CN110357675A - A kind of breeding waste processing method and system - Google Patents

A kind of breeding waste processing method and system Download PDF

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Publication number
CN110357675A
CN110357675A CN201910657279.3A CN201910657279A CN110357675A CN 110357675 A CN110357675 A CN 110357675A CN 201910657279 A CN201910657279 A CN 201910657279A CN 110357675 A CN110357675 A CN 110357675A
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processing
stock
stream stock
humification
sludge
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靳津津
张龙
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Korea Rbs Co Ltd
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Korea Rbs Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/50Treatments combining two or more different biological or biochemical treatments, e.g. anaerobic and aerobic treatment or vermicomposting and aerobic treatment
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00Fertilisers from human or animal excrements, e.g. manure
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00Fertilisers from human or animal excrements, e.g. manure
    • C05F3/06Apparatus for the manufacture
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • Hydrology & Water Resources (AREA)
  • Water Supply & Treatment (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Fertilizers (AREA)
  • Treatment Of Sludge (AREA)

Abstract

The present invention relates to water treatment field, in particular to a kind of breeding waste processing method and system.The present invention provides a kind of breeding waste processing method, comprising: homogeneous processing;Solid-liquid separation treatment;Humification processing;Secondary humification processing;Precipitation process;Culture processing;Aerobic fermentation processing;Afterripening fermentation processing.Breeding waste processing system and method provided by the present invention, can be with efficient process breeding waste, and provides the valuable products such as liquid fertilizer, solid fertilizer, has good industrialization prospect.

Description

A kind of breeding waste processing method and system
Technical field
The present invention relates to water treatment field, in particular to a kind of breeding waste processing method and system.
Background technique
The fecaluria of poultry is stored in the hole of field for a long time and is allowed to fermentation as agricultural fertilizers such as liquid fertilizers, still by past people Cause this raw mode that can not be applicable in recently as the extensive development of agricultural.Legal provisions and strengthening in poultry occur Various fecalurias have to pass through the processing for the treatment of facility.Though thus farmers' invested it is huge prepare treatment facility, handle When the stench etc. of fecaluria that is occurred become another problem.
Accordingly, people just propose the method for promoting poultry fecaluria recycling using the self cleaning of soil.With dynamic Remains or excreta of plant etc. are that the organic matter represented is denaturalized in the soil as inorganic matter and soil humic object.It is reacting at this time In play the exactly edaphon of decisive role, micropopulation keeps the organic matter degraded to prevent by humification reaction Only organic matter corruption, and then prevent the generation of stench.
But with the technology of natural purification method (RBS technology), there are no be widely used at home as standardization.Still have Most of farmers' releases or depends on wantonly low efficiency and causes the anaerobic fermentation technology of secondary environmental pollution.
Summary of the invention
In view of the foregoing deficiencies of prior art, the purpose of the present invention is to provide a kind of breeding waste processing methods And system, for solving the problems of the prior art.
In order to achieve the above objects and other related objects, one aspect of the present invention provides a kind of breeding waste processing method, Include:
A raw water) is subjected to homogeneous processing;
B) be subjected to it is homogeneous treated stream stock carry out solid-liquid separation treatment, with provide first by flow stock and second pass through stream Stock, described first by flowing stock for liquid phase stream stock, and the described second moisture content for passing through stream stock is 60~90wt%;
C humification processing) is carried out by stream stock by first, passes through stream stock to provide third;
D third) is subjected to secondary humification processing by stream stock, to provide four-way overcurrent stock;
E four-way overcurrent stock) is subjected to precipitation process, to provide liquid fertilizer and sludge stream stock;
F sludge stream stock provided by step E)) is subjected to culture processing, to provide culturing sludge object, at least part of dirt Mud culture be used to mix with raw water to carry out homogeneous processing, and at least part of culturing sludge object be used to pass through stream with first To carry out humification processing, at least part of culturing sludge object be used to mix with third by flowing stock to carry out for stock mixing Secondary humification processing;
G aerobic fermentation processing) is carried out by stream stock by second, it is logical by stream stock, at least part of 5th to provide the 5th Overcurrent stock be used to mix with second by flowing stock to carry out aerobic fermentation processing;
H afterripening fermentation processing) is carried out by stream stock by at least part of 5th, to provide solid fertilizer.
In some embodiments of the present invention, it is subjected to homogeneous treated stream stock and/or first can also be subjected to by flowing stock Corpusculed processing.
In some embodiments of the present invention, in the humification processing, MLSS >=3000mg/L, DO≤0.7ppm, ORP≥100mv。
In some embodiments of the present invention, in the secondary humification processing, MLSS >=3000mg/L, DO≤0.7ppm, ORP >=100mv, aeration quantity 0.03m3air/min.m3~0.04m3air/min.m3
In some embodiments of the present invention, in the secondary humification processing, by the sludge foldback of rear end, the amount of foldback is Flow the 80~800% of stock introduction volume.
In some embodiments of the present invention, the time of the processing of humification twice on the whole is 20~35 days.
In some embodiments of the present invention, hydraulic detention time >=8 hour.
In some embodiments of the present invention, the time for cultivating processing can be 12~72 hours, and the influx of air can be with For 100L/Min, being catalyzed investment weight humous is 0.05~0.5wt% that homogeneity handles Central Plains water influx, activated silica The investment weight of hydrochlorate is 0.1~0.8wt% that homogeneity handles Central Plains water influx.
In some embodiments of the present invention, at least part of culturing sludge object is used for homogeneous processing, the sludge training of foldback Feeding object is step A) in raw water usage amount 10~50wt%.
In some embodiments of the present invention, at least part of culturing sludge object is used for humification processing, foldback Culturing sludge object can be first 35~60wt% by the usage amount of stream stock.
In some embodiments of the present invention, at least part of culturing sludge object is used for secondary humification processing, foldback Culturing sludge object can be third by flowing the 200~800% of the usage amount of stock.
In some embodiments of the present invention, in the aerobic fermentation processing, oxygen concentration >=40%, reaction temperature is 60~80 DEG C, the reaction time of aerobic fermentation processing is 10~45 days.
In some embodiments of the present invention, the 5th by flowing the moisture content of stock for 20~50wt%.
In some embodiments of the present invention, the time of afterripening fermentation processing can be 28~32 days.
Another aspect of the present invention provides a kind of breeding waste processing system, comprising:
Homogenous unit, for raw water to be carried out homogeneous processing;
Equipment for separating liquid from solid, for will be subjected to it is homogeneous treated that stream stock carries out solid-liquid separation treatment, it is logical to provide first By stream stock, the equipment for separating liquid from solid is usually in fluid communication with homogenous unit overcurrent stock and second;
Flow adjusting device is used to carry out humification processing by stream stock for first, passes through stream stock to provide third, The flow adjusting device is usually in fluid communication with equipment for separating liquid from solid;;
Humification device, for third to be carried out secondary humification processing by stream stock, to provide four-way overcurrent stock, institute It states humification device and flow adjusting device is in fluid communication;
Settler, for four-way overcurrent stock to be carried out precipitation process, to provide liquid fertilizer and sludge stream stock, the precipitating Device and humification device are in fluid communication;
Culture apparatus, for sludge stream stock to be carried out culture processing, to provide culturing sludge object, the culture apparatus and heavy Shallow lake device is in fluid communication, and the culture apparatus and homogenous unit are in fluid communication, the culture apparatus and flow adjusting device fluid Connection, the culture apparatus and humification device are in fluid communication;
Aerobic fermentation device, for carrying out aerobic fermentation processing by stream stock for second, to provide the 5th by stream stock, institute Stating aerobic fermentation device can be in fluid communication with equipment for separating liquid from solid, and the introduction pipe of the aerobic fermentation device introduces pipe with it Road is in fluid communication;
Afterripening fermentation device, for carrying out afterripening fermentation processing by stream stock for at least part of 5th, to provide solid fertilizer, The afterripening fermentation device and aerobic fermentation device are in fluid communication.
In some embodiments of the present invention, agitating device is equipped in the flow adjusting device.
In some embodiments of the present invention, the connecting pipe of equipment for separating liquid from solid and flow adjusting device is equipped with particulate Change processing unit.
In some embodiments of the present invention, agitating device is equipped in the humification device.
In some embodiments of the present invention, in the humification device, by the fluid flow direction in reaction system, also set There is humification device foldback pipeline.
In some embodiments of the present invention, in the settler, it is equipped with flow stabilisation device.
In some embodiments of the present invention, in the settler, it is equipped with aggregation apparatus.
It is equipped with fermentation in some embodiments of the present invention, in the culture apparatus and promotes layer, the fermentation promotion layer includes Active silicic acid salt deposit and catalysis humic soil layer.
In some embodiments of the present invention, feeder is additionally provided in the culture apparatus.
In some embodiments of the present invention, water supply device is equipped in the aerobic fermentation device.
Detailed description of the invention
Fig. 1 is shown as breeding waste processing system structural schematic diagram of the present invention.
Component label instructions
1 Homogenous unit
2 Equipment for separating liquid from solid
21 First passes through stream stock
22 Second passes through stream stock
3 Humification device
31 Four-way overcurrent stock
4 Settler
41 Liquid fertilizer
42 Sludge stream stock
5 Culture apparatus
51 First culturing sludge logistics stock
52 Second culturing sludge logistics stock
53 Third culturing sludge logistics stock
6 Aerobic fermentation device
61 5th passes through stream stock
7 Afterripening fermentation device
71 Gu fertilizer
8 Mixing arrangement
81 Third passes through stream stock
Specific embodiment
Inventor passes through a large amount of practical studies, provides a kind of breeding waste processing method, the processing side Method can be with efficient process breeding waste, and provides the valuable products such as liquid fertilizer, solid fertilizer, has good industrialization prospect, The present invention is completed on this basis.
First aspect present invention provides a kind of breeding waste processing method, comprising:
A raw water) is subjected to homogeneous processing;
B) be subjected to it is homogeneous treated stream stock carry out solid-liquid separation treatment, with provide first by flow stock and second pass through stream Stock, described first by flowing stock for liquid phase stream stock, and the described second moisture content for passing through stream stock is 60~90wt%;
C humification processing) is carried out by stream stock by first, passes through stream stock to provide third;D third) is passed through into stream Stock carries out secondary humification processing, to provide four-way overcurrent stock;
E four-way overcurrent stock) is subjected to precipitation process, to provide liquid fertilizer and sludge stream stock;
F sludge stream stock provided by step E)) is subjected to culture processing, to provide culturing sludge object, at least part of dirt Mud culture be used to mix with raw water to carry out homogeneous processing, and at least part of culturing sludge object be used to pass through stream with first To carry out humification processing, at least part of culturing sludge object be used to mix with third by flowing stock to carry out for stock mixing Secondary humification processing;
G aerobic fermentation processing) is carried out by stream stock by second, it is logical by stream stock, at least part of 5th to provide the 5th Overcurrent stock be used to mix with second by flowing stock to carry out aerobic fermentation processing;
H afterripening fermentation processing) is carried out by stream stock by at least part of 5th, to provide solid fertilizer.
It may include: that raw water is subjected to homogeneous processing in breeding waste processing method provided by the present invention, it is described even Matter processing is often referred to each component of object to be processed carrying out well-mixed processing method, for example, it may be the side such as stirring, aeration Method, it is sufficiently homogeneous so as to the treating material that will include waste.The raw water usually can be livestock culture waste, The livestock culture waste usually may include the excrement and/or urine of poultry, the constituent content of the livestock culture waste The factors such as the collecting mode according to feeding manner, the usage amount of ejected wash water, season and fecaluria may exist one on constituent content Fixed difference, for example, by taking poultry waste as an example, TN (total nitrogen content) can for 4000~6000mgl/L, 4000~ 4500mgl/L, 4500~5000mgl/L, 5000~5500mgl/L or 5500~6000mgl/L, for another example (total phosphorus contains T-P Amount) can for≤1500mgl/L, 600~800mgl/L, 800~1000mgl/L, 1000~1200mgl/L or 1200~ 1500mgl/L, for another example COD (COD) can for 40000~60000mgl/L, 40000~45000mgl/L, 45000~50000mgl/L, 50000~55000mgl/L or 55000~60000mgl/L, for another example BOD (biological aerobic Amount) can for 40000~60000mgl/L, 40000~45000mgl/L, 45000~50000mgl/L, 50000~ 55000mgl/L or 55000~60000mgl/L, for another example SS (solid suspension concentration) can for≤35000mgl/L, 20000~25000mgl/L, 25000~30000mgl/L or 30000~35000mgl/L, for another example pH value can be alkali Property, it more specifically can be 7.5~10,7.5~8,8~8.5,8.5~9,9~9.5 or 9.5~10.
In breeding waste processing method provided by the present invention, can also include: will be subjected to it is homogeneous treated stream stock Solid-liquid separation treatment is carried out, to provide first by stream stock and second by stream stock.The solid-liquid separation treatment is often referred to flow The processing method that liquid phase and solid phase are separated in stock, for example, it may be centrifuge separation, one-way flow sieve, drum sieve, vibrating screen etc. Method, the solid-liquid separation treatment sufficiently can suitably divide the liquid and solid phases in the homogeneous resulting waste of processing From.The first-class stock is usually the liquid phase stream stock being made of substantially liquid, and usually, BOD and/or COD compare raw water For can reduce by 30~60% or so, the character of liquid phase stream stock may exist due to the influence of the mode and efficiency of separation of solid and liquid Certain difference, for example, described first by stream stock in, BOD can for 40000~60000mgl/L, 40000~ 45000mgl/L, 45000~50000mgl/L, 50000~55000mgl/L or 55000~60000mgl/L, for another example SS It can be 25000~35000mgl/L, 25000~30000mgl/L or 30000~35000mgl/L, for another example T-N can be with For 4000~6000mgl/L, 4000~4500mgl/L, 4500~5000mgl/L, 5000~5500mgl/L or 5500~ 6000mgl/L, T-P can be 800~1200mgl/L, 800~1000mgl/L or 1000~1200mgl/L.For another example institute It is usually the stream stock for containing a large amount of solid formations that second, which is stated, by stream stock, wherein second by the moisture content of stream stock be usually 60~ 90wt%, 60~70wt%, 70~80wt% or 80~90wt%, described second by stream stock, BOD can for 25000~ 35000mgl/L, 25000~27000mgl/L, 27000~29000mgl/L, 29000~31000mgl/L, 31000~ 33000mgl/L or 33000~35000mgl/L, SS can for 2500~3500mgl/L, 2500~2700mgl/L, 2700~ 2900mgl/L, 2900~3100mgl/L, 3100~3300mgl/L or 3300~3500mgl/L, T-N can for 3000~ 4000mgl/L, 3000~3200mgl/L, 3200~3400mgl/L, 3400~3600mgl/L, 3600~3800mgl/L or 3800~4000mgl/L, T-P can for 300~500mgl/L, 300~340mgl/L, 340~380mgl/L, 380~ 420mgl/L, 420~460mgl/L or 460~500mgl/L.
In breeding waste processing method provided by the present invention, it is subjected to homogeneous treated stream stock and/or first passes through Stream stock can also be subjected to corpusculed processing, for example, after can be to stream stock resulting after homogeneous processing and/or solid-liquid separation treatment Resulting first carries out high magnetization treatment by stream stock, promotes the corpusculed of fluid molecule, and then expand oxygen contact area, institute Efficiente magnetizing processing is stated to be often referred to make hydrone be separated into micro situation using magnetic force when water flows in the stronger environment in magnetic field And water ion is activated, this structure can reduce the turbidity and concentration of liquid in raw water, specifically, can be by the stream after separation of solid and liquid Stock is magnetic by continuous installation outside the metal of connection or the conveying comb of polymer system during being delivered to mixing arrangement The magnetic force of lid, the magnetic lid can be more than 10000 Gausses, and the particle of the stream stock transmitted by comb is separated into microfine Son improves the contact area with oxygen, and the aerobic of waste streams stock is accelerated to react.After the separation of solid and liquid and corpusculed processing Stream stock in, BOD can be 25000~35000mgl/L, 25000~27000mgl/L, 27000~29000mgl/L, 29000 ~31000mgl/L, 31000~33000mgl/L or 33000~35000mgl/L, 2500~3500mgl/L of SS, 2500~ 2700mgl/L, 2700~2900mgl/L, 2900~3100mgl/L, 3100~3300mgl/L or 3300~3500mgl/L, T-N can be 3000~4000mgl/L, 3000~3200mgl/L, 3200~3400mgl/L, 3400~3600mgl/L, 3600 ~3800mgl/L or 3800~4000mgl/L, T-P can for 300~500mgl/L, 300~340mgl/L, 340~ 380mgl/L, 380~420mgl/L, 420~460mgl/L or 460~500mgl/L.The particle size of stock is flowed by strong magnetic force Influence can be contracted to by 140~144Hz 50~60Hz, 50~52Hz, 52~54Hz, 54~56Hz, 56~58Hz or 58~ 60Hz。
Breeding waste processing method provided by the present invention can also include: to carry out primary corruption by stream stock for first Growing processing passes through stream stock to provide third.The humification processing is often referred to the work for needing treated substance in microorganism With the lower process by forming humus under biochemical and chemical action.In humification processing various microorganisms (example: Bacillus sp,Pseudomonas sp,Micrococus sp,Flavoba-cterium sp.,Bacullus sphaericus.,Bacillus megaterium,Cladosporium,Penicillium,Tricoderma, Stachybotris etc.) concentration usually can be with >=5000ppm, the humification processing is generally in high MLSS (mixed liquor Suspended sediment concentration, mixed liquid suspended solids) it carries out under state, for example, MLSS can be with >=3000mg/ L, >=4000mg/L or >=5000mg/L, can be improved the population densities for the nitrifier that sludge age is longer, reproduction speed is slower, because The capacity of this notably sludge, but in a humification treatment process, sludge is generally also unsuitable excessive, judge whether sludge is excessive Should be the prior art to those skilled in the art, for example, DO typically≤0.7ppm, ORP usually can with >= 100mv, so as to prevent sludge excessive.In the humification processing, first can carry out certain corruption by flowing stock Growing reaction, the humification processing usually carry out under anaerobic, and after humification processing, first passes through Water soluble organic substance cohesion, condensation, producing high-molecular, coincidence, polycondensation in stream stock is until sludge, liquid is gone during this It removes, while dissolving the corpuscular property substance for forming stench in waste water and being also removed, and start humification reaction, in fluid BOD content can be further reduced.In the treatment process of entire breeding waste processing method, raw water (for example, waste) Introduction volume it is not necessarily constant, so after being separated by solid-liquid separation obtained first by stream stock amount be also not necessarily perseverance Fixed.It therefore, can be by device used in it (for example, mixing when carrying out humification processing by stream stock for first Device) convection current stock amount and after concentration carries out equalization processing, then subsequent device is delivered to, and carry out subsequent processing, after making The amount of stream stock in continuous treatment process maintains quantitative state substantially.
Breeding waste processing method provided by the present invention can also include: that third is carried out secondary corruption by stream stock Growing processing, to provide four-way overcurrent stock.In the secondary humification processing various microorganisms (example: Bacillus sp, Pseudomonassp,Micrococus sp,Flavoba-cterium sp.,Bacullus sphaericus.,Bacillus Megaterium, Cladosporium, Penicillium, Tricoderma, Stachybotris etc.) concentration usually can be with >=5000ppm, secondary humification processing is generally in high MLSS (mixed genetic-neural network, mixed liquid Suspended solids) carry out under state, for example, MLSS can with >=3000mg/L, >=4000mg/L or >=5000mg/L, The population densities for the nitrifier that sludge age is longer, reproduction speed is slower can be improved, therefore the notably capacity of sludge, but secondary corruption In growing treatment process, sludge is generally also unsuitable excessive, judges whether sludge is excessive and to those skilled in the art should The prior art, for example, DO typically≤0.7ppm, ORP usually can be with >=100mv, so as to prevent sludge excessive. The secondary humification processing can usually carry out under aerobic condition, and those skilled in the art may be selected suitable method and keep Oxygen content in reaction system, for example, can be using the methods of aeration, during supplement, it usually needs avoid as far as possible physical External force, so as to avoid external force from destroying sludge, for example, aeration quantity can maintain 0.03m3air/min.m3~ 0.04m3air/min.m3Under conditions of.In the secondary humification treatment process, to expand denitrification effect, by reaction system Fluid flow direction, can be relatively forward by the way that the posterior fluid in relative position in reaction system is returned to reaction system Position, for example, the sludge of rear end can be returned to front end and/or centre, the amount of foldback can achieve to flow in humification processing 80~200%, 80~120%, 120~160%, 160~200%, 200~250%, 250~300%, the 300 of stock introduction volume ~400%, 400~500%, 500~600% or 600~800%, so as to improve breeding during humified While the population densities of slow Nitromonas, contained Nitromonas is provided to humification processing in culture sludge, compared with The efficiency of naturally-occurring breeding Nitromonas wants high in humification processing, for another example the time of the processing of humification twice on the whole can Think 20~35 days, 20~25 days, 25~30 days or 30~35 days, the time greatly shortens compared with the existing technology.Secondary humic In change processing, the third for having carried out certain humification pre-reaction can be reacted by flowing stock with further progress humification, enough Oxygen content third can be made by the substances fast decoupled such as BOD, SS, T-N, T-P in stream stock, BOD, COD compare raw water 60~80% are reduced, the nitrification ratio in humification treatment process can be more than 98%, can will be first during disposed of in its entirety BOD, COD in the secondary waste for flowing into reaction system breathe aerobic microorganism and amphimicrobe as charcoal element source And the oxygen of the sludge from humification processing stream access point foldback and the Nox intramolecular in humification processing rear end foldback sludge Gas can reduce BOD, COD value while promoting denitrogenation to carry out.Four-way overcurrent stock obtained is usually that stream stock and 53 are micro- The mixed style of biological sludge can further be processed to provide liquid fertilizer and sludge.
Breeding waste processing method provided by the present invention can also include: that four-way overcurrent stock is carried out place of settling Reason, to provide liquid fertilizer and sludge stream stock.The precipitation process be often referred to by the purpose object (for example, product or impurity) in fluid with The processing method separated again is precipitated in unformed solid phase form.In the precipitation process, since the DO of fluid is lower, processing The nitrogen that can also be further backing out in fluid in the process, and BOD, COD can be reduced with the removal of T-N.The place of settling In reason, hydraulic detention time be specifically as follows >=8 hours, >=12 hours, >=16 hours or >=20 hours.The precipitation process In, water body generally remains stabilization, and to guarantee the effect of precipitation process, the method for keeping water body stable is for those skilled in the art For should be known, for example, can using round or rectangular groove tank, can also using can aggregate and precipitate sludge 0.1~ The circular spatula (scraper) of 0.3RPM can also install device (truncation surface and water body with weir function under a fixed spacing The angle of flow direction can be 90 degree or so), it is certain that purpose makes the water surface more flow holding.The resulting product top of precipitation process can To be the part being cleaned, usually can be used as liquid is liquid fertilizer, and the pH of the liquid fertilizer can be alkalescent, is specifically as follows 7.5~8.5,7.7~7.9,7.9~8.1,8.1~8.3 or 8.3~8.5, BOD can be 2500~3500mgl/L, 2500 ~2700mgl/L, 2700~2900mgl/L, 2900~3100mgl/L, 3100~3300mgl/L or 3300~3500mgl/ L, SS can be 1200~1800mgl/L, 1200~1400mgl/L, 1400~1600mgl/L or 1600~1800mgl/L, T-N can for 1200~2000mgl/L, 1200~1400mgl/L, 1400~1600mgl/L, 1600~1800mgl/L or 1800~2000mgl/L, T-P can for 200~300mgl/L, 200~220mgl/L, 220~240mgl/L, 240~ 260mgl/L, 260~280mgl/L or 280~300mgl/L, the main nutrient composition as liquid fertilizer can include but is not limited to One of K (potassium), Ca (calcium), Mg (magnesium), Na (sodium), Fe (iron) etc. or a variety of combinations, wherein the content of K can be 2500~3500mg/Kg, 2500~2700mg/Kg, 2700~2900mg/Kg, 2900~3100mg/Kg, 3100~3300mg/ The content of Kg or 3300~3500mg/Kg, Ca can for 1000~1300mg/Kg, 1000~1100mg/Kg, 1100~ The content of 1200mg/Kg or 1200~1300mg/Kg, Mg can for 250~300mg/Kg, 250~270mg/Kg, 270~ The content of 290mg/Kg, 270~290mg/Kg, 290~310mg/Kg, 310~330mg/Kg or 330~300mg/Kg, Na can Think 1300~2000mg/Kg, 1300~1500mg/Kg, 1500~1650mg/Kg, 1650~1800mg/Kg or 1800~ The content of 2000mg/Kg, Fe can for 100~250mg/Kg, 100~150mg/Kg, 150~200mg/Kg or 200~ 250mg/Kg.Provided liquid fertilizer can be stored, and (for example, broadcasting sowing etc. as fertilizer) can also be utilized.Place of settling During reason, after separating with liquid phase object in provided sludge stream stock, solid content may include, usually also containing a large amount of stream Body, these fluids usually can be sludge etc..
It can also include: by sludge stream provided by step E) in breeding waste processing method provided by the present invention Stock carries out culture processing, to provide culturing sludge object.Culture processing be often referred to object to be processed in catalysis Humus and/or The processing method cultivated under the conditions of active silicate is existing in incubation, can also not only be trained with pulling sludge Sludge is supported, makes sludge that humic active reaction occur, to activate various edaphons, the metabolic activity of these microorganisms can be given birth to At vitamin, antibiotics, growth promoting substance (for example, auxin, gibberellin etc.).The side of culture processing is carried out to sludge stream stock Method should be known to those skilled in the art, for example, the sludge stream stock as culture can be sufficiently spread out, And merging catalysis Humus (for example, catalysis fertile soil) and/or active silicate etc. in culture apparatus, to carry out at culture Reason.The catalysis fertile soil can be such as peat humic-like substance, and the peat humic-like substance digging is derived from from special area The water plants class such as wetland, marsh and a part taken after the above humification accumulation of hundreds of thousands of years furthermore are passed through at processing It manages and is made, be to be distributed relatively uniform Humus composition in worldwide, the peat humic-like substance is in acidity, example Such as, the pH value of the peat humic-like substance can be 2.5~3.5.The active silicate is also referred to as zeolite, and the zeolite can be with It is the pelelith that volcano eruption generates, being different from general silicate has porous particles, and adsorptivity is superpower.The sludge training It supports in processing, the dosage relative scale for being catalyzed fertile soil and active silicate can be 1:1.5~2.5,1:1.6~2.4,1: 1.7~2.3,1:1.8~2.2 or 1:1.9~2.1, Central Plains water flow can be handled for homogeneity by being catalyzed investment weight humous Enter the 0.05~0.5wt%, 0.1~0.3wt% or 0.15~0.25wt% of amount, the investment weight of active silicate can be 0.1~0.8wt%, 0.2~0.6wt% or the 0.3~0.5wt% of Central Plains water influx, incubation are handled for homogeneity In, it usually needs certain aerobic condition is kept, for example, the influx of air can be 100L/Min, cultivates the time of processing It can be 12~72 hours, 12~24 hours, 24~36 hours, 36~48 hours or 48~72 hours.It is turned out through this process Culture sludge in rich in various edaphons (for example, the microorganism can be Bacillus sp, Pseudomonas sp,Micrococus sp,Flavoba-cterium sp.,Bacullus sphaericus.,Bacillus Megaterium, Cladosporium, Penicillium, Tricoderma, Stachybotris etc.).Dirt in culture processing Mudflow stock usually requires to keep a certain amount, although may have certain difference according to the flow of operating condition sludge stream stock It is different, but the influx of sludge stream stock and the discharge rate of culture are substantially equal amount of under normal circumstances.
In breeding waste processing method provided by the present invention, at least part of culturing sludge object is used for homogeneous place Reason.Step F at least partly) provided in culturing sludge object can be with step A) in raw water mix, the sludge being returned Viscose metallic substance in culture in the metabolite of contained pseudomonad (for example, it may be Pseudomonas Member etc.) Condensation can be agglomerated rapidly with the organic matter in raw water, be returned der Pilz contained in the culturing sludge object of inflow (for example, can To be Cladosporium, Penicillium, Tricoderma, Stachybotris etc.) microscope mycelia to wind these solidifying Humification occurs after polymers and is steadily overlapped polycondensation, the boiling together property organic matter in foldback culturing sludge object with flow in stock from Sub- property inorganic matter forms complex compound or resistance to complex compound after enduring bonding reaction, and is removed in the liquid state, meanwhile, constitute stench It is soluble in water with ionic condition after molecule generation aquation, therefore (+) ion such as ingredient NH4 of stench is as complexing Object, resistance to complex compound promote stench to be eliminated after being captured, in raw water using BOD, COD carbon as energy source denitrifier (for example, Bacillus sp.Pseudomonas sp, Micrococcus sp etc.) it can be with the nitrogen oxidation in the culturing sludge object of foldback Object (hereinafter referred to as NOx) denitrogenation carried out with nitrate respiration effect.The culturing sludge object of foldback can be step A) in raw water Usage amount 10~50wt%, 10~20wt%, 20~30wt%, 30~40wt% or 40~50wt%.
In breeding waste processing method provided by the present invention, at least part of culturing sludge object is used for a humic Change processing.Step F at least partly) provided in culturing sludge object can be with step B) provided by it is first mixed by stream stock It closes, to carry out humification processing.The step C) in, the culturing sludge object of foldback can be first to be made by stream stock 35~60wt%, 35~40wt%, 40~45wt%, 45~50wt%, 50~55wt% or the 55~60wt% of dosage.
In breeding waste processing method provided by the present invention, at least part of culturing sludge object is used for secondary humic Change processing.Step F at least partly) provided in culturing sludge object can be returned, at humification secondary in step D) The stream stock of reason mixes, to carry out secondary humification processing.The step D) in, it is logical that the culturing sludge object of foldback can be third 200~800%, 200~300%, 300~400%, 400~500%, 500~600%, the 600 of the usage amount of overcurrent stock~ 700% or 700~800%.
Contained growth promoting substance and bioactive substance etc. are (for example, auxin, gibberellin, low molecular weight in foldback sludge Organic acid, amino acid etc.) activity that microorganism can be improved, promote the reproduction speed of Nitromonas, amino nitrogen is in above-mentioned Nitromonas Under the action of promote nitrate nitrogen oxidation, not only act as the effect of deodorization, also built in processed material multiple beneficial bacterium with Environment that edaphon can inhabit and optimization, recycle as that can restore natural organic fertilizer.
Breeding waste processing method provided by the present invention can also include: to carry out aerobic hair by stream stock for second Ferment processing, to provide the 5th by stream stock.The aerobic fermentation processing is often referred to deposit in active silicate and/or catalysis Humus Under the conditions, using microorganism (for example, the microorganism can be Bacillus sp, Pseudomonas sp, Micrococus sp,Flavoba-cterium sp.,Bacullus sphaericus.,Bacillus megaterium, Cladosporium, Penicillium, Tricoderma, Stachybotris etc.) effect will flow stock in organic matter decompose Processing method.Described second by generally including organic solid content water resistance crumb structure in stream stock, can in water There are some soil particles to flock together, is not dispersed into the structure of individual particles.In the aerobic fermentation processing, active silicic acid Salt catalyst may generally function as the effect for promoting humification reaction, generates microbial metabolism after reacting with catalysis Humus and produces Cohesion, contracting occur for object, organic matter decomposition product, the chelate compound for being synthetically generated object again, caking property material etc., these substances It closes, agglomerate, polycondensation is located simultaneously as the organic matter in the increase water organic water borne solution of molecular weight is removed in liquid Reason water or sludge not only have strong chelate structure, and the metabolite etc. of these usual micropopulations also has stronger mould With deodorizing function.In the aerobic fermentation processing, the catalysis Humus of microbial activity may be incorporated into (for example, peat class is rotten Grow matter etc.), iterative cycles of the microbial activity peat humic-like substance Jing Guo liquid have been cultured in the process, therefore can not It needs individually to be put into again by outside, certainly, if can be put into inoculation step with about 1/1000 ratio Talking about effect can be more preferable.In the aerobic fermentation processing, reaction is usually carried out under aerobic condition, for example, the oxygen in reaction environment Concentration can be with >=40%, for another example oxygen concentration may range from 50~150L/min.m in reaction environment3.The aerobic hair In ferment processing, reaction is generally preferably in 60~80 DEG C, 60~65 DEG C, 65~70 DEG C, 70~75 DEG C or 75~80 DEG C of high temperature item It is carried out under part, is not usually required to be heated by the heat source of external source in reaction process, the method for controlling reaction temperature is usual It can be stirring, the metabolic activity of microorganism can cause temperature to rise when overturning is stirred, it should be noted that reaction temperature must not rise to 90 DEG C or more, i.e., it is generally necessary under the conditions of≤90 DEG C of temperature.Aerobic fermentation processing reaction time be 10~45 days, 10~ 15 days, 15~20 days, 20~25 days, 25~30 days, 30~35 days, 35~40 days or 40~45 days.Effectively induction aerobic fermentation The second of processing at least should be 60~75% or more by the appropriated moisture of stream stock, reactant when to prevent aerobic fermentation from handling The high-temperature aerobic fermentation (60~80 degrees Celsius) of the inside of system, which may cause a large amount of moisture evaporation, causes fermentation efficiency low, can To introduce suitable culture sludge liquid, the culture sludge liquid can be from culture processing or precipitation process.Introduce culture The method of sludge liquid, which can be, is sprayed to water in reaction system, alternatively, to prevent secondary pollution from can handle aerobic fermentation The raw water that a part in middle leaching water (water flowed out in reaction system) occurred is handled as liquid fertilizer carries out foldback or one Part is used to adjust the temperature and moisture of reaction system.Height typically 2~3m of fermentation layer, 2 in aerobic fermentation processing ~2.5m or 2.5~3m, can further improve treatment effeciency.The aerobic fermentation processing the resulting 5th passes through in stream stock, with On the whole by the quality of stream stock on the basis of, the content of organic matter quality can for 30~45%, 30~35%, 35~40%, Or 40~45wt%, moisture content can be 40~55wt%, 40~45wt%, 45~50wt% or 50~55wt%, nitrogen contains Amount can be 0.8~1.2wt%, 0.8~0.9wt%, 0.9~1.0wt%, 1.0~1.1wt% or 1.1~1.2wt%, phosphorus Content can be 1~3wt%, and potassium content can be 1~2wt%.
Breeding waste processing method provided by the present invention can also include: the water content tune by second by stream stock Section passes through stream stock to 60~75wt% to provide second after water content is adjusted.Second by stream stock in moisture content 60% with Resolution ratio will decline when lower, and the diffusion phenomena of oxygen will not then occur 75% or more, act on lower generation stench according to anaerobic organism Or solid extensive use of chemical fertilizer efficiency can reduce.The method for adjusting moisture content should be known to those skilled in the art, for example, Can sharp sawdust (for example, C/N sawdust below than 25), foldback the 5th by the method for stream stock, for example, at least part of 5th leads to Overcurrent stock can be used for second by flow stock mix, the described 5th by flow stock moisture content typically 20~ 50wt%, the 5th metabolic activity for having passed through microorganism by flowing stock generate the various metabolism for being largely beneficial to soil and plant Product and beneficial activity microorganism, a portion (usually can be the 5th by stream stock 30~50wt%) can with it is new The second stock of inflow mixes, and can play the role of adjusting moisture and promote fermentation activity.
Breeding waste processing method provided by the present invention can also include: by at least part of 5th by stream stock Afterripening fermentation processing is carried out, to provide solid fertilizer.In afterripening fermentation processing, after high temperatures microbial action breaks, largely may be used The organic matter being decomposed has been decomposed, therefore decomposition rate obviously slows down, Gu fertile temperature also decreases to 30 DEG C~40 DEG C, contains Water rate is also down to 55% or less.It should for those skilled in the art by the method that stream stock carries out afterripening fermentation processing to the 5th It is known, for example, the time of afterripening fermentation processing can be about 30 days, 20~40 days, 25~35 days or 28~32 days.Afterwards In ripe fermentation treatments, middle warm nature microorganism enters stabilization sub stage again, type and density with the microorganism of initial stage There are little bit differents, because quite a few in the organic matter in the stage of ripeness has turned into the humus for being difficult to be decomposed again (humus), the processed material in this way until afterripening fermentation itself is used as organic solid fertilizer, or with other through everfermentation at Organic compound fertilizer is produced after the mixing such as cow dung, chicken manure of reason.The major function of the solid fertilizer includes improving soil physical property, improving The plants such as soil chemistry, improvement geobiont property, the complete decomposition of harmful substance, growth promoting substance, physiological activator swash Cellulose content is higher, it is standby can store the substance of microelement, prevent continuous cropping obstacle etc., in the solid fertilizer, the content of nitrogen can be 0.8 ~1.2wt%, 0.8~0.9wt%, 0.9~1.0wt%, 1.0~1.1wt% or 1.1~1.2wt%, the content of phosphorus can be with For 1~3wt%, 1~1.5wt%, 1.5~2wt%, 2~2.5wt% or 2.5~3wt%, the content of potassium can for 1~ 2%, moisture content can be for 60wt% or less, 55wt% or less, 50wt% or less or 45wt% hereinafter, the content of organic matter It can be 35wt% or more, 40wt% or more or 45wt% or more, C/N ratio can be 45 or less, 40 or less or 35 hereinafter, rotten Ripe degree can be 3.5 or more, 4 or more or 4.5 or more, and pH can be alkalescent, be specifically as follows 7.5~8.5,7.5~7.7, 7.7~7.9,7.9~8.1,8.1~8.3 or 8.3~8.5.
Second aspect of the present invention provides a kind of breeding waste processing system, as shown in Figure 1, may include:
Homogenous unit, for raw water to be carried out homogeneous processing;
Equipment for separating liquid from solid, for will be subjected to it is homogeneous treated that stream stock carries out solid-liquid separation treatment, it is logical to provide first Overcurrent stock and second passes through stream stock, and described first by flowing stock for liquid phase stream stock, and the described second moisture content for passing through stream stock is 60 ~90wt%;
Flow adjusting device passes through stream stock for carrying out humification processing by stream stock for first to provide third;
Humification device, for third to be carried out secondary humification processing by stream stock, to provide four-way overcurrent stock;
Settler, for four-way overcurrent stock to be carried out precipitation process, to provide liquid fertilizer and sludge stream stock;
Culture apparatus, for sludge stream stock to be carried out culture processing, to provide culturing sludge object, at least part of sludge training Feeding object be used to mix with raw water to carry out homogeneous processing, and at least part of culturing sludge object be used to mix with first by stream stock It closes to carry out humification processing, at least part of culturing sludge object be used to mix with third by stream stock secondary to carry out Humification processing;
Aerobic fermentation device, for carrying out aerobic fermentation processing by stream stock for second, to provide the 5th by stream stock, until Least a portion of 5th be used to mix with second by flowing stock to carry out at aerobic fermentation by flowing stock;
Afterripening fermentation device, for carrying out afterripening fermentation processing by stream stock for at least part of 5th, to provide solid fertilizer.
It may include homogenous unit in breeding waste processing system provided by the present invention, the homogenous unit can be with For raw water to be carried out homogeneous processing, the homogenous unit can usually can be suitable container, specifically can be for example anti- Ying Chi, reactor tank etc..In the homogenous unit, it can be usually equipped with agitating device, for example, it may be blender, aerator Deng so as to so that raw water is sufficiently homogeneous.
It can also include equipment for separating liquid from solid, the solid-liquid point in breeding waste processing system provided by the present invention From device can be used for be subjected to it is homogeneous treated stream stock carry out solid-liquid separation treatment, with provide first by stream stock and second By flowing stock, described first by flowing stock for liquid phase stream stock, and the described second moisture content for passing through stream stock is 60~90wt%.It is described Equipment for separating liquid from solid can usually be in fluid communication with homogenous unit, introduce so as to be subjected to resulting stream stock after homogeneous processing To be subjected to solid-liquid separation treatment in equipment for separating liquid from solid.Suitable equipment for separating liquid from solid may be selected in those skilled in the art, for example, It can be centrifugal separator, one-way flow sieve, drum sieve, vibrating screen etc..
It can also include flow adjusting device, the flow tune in breeding waste processing system provided by the present invention Engagement positions can be used for carrying out humification processing by stream stock for first, pass through stream stock to provide third, and adjustable Flow passes through stream stock to provide the third of constant flow rate.The flow adjusting device usually can be with equipment for separating liquid from solid fluid Connection, so as to be introduced into first in flow adjusting device by flowing stock, to carry out humification processing.The flow tune Engagement positions can usually can be suitable anaerobic reaction container, specifically can be such as reaction tank, reactor tank.The flow It adjusts in device, can usually be equipped with agitating device, for example, it may be blender etc., so as to so that each material is sufficiently mixed.
In breeding waste processing system provided by the present invention, the communicating pipe of equipment for separating liquid from solid and flow adjusting device Corpusculed processing unit can be equipped on road, so as to being subjected to homogeneity and handle later stream stock to carry out at corpusculed Corpusculed processing unit can be equipped on the connecting pipe of reason, homogenous unit and equipment for separating liquid from solid, so as to first Corpusculed processing is carried out by stream stock.The corpusculed processing unit specifically can be magnetic lid, and the magnetic lid can be with The magnetic force of appropriate intensity is provided.
It can also include humification device in breeding waste processing system provided by the present invention, the humic makeup Setting, which can be used for, carries out secondary humification processing by stream stock for third, to provide four-way overcurrent stock.The humification device It can be in fluid communication with flow adjusting device, it is secondary to be subjected to so as to which third to be introduced into humification device by flowing stock Humification processing.The humification device usually can be suitable aerobic reaction container, specifically can be such as reaction tank, anti- Tank etc. is answered, is typically provided with apparatus of oxygen supply in the humification device, for example, it may be aerator etc., so as to provide conjunction Suitable aerobic condition.In the humification device, it is usually also provided with agitating device, for example, it may be blender etc., thus Each material can be made to be sufficiently mixed.In the humification device, to expand denitrification effect, by the fluid flowing side in reaction system To humification device foldback pipeline being also provided in reaction unit, thus by the posterior portion in relative position in humification device Divide the partial fluid communication forward with relative position, so that the foldback of fluid is realized, for example, the sludge of rear end can be returned to Front end and/or centre.
It can also include settler, the settler can in breeding waste processing system provided by the present invention To be used to four-way overcurrent stock carrying out precipitation process, to provide liquid fertilizer and sludge stream stock.The settler can be with humic Fluid communication is set in makeup, so as to which four-way overcurrent stock to be introduced into settler, to be subjected to precipitation process.The precipitating dress It sets and usually can be suitable reaction vessel, specifically can be such as reaction tank, reactor tank.In the settler, may be used also To be equipped with flow stabilisation device, so as to so that when the fluid is flowing in settler keeps certain stability, the stream Body stabilising arrangement can be such as weir.In the settler, it is also provided with aggregation apparatus, so as to can aggregate and precipitate Sludge specifically can be such as spatula.
It can also include culture apparatus, the culture apparatus can in breeding waste processing system provided by the present invention To be used to sludge stream stock carrying out culture processing, to provide culturing sludge object.The culture apparatus can be with settler fluid Connection, so as to which sludge stream stock is introduced culture apparatus, to be subjected to culture processing.The settler usually can be properly Reaction vessel, specifically can be such as reactor tank.In the culture apparatus, it can usually be equipped with fermentation and promote layer, it is described It may include active silicic acid salt deposit and catalysis humic soil layer that fermentation, which promotes layer, and active silicate is usual in the active silicic acid salt deposit For pulverulence, partial size can be 0.2~0.5mm, and thickness can be 0.2~0.5mm, the catalysis humic the thickness of the layer It can be 1~5mm, catalysis fertile soil is usually soil property state.It can also include feeder in the culture apparatus, for example, It can be air blown producer etc., can successively be set so as to provide sufficient air to treating material by the flow direction of air Material, active silicic acid salt deposit and catalysis humic soil layer to be handled.
In breeding waste processing system provided by the present invention, the culture apparatus can connect with homogenous unit fluid It is logical, so as to which at least part of culturing sludge object is introduced homogenous unit, the culturing sludge object of foldback is mixed with raw water with Carry out homogeneous processing.The culture apparatus can be in fluid communication with flow adjusting device, so as to by least part of sludge Culture introduces flow adjusting device, and the culturing sludge object of foldback is mixed with first by flowing stock to carry out at a humification Reason.The culture apparatus can be in fluid communication with humification device, rotten so as to introduce at least part of culturing sludge object It grows during makeup sets, the culturing sludge object of foldback is mixed with the fluid in humification device, to carry out secondary humification processing.
It can also include aerobic fermentation device, the aerobic hair in breeding waste processing system provided by the present invention Ferment device can be used for carrying out aerobic fermentation processing by stream stock for second, to provide the 5th by stream stock.The aerobic fermentation Device can be in fluid communication with equipment for separating liquid from solid, so as to be introduced into second in aerobic fermentation device by flowing stock, with warp It is handled by aerobic fermentation.The aerobic fermentation device can be suitable reaction vessel, specifically can be such as reactor tank.Institute Apparatus of oxygen supply can be usually equipped with by stating in aerobic fermentation device, to provide good aerobic reaction condition, the apparatus of oxygen supply can To be air comb etc..In the aerobic fermentation device, it is also provided with water supply device, so as to suitably adjust reaction system In water content, the water supply device can be spray thrower etc..The introduction pipe of the aerobic fermentation device can be introduced with it Fluid communication, so as to be mixed at least part of 5th by flowing stock to carry out aerobic hair by stream stock with second Ferment.
It can also include afterripening fermentation device in breeding waste processing system provided by the present invention, the after-ripening hair Ferment device can be used for carrying out afterripening fermentation processing by stream stock for at least part of 5th, to provide solid fertilizer.The after-ripening hair Ferment device can be in fluid communication with aerobic fermentation device, so as to which the 5th is introduced into afterripening fermentation device by flowing stock, with It is subjected to afterripening fermentation processing.The afterripening fermentation device can be suitable reaction vessel, specifically can be such as reactor tank.
Breeding waste processing system and method provided by the present invention, can be with efficient process breeding waste, and provides The valuable products such as liquid fertilizer, solid fertilizer, have good industrialization prospect.
Illustrate embodiments of the present invention below by way of specific specific example, those skilled in the art can be by this specification Other advantages and efficacy of the present invention can be easily understood for disclosed content.The present invention can also pass through in addition different specific realities The mode of applying is embodied or practiced, the various details in this specification can also based on different viewpoints and application, without departing from Various modifications or alterations are carried out under spirit of the invention.
Before further describing the specific embodiments of the present invention, it should be appreciated that protection scope of the present invention is not limited to down State specific specific embodiment.Unless otherwise defined, all technical and scientific terms and this technology used in the present invention are led The normally understood meaning of field technique personnel is identical.In addition to specific method, equipment, material used in the embodiment, according to this technology Grasp and of the invention record of the technical staff in field to the prior art, can also use with described in the embodiment of the present invention Any method, equipment and the material of the similar or equivalent prior art of method, equipment, material realizes the present invention.
Embodiment 1
Poultry fecaluria is had collected by five pens, respectively moves in 15~25%, the character testing result after collecting poultry fecaluria It is average as follows: BOD 35,000mgl/L, SS 34,000mgl/L, T-N 6,000mgl/L, T-P 800mgl/L.This is implemented Main purpose be organic in order to demonstrate the safety of the technology of the present invention, treatment effeciency, the smelly eliminating effect in treatment process, production Liquid fertilizer and solid fertilizer.
Firstly, homogeneity device is with poultry fecaluria 100m on the 1st3Treating capacity on the basis of, can store two days or more Influx.Catchment volume in this implementation is designed as 220m3, tiny aerator in water is mounted with inside homogeneity device, Major function is to prevent the layering or precipitating of the liquid and solid of poultry fecaluria waste water, and induced concentration homogeneity.By the first dirt Mud culture logistics stock is mixed by a certain percentage with raw water, and the amount of used raw water is about 100m3, the first sludge of foldback The amount of culture logistics stock is about 50% (50m of raw water amount3), the contained dirty substance in the raw water of inflow agglomerates condensation, like Having used chemical coagulant generally makes the particle of sludge-like substance become larger, and liquid state organics are captured in sludge in raw water, drop The dirty concentration of low liquid simultaneously induces the stench for reducing early stage.
The character of foldback culturing sludge object is as follows: BOD 300mgl/L, SS 98mgl/L, T-N 1,500mgl/L, T-P 700mgl/L.The mixing total amount for the culturing sludge object that raw water in homogeneity device is provided with the first culturing sludge logistics stock is 150m3, occur to be transported to equipment for separating liquid from solid after certain homogeneity using the tiny aeration in water, after being separated by solid-liquid separation Solid-state second passes through stream stock 20m3Amount be transported to aerobic installation for fermenting, liquid first passes through stream stock about 130m3Amount it is defeated It send to mixing arrangement.Common low speed screw dehydration mode in the used poultry fecaluria separation of solid and liquid of separation of solid and liquid of the invention, Its treating capacity is 20m3/Hr。
Culturing sludge object refers to through bioreactor microbial activity device, appropriate to put into original corruption contained in soil Matter and active silicate are grown, the metabolic function and soil of the micropopulation for making to inhabit in activated sludge are mixed with activated sludge In it is identical, thus obtain culture.This culture can drain various humic acid, antibiotics, growth promoting substance, sequestering Organic matter (example: lichenic acid, uronic acid, amino sugar, amine etc.) sequestering higher polyphenol etc..
Herein, liquid first is delivered to outside the metal of mixing arrangement or the comb of polymer system by stream stock and is equipped with Magnetic lid more than 12000 Gauss of magnetic force of 10 multizone tunnel types.Pass through the particle structure quilt of the transported stream stock of comb It is separated into minuteness particle, expands the contact surface of particle and oxygen, the first of liquid can be accelerated to react by the aerobic of stream stock.
It is transported to the 130m of mixing arrangement3First by stream stock and foldback the second culturing sludge logistics stock 50m3Weight Total amount reaches 180m after new mixing3, make to flow into waste water again through this process, that is, first passes through the water solubility in stream stock Organic matter cohesion, condensation, producing high-molecular, coincidence, polycondensation are until sludge, liquid is removed during this, while being dissolved useless The ionic substance for forming stench in water is also removed, and starts humification reaction.
By this process, liquid BOD is reduced to about 14,000mgl/L by 35 initial, 000mgl/L, and residue is in sludge The state being captured carries out humification reaction after flowing into humification device.
The NOx in culturing sludge object being delivered in mixing arrangement by the second culturing sludge logistics stock and the waste water of inflow mix It after closing stirring is influenced that denitrification reaction occurs by denitrifier, part BOD is removed, and the above phenomenon is carried out under anaerobic state Function, therefore blender has been used to be mixed, incorporation time can be 24~78 hours.
Corruption is delivered to after a humification reacts third obtained by stream stock-traders' know-how flow adjustment in mixing arrangement 8 It grows makeup and sets 3, and further with third culturing sludge logistics stock (about 50m3), the aerator in water, which has been selected, destroys sludge It is smaller and pass the aeration that oxygen rate is higher, the preferable tiny bubble air diffusion apparatus of agitating function (aerator in water), in aeration tank Amount maintains 0.03m3air/min.m3~0.04m3air/min.m3.The conveying for flowing to the waste water of sedimentation basin also takes nature The mode of inflow.Aeration process is the process for being aoxidized, being decomposed to organic matter using microorganism.
Due to having enough oxygen contents in fluid in aerator, so as to so that BOD, SS in first-class stock, The substances fast decoupled such as T-N, T-P.The foldback ratio of humification device is 80~120% (examples: inflow water of mixing arrangement flow 180m3/ foldback water 200m3), the processing time in humification device 3 probably needs 17 days on the basis of fine aeration mode.
Four-way overcurrent stock after humification is reacted by be delivered to settler (residence time 12 hours or more, And be equipped with can aggregate and precipitate sludge spatula and stablize the weir device that more flows).Products therefrom is separated into the liquid that top SS is cleaned Fertilizer and sludge stream stock include solid stream stock (microorganism) in precipitated sludge stream stock.
According to analysis, the part that this process middle and upper part is cleaned has the character of liquid fertilizer, can be used as liquid fertilizer, mean parameter Are as follows: PH7.6, BOD 300mgl/L, SS 98mgl/L, T-N 1,500mgl/L, T-P 700mgl/L, as liquid fertilizer nutrition at Point, content are as follows: K (potassium) 2,136mg/Kg, Ca (calcium) 1,887mg/Kg, Mg (magnesium) 265mg/Kg, Na (sodium) Isosorbide-5-Nitrae 64mg/Kg, Fe (iron) 188mg/Kg.
It can be placed in culture apparatus by the precipitation process sludge stream stock obtained comprising solid, culture is in It is sufficiently spread out state, can be located on web plate, upper end setting, which inspires ferment layer (example: can be two layers) close to one layer of culture, is The active silicate of moderate in grain size, partial size is 5~10, with a thickness of the float stone (big stone size as fist) of 5~10Cm, from The farther away layer of culture is catalysis peat, and with a thickness of 1~2Cm, the length for being catalyzed peat is the bullet shape of 2~5Cm.Cylinder The diameter of open upper end part can be about 50cm, and the tank slot as culture apparatus is that diameter is 1.2m~1.5m, high 1.5~2m Cylinder, stainless steel material, bottom be it is latticed, top is taper.
The air diffusion apparatus ventilating air connected by groove tank lower end makes air with catalysis fertile soil and active silicate good Activation (culturing sludge reaction) reaction, on the basis of flowing into the air capacity in culture apparatus, the sky of inflow are generated in good construction Tolerance is 100~200L/Min, and incubation time is 24~72 hours.Various soil are rich in the culture sludge turned out through this process (example: the microorganism is Bacillus sp, Pseudomonas sp, Micrococus sp, Flavoba- to earth microorganism cterium sp.,Bacullus sphaericus.,Bacillus megaterium,Cladosporium, Penicillium, Tricoderma, Stachybotris etc.), and it is returned to the first culturing sludge logistics stock, the training of the second sludge Support logistics stock, third culturing sludge logistics stock.
Second be mixed in aerobic fermentation device passes through stream stock and sawdust and moisture tune by the 5th of stream stock and foldback Moisture content is adjusted to 65~70% after section agent mixing.Average input ratio is second by flowing the 5th of stock about 60%, foldback By flowing stock about 20%, sawdust 16%, other fermentation catalysts (including active silicate, humus) 4%.Lower end utilizes air Device and comb are sufficiently stirred it using screw blender to maintain aerobic conditions.The basic item of aerobic fermentation Part: air is injected in the solid-state lower end of accumulation and starts to stir, the metabolic temperature of microorganism is made after activation of microorganism, that is, is discarded The fermentation temperature of object reaches minimum 50 degree or more.45 degree of initial stage mesophilic digestion or more 5~10 days, 60~85 degree of mid-term hot fermentation 2~7 days in range, 50 degree of later period afterripening fermentation or less 17~27 days, the activity of microorganism is gradually dropped after hot fermentation Low, temperature also begins to decline and maintains between 35~45 degree, and microorganism is gradually transformed into the process of spore state.Aerobic fermentation Device, using 30 days After-ripenings of afterripening fermentation device, finally obtained good solid fertilizer after 30 days fermentation phases. The methods of the solid fertile color of detection, taste, appearance, moisture content are generallyd use, but is mainly still measured on the basis of C/N ratio, It can be judged as the decomposed state that is over when general C/N ratio is below 25%.The content of this solid fertilizer are as follows: nitrogen 1.02%, phosphoric acid 1.6%, potassium 1.8%, moisture 48% is hereinafter, 42% or more organic matter, and C/N is than 25 hereinafter, 5.2 or more rotten degree, PH8.3.
In conclusion the present invention effectively overcomes various shortcoming in the prior art and has high industrial utilization value.
The above-described embodiments merely illustrate the principles and effects of the present invention, and is not intended to limit the present invention.It is any ripe The personage for knowing this technology all without departing from the spirit and scope of the present invention, carries out modifications and changes to above-described embodiment.Cause This, institute is complete without departing from the spirit and technical ideas disclosed in the present invention by those of ordinary skill in the art such as At all equivalent modifications or change, should be covered by the claims of the present invention.

Claims (10)

1. a kind of breeding waste processing method, comprising:
A raw water) is subjected to homogeneous processing;
B) be subjected to it is homogeneous treated stream stock carry out solid-liquid separation treatment, with provide first by stream stock and second by stream stock, Described first by flowing stock for liquid phase stream stock, and the described second moisture content for passing through stream stock is 60~90wt%;
C humification processing) is carried out by stream stock by first, passes through stream stock to provide third;
D third) is subjected to secondary humification processing by stream stock, to provide four-way overcurrent stock;
E four-way overcurrent stock) is subjected to precipitation process, to provide liquid fertilizer and sludge stream stock;
F sludge stream stock provided by step E)) is subjected to culture processing, to provide culturing sludge object, at least part of sludge training Feeding object be used to mix with raw water to carry out homogeneous processing, and at least part of culturing sludge object be used to mix with first by stream stock It closes to carry out humification processing, at least part of culturing sludge object be used to mix with third by stream stock secondary to carry out Humification processing;
G aerobic fermentation processing) is carried out by stream stock by second, to provide the 5th by stream stock, at least part of 5th passes through stream Stock be used to mix with second by flowing stock to carry out aerobic fermentation processing;
H afterripening fermentation processing) is carried out by stream stock by at least part of 5th, to provide solid fertilizer.
2. breeding waste processing method as described in claim 1, which is characterized in that be subjected to it is homogeneous treated stream stock and/ Or first by flow stock can also be subjected to corpusculed processing.
3. breeding waste processing method as described in claim 1, which is characterized in that in the humification processing, MLSS >=3000mg/L, DO≤0.7ppm, ORP >=100mv.
4. breeding waste processing method as described in claim 1, which is characterized in that in the secondary humification processing, MLSS >=3000mg/L, DO≤0.7ppm, ORP >=100mv, aeration quantity 0.03m3air/min.m3~0.04m3air/ min.m3;And/or in the secondary humification processing, by the sludge foldback of rear end, the amount of foldback be stream stock introduction volume 80~ 800%;And/or the time of the processing of humification twice on the whole is 20~35 days.
5. breeding waste processing method as described in claim 1, which is characterized in that in the precipitation process, hydraulic retention Time >=8 hour.
6. breeding waste processing method as described in claim 1, which is characterized in that cultivate processing time can for 12~ 72 hours, the influx of air can be 100L/Min, and being catalyzed investment weight humous is that homogeneity handles the inflow of Central Plains water 0.05~0.5wt% of amount, the investment weight of active silicate are 0.1~0.8wt% that homogeneity handles Central Plains water influx.
7. breeding waste processing method as described in claim 1, which is characterized in that at least part of culturing sludge object by with In the culturing sludge object of homogeneous processing, foldback be step A) in raw water usage amount 10~50wt%;
And/or at least part of culturing sludge object is used for humification processing, the culturing sludge object of foldback can be first By the 35~60wt% for flowing the usage amount of stock;
And/or at least part of culturing sludge object is used for secondary humification processing, the culturing sludge object of foldback can be third By flow the usage amount of stock 200~800%;
And/or in the aerobic fermentation processing, oxygen concentration >=40%, reaction temperature is 60~80 DEG C, and aerobic fermentation is handled anti- It is 10~45 days between seasonable.
8. breeding waste processing method as described in claim 1, which is characterized in that the 5th moisture content for passing through stream stock is 20 ~50wt%.
9. breeding waste processing method as described in claim 1, which is characterized in that afterripening fermentation processing time can be 28~32 days.
10. a kind of breeding waste processing system, comprising:
Homogenous unit, for raw water to be carried out homogeneous processing;
Equipment for separating liquid from solid, for will be subjected to it is homogeneous treated that stream stock carries out solid-liquid separation treatment, first pass through stream to provide By stream stock, the equipment for separating liquid from solid is usually in fluid communication with homogenous unit stock and second;
Flow adjusting device is used to carry out humification processing by stream stock for first, passes through stream stock to provide third, described Flow adjusting device is usually in fluid communication with equipment for separating liquid from solid;;
Humification device, for third to be carried out secondary humification processing by stream stock, to provide four-way overcurrent stock, the corruption It grows makeup and sets and be in fluid communication with flow adjusting device;
Settler, for four-way overcurrent stock to be carried out precipitation process, to provide liquid fertilizer and sludge stream stock, the settler It is in fluid communication with humification device;
Culture apparatus, for sludge stream stock to be carried out culture processing, to provide culturing sludge object, the culture apparatus and precipitating are filled Fluid communication is set, the culture apparatus and homogenous unit are in fluid communication, and the culture apparatus and flow adjusting device are in fluid communication, The culture apparatus and humification device are in fluid communication;
Aerobic fermentation device is described good with offer the 5th by stream stock for carrying out aerobic fermentation processing by stream stock for second Aerobe fermentation device can be in fluid communication with equipment for separating liquid from solid, and the introduction pipe of the aerobic fermentation device introduces pipeline stream with it Body connection;
Afterripening fermentation device, it is described to provide solid fertilizer for carrying out afterripening fermentation processing by stream stock for at least part of 5th Afterripening fermentation device and aerobic fermentation device are in fluid communication.
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Application publication date: 20191022