CN110396457A - 一种防串色洗衣凝珠及其制备方法 - Google Patents
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Abstract
一种防串色洗衣凝珠及其制备方法,涉及洗衣凝珠技术领域。该防串色洗衣凝珠由以下组分制备得到:表面活性剂、生物活性酵素、脂肪酶、蛋白酶、无磷硬水软化剂、椰油酸酯、香料、肽。本发明制备的防串色洗衣凝珠采用的生物活性酵素含有生物活性酶和植物精华,具有防串色的功能,以及添加的脂肪酶和蛋白酶能够协同生物活性酵素起到护衣护色和防染色的作用,同时还具有亲肤柔软无刺激的特点。
Description
技术领域
本发明涉及洗衣凝珠技术领域,特别是涉及一种防串色洗衣凝珠及其制备方法。
背景技术
洗衣凝珠,亦称洗衣珠,是一种创新性的洗衣产品,因外形似珠子,而得名为洗衣凝珠。洗衣凝珠采用水溶膜包裹浓缩洗涤剂,遇水则溶,使用时无需剪开外膜,专为机洗设计,操作简单,方便不脏手,小小一颗洗衣凝珠能洗一筒衣服。
中国发明专利申请(申请号CN201510437124.0申请日2015.07.23)公开了一种多功能洗衣凝珠,其重量百分比组分包括:C14-16烯烃磺酸钠30-35%、脂肪醇聚氧乙烯醚(9EO)15-20%、十二烷基苯磺酸10-12%、阳离子烷基多糖苷5-8%、乙二胺四乙酸二钠0.01-0.03%、D-泛醇1-2%、苯氧乙醇0.3-0.7%、香精0.1-0.3%、三氯生0.05-0.1%、蛋白酶0.01-0.03%、余量为去离子水。该产品具有洗涤、护理、杀菌、消臭、愉悦身心多重功效,节能减排,使用方便。但该专利申请主要有效成分为采用大量的表面活性剂C14-16烯烃磺酸钠、脂肪醇聚氧乙烯醚和十二烷基苯磺酸,并未有其他有效的添加物,对于脱色的衣物无法起到防串色的效果,这样就造成洗衣凝珠的洗涤功能等级不高,及其洗涤功能相对较单一,无法满足需求。
发明内容
本发明的目的在于避免现有技术中的不足之处而提供一种防串色洗衣凝珠,该防串色洗衣凝珠具有防串色,护衣护色,防染色的作用。该发明的第二个目的是提供上述防串色洗衣凝珠的制备方法。
本发明的目的通过以下技术方案实现:
提供一种防串色洗衣凝珠,包括以下按质量百分比计的组分:表面活性剂50-70%、生物活性酵素5-12%、脂肪酶3-10%、蛋白酶5-12%、无磷硬水软化剂2-6%、椰油酸酯3-13%、香料0.5-2%、肽3-6%。
进一步的,所述防串色洗衣凝珠包括以下按质量百分比计的组分:表面活性剂55-65%、生物活性酵素6-8%、脂肪酶5-8%、蛋白酶6-8%、无磷硬水软化剂3-5%、椰油酸酯6-10%、香料1-1.8%、肽4-5%。
进一步的,所述表面活性剂为十二烷基苯磺酸钠与月桂醇聚氧乙烯醚硫酸钠复配,十二烷基甜菜碱与直链烷基苯磺酸酸钠复配,脂肪酸钠与脂肪醇聚氧乙烯醚复配中的一种或多种混合,也可以是上述材料和其复配中的一种或多种混合。
进一步的,所述生物活性酵素为采用葡萄柚、山茶和无患子中的一种或多种原料进行发酵制得,采用的生物活性酵素含有生物活性酶和植物精华,具有防串色的功能。
进一步的,所述脂肪酶为番木瓜脂肪酶、花生脂肪酶和白地霉脂肪酶中的一种或多种混合,其中添加的脂肪酶能够协同生物活性酵素,起到护衣护色和防染色的作用,同时还亲肤柔软无刺激。
进一步的,所述蛋白酶为木瓜蛋白酶、中性蛋白酶和糜蛋白酶中的一种或多种混合,其中添加的蛋白酶,能够协同生物活性酵素,起到护衣护色和防染色的作用,同时还亲肤柔软无刺激。
进一步的,所述无磷硬水软化剂为沸石、磺化煤和硬脂酸钠中的一种或多种混合,能够在保证软化水体作用的情况下对环境无污染。
提供一种防串色洗衣凝珠的制备方法,包括以下步骤:
1)将表面活性剂、生物活性酵素和椰油酸酯按顺序依次加入,然后搅拌混合后进行冷却至其温度低于20℃;
2)将脂肪酶、蛋白酶和肽按顺序依次加入上述混合物中,然后搅拌混合静止至其温度为室温;
3)将无磷硬水软化剂和香料加入上述混合物中,然后搅拌混合使用水溶膜包裹制成洗衣凝珠。
进一步的,所述水溶膜中添加有苦味剂,防止老人儿童误食。
进一步的,所述水溶膜为淀粉、聚乙烯醇和聚丙烯酸中的一种或多种混合。
本发明的有益效果:采用的生物活性酵素含有生物活性酶和植物精华,具有防串色的功能,以及添加的脂肪酶和蛋白酶能够协同生物活性酵素起到护衣护色和防染色的作用,同时还具有亲肤柔软无刺激的特点。
附图说明
图1是本发明实施例1、2、3中制得的洗衣凝珠与标准洗衣液按照AATCC61-水洗色牢度的要求对比结果图。
图2是本发明实施例1、2、3中制得的洗衣凝珠按照GB/T 13174-2008的要求稀释5倍后与标准洗衣液对比结果图。
具体实施方式
实施例1
一种防串色洗衣凝珠,包括以下按质量百分比计的组分:十二烷基苯磺酸钠与月桂醇聚氧乙烯醚硫酸钠复配剂62%、无患子活性酵素7%、番木瓜脂肪酶8%、木瓜蛋白酶8%、硬脂酸钠3%、椰油酸酯6.5%、香料1%、肽4.5%。
一种防串色洗衣凝珠的制备方法,包括以下步骤:
1)将十二烷基苯磺酸钠与月桂醇聚氧乙烯醚硫酸钠复配剂、无患子活性酵素和椰油酸酯按顺序依次加入,然后搅拌混合后进行冷却至其温度低于20℃;
2)将番木瓜脂肪酶、木瓜蛋白酶和肽按顺序依次加入上述混合物中,然后搅拌混合静止至其温度为室温;
3)将硬脂酸钠和香料加入上述混合物中,然后搅拌混合使用水溶膜包裹制成洗衣凝珠。
实施例2
一种防串色洗衣凝珠,包括以下按质量百分比计的组分:十二烷基甜菜碱与直链烷基苯磺酸酸钠复配剂30%、脂肪酸钠与脂肪醇聚氧乙烯醚复配剂31%、山茶活性酵素3%、无患子活性酵素4%、花生脂肪酶4%、白地霉脂肪酶4%、中性蛋白酶3%、糜蛋白酶3 %、沸石1.5%、硬脂酸钠1.5%、椰油酸酯8.5%、香料1.5%、肽5%。
一种防串色洗衣凝珠的制备方法,包括以下步骤:
1)将十二烷基甜菜碱与直链烷基苯磺酸酸钠复配剂、脂肪酸钠与脂肪醇聚氧乙烯醚复配剂、山茶活性酵素、无患子活性酵素和椰油酸酯按顺序依次加入,然后搅拌混合后进行冷却至其温度低于20℃;
2)将花生脂肪酶、白地霉脂肪酶、中性蛋白酶、糜蛋白酶和肽按顺序依次加入上述混合物中,然后搅拌混合静止至其温度为室温;
3)将沸石、硬脂酸钠和香料加入上述混合物中,然后搅拌混合使用水溶膜包裹制成洗衣凝珠。
实施例3
一种防串色洗衣凝珠,包括以下按质量百分比计的组分:十二烷基苯磺酸钠15%、直链烷基苯磺酸酸钠20%、脂肪醇聚氧乙烯醚25%、葡萄柚活性酵素3%、山茶活性酵素3%、无患子活性酵素3%、番木瓜脂肪酶3%、花生脂肪酶1%、白地霉脂肪酶1%、木瓜蛋白酶3%、中性蛋白酶2%、糜蛋白酶2%、沸石1%、磺化煤1%、硬脂酸钠1%、椰油酸酯10%、香料2%、肽4%。
一种防串色洗衣凝珠的制备方法,包括以下步骤:
1)将十二烷基苯磺酸钠、直链烷基苯磺酸酸钠、脂肪醇聚氧乙烯醚、葡萄柚活性酵素、山茶活性酵素、无患子活性酵素和椰油酸酯按顺序依次加入,然后搅拌混合后进行冷却至其温度低于20℃;
2)将番木瓜脂肪酶、花生脂肪酶、白地霉脂肪酶、木瓜蛋白酶、中性蛋白酶、糜蛋白酶和肽按顺序依次加入上述混合物中,然后搅拌混合静止至其温度为室温;
3)将沸石、磺化煤、硬脂酸钠和香料加入上述混合物中,然后搅拌混合使用水溶膜包裹制成洗衣凝珠。
实验例:
按照AATCC61-水洗色牢度的要求,将实施例1、2、3中制得的洗衣凝珠与标准洗衣液对比,得到的结果如图1所示。
按照GB/T 13174-2008的要求,将实施例1、2、3中制得的洗衣凝珠稀释5倍后与标准洗衣液对比,得到的结果如图2所示。
通过上述对比实验可以看出,本发明洗衣凝珠具有良好的防串色功能,其去污性能也能够满足GB/T 13174-2008国家标准。
最后应当说明的是,以上实施例仅用以说明本发明的技术方案,而非对本发明保护范围的限制,尽管参照较佳实施例对本发明作了详细地说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的实质和范围。
Claims (10)
1.一种防串色洗衣凝珠,其特征在于:包括以下按质量百分比计的组分:表面活性剂50-70%、生物活性酵素5-12%、脂肪酶3-10%、蛋白酶5-12%、无磷硬水软化剂2-6%、椰油酸酯3-13%、香料0.5-2%、肽3-6%。
2.如权利要求1所述的一种防串色洗衣凝珠,其特征在于:包括以下按质量百分比计的组分:表面活性剂55-65%、生物活性酵素6-8%、脂肪酶5-8%、蛋白酶6-8%、无磷硬水软化剂3-5%、椰油酸酯6-10%、香料1-1.8%、肽4-5%。
3.如权利要求1-2任一项所述的一种防串色洗衣凝珠,其特征在于:所述表面活性剂为十二烷基苯磺酸钠与月桂醇聚氧乙烯醚硫酸钠复配,十二烷基甜菜碱与直链烷基苯磺酸酸钠复配,脂肪酸钠与脂肪醇聚氧乙烯醚复配中的一种或多种混合,也可以是上述材料和其复配中的一种或多种混合。
4.如权利要求1-2任一项所述的一种防串色洗衣凝珠,其特征在于:所述生物活性酵素为采用葡萄柚、山茶和无患子中的一种或多种原料进行发酵制得。
5.如权利要求1-2任一项所述的一种防串色洗衣凝珠,其特征在于:所述脂肪酶为番木瓜脂肪酶、花生脂肪酶和白地霉脂肪酶中的一种或多种混合。
6.如权利要求1-2任一项所述的一种防串色洗衣凝珠,其特征在于:所述蛋白酶为木瓜蛋白酶、中性蛋白酶和糜蛋白酶中的一种或多种混合。
7.如权利要求1-2任一项所述的一种防串色洗衣凝珠,其特征在于:所述无磷硬水软化剂为沸石、磺化煤和硬脂酸钠中的一种或多种混合。
8.如权利要求1-2任一项所述的一种防串色洗衣凝珠的制备方法,其特征在于:包括以下步骤:
1)将表面活性剂、生物活性酵素和椰油酸酯按顺序依次加入,然后搅拌混合后进行冷却至其温度低于20℃;
2)将脂肪酶、蛋白酶和肽按顺序依次加入上述混合物中,然后搅拌混合静止至其温度为室温;
3)将无磷硬水软化剂和香料加入上述混合物中,然后搅拌混合使用水溶膜包裹制成洗衣凝珠。
9.如权利要求8所述的一种防串色洗衣凝珠的制备方法,其特征在于:所述水溶膜中添加有苦味剂。
10.如权利要求8所述的一种防串色洗衣凝珠的制备方法,其特征在于:所述水溶膜为淀粉、聚乙烯醇和聚丙烯酸中的一种或多种混合。
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