CN110358326A - 一种六铝酸钙蓝色陶瓷颜料及其制备方法 - Google Patents

一种六铝酸钙蓝色陶瓷颜料及其制备方法 Download PDF

Info

Publication number
CN110358326A
CN110358326A CN201910571341.7A CN201910571341A CN110358326A CN 110358326 A CN110358326 A CN 110358326A CN 201910571341 A CN201910571341 A CN 201910571341A CN 110358326 A CN110358326 A CN 110358326A
Authority
CN
China
Prior art keywords
ceramic pigment
blue
blue ceramic
calcium hexaluminate
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910571341.7A
Other languages
English (en)
Other versions
CN110358326B (zh
Inventor
宋希文
王青春
郭瑞
吴潇阳
郜健全
包金小
吕浩东
谢敏
周芬
杨皓
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Inner Mongolia University of Science and Technology
Original Assignee
Inner Mongolia University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inner Mongolia University of Science and Technology filed Critical Inner Mongolia University of Science and Technology
Priority to CN201910571341.7A priority Critical patent/CN110358326B/zh
Publication of CN110358326A publication Critical patent/CN110358326A/zh
Application granted granted Critical
Publication of CN110358326B publication Critical patent/CN110358326B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/44—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
    • C04B35/62675—Thermal treatment of powders or mixtures thereof other than sintering characterised by the treatment temperature
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/0009—Pigments for ceramics
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C01P2006/62—L* (lightness axis)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C01P2006/63—Optical properties, e.g. expressed in CIELAB-values a* (red-green axis)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/60—Optical properties, e.g. expressed in CIELAB-values
    • C01P2006/64—Optical properties, e.g. expressed in CIELAB-values b* (yellow-blue axis)
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C04B2235/3218—Aluminium (oxy)hydroxides, e.g. boehmite, gibbsite, alumina sol
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3279—Nickel oxides, nickalates, or oxide-forming salts thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

本发明公开了一种六铝酸钙蓝色陶瓷颜料及其制备方法，以价格低廉的氢氧化铝（Al(OH)3）、氢氧化钛（Ti(OH)4）、氧化镍（NiO）、碳酸钙为原料，制备蓝色陶瓷颜料，以解决钴蓝中钴价格昂贵的问题，制备的蓝色陶瓷颜料蓝度值b*达到‑37.07，与钴蓝b*值相近。

Description

一种六铝酸钙蓝色陶瓷颜料及其制备方法
技术领域
本发明属于陶瓷颜料及其制备领域，特别涉及一种六铝酸钙蓝色陶瓷颜料及其制备方法。
背景技术
钴蓝色泽鲜艳纯净，是一种色调非常饱和蓝色颜料，同时它的耐温性较高，可达1200-1400℃，是一般颜料望尘莫及的，可用于高温陶瓷色料、卷材涂料、高温涂料、聚烯烃、工程树脂、高级美术颜料以及彩石、水泥建材等行业；但其原材料需要用到大量的氧化钴或钴化合物，价格昂贵，工业级的氧化钴价格就可达人民币18万元/吨，生产成本较高，所以限制其无法在普通的领域得到广泛应用；因此迫切需要寻求一种色泽度和钴蓝相同的非钴的蓝色色料来解决以上问题；
六铝酸钙（CaAl12O19)具有较高的熔点，转熔点在1830℃以上，其高温稳定性好，并且抗碱性侵蚀能力强；它的晶体结构由含阳离子Ca的镜面和具有尖晶石结构的尖晶石基块两层沿着C轴交替堆积而成，CaAl12O19晶体中含有较多四面体和八面体，根据晶体学理论，四面体中d轨道的分裂能较小，电子跃迁吸收能量较小，可显示可见光的颜色，同时从价格上来说，目前氢氧化铝的价格只有人民币0.25万元/吨，而碳酸钙的价格更是仅仅为0.03万元/吨，远远低于氧化钴。
发明内容
本发明的目的在于提供一种六铝酸钙蓝色陶瓷颜料及其制备方法，应用价格低廉的原料制备蓝色陶瓷颜料，以解决钴蓝中钴价格昂贵的问题，其蓝度值b*达到与钴蓝相近的水平。
本发明采用的技术方案如下：一种六铝酸钙蓝色陶瓷颜料,其特征是，所述颜料的化学式为：
CaAl12-2xNixTixO19
化学式中所标注的均为物质的量比，其中0.6≤x≤1.0。
进一步，上述的六铝酸钙蓝色陶瓷颜料中的一种为：x的取值为0.6。
进一步，上述的六铝酸钙蓝色陶瓷颜料中的一种为：x的取值为0.8。
进一步，上述的六铝酸钙蓝色陶瓷颜料中的一种为：x的取值为1.0。
上述的六铝酸钙蓝色陶瓷颜料，其原材料包括：氢氧化铝（Al(OH)3）、氢氧化钛（Ti(OH)4）、氧化镍（NiO）、碳酸钙。
上述的六铝酸钙蓝色陶瓷颜料的制备方法，包括如下步骤：
（1）按CaAl12-2xNixTixO19中Ca、Al、Ni、Ti的化学计量比，分别称取氢氧化铝（Al(OH)3）、氢氧化钛（Ti(OH)4）、氧化镍（NiO）、碳酸钙，将上述原料装入球磨罐中，倒入无水乙醇球磨，得到混合均匀细化的浆料；
（2）将步骤（1）得到的浆料放入70℃-90℃环境（具体为80℃左右）的烘干箱中干燥；
（3）将步骤（2）干燥好的CaAl12-2xNixTixO19粉体放入箱式电子炉中进行加盖煅烧，温控制度为：从室温以5℃/分钟的速率升温至1000℃，之后以2℃/分钟的速率升温至1350℃，1350℃下保温3个小时，之后以100℃/h速率降温至室温，得到蓝色陶瓷颜料。
进一步，上述步骤（1）中原料总质量与无水乙醇的比为1:2。
进一步，上述步骤（1）中球磨时间为24小时。
本发明的有益效果在于：以价格低廉的氢氧化铝（Al(OH)3）、氢氧化钛（Ti(OH)4）、氧化镍（NiO）、碳酸钙为原料，制备蓝色陶瓷颜料，以解决钴蓝中钴价格昂贵的问题，制备的蓝色陶瓷颜料颜色基本达到钴蓝的颜色，特别是x=0.8的样品，其b值达到-37.07，与钴蓝蓝度值相当，同时明度值L*比现有钴蓝粉体高。
附图说明
图1为本发明制备方法步骤（3）中的温控制度图。
图2为本发明实施例1制备得到蓝色陶瓷颜料。
图3为本发明实施例2制备得到蓝色陶瓷颜料。
图4为本发明实施例3制备得到蓝色陶瓷颜料。
图5为现有钴蓝粉体的实物照。
图6为样品的紫外-可见漫反射光谱图。
具体实施方式
为了使本领域的技术人员更好地理解本发明的技术方案，下面将结合实施例对本发明作进一步的详细介绍，以下所述，仅用以说明本发明的技术方案而非限制。
实施例1
CaAl12-2xNixTixO19中x的取值为0.6的六铝酸钙蓝色陶瓷颜料的制备方法，包括如下步骤：
（1）按CaAl10.8Ni0.6Ti0.6O19中Ca、Al、Ni、Ti的化学计量比，分别称取氢氧化铝（Al(OH)3）、氢氧化钛（Ti(OH)4）、氧化镍（NiO）、碳酸钙，将上述原料装入球磨罐中，倒入无水乙醇球磨24小时，得到混合均匀细化的浆料；原料总质量与无水乙醇的比为1:2；
（2）将步骤（1）得到的浆料放入80℃左右环境的烘干箱中干燥；
（3）将步骤（2）干燥好的粉体放入箱式电子炉中进行加盖煅烧，温控制度为：从室温以5℃/分钟的速率升温至1000℃，然后以2℃/分钟的速率升温至1350℃，1350℃下保温3个小时，之后以100℃/h速率降温至室温，得到蓝色陶瓷颜料如图2所示。
实施例2
将实施例1中x的取值为0.8，采用相同制备方法制得的蓝色陶瓷颜料如图3所示。
实施例3
将实施例1中x的取值为1.0，采用相同制备方法制得的蓝色陶瓷颜料如图4所示。
对比分析
使用柯尼卡美能达色度计测量了CIELAB颜色参数，获得三个相关参数L*a*b*，分别表示为亮度，红色/绿色和黄色/蓝色色值；如图5所示为现有钴蓝粉体的实物照，其b*值为-38.19、明度值L*为53.98；上述3种陶瓷颜料的色度值如表1所示，可见x=0.6、0.8、1.0时其颜色基本达到钴蓝的颜色，特别是x=0.8的样品，其b值达到-37.07，与钴蓝蓝度值相当，同时明度值L*都比现有钴蓝粉体高；
利用分光光度计测量样品的紫外-可见漫反射光谱图如图6所示；曲线的反射率峰值所对应的波长色光的颜色即为该颜料的色相，而曲线反射率的高低表明了颜色的明度的不同。如图6所示，由于蓝色光的波长大致在450到480nm的范围内，由图可见所有样品的反射光谱峰的峰值都在这个范围内，同时本发明的颜料比钴蓝的反射率高，则表现出具有较高的明度，色彩更为鲜艳。
因此我们利用市场价格远远低于氧化钴的原料制备了蓝度值和钴蓝相当的蓝色陶瓷色料，有较好的应用前景。
表1x取不同值（x=0.6、0.8、1.0）时CaAl12-2xNixTixO19与现有钴蓝颜料的色度值对比表
。
尽管参照前述实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换，凡在本发明的精神和原则之内，所做的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (8)

1. 一种六铝酸钙蓝色陶瓷颜料,其特征是，所述颜料的化学式为：
CaAl12-2xNixTixO19
化学式中所标注的均为物质的量比，其中0.6≤x≤1.0。
2.根据权利要求1所述的六铝酸钙蓝色陶瓷颜料，其特征在于：x的取值为0.6。
3.根据权利要求1所述的六铝酸钙蓝色陶瓷颜料，其特征在于：x的取值为0.8。
4.根据权利要求1所述的六铝酸钙蓝色陶瓷颜料，其特征在于：x的取值为1.0。
5.根据权利要求1-4任一所述的六铝酸钙蓝色陶瓷颜料，其特征在于：其原材料包括：氢氧化铝（Al(OH)3）、氢氧化钛（Ti(OH)4）、氧化镍（NiO）、碳酸钙。
6.根据权利要求5所述的六铝酸钙蓝色陶瓷颜料的制备方法，其特征在于包括如下步骤：
按CaAl12-2xNixTixO19中Ca、Al、Ni、Ti的化学计量比，分别称取氢氧化铝（Al(OH)3）、氢氧化钛（Ti(OH)4）、氧化镍（NiO）、碳酸钙，将上述原料装入球磨罐中，倒入无水乙醇球磨，得到混合均匀细化的浆料；
将步骤（1）得到的浆料放入70℃-90℃环境的烘干箱中干燥；
将步骤（2）干燥好的CaAl12-2xNixTixO19粉体放入箱式电子炉中进行加盖煅烧，温控制度为：从室温以5℃/分钟的速率升温至1000℃，之后以2℃/分钟的速率升温至1350℃，1350℃下保温3个小时，之后以100℃/h速率降温至室温，得到蓝色陶瓷颜料。
7.根据权利要求6所述的六铝酸钙蓝色陶瓷颜料的制备方法，其特征在：步骤（1）中原料总质量与无水乙醇的比为1:2。
8.根据权利要求6所述的六铝酸钙蓝色陶瓷颜料的制备方法，其特征在：步骤（1）中球磨时间为24小时。
CN201910571341.7A 2019-06-28 2019-06-28 一种六铝酸钙蓝色陶瓷颜料的制备方法 Active CN110358326B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910571341.7A CN110358326B (zh) 2019-06-28 2019-06-28 一种六铝酸钙蓝色陶瓷颜料的制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910571341.7A CN110358326B (zh) 2019-06-28 2019-06-28 一种六铝酸钙蓝色陶瓷颜料的制备方法

Publications (2)

Publication Number Publication Date
CN110358326A true CN110358326A (zh) 2019-10-22
CN110358326B CN110358326B (zh) 2021-05-11

Family

ID=68215812

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910571341.7A Active CN110358326B (zh) 2019-06-28 2019-06-28 一种六铝酸钙蓝色陶瓷颜料的制备方法

Country Status (1)

Country Link
CN (1) CN110358326B (zh)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040470A (zh) * 2019-12-17 2020-04-21 佛山科学技术学院 一种蓝色无机颜料及其制备方法
WO2021179618A1 (zh) * 2020-03-13 2021-09-16 武汉科技大学 一种含钛六铝酸钙材料及其制备方法
CN114539818A (zh) * 2022-02-11 2022-05-27 包头稀土研究院 提高蓝色颜料的色彩饱和度的方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104830333A (zh) * 2015-03-06 2015-08-12 江苏师范大学 一种Li、Mg共掺的双钙钛矿红色荧光粉及其制备方法

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104830333A (zh) * 2015-03-06 2015-08-12 江苏师范大学 一种Li、Mg共掺的双钙钛矿红色荧光粉及其制备方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
JUN LI ET AL: "Colored Oxides with Hibonite Structure: A Potential Route to Non-cobalt Blue Pigments", 《PROGRESS IN SOLID STATE CHEMISTRY》 *
MATTEO ARDIT ET.AL: "Ni-Ti Codoped Hibnite Ceramic Pigments by Combutstion Synthesis:Crystal Struture and Optical Properties", 《JOURNAL OF THE AMERICAN CERAMIC SOCIETY》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111040470A (zh) * 2019-12-17 2020-04-21 佛山科学技术学院 一种蓝色无机颜料及其制备方法
CN111040470B (zh) * 2019-12-17 2021-03-26 佛山科学技术学院 一种蓝色无机颜料及其制备方法
WO2021179618A1 (zh) * 2020-03-13 2021-09-16 武汉科技大学 一种含钛六铝酸钙材料及其制备方法
CN114539818A (zh) * 2022-02-11 2022-05-27 包头稀土研究院 提高蓝色颜料的色彩饱和度的方法

Also Published As

Publication number Publication date
CN110358326B (zh) 2021-05-11

Similar Documents

Publication Publication Date Title
Smith et al. Spectral properties of the UV absorbing and near-IR reflecting blue pigment, YIn1-xMnxO3
CN110358326A (zh) 一种六铝酸钙蓝色陶瓷颜料及其制备方法
US9803063B2 (en) Blue inorganic colourants/pigments and process for preparation thereof
US10202510B2 (en) Pigments based on LiSbO3 and LiNbO3 related structures
KR102280563B1 (ko) 무기 적색 안료
AU2018235412B2 (en) Near infrared-reflective black pigment and method for producing same
JP6039747B2 (ja) ニッケル非含有緑色顔料
Radhika et al. Rare earth doped cobalt aluminate blue as an environmentally benign colorant
CN110878179B (zh) 一种黑色热反射颜料及其制备方法和应用
JP5404905B2 (ja) サマリウムやモリブデン化合物からなる新規な黄色系無機顔料、及びその調整方法
US10035914B2 (en) Inorganic blue pigments from cobalt doped magnesium having transition element oxides and a process for the preparing the same
KR102146241B1 (ko) 열 안정성, 산성 조건에 대한 내성 및 우수한 내광성을 나타내는, 산화안티몬 및/또는 산화니오븀을 포함하는 핑크색 및 바이올렛색 안료
Lv et al. Codoping Ti in low Co-containing hibonite achieving excellent optical properties for near-infrared reflective pigment applications
CN103097299A (zh) 替代的锡铌氧化物颜料
US20190203053A1 (en) PIGMENTS BASED ON LiSbO3 AND LiNbO3 RELATED STRUCTURES
Karolová et al. The Effect of Preparation Method on Pigmentary Properties of Managanese Doped Cassiterite Pigments
CN115432737A (zh) 一种粉色热反射颜料及其制备方法
Karolová et al. The effect of preparation method on pigmentary properties of manganese

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information

Inventor after: Wang Qingchun

Inventor after: Yang Hao

Inventor after: Song Xiwen

Inventor after: Bao Jinxiao

Inventor after: Guo Rui

Inventor after: Wu Xiaoyang

Inventor after: Gao Jianquan

Inventor after: Lv Haodong

Inventor after: Xie Min

Inventor after: Zhou Fen

Inventor before: Song Xiwen

Inventor before: Yang Hao

Inventor before: Wang Qingchun

Inventor before: Guo Rui

Inventor before: Wu Xiaoyang

Inventor before: Gao Jianquan

Inventor before: Bao Jinxiao

Inventor before: Lv Haodong

Inventor before: Xie Min

Inventor before: Zhou Fen

CB03 Change of inventor or designer information
GR01 Patent grant
GR01 Patent grant