CN110330833A - A kind of environmental friendly putty - Google Patents

A kind of environmental friendly putty Download PDF

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Publication number
CN110330833A
CN110330833A CN201910772000.6A CN201910772000A CN110330833A CN 110330833 A CN110330833 A CN 110330833A CN 201910772000 A CN201910772000 A CN 201910772000A CN 110330833 A CN110330833 A CN 110330833A
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China
Prior art keywords
parts
powder
environmental friendly
water
putty
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Pending
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CN201910772000.6A
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Chinese (zh)
Inventor
张殿学
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Heilongjiang Xinyanxue Environmental Science And Technology Development Co Ltd
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Heilongjiang Xinyanxue Environmental Science And Technology Development Co Ltd
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Priority to CN201910772000.6A priority Critical patent/CN110330833A/en
Publication of CN110330833A publication Critical patent/CN110330833A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/34Filling pastes

Abstract

The invention discloses a kind of environmental friendly putties, it is comprised the following components in parts by weight, pulvis: 20-28 parts of seaweed soil, and 15-22 parts of mud stone, 8-12 parts of aloe powder, six 15-25 parts of ring stones, 10-18 parts of cellulose fibre, 12-20 parts of calcium oxide;12-15 parts of auxiliary agent;Auxiliary material: water-soluble 5-15 parts of flexible putty rubber powder, 3-8 parts of polypropylene fibre, 1-4 parts of starch, 0.1-0.5 part of neopelex, 0.2-0.8 part of negative ion powder;A kind of environmental friendly putty of the invention has good ductility, metope can be effectively prevent to crack, while few containing noxious material, environment protection health.

Description

A kind of environmental friendly putty
Technical field
The present invention relates to the field of building materials more particularly to a kind of environmental friendly putties.
Background technique
Putty (fillering) is a kind of material of decoration property of smooth surface of wall, is a kind of thick slurry coating material, is coating Essential a kind of product before painting.Painting is imposed on priming paint or is directly applied and imposes on object, to remove on coated article surface Rugged defect.It is formulated using a small amount of Qi Ji, auxiliary agent, mass filler and suitable coloring pigment, pigment master used If iron oxide red, carbon black, chrome yellow etc..Filler is mainly calcium bicarbonate, talcum powder etc..The working surface that there is recess in part can be filled up, It can also be struck off in all surfaces, usually after prime coat parches, be applied over primer coat surface.It is required that adhesion is good, toasted It is not cracked in journey.
There are many powder of lacquer putty for use on or putty jelly on the market now, mostly uses the materials systems such as talcum powder, dry powder greatly mostly Standby to form, although cost of material is low, complex process, overall cost is high, especially containing harmful substances such as formaldehyde, to people's Nervous system has a great impact, and especially infant and elderly and infirm's harm is bigger, or even causes serious disease, and And there are extensibility and film forming deficiency biological questions, wall crazing not can effectively prevent.
Summary of the invention
The purpose of the present invention is to solve the shortcomings of the prior art and a kind of environmental friendly putty is provided, have good extension Property, metope can be effectively prevent to crack, while few containing noxious material, environment protection health.
In order to achieve the above objectives, the present invention is achieved through the following technical solutions.
A kind of environmental friendly putty, it is comprised the following components in parts by weight,
Pulvis: 20-28 parts of seaweed soil, 15-22 parts of mud stone, 8-12 parts of aloe powder, six 15-25 parts of ring stones, cellulose 10-18 parts of fiber, 12-20 parts of calcium oxide;
12-15 parts of auxiliary agent;
Auxiliary material: water-soluble 5-15 parts of flexible putty rubber powder, 3-8 parts of polypropylene fibre, 1-4 parts of starch, detergent alkylate 0.1-0.5 part of sodium sulfonate, 0.2-0.8 part of negative ion powder;
The granularity of the seaweed soil is 500-580 mesh;
The granularity of the mud stone is 520-550 mesh;
The granularity of the six rings stone is 320-410 mesh;
The cellulose fibre select cotton, fiber crops, bamboo material regenerated celulose fibre, granularity is 320-410 mesh;
The granularity of the aloe powder is 420-450 mesh;
Calcium powder is made in the calcium oxide, its granularity of calcium powder is 420-600 mesh.
Further, it is comprised the following components in parts by weight, pulvis: 22 parts of seaweed soil, and 18 parts of mud stone, 10 parts of aloe powder, Six 20 parts of ring stones, 15 parts of cellulose fibre, 15 parts of calcium oxide;12 parts of auxiliary agent, auxiliary material: 10 parts of water-soluble flexible putty rubber powder gathers 5 parts of tacryl, 3 parts of starch, 0.3 part of neopelex, 0.5 part of negative ion powder.
Further, it is comprised the following components in parts by weight, pulvis: 20 parts of seaweed soil, and 22 parts of mud stone, 12 parts of aloe powder, Six 15 parts of ring stones, 10 parts of cellulose fibre, 12 parts of calcium oxide;12 parts of auxiliary agent, auxiliary material: 15 parts of water-soluble flexible putty rubber powder gathers 3 parts of tacryl, 4 parts of starch, 0.5 part of neopelex, 0.2 part of negative ion powder;
Further, it is comprised the following components in parts by weight, pulvis: 28 parts of seaweed soil, and 15 parts of mud stone, 8 parts of aloe powder, six 25 parts of ring stone, 18 parts of cellulose fibre, 20 parts of calcium oxide;15 parts of auxiliary agent, auxiliary material: 5 parts of water-soluble flexible putty rubber powder, polypropylene 8 parts of fiber, 1 part of starch, 0.1 part of neopelex, 0.8 part of negative ion powder.
Further, the auxiliary agent includes defoaming agent, thickener, the fungicide that mass ratio is 1:2-4:2, the defoaming Agent includes the quality such as ethylene glycol siloxanes, dimethyl silicone polymer compounding;The thickener includes methylcellulose, hydroxypropyl first The quality such as base cellulose, sodium carboxymethylcellulose and hydroxyethyl cellulose compounding.
It further, is at most base-material with weight, by matter the preparation method comprises the following steps: choosing the powder for being sieved to specified partial size Amount successively adds other powders from more to less, and stirs evenly, then the water-soluble flexible putty rubber powder in addition auxiliary material, poly- third Mixed sub-material, is finally added in agitator tank by alkene fiber, starch, neopelex, and stir evenly, on one side plus Auxiliary agent is added in water stirring on one side, stirs evenly;
Further, the quality of water is powder, 0.8-1.1 times of auxiliary material quality sum in preparation method.
Further, auxiliary agent adds in three times in preparation method, and the mass ratio added for the first time, for the second time, for the third time is 1:2:5.
A kind of environmental friendly putty of the invention has good ductility, metope can be effectively prevent to crack, while containing Toxic Matter is few, environment protection health.
Specific embodiment
Below with reference to embodiment, the present invention will be further described, but is not limited to the content on specification.
A kind of environmental friendly putty, it is comprised the following components in parts by weight, pulvis: 20-28 parts of seaweed soil, and 15-22 parts of mud stone, 8-12 parts of aloe powder, six 15-25 parts of ring stones, 10-18 parts of cellulose fibre, 12-20 parts of calcium oxide;12-15 parts of auxiliary agent, Auxiliary material: water-soluble 5-15 parts of flexible putty rubber powder, 3-8 parts of polypropylene fibre, 1-4 parts of starch, neopelex 0.1-0.5 part, 0.2-0.8 part of negative ion powder.
Wherein, seaweed native (mud) is a kind of environment protection health decoration coating based on seaweeds placer deposits substance, is current One of most environmentally friendly coating variety.Due to algae clay health environment-friendly, not only there is fine dicoration, also there is functionality, is substitution The house decorative material of new generation of wallpaper and emulsion paint.Algae clay is not easy to be infected with dust, fire protection flame retarding, water-fast moisture resistance, antifouling anti- It is mould.The granularity of seaweed soil is 500-580 mesh.
Mud stone refers to the clay of weak consolidation by moderate epigenesis (such as squeezing action, dehydration, recrystallization Effect and cementation) form the rock of strong knot.It is to have consolidated diagenesis, but stratification is unobvious, or in bulk, locally lose Plasticity meets the appositional pattern rock that water does not expand immediately.Mineralogical composition is complicated, mainly by clay mineral (such as hydromica, kaolinite Stone, montmorillonite etc.) secondly composition is detrital mineral (quartz, feldspar, mica etc.), rear rawore object (such as allochite, chlorite) And ferrimanganic matter and organic matter.Quality is soft, and the degree of consolidation is weak compared with shale, recrystallizes unobvious.Common type has: 1. calcareous mud Rock.Containing appropriate calcium carbonate, it is common in the sedimentary type formations of continent red series of rocks and ocean, Diarrhea lacustrine facies.2. irony mud stone.Containing more Iron mineral, such as bloodstone, limonite, goethite, are more common in red bed.3. siliceous mudstone.SiO2Content is higher, be free of or Seldom contain irony and carbonate matter object, often with ferruginous rock, silicalite, manganic rook phase association.Mud stone has water suction, bonding, fire resisting etc. Performance can be used for the industry such as brick and tile, potting.The granularity of mud stone is 520-550 mesh.
Six ring stones originate in Baotou possession Yellow River basin, are created on the Ordovician system (away from 200,000,000 4 thousand ten thousand years modern), belong to heavy Product rock.It is cut into well-regulated block through calcite, is formed through periodic ringed precipitation at block center by limonite present " ring ".This stone pool is simple and tasteful, texture is completely peculiar, exactly likes thousand Nian Gumu annual rings, and pattern shape coloured silk is different, real to belong to rare in this world Lithotome.Its ore body surface layer is in slaty, and each sheet has the overall shape and colour circle of oneself.There is triangle, trapezoidal, square Shape, parallelogram etc., the smallest complete triangle pattern side length only 3cm, maximum side length about 1.5m.Lower layer is original state rock Layer, thickness reach 1.7m, largest grain size 3.8*1.7*0.8m, are in cuboid, and colour circle is complete.The production processed with natural six rings stone Product function is special.The granularity of six ring stones is 320-410 mesh.
Cellulose fibre is made of to use a kind of extremely frigid zones special plant species as raw material, be after chemical synthetic fiber it The environment-friendly concrete durability dedicated fiber to grow up afterwards, engineering circles are known as third generation concrete dedicated fiber, have natural Hydrophily and high-strength and high-modulus feature.The fiber is to use a kind of extremely frigid zones special plant species for raw material, through it is a series of solely Made of special chemical treatment and machining, itself has the characteristics that natural hydrophily and high-strength and high-modulus, because of its platymiscium Cell nature merisis is unartificial to be made, and surface is made to have very strong bond stress.Cellulose fibre mainly select cotton, Numb, bamboo material regenerated celulose fibre, granularity are 320-410 mesh.
The main component of aloe powder is aloe, aloe: for Monocotyledonae, A Fuhua section (also known as Asphodelaceae, only tail Careless section), the perennial evergreen herbaceous plant of Aloe.Also known as aloe barbadensis Miller, the Chinese aloe aloe, oily green onion, foreign aloe, kingfisher Ye Lu Luxuriant growth, U.S. aloe etc..Leafage is raw, big and plump, in seat shape or is born in stem top, the normal lanceolar of leaf or the short width of leaf, there is pointed tooth at edge Shape thorn.Inflorescence is umbrella shape, total shape, spike, cone etc., and color is in red, yellow or tool redness of the skin or complexion spot, six, petal, six pieces of gynoecium.Flower By the more joints of base portion at tubular.Aloe is to the protective effect of cell tissue and the tax of damaged cell palingenesis living.Select aloe Powder can effectively increase putty into people's greasy property and thickening properties after agent, can prevent and treat the dry and cracked deformation of cellulose fibre.Aloe The granularity of powder is 420-450 mesh.
Calcium oxide needs to be made calcium powder, and calcium powder is filler, mainly plays filling effect.Its granularity is 420-600 mesh.
Auxiliary agent includes defoaming agent, thickener and the fungicide that mass ratio is 1:2-4:2.
Defoaming agent includes the quality such as ethylene glycol siloxanes, dimethyl silicone polymer compounding.Select silane defoaming agent, surface Power is small, high surface activity, and defoaming power is strong, and dosage is few, at low cost.It is not miscible with water and most organic matters, to most of gas Bubble medium can defoam.It has preferable thermal stability, can use within the scope of 5 DEG C -150 DEG C broad temperature;Its chemistry Stability is preferable, difficult to use in acid, alkali, salting liquid, lossless product quality with other substance reactions as long as configuration is appropriate.
Thickener includes methylcellulose, hydroxypropyl methyl cellulose, sodium carboxymethylcellulose and hydroxyethyl cellulose etc. Quality compounding.
The easy moisture absorption of sodium carboxymethylcellulose, it is odorless, water can be directly dissolved in.Aqueous solution has good viscosity, stability, guarantor Protect colloidality and film forming, be not easy corrupt mildew, stablize under alkalinity and solutions of weak acidity, it is cheap can be with carboxymethyl cellulose Element collocation uses.
Hydroxyethyl cellulose (binder) be it is a kind of white or pale yellow powder, have it is good thickening, suspend, dispersion, The characteristics such as emulsification, bonding, film forming, protection moisture and offer protecting colloid.Water holding capacity is higher by one times than methylcellulose, has Preferable flow adjustment;Dispersibility is most compared with generally acknowledged methylcellulose and hydroxypropyl methyl cellulose for its dispersibility Difference, but protecting colloid ability is most strong.
The superiority of carboxymethyl cellulose includes thickening property, water-retaining property, metabolism inertia, film forming formability, dispersion stabilization Deng can be used as thickener, adhesive, lubricant.
The water retention property of hydroxypropyl methyl cellulose makes slurry be cracked because dry too fast after smearing, and enhancing is hardened Intensity afterwards.
Water-soluble flexible putty rubber powder is as binder in auxiliary material, can be modified to cement and toughening, to improve greasy The performance performance of sub- rubber powder.
Polypropylene fibre can be improved the cracking resistance of putty.
The superiority of starch includes thickening property, water-retaining property, metabolism inertia, film forming formability, dispersion stabilization etc..
Neopelex (bleeding agent) is white powder, can enhance the infiltration compatibility of putty and matrix.
Negative ion powder is the principle that anion is generated using nature, a kind of artificial synthesized or proportion complex mineral, Typically tourmaline powder+lanthanide series or rare earth element, wherein the ratio of rare earth element greatly exceeds tourmaline Powder, rare earth have accounted for 60% or more, and it is the effective means with germ and purification air is killed that anion, which is identified,.Its mechanism master After being anion in conjunction with bacterium, so that bacterium is generated the change of structure or the transfer of energy, lead to bacterial death, most final decline It is sunken to ground.Medical research shows that electronegative particle increases oxygen content in blood in air, is conducive to blood oxygen conveying, absorbs And utilization, have and promote human metabolism, improve human immunological competence, enhance human muscle energy, adjusts body function balance Effect.
Major function: (1) purificationization air: movement is that " Z " font is presented to the anion in anion powder in air 's.And conveying negative electrical charge is to bacterium, dust, smoke particles and water droplet etc., charge be polymerized to ball in conjunction with this this particle phase and Sink, to achieve the purpose that purify air.
(2) eliminate foreign flavor indoors and various pernicious gases: art work used in fitment process evaporates indoors The irritative gas such as benzene, formaldehyde, ketone, ammonia and daily life in leftovers leftovers acid smell, cigarette etc. is harmful to people's sheet different Taste, with wall cloth, curtain containing anion powder etc. or the coating containing anion powder, the negative aeroion of release can be effective It is eliminated on ground.
Preparation method:
The powder for being sieved to specified partial size is chosen, is at most base-material with weight, successively adds it from more to less by quality Its powder, and stir evenly, then add water-soluble flexible putty rubber powder, the polypropylene fibre, starch, dodecyl in auxiliary material Benzene sulfonic acid sodium salt, and stir evenly, finally mixed sub-material is added in agitator tank, adds auxiliary agent while adding water and stirring, Wherein the quality of water is powder, 0.8-1.1 times of auxiliary material quality sum.Auxiliary agent adds in three times, for the first time, for the second time, for the third time The mass ratio of addition is 1:2:5.
Specific embodiment 1
A kind of environmental friendly putty, it is comprised the following components in parts by weight, pulvis: 22 parts of seaweed soil, and 18 parts of mud stone, aloe powder 10 Part, six 20 parts of ring stones, 15 parts of cellulose fibre, 15 parts of calcium oxide;12 parts of auxiliary agent, auxiliary material: 10 parts of water-soluble flexible putty rubber powder, 5 parts of polypropylene fibre, 3 parts of starch, 0.3 part of neopelex, 0.5 part of negative ion powder;
Specific embodiment 2
A kind of environmental friendly putty, it is comprised the following components in parts by weight, pulvis: 20 parts of seaweed soil, and 22 parts of mud stone, aloe powder 12 Part, six 15 parts of ring stones, 10 parts of cellulose fibre, 12 parts of calcium oxide;12 parts of auxiliary agent, auxiliary material: 15 parts of water-soluble flexible putty rubber powder, 3 parts of polypropylene fibre, 4 parts of starch, 0.5 part of neopelex, 0.2 part of negative ion powder;
Specific embodiment 3
A kind of environmental friendly putty, it is comprised the following components in parts by weight, pulvis: 28 parts of seaweed soil, and 15 parts of mud stone, aloe powder 8 Part, six 25 parts of ring stones, 18 parts of cellulose fibre, 20 parts of calcium oxide;15 parts of auxiliary agent, auxiliary material: 5 parts of water-soluble flexible putty rubber powder, 8 parts of polypropylene fibre, 1 part of starch, 0.1 part of neopelex, 0.8 part of negative ion powder.
In accordance with the above-mentioned embodiment 1,2,3 proportion and the putty of associated production technique preparation, it is all to have project through detecting Meet the standard requirements of " architecture indoor putty " JG/T3049-1998, it is qualified.Test the result is as follows:
In accordance with the above-mentioned embodiment 1, the putty of 2,3 formula preparation, is detected after Specific construction, testing result is as follows:
By above-mentioned detection it is found that putty water-proofing anticracking of the invention is strong, caking ability is high, has excellent processing performance With application property.
Putty of the invention, water-proofing anticracking is strong, and caking ability is high, and non-toxic and tasteless, can effectively prevent cement shrinkage tortoise Split, have many advantages, such as it is good can application property, feel lubrication, reduce curing time.
A kind of environmental friendly putty of the invention has good ductility, can effectively prevent metope cracking jaundice, contain simultaneously Noxious material is few, environment protection health.
Obviously, above embodiment of the invention be only to clearly illustrate example of the present invention, and not be Restriction to embodiments of the present invention.For those of ordinary skill in the art, on the basis of the above description also It can make other variations or changes in different ways.Here all embodiments can not be exhaustive.It is all to belong to this The obvious changes or variations that the technical solution of invention is extended out are still in the scope of protection of the present invention.

Claims (8)

1. a kind of environmental friendly putty, it is characterised in that: it is comprised the following components in parts by weight,
Pulvis: 20-28 parts of seaweed soil, 15-22 parts of mud stone, 8-12 parts of aloe powder, six 15-25 parts of ring stones, cellulose fibre 10-18 parts, 12-20 parts of calcium oxide;
12-15 parts of auxiliary agent;
Auxiliary material: water-soluble 5-15 parts of flexible putty rubber powder, 3-8 parts of polypropylene fibre, 1-4 parts of starch, dodecyl benzene sulfonic acid 0.1-0.5 part of sodium, 0.2-0.8 part of negative ion powder;
The granularity of the seaweed soil is 500-580 mesh;
The granularity of the mud stone is 520-550 mesh;
The granularity of the six rings stone is 320-410 mesh;
The cellulose fibre select cotton, fiber crops, bamboo material regenerated celulose fibre, granularity is 320-410 mesh;
The granularity of the aloe powder is 420-450 mesh;
Calcium powder is made in the calcium oxide, its granularity of calcium powder is 420-600 mesh.
2. a kind of environmental friendly putty according to claim 1, it is characterised in that: it is comprised the following components in parts by weight, pulvis: 22 parts of seaweed soil, 18 parts of mud stone, 10 parts of aloe powder, six 20 parts of ring stones, 15 parts of cellulose fibre, 15 parts of calcium oxide;12 parts of auxiliary agent, Auxiliary material: 10 parts of water-soluble flexible putty rubber powder, 5 parts of polypropylene fibre, 3 parts of starch, 0.3 part of neopelex, bear from 0.5 part of sub- powder.
3. a kind of environmental friendly putty according to claim 1, it is characterised in that: it is comprised the following components in parts by weight, pulvis: 20 parts of seaweed soil, 22 parts of mud stone, 12 parts of aloe powder, six 15 parts of ring stones, 10 parts of cellulose fibre, 12 parts of calcium oxide;12 parts of auxiliary agent, Auxiliary material: 15 parts of water-soluble flexible putty rubber powder, 3 parts of polypropylene fibre, 4 parts of starch, 0.5 part of neopelex, bear from 0.2 part of sub- powder.
4. a kind of environmental friendly putty according to claim 1, it is characterised in that: it is comprised the following components in parts by weight, pulvis: 28 parts of seaweed soil, 15 parts of mud stone, 8 parts of aloe powder, six 25 parts of ring stones, 18 parts of cellulose fibre, 20 parts of calcium oxide;15 parts of auxiliary agent, Auxiliary material: 5 parts of water-soluble flexible putty rubber powder, 8 parts of polypropylene fibre, 1 part of starch, 0.1 part of neopelex, anion 0.8 part of powder.
5. a kind of environmental friendly putty according to claim 1, it is characterised in that: the auxiliary agent includes that mass ratio is 1:2-4:2 Defoaming agent, thickener, fungicide, the defoaming agent include the quality such as ethylene glycol siloxanes, dimethyl silicone polymer compounding;Institute Stating thickener includes that the quality such as methylcellulose, hydroxypropyl methyl cellulose, sodium carboxymethylcellulose and hydroxyethyl cellulose are multiple Match.
6. a kind of environmental friendly putty according to claim 1, it is characterised in that: be sieved to specified grain the preparation method comprises the following steps: choosing The powder of diameter is at most base-material with weight, successively adds other powders from more to less by quality, and stir evenly, then add Add water-soluble flexible putty rubber powder, polypropylene fibre, the starch, neopelex in auxiliary material, and stir evenly, finally Mixed sub-material is added in agitator tank, auxiliary agent is added while adding water and stirring, stirs evenly.
7. a kind of environmental friendly putty according to claim 6, it is characterised in that: the quality of water is powder, auxiliary in preparation method 0.8-1.1 times for expecting quality sum.
8. a kind of environmental friendly putty according to claim 6, it is characterised in that: auxiliary agent adds in three times in preparation method, the Once, the mass ratio added for the second time, for the third time is 1:2:5.
CN201910772000.6A 2019-08-21 2019-08-21 A kind of environmental friendly putty Pending CN110330833A (en)

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Cited By (1)

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CN113831781A (en) * 2021-10-15 2021-12-24 浙江建工新材料有限公司 Waterproof, mildewproof and fireproof inorganic environment-friendly putty

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