CN110358641A - A kind of multifunction surface cleaning agent and preparation method thereof - Google Patents
A kind of multifunction surface cleaning agent and preparation method thereof Download PDFInfo
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- CN110358641A CN110358641A CN201910685864.4A CN201910685864A CN110358641A CN 110358641 A CN110358641 A CN 110358641A CN 201910685864 A CN201910685864 A CN 201910685864A CN 110358641 A CN110358641 A CN 110358641A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/004—Surface-active compounds containing F
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
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Abstract
The invention discloses a kind of multifunction surface cleaning agents and preparation method thereof.The multifunction surface cleaning agent includes following raw material according to parts by weight: 120~180 parts of anionic surfactant, 90~110 parts of nonionic surfactant, 10~30 parts of amphoteric surfactant, 20~40 parts of acid amide type surfactant, 40~60 parts of fluorine richness glucoside, 0~10 part of amino acid perfluoro hexyl polyoxyethylene ether, 0~15 part of amino acid fullerene polyoxyethylene ether, 0~5 part of the fungicide, 0~5 part of preservative, 0~5 part of essence, 650 parts of water.Fatty acid of the invention introduces fluorine-containing surfactant and hydrophilic radical, the acid amide type surfactant of formation by chemical modification, it arranges in pairs or groups again various surfactants, manufactured multifunction surface cleaning agent cleaning effect is good, no pollution to the environment, it is not damaged to the clean object of institute to no damage to human body.
Description
Technical field
The present invention relates to cleaning agent technical field, in particular to a kind of multifunction surface cleaning agent and preparation method thereof.
Background technique
Currently, the use scope of cleaning agent is being gradually expanded, by being conventionally used to washing clothing, cleaning furniture and apparatus,
Such as plastic cement, optical glass lens, metal product (copper, iron, aluminium, steel, alloy) material clean areal stretch into industrial trade
The cleaning of the various greasy dirts, spot, grease such as oil, cutting oil, antirust oil, lubricating oil, punching oil.At this stage, for guarantor and
The safety of equipment, cleaning agent is also very extensive in the fields application such as electric appliance, instrument, distribution box, tableware, food, fruits and vegetables, in order to full
Cleaning requirement of the sufficient different field to cleaning agent, more stringent requirements are proposed to cleaning agent by people, and not requiring nothing more than it has preferably
Dirt-removing power, also require its environment-friendly degradable, antibacterial and cleaning effect and high-efficient.
Traditional cleaning agent integrally deoils in the prior art, and ability is poor, and cleaning action is unobvious, hurts hand and can increase pair
The oxidation and corrosiveness of the surface to be cleaned, have serious corrosivity, and biological non-degradable also has one to environment and human body
Fixed harmfulness.
Summary of the invention
The purpose of the present invention is intended to provide a kind of multifunction surface cleaning agent and preparation method thereof, is asked with solving above-mentioned technology
Topic.
To achieve the goals above, the technical solution of the present invention is as follows:
In a first aspect, a kind of multifunction surface cleaning agent provided by the invention, including raw material as follows according to parts by weight:
120~180 parts of anionic surfactant, 90~110 parts of nonionic surfactant, 10~30 parts of amphoteric surfactant,
20~40 parts of acid amide type surfactant, 40~60 parts of fluorine richness glucoside, amino acid perfluoro hexyl polyoxyethylene ether 0~
10 parts, 0~15 part of amino acid fullerene polyoxyethylene ether, 0~5 part of fungicide, 0~5 part of preservative, 0~5 part of essence, water
650 parts.
Preferably, the nonionic surfactant is selected from fatty alcohol polyoxyethylene ether AEO-3, fatty alcohol polyoxyethylene ether
One of AEO-7, fatty alcohol polyoxyethylene ether AEO-9, fatty alcohol polyoxyethylene ether JFC or a variety of.
Preferably, the anionic surfactant is selected from dodecyl sodium sulfate, fatty alcohol phosphate, fatty alcohol polyoxy
One of ethylene ether sodium sulfate, soap lye are a variety of.
Preferably, the amino acid perfluoro hexyl polyoxyethylene ether is to be made using following methods: being weighed following by weight
Measure the raw material of number meter: 00~200 part of amino acid 1,5~20 parts of perfluoro hexyl glycol, 50~150 parts of dimethylformamide, complete
0.1~1 part of fluoroalkyl sulfonic acids, -300 parts of polyethylene glycol 200, by amino acid, perfluoro hexyl glycol, dimethylformamide, perfluor
4~8 hours addition polyethylene glycol are reacted at 60~75 DEG C after alkyl sulfonic acid mixing, are cooled to 60~75 DEG C, and it is anti-to continue heat preservation
It answers 8-10 hours, obtains amino acid perfluoro hexyl polyoxyethylene ether.
Preferably, the amino acid fullerene polyoxyethylene ether be using following methods be made: weigh it is following by weight
The raw material of number meter: 300~400 parts of amino acid, 10~30 parts of polyhydroxy fullerene, 400~500 parts of dimethylformamide, complete
0.1~1 part of fluoroalkyl sulfonic acids, polyethylene glycol 400~500 part, by amino acid, polyhydroxy fullerene, dimethylformamide, perfluor
It is reacted 4~8 hours at 80~120 DEG C after alkyl sulfonic acid mixing, adds polyethylene glycol, 60~75 DEG C are cooled to, after continuation of insurance
Temperature reaction 8~10 hours, obtains amino acid fullerene polyoxyethylene ether.
Preferably, the acid amide type surfactant is to be made using following methods: weigh it is following according to parts by weight
Raw material: 400~500 parts of fatty acid, 220~240 parts of aminated compounds, 0.1~1 part of catalyst, 40~82 parts of boric acid, nonionic
0~10 part of fluorocarbon surfactant, 160~260 parts of polyhydric alcohol polymer；By formula ratio, by fatty acid, aminated compounds, urge
Agent sequentially adds in reaction kettle, under the protection of inert gas, is warming up to 140~180 DEG C, is stirred to react 2~5 hours, takes out
Vacuum heat-preserving 2~4 hours, temperature was cooled to not higher than 100 DEG C, boric acid is added, is stirred to react 3~5 hours, adds nonionic
Fluorocarbon surfactant, polyhydric alcohol polymer are stirred to react 3~5 hours, and acid amide type surfactant is made.
It is further preferred that the fatty acid is selected from one of cottonseed oil, butter, lauric acid, oleic acid, stearic acid or more
Kind.
It is further preferred that the aminated compounds is selected from hydroxyethyl ethylenediamine, diethylenetriamine, propane diamine, diethanol
One of amine, triethanolamine, triethylene tetramine, tetraethylenepentamine are a variety of.
It is further preferred that the polyhydric alcohol polymer is selected from one of polyethylene glycol, polypropylene glycol, polyoxyethylene oxypropylene
Or it is a variety of.
Preferably, the structural formula of the fluorine richness glucoside is as follows:Wherein ,-R1It is the alkyl of 3~18 carbon for carbon chain lengths；-R2For
For one of following structural:
n1、n2、n3、n3For positive integer, n1=3~18, n2=3~18, n3=12~18, n4
=3~9.
Compared with prior art, the beneficial effects of the present invention are:
In the inventive solutions, fatty acid (such as cottonseed oil, butter) introduces fluorochemical surface by chemical modification
Activating agent and hydrophilic radical, the acid amide type surfactant of formation, then arrange in pairs or groups fluorine richness glucoside, anion surface active
Agent, nonionic surfactant, amphoteric surfactant, manufactured multifunction surface cleaning agent cleaning effect is good, to environment without
Pollution, not damaged to the clean object of institute to no damage to human body, Biodegradation Times are short, and biological degradation rate is 95% or more.
Specific embodiment
Specific embodiments of the present invention will be further explained below.It should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but and does not constitute a limitation of the invention.In addition, invention described below
Technical characteristic involved in each embodiment can be combined with each other as long as they do not conflict with each other.
In a first aspect, a kind of multifunction surface cleaning agent provided by the invention, including raw material as follows according to parts by weight:
120~180 parts of anionic surfactant, 90~110 parts of nonionic surfactant, 10~30 parts of amphoteric surfactant,
20~40 parts of acid amide type surfactant, 40~60 parts of fluorine richness glucoside, amino acid perfluoro hexyl polyoxyethylene ether 0~
10 parts, 0~15 part of amino acid fullerene polyoxyethylene ether, 0~5 part of fungicide, 0~5 part of preservative, 0~5 part of essence, water
650 parts.
In embodiments of the present invention, the nonionic surfactant is selected from fatty alcohol polyoxyethylene ether AEO-3, fat
One of alcohol polyoxyethylene ether AEO-7, fatty alcohol polyoxyethylene ether AEO-9, fatty alcohol polyoxyethylene ether JFC or a variety of.
In embodiments of the present invention, the anionic surfactant is selected from dodecyl sodium sulfate, fatty alcohol phosphoric acid
One of ester, sodium sulfate of polyethenoxy ether of fatty alcohol, soap lye are a variety of.
In embodiments of the present invention, the preservative is butyl p-hydroxybenzoate.
In embodiments of the present invention, the fungicide is isothiazolinone.
In embodiments of the present invention, the amino acid perfluoro hexyl polyoxyethylene ether is to be made using following methods:
Weigh following raw materials according to parts by weight: 00~200 part of amino acid 1,5~20 parts of perfluoro hexyl glycol, dimethylformamide
50~150 parts, 0.1~1 part of perfluoro alkyl sulfonic acid, -300 parts of polyethylene glycol 200, by amino acid, perfluoro hexyl glycol, dimethyl
4~8 hours addition polyethylene glycol are reacted at 60~75 DEG C after formamide, perfluoro alkyl sulfonic acid mixing, are cooled to 60~75 DEG C,
Continue insulation reaction 8-10 hours, obtains amino acid perfluoro hexyl polyoxyethylene ether.
In embodiments of the present invention, the amino acid fullerene polyoxyethylene ether is to be made using following methods: being claimed
Take following raw materials according to parts by weight: 300~400 parts of amino acid, 10~30 parts of polyhydroxy fullerene, dimethylformamide
400~500 parts, 0.1~1 part of perfluoro alkyl sulfonic acid, polyethylene glycol 400~500 part, by amino acid, polyhydroxy fullerene, diformazan
It is reacted 4~8 hours at 80~120 DEG C after base formamide, perfluoro alkyl sulfonic acid mixing, adds polyethylene glycol, be cooled to 60
~75 DEG C, continues insulation reaction 8~10 hours, obtain amino acid fullerene polyoxyethylene ether.
In embodiments of the present invention, the acid amide type surfactant be using following methods be made: weigh it is following by
The raw material of parts by weight meter: 400~500 parts of fatty acid, 220~240 parts of aminated compounds, 0.1~1 part of catalyst, boric acid 40
~82 parts, 0~10 part of non-ion fluorin carbon surface active agent, 160~260 parts of polyhydric alcohol polymer；By formula ratio, by fatty acid,
Aminated compounds, catalyst sequentially add in reaction kettle, under the protection of inert gas, are warming up to 140~180 DEG C, stirring is anti-
It answers 2~5 hours, vacuumizes heat preservation 2~4 hours, be cooled to temperature not higher than 100 DEG C, boric acid is added, it is small to be stirred to react 3~5
When, non-ion fluorin carbon surface active agent, polyhydric alcohol polymer are added, is stirred to react 3~5 hours, it is living that acid amide type surface is made
Property agent.
It is understood that in this embodiment, fatty acid (such as glucose, cottonseed oil, butter) and amine chemical combination
After object carries out amide reaction, then boronation is carried out with boric acid and is reacted, finally carry out condensation reaction with fluorocarbon surfactant etc. and obtain
To acid amide type surfactant of the invention, this surfactant has excellent cleaning function, acidproof, alkaline-resisting, with other
Surfactant compatibility is good.
Further, the fatty acid is selected from one of cottonseed oil, butter, lauric acid, oleic acid, stearic acid or a variety of.
Further, the aminated compounds is selected from hydroxyethyl ethylenediamine, diethylenetriamine, propane diamine, diethanol amine, three
One of ethanol amine, triethylene tetramine, tetraethylenepentamine are a variety of.
Further, the inert gas is selected from one of nitrogen, argon gas, helium or a variety of.
Further, the fluorocarbon surfactant is non-ion fluorin carbon surface active agent, is made using following methods:
After phenol, hexafluoropropene compound, alkalescent catalyst are mixed, is reacted at 50~100 DEG C, add dense sulphur
Acid is heated to 90~130 DEG C of sulfonating reactions, adds organic solvent, reacts under conditions of 50~100 DEG C and fluorocarbon surface is made
The molar ratio of activating agent, the phenol and hexafluoropropylene dimmer is 1:1；Sulfuric acid and hexafluoropropene dimerization in the concentrated sulfuric acid
The molar ratio of body is 1:1.
Further, the hexafluoropropene compound is selected from hexafluoropropene monomer, hexafluoropropylene dimmer, hexafluoropropene
One of tripolymer is a variety of.
Further, the quality of the alkalescent catalyst is the 0.5~10% of the phenol quality.
Further, the organic solvent is selected from one of ethylene oxide, propane, polyalcohol or a variety of.
Further, the polyhydric alcohol polymer is selected from one of polyethylene glycol, polypropylene glycol, polyoxyethylene oxypropylene or more
Kind.
Further, the molecular weight of the polyhydric alcohol polymer is 200~1000.
In embodiments of the present invention, the structural formula of the fluorine richness glucoside is as follows:Wherein ,-R1It is the alkyl of 3~18 carbon for carbon chain lengths；-R2For
For one of following structural:
n1、n2、n3、n3For positive integer, n1=3~18, n2=3~18, n3=12~18,
n4=3~9.
In embodiments of the present invention, the multifunction surface cleaning agent, including raw material as follows according to parts by weight: ten
50 parts of dialkyl sulfonates, 650 parts of water, 40 parts of fluorine richness glucoside, 40 parts of acid amide type surfactant, fatty alcohol polyoxy second
70 parts of alkene ether JFC, 10 parts of beet alkali ampholytic surface active agent, 40 parts of fatty alcohol polyoxyethylene ether AEO-9, fatty alcohol polyoxy second
100 parts of alkene ether sodium sulfate, 2 parts of fungicide, 1 part of preservative, 3 parts of essence.
In embodiments of the present invention, the multifunction surface cleaning agent, including raw material as follows according to parts by weight: ten
50 parts of dialkyl sulfonates, 650 parts of water, 60 parts of fluorine richness glucoside, 20 parts of acid amide type surfactant, fatty alcohol polyoxy second
50 parts of alkene ether JFC, 30 parts of beet alkali ampholytic surface active agent, 40 parts of fatty alcohol polyoxyethylene ether AEO-9, fatty alcohol polyoxy second
100 parts of alkene ether sodium sulfate, 2 parts of fungicide, 1 part of preservative, 3 parts of essence.
In embodiments of the present invention, the multifunction surface cleaning agent, including raw material as follows according to parts by weight: ten
50 parts of dialkyl sulfonates, 650 parts of water, 60 parts of fluorine richness glucoside, 20 parts of acid amide type surfactant, fatty alcohol polyoxy second
50 parts of alkene ether JFC, 30 parts of beet alkali ampholytic surface active agent, 40 parts of fatty alcohol polyoxyethylene ether AEO-9, fatty alcohol polyoxy second
100 parts of alkene ether sodium sulfate, 5 parts of amino acid perfluoro hexyl polyoxyethylene ether, 2 parts of fungicide, 1 part of preservative, 3 parts of essence.
In the present embodiment, the multifunction surface cleaning agent, including raw material as follows according to parts by weight: dodecane
50 parts of base sodium sulfonate, 650 parts of water, 40 parts of fluorine richness glucoside, 40 parts of acid amide type surfactant, fatty alcohol polyoxyethylene ether
70 parts of JFC, 10 parts of beet alkali ampholytic surface active agent, 40 parts of fatty alcohol polyoxyethylene ether AEO-9, fatty alcohol polyoxyethylene ether
100 parts of sodium sulphate, 10 parts of amino acid fullerene polyoxyethylene ether, 2 parts of fungicide, 1 part of preservative, 3 parts of essence.
The embodiment of the present invention is further described below.
The molecular structural formula of fluorine richness glucoside in following example 1~8 are as follows:Wherein ,-R1It is the alkyl of 12 carbon for carbon chain lengths；-R2For for
One of following structural:
n1=6.
Fluorocarbon surfactant in following embodiment is non-ion fluorin carbon surface active agent, is made using following methods:
After phenol, hexafluoropropylene dimmer, alkalescent catalyst are mixed, is reacted at 50~100 DEG C, add dense sulphur
Acid is heated to 90~130 DEG C of sulfonating reactions, adds ethylene oxide, reacts under conditions of 50~100 DEG C and fluorocarbon surface is made
The molar ratio of activating agent, the phenol and hexafluoropropylene dimmer is 1:1；Sulfuric acid and hexafluoropropene dimerization in the concentrated sulfuric acid
The molar ratio of body is 1:1；The quality of the alkalescent catalyst is the 0.8% of the phenol quality；The ethylene oxide and institute
The molar ratio for stating hexafluoropropylene dimmer is 44:60.
Amino acid perfluoro hexyl polyoxyethylene ether in following embodiment is to be made using following methods: weigh it is following by
The raw material of parts by weight meter: 50 parts of amino acid 1,10 parts of perfluoro hexyl glycol, 100 parts of dimethylformamide, perfluoro alkyl sulfonic acid
0.5 part, 250 parts of Macrogol 600, after amino acid, perfluoro hexyl glycol, dimethylformamide, perfluoro alkyl sulfonic acid are mixed
6 hours addition Macrogol 600s are reacted at 75 DEG C, are cooled to 70 DEG C, are continued insulation reaction 9 hours, are obtained amino acid perfluor
Hexyl polyoxyethylene ether.
Amino acid fullerene polyoxyethylene ether in following embodiment is to be made using following methods: being weighed following by weight
The raw material of amount number meter: 350 parts of amino acid, 20 parts of polyhydroxy fullerene, 450 parts of dimethylformamide, perfluoro alkyl sulfonic acid 0.6
Part, 450 parts of Macrogol 600, by amino acid, polyhydroxy fullerene, dimethylformamide, perfluoro alkyl sulfonic acid mix after
It is reacted 4~8 hours at 80~120 DEG C, adds Macrogol 600, be cooled to 70 DEG C, continued insulation reaction 9 hours, obtain ammonia
Base acid fullerene polyoxyethylene ether.
Embodiment 1
A kind of preparation method of multifunction surface cleaning agent provided in this embodiment, includes the following steps:
(1) in 1000L stainless steel cauldron, cottonseed oil 500Kg, hydroxyethyl ethylenediamine 120Kg, divinyl are sequentially added
Triamine 120Kg, catalyst 0.8Kg are passed through nitrogen, open stirring, react 4 hours under the conditions of 145~160 DEG C, and it is small to evacuate 3
When, 100 DEG C are cooled to, boric acid 82Kg is added, reacts 4 hours, adds non-ion fluorin carbon surface active agent 10Kg, polyethylene glycol
(molecular weight 600) 160Kg, cooling discharge after reaction 4 hours, obtains acid amide type surfactant；
(2) in 1000L steeliness blender, dodecyl sodium sulfate 50Kg, water 650Kg is added, after dissolution, fluorine is added
Modified glucose glycosides 40Kg, the resulting acid amide type surfactant 40Kg of step (1), fatty alcohol polyoxyethylene ether JFC 70Kg,
Beet alkali ampholytic surface active agent 10Kg, fatty alcohol polyoxyethylene ether AEO-9 40Kg, sodium sulfate of polyethenoxy ether of fatty alcohol
(AES) 100Kg, fungicide 2Kg, preservative 1Kg, essence 3Kg stir 4 hours and discharge, obtain multifunction surface cleaning agent.
Embodiment 2
A kind of preparation method of multifunction surface cleaning agent provided in this embodiment, includes the following steps:
(1) in 1000L enamel reaction still, sequentially add oleic acid 200Kg, butter 200Kg, hydroxyethyl ethylenediamine 240Kg,
It is passed through nitrogen, catalyst 0.8Kg is added, stirring is opened, is reacted 4 hours under the conditions of 140~160 DEG C, is evacuated 3 hours, cooling
To 90 DEG C, boric acid 50Kg is added, reacts 3 hours, adds polyethylene glycol (molecular weight 400) 260Kg, reaction is dropped after 4 hours
Temperature discharging, obtains acid amide type surfactant；
(2) in 1000L steeliness blender, dodecyl sodium sulfate 50Kg, water 650Kg is added, after dissolution, fluorine is added
Modified glucose glycosides 60Kg, the resulting acid amide type surfactant 20Kg of step (1), fatty alcohol polyoxyethylene ether JFC 50Kg,
Beet alkali ampholytic surface active agent 30Kg, fatty alcohol polyoxyethylene ether AEO-7 40Kg, sodium sulfate of polyethenoxy ether of fatty alcohol
(AES) 100Kg, fungicide 2Kg, preservative 1Kg, essence 3Kg stir 4 hours and discharge, obtain multifunction surface cleaning agent.
Embodiment 3
The step of beneficial effect in order to further illustrate the present invention, repetition above-described embodiment 1 (1), acid amide type table is made
Dodecyl sodium sulfate 70Kg, water 650Kg is added in 1000L steeliness blender in face activating agent, after dissolution, fluorine is added and changes
Property glucoside 55Kg, the resulting acid amide type surfactant 25Kg of step (1), fatty alcohol polyoxyethylene ether JFC 40Kg, sweet tea
Dish alkali amphoteric surfactant 18Kg, fatty alcohol polyoxyethylene ether AEO-7 50Kg, sodium sulfate of polyethenoxy ether of fatty alcohol (AES)
50Kg, fungicide 2Kg, preservative 1Kg, essence 3Kg stir 4 hours and discharge, obtain multifunction surface cleaning agent.
Embodiment 4
The step of beneficial effect in order to further illustrate the present invention, repetition above-described embodiment 1 (1), acid amide type table is made
Dodecyl sodium sulfate 80Kg, water 650Kg is added in 1000L steeliness blender in face activating agent, after dissolution, fluorine is added and changes
Property glucoside 45Kg, the resulting acid amide type surfactant 22Kg of step (1), fatty alcohol polyoxyethylene ether JFC 50Kg, sweet tea
Dish alkali amphoteric surfactant 15Kg, fatty alcohol polyoxyethylene ether AEO-7 50Kg, sodium sulfate of polyethenoxy ether of fatty alcohol (AES)
100Kg, fungicide 2Kg, preservative 1Kg, essence 3Kg stir 4 hours and discharge, obtain multifunction surface cleaning agent.
Embodiment 5
The step of beneficial effect in order to further illustrate the present invention, repetition above-described embodiment 1 (1), acid amide type table is made
Dodecyl sodium sulfate 90Kg, water 650Kg is added in 1000L steeliness blender in face activating agent, after dissolution, fluorine is added and changes
Property glucoside 50Kg, the resulting acid amide type surfactant 27Kg of step (1), fatty alcohol polyoxyethylene ether JFC 40Kg, sweet tea
Dish alkali amphoteric surfactant 20Kg, fatty alcohol polyoxyethylene ether AEO-7 70Kg, sodium sulfate of polyethenoxy ether of fatty alcohol (AES)
70Kg, fungicide 2Kg, preservative 1Kg, essence 3Kg stir 4 hours and discharge, obtain multifunction surface cleaning agent.
Embodiment 6
The step of beneficial effect in order to further illustrate the present invention, repetition above-described embodiment 2 (1), acid amide type table is made
Dodecyl sodium sulfate 70Kg, water 650Kg is added in 1000L steeliness blender in face activating agent, after dissolution, fluorine is added and changes
Property glucoside 55Kg, the resulting acid amide type surfactant 23Kg of step (1), fatty alcohol polyoxyethylene ether JFC 60Kg, sweet tea
Dish alkali amphoteric surfactant 27Kg, fatty alcohol polyoxyethylene ether AEO-7 50Kg, sodium sulfate of polyethenoxy ether of fatty alcohol (AES)
100Kg, fungicide 2Kg, preservative 1Kg, essence 3Kg stir 4 hours and discharge, obtain multifunction surface cleaning agent.
Embodiment 7
The step of beneficial effect in order to further illustrate the present invention, repetition above-described embodiment 2 (1), acid amide type table is made
Dodecyl sodium sulfate 90Kg, water 650Kg is added in 1000L steeliness blender in face activating agent, after dissolution, fluorine is added and changes
Property glucoside 45Kg, the resulting acid amide type surfactant 27Kg of step (1), fatty alcohol polyoxyethylene ether JFC 55Kg, sweet tea
Dish alkali amphoteric surfactant 25Kg, fatty alcohol polyoxyethylene ether AEO-7 55Kg, sodium sulfate of polyethenoxy ether of fatty alcohol (AES)
90Kg, fungicide 2Kg, preservative 1Kg, essence 3Kg stir 4 hours and discharge, obtain multifunction surface cleaning agent.
Embodiment 8
The step of beneficial effect in order to further illustrate the present invention, repetition above-described embodiment 2 (1), acid amide type table is made
Dodecyl sodium sulfate 60Kg, water 650Kg is added in 1000L steeliness blender in face activating agent, after dissolution, fluorine is added and changes
Property glucoside 50Kg, the resulting acid amide type surfactant 30Kg of step (1), fatty alcohol polyoxyethylene ether JFC 55Kg, sweet tea
Dish alkali amphoteric surfactant 20Kg, fatty alcohol polyoxyethylene ether AEO-7 45Kg, sodium sulfate of polyethenoxy ether of fatty alcohol (AES)
90Kg, fungicide 2Kg, preservative 1Kg, essence 3Kg stir 4 hours and discharge, obtain multifunction surface cleaning agent.
Embodiment 9
Beneficial effect in order to further illustrate the present invention, using with it is above-mentioned be prepared by the similar preparation method of embodiment 1
Multifunction surface cleaning agent, the present embodiment and the difference of embodiment 1 are only that: the molecule of the fluorine richness glucoside of the present embodiment
Structural formula are as follows:
Wherein ,-R1It is the hydrocarbon of 12 carbon for carbon chain lengths
Base；-R2For for following structural:
n1=
3。
Embodiment 10
Beneficial effect in order to further illustrate the present invention, using with it is above-mentioned be prepared by the similar preparation method of embodiment 1
Multifunction surface cleaning agent, the present embodiment and the difference of embodiment 1 are only that: the molecule of the fluorine richness glucoside of the present embodiment
Structural formula are as follows:
Wherein ,-R1It is the hydrocarbon of 12 carbon for carbon chain lengths
Base；-R2For for following structural:
n1=
18。
Embodiment 11
Acid amide type surfactant is made in the step of repeating embodiment 1 (1), in 1000L steeliness blender, is added ten
After dissolution, fluorine richness glucoside 40Kg, the resulting acid amide type table of step (1) is added in dialkyl sulfonates 50Kg, water 650Kg
Face activating agent 40Kg, fatty alcohol polyoxyethylene ether JFC 70Kg, beet alkali ampholytic surface active agent 10Kg, aliphatic alcohol polyethenoxy
Ether AEO-9 40Kg, it sodium sulfate of polyethenoxy ether of fatty alcohol (AES) 100Kg, amino acid fullerene polyoxyethylene ether 10Kg, kills
Microbial inoculum 2Kg, preservative 1Kg, essence 3Kg stir 4 hours and discharge, obtain multifunction surface cleaning agent.
Embodiment 12
Acid amide type surfactant is made in the step of repeating embodiment 2 (1), in 1000L steeliness blender, is added ten
After dissolution, fluorine richness glucoside 60Kg, the resulting acid amide type table of step (1) is added in dialkyl sulfonates 50Kg, water 650Kg
Face activating agent 20Kg, fatty alcohol polyoxyethylene ether JFC 50Kg, beet alkali ampholytic surface active agent 30Kg, aliphatic alcohol polyethenoxy
Ether AEO-7 40Kg, sodium sulfate of polyethenoxy ether of fatty alcohol (AES) 100Kg, amino acid perfluoro hexyl polyoxyethylene ether 5Kg,
Fungicide 2Kg, preservative 1Kg, essence 3Kg stir 4 hours and discharge, obtain multifunction surface cleaning agent.
Comparative example 1
Beneficial effect in order to further illustrate the present invention, using with it is above-mentioned be prepared by the similar preparation method of embodiment 1
The difference of multifunction surface cleaning agent, this comparative example and embodiment 1 is only that: this comparative example is not added fluorine in step (2) and changes
Property glucoside.
Comparative example 2
Beneficial effect in order to further illustrate the present invention, using with the above-mentioned preparation side that be embodiment 1 step (2) similar
Method prepares multifunction surface cleaning agent, and the difference of this comparative example and embodiment 1 is only that: this comparative example adds not in step (2)
Enter acid amide type surfactant.
Effect example
Beneficial effect in order to further illustrate the present invention, to above-described embodiment 1~12 and the resulting table of comparative example 1~2
The detergency and biological degradation rate of face cleaning agent are tested, and the result of test is as follows:
The test data of each surface cleaner of table 1 counts
Above the embodiments of the present invention are described in detail, but the present invention is not limited to described embodiments.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more
Kind change, modification, replacement and modification, still fall in protection scope of the present invention.
Claims (10)
1. a kind of multifunction surface cleaning agent, which is characterized in that including raw material as follows according to parts by weight: anionic surface is living
Property 120~180 parts of agent, 90~110 parts of nonionic surfactant, 10~30 parts of amphoteric surfactant, acid amide type surface it is living
Property 20~40 parts of agent, 40~60 parts of fluorine richness glucoside, 0~10 part of amino acid perfluoro hexyl polyoxyethylene ether, amino acid
0~15 part of fullerene polyoxyethylene ether, 0~5 part of fungicide, 0~5 part of preservative, 0~5 part of essence, 650 parts of water.
2. multifunction surface cleaning agent according to claim 1, which is characterized in that the nonionic surfactant is selected from
Fatty alcohol polyoxyethylene ether AEO-3, fatty alcohol polyoxyethylene ether AEO-7, fatty alcohol polyoxyethylene ether AEO-9, fatty alcohol polyoxy
One of vinethene JFC or a variety of.
3. multifunction surface cleaning agent according to claim 1, which is characterized in that the anionic surfactant is selected from
One of dodecyl sodium sulfate, fatty alcohol phosphate, sodium sulfate of polyethenoxy ether of fatty alcohol, soap lye are a variety of.
4. multifunction surface cleaning agent according to claim 1, which is characterized in that the amino acid perfluoro hexyl polyoxy second
Alkene ether is to be made using following methods: weighing following raw materials according to parts by weight: 00~200 part of amino acid 1, perfluoro hexyl
5~20 parts of glycol, 50~150 parts of dimethylformamide, 0.1~1 part of perfluoro alkyl sulfonic acid, -300 parts of polyethylene glycol 200, by ammonia
It reacts 4~8 hours and is added at 60~75 DEG C after base acid, the mixing of perfluoro hexyl glycol, dimethylformamide, perfluoro alkyl sulfonic acid
Polyethylene glycol is cooled to 60~75 DEG C, continues insulation reaction 8-10 hours, obtains amino acid perfluoro hexyl polyoxyethylene ether.
5. multifunction surface cleaning agent according to claim 1, which is characterized in that the amino acid fullerene polyoxyethylene
Base ether is to be made using following methods: weigh following raw materials according to parts by weight: 300~400 parts of amino acid, and polyhydroxy fowler
10~30 parts of alkene, 400~500 parts of dimethylformamide, 0.1~1 part of perfluoro alkyl sulfonic acid, polyethylene glycol 400~500 part will
It is reacted 4~8 hours at 80~120 DEG C after amino acid, polyhydroxy fullerene, dimethylformamide, perfluoro alkyl sulfonic acid mixing,
Polyethylene glycol is added, is cooled to 60~75 DEG C, continues insulation reaction 8~10 hours, obtains amino acid fullerene polyoxyethylene
Base ether.
6. multifunction surface cleaning agent according to claim 1, which is characterized in that the acid amide type surfactant is to adopt
It is made with following methods: weighing following raw materials according to parts by weight: 400~500 parts of fatty acid, aminated compounds 220~240
Part, 0.1~1 part of catalyst, 40~82 parts of boric acid, 0~10 part of non-ion fluorin carbon surface active agent, polyhydric alcohol polymer 160~
260 parts；By formula ratio, fatty acid, aminated compounds, catalyst are sequentially added in reaction kettle, under the protection of inert gas,
140~180 DEG C are warming up to, is stirred to react 2~5 hours, is vacuumized 3 hours, temperature is cooled to not higher than 100 DEG C, boric acid is added,
It is stirred to react 3~5 hours, adds non-ion fluorin carbon surface active agent, polyhydric alcohol polymer, be stirred to react 3~5 hours, make
Obtain acid amide type surfactant.
7. multifunction surface cleaning agent according to claim 6, which is characterized in that the fatty acid is selected from cottonseed oil, ox
One of oil, lauric acid, oleic acid, stearic acid are a variety of.
8. multifunction surface cleaning agent according to claim 6, which is characterized in that the aminated compounds is selected from ethoxy
One of ethylenediamine, diethylenetriamine, propane diamine, diethanol amine, triethanolamine, triethylene tetramine, tetraethylenepentamine are more
Kind.
9. multifunction surface cleaning agent according to claim 6, which is characterized in that the polyhydric alcohol polymer is selected from poly- second
One of glycol, polypropylene glycol, polyoxyethylene oxypropylene are a variety of.
10. multifunction surface cleaning agent according to claim 1, which is characterized in that the knot of the fluorine richness glucoside
Structure formula is as follows:Wherein ,-R1It is 3~18 carbon for carbon chain lengths
Alkyl；-R2For for one of following structural:
n1、n2、n3、n3For positive integer, n1=3~18, n2=3~18, n3=12~18, n4
=3~9.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234965A (en) * | 2020-01-15 | 2020-06-05 | 东莞市四辉表面处理科技有限公司 | Novel oleic soap for efficient industrial wax removal and preparation method thereof |
| CN115161128A (en) * | 2022-08-09 | 2022-10-11 | 安徽安皓瑞科技有限公司 | Foamless high concentration sterilization type hard surface cleaning agent |
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| CN108610478A (en) * | 2018-04-04 | 2018-10-02 | 广州顺润新材料科技有限公司 | A kind of fluorine-containing alkyl glycosides and its preparation method and application |
| CN109321377A (en) * | 2018-10-26 | 2019-02-12 | 广东天仁科技有限公司 | A kind of acid amide type surfactant and its preparation method and application |
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2019
- 2019-07-28 CN CN201910685864.4A patent/CN110358641A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108610478A (en) * | 2018-04-04 | 2018-10-02 | 广州顺润新材料科技有限公司 | A kind of fluorine-containing alkyl glycosides and its preparation method and application |
| CN109321377A (en) * | 2018-10-26 | 2019-02-12 | 广东天仁科技有限公司 | A kind of acid amide type surfactant and its preparation method and application |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234965A (en) * | 2020-01-15 | 2020-06-05 | 东莞市四辉表面处理科技有限公司 | Novel oleic soap for efficient industrial wax removal and preparation method thereof |
| CN115161128A (en) * | 2022-08-09 | 2022-10-11 | 安徽安皓瑞科技有限公司 | Foamless high concentration sterilization type hard surface cleaning agent |
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