CN110099670A

CN110099670A - Contain oiliness continuous phase, liquid β, the composition of β-diphenylacrylate ester UV smoke agent for shielding, liquid salicylate UV smoke agent for shielding and non-annularity volatile silicone oils

Info

Publication number: CN110099670A
Application number: CN201780079778.8A
Authority: CN
Inventors: E.瓦尔韦德; H.李
Original assignee: LOreal SA
Current assignee: LOreal SA
Priority date: 2016-12-21
Filing date: 2017-11-24
Publication date: 2019-08-06
Also published as: BR112019012642B1; JP7118970B2; KR102409170B1; US20200085723A1; KR102445119B1; FR3060383B1; JP2022105201A; KR20190097197A; EP3558238A1; ES2962129T3; WO2018114212A1; FR3060383A1; KR20210146437A; EP3558238B1; EP3558238C0; JP2020514259A; BR112019012642A2

Abstract

The present invention relates to a kind of compositions, the composition especially includes physiologically acceptable medium, particularly for coating keratin material, more specifically to keratin material such as skin is made up and/or is nursed, a) oiliness continuous phase and b) the organic UV masking agent composition of at least one liquid include: (i) at least one β, β-diphenylacrylate esters type UV smoke agent for shielding, and the UV smoke agent for shielding of (ii) at least one salicylate type；And c) at least one non-annularity volatile silicone oils；And d) at least one pigment.The invention further relates to a kind of methods made up and/or nursed for coating keratin material, more specifically to keratin material such as skin, it is characterised in that this method includes the composition to keratin material application such as previous definition.

Description

Contain oiliness continuous phase, liquid β, β-diphenylacrylate ester UV smoke agent for shielding, liquid water The composition of poplar acid esters UV smoke agent for shielding and non-annularity volatile silicone oils

The field nursed and/or made up the present invention relates to keratin material, especially skin proposes a kind of novelty Composition, the composition include oiliness continuous phase and the organic smoke agent for shielding of particular liquid mixture, the composition is with regard to its light It is most special in terms of protective value and the feeling provided during it applies (and being especially administered on skin) for user It is not advantageous.

Cosmetic make-up compositions (such as foundation cream) are commonly used in giving the color of keratin material such as skin beauty, but also The aesthetic feeling of irregular skin is promoted by hiding scar scar (mark) and skin pigmentation disorder (dyschromias), and is reduced Lie prostrate the visibility of flaw such as pore and wrinkle.Many preparations have been developed so far.Usually using a large amount of pigment to obtain The dressing effect of uniform covering.The present invention relates to it is with oiliness continuous phase, especially be in water-in-oil emulsion form composition, It is particularly advantageous the simplification of their pigment preparations with them to the simplification of keratin material such as dermal administration.

Other than the colour of skin of enhancing skin and correction flaw, also seek to protect keratin material such as skin from wave daily Long range is to influence caused by 280 UV ray to 400nm.Particularly, UV-B ray (wavelength is 280 to 320nm) may draw The damage to epidermis biomechanics characteristic is played, this is reflected as wrinkle occur, so as to cause premature skin ageing.

It is logical in order to remedy these influences, the make-up composition (such as foundation cream) with oiliness continuous phase as caused by UVB ray The organic UV smoke agent for shielding of lipophilicity is often included at least, is at least masked out with being sufficient to obtain the amount of good light Vaccine effectiveness UVB radiation, the light protection effect are reflected as high sun protection factor SPF (such as SPF >=30).

Sun protection factor (SPF) by reach in the case where UV smoke agent for shielding erythema formed threshold value necessary to UV dose of radiation with The ratio for reaching UV amount of radiation necessary to erythema formation threshold value in the case where no UV smoke agent for shielding is indicated with mathematical way.Cause This, this coefficient is related to the protection effect with the biological effect spectrum centered on UVB range, and therefore explains to this UVB spoke The protection penetrated.

In these compositions, the β, β-especially sold by BASF AG (BASF) with trade name Uvinul N539 The organic UV smoke agent for shielding of the liquid of diphenylacrylate esters type (such as compound 2- ethylhexyl 2- cyano -3,3- diphenyl propylene Acid esters or Cyanide Dioctyl Acrylate) with regard to their compatibilities in the oil, they are to the high effect of UVB radiation and they are good Photostability for be particularly advantageous.It is a large amount of in the composition with oiliness continuous phase in order to obtain high protection factor Using these organic smoke agents for shielding, once being applied to skin, just having makes its organoleptic quality (especially non-sticky effect, non-greasy Effect, soft feeling, slim and graceful feeling and slipping) deterioration tendency.

Volatile silicone oils are due to their good cosmetic properties, the feeling especially with pleasant when skin contact And commonly used in the cosmetic composition with oiliness continuous phase.These oil also can be rapid after being applied to keratin material Evaporation.However, the organic UV smoke agent for shielding of β, β-diphenylacrylate esters type liquid is difficult to mix with volatile silicone oils, and can It can lead to the uneven distribution and effect forfeiture of the smoke agent for shielding on the skin.

Patent application WO 20,10/,045 163, US 201,1/0 033 512 and WO 20,07/,148 293, which are disclosed, to be had The example of the composition of oiliness continuous phase, the composition include the UV masking of Cyanide Dioctyl Acrylate, salicylate types Agent, the combination of emulsifying elastomer polysiloxanes and non-emulsified elastomer polysiloxane, emulsifier and polar oil.

Patent application WO 20,13/,078 197 discloses the reality of the sunscreen composition of the synergistic combination comprising five kinds of smoke agents for shielding Example: with the Avobenzone of specified weight ratio, heliophan, octyl salicylate, Cyanide Dioctyl Acrylate and hydroxyl Benzophenone.These are free from the alcohol composition of polysiloxanes or the oil/water lotion with not specified polysiloxanes.

Patent application US 201,3/0 315 846 proposes a kind of composition in very special serum form.Example 3 It is direct lotion, in the presence of the mixture of 1% Y 7175 DC 2-1184, with 5% salicylic acid front three The mixture of cyclohexyl and Cyanide Dioctyl Acrylate.

Patent FR 2 861 593 also proposed based on Cyanide Dioctyl Acrylate, Avobenzone and non-annularity volatility The example of the oil/water lotion of silicone oil (such as five siloxanes of decamethyl tetrasiloxane and ten dimethyl).

Therefore, there is still a need for finding the novel composition made up for keratin material, the composition has Oiliness continuous phase can contain at least one β, β-diphenylacrylate in the presence of at least one volatile silicone oils and pigment Organic UV smoke agent for shielding of esters type, the composition give good smooth protection effect, good makeup quality (as cover) and good Colour of skin uniformity well and also good organoleptic quality are (after such as flexibility, non-sticky effect, non-greasy effect, application not In the presence of making us feeling and good slipping slim and graceful after not pleasant film sense, application), without the technology previously listed Disadvantage.

Applicant is it was unexpectedly found that this purpose can realize that the composition especially includes physiology by a kind of composition Acceptable medium on, particularly for coating keratin material, more specifically to keratin material such as skin Adornment and/or nursing, the composition contain:

A) oiliness continuous phase, and

B) at least one organic UV of liquid covers agent composition, includes:

(i) at least one β, β-diphenylacrylate esters type UV smoke agent for shielding, and

(ii) the UV smoke agent for shielding of at least one salicylate type；

C) at least one non-annularity volatile silicone oils；And

D) at least one pigment.

This discovery constitutes basis of the invention.

One of according to aspects of the present invention, the present invention relates to a kind of composition, the composition especially includes physiologically may be used The medium of receiving, particularly for coating keratin material, more specifically to keratin material such as skin carry out makeup and/or Nursing,

A) oiliness continuous phase, and

B) at least one organic UV of liquid covers agent composition, includes:

(ii) the UV smoke agent for shielding of at least one salicylate type；And

C) at least one non-annularity volatile silicone oils；And

D) at least one pigment.

The invention further relates to one kind to carry out for coating keratin material, more specifically to keratin material such as skin The method of makeup and/or nursing, it is characterised in that this method includes the composition to keratin material application such as previous definition.

Definition

In the context of the present invention, term " keratin material " especially means (body, face, eye circumference or eyelid) Skin.

Term " physiologically acceptable " refers to, face with pleasant compatible with skin and/or its covering Color, smell and feeling and it will not cause to be easy to prevent consumer to use any unacceptable discomfort of this composition (shouting pain or tight).

Term " composition containing oiliness continuous phase " means

I) anhydrous composition comprising single oily phase, such as oil, oil-base gel or anhydrous emulsifiable paste,

Ii) or water-in-oil emulsion, it is also known as reversed-phase emulsion.

For purposes of the present invention, term " anhydrous " refers to small by weight comprising the total weight relative to the composition In or equal to 2%, be preferably less than or equal to the composition of 1% and the water of more preferably less than 0.5% content by weight, or It is even not aqueous.In appropriate circumstances, this small amount of water especially can be by that may contain the composition components of its surplus It introduces.

For purposes of the present invention, be also known as reversed-phase emulsion term " water-in-oil emulsion " be intended to indicate that it is continuous by oiliness Any composition of phase composition, in the continuous oily phase, water phase is dispersed in droplets, so that observing with the naked eye macroscopic view Upper uniform mixture.

Term " the organic UV smoke agent for shielding of liquid " means that can filter out the UV that range is 280 to 400nm radiates and in room It is any organic compound of liquid under warm (20 DEG C -25 DEG C) and atmospheric pressure.

The organic UV of β, β-diphenylacrylate ester/salicylate liquid covers agent composition

Composition according to the present invention includes that the organic UV of liquid covers agent composition, which includes:

(ii) the UV smoke agent for shielding of at least one salicylate type.

The mixture of preferred form according to the present invention, the opacifier will be pressed with the total weight relative to the composition The concentration of poidometer at least 15% and more preferably it is present in composition of the invention with by weight at least 20% concentration In.

Preferably, relative to the total weight of the composition, the β, β-diphenylacrylate ester/salicylate opacifier The concentration that mixture is by weight 15% to 40% with range and more preferably range is by weight 20% to 30% makes With.

A) β, β-diphenylacrylate ester compounds

In β, β-diphenylacrylate esters type UV smoke agent for shielding, it can be mentioned that having those of lower formula (I):

Wherein R₁To R₃It can have following meanings:

-R₁With R '_l, can be same or different, indicate hydrogen atom, linear chain or branched chain C₁-C₈Alkoxy or straight chain or Branch C₁-C₄Alkyl；

-R₁With R '₁In contraposition or meta position；

-R₂Indicate linear chain or branched chain C₁-C₁₂Alkyl；

-R₃Indicate hydrogen atom or CN group.

In linear chain or branched chain C₁-C₈In alkoxy, such as it can be mentioned that methoxyl group, ethyoxyl, positive propoxy, isopropoxy, It is n-butoxy, isobutoxy, tert-butoxy, n-pentyloxy, isoamoxy, neopentyl oxygen, positive hexyloxy, positive oxygroup in heptan, just pungent Oxygroup and 2- ethyl hexyl oxy.

In linear chain or branched chain C₁-C₄In alkyl, methyl, ethyl, n-propyl, isopropyl, positive fourth can be more particularly referred to Base, isobutyl group and tert-butyl.For C₁-C₁₂Alkyl, other than those of mentioned above, for example, can also refer to just Amyl, isopentyl, neopentyl, n-hexyl, n-heptyl, n-octyl, 2- ethylhexyl, decyl and lauryl.

In the compound with logical formula (I), it can be mentioned that following compound:

Alpha-cyano-β, β-diphenylacrylate 2- ethylhexyl or octocrylene, especially by BASF Company is with trade name Uvinul N539 sale；

Alpha-cyano-β, β-diphenyl-ethyl acrylate or etocrilene (Etocrylene), especially by BASF AG With trade name UvinulSale,

β, β-diphenylacrylate 2- ethylhexyl,

Bis- (4 '-methoxyphenyl) ethyl acrylates of β, β-.

In β, β-diphenylacrylate esters type UV smoke agent for shielding, compound 2- cyano -3,3- will be more particularly used Diphenylacrylate 2- ethylhexyl or Cyanide Dioctyl Acrylate, especially by BASF AG with trade name Uvinul N539 sale.

Relative to the total weight of composition, one or more β, β-diphenylacrylate ester compounds preferably with range be by The concentration of poidometer 5% to 10% and more preferable 6% to 8% is present in the composition.

B) salicylate compounds

In the salicylate compounds that can be used according to the present invention, it will use:

Heliophan is sold by Rona/EM Industries company with title Eusolex HMS,

Ethylhexyl salicylate is sold by the fragrant company (Symrise) of moral with title Neo Heliopan OS,

And its mixture.

Relative to the total weight of composition, one or more salicylate compounds are preferably with range for by weight 5% Concentration to 20% and more preferable 10% to 15% is present in the composition.

Oiliness continuous phase

Composition of the invention includes oiliness continuous phase.The phase is that liquid (is being not present under room temperature (20 DEG C -25 DEG C) In the case where structuring agents).It is organic and unmixing with water.

It includes at least one non-annularity volatile silicone oils and β, β-diphenylacrylate ester/organic UV of salicylate liquid Cover agent composition.

It can also contain one or more additional oil that can be selected from following item:

Cyclic materials silicone oil；

Nonvolatile oil is selected from oil, silicone oil and fluorocarbon oil and its mixture based on hydrocarbon,

Volatile base is in the oil of hydrocarbon；

The solvable or miscible ingredient in oily phase；

Its mixture.

Term " oil " means in room temperature (25 DEG C) and atmospheric pressure (760mmHg, i.e., 10⁵It Pa is the fatty material of liquid under). Oil can be volatility or non-volatile.

For purposes of the present invention, term " silicone oil " means comprising at least one silicon atom and an especially at least Si-O base The oil of group, and more particularly organopolysiloxane.

Term " fluorocarbon oil " refers to the oil comprising at least one fluorine atom.

Term " oil based on hydrocarbon " mean to mainly contain carbon and hydrogen atom and it is possible it is one or more selected from hydroxyl, ester, The oil of the functional group of ether and carboxylic acid functional.

Term " non-annularity oil " indicates the linear chain or branched chain oil for not including any ring.In other words, it is according to the present invention oil not Containing (miscellaneous) aryl and/or (miscellaneous) naphthenic base.

For purposes of the present invention, term " ethereal oil " refer at room temperature and atmospheric pressure can with skin contact Less than one hour in any oil for volatilizing.Ethereal oil is volatility cosmetic compounds, is liquid at room temperature, especially In at room temperature and atmospheric pressure with the vapour pressure of non-zero, especially there is range 0.13Pa to 40000Pa (10^-3To 300mmHg), spy Other ground range 1.3Pa to 13000Pa (0.01 to 100mmHg) and more particularly range 1.3Pa to 1300Pa (0.01 to Vapour pressure 10mmHg).

Term " nonvolatile oil " means to retain on skin or keratin fiber at room temperature and atmospheric pressure at least several Hour and especially have less than 10^-3The oil of the vapour pressure of mmHg (0.13Pa).

The total concentration of oily phase in composition of the invention preferably the total weight relative to the composition by weight In the range of 30% to 95% and more particularly in the range of by weight 40% to 70%.

A)Non-annularity volatile silicone oils

According to the present invention, non-annularity volatile silicone oils according to the present invention are preferably selected from:

The acyclic straight polysiloxanes of formula (II):

R₃SiO-(R₂SiO)_n-SiR₃ (II)

Wherein R can be identical or different, indicate:

The saturated or unsaturated group based on hydrocarbon, contain 1 to 10 carbon atom and preferably 1 to 6 carbon atom, Optionally replace by one or more fluorine atoms or by one or more hydroxyls, or

Hydroxyl,

One of group R may be phenyl,

N is the integer that range is 0 to 8, preferred scope is 2 to 6 and also better range is 3 to 5, the poly- silicon of formula (II) Siloxane compound contains no more than 15 carbon atoms,

The polysiloxanes of branch with lower formula (III) or (IV):

R₃SiO-[(R₃SiO)RSiO]-(R₂SiO)x-SiR₃ (III)

[R₃SiO]₄Si (IV)

Wherein R can be identical or different, indicate:

The saturated or unsaturated group based on hydrocarbon contains 1 to 10 carbon atom, optionally by one or more fluorine Atom is replaced by one or more hydroxyls, or

Hydroxyl,

One of group R may be phenyl,

X is the integer that range is 0 to 8,

The polysiloxane compound of formula (III) or (IV) contain no more than 15 carbon atoms.

Ratio preferably for formula (II), the compound of (III) and (IV), between carbon atom number and silicon atom number Rate is 2.25 to 4.33.

The polysiloxanes of formula (II) to (IV) can be prepared according to the known method for synthesizing polysiloxane compound.

The example for the non-annularity Y 7175 that can be used according to the present invention is as follows；These polysiloxanes can To be used alone or as mixture.

In the polysiloxanes of formula (II), it is mentioned that:

A) following disiloxane (L2):

Hexamethyldisiloxane, especially by Dow Corning Corporation (Dow Coming) with title DC 200Fluid 0.65cst Sale

1,3- di-t-butyl-, 1,1,3,3- tetramethyl disiloxane；

1,3- dipropyl -1,1,3,3- tetramethyl disiloxanes；

Heptyl pentamethyl disiloxane；

1,1,1- triethyl group -3,3,3- trimethyldisiloxane；

Hexaethyldisiloxane；

Bis- (2- methyl-propyl) disiloxane of 1,1,3,3- tetramethyl -1,3-；

Pentamethyl octyl disiloxane；

1,1,1- trimethyl -3,3,3- tri- (1- Methylethyl) disiloxane；

1- butyl -3- ethyl -1,1,3- trimethyl -3- disiloxane；

Pentamethyl amyl disiloxane；

1- butyl -1,1,3,3- tetramethyl -3- (1- Methylethyl) disiloxane；

Bis- (1- methyl-propyl) disiloxane of 1,1,3,3- tetramethyl -1,3-；

1,1,3- triethyl group -1,3,3- tripropyl disiloxane；

(3,3- dimethylbutyl) pentamethyl disiloxane；

(3- methyl butyl) pentamethyl disiloxane；

(3- methyl amyl) pentamethyl disiloxane；

1,1,1- triethyl group -3,3- dimethyl -3- disiloxane；

1- (1,1- dimethyl ethyl) -1,1,3,3,3- pentamethyl disiloxane；

1,1,1- trimethyl -3,3,3- tripropyl disiloxane；

1,3- dimethyl -1,1,3,3- tetra- (1- Methylethyl) disiloxane；

1,1- dibutyl -1,3,3,3- tetramethyl disiloxanes；

Bis- (1- Methylethyl) disiloxane of 1,1,3,3- tetramethyl -1,3-；

Bis- (1- Methylethyl) disiloxane of 1,1,1,3- tetramethyl -3,3-；

1,1,1,3- tetramethyl -3,3- dipropyl disiloxane；

Bis- (3- methyl butyl) disiloxane of 1,1,3,3- tetramethyl -1,3-；

Butyl pentamethyl disiloxane；

Five ethyl-methyl disiloxane；

1,1,3,3- tetramethyl -1,3- diamyl disiloxane；

1,3- dimethyl -1,1,3,3- tetrapropyl disiloxane；

1,1,1,3- tetraethyl -3,3- dimethyldisiloxane；

1,1,1- triethyl group -3,3,3- tripropyl disiloxane；

1,3- dibutyl -1,1,3,3- tetramethyl disiloxanes；

Hexyl pentamethyl disiloxane；

B) following trisiloxanes (L3):

Octamethyltrisiloxane, especially by Dow Corning Corporation with title Xiameter PMX-200Silicone Fluid 1CS sale；

3- amyl -1,1,1,3,5,5,5- heptamethyltrisiloxane；

1- hexyl -1,1,3,3,5,5,5- heptamethyltrisiloxanes；

1,1,1,3,3,5,5- seven methyl -5- octyl trisiloxanes；

1,1,1,3,5,5,5- seven methyl -3- octyl trisiloxanes, is especially sold by OSI company with title Silsoft 034 It sells；

1,1,1,3,5,5,5- seven methyl -3- hexyl trisiloxanes, especially by Dow Corning Corporation with title DC 2-1731 pin It sells；

1,1,3,3,5,5- vegolysen, 5- dipropyl trisiloxanes；

3- (1- ethyl-butyl) -1,1,1,3,5,5,5- heptamethyltrisiloxane；

1,1,1,3,5,5,5- seven methyl -3- (1- methyl amyl) trisiloxanes；

1,5- diethyl -1,1,3,3,5,5- hexam ethylcyclotrisiloxanes；

1,1,1,3,5,5,5- seven methyl -3- (1- methyl-propyl) trisiloxanes；

3- (1,1- dimethyl ethyl) -1,1,1,3,5,5,5- heptamethyltrisiloxane；

Bis- (1- Methylethyl) trisiloxanes of 1,1,1,5,5,5- hexamethyl -3,3-；

1,1,1,3,3,5,5- seven methyl-1, bis- (1- methyl-propyl) trisiloxanes of 5-；

1,5- bis- (1,1- dimethyl ethyls) -1,1,3,3,5,5- hexam ethylcyclotrisiloxane；

3- (3,3- dimethylbutyl) -1,1,1,3,5,5,5- heptamethyltrisiloxane；

1,1,1,3,5,5,5- seven methyl -3- (3- methyl butyl) trisiloxanes；

1,1,1,3,5,5,5- seven methyl -3- (3- methyl amyl) trisiloxanes；

1,1,1,3,5,5,5- seven methyl -3- (2- methyl-propyl) trisiloxanes；

1- butyl -1,1,3,3,5,5,5- heptamethyltrisiloxanes；

1,1,1,3,5,5,5- seven methyl -3- propyl trisiloxanes；

3- isohesyl -1,1,1,3,5,5,5- heptamethyltrisiloxane；

1,3,5- triethyl group -1,1,3,5,5- pentamethyl trisiloxanes；

3- butyl -1,1,1,3,5,5,5- heptamethyltrisiloxane；

3- tertiary pentyl -1,1,1,3,5,5,5- heptamethyltrisiloxane；

1,1,1,5,5,5- hexamethyl -3,3- dipropyl trisiloxanes；

3,3- diethyl -1,1,1,5,5,5- hexam ethylcyclotrisiloxane；

1,5- dibutyl -1,1,3,3,5,5- hexam ethylcyclotrisiloxanes；

1,1,1,5,5,5- Hexaethyl -3,3- dimethyl trisiloxanes；

3,3- dibutyl -1,1,1,5,5,5- hexam ethylcyclotrisiloxane；

3- ethyl -1,1,1,3,5,5,5- heptamethyltrisiloxane；

3- heptyl -1,1,1,3,5,5,5- heptamethyltrisiloxane；

1- ethyl -1,1,3,3,5,5,5- heptamethyltrisiloxanes；

C) following tetrasiloxane (L4):

Decamethyl tetrasiloxane；

1,1,3,3,5,5,7,7- prestox -1,7- dipropyl tetrasiloxane；

1,1,1,3,3,5,7,7,7- nine methyl -5- (1- Methylethyl) tetrasiloxane；

1- butyl -1,1,3,3,5,5,7,7,7- nine methyl tetrasiloxanes；

3,5- diethyl -1,1,1,3,5,7,7,7- octamethylcyclotetrasiloxane；

1,3,5,7- tetraethyl -1,1,3,5,7,7- hexamethyl tetrasiloxanes；

3,3,5,5- tetraethyls -1,1,1,7,7,7- hexamethyl tetrasiloxane；

1,1,1,3,3,5,5,7,7- nine methyl -7- phenyl tetrasiloxane；

3,3- diethyl -1,1,1,5,5,7,7,7- octamethylcyclotetrasiloxane；

1,1,1,3,3,5,7,7,7- nine methyl -5- phenyl tetrasiloxane；

D) five silicon hydrogen alkane (L5) below:

Ten dimethyl, five siloxanes；

1,1,3,3,5,5,7,7,9,9- decamethyl -1,9- dipropyl, five siloxanes；

3,3,5,5,7,7- Hexaethyls -1,1,1,9,9,9- hexamethyl, five siloxanes；

1,1,1,3,3,5,7,7,9,9,9- ten monomethyl -5- phenyl, five siloxanes；

1- butyl -1,1,3,3,5,5,7,7,9,9,9- ten monomethyl, five siloxanes；

3,3- diethyl -1,1,1,5,5,7,7,9,9,9- decamethyl, five siloxanes；

1,3,5,7,9- penta ethyl -1,1,3,5,7,9,9- seven methyl, five siloxanes；

3,5,7- triethyl groups -1,1,1,3,5,7,9,9,9- nine methyl, five siloxanes；

1,1,1- triethyl group -3,3,5,5,7,7,9,9,9- nine methyl, five siloxanes；

E) six siloxanes (L6) below:

1- butyl -1, l, 3,3,5,5,7,7,9,9,11,11,11- ten trimethyl, six siloxanes；

3,5,7,9- tetraethyls -1,1,1,3,5,7,9,11,11,11- decamethyl, six siloxanes；

Tetradecamethylhexasiloxane；

F) ten hexamethyls, seven siloxanes (L7)；

G) ten prestoxs, eight siloxanes (L8).

In the polysiloxanes of formula (III), it can be mentioned that:

A) following tetrasiloxane (L4):

2- [bis- [(trimethyl silyl) oxygroup] disilicon malignant alkyls of 3,3,3- trimethyls -1,1-] ethyl；

1,1,1,5,5,5- hexamethyl -3- (2- methyl-propyl) -3- [(trimethyl silyl) oxygroup] trisiloxanes；

3- (1,1- dimethyl ethyl) -1,1,1,5,5,5- hexamethyl -3- [(trimethyl silyl) oxygroup] three silicon oxygen Alkane；

3- butyl -1,1,1,5,5,5- hexamethyl -3- [(trimethyl silyl) oxygroup] trisiloxanes；

1,1,1,5,5,5- hexamethyl -3- propyl -3- [(trimethyl silyl) oxygroup] trisiloxanes；

3- ethyl -1,1,1,5,5,5- hexamethyl -3- [(trimethyl silyl) oxygroup] trisiloxanes；

1,1,1- triethyl group -3,5,5,5- tetramethyl -3- (trimethylsiloxy) trisiloxanes；

3- methyl-1,1,1,5,5,5- hexamethyl -3- [(trimethyl silyl) oxygroup] trisiloxanes；

3- [(dimethylphenylsilyl) oxygroup] -1,1,1,3,5,5,5- heptamethyltrisiloxane；

1,1,1,5,5,5- hexamethyl -3- (2- methyl amyl) -3- [(trimethyl silyl) oxygroup] trisiloxanes；

1,1,1,5,5,5- hexamethyl -3- (4- methyl amyl) -3- [(trimethyl silyl) oxygroup] trisiloxanes；

3- hexyl -1,1,1,5,5,5- hexamethyl -3- [(trimethyl silyl) oxygroup] trisiloxanes；

1,1,1,3,5,5,5- seven methyl -3- [(trimethyl silyl) oxygroup] trisiloxanes；

B) five siloxanes (L5) below:

1,1,1,3,5,5,7,7,7- nine methyl -3- (trimethylsiloxy) tetrasiloxane；

1,1,1,3,3,7,7,7- prestox -5- phenyl -5- [(trimethyl silyl) oxygroup] tetrasiloxane；

C) seven siloxanes (L7) below:

1,1,1,3,5,5,7,7,9,9,11,11,11- ten trimethyl -3- [(trimethyl silyl) oxygroup] six silicon oxygen Alkane

In the polysiloxanes of formula (IV), it can be mentioned that:

Bis- (trimethylsiloxy) trisiloxanes of 1,1,1,5,5,5- hexamethyl -3,3-.

Other volatile silicone oils selected from following item can also be used:

A) following tetrasiloxane (L4):

2,2,8,8- tetramethyl -5- [(pentamethyl disilicon malignant alkyl) methyl] -3,7- dioxa -2,8-, bis- sila nonane；

2,2,5,8,8- pentamethyl -5- [(trimethyl silyl) methoxyl group] -4,6- dioxa -2,5, tri- sila nonyl of 8- Alkane；

Bis- [(trimethyl silyl) methyl] -1, the 3- disiloxane glycol of 1,3- dimethyl -1,3-；

3- ethyl -1,1,1,5,5,5- hexamethyl -3- [3- (trimethylsiloxy) propyl] trisiloxanes；

1,1,1,5,5,5- hexamethyl -3- phenyl -3- [(trimethyl silyl) oxygroup] trisiloxanes (Dow 556Fluid)；

B) five siloxanes (L5) below:

2,2,7,7,9,9,11,11,16,16- decamethyls -3,8,10,15- tetra- oxa-s -2,7,9,11,16- five silas ten Seven alkane；

Four [(trimethyl silyl) methyl] esters of silicon acis；

C) six siloxanes (L6) below:

3,5- diethyl -1,1, bis- [(trimethyl silyl) oxygroup] tetrasiloxanes of 1,7,7,7- hexamethyl -3,5-,

Bis- [(trimethyl silyl) oxygroup] tetrasiloxanes of 1,1,1,3,5,7,7,7- prestox -3,5-；

D) seven siloxanes (L7):

1,1,1,3,7,7,7- seven methyl -3,5,5- tri- [(trimethyl silyl) oxygroup] tetrasiloxane；

E) eight siloxanes (L8) below:

1,1,1,3,5,5,9,9,9- nine methyl -3,7,7- tri- [(trimethyl silyl) oxygroup] five siloxanes；

1,1,1,3,5,7,9,9,9- nine methyl -3,5,7- tri- [(trimethyl silyl) oxygroup] five siloxanes；

1,1,1,7,7,7- hexamethyl -3,3,5,5- tetra- [(trimethyl silyl) oxygroup] tetrasiloxanes.

Non-annularity volatile silicone oils according to the present invention preferably at 25 DEG C have range be 0.5 to 8 centistoke (0.5 to 8mm²/ s) viscosity.Viscosity Measurement Methods in the present invention for characterizing silicone oil according to the present invention can be " crude at 25 DEG C The kinematic viscosity of product, CID-012-01 " or " remaining Bai Luode (Ubbelohde) viscosity at 25 DEG C, DIN 51562-1 PV04001”。

In non-annularity volatile silicone oils according to the present invention, will more particularly select straight chain acyclic volatile silicone oils, And more particularly:

Octamethyltrisiloxane, especially by Dow Corning Corporation with title Xiameter PMX-200Silicone Fluid LCS sale；

Decamethyl tetrasiloxane, especially by Dow Corning Corporation with title Xiameter PMX-200Silicone FluidSale；

Five siloxanes of-ten dimethyl, such as by company, SHIN-ETSU HANTOTAI (Shin Etsu) with title KF-96L-DM- Fluid-The commodity of sale；The Berb- of BRB international corporationOr the Silicone Fluid of Dow Corning Corporation

Its mixture, and five siloxanes of more particularly ten dimethyl.

Preferred form according to the present invention, non-annularity volatile silicone oils/β, β-diphenylacrylate ester/salicylate hide The weight ratio of agent composition is covered above or equal to 0.5, more preferably equal to or greater than 0.7.

Non-annularity volatile silicone oils/β, the weight ratio of β-diphenylacrylate ester/salicylate masking agent composition can be with Especially 0.5 to 3 and it is more preferable 0.7 to 1.5 in the range of.

B) additional oil

Additional oil can be selected from any kind of oil, be preferably physiologically acceptable oil, especially mineral oil, Animal oil, vegetable oil or synthetic oil；Especially volatility or non-volatile oil and/or silicone oil and/or fluorinated oil based on hydrocarbon, and Its mixture.

i)Volatile base is in the oil of hydrocarbon

As the example that can be used for the ethereal oil of the invention based on hydrocarbon, it is mentioned that:

Oil based on hydrocarbon contains 8 to 16 carbon atoms, and the C of especially petroleum resources₈-C₁₆Isoalkane is (also referred to as For isoparaffin), such as Permethyl 99A (also referred to as 2,2,4,4,6- five methylheptanes), isodecane and isohexadecane, such as with The oil of trade name Isopar or Permethyl sale, branch C₈-C₁₆Ester and isohexyl neopentanoate ester and its mixture.It can also make With other volatile bases in the oil of hydrocarbon, such as petroleum distillate, especially by Shell Co. Ltd (Shell) with title Shell Solt Those of sale；Volatile linear alkane is such as described in the patent application DE10 2,008 012 from Kening Co., Ltd (Cognis) Those of in 457.

ii)The non-volatile oil based on hydrocarbon

As the example that can be used for the nonvolatile oil of the invention based on hydrocarbon, it is mentioned that:

The oil based on hydrocarbon of animal origin, such as perhydro-squalene；

The linear chain or branched chain hydrocarbon of mineral or synthesis source, such as liquid paraffin and its derivant, vaseline, poly decene, poly- fourth Alkene, Parleam such as Parleam or saualane；

Phytosterin ester (phytostearyl ester), as phytosterols oletate, phytosterol isostearate and Lauroyl/octyl dodecanol base/phytosterol glutamate (aginomoto company (Ajinomoto), Eldew)；

It is C that the triglycerides being made of the aliphatic ester of glycerol, especially its fatty acid, which can have range,₄To C₃₆And it is outstanding It is C₁₈To C₃₆Chain length, these oil may be linear chain or branched chain and saturated or unsaturated；These oil especially can be with Be enanthic acid or Trivent OCG, wheat-germ oil, sunflower oil, grape seed oil, sesame seed oil (820.6g/mol), corn oil, Apricot oil, castor oil, shea butter, avocado oil, olive oil, soybean oil, Sweet Almond Oil, palm oil, rapeseed oil, cottonseed oil, fibert Oil, macadimia nut oil, SIMMONDSIA CHINENSIS SEED OIL, clover oil, poppy seed oil, squash oil, cucurbita pepo oil, currant oil, evening primrose oil, millet Oily, big wheat oil, quinoa oil, rye-seed oil, safflower oil, tung oil, passionflower oil or musk rose oil；Shea butter；Or it can replace Dai Di, caprylic/capric triglyceride, such as by French Di Bo Sterling LLC (St é arineries Dubois) sale that A bit or by Dynamit Nobel AG (Dynamit Nobel) with title MiglyolWithSale Those；

Synthesis ether containing 10 to 40 carbon atoms, such as dicaprylyl ether；

The ester based on hydrocarbon of formula RCOOR ', wherein RCOO indicates the carboxylic acid residues comprising 2 to 40 carbon atoms, and R ' The chain based on hydrocarbon containing 1 to 40 carbon atom is indicated, such as cetearyl octanoate, isopropyl alcohol ester such as myristic acid isopropyl Ester or isopropyl myristate, palm acid ethyl ester, palmitinic acid 2- ethylhexyl, stearic acid isopropyl esters or isostearic acid are different The different hard ester alcohol ester of propyl diester, isostearic acid, octyldodecyl ester, adipic acid diisopropyl ester, heptanoate (and especially enanthic acid Iso stearyl ester), caprylate, decylate or the monoricinolein such as propylene, cetearyl base of alcohol or polyalcohol Ester, sad tridecane base ester, bis- heptanoate of 2- ethylhexyl 4- and 2- ethyl hexyl palmitat, benzoic acid alkyl base ester, poly- second Two heptanoate of glycol, propylene glycol 2- ethylhexanoate and its mixture, benzoic acid C12 to C15 alcohol ester, lauric acid hexyl ester, Pivalate such as isodecyl base ester, neopentanoic acid isotridecyl ester, neopentanoic acid iso stearyl ester and neopentanoic acid 2- octyl Dodecyl ester, isononoate such as isononanoic acid isononyl ester, isononanoic acid isotridecyl ester and isononanoic acid octyl ester, erucic acid oil Alcohol ester, sarcosine isopropyl lauroyl base ester, diisopropyl sebacate, the different spermaceti base ester of stearic acid, isodecyl base ester, Behenic acid iso stearyl ester and myristic acid nutmeg base ester；

The polyester obtained by the condensation of unsaturated fat acid dimer and/or tripolymer and glycol, such as in patent application Described in FR 0 853 634 those, especially such as dilinoleic acid and 1,4-butanediol.In this regard can it is specifically mentioned by Synbiotics AB (Biosynthis) is with title Viscoplast(INCI title: dilinoleic acid/butanediol is total Polymers) sale polymer or polyalcohol and diacid dimer and its ester copolymer, such as Hailuscent

Polyol ester and pentaerythritol ester, such as dipentaerythritol tetrahydroxy-stearic acid ester/pentaerythritol tetraisostearate,

Fatty alcohol containing 12 to 26 carbon atoms, such as octyldodecanol, 2- butyl octanol, 2- hexyl decyl alcohol, 2- Undecylpentadecanol and oleyl alcohol；

Dialkyl carbonate, two alkyl chains are possible to identical or different, such as by Kening Co., Ltd with title CetiolThe carbonic acid dioctyl ester of sale, and

Vinylpyrrolidone copolymer, the vinyl pyrrolidone such as sold or manufactured by ISP company/1- hexadecylene Copolymer A ntaron V-

The range for the total carbon number having is 35 to 70 straight-chain fatty acid ester, such as four pelargonate of pentaerythrite,

Hydroxylating ester, such as three isostearate of polyglyceryl -2-；

Aromatic ester, such as trimellitic acid tridecane base ester, benzoic acid C₁₂-C₁₅Alcohol ester, benzoic acid 2- phenylethylester and water Poplar acid butyl octyl ester,

The C of branched fatty alcohol or fatty acid₂₄-C₂₈Ester, as described in the patent application EP-A-0 955 039 those Ester, and especially three Isoeicosane base ester of citric acid, four isononoate of pentaerythrite, three glyceryl isostearates, three (the 2- last of the ten Heavenly stems Base) myristate, glyceryl, four (2- of pentaerythritol tetraoctyl stearate, -2 pentaerythritol tetraisostearate of polyglyceryl or pentaerythrite Decyl) myristate,

The ester and polyester of-two poly-dihydric alcohols and monocarboxylic acid or dicarboxylic acids, such as ester of two poly-dihydric alcohols and fatty acid with And two poly-dihydric alcohol and dimerization dicarboxylic acids ester, such as by Nippon Seika K.K. (Nippon Fine Chemical) sell And the Lusplan DD- described in patent application US 2004-175 338With Lusplan DD-It will The content of the patent application is incorporated by reference into the application,

And its mixture.

According to specific embodiment, the non-volatile oil based on hydrocarbon is by being liquid under room temperature (25 DEG C) and atmospheric pressure The organic UV smoke agent for shielding of lipophilicity, particularly by β as previously described, β-diphenylacrylate ester/salicylate smoke agent for shielding mixing What object was constituted.

Liquid lipophilic cinnamate compound can also be used, such as:

Ethylhexyl methoxy cinnamate, especially by Royal DSM nutriment Co., Ltd (DSM Nutritional Products it) is sold with trade name Parsol MCX,

Methoxycinnamate isopropyl propionate,

Methoxycinnamate isoamyl valerate is sold by the fragrant company of moral with trade name Neo Heliopan E 1000.

iii)Non-volatile fluorocarbon oil and/or silicone oil

Among non-volatile fluorocarbon oil and/or silicone oil, it is mentioned that:

Optionally be based partially on hydrocarbon and/or polysiloxanes fluorocarbon oil, such as the fluorine described in file EP-A-847 752 Silicone oil, perfluoroalkyl polyether and fluorine polysiloxanes,

Silicone oil, such as non-volatile dimethicones (PDMS)；Phenyl polysiloxane, such as the poly- trimethyl silicane oxygen of phenyl Alkane, phenyl dimethicones, phenyl (trimethylsiloxy) diphenyl siloxane, diphenyl dimethicone With diphenyl (methyldiphenyl base) trisiloxanes.

iv)Volatile cyclic silicone oil

As volatile cyclic silicone oil, it can be mentioned that octamethylcy-clotetrasiloxane, decamethylcyclopentaandoxane and ten diformazans Six siloxanes of basic ring and its mixture.

Pigment

Composition according to the present invention includes at least one pigment.

Term " pigment " means that white or colored mineral or organic granular, these particles do not dissolve in aqueous medium, and It is intended to make resulting composition and/or deposit to colour and/or opaque.These pigment can be white or colored, and be Mineral and/or organically.

Preferably, composition include relative to the composition total weight by weight at least 5% pigment, more preferably By weight 5% to 40% pigment, particularly by weight 10% to 30% and preferably by weight 10% to 20% Pigment.

According to specific embodiment, pigment used according to the invention is selected from coloring earth.

Term " coloring earth " refers to meeting the pass in Liv Ullmann encyclopaedical (Ullmann ' s encyclopaedia) Any pigment of definition in the chapters and sections of inorganic pigment.Among coloring earth for use in the present invention, it can be mentioned that oxidation Zirconium or ceria and there are also zinc oxide, the oxide (black, yellow or red) of iron or chromium oxide, manganese violet, ultramarine blue, Chromium hydroxide and barba hispanica, titanium dioxide and metal powder (such as aluminium powder or copper powders).Following mine can also be used Object pigment: Ta₂O₅、Ti₃O₅、Ti₂O₃, TiO, be in and TiO₂Form of mixtures ZrO₂、ZrO₂、Nb₂O₅、CeO₂、ZnS。

The size of useful pigment is generally greater than 100nm and can be in up to 10 μ in the context of the present invention M, in the range of preferably 200nm to 5 μm and more preferably 300nm to 1 μm.

Concrete form according to the present invention, pigment have certain size, it is characterised in that D [50] is greater than 100nm and can Can at up to 10 μm, preferably 200nm to 5 μm and more preferably 300nm to 1 μm in the range of.

The size uses 3000 Particle Size Analyzer of business MasterSizer from Malvern company (Malvern) to pass through Static light scattering measures, this allows to determine in wide scope (can extend to 1000 μm with 0.01 μm) grain of all particles Degree distribution.Data are handled based on standard Mie theory.The theory is best suited for sub-micron at most micron (multimicron) Size distribution in range；It allows to determine " effective " partial size.This theory is especially described in following publication: Van de Hulst, H.C., Light Scattering by Small Particles [being scattered by short grained light], the 9th chapter and 10 chapters, Wiley [Willie publishing house], New York, 1957.

D [50] represents full-size possessed by the particle of 50 volume %.

In the context of the present invention, coloring earth more particularly iron oxide and/or titanium dioxide.It can be more particularly The example referred to includes the titanium dioxide and iron oxide coated with aluminium stearoyl-glutamic acid salt, such as by Miyoshi Kasei Inc (Miyoshi Kasei) is sold with call number NAI.

As the coloring earth that can be used in the present invention, mother-of-pearl can also be referred to.

Term " mother-of-pearl " be construed as meaning any type of colored particles (can be iridescent colors or be not rainbow It is colored), especially certain mollusk generated in its shell or alternative solution be synthesis, and it passes through optics Interference has coloring effect.

Mother-of-pearl can selected from pearlescent pigment such as use iron oxide-coated mica titanium, with bismuth oxychloride coat mica titanium, With the mica titanium of oxidation chromium coating, the mica titanium coated with organic dyestuff and there are also the pearlescent pigment based on bismuth oxychloride.It Can also be mica particles, be superimposed the metal oxide and/or organic dyestuff of at least two sequential layers in particle surface.

The example for the mother-of-pearl that also can be mentioned that includes the day for being covered with titanium oxide, iron oxide, natural pigment or bismuth oxychloride Right mica.

On the market it is mentioned that Engelhard Corp (Engelhard) sold in available mother-of-pearl Timica, Flamenco and Duochrome (are based on mica), the Timiron mother-of-pearl of Merck & Co., Inc. (Merck) sale, love card The Prestige mother-of-pearl based on mica of company (Eckart) sale and sun Chemical Corporation's sale based on synthetic mica Sunshine mother-of-pearl.

The mother-of-pearl can more particularly have yellow, pink colour, red, bronze colour, orange, brown, gold and/or coppery Or flash of light.

It, can be specifically mentioned especially by En Geer as the illustration for the mother-of-pearl that can be used in the context of the present invention Ha De company is with title Brilliant gold 212G (Timica), Gold 222C (Cloisonne), Sparkle gold (Timica), the gold pearl of Gold 4504 (Chromalite) and Monarch gold 233X (Cloisonne) sale is female； Especially by Merck & Co., Inc. with title Bronze fine (17384) (Colorona) and Bronze (17353) (Colorona) and by The bronze mother-of-pearl that Engelhard Corp is sold with title Super bronze (Cloisonne)；Especially by En Geerha Moral company is with title Orange 363C (Cloisonne) and Orange MCR 101 (Cosmica) and by Merck & Co., Inc. with name Claim the orange mother-of-pearl of Passion orange (Colorona) and Matte orange (17449) (Microna) sale；Especially By Engelhard Corp with title Nuantique copper 340XB (Cloisonne) and Brown CL4509 (Chromalite) mother-of-pearl for the brown colouration sold；Especially by Engelhard Corp with title Copper 340A (Timica) mother-of-pearl with coppery flash of light of sale；Especially by Merck & Co., Inc. with title Sienna fine (17386) (Colorona) mother-of-pearl with red flashing light sold；Especially by Engelhard Corp with title Yellow (4502) (Chromalite) mother-of-pearl with yellow flash sold；Especially by Engelhard Corp with title Sunstone The red colored mother-of-pearl with golden flash of light of G012 (Gemtone) sale；Especially by Engelhard Corp with title The pink colour mother-of-pearl of Tan opal G005 (Gemtone) sale；Especially by Engelhard Corp with title Nu antique The black mother-of-pearl with golden flash of light of bronze 240AB (Timica) sale；Especially by Merck & Co., Inc. with title Matte The blue mother-of-pearl of blue (17433) (Microna) sale；Especially sold by Merck & Co., Inc. with title Xirona Silver White pearl with silver color flash of light is female；The gold especially sold by Merck & Co., Inc. with title Indian summer (Xirona) The orange mother-of-pearl of green powder and its mixture.

In the pigment that can be used according to the present invention, it can also refer to different from simple conventional coloring effect Those of optical effect, i.e., the unification such as generated by convention pigment (such as solid color pigments) and stable effect.For the present invention Purpose, term " stabilized " mean lack as the function of viewing angle or alternatively in response to temperature change The effect of color change.

For example, this material can be selected from the particle of flash metal luster, goniochromatic colorant, diffractive pigment, thermotropic Colour-changing agent, optical brightener and there are also fiber, especially interference fibers.Needless to say, these different materials can be combined with same When two kinds of effects are provided, or even according to novel effect according to the present invention.

Can be used for the particle with flash metal luster of the invention in particular selected from:

The particle of at least one metal and/or at least one metal derivative,

Organic or mineral substrates particle comprising single material or more materials has gold at least partially at least one Belong to the layer coating of flash of light, which includes at least one metal and/or at least one metal derivative, and

The mixture of the particle.

In the metal that can reside in the particle, it can be mentioned that such as Ag, Au, Cu, Al, Ni, Sn, Mg, Cr, Mo, Ti, Zr, Pt, Va, Rb, W, Zn, Ge, Te and Se and its mixture or alloy.Preferred metal be Ag, Au, Cu, Al, Zn, Ni, Mo and Cr and its mixture or alloy (such as bronze and brass).

Term " metal derivative " indicates to change derived from metal, especially oxide, fluoride, chloride and sulfide Close object.

It can be mentioned that the examples of these particles include aluminum particulate, as those Xing Bolian companies (Silberline) sell Entitled Starbrite 1200It is sold with Eckart GmbH & Co. KG entitledParticle.

It can also be mentioned that the metal powder or alloy mixture of copper, as radium bronze company (Radium Bronze) is sold The call number 2844 sold, metallic pigments (such as aluminium or bronze), as Eckart GmbH & Co. KG with title Rotosafe 700 sale those of, Eckart GmbH & Co. KG is with the alumina particles and metal alloy of the title Visionaire Bright Silver silicon dioxide coating sold Particle, such as Eckart GmbH & Co. KG is with the bronze of the title Visionaire Bright Natural Gold silicon dioxide coating sold (alloy of copper and zinc) powder.

They can also be the particle comprising glass baseplate, such as by Nippon Sheet Glass Co Ltd (Nippon Sheet Glass) with those of title Microglass Metashine sale.

Goniochromatic colorant can be selected from such as interference multilayered structure and liquid crystal colorant.

The example for the symmetry multilayer interference structure that can be used in the composition prepared in accordance with the present invention be for example with Flowering structure: Al/SiO₂/Al/SiO₂/ Al, the pigment with this structure are sold by E.I.Du Pont Company (DuPont de Nemours)； Cr/MgF₂/Al/MgF₂/ Cr, the pigment with this structure is by Fu Cai Ces Co., Ltd (Flex) with title Chromaflair pin It sells；MoS₂/SiO₂/Al/SiO₂/MoS₂；Fe₂O₃/SiO₂/Al/SiO₂/Fe₂O₃And Fe₂O₃/SiO₂/Fe₂O₃/SiO₂/Fe₂O₃, tool There is the pigment of these structures by BASF AG with title Sicopearl sale；MoS₂/SiO₂/ mica-oxide/SiO₂/ MoS₂；Fe₂O₃/SiO₂/ mica-oxide/SiO₂/Fe₂O₃；TiO₂/SiO₂/TiO₂And TiO₂/Al₂O₃/TiO₂；SnO/TiO₂/ SiO₂/TiO₂/SnO；Fe₂O₃/SiO₂/Fe₂O₃；SnO/ mica/TiO₂/SiO₂/TiO₂/ mica/SnO, the face with these structures Material is by Merck & Co., Inc. (Darmstadt (Darmstadt)) with title Xirona sale.For example, these pigment can be by Merck & Co., Inc. has silica/titanium oxide/stannic oxide structure pigment, by Merck with what title Xirona Magic was sold Company has silica/brown oxidation iron construction pigment, Yi Jiyou with what title Xirona Indian Summer was sold Silica/titanium oxide/mica/stannic oxide structure that Merck & Co., Inc. is sold with title Xirona Caribbean Blue Pigment.It can also be mentioned that unlimited color (Infinite Colors) pigment of Shiseido company (Shiseido).According to difference The thickness and property of coating obtain different effects.Therefore, in structure Fe₂O₃/SiO₂/Al/SiO₂/Fe₂O₃In the case where, it is right In 320 to 350nm SiO₂Layer, color from green gold discoloration be cervinus；For 380 to 400nm SiO₂Layer, becomes from red It is golden；For 410 to 420nm SiO₂Layer becomes green from purple；And for 430 to 440nm SiO₂Layer becomes from coppery For red.

As the example of the pigment with polymeric multilayer structure, it is mentioned that the entitled color sold by 3M company Those of scintillator (Color Glitter).

The example for the liquid-crystal goniochromatic particle that can be used include by Chenix company sell those of and there are also by Wa Ke company (Wacker) is with titleThe product of HC sale.

Hydrophobicity coating pigment

Preferably, composition according to the present invention includes that at least one is applied at least one lipophilicity or hydrophobic compound The pigment covered, and especially as detailed below.

Such pigment is particularly advantageous, since it is considered that it can be with larger quantities together with a large amount of water. In addition, they show main affinity to oily gum condensed-phase in the case where handling them with hydrophobic compound, the oiliness Then gelling mutually can transmit them.

Needless to say, composition according to the present invention can concurrently contain uncoated pigment.

The coating also may include at least one other non-lipophilic compound.

For purposes of the present invention, " coating " of pigment according to the present invention usually expression carries out full pigment with surface agent Portion or partial surface treatment, the surface agent absorption and sorption or are grafted on the pigment.

The pigment of surface treatment can be according to chemistry, electricity, mechanochemistry or mechanicalness well known to those skilled in the art It is prepared by matter process for treating surface.It can be with commodity in use.

Surface agent can form absorption and sorption by evaporation solvent, chemical reaction and covalent bond or be grafted on pigment.

According to a variant, surface treatment is made of the coating of pigment.

The coating can account for by weight the 0.1% to 20% of the total weight of the pigment of coating and especially be by weight 0.5% to 5%.

Coating can be carried out for example in the following manner: by by particle be incorporated into makeup or care composition its Before in his ingredient, under stiring, optionally particle and the surface agent are simply mixed liquid surface agent under heating It is adsorbed onto solid particles surface.

Coating can for example by surface agent and solid pigment particle surface occur chemical reaction and surface agent with Covalent bond is formed between grain to carry out.The method is especially described in patent US 4 578 266.

Chemical surface treatment may include that surface agent is diluted in volatile solvent, and pigment is dispersed in this mixture In, and then slow evaporation falls volatile solvent, so that surface agent is deposited at the surface of pigment.

Lipophilicity or hydrophobicity inorganic agent

When pigment includes lipophilicity or hydrophobic coating, which is preferably in the rouge of composition according to the present invention In fat phase.

According to a particular embodiment of the invention, pigment can be at least one compound selected from the following used according to the invention Coating: silicone surface agent；Fluorine surface agent；Fluorosilicone surface agent；Metallic soap；N- acylamino acid or its salt；Lecithin and its spread out Biology；Three iso stearyl titanate esters of isopropyl；Iso stearyl sebacate；Natural plants or animal wax；Polarity synthetic wax；Fat Ester；Phosphatide；And its mixture.

Silicone surface agent

According to specific embodiment, pigment can be carried out at all or part of surface with the compound with siloxanes property Reason.

Silicone surface agent can be selected from organopolysiloxane, silane derivative, silicon-acrylate copolymer, silicone Resin and its mixture.

Term " organopolysiloxane compound " refers to the alternating comprising silicon atom and oxygen atom and includes connection To the compound of the structure of the organic group of silicon atom.

i)Inelastic body organopolysiloxane

The inelastic body organopolysiloxane that can especially refer to include dimethyl silicone polymer, poly- methylhydrogensiloxane and Poly-alkoxyl dimethyl siloxane.

Alkoxy can be indicated by group R-O-, so that R indicates methyl, ethyl, propyl, butyl or octyl, 2- phenyl second Base, 2- phenyl propyl or 3,3,3- trifluoro propyls, such as phenyl, tolyl or xylyl aryl or such as phenylethyl takes The aryl in generation.

A kind of method being surface-treated with polymethyl hydrogen siloxane to pigment includes that pigment is dispersed in organic solvent In, and then add polysiloxane compound.When heating mixture, formed altogether between silicone compounds and surface of pigments Valence link.

According to preferred embodiment, silicone surface agent can be inelastic body organopolysiloxane, be especially selected from poly dimethyl Siloxanes.

ii)Alkyl silane and alkoxy silane

Silane with alkoxy-functional is especially described in " A silaneprimer, Chemistry by Witucki And applications of alkoxy silanes [silane primer, the chemical property and application of alkoxy silane], Journal of Coatings Technology [coating technology magazine], 65,822, the 57-60 pages, in 1993 ".

Alkoxy silane such as with call number Silquest A-137 (OSI special type product company (OSI Specialities)) and The alkyl triethoxysilane and alkyl trimethoxysilane of Prosil 9202 (PCR, Inc.) sale can be used for coating pigment.

To with reactive terminal group, such as the use of the alkyl polysiloxane of alkoxy, hydroxyl, halogen, amino or imino group It is described in patent application JP H07-196946.They are also applied for processing pigment.

iii)Polysiloxanes-acrylate polymer

It can be used as being described in patent US 5 725 882, US 5 209 924, US 4 972 037, US 4 981 903, there is silicon oxygen in US 4 981 902 and US 5 468 477 and patent US 5 219 560 and EP 0 388 582 Polysiloxanes-acrylate polymer of the grafting of alkane skeleton.

Other polysiloxanes-acrylate polymers can be in its structure comprising the poly- of the unit with lower formula (I) Siloxane polymer:

Wherein group G₁, can be same or different, indicate hydrogen or C₁-C₁₀Alkyl or alternatively phenyl；Base Group G₂, can be same or different, indicate C₁-C₁₀Alkylidene；G₃It indicates by least one olefinic unsaturation anionic monomer Polymerization (homopolymerization) generate polymer residue；G₄Indicate the polymerization (homopolymerization) by least one olefinic unsaturation hydrophobic monomer The polymer residue of generation；M and n is equal to 0 or 1；A is 0 to 50 integer；B is the integer that can be 10 to 350, and c is that range is 0 to 50 integer；With the proviso that one of these parameters and c are not 0.

Preferably, the unit with upper formula (I) is at least one of following characteristics and even more preferably with institute There are following characteristics:

Group G1 indicates alkyl, preferably methyl；

- n is not zero, and group G2 indicates divalent C1-C3 group, preferably propylene group；

- G3 is indicated by monomer, preferably acrylic acid and/or the methacrylic acid of at least one ethylenically unsaturated carboxylic acids type It polymerize the polymeric groups that (homopolymerization) generates；

- G4 is indicated by the monomer of at least one (methyl) acrylic acid (C1-C10) Arrcostab type, preferably such as (methyl) third The polymeric groups that the polymerization (homopolymerization) of olefin(e) acid isobutyl ester or (methyl) methyl acrylate generates.

The example of polysiloxane polymer corresponding to formula (I) especially exists via the connection chain element of thio propylene type It is grafted with the poly- diformazan of the mixed polymer unit of poly- (methyl) acrylic-type and poly- (methyl) methyl acrylate type thereon Radical siloxane (PDMS).

Other examples of polysiloxane polymer corresponding to formula (I) are especially via the connection chain list of thio propylene type Member is grafted with the dimethyl silicone polymer (PDMS) of the polymer unit of poly- (methyl) isobutyl acrylate type on it.

iv)Silicone resin

Silicone surface agent can be selected from silicone resin.

Term " resin " refers to three-dimensional structure.

Silicone resin can be dissolved or be swollen in silicone oil.These resins are the organo-siloxanes polymers of crosslinking.

The nomenclature of silicone resin is various siloxanes lists known, which includes at title " MDTQ " according to it Body unit describes, the type of each of alphabetical " MDTQ " characterization unit.

Alphabetical M expression (CH₃)₃SiO_1/2Monofunctional unit, silicon atom is connected only in the polymer comprising this element An oxygen atom on.

Alphabetical D means difunctional unit (CH₃)₂SiO_2/2, wherein on silicon atom bonding to two oxygen atoms.

Tee expression (CH₃)SiO_3/2Trifunctional units.

In unit M, D and T of previous definition, at least one methyl can be replaced by the group R in addition to methyl, the base Group the R such as group (especially alkyl) based on hydrocarbon containing 2 to 10 carbon atoms or phenyl or be alternatively hydroxyl.

Finally, letter Q refers to tetrafunctional cell S iO_4/2, wherein on silicon atom bonding to four hydrogen atoms, this four hydrogen Atom itself is bonded on the rest part of polymer.

Various resins with different characteristics can be obtained by these different units, and the characteristic of these polymer is according to monomer The type of (or unit), the type of substituent group and number, polymer chain length, the degree of branching and side chain size and change.

The example for these silicone resins that can be mentioned that includes:

Siloxysilicate material can be formula [(CH₃)₃XSiXO]_xX(SiO_4/2)_yThe trimethyl first of (MQ unit) Siloxy esters of silicon acis, wherein x and y is the integer of range 50 to 80；

Formula (CH₃SiO_3/2)_xThe polysilsesquioxane of (T unit), wherein x is greater than 100 and its at least one methyl can be with Replaced by group R as defined above；

Poly methyl silsesquioxane is the polysilsesquioxane replaced without methyl by another group.

Such poly methyl silsesquioxane is described in US 5 246 694.

As the example of commercially available poly methyl silsesquioxane resin, it can be mentioned that sold by following company It is a little:

- You Wake company is with call number resin M K sale, such as Belsil PMS MK: including CH₃SiO_3/2Repetitive unit (T Unit) polymer, can also comprising by weight be up to 1% (CH₃)₂SiO_2/2Unit (D unit) and have about 10000 average molecular weight；

By company, SHIN-ETSU HANTOTAI with call number KR-220L sale, by formula CH₃SiO_3/2Unit T form and contain Si-OH (silanol) end group；With call number KR-242A sale, it includes the dimethyl units D of 98% unit T and 2% and contain Si-OH end group；Or with call number KR-251 sale, it includes the dimethyl units D of 88% unit T and 12% and contain Si-OH end group.

The siloxysilicate material resin that can be mentioned that includes the trimethylsiloxy silicon for being optionally in powder type Acid esters (TMS) resin.This kind of resin is by General Electric Co. Limited (General Electric) with 1 170- of call number SR1000, E 002 or SS 4230 is sold, or by Wa Ke silicone group (Wacker Silicone Corporation) with call number TMS 803, Wacker 803 and 804 is sold.

It can also refer to the trimethylsiloxysilicate resin sold in solvent such as cyclopolymethyl siloxane, such as It is sold with title KF-7312J by company, SHIN-ETSU HANTOTAI or is sold by Dow Corning Corporation with call number DC 749 and DC 593.

The example of commercial reference as the pigment handled with silicone compounds, it can be mentioned that:

The red iron oxide sold by Miyoshi Kasei Inc with call number SA-C 338075-10/poly dimethyl silicon Oxygen alkane；And

By handling the pigment that DC red 7 is obtained with polysiloxane compound, You Kelian company (Coletica) is with call number Gransil GCM (it is the mixture of D5 and polysiloxanes 11) sale.

Fluorine surface agent

Pigment can carry out all or part of surface treatment with the compound with fluorine property.

Fluorine surface agent can selected from perfluoralkyl phosphate, perfluoropolyether, polytetrafluoro polyethylene (PTFE), perfluoro alkane, Perfluoroalkyl silazane, polyhexafluoropropylene oxide and the polysiloxane comprising perfluoroalkyl perfluoropolyether group.

Term " perfluoroalkyl " means the alkyl that wherein all hydrogen atoms have been replaced by a fluorine atom.

Perfluoropolyether is especially described in patent application EP 0486135, and by Montefluos company with trade name Fomblin sale.

Perfluoralkyl phosphate is particularly described in patent application JP H05-86984.It can be used by Asahi Glass strain formula meeting The perfluoroalkyl diethanol amine phosphate that society (Asahi Glass) is sold with call number AsahiGuard AG530.

The straight chain perfluoro alkane that can be mentioned that is that perfluorinated cycloalkanes, perfluor (alkyl naphthene), perfluor polycyclic alkane, aromatics are complete Fluorohydrocarbon (perfluoroarene) and include at least one heteroatomic perfluoro organic compound based on hydrocarbon.

In perfluoro alkane, it can be mentioned that linear paraffin is serial, such as perfluorooctane, Perfluorononane or perfluor last of the ten Heavenly stems Anhui.

In perfluorinated cycloalkanes and perfluor (alkyl naphthene), it can be mentioned that by Rhodia (Rhodia) with title Perfluorodecalin, perfluor (methyl naphthalane) and perfluor (the C3-C5 alkyl cyclohexane) such as perfluor (butyl that Flutec PP5 GMP is sold Hexamethylene).

In perfluor polycyclic alkane, it can be mentioned that bicyclic [3.3.1] nonane derivatives such as perfluor trimethyl is bicyclic [3.3.1] Nonane, adamantane derivative such as perfluor dimethyladamantane and hydrogenation ten tetrahydro generation of perfluor phenanthrene derivative such as 24 fluoro It is luxuriant and rich with fragrance.

In perfluoroarene, it can be mentioned that perfluor naphthalene derivatives, such as perfluor naphthalene and perfluoro-methyl -1- naphthalene.

The example of commercial reference as the pigment handled with fluorine compounds, it can be mentioned that:

The oxide yellow sold by big east chemical conversion Co., Ltd. (Daito Kasei) with call number PF 5Yellow 601 Iron/perfluoralkyl phosphate；

Red iron oxide/perfluor Anhui base the phosphorus sold by big east chemical conversion Co., Ltd. with call number PF 5Red R 516L Acid esters；

Black iron oxide/the perfluoroalkyl sold by big east chemical conversion Co., Ltd. with call number PF 5Black BL 100 Phosphate；

Titanium dioxide/the perfluoroalkyl phosphate sold by big east chemical conversion Co., Ltd. with call number PF 5TiO2 CR 50 Ester,

The oxide yellow that-You Meixi company (Toshiki) is sold with call number Iron oxide yellow BF-25-3 The poly- methyl isopropyl ether of iron/perfluor；

The red poly- methyl of 7/ perfluor of DC sold by capable company, section (Cardre Inc.) with call number D&C Red 7FHC Isopropyl ether；And

The DC Red 5/ sold by Warner Zhan Jinsen company (Wamer-Jenkinson) with call number T 9506 PTFE。

Fluorosilicone surface agent

Pigment can carry out all or part of surface treatment with the compound with fluorosilicone property.

Fluosilicic oxyalkane compound can be selected from perfluoroalkyl dimethyl silicone polymer, perfluoroalkyl silanes and perfluoroalkyl three Alkoxy silane.

The perfluoroalkyl silanes that can be mentioned that include the product sold by silicone company, SHIN-ETSU HANTOTAI (Shin-Etsu Silicone) LP-IT and LP-4T.

Perfluoroalkyl dimethyl silicone polymer can be expressed from the next:

Wherein:

- R indicate the linear chain or branched chain containing 1 to 6 carbon atom divalent alkyl, preferably divalent methyl, ethyl, propyl or Butyl；

- Rf indicates the perfluoroalkyl containing 1 to 9 carbon atom and preferably 1 to 4 carbon atom；

- m is selected between 0 and 150 and is preferably selected from 20 to 100；And

- n is selected and preferably 1 to 100 between 1 and 300.

The example of commercial reference as the pigment handled with fluorine polysiloxane compound, it can be mentioned that by Advanced The titanium dioxide that Dermaceuticals international corporation is sold with call number Fluorosil Titanium dioxide 100TA/ Fluorosilicone.

Other lipophilic surface's agent

Hydrophobicity inorganic agent can also be selected from:

I) metallic soap, such as two aluminium myristates and hydrogenated tallow glutamic acid aluminium salt；

The metallic soap that can especially refer to includes the fatty acid containing 12 to 22 carbon atoms and especially contains 12 to 18 The metallic soap of those of a carbon atom.

The metal of metallic soap can especially zinc or magnesium.

The metallic soap that can be used includes zinc laurate, magnesium stearate, magnesium myristate and zinc stearate and its mixing Object.

Ii) fatty acid, such as lauric acid, myristic acid, stearic acid and palmitinic acid；

Iii) N- acylamino acid or its salt may include the acyl group containing 8 to 22 carbon atoms, such as 2- ethyl hexyl Acyl group, caproyl, lauroyl, myristoyl, palmityl, stearyl or cocoyl；

Amino acid can be such as lysine, glutamic acid or alanine.

The salt of these compounds can be aluminium salt, magnesium salts, calcium salt, zirconates, zinc salt, sodium salt or sylvite.

Therefore, according to particularly preferred embodiment, N- acyl amino acid derivative can glutamate derivatives in particular And/or its salt, and more particularly stearoyl-glutamic acid salt, such as stearoyl-glutamic acid aluminium.

Iv) lecithin and its derivative；

V) three iso stearyl titanate esters of isopropyl；

The example of pigment as the processing of three isostearic acid isopropyl oxygen titanium salts (ITT), it can be mentioned that by Kobo company with quotient Product call number BWBO-I2 (iron oxide CI77499 and three isostearic acid isopropyl oxygen titanium salts), BWYO-I2 (iron oxide CI77492 and Three isostearic acid isopropyl oxygen titanium salts) and BWRO-I2 (iron oxide CI77491 and three isostearic acid isopropyl oxygen titanium salts) sale that A bit.

Vi) decanedioic acid iso stearyl ester；

Vii) natural plants or animal wax or polarity synthetic wax；

Viii) fatty ester, particularly jojoba ester；

Ix) phosphatide；And

X) its mixture.

The wax referred in previously mentioned compound can be commonly used in those of in cosmetics, as defined below 's.

They especially can be wax, silicon wax and/or fluorine wax based on hydrocarbon, optionally include ester or hydroxy functional group.They It can also be natural or synthetic source.

Term " polar waxes " refers to the wax containing the chemical compound comprising at least one polar group.Polar group is It is well-known to those skilled in the art；They may, for example, be alcohol, ester or carboxylic acid group.It does not include polyethylene in polar waxes Wax, paraffin, microwax, ceresine and Fischer-Tropsch wax (Fischer-Tropsch wax).

Particularly, the average Hansen Solubility Parameter δ a that polar waxes have at 25 DEG C makes 0 (J/cm of δ a >³)^1/2And Also better 1 (J/cm of δ a >³)^1/2:

Wherein δ p and δ h is respectively to contribute particular for the polarity contribution of Hansen Solubility Parameter and coactive pattern.

Following article is described in by C.M.Hansen according to definition of the solvent of Hansen in three-dimensional solubility space: " The three-dimensional solubility parameters [three solubility parameters] ", J.Paint Technol. [coating technology magazine] 39,05 (1967):

- δ h characterizes specific interaction force (such as hydrogen bond, acid/base, donor/acceptor)；

- δ p is characterized between debye interaction force and induced dipoles and permanent dipole between permanent dipole Ke Suomu interaction force.

Parameter δ p and δ h are with (J/em³)^1/2It indicates.

Polar waxes are especially by also including hetero atom (such as O, N and P) except the carbon atom in its chemical structure and hydrogen atom Molecule formed.

The non-limiting illustration for these polar waxes that can especially refer to includes natural polar waxes, such as beeswax, lanolin wax, orange Wax, lemon wax and Insects in China wax, rice bran wax, Brazil wax, candelila wax, ouricury wax, cork fibrous wax, sugarcane Wax, Japan tallow, sumac wax and lignite wax.

According to specific embodiment, at least one compound selected from the following can be used to coat in pigment: silicone surface agent； Fluorine surface agent；N- acylamino acid or its salt；Three iso stearyl titanate esters of isopropyl；Natural plants or animal wax；Fatty ester；And Its mixture.

According to particularly preferred embodiment, pigment can use N- acylamino acid and/or its salt, particularly glutamic acid derivative Object and/or its salt or fatty ester, particularly jojoba ester coat.

According to particularly preferred embodiment, pigment with N- acylamino acid and/or its salt, particularly can use glutamic acid Derivative and/or its salt, especially stearoyl-glutamic acid salt, such as stearoyl-glutamic acid aluminium coat.

The example of the pigment for the coating according to the present invention that can more particularly refer to includes using aluminium stearoyl-glutamic acid salt The titanium dioxide and iron oxide of coating, such as sold by Miyoshi Kasei Inc with call number NAI.

The pigment of unused hydrophobic compound coating

As previously mentioned, composition can also contain either with or without the pigment with lipophilicity or hydrophobic compound coating.

These other pigment can with hydrophilic compounds coat or it is uncoated.

These pigment can be the coloring earth especially such as previous definition.

These pigment can also be organic pigment.

Term " organic pigment " mean to meet in Liv Ullmann encyclopaedical (Ullmann ' s encyclopaedia) about Any pigment of definition in the chapters and sections of organic pigment.Organic pigment especially can be selected from nitroso, nitro, azo, xanthene, quinoline Quinoline, anthraquinone, phthalocyanine, metal complex species, isoindolinone, isoindoline, quinacridone, purple cyclic ketones, diketone pyrrolo- pyrrole It coughs up, thioindigo, dioxazines, triphenylmenthane and quinophthalone compound.

One or more organic pigments can be for example selected from following item: carmine, carbon black, nigrosine, melanin, azo Huang, quinacridone, phthalocyanine blue, chrysanthemum are compiled with call number CI 42090,69800,69825,73000,74100 and 74160 Enter the blue pigment of color index (ColorIndex), with call number CI 11680,11710,15985,19140,20040, 21100,21108,47000 and 47005 yellow uitramarine for being incorporated into color index, with call number CI 61565,61570 and 74260 are incorporated into the viridine green of color index, are incorporated into color with call number CI 11725,15510,45370 and 71105 and refer to Several orange pigments, with call number CI 12085,12120,12370,12420,12490,14700,15525,15580, 15620、15630、15800、15850、15865、15880、17200、26100、45380、45410、58000、73360、73915 The red pigment for being incorporated into color index with 75470, and be such as described in patent FR 2 679 771 by indoles or benzene The pigment that the oxidation polymerization of amphyl obtains.

These pigment can also be in the form of the composite pigment being such as described in patent EP 1 184 426.These compound face Material can be especially made of particle, these particles include the mineral core covered at least partially with organic pigment and at least one use In the adhesive that organic pigment and the core is fixed.

The pigment can also be color lake.Term " color lake " means the insoluble dyes being adsorbed on insoluble granule, thus The component of acquisition keeps insoluble during use.

The mineral substrates of Dye Adsorption on it are, for example, aluminium oxide, silica, calcium borosilicate sodium or calcium borosilicate aluminium And aluminium.

In these organic dyestuff, it can be mentioned that alkermes.It can also refer to product known to following title: D&C Red 21 (CI 45 380), D&C orange 5 (CI 45 370), D&C red 27 (CI 45 410), D&C orange 10 (CI 45 425), D&C are red 3 (CI 45 430), D&C red 4 (CI 15 510), D&C red 33 (CI 17 200), D&C Huang 5 (CI 19 140), 6 (CI of D&C Huang 15 985), D&C green (CI 61 570), D&C Huang 1O (CI 77 002), D&C green 3 (CI 42 053), (CI 42 of D&C indigo plant 1 090)。

It can be mentioned that the example in color lake be with product known to title D&C red 7 (CI 15850:1).

The property of hydrophilic coating

As previously mentioned, these other pigment can be coated with hydrophilic compounds.

In order to optimize dispersion of the hydrophilic compounds for being surface-treated to pigment in the water phase of gelling Property, it is chosen more particularly from biopolymer, carbohydrate, polysaccharide, polyacrylate and polyethyleneglycol derivative.

As the example of biopolymer, it can be mentioned that the polymer based on carbohydrate type monomer.

More particularly, it can be mentioned that biological carbohydrate gum；Chitosan and its derivative, such as butoxy chitosan, carboxymethyl chitosan Sugar, carboxylic butyl chitosan, chitosan gluconate, chitosan adipate ester, chitosan ethyl glycolate, chitosan lactate etc.； Chitosan and its derivatives, such as carboxymethyl chitosan, chitin ethyl glycolate；Cellulose and its derivates such as cellulose acetate； Microcrystalline cellulose；PASELLI EASYGEL；Sodium Hyaluronate；Soluble protein glycan；Galactolipin-araban；Glycosaminoglycan Class；Glycogen；Sclerotium gum；Dextran；Starch and its derivative；And its mixture.

The example for the carbohydrate that can especially refer to includes the polyhydroxy aldehyde and polyhydroxyketone with following general formula: C_x(H₂O)_y

Wherein x and y can be in the range of 1 to 1 000 000.

Carbohydrate can be monosaccharide, disaccharides or polysaccharide.

Especially it can be mentioned that the example of carbohydrate include amylodextrin, beta glucan, cyclodextrin, modified corn starch, sugar Original, hyaluronic acid, hydroxypropyl cyclodextrin, lactose, maltitol, guanosine, glyceryl starch, wheaten starch, trehalose, sucrose and Its derivative, gossypose and sodium chondroitin sulfate.

Individually or with three (C₁-C₂₀) C that is applied in combination of alkyl silane₁-C₂₀Aklylene glycol or C₁-C₂₀Alkylene glycol ether It is also used as surface treating agent.

Examples which may be mentioned include the pigment handled with PEG alkyl ether alkoxysilane surface, for example, by Kobo company with The pigment of title SW pigment sale handled with PEG-8- methyl ether triethoxysilane.

Silicone, such as the dimethyl silicone polymer with hydrophilic radical is (also with designation Dimethicone polyol Or alkyl dimethicone polyol and it is known) can also be suitable as surface treating agent in the present invention.Particularly, Such dimethyl silicone polymer may include the C as repetitive unit₁-C₂₀Oxyalkylene, such as ethylene oxide or propylene oxide.

It can be mentioned that example be with PEG-12- dimethyl silicone polymer handle pigment, You Senxin company (Sensient Corporation) with title LCW AQ Pigment sale.

The amount of the pigment and/or uncoated pigment that are coated at least one hydrophilic compounds is especially by the change considered The restriction of the desired use of cosmetic compositions, and this amount adjustment obviously fall in composite formula designer ability it It is interior.

Appearance form

Composition according to the present invention includes oiliness continuous phase.

Concrete form according to the present invention, they can be in anhydrous composition such as oil, emulsifiable paste, balm or oil-base gel (oil Gel) form.

According to particularly preferred form, composition is in the formation of water-in-oil emulsion, which includes that oiliness is continuous Phase and the water phase for being scattered in the oily phase.They can be in the form of more or less liquid or thick emulsifiable paste.

Concrete form according to the present invention, the composition are water-in-oil emulsions, are included at least:

A) oiliness continuous phase；

B) it is scattered in the aqueous discontinuous phase of the oily phase；

C) organic UV covers agent composition, includes i) Cyanide Dioctyl Acrylate and ii) ethylhexyl salicylate and/ Or heliophan；And

D) at least one non-annularity volatile silicone oils, be especially selected from octamethyltrisiloxane, decamethyl tetrasiloxane and Ten dimethyl, five siloxanes and its mixture, and five siloxanes of more particularly ten dimethyl.

A) oiliness continuous phase；

B) it is scattered in the aqueous discontinuous phase of the oily phase；

C) agent composition, the mixture are covered relative to organic UV of the total weight of the composition by weight at least 15% Include i) Cyanide Dioctyl Acrylate and ii) ethylhexyl salicylate and/or heliophan；And

D) at least one non-annularity volatile silicone oils, be especially selected from octamethyltrisiloxane, decamethyl tetrasiloxane and Ten dimethyl, five siloxanes and its mixture, and five siloxanes of more particularly ten dimethyl；The non-annularity volatility silicon The oily weight ratio with organic UV masking agent composition is at least 0.5 and more particularly at least 0.7.

A)Water phase

Water phase includes water and optionally water-soluble or miscible with water ingredient, such as water-soluble solvent.

Being suitable for the invention water can be Hua Shui, such as corn flower water and/or mineral water such as Vittel water, Lucas water or Manage skin spring (La Roche Posay) water and/or thermal water.

In the present invention, term " water-soluble solvent " indicates at room temperature as liquid and miscible with water (at 25 DEG C and big It is by weight with the compatibility of water greater than compound 50%) under air pressure.

The water-soluble solvent that can be used in the present compositions can also be volatile.

In the water-soluble solvent that can be used in composition according to the present invention, it is particularly possible to refer to low-grade monobasic alcohol class (contain 1 to 5 carbon atom, such as ethyl alcohol and isopropanol), glycols (contain 2 to 8 carbon atoms, such as ethylene glycol, propylene glycol, 1, 3- butanediol and dipropylene glycol), C₃And C₄Ketone and C₂-C₄Aldehydes.

When composition is water-in-oil emulsion, water phase preferably with the total weight relative to the composition by weight at least 20%, the concentration that preferred scope is by weight 30% to 60%, more particularly by weight 40% to 50% exists.

B)Emulsifier

Water-in-oil emulsion according to the present invention generally includes one or more emulsifying surfactants, these emulsification surfaces Activating agent is preferably non-ionic.

For the purposes of the present invention, " emulsifying surfactant " means amphiphilic surfactant's compound, that is, has not The two-part compound of same polarity.In general, a part is lipophilic (being soluble or dispersible in oily phase).Another part It is hydrophilic (being soluble or dispersible in water).Emulsifying surfactant is characterized in that their HLB, and (hydrophilic and oleophilic is flat Weighing apparatus) value, HLB is the ratio in molecule between hydrophilic segment and lipophilic portion.Term " HLB " is ripe for those skilled in the art Know, and is for example described in " The HLB system.A time-saving guide to Emulsifier Selection [HLB system, emulsifier select time saving guide] " (it is published by U.S. empire chemical industrial company (ICI Americas Inc.), 1984) in.For emulsifying surfactant, the HLB of W/O lotion is used to prepare usually in the range of 3 to 8.According to this hair The HLB of the bright one or more surfactants used can be measured via Griffin method or Davies method.

As the example of W/O emulsifying surfactant, it can be mentioned that sorbitan, glycerol, polyalcohol or sugar alkane Base ester or ether；Silicone surfactant, such as dimethicone copolyol, such as by company, SHIN-ETSU HANTOTAI with brand X-22-Sale with INCI designation Dimethicone (and) PEG/PPG-18/18 dimethyl silicone polymer that A bit；The mixture of Cyclomethicone and dimethicone copolyol, by Dow Corning Corporation with title DC 5225 Sale；And alkyl dimethicone polyol, such as it is formulated by Dow Corning Corporation with title Dow Coming 5200 The laurylmethicone polyol of auxiliary agent sale；Abil EM 90, such as cetyl PEG/PPG-10/1 dimethyl silicone polymer, such as by Ying Chuangaoshi Mitt USA Corporation (Evonik Goldschmidt) with title Abil EMThe product and Abil EM 90 of sale, polyglycereol isostearate (4mol) and laurel The mixture of the own ester of acid, by Gao Shi Mitt USA Corporation with title Abil WESale.It can also be by one or more co-emulsifiers Agent (it can be advantageously selected from the group comprising polyalcohol Arrcostab) is added to wherein.

It can also refer to non-silicone emulsifying surfactant, especially sorbitan, glycerol, polyalcohol or sugar Arrcostab or ether.

As polyalcohol Arrcostab, it is particularly possible to refer to macrogol ester, such as PEG-30 dimerization hydroxy stearic acid ester, such as by The product that standing grain major company (Croda) is sold with title Cithrol DPHS-SO- (MV).

It can be mentioned that glycerol and/or the example of sorbitan ester include polyglyceryl isostearate (INCI Claim: -4 isostearate of polyglycereol), such as by Ying Chuangaoshi Mitt USA Corporation with title Isolan GIThe product of sale；Dehydration D-sorbite isostearate, such as by Imperial Chemical Industries (ICI) with title ArlacelThe product of sale；It is de- Water D-sorbite glyceryl isostearate, such as by Imperial Chemical Industries with title ArlacelThe product of sale, (INCI title: polyglycereol -4 two is different hard for the diester of the mixture of isostearic acid, poly- hydroxy stearic acid and decanedioic acid and polyglycereol -4 Resin acid ester/poly- hydroxy stearic acid ester/sebacate), such as by Ying Chuan company (Evonik) with title IsolanSale Product and its mixture.

Concrete form according to the present invention, emulsifying surfactant can be selected from emulsification elastomer silicones.

Term " elastomer silicone " means there is viscous-elastic behaviour and the especially consistency with sponge or flexible bulb Soft, deformable organopolysiloxane.Its elasticity modulus is so that this material withstands deformation and has limited prolong Stretching property and shrinkage.This material can restore its original-shape after stretching, extension.

Emulsify the organosilicone elastic that elastomer silicone can be selected from polyoxyalkylenated elastomer silicone and bound to polyglycerol Body and its mixture.

a)Polyoxyalkylenated elastomer silicone

Polyoxyalkylenated elastomer silicone is the organopolysiloxane of crosslinking, it can be by containing at least one bonding The crosslinking addition of the diorganopolysiloxanecompositions of hydrogen on to silicon and the polyoxyalkylene containing at least two ethylenically unsaturated groups It reacts and obtains.

Preferably, the organopolysiloxane of polyoxyalkylenated crosslinking is by containing at least two be respectively bonded on silicon The diorganopolysiloxanecompositions (A1) of hydrogen are especially urged in platinum with the polyoxyalkylene (B1) containing at least two ethylenically unsaturated groups Crosslinking addition reaction in the presence of agent (C1) and obtain, for example, such as in patent US 5 236 986 and US 5 412 004 It is described.

Specifically, the polyoxyalkylene that organopolysiloxane can be blocked by dimethylvinylsiloxy is (special Polyethylene glycol oxide and/or polypropylene oxide) with trimethylsiloxy sealing end methylhydrogenpolysi,oxane in platinum catalyst In the presence of reaction and obtain.

It can be the alkyl containing 1 to 18 carbon atom, such as first with the organic group of the silicon atom bonding of compound (A1) Base, ethyl, propyl, butyl, octyl, decyl, dodecyl (or lauryl), myristyl, cetyl or stearyl；Substituted alkane Base, such as 2- phenylethyl, 2- phenyl propyl or 3,3,3- trifluoro propyls；Aryl, such as phenyl, tolyl or xylyl；Replace Aryl, such as phenylethyl；And group of the monovalence based on hydrocarbon replaced, such as epoxy group, carboxylate or sulfydryl.

Therefore compound (A1) can be selected from methylhydrogenpolysi,oxane, the trimethyl first silicon of trimethylsiloxy sealing end Alkoxy end-capped dimethyl siloxane/methylhydrogensiloxacopolymer copolymer, dimethyl siloxane/methylhydrogensiloxane cyclic copolymerization Dimethyl siloxane/methyl hydrogen siloxane/lauryl methicone copolymer of object and trimethylsiloxy sealing end.

Compound (C1) is the catalyst for cross-linking reaction, and especially chloroplatinic acid, chloroplatinic acid-alkene complex, Chloroplatinic acid-alkenyl siloxane complex compound, chloroplatinic acid-diketone complex compound, platinum black and Supported Pt Nanoparticles.

Advantageously, polyoxyalkylenated elastomer silicone can especially contain at least two by divinyl compound The polyoxyalkylene of vinyl groups is reacted with the Si -- H bond of polysiloxanes and is formed.

Polyoxyalkylenated elastomer silicone according to the present invention preferably at least one oil based on hydrocarbon and/or at least one Kind silicone oil is mixed to form gel.In these gels, polyoxyalkylenated elastomer can be in the form of aspherical particle.

Polyoxyalkylenated elastomer is especially described in patent US 5 236 986, US 5 412 004, US 5 837 793 In US 5 811 487.

As polyoxyalkylenated elastomer silicone, can be used with those of following INCI title:

Dimethyl silicone polymer/PEG-10/15 cross-linked polymer,

PEG-15/ lauryl dimethicone cross-linked polymer,

PEG-10/ lauryl dimethicone cross-linked polymer,

PEG-12 Dimethicone Crosspolymer,

PEG-10 Polydimethylsiloxane cross-linked polymer,

PEG-10 Polydimethylsiloxane/vinyl dimethicone cross polymer,

PEG-12 dimethyl silicone polymer/PPG-20 cross-linked polymer,

And its mixture.

They especially by company, SHIN-ETSU HANTOTAI withTitle sale:

KSG-(INCI title: dimethyl silicone polymer and dimethyl silicone polymer/PEG-10/15 cross-linked polymeric Object；

KSG-INCI title: PEG-15/ lauryl dimethicone cross-linked polymer and mineral oil:

KSG-INCI title: PEG-15/ lauryl dimethicone cross-linked polymer and Permethyl 99A；

KSG-INCI title: PEG-15/ lauryl dimethicone cross-linked polymer and three isooctyl acids are sweet Grease (Triethylhexanoin)；

KSG-INCI title: saualane and PEG-15/ lauryl dimethicone cross-linked polymer.They Especially by Dow Corning Corporation with title Dow Corning 9011Silicone Elastomer Sale；INCI Claim: cyclopentasiloxane and PEG-12 Dimethicone Crosspolymer.

It can also refer to by Dow Corning Corporation with title Dow Coming EL-7040Hydro Elastomer The product of sale, the compound have INCI title: PEG-12 dimethyl silicone polymer/PPG-20 cross-linked polymer.

b)The elastomer silicone of bound to polyglycerol

The elastomer silicone of bound to polyglycerol is elastomer crosslinked organopolysiloxane, it can be by containing at least one The compound of the diorganopolysiloxanecompositions and the bound to polyglycerol containing ethylenically unsaturated groups of a hydrogen being bonded on silicon is special It is crosslinking addition reaction in the presence of platinum catalyst and obtains.

Preferably, elastomer crosslinked organopolysiloxane is by containing at least two hydrogen being respectively bonded on silicon Diorganopolysiloxanecompositions (A) are especially urged in platinum with the glycerinated compound (B) containing at least two ethylenically unsaturated groups Crosslinking addition reaction in the presence of agent (C) and obtain.

Specifically, the chemical combination for the bound to polyglycerol that organopolysiloxane can be blocked by dimethylvinylsiloxy Object is obtained with methylhydrogenpolysi,oxane the reacting in the presence of platinum catalyst that trimethylsiloxy blocks.

Compound (A) is the basic reaction object to form organopolysiloxane elastomers, and be crosslinked be by compound (A) with What the addition reaction that compound (B) occurs in the presence of catalyst (C) carried out.

Compound (A) contains the organic of at least two hydrogen atoms for being bonded to different silicon atoms in each molecule in particular Polysiloxanes.

Compound (A) can have any molecular structure, especially linear chain structure or branched structure or cyclic structure.

Compound (A) can have the viscosity that range is 1 to 50000 centistokes(cst) at 25 DEG C, especially to be convenient to and chemical combination Object (B) is miscible.

It can be the alkyl containing 1 to 18 carbon atom, such as first with the organic group of the silicon atom bonding of compound (A) Base, ethyl, propyl, butyl, octyl, decyl, dodecyl (or lauryl), myristyl, cetyl or stearyl；Substituted alkane Base, such as 2- phenylethyl, 2- phenyl propyl or 3,3,3- trifluoro propyls；Aryl, such as phenyl, tolyl or xylyl；Replace Aryl, such as phenylethyl；And group of the monovalence based on hydrocarbon replaced, such as epoxy group, carboxylate or sulfydryl.Preferably, The organic group is selected from methyl, phenyl and lauryl group.

Therefore compound (A) can be selected from methylhydrogenpolysi,oxane, the trimethyl first silicon of trimethylsiloxy sealing end Alkoxy end-capped dimethyl siloxane/methylhydrogensiloxacopolymer copolymer, dimethyl siloxane/methylhydrogensiloxane cyclic copolymerization Dimethyl siloxane/methyl hydrogen siloxane/lauryl methicone copolymer of object and trimethylsiloxy sealing end.

Compound (B) can be the compound of the bound to polyglycerol corresponding to following formula (B '):

C_mH_2m-1-O-[Gly]_n-C_mH_2m-1 (B′)

Wherein m be range be 2 to 6 integer, n be range be 2 to 200, preferred scope is 2 to 100, preferred scope 2 To 50 integer, preferably n range is 2 to 20, preferred scope is 2 to 10 and preferred scope is 2 to 5, and particularly n is equal to 3；Gly is indicated:

-CH₂-CH(OH)-CH₂- O- or-CH₂-CH(CH₂OH)-O-

Advantageously, the number of the vinyl group of per molecule compound (B) and per molecule compound (A) are bonded to silicon atom The sum of the number of hydrogen atom be at least 4.

Advantageously, by compound (A) with a certain amount of addition, so that being bonded to the hydrogen atom of silicon atom in compound (A) Total amount and all ethylenically unsaturated groups in compound (B) total amount between range of the molecular proportion 1/1 to 20/1 It is interior.

Compound (C) is the catalyst for cross-linking reaction, and especially chloroplatinic acid, chloroplatinic acid-alkene complex, chlorine Platinic acid-alkenyl siloxane complex compound, chloroplatinic acid-diketone complex compound, platinum black and Supported Pt Nanoparticles.

The compound (A) of every 1000 parts by weight and the total amount of compound (B), catalyst (C) as clean platinum Additive amount is preferably that 0.1 parts by weight are to 1000 parts by weight and also better 1 parts by weight to 100 parts by weight.

The elastomer silicone of bound to polyglycerol according to the present invention usually at least one oil based on hydrocarbon and/or at least one Kind silicone oil is mixed to form gel.In these gels, the elastomer of bound to polyglycerol is usually in the form of aspherical particle.

Such elastomer is especially described in patent application WO 2004/024798.

As the elastomer silicone of bound to polyglycerol, the following compound with following INCI titles can be used:

- 3 cross-linked polymer of dimethyl silicone polymer/polyglycereol,

- 3 cross-linked polymer of lauryl dimethicone/polyglycereol,

And its mixture.

They are particularly sold by company, SHIN-ETSU HANTOTAI with following title:

KSG-INCI title: -3 cross-linked polymer of dimethyl silicone polymer/polyglycereol and dimethyl silicone polymer；

KSG-INCI title: -3 cross-linked polymer of mineral oil and lauryl dimethicone/polyglycereol；

KSG-INCI title: -3 cross-linked polymer of Permethyl 99A and lauryl dimethicone/polyglycereol；

KSG-INCI title: three isooctyl acid glyceride and lauryl dimethicone/polyglycereol -3 are crosslinked Polymer；

KSG-INCI title: -3 cross-linked polymer of shark alkane and lauryl dimethicone/polyglycereol.

Concrete form according to the present invention will select following item as emulsifier:

- PEG-30 dimerization hydroxy stearic acid ester；

And -4 diisopstearate of polyglycereol/poly- hydroxy stearic acid ester/sebacate；

And its mixture.

Additive

In addition, composition according to the present invention may be embodied in addition usually used in care product and/or cosmetics Agent, such as

Activator such as vitamin, such as vitamin A, E, C, B₃；Scutelloside or plant extracts containing the scutelloside, The especially root of the root of radix scutellariae (Chinese skullcap) and especially radix scutellariae (Scutellaria baicalensis) Plant extracts (INCI title: radix scutellariae root extract)；Moisturizer；

Remove β as previously described, the sun-screening agent except β-diphenylacrylate ester and the organic UV smoke agent for shielding of salicylate；

Filler；

Additional dyestuff；

And its mixture.

The property quality and quantity of additive present in composition according to the present invention is adjusted to those skilled in the art It is customary operations, so that therefore desired cosmetic property will not be affected.

A) additional UV smoke agent for shielding

Composition according to the present invention can also be selected from organic UV smoke agent for shielding and/or mineral opacifier containing one or more Additional UV smoke agent for shielding.

i)Organic UV smoke agent for shielding

Organic UV smoke agent for shielding is especially selected from Cinamic compounds；Dibenzoylmethane compounds；Anthranilate chemical combination Object；Benzylidene camphor compound；Benzophenone cpd；Triaizine compounds；Benzotriazole cpd is especially such as described in Silicone benzotriazole in patent EP 0392883, and such as it is described in application US 5 237 071, US 5 166 355, GB 2303549, the di-2-ethylhexylphosphine oxide in DE 197 26 184 and EP 893119 (hydroxy phenyl benzotriazole) compound；Benzal third Those of esterification closes object, especially referred in patent US 5 624 663；Benzimidizole derivatives；Imidazoline chemical combination Object；Double benzoxazoles based compounds, are such as described in patent EP 669323 and US 2 463 264；Benzoxazoles compound, It is such as described in patent application EP 0832642, EP 1027883, EP 1300137 and DE 10162844；Cover polymer With masking siloxanes, as specifically apply WO-93/04665 described in those of；Such as it is described in US 4 195 999, patent Apply for WO 2004/006878, patent application WO 2008/090066, WO 2011113718, WO 2009027258, WO 2013010590, IP COM disclosed in WO 2013011094, WO 2013011480 and file on 2 23rd, 2009 IP COM JOURNAL N ° 000182396D disclosed in JOURNAL N ° 000179675D, on April 29th, 2009,2009 years 11 IP COM Journal N ° disclosed in IP COM JOURNAL N ° 000189542D disclosed in months 12 days and on March 4th, 2004 Merocyanine compound and its mixture in IPCOM000011179D.

Those of as the example of organic light protective agent, it can be mentioned that hereafter indicated with its INCI title:

Dibenzoylmethane compounds

Butyl methoxydibenzoylmethise, especially by Royal DSM nutriment Co., Ltd with trade name ParsolSale；

Cinamic compounds:

Ethylhexyl methoxy cinnamate, especially by Royal DSM nutriment Co., Ltd with trade name Parsol Sale,

Methoxycinnamate isopropyl propionate,

Neo Heliopan E1000, by the fragrant company of moral with trade name Neo Heliopan ESale,

Benzophenone cpd:

Benzophenone-1, by BASF AG with trade name UvinulSale,

Benzophenone-2, by BASF AG with trade name Uvinul DSale,

Benzophenone-3 or Oxybenzone, by BASF AG with trade name Uvinul MSale,

UVINUL MS 40, by BASF AG with trade name Uvinul MSSale,

Benzophenone -5,

Benzophenone -6, by Nuo Karui company (Norquay) with trade name HelisorbSale,

Benzophenone -8, by American Cyanamid Company (American Cyanamid) with trade name Spectra-Sorb UV-Sale,

Benzophenone 9, by BASF AG with trade name Uvinul DSSale,

Benzophenone-1 2,

2- (4- diethylamino -2- hydroxy benzoyl) just own ester of benzoic acid, by BASF AG with trade name Uvinul ASale, or as the mixture with octyl methoxycinnamate with trade name Uvinul A Plus Sale,

1,1 '-(Isosorbide-5-Nitrae-piperazine diyl) is bis- [1- [2- [4- (diethylamino) -2- (2-hydroxybenzoyl)] phenyl] ketone] (CAS919803-06-8), it is such as described in patent application WO 20,07/,071 584；This compound is advantageously to be micronized shape Formula (0.02 to 2 μm of mean size) and the specifically use in the form of water-borne dispersions, which can such as basis Method of micronization described in patent application GB-A-2 303 549 and EP-A-893 119 obtains.

Benzylidene camphor compound:

3- Benzylidene camphor, by Qie Mansi company (Chimex) with title MexorylManufacture,

PARSOL 500, by Merck & Co., Inc. (Merck) with title EusolexSale,

Benzylidene camphor sulphonic acid, by Qie Si Mann with title MexorylManufacture,

Camphor benzene pricks ammonium methyl sulphate, by Qie Si Mann with title MexorylManufacture,

Terephthalidene Dicamphor Sulfonic Acid (terephthalylidenedicamphorsulfonic acid), by cutting This Mann is with title MexorylManufacture,

Polyacryl amide ylmethyl Benzylidene camphor, by Qie Mansi company with title MexorylManufacture.

Phenylbenzimidazol compound:

Phenylbenzimidazolesulfonic acid, especially by Merck & Co., Inc. with trade name EusolexSale.

Double benzoxazoles based compounds:

Neo Heliopan AP, by the fragrant company of moral with trade name Neo HeliopanSale.

Benzotriazole cpd

Drometrizole trisiloxanes, by Qie Mansi company with title MexorylManufacture；

Tinuvin 360 is especially in solid form, such as public by Fairmont chemistry (Fairmount Chemical) is taken charge of with trade name Mixxim BB/The product of sale, or in the aqueous of micronized particle The form of dispersion, these micronized particles have at 0.01 to 5 μm and 0.01 to 2 μm and more particularly more preferable Average particle size in 0.020 to 2 μ m, wherein at least one alkyl polyglucoside surfactant have a structure that

CnH_2n+1O(C₆H₁₀O₅)_xH, wherein n is 8 to 16 integer and x is (C₆H₁₀O₅) unit average degree of polymerization simultaneously And in the range of 1.4 to 1.6, such as it is described in patent GB-A-2303549, especially by BASF AG with trade name TinosorbSale, or the mono- (C of at least one in the polyglycereol with the glycerol polymerization degree for being at least 5₈-C₂₀) alkane In the presence of base ester in the form of the water-borne dispersions of micronized particle, these micronized particles have at 0.02 to 2 μm and Average particle size in more preferable 0.01 to 1.5 μm and more particularly 0.02 to 1 μ m is such as described in application WO2009/ Water-borne dispersions in 063392.

Triaizine compounds:

Tinosorb S, by BASF AG with trade name TinosorbSale,

Uvinul T 150, especially by BASF AG with trade name UvinulSale；

Diethylhexyl Butamido Triazon, by 3V Inc., Sigma (Sigma 3V) with trade name UvasorbSale,

The symmetrical triazine replaced by naphthyl group or polyphenyl group, is described in patent US 6 225 467, patent application WO 20,04/,085 412 (referring to compound 6 and 9) or file " Symmetrical Triazine Derivatives [symmetrical three Oxazine derivatives class] ", IP.COM IPCOM000031257 Journal, INC, the beautiful Etard of the Western Han Dynastry, USA New York (in September, 2004 20 days) in, especially 2,4,6- tri- (diphenyl) triazines and 2,4,6- tri- (terphenyl) triazines, also in patent application WO 06/ 035 000, WO 06/,034 982, WO 06/,034 991, WO 06/,035 007, WO2006/034 992 and WO 2006/ It is referred in 034 985, these compounds are advantageously with Micronised form (0.02 to 3 μm of average particle size) and especially with aqueous Dispersion uses, these compounds can for example basis be described in patent application GB-A-2 303 549 and EP-A-893 119 Method of micronization obtains；

The silicone triazine replaced by two aminobenzoic acid ester groups, is such as described in patent EP 0 841 341, special It is not bis- (normal-butyl 4 '-amino toluenyl malonic ester) -6- [(3- { 1,3,3,3- tetramethyl -1- [(the trimethyl first silicon of 2,4- Alkyl) oxygroup] disilicon malignant alkyl } propyl) amino]-s-triazine.

O-amino benzoyl acid compound:

Menthyl anthranilate, by the fragrant company of moral with trade name Neo HeliopanSale.

Imidazolinium compounds:

Dimethoxybenzyliden dioxoimidazolidin propionic acid ethylhexyl,

Toluenyl malonic ester compound:

Polysiloxane containing toluenyl malonic ester functional group, such as Dimethicodiethylbenzalmalonate, by Royal DSM nutriment Co., Ltd is with trade name ParsolSale.

Benzoxazoles compound:

2,4- bis- [5- (1,1- dimethyl propyl) benzoxazoles -2- base (4- phenyl) imino group] -6- (2- ethylhexyl) Imino group -1,3,5-triazines, by 3V Inc., Sigma with title UvasorbSale.

ii)Mineral UV smoke agent for shielding

Used mineral UV smoke agent for shielding is metal oxide pigment according to the present invention.It is highly preferred that mineral of the invention UV smoke agent for shielding be have following Average Element granular size metal oxide particle: less than or be equal to 0.5 μm, more preferably 0.005 to 0.5 μm, even more preferably 0.01 to 0.2 μm, also better 0.01 to 0.1 μm and more particularly 0.015 to 0.05 μm。

They can in particular selected from titanium oxide, zinc oxide, iron oxide, zirconium oxide and cerium oxide, or mixtures thereof.

Such coating or uncoated metal oxide pigment are described in patent application EP-A-0 518 773.It can mention And commercial pigment include by Sa Qibin pigment company (Sachtleben Pigments), ICI Imperial Chemical Industries (Tayca), silent The product of gram company and goldschmidt chemical corporation (Degussa) sale.

These metal oxide pigments can be coating or uncoated.

The pigment of coating is to have carried out the one of chemistry, electronics, mechanochemistry and/or engineering properties with multiple compounds Kind or the pigment of a variety of surface treatments, these compounds are that for example amino acid, beeswax, fatty acid, fatty alcohol, anionic surface are living Property agent, lecithin, the sodium of fatty acid, potassium, zinc, iron or aluminium salt, metal (titanium or aluminium) alcoholates, polyethylene, siloxanes, albumen Matter (collagen, elastin laminin), alkanolamine, Si oxide, metal oxide or calgon.

The pigment more specifically titanium oxide of these coatings, these titanium oxides are coated with following item:

Silica such as comes from the product of Ikeda company (Ikeda)

Silica and iron oxide, such as from the product Sunveil of company Ikeda

Silica and aluminium oxide, such as the product Microtitanium Dioxide MT from ICI Imperial Chemical Industries 500 With Microtitanium Dioxide MT 100 SA, and from titanium dioxide company (Tioxide) Tioveil,

Aluminium oxide such as comes from the product Tipaque TTO-55 of Shi Yuan company (Ishihara)And Tipaque TTO-55And the UVT 14/4 from Sa Qibin pigment company,

Aluminium oxide and aluminum stearate, such as the product Microtitanium DioxideMT 100 from ICI Imperial Chemical IndustriesMT 100MT 100And MT-Product Solaveil from advantageous Keimar Corp. (Uniqema) CT-10With Solaveil CTAnd the product E usolex T- from Merck & Co., Inc.

Silica, aluminium oxide and alginic acid, such as the product MT-100 from ICI Imperial Chemical Industries

Aluminium oxide and Aluminum trilaurate, such as the product Microtitanium Dioxide MT from ICI Imperial Chemical Industries 100

Iron oxide and ferric stearate, such as the product Microtitanium Dioxide MT from ICI Imperial Chemical Industries 100

Zinc oxide and zinc stearate, such as the product BR from ICI Imperial Chemical Industries

Silica and aluminium oxide and with silicone-treated, such as the product Microtitanium from ICI Imperial Chemical Industries Dioxide MT 600Microtitanium Dioxide MT 500Or Microtitanium Dioxide MT 100

It silica, aluminium oxide and aluminum stearate and is handled with siloxanes, such as comes from Industrial Corporation of titanium The product STT-30- of (Titan Kogyo)

It silica and is handled with siloxanes, such as from the product UV-Titan X of Sa Qibin pigment company

It aluminium oxide and is handled with siloxanes, such as product Tipaque TTO-55 from Shi Yuan companyOr Product UV Titan M from Sa Qibin pigment company

Triethanolamine, such as the product STT-65-S from Industrial Corporation of titanium,

Stearic acid, such as the product Tipaque TTO-55 from Shi Yuan company

Calgon, such as the product Microtitanium Dioxide MT 150 from ICI Imperial Chemical Industries

The TiO that octyl trimethyl silane treatment is crossed₂, by Degussa silica company (Degussa Silices) with quotient Name of an article TSale,

The processed TiO of dimethyl silicone polymer₂, by capable company, section (Cardre) with 70250 Cardre of trade name UFSale,

The processed anatase/rutile TiO of polydimethylhydrogensiloxane₂, by colour technology company (Color Techniques) with trade name Microtitanium Dioxide USP GradeSale.

It can also refer to doped at least one transition metal such as TiO of iron, zinc or manganese and more specifically manganese₂Face Material.Preferably, the pigment of the doping is in the form of oil dispersion.The oil being present in oil dispersion is preferably selected from glycerol Those of three esters, including capric acid/octanoic acid.The oil dispersion of titanium dioxide granule also may include one or more dispersing agents, example Such as sorbitan ester, such as the polyoxyalkylenated aliphatic ester of Sorbitan isostearate or glycerol, such as TRI- PPG-3 myristyl ether citrate and the poly- monoricinolein of polyglyceryl -3.Preferably, the oil dispersion of titanium dioxide granule At least one dispersing agent comprising the polyoxyalkylenated aliphatic ester selected from glycerol.It can more particularly refer in TRI-PPG-3 meat In the presence of myristyl ether citrate and the poly- ricinoleate ester of polyglyceryl -3 and sorbitan isostearate, doping There is the TiO of manganese₂Oil dispersion of the particle in capric acid/Trivent OCG, the oil dispersion have following INCI title: - 3 ricinoleate ester of titanium dioxide (and) TRI-PPG-3 myristyl ether citrate (and) polyglyceryl (and) Sorbitan Alcohol isostearate, such as by standing grain major company with trade name OptisolThe product of sale.

Uncoated titanium oxide pigments are for example by ICI Imperial Chemical Industries with trade name Microtitanium Dioxide MT 500B or Microtitanium Dioxide MT 600By goldschmidt chemical corporation with title P 25, You Wake company (Wackherr) with title Transparent Titanium OxideBy Miyoshi Kasei Inc with titleBy Tomen company (Tomen) with titleAnd by titanium dioxide company with title Tioveil AQ sale 's.

Uncoated zinc oxide pigment is, for example:

- You Weijie scientific & technical corporation (Sunsmart) is with those of title Z-Cote sale；

By Hai Mingsi company (Elementis) with titleThose of sale；

By nanometer top-quality technologies company (Nanophase Technologies) with title Nanogard WCD Those of sale.

The zinc oxide pigment of coating is, for example:

By Toshiba (Toshibi) with title Zinc Oxide CS-Those of sale is (with poly- methyl hydrogen SiClx The ZnO of oxygen alkane coating)；

By nanometer top-quality technologies company with title Nanogard Zinc OxideThose of sale is (in FinsolvIt is in 40% dispersion in benzoic acid C12-C15 Arrcostab)；

By Japanese great Dong company (Daito) with title Daitopersion Zn-And DaitopersionZn- (dispersion in cyclopolymethyl siloxane/oxyethylation dimethyl silicone polymer contains 30% or 50% for those of sale The zinc oxide coated with silica and poly- methylhydrogensiloxane)；

By big King Company (Daikin) with title NFD UltrafineThose of sale (uses perfluoroalkyl phosphate The ZnO of ester and the copolymer coating based on perfluor alkyl ethide, as the dispersion in cyclopentasiloxane)；

By company, SHIN-ETSU HANTOTAI with title SPD-Those of sale (is coated with the acrylate copolymer of silicone graft ZnO is dispersed in ring dimethyl siloxane)；

By ISP company with title Escalol(ZnO that alumina treatment is crossed, is dispersed in methoxy for those of sale In base 2-Ethylhexyl cinnamate/PVP- hexadecene copolymer/polymethyl siloxane mixture)；

By Fu Ji pigment company (Fuji Pigment) with title Fuji ZnO-SMS-Those of sale (uses dioxy The ZnO of SiClx and poly methyl silsesquioxane coating)；

By Hai Mingsi company with title Nanox GelThose of sale (is dispersed in 55% concentration with hydroxyl The benzoic acid C of base stearic acid condensation polymer₁₂-C₁₅ZnO in Arrcostab).

Uncoated cerium oxide pigment may, for example, be by Luo Na-Rhone-Poulenc (- Poulenc) with title Colloidal CeriumThose of sale.

Uncoated iron oxide pigment is for example by Arnold company (Arnaud) with title Nanogard WCD (FE)、Nanogard Iron FE 45BL AQ、Nanogard FE 45RWith Nanogard WCD (FE) or by Mitsubishi (Mitsubishi) with title TY-Sale.

The iron oxide pigment of coating is for example by Arnold company with title Nanogard WCD 2008 (FE 45B FN)Nanogard WCD(FE 45B)、Nanogard FE 45BLWith Nanogard FE 45Or by BASF AG with title Transparent IronSale.

It can also refer to the mixture of the mixture of metal oxide, especially titanium dioxide and ceria, including with The titanium dioxide of silicon dioxide coating and ceria etc. weight mixture (by Ikeda company with title Sunveil Sale), and the mixture of also useful aluminium oxide, the titanium dioxide of silica and silicone coated and zinc oxide, such as by Sa The product M of its guest's pigment company saleOr titanium dioxide and titanium dioxide with the coating of aluminium oxide, silica and glycerol The mixture of zinc, the product M sold such as Sa Qibin pigment company

According to the present invention, the coating particularly preferably based on titanium oxide or uncoated mineral smoke agent for shielding.

b)Filler

Composition according to the present invention can also include at least one organic or mineralogical property filler, can especially give They are matt, cover, the complementary characteristic of persistence and/or improved stability.

Term " filler " is understood to mean that any type of nothing in the insoluble form being dispersed in the medium of composition Color or white solid particle.These mineral or the particle of organic nature give composition main body or rigidity and/or give cosmetics Flexibility and uniformity.

It can have stratiform, spherical, spherical or fibers form for the filler in composition according to the present invention or at this The intermediate of any other form between a little finite forms.

Filler according to the present invention may or may not be what surface coated, and particularly they can use silicon Ketone, amino acid, fluorinated derivatives promote any other substance of filler dispersion in the composition and compatibility to carry out table Surface treatment.

It can be mentioned that the example of mineral filler include talcum, mica, silica, hollow silica microsphere, kaolinite Soil, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, glass or ceramic microcapsules or silica and titanium dioxide it is compound Object, such as the TSG series by Nippon Sheet Glass Co Ltd's sale.

It can be mentioned that the example of organic filler include polyamide powder (from atropic company (Atochem)Orgasol), polyethylene powders, polymethylmethacrylate powder, polytetrafluoroethylene (PTFE) (Teflon) powder, propylene Acid copolymer powder (Polytrap from Dow Corning Corporation), lauroyl lysine, polymeric hollow microsphere such as gather inclined dichloro Those of ethylene/propene nitrile (such as Expancel (Nobel industrial group (Nobel Industrie)), hexa-methylene two are different Cyanate/trihydroxy methyl hexyl lactone copolymer powder (plastic powders from Mei Xi company), silicone resin microbeads (such as come From the Tospearl of Toshiba (Toshiba)), synthesis or naturally be micronized wax, derived from containing 8 to 22 carbon atoms and It is preferred that metallic soap (such as zinc stearate, magnesium stearate, lithium stearate, the zinc laurate of the organic carboxyl acid of 12 to 18 carbon atoms Or magnesium myristate,It is L 200 (Kai Mudaier company (Chemdal Corporation)), (outstanding with silicone resin It is with silsesquioxane resins) powder of the elastomer organopolysiloxane of the crosslinking of coating is (as being for example described in patent US 5 In 538 793), polyurethane powder be especially include copolymer cross-linked polyurethane powder, the copolymer include three hydroxyls Methylhexyl lactone.It can be especially hexamethylene diisocyanate/trihydroxy methyl hexyl lactone polymer.Such particle is outstanding It is for example with title Plastic Powder D-Or Plastic Powder D-And its happiness of mixture U.S. is public Department is commercially available.It may also is that cellulose powder, as Japanese great Dong company sells in Cellulobeads series Product.

According to a particular embodiment of the invention, the composition includes the elasticity of at least one crosslinking coated with silicone resin Body organopolysiloxane powder.

Term " organopolysiloxane elastomers " or " silicone elastomer " mean it is with viscoplasticity and especially to have Have the softness of the consistency of sponge or soft ball, crosslinking, deformable organopolysiloxane.Its elasticity modulus is so that this material It withstands and deforms and there is limited extensibility and shrinkage.This material can restore its original-shape after stretching, extension.

Such elastomer powder is by company, SHIN-ETSU HANTOTAI with title KSP-KSP-KSP-KSP-KSP-And KSP-Sale, and there is INCI title: vinyldimethicone/poly- methyl Siloxanes silsequioxane crosspolymers.

It can also refer to:

With the elastomer organopolysiloxane powder for the crosslinking that silicone resin coats, the mixing of fluoroalkyl-functional is such as used The powder of silicone, especially by company, SHIN-ETSU HANTOTAI with names KSP-Sale, and there is INCI title: trifluoro propyl Dimethyl silicone polymer/vinyl trifluoro propyl dimethyl silicone polymer/silsequioxane crosspolymers；Or

The powder for using the mixing silicone of phenyl functionalization, especially by company, SHIN-ETSU HANTOTAI with title KSP-Sale, and With INCI title: diphenyl dimethicone/vinyl diphenyl dimethyl silicone polymer/silsesquioxane crosslinking is poly- Close object.

According to advantageous embodiment, composition according to the present invention includes the organic poly- silicon coated with silsesquioxane resins Oxygen alkane elastomer powder, with INCI title vinyldimethicone/methicone silesquioxane crosslinking Polymer, such as with title KSP-Those of sale.

Relative to the total weight of the composition, one or more organopolysiloxane elastomers coated with silicone resin The content that powder can be by weight 0.5% to 12%, advantageously by weight 1% to 8% with range exists.

c)Additional dyestuff

Composition according to the present invention can also include at least one other dyestuff, and preferably its ratio be relative to combination The total weight of object by weight at least 0.01%.

For obvious cause, the color provided about the intensity of desired color effects and the dyestuff by being considered is strong Degree, this amount is easy to change significantly, and its adjustment is clearly fallen in the limit of power of those skilled in the art.

Be suitable for the invention additional dyestuff can be it is water-soluble, it is also possible to be fat-soluble.

For purposes of the present invention, term " water-soluble dye " means any natural or synthesis usually organicization Object is closed, it is soluble in the miscible solvent of water phase or water and can assign color.

As the water-soluble dye suitable for the present invention, it is particularly possible to refer to synthesis or natural water-soluble dye, Such as FDC is red 4, DC is red 6, DC is red 22, DC is red 28, DC is red 30, DC is red 33, DC orange 4, DC Huang 5, DC Huang 6, DC Huang 8, FDC are green 3, DC is green 5, FDC indigo plant 1, betanin (beet root), famille rose, copper chlorophyllin, methylene blue, anthocyanin (desugar oenine (enocianin), black carrot, the rose of Sharon, elder (elder)), caramel colorant (caramel) and riboflavin.

These water-soluble dyes are such as beet root juice and caramel.

For purposes of the present invention, term " lipid-soluble dye " means any natural or synthesis usually organicization Close object, it is oily mutually or can be miscible with fatty material solvent in be soluble and color can be assigned.

As being suitable for the invention lipid-soluble dye, can specifically mentioned synthesis or natural lipid-soluble dye, example As DC is red 17, DC is red 21, DC is red 27, DC is green 6, DC Huang 11, DC violet 2, DC orange 5, tonyred, carrotene (β-carrot Element, lycopene), lutein (capsanthin, capsorubin, lutein), palm oil, sudan brown, quinoline yellow, roucou and Curcumin.

Cosmetic composition

The invention further relates to the makeups in a kind of medium acceptable in a physiologically including composition as defined above Product composition.

Term " physiologically acceptable medium " is intended to indicate that especially suitable for applying composition according to the present invention In the medium of skin.

Physiologically acceptable medium typically be adapted to the property for the supporter that composition must be applied thereto and It is further adapted to the appearance that composition must be packaged.

Using

According to one embodiment, composition of the invention can be advantageously in for skin and/or keratin fiber, body The form for the composition that body or face, particularly face are nursed.

According to another embodiment, composition of the invention can be advantageously in for keratin material, particularly body The form for the composition that the skin of body or face, particularly face is made up.

Therefore, subpattern according to this embodiment, composition of the invention can be advantageously in cream base compositions before adornment Form.

Composition of the invention can be advantageously in the form of foundation cream.

Another subpattern according to this embodiment, composition of the invention can be advantageously in for skins and especially It is the form for the composition that face is made up.Therefore it can be eye shadow or face powder.

This composition is prepared in particular according to the general knowledge of those skilled in the art.

In the whole instruction (including claims), term " including/kind " is interpreted as and " including at least one A/kind " synonymous, unless otherwise specified.

Unless otherwise specified, term " ... with ... between " and " range be from ... extremely ... " be understood to include Limiting value.

The present invention is described in more detail by example and attached drawing presented below.Unless otherwise specified, shown amount with Weight percent indicates.

Example: in water/fat liquor form foundation cream

Preparation method

The preparation of aqueous phase B:

In glass beaker: being under stiring dissolved in water niacinamide using bar magnet, add caffeine then to obtain Then clear solution adds scutelloside to obtain pH and is 4.7 clear yellow transparent solution, and then adds MgSO₄Salt, Propylene glycol and phenoxetol, to obtain the clear yellow transparent solution that pH is 4.75.

The preparation of oily phase A:

In capsule, a part of silicone (twice of clay amount) is taken out, to soak clay with flexible spatula,

On hot plate, in main beaker, by ethylhexyl salicylate and PEG-30 dimerization hydroxy stearic acid ester and Isolan GPS is heated at about 55 DEG C, until PEG-30 dimerization hydroxy stearic acid ester melts, and then sun-proof by other two kinds of addition Agent (temperature is down to about 30 DEG C) cools down mixture, and adds remaining silicone.

Emulsification:

Water phase is added to the white that concentration is obtained in oily phase bit by bit under stiring using Moritz mixer Alkali improves mixing speed and stirs mixture 10 minutes until obtaining fluid mixture.It will modified clay and volatile silicone oils Mixture be added in white alkali, gained mixture is vigorously stirred in the turbine with activated clay very much, and is allowed to Stirring 15 minutes until mixture retrogradation.KSP 100 is added under stiring using Moritz mixer, and mixture is placed 10 minutes until its retrogradation.Vitamin E is added, and then adds pigment, until colour developing is good.Then the preparation is carried out Defoaming.

The scheme of effect is covered for evaluating in vitro SPF

According to by B.L.Diffey in J.Soc.Cosmet.Chem. [cosmetic chemistry magazine] 40,127-133, (1989) Described in in-vitro method measure sun protection factor.Use the UV-2000 spectrophotometric for coming from Lan Fei Optical Co., Ltd (Labsphere) Meter measures.Composition by it is uniform and even in the form of deposit with ratio 1mg/cm²It is applied to the slab of PMMA.

External sun protection factor SPF is 78.91 ± 19.85.

The composition of acquisition provides good light protection (SPF > 30), be under room temperature (20 DEG C -25 DEG C) it is stable and With uniform appearance (the good compatibility of Cyanide Dioctyl Acrylate in non-annularity volatile silicone oils).When being applied to skin When skin, observe good slipping and good organoleptic attribute be such as not present greasy effect, there is no film to feel on skin with And slim and graceful effect.

Claims

1. a kind of composition especially includes physiologically acceptable medium, particularly for coating keratin material, particularly Ground is made up and/or is nursed for keratin material such as skin, and the composition includes:

A) oiliness continuous phase, and

B) at least one organic UV covers agent composition, which includes:

(ii) the UV smoke agent for shielding of at least one salicylate type；And

C) at least one non-annularity volatile silicone oils；And

D) at least one pigment.

2. composition according to claim 1, wherein relative to the total weight of the composition, the organic UV of liquid is hidden The concentration for covering agent composition is by weight at least 15% and more preferably concentration is by weight at least 20%.

3. composition according to claim 1 or 2, wherein relative to the total weight of the composition, the organic UV of liquid Masking agent composition concentration range be by weight 15% to 40% and more preferably range be by weight 20% to 30%.

4. composition according to any one of the preceding claims, wherein the β, β-diphenylacrylate esters type UV Smoke agent for shielding is compound Octocrylene or Cyanide Dioctyl Acrylate.

5. composition according to any one of the preceding claims, wherein the UV smoke agent for shielding of the salicylate type is choosing From:

Heliophan,

Ethylhexyl salicylate,

And its mixture.

6. composition according to any one of the preceding claims, wherein relative to the total weight of the composition, the present invention The total concentration preferred scope of oily phase of composition be by weight 30% to 95% and particularly range is by weight 50% to 70%.

7. composition according to any one of the preceding claims, wherein the non-annularity volatile silicone oils are to be selected from:

The acyclic straight polysiloxanes of formula (II):

R₃SiO-(R₂SiO)_n-SiR₃ (II)

Wherein R can be identical or different, indicate:

The saturated or unsaturated group based on hydrocarbon contains 1 to 10 carbon atom and preferably 1 to 6 carbon atom, optionally Ground replaces by one or more fluorine atoms or by one or more hydroxyls, or

Hydroxyl,

One of group R may be phenyl,

N is the integer that range is 0 to 8, preferred scope is 2 to 6 and also better range is 3 to 5, the polysiloxanes of formula (II) Compound contains no more than 15 carbon atoms,

The polysiloxanes of the branch of lower formula (III) or (IV):

R₃SiO-[(R₃SiO)RSiO]-(R₂SiO)x-SiR₃ (III)

[R₃SiO]₄Si (IV)

Wherein R can be identical or different, indicate:

The saturated or unsaturated group based on hydrocarbon contains 1 to 10 carbon atom, optionally by one or more fluorine atoms Or replaced by one or more hydroxyls, or

Hydroxyl,

One of group R may be phenyl,

X is the integer that range is 0 to 8,

The polysiloxane compound of the formula (III) or (IV) contain no more than 15 carbon atoms.

8. composition according to any one of the preceding claims, wherein the non-annularity volatile silicone oils have at 25 DEG C Having range is 0.5 to 8 centistoke (0.5 to 8mm²/ s) viscosity.

9. composition according to any one of the preceding claims, wherein the non-annularity volatile silicone oils are straight chains, and And it is chosen more particularly from octamethyltrisiloxane, decamethyl tetrasiloxane and ten dimethyl, five siloxanes and its mixture, and Five siloxanes of more particularly ten dimethyl.

10. composition according to any one of the preceding claims, wherein the non-annularity volatile silicone oils/β, β-hexichol The weight ratio of base acrylate/salicylate masking agent composition is greater than or equal to 0.5, more preferably equal to or greater than 0.7, more Especially 0.5 to 3 and be also better 0.7 to 1.5.

11. composition according to any one of the preceding claims, the composition includes relative to the total of the composition The pigment of weight at least 5%, more preferably by weight 5% to 25% pigment, particularly by weight 10% to 30% and preferably by weight 10% to 20% pigment.

12. composition according to any one of the preceding claims, the composition includes at least one at least one parent The pigment of the iron oxide and/or titanium dioxide of lipid or the pigment of hydrophobic compound coating, especially hydrophobicity coating.

13. composition according to any one of claim 1 to 12, the composition is in the form of anhydrous composition.

14. composition according to any one of claim 1 to 12, the composition is in the form of water-in-oil emulsion.

15. composition according to any one of the preceding claims, the composition is in the form of foundation cream.

16. a kind of method for coating keratin material, more specifically to keratin material such as skin carry out makeup and/ Or the method for nursing, which is characterized in that this method includes to keratin material application such as according to claim 1 to any in 15 Composition defined in.