquid and/or hard fat phase.
According to a kind of embodiment, composition according to the present invention is emulsion form.
Particularly, composition of the invention can include at least one liquid aliphatic phase, especially at least a kind of following oil.
Term " oil " refers to any fatty material, in room temperature (20-25 DEG C) and is liquid at atmosheric pressure.
The composition of the present invention can include liquid aliphatic phase, and content is 1% to 90%, particularly 5% to 80%, particularly
10% to 70%, more particularly 20% to 50%, by weight, compared with the total weight of composition.
Oil phase suitable for preparing cosmetic composition according to the present invention can include alkyl oil, silicone oil, fluoro oil or non-
Fluoro oil or its mixture.
Oil can be volatile or non-volatile.
They can be animal, plant, inorganic matter or synthesis source.
Term " fixed oil " refers to such oil, at room temperature and pressure still in skin or keratin fiber
On.More specifically, the evaporation rate of fixed oil is less stringent than 0.01 milli gram/cm/minute.
To measure the evaporation rate, 15 grams of oil to be tested or oil mixture are placed in the crystallising dish of 7 centimetres of diameter,
It is positioned on the balance in about 0.3 cubic metre of big cabin, the temperature in the big cabin adjusts the temperature to 25 DEG C, humidity tune
Save the relative humidity to 50%.The liquid is made freely to evaporate, ventilation is provided without stirring it, while by fan
(Papst-Motoren, 8550 newton of benchmark, with 2700 revs/min of rotations), the fan is placed on containing the oil or described mixed
It closes in the upright position above the crystallising dish of object, flabellum is towards crystallising dish, apart from 20 centimetres of the bottom of crystallising dish.Periodic measurement exists
The quality of remaining oil in crystallising dish.Evaporation rate is with per unit area（Square centimeter）Per unit time（Minute）It is steamed
The milligram number expression of the oil of hair.
Term " volatile oil " refers to any non-aqueous media, at room temperature and pressure, after with skin or lip contact
When small less than 1, it can evaporate.Volatile oil is cosmetic volatile oil, is liquid at room temperature.More specifically, volatilize
The evaporation rate of oil is 0.01 to 200 milli gram/cm/minute, including endpoint.
For the purpose of the present invention, term " silicone oil " refers to such oil, including at least one silicon atom, and especially
At least one Si-O groups.
Term " fluoro oil " refers to such oil, including at least one fluorine atom.
Term " alkyl oil " refers to such oil, mainly includes hydrogen and carbon atom.
Oil can optionally include oxygen, nitrogen, sulphur and/or phosphorus atoms, such as in the form of hydroxyl or acid group.
Volatile oil
The alkyl oil of optional self-contained 8 to 16 carbon atoms of volatile oil, and especially C8-C16 branched paraffins (also known as different alkane
Hydrocarbon), such as Permethyl 99A (also known as 2,2,4,4,6- five methylheptanes), isodecane and isohexadecane, such as in trade name
The oil sold under Isopar or Permethyl.
The volatile oil that can also use includes volatile siloxane, such as volatility is linear or cyclic silicone oils, especially viscosity
Less than or equal to 8 centistokes (cSt) (8 × 10-6Square meter per second) those, and especially comprising 2 to 10 silicon atoms and particularly
2 to 7 silicon atoms, these siloxanes optionally include alkyl or alkoxy containing 1 to 10 carbon atom.As can be used for this
Volatile silicone oils in invention can especially refer to the dimethyl silicone polymer that viscosity is 5 to 6cSt, four silica of prestox ring
Alkane, decamethylcyclopentaandoxane, ten diformazan basic rings, six siloxanes, seven methylhexyl trisiloxanes, seven Methyl Octyl trisiloxanes,
Hexamethyldisiloxane, octamethyltrisiloxane, decamethyl tetrasiloxane and ten dimethyl, five siloxanes and its mixture.
According to a kind of embodiment, composition of the invention can include 1wt% to 80wt% or even 5wt% to 70wt%,
Or the volatile oil of even 10wt% to 60wt% and especially 15wt% to 50wt%, compared with the total weight of composition.
Fixed oil
Fixed oil can be especially selected from nonvolatile hydrocarbon-based oils, fluoro oil and/or silicone oil.
The non-volatile alkyl oil that can especially mention includes：
The alkyl oil of-animal origin, such as perhydro squalene,
The alkyl oil of-plant origin, such as phytosterol ester, such as phytosterol oleate, phytosterol isostearic acid
Ester and lauryl/octyldodecyl/phytosterol glutamate (Ajinomoto, Eldew PS203), by the fat of glycerine
The triglycerides that acid esters is formed, particularly wherein aliphatic acid can have C4 to C36, the chain length of especially C18 to C36, these oil
Perhaps it is linear or branch, and saturation or undersaturated；These oil especially can be enanthic acid or Trivent OCG, breast
Oily wood fruit oil, alfalfa oil, poppy seed oil, winter squash oil, millet oil, big wheat oil, chenopodium oil, rye-seed oil, candlenut oil, passionflower
Oil, missible oil wood fruit fat, aloe, Sweet Almond Oil, persic oil, peanut oil, argan oil, avocado oil, kopok oil, Common Borage
Seed oil, broccoli oil, pot marigold oil, cameline oil, canola oil, carrot oil, safflower oil, linseed oil, rapeseed oil, cottonseed oil, coconut palm
Seed oil, marrow seed oil, wheat-germ oil, jojoba oil, lily caul-fat, Australia nut oil, corn oil, white pond flower seed oil, St. john's wort
Oil, gardenia flower oil, hazelnut oil, apricot kernel oil, walnut oil, olive oil, evening primrose oil, palm oil, blackcurrant seed oil, unusual fruit seed
Oil, grape seed oil, pistachio seed oil, winter squash oil, squash oil, musk rose oil, sesame oil, soya-bean oil, sunflower oil, castor oil
And cocerico oil and its mixture or alternatively caprylic/capric triglyceride, such as by Stearineries Dubois companies
Sell those or sold with the title of Miglyol 810,812 and 818 by Dynamit Nobel companies those,
- inorganic or synthesis source linear or branch hydrocarbon, such as liquid alkanes and its derivative, vaseline, the poly- last of the ten Heavenly stems
Alkene, polybutene, Parleam such as Parleam and saualane；
- synthesis the ether containing 10 to 40 carbon atoms；
- synthetic ester, such as the oil of formula R1COOR2, wherein R1 are linear or branch the aliphatic acid containing 1 to 40 carbon atom
Residue, R2 are hydrocarbyl chains, especially branch, containing 1 to 40 carbon atom, condition be carbon atom number in chain R1 and R2 it
With more than or equal to 10.Ester can be especially selected from the aliphatic ester of alcohol, such as cetearyl stearyl ester, isopropyl alcohol ester, such as beans
Cool isopropyl propionate, isopropyl palmitate, ethyl palmitate, palmitic acid 2- ethylhexyls, isopropyl stearate, isostearic acid isopropyl
Ester, isostearyl isostearate ester, octyl stearate, hydroxylated ester, such as lactic acid isooctadecanol ester, hydroxy stearate are misery
Ester, diisopropyl adipate, especially heptanoate and enanthic acid isooctadecanol ester, alcohol or polyalcohol caprylate, decylate or castor-oil plant alcohol
Acid esters, such as propylene, cetearyl alcohol ester, sad tridecane base ester, bis- heptanoate (2- of 2- ethylhexyls 4-
Ethylhexyl 4-diheptanoate), palmitic acid 2- ethylhexyls, benzoic acid alkyl base ester, two heptanoate of polyethylene glycol, third
Glycol 2- ethylhexanoates and its mixture, benzoic acid C12-C15 alcohol esters, lauric acid hexyl ester, pivalate, such as new penta
Sour isodecyl ester, neopentanoic acid isotridecyl ester, neopentanoic acid isooctadecanol ester, Elefac I 205, isononoate, example
Such as isononyl isononanoate, isononanoic acid isotridecyl ester, isononanoic acid octyl group ester, hydroxylated ester, such as lactic acid isooctadecanol ester
And diisooctadecanol malate,
- polyol ester and pentaerythritol ester, such as dipentaerythritol tetrahydroxy-stearic acid ester/pentaerythritol tetraisostearate,
The ester of-dimer diol and diacid dimer, such as Lusplan DD-DA5 and Lusplan DD-DA7, by
Nippon Fine Chemical sell and are described in patent application US 2004-175 338,
- dimer diol and the copolymer of diacid dimer and its ester, such as two sub-oil base glycol dimer/dilinoleic acid two
Polymers（dilinoleyl diol dimer/dilinoleic dimer）Copolymer and its ester, such as Plandool-G,
The copolymer and its ester of-polyalcohol and diacid dimer, such as Hailuscent ISDA or dilinoleic acid
(dilinoleic acid)/butanediol copolymer,
- it is liquid, the fat with branch the and/or undersaturated carbon-based chain containing 12 to 26 carbon atoms at room temperature
Fat alcohol, such as 2- octyldodecanols, isooctadecanol, oleyl alcohol, 2- hexyl decyl alcohols, 2- butyl octanol and 2- undecyl pentadecanes
Alcohol；
- C12-C22 higher fatty acids, such as oleic acid, linoleic acid or leukotrienes and its mixture,
- dialkyl carbonate, two alkyl chains may be identical or different, such as carbonic acid dioctyl ester, in Cetiol CC
Title under sold by Cognis,
The oil of-high mole, particularly mole is about 400 to about 10000 grams/mol, and particularly about 650 to about
10000 grams/mol, particularly, about 750 to about 7500 grams/mol, more specifically about 1000 to about 5000 grams/mol.As can
For the oil of the high mole of the present invention, it is particularly possible to refer to selected from following oil：
* lipophilic polymer,
* total carbon number is 35 to 70 linear aliphatic acid esters,
* hydroxylated ester,
* aromatic ester,
* the aliphatic acid or aliphatic alcohol ester of C24-C28 branches,
* silicone oil,
* the oil of plant origin and
* its mixture；
- optionally part alkyl and/or siloxanes fluoro oil, such as fluoro silicone oil, fluoropolyether and fluorosilicone, such as
Described in file EP-A-847752；
- silicone oil, such as linear or cricoid non-volatile dimethyl silicone polymer (PDMS)；Dimethyl silicone polymer,
It is to dangle or in the end of silicone chains, these groups include 2 to 24 carbon atoms including alkyl, alkoxy or phenyl；
Phenysiloxane polymer, such as phenyl trimethicone, phenyl dimethicones, phenyl trimethicone siloxy two
Phenyl siloxane, diphenyl dimethicone, diphenyl methyl diphenyl trisiloxanes and 2- phenethyl trimethyl silica
Base esters of silicon acis and
- its mixture.
According to a kind of special embodiment, the fat of composition according to the present invention mutually can only include volatility
Close object.
Additive
In special embodiment, cosmetic composition according to the present invention further includes at least one selected from following change
Close object：Water, hydrophilic solvent, lipophilic solvent, oil and its mixture.
Cosmetic composition according to the present invention may also include any additive commonly used in field of interest, example
Such as, selected from glue, anion, cation, both sexes or nonionic surface active agent, silicone surfactant, resin, thickening
Agent, structuring agents such as wax, dispersant, antioxidant, essential oil, preservative, fragrance, neutralizer, preservative, UV- smoke agents for shielding are changed
The activating agent of adornment, such as vitamin, wetting agent, emollient or collagen-protective agent and its mixture.
To those skilled in the art, adjust the additive in the presence of composition according to the present invention attribute and
Quantity is to be the thing of a routine operation thus without influencing desired its cosmetic properties and stability.
Other colorant
Composition according to the present invention can also include at least one colorant.Cosmetic composition according to the present invention can
It is at least one selected from following colorant to be advantageously combined：Organic or inorganic colorant, particularly such as conventionally used for cosmetics
Pigment in composition can be fat-soluble or water-soluble and its mixture.
Particularly, inorganic colourant in addition is titanium dioxide, is used to improve covering performance on the skin.
Particularly, organic pigment in addition is used to provide better appearance for product.
The content of other colorant can be 0.001 to 5%, preferably 0.01 to 2% and more preferable 0.5 to 2%.
Term " pigment " is understood to refer to white or coloured, inorganic or organic granular, in solution not soluble in water
And it is intended to the film band color and/or opaque for making gained.
As inorganic pigment for use in the present invention, it can be mentioned that titanium oxide or titanium dioxide, zirconium oxide or ceria,
And zinc oxide, ferriferous oxide or chromium oxide, barba hispanica (ferric blue), manganese violet, ultramarine（ultramarine blue）And chromium
Hydrate.As preferred inorganic pigment, it can be mentioned that titanium dioxide, ferriferous oxide and its mixture.
Preferably, inorganic pigment is titanium dioxide.
Titanium dioxide can be, for example, the titanium dioxide of surface treatment.It is suitable for the invention the titanium dioxide of surface treatment
The non-limiting examples of titanium can be such titanium dioxide, and surface is with the processing of C9-15 fluorinated alcohols phosphate and/or further
Use metal oxide treated.
Preferably, it can be mentioned that with C9-C15 fluorinated alcohols phosphate be surface-treated titanium dioxide, with PF-5 TiO2 CR-
Titanium dioxide that is that 50 trade name is sold by Daito Kasei Kogyo or being surface-treated with C9-C15 fluorinated alcohols phosphate
Titanium is sold with the trade name of PFX-5 TiO2 CR-50 by Daito Kasei Kogyo.
Among the organic pigment that can be used in the present invention, it can be mentioned that carbon black, the pigment of D＆C types, based on cochineal
Red (cochineal carmine) or color lake based on barium, strontium, calcium or aluminium or alternatively diketopyrrolopyrrolecocrystals
(DPP), as described in file EP-A-542669, EP-A-787730, EP-A-787731 and WO-A-96/08537.
Those of following titles are among the organic pigment that can especially refer to：The brown No. 1, D＆C of D＆C indigo plants No. 4, D＆C
The green No. 6 of green No. 5, D＆C, D＆C oranges No. 4, D＆C oranges No. 5, D＆C oranges No. 10, D＆C oranges No. 11, D＆C is red
No. the red No. 7 of 6, D＆C, D＆C red No. 17, D＆C red No. 21, the D＆C red No. 27 of red No. 22, D＆C, D＆C is red
No. the red No. 36, D＆C of the red No. 30 of 28, D＆C, D＆C red No. 31, D＆C red No. 33, D＆C red No. 34, D＆C
Purple No. 2, D＆C Huangs No. 7, D＆C Huangs No. 8, D＆C Huangs No. 10, D＆C Huangs No. 11, FD＆C indigo plants No. 1, FD＆C
Green No. 3, FD＆C red No. 40, FD＆C Huangs No. 5, FD＆C Huangs No. 6, D＆C black 2 (carbon black) and phthalocyanine blue and it is mixed
Close object.
Cosmetic composition according to the present invention can also include water-soluble or lipid-soluble dye.Lipid-soluble dye, for example,
Tonyred, red 17, the DC of DC green 6, beta carotene, the Sudan is brown, DC Huangs 11, DC purples 2, DC oranges 5 and quinoline yellow.Water solubility dye
Material e.g. beet root juice and burnt sugar coloring (caramel).According to a kind of specific embodiment, composition of the invention is included extremely
A kind of few special colorant, is selected from：Goniochromatism（goniochromatic）Colorant, photo-chromic colorant, fluorescer,
Optical brightener, color lake, organic pigment, composite pigment and its mixture.
Filler
Composition according to the present invention can also include the filler of at least one organic or inorganic property.
In general, the content of filler in the present compositions for 0.1 to 20wt%, preferably 0.5 to 10wt% and more preferably
1 to 5wt%, based on the weight of composition.
In special embodiment, the content of filler is less than 5wt%, preferably less than 3wt%, by the weight of composition
Meter.
Term " filler " is understood to refer to the colourless or white solid particle of any shape, is insoluble in and divides
It is dispersed in the form in the medium of composition.They are inorganic or organic in nature and make imparting mildness and tarnish
It is possibly realized to the composition and homogeneous cosmetic results.
Can be laminar, coccoid or balled form for the filler in composition according to the present invention, fiber shape
Formula or between these prescribed forms any other intermediate forms.
Filler according to the present invention can with or surface coating may not be carried out, particularly they can use siloxanes, amino acid,
Fluoro derivatives or any other substance (promoting the scattered and compatibility of filler in the composition) are surface-treated.
Among available for the inorganic filler in composition according to the present invention, it can be mentioned that talcum, mica, titanium dioxide
Silicon, trimethylsiloxysilicates, kaolin, bentonite, calcium carbonate, magnesium bicarbonate, hydroxyapatite, boron nitride, hollow dioxy
SiClx microballoon (silica beads, obtained from Maprecos), glass or ceramic microcapsules, silica based filler, such as Aerosil
200 or Aerosil 300；Sunsphere H-33 and Sunsphere H-51, are sold by Asahi Glass；By Asahi
The Chemicelen that Chemical is sold；The composite material of silica and titanium dioxide, such as by Nippon Sheet
The TSG series and its mixture that Glass is sold.
Filler suitable for the present invention can be preferentially talcum, silica or its mixture.
Among available for the organic filler in composition according to the present invention, it can be mentioned that polyamide powder (Nylon
Orgasol, obtained from Atochem), poly -β alanine and polyethylene powders, polytetrafluoroethylene (PTFE) (Teflon) powder, lauroyl
Lysine, starch, tetrafluoroethylene polymer powder, polymeric hollow microsphere, such as Expancel (Nobel Industrie),
From containing 8 to 22 carbon atoms, the metallic soap of the organic carboxyl acid of preferably 12 to 18 carbon atoms, such as zinc stearate, tristearin
Sour magnesium or lithium stearate, zinc laurate, myristic acid magnesium, Polypore L 200 (Chemdal Corporation), organosilicon
Resin microbeads (Tospearl, obtained from Toshiba, such as), polyurethane powder, the particularly crosslinked poly- ammonia including copolymer
The powder of ester, the copolymer include trihydroxy methyl caprolactone, such as diisocyanate hexa-methylene ester/trihydroxy methyl caprolactone gathers
Object is closed, is sold with the title of Plastic Powder D-400 or Plastic Powder D-800 by Toshiki companies,
Babassu microwax, such as the product sold with the title of MicroCare 350 by Micro Powders companies, synthesis
The microwax of wax, such as the product sold with the title of MicroEase 114S by Micro Powders companies, by cohune
The microwax that the mixture of palmitic acid wax and polyethylene wax is formed, such as with the title of MicroCare 300 and 310 by Micro
Those of Powders companies sale, the microwax being made of the mixture of Brazil wax and synthetic wax, such as by Micro
The product that Powders companies are sold with the title of MicroCare 325, polyethylene microwax, such as with Micropoly 200
, the title of 220,220L and 250S sold by Micro Powders companies those；With its mixture.
UV sun-prevention components
Shielding (screening) composition according to the present invention includes organic and/or inorganic UV sun-prevention components, in UV-A
And/or in UV-B regions be active, it is hydrophilic and/or oleophylic.
The organic UV sun-prevention components of hydrophilic and/or oleophylic are in particular selected from dibenzoylmethane derivatives；Cinnamic acid
(cinnamic) derivative；Salicylic acid (salicylic) derivative；Benzophenone derivates；β, β-diphenylacrylate ester spread out
Biology；P-aminobenzoic acid (PABA) derivative；With its mixture.
As the example of organic UV sun-prevention components, it can be mentioned that those represented below with its INCI title：
- p-aminobenzoic acid derivative：
- PABA,
- ethyl PABA,
- ethyldihydroxypropyl PABA,
- ethylhexyl PABA is particularly sold under trade mark " Escalol 507 " by ISP,
- glyceryl PABA,
- dibenzoylmethane derivatives：
- butylmethoxydibenzoylmethane, particularly by Hoffmann- under trade mark " Parsol 1789 "
LaRoche is sold,
- isopropyldibenzoylmethane methane,
- salicyclic acid derivatives：
- Homosalate is sold under trade mark " Eusolex HMS " by Rona/EM Industries,
- ethylhexyl salicylate is sold under trade mark " Neo Heliopan OS " by Haarmann and Reimer,
- dipropylene glycol salicylate is sold under trade mark " Dipsal " by Scher,
- trolamine salicylate is sold under trade mark " Neo Heliopan TS " by Haarmann and Reimer,
- cinnamon derivative：
- ethylhexyl methoxy cinnamate is particularly sold under trade mark " Parsol MCX " by Hoffmann-LaRoche
It sells,
- methoxycinnamate isopropyl propionate,
- methoxycinnamate isoamyl valerate, by Haarmann and under trade mark " Neo Heliopan E 1000 "
Reimer is sold,
- Cinoxate,
- methoxy cinnamic acid DEA salt,
- methyl cinnamic acid diisopropyl ester (Diisopropyl Methylcinnamate),
- glyceryl ethylhexanoate ester dimethoxy-cinnamic acid ester,
- β, β-diphenylacrylate：
- Ou Tuokuilei is particularly sold under trade mark " Uvinul N539 " by BASF,
- according to Care woods is stood, particularly sold under trade mark " Uvinul N35 " by BASF,
- benzophenone derivates：
- benzophenone-1 is sold under trade mark " Uvinul 400 " by BASF,
- benzophenone-2 is sold under trade mark " Uvinul D50 " by BASF,
- benzophenone-3 or oxybenzone are sold under trade mark " Uvinul M40 " by BASF,
- UVINUL MS 40 is sold under trade mark " Uvinul MS40 " by BASF,
- benzophenone -5,
- benzophenone -6 are sold under trade mark " Helisorb 11 " by Norquay,
With its mixture.
Preferred UV sun-prevention components are selected from cinnamic acid derivative, β, β-diphenylacrylate, and salicylic acid derives
Object and its mixture.
Preferred UV sun-prevention components are especially selected from ethylhexyl methoxy cinnamate, Ou Tuokuilei and salicylic acid ethyl hexyl
Ester and its mixture.
Especially it is mentioned that：Ethylhexyl methoxy cinnamate, it is public by BASF with 80 trade names of UVINUL MC
Department's sale；Ethylhexyl salicylate is sold with NEO HELIOPAN OS trade names by SYMRISE companies；And Ou Tuokui
Thunder is sold with 303 trade names of NEO HELIOPAN by SYMRISE companies.
Composition according to the present invention can include 0.1wt% to 30wt%, such as 0.5 to 20wt%, such as 1 to 15wt%,
The UV sun-prevention components of for example, at least 1wt%, compared with the total weight of composition.
Embodiment
Embodiment 1：The lotion O/W of combination with the present invention.
After research, good embodiment, appearance is pinkish slightly white, can transfer in the pink of condition shine
Optical effect.
| Phase | INCI titles | Raw material %, by weight Gauge |
| A | Water | Qsp 100 |
| A | Glycerine (glycerine, 99.8% PF, obtained from Emery Oleochemicals LLC) | 8 |
| A | Preservative | 0.8 |
| A | Propylene glycol (propylene glycol USP/EP, obtained from Dow Chemical) | 8 |
| A | EDETATE SODIUM (Versene Na2 crystal, obtained from Dow Chemical) | 0.05 |
| A | Phosphoric acid monohexadecyl ester potassium (Amphisol K, obtained from DSM Nutritional Products, Inc.) | 1 |
| A | Carbomer (980 polymer of Carbopol, obtained from Lubrizol) | 0.3 |
| A | Xanthans (Keltrol CG, obtained from CG-T Kelco) | 0.1 |
| A | Cyclohexasiloxane (Xiameter PMX-0246 Cyclohexasiloxane, obtained from Dow Corning) | 6 |
| A | Triethanolamine (Tirethanolamine 99% (TEA 99), obtained from Dow Chemical) | 0.3 |
| B | Stearic acid (Palmera B1802CG, obtained from Klk Oleo) | 2 |
| B | Stearine (and) PEG-100 stearates (Simulsol 165, obtained from Seppic) | 1.5 |
| B | Cetanol (Ecorol 16/98, obtained from Ecogreen Oleochemicals) | 0.7 |
| B | Dimethyl silicone polymer (viscosity：350cSt, Xiameter PMX-200 Silicon Fluid 350CS, obtained from Dow Corning®) | 0.5 |
| B | Octyldodecanol (Eutanol G, obtained from Cognis (BASF)) | 4 |
| B | Ethylhexyl methoxy cinnamate (Parsol MCX, obtained from DSM Nutritional Products) | 7.5 |
| B | Triethanolamine (Tirethanolamine 99% (TEA 99), obtained from Dow Chemical) | 0.4 |
| B | Phenoxyethanol (Sepicide LD, obtained from Seppic) | 0.7 |
| B | Cyclohexasiloxane (Xiameter PMX-0246 Cyclohexasiloxane, obtained from Dow Corning) | 1 |
| B | Titanium dioxide (and) C9-15 fluorinated alcohols phosphate (and) aluminium hydroxide (PFX-5 TiO2 CR-50, obtained from Daito Kasei Kogyo) | 1 |
| C | Mica (and) titanium dioxide (Flamenco Summit Red R30D, obtained from BASF) | 4 |
| C | Titanium dioxide (and) mica (Timiron Silk Blue, obtained from Merck) | 0.3 |
| C | Bismuth oxychloride (RonaFlair ESQ, obtained from Merck) | 2.7 |
| C | Talcum (Luzenac Pharma M, obtained from Luzenac) | 0.5 |
| C | Silica (Solesphere H-51, obtained from AGC SI-TECH) | 0.5 |
| D | Red 4 (Unicert red 07004-J, obtained from Sensient Cosmetic Technologies) | 0.005 |
| D | 5 (Unicert yellow 08005-J, obtained from Sensient Cosmetic Technologies) of Huang | 0.0038 |
| E | Fragrance | 0.25 |
Preparation method.
It heats phase A to about 75 DEG C and merges various composition wherein；
Phase B is prepared, and is heated approximately to 75 DEG C；
Mixed phase A and B stir mixture until obtaining homogeneous lotion with Rayneri；
Remaining is mutually incorporated to lotion and stirs mixture until its cooling.
Appraisal procedure and result
The composition of the present invention of embodiment 1 is administered on the skin of 30 Asia women.It is stood after application composition
The result after application is assessed by 3 experts.
Assessment result
It carries out immediately after application, the results showed that：
| - bright (luminosity) is significantly improved | +29.5%(p<0.01); |
| - clarity (clarity) (brightness (brightness)) significantly improves | +15.5%(p<0.01); |
| -- transparency (transparency) significantly improves | +8.5%(p<0.01); |
| - olive colour component significantly reduces | -7.1%(p<0.01) |
| - yellow color component substantially reduces | -18.9%(p<0.01); |
| - pink component dramatically increases | +16.9%(p<0.01). |
Other color components variation of main performance skin color is as follows：
| - brown component significant changes | -11.0%(p<0.01); |
| - light brown component significant changes | -10.6%(p<0.01); |
| - cream-coloured component significant changes | -10.4%(p<0.01); |
These variations show the composition of embodiment 1 notable blast skin color at once after application.
All these data have been shown in significantly improving for the skin luminosity of horse back after the composition using embodiment 1.
All the indexs (L, B, T, olive colour, yellow and pink) studied are towards desired direction.
Embodiment 2：The effect of the combination of the present invention.
3 parts of comparative examples are prepared so as to Evaluated effect, compared with the present invention of embodiment 1.
| Phase | INCI titles | Raw material %, by weight | Raw material %, by weight Meter | Raw material %, by weight |
| Comparative example 1 | Comparative example 2 | Comparative example 3 | ||
| A | Water | Qsp 100 | Qsp 100 | Qsp 100 |
| A | Glycerine (glycerine, 99.8% PF, obtained from Emery Oleochemicals LLC) | 8 | 8 | 8 |
| A | Preservative | 0.8 | 0.8 | 0.8 |
| A | Propylene glycol (propylene glycol USP/EP, obtained from Dow Chemical) | 8 | 8 | 8 |
| A | EDETATE SODIUM (Versene Na2 crystal, obtained from Dow Chemical) | 0.05 | 0.05 | 0.05 |
| A | Phosphoric acid monohexadecyl ester potassium (Amphisol K, obtained from DSM Nutritional Products, Inc.) | 1 | 1 | 1 |
| A | (980 polymer of Carbopol, is obtained from carbomer Lubrizol) | 0.3 | 0.3 | 0.3 |
| A | Xanthans (Keltrol CG, obtained from CG-T Kelco) | 0.1 | 0.1 | 0.1 |
| A | Cyclohexasiloxane (Xiameter PMX-0246 Cyclohexasiloxane, obtained from Dow Corning) | 6 | 6 | 6 |
| A | Triethanolamine (99% (TEA of Tirethanolamine 99), obtained from Dow Chemical) | 0.3 | 0.3 | 0.3 |
| B | Stearic acid (Palmera B1802CG, obtained from Klk Oleo) | 2 | 2 | 2 |
| B | Stearine (and) PEG-100 stearates (Simulsol 165, obtained from Seppic) | 1.5 | 1.5 | 1.5 |
| B | Cetanol (Ecorol 16/98, obtained from Ecogreen Oleochemicals) | 0.7 | 0.7 | 0.7 |
| B | Dimethyl silicone polymer (viscosity：350cSt, Xiameter PMX-200 Silicon Fluid 350CS, are obtained from Dow Corning®) | 0.5 | 0.5 | 0.5 |
| B | Octyldodecanol (Eutanol G, obtained from Cognis (BASF)) | 4 | 4 | 4 |
| B | Ethylhexyl methoxy cinnamate (Parsol MCX, Obtained from DSM Nutritional Products) | 7.5 | 7.5 | 7.5 |
| B | Triethanolamine (99% (TEA of Tirethanolamine 99), obtained from Dow Chemical) | 0.4 | 0.4 | 0.4 |
| B | Phenoxyethanol (Sepicide LD, obtained from Seppic) | 0.7 | 0.7 | 0.7 |
| B | Cyclohexasiloxane (Xiameter PMX-0246 hexamethylenes Siloxanes, obtained from Dow Corning) | 1 | 1 | 1 |
| B | Titanium dioxide (and) C9-15 fluorinated alcohols phosphate (and) hydrogen Aluminium oxide (PFX-5 TiO2 CR-50, obtained from Daito Kasei Kogyo) | 6.993 | 1 | 1 |
| B | Ferriferous oxide (and) C9-15 fluorinated alcohols phosphates (PFX-5 Sunpuro Huang C33-9001, obtained from Daito Kasei Kogyo) | 0.805 | 0 | 0 |
| B | Ferriferous oxide (and) C9-15 fluorinated alcohols phosphates (PFX-5 The black C33-7001 of Sunpuro, obtained from Daito Kasei Kogyo) | 0.042 | 0 | 0 |
| B | Ferriferous oxide (and) C9-15 fluorinated alcohols phosphates (PFX-5 The red C33-8001 of Sunpuro, obtained from Daito Kasei Kogyo) | 0.16 | 0 | 0 |
| C | Mica (and) titanium dioxide (Flamenco Summit Red R30D, obtained from BASF) | 0 | 0 | 4 |
| C | Titanium dioxide (and) mica (Timiron Silk Blue, obtained from Merck) | 0 | 0 | 0 |
| C | Bismuth oxychloride (RonaFlair ESQ, obtained from Merck) | 0 | 2.7 | 2.7 |
| C | (Luzenac Pharma M, are obtained from talcum Luzenac) | 0.5 | 0.5 | 0.5 |
| C | Silica (Solesphere H-51, obtained from AGC SI-TECH) | 0.5 | 0.5 | 0.5 |
| D | Red 4 (Unicert red 07004-J, are obtained from Sensient Cosmetic Technologies) | 0.005 | 0.005 | 0.005 |
| D | (Unicert yellow 08005-J, are obtained from Huang 5 Sensient Cosmetic Technologies) | 0.0038 | 0.0038 | 0.0038 |
| E | Fragrance | 0.25 | 0.25 | 0.25 |
Preparation method.
It heats phase A to about 75 DEG C and merges various composition wherein；
Phase B is prepared, and is heated approximately to 75 DEG C；
Mixed phase A and B stir mixture until obtaining homogeneous lotion with Rayneri；
Remaining is mutually incorporated to lotion and stirs mixture until its cooling.
Appraisal procedure and result
The composition of embodiment 1, comparative example 1,2 and 3 is administered to the skin of 6 Asia women.Knot after
Fruit is assessed by 2 for expert.
Bright and health illumination effect caused by the present invention is the total of blast to skin, anti-yellowing color and whitening effect
Effect.
Test result is shown in following table.
| Test result | Embodiment 1 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| For the brightening effect of skin | 3 | 3 | 4 | 3 |
| Anti-yellowing skin color | 3 | 2 | 1 | 1 |
| For the whitening effect of skin | 4 | 2 | 4 | 4 |
| The illumination effect of light and health to skin | 4 | 2 | 2 | 3 |
5：Very high effect；
4：High effect；
3：Moderate effect；
2：Poorly efficient fruit；
1：To no effect.
Claims (16)
1. for the cosmetic composition for keratin material of nursing and/or make up, it is included in physiologically acceptable medium
Following components：
(a) at least one scattering filler is less than 35 microns of cluster crystal structural scattering filler for particle size,
(b) at least red or pink mother-of-pearl and
(c) at least one blue mother-of-pearl,
Wherein described at least one red mother-of-pearl or blue mother-of-pearl, which are respectively selected from, to be applied the mica coated with iron oxide, applies coated with chlorine
The mica of bismuth oxide applies the mica coated with chromium oxide, applies coated with SnO2Mica, apply coated with BaSO4Mica, apply coated with oxidation
The mica of titanium or titanium dioxide applies the mica coated with organic dyestuff and the pearlescent pigment based on bismuth oxychloride, folds in its surface
The metal oxide of few two pantostrats and/or the mica particles and its mixture of toner are added to,
Wherein described at least one scattering filler and the weight ratio of at least red mother-of-pearl are 20:1 to 1:20,
The weight ratio of wherein described at least red mother-of-pearl and at least blue mother-of-pearl is 10:1 to 1:10.
2. the cosmetic composition of claim 1, wherein the refractive index of scattering filler is 1.6 to 2.5.
3. composition according to claim 1, wherein at least one scattering filler is selected from boron nitride, barium sulfate, oxychloride
Bismuth, aluminium oxide and composite powder and its mixture based on titanium dioxide and substrate.
4. composition according to claim 3, wherein the substrate be selected from talcum, mica, barium sulfate, boron nitride, bismuth oxychloride,
Aluminium oxide.
5. the cosmetic composition of claim 1, wherein at least one scattering filler is bismuth oxychloride.
6. the cosmetic composition of claim 1, wherein the content of at least one scattering filler in the composition is 0.5%
To 15%, the total amount based on the composition.
7. the cosmetic composition of claim 1, wherein the content of at least red or pink mother-of-pearl in the composition
For 1 to 10%, by weight, the total amount based on the composition.
8. the cosmetic composition of claim 1, wherein the content of at least blue mother-of-pearl in the composition for 0.05 to
1%, by weight, the total amount based on the composition.
9. the cosmetic composition of claim 1, it is characterised in that its form is lotion.
10. the cosmetic composition of claim 1 further includes at least one other colorant.
11. the cosmetic composition of claim 10, wherein at least one other colorant be selected from goniochromatism colorant,
Photo-chromic colorant, fluorescer, optical brightener, color lake, organic pigment, composite pigment and its mixture.
12. the cosmetic composition of claim 10 or 11, wherein the content of at least one colorant in the composition is
0.001 to 5%.
13. the cosmetic composition of claim 1 further includes at least one other filler.
14. the cosmetic composition of claim 1 further comprises at least one UV sun-prevention components.
15. for the method for keratin material of nursing and/or make up, including the combination for defining any one of claim 1-14
Object is administered to keratin material.
16. include at least cluster crystal structural scattering filler of the particle size less than 35 microns in cosmetic composition, it is at least red
The combination of mother-of-pearl and at least blue mother-of-pearl for improving the light of the colour of skin and the purposes of illumination effect, wherein it is described at least
A kind of red mother-of-pearl or blue mother-of-pearl, which are respectively selected from, to be applied the mica coated with iron oxide, applies the mica coated with bismuth oxychloride, applies
Coated with the mica of chromium oxide, apply coated with SnO2Mica, apply coated with BaSO4Mica, apply coated with titanium oxide or the cloud of titanium dioxide
It is female, apply the mica coated with organic dyestuff and the pearlescent pigment based on bismuth oxychloride, be superimposed at least two pantostrats in its surface
The mica particles and its mixture of metal oxide and/or toner,
Wherein described at least one scattering filler and the weight ratio of at least red mother-of-pearl are 20:1 to 1:20,
The weight ratio of wherein described at least red mother-of-pearl and at least blue mother-of-pearl is 10:1 to 1:10.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2012/078824 WO2014012230A1 (en) | 2012-07-18 | 2012-07-18 | Cosmetic composition comprising scattering filler and nacres |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104470489A CN104470489A (en) | 2015-03-25 |
| CN104470489B true CN104470489B (en) | 2018-05-22 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201280074785.6A Active CN104470489B (en) | 2012-07-18 | 2012-07-18 | Cosmetic composition including scattering filler and mother-of-pearl |
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| Country | Link |
|---|---|
| CN (1) | CN104470489B (en) |
| WO (1) | WO2014012230A1 (en) |
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|---|---|---|---|---|
| JP6178089B2 (en) * | 2013-03-27 | 2017-08-09 | ポーラ化成工業株式会社 | Dullness improvement cosmetic |
| FR3042706B1 (en) * | 2015-10-26 | 2017-12-08 | Oreal | COSMETIC COMPOSITION CONFERRING A NATURAL TINT AND A GOOD MINE EFFECT |
| WO2017101106A1 (en) * | 2015-12-18 | 2017-06-22 | L'oreal | Composition with improved radiance effect |
| CN106038465B (en) * | 2016-07-12 | 2019-04-19 | 广州智媛生物科技有限公司 | A kind of composition and preparation method thereof with bright color effect |
| JP6995472B2 (en) * | 2016-10-31 | 2022-01-14 | ロレアル | Composition for natural skin lightening effect |
| JP7242256B2 (en) * | 2018-11-06 | 2023-03-20 | ロレアル | Makeup powder composition containing goniochromatic pigment and white pigment |
| WO2020160236A1 (en) * | 2019-02-01 | 2020-08-06 | Beiersdorf Ag | Sunscreen compositions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1395917A (en) * | 2001-06-25 | 2003-02-12 | 花王株式会社 | Cosmetic composition |
| CN101891969A (en) * | 2009-05-15 | 2010-11-24 | 默克专利股份有限公司 | Pigment composition |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2848822B1 (en) * | 2002-12-24 | 2006-01-13 | Oreal | COSMETIC COMPOSITION OF FOUNDATION TYPE FOR MAKE-UP OF DARK SKIN |
| FR2921261B1 (en) * | 2007-09-20 | 2009-11-20 | Oreal | ANHYDROUS COSMETIC COMPOSITION COMPRISING FIBERS |
-
2012
- 2012-07-18 WO PCT/CN2012/078824 patent/WO2014012230A1/en active Application Filing
- 2012-07-18 CN CN201280074785.6A patent/CN104470489B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1395917A (en) * | 2001-06-25 | 2003-02-12 | 花王株式会社 | Cosmetic composition |
| CN101891969A (en) * | 2009-05-15 | 2010-11-24 | 默克专利股份有限公司 | Pigment composition |
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| Publication number | Publication date |
|---|---|
| WO2014012230A1 (en) | 2014-01-23 |
| CN104470489A (en) | 2015-03-25 |
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