CN110330804A - A kind of full degradable mulch of addition biomass fiber controllable biological base - Google Patents

A kind of full degradable mulch of addition biomass fiber controllable biological base Download PDF

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Publication number
CN110330804A
CN110330804A CN201910588058.5A CN201910588058A CN110330804A CN 110330804 A CN110330804 A CN 110330804A CN 201910588058 A CN201910588058 A CN 201910588058A CN 110330804 A CN110330804 A CN 110330804A
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CN
China
Prior art keywords
straw
mulch
wheat
biomass fiber
degradable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910588058.5A
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Chinese (zh)
Inventor
赵晓微
赵忠华
张小蕊
李连琦
吴翔
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Daqing Zhenghe Energy Technology Development Co Ltd
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Daqing Zhenghe Energy Technology Development Co Ltd
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Publication date
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Priority to CN201910588058.5A priority Critical patent/CN110330804A/en
Publication of CN110330804A publication Critical patent/CN110330804A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G13/00Protecting plants
    • A01G13/02Protective coverings for plants; Coverings for the ground; Devices for laying-out or removing coverings
    • A01G13/0256Ground coverings
    • A01G13/0268Mats or sheets, e.g. nets or fabrics
    • A01G13/0275Films
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2397/00Characterised by the use of lignin-containing materials
    • C08J2397/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/11Esters; Ether-esters of acyclic polycarboxylic acids
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/28Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture specially adapted for farming

Abstract

The invention discloses a kind of full degradable mulch of addition biomass fiber controllable biological base, the processing step of the preparation method of mulch is as follows: pretreatment: the wheat-straw of collection being cleaned using clear water, clean the sewage generated, pass through the layering of filter screen, Reusability, environmental protection and energy saving;Drying: the wheat-straw after cleaning passes through after stalk drying machine drying;Decoloration detoxification: the wheat-straw of drying is put into hydrolytic tank, the ratio of solution is in hydrolytic tank, activated carbon dosage: hydrolyzate volume=2: 1, temperature is 35 DEG C, a kind of full degradable mulch of addition biomass fiber controllable biological base of the invention, by the way that biomass fiber is added, biomass fiber 200--1500 mesh micro mist includes wheat-straw, stalk, rice straw, one of animal hair etc. or several mixture, make full use of resource, it is more environmentally friendly, the mulch produced is degradable, to promotion China's soil pollution treatment, the aspect that develops eco-agriculture has the application prospect being widely popularized.

Description

A kind of full degradable mulch of addition biomass fiber controllable biological base
Technical field
The present invention relates to a kind of mulch, the in particular to a kind of full degradable mulch of addition biomass fiber controllable biological base, Belong to biodegradation material technical field.
Background technique
Mulch, that is, covered ground film, usually transparent or black PE film, also has green, silver thin film, covers for ground Lid keeps soil moisture to improve the soil moisture, maintains soil texture, prevents pest attacks crop and certain micro-organisms from causing Disease etc., promote the function of plant growth.Mulch seems thin layer, but acts on quite big.Can not only improve ground temperature, Water conservation, soil conservation, fertilizer conservation improve fertilizer efficiency, and there are also weed eradication, disease-resistant, waterlogging-resistant, suppression salt of taking precautions against drought to keep a full stand of seedings, improve photo-thermal item near the ground Part makes the multiple functions such as product hygiene.
Traditional mulch uses polyethylene film, can neither degrade, and be difficult to recycle, residual film is not only the one of " white pollution " A important sources also cause the sustainable use of land resource and seriously threaten, and remaining mulch in the soil can not only shadow Crop growth is rung, also agricultural machinery is caused to damage.
Summary of the invention
The purpose of the present invention is to provide a kind of full degradable mulch of addition biomass fiber controllable biological base, on solving The traditional mulch proposed in background technique is stated using polyethylene film, can neither be degraded, and be difficult to recycle, residual film is not only " white One important sources of color pollution ", also cause the problem of seriously threatening to the sustainable use of land resource.
To achieve the above object, the invention provides the following technical scheme: a kind of addition biomass fiber controllable biological base is complete The processing step of degradable mulch, the preparation method of mulch is as follows:
Pretreatment: the wheat-straw of collection is cleaned using clear water, cleans the sewage of generation, passes through the mistake layer by layer of filter screen Filter, Reusability, environmental protection and energy saving;
Drying: the wheat-straw after cleaning passes through after stalk drying machine drying;
Decoloration detoxification: the wheat-straw of drying is put into hydrolytic tank, and the ratio of solution is activated carbon dosage in hydrolytic tank: Hydrolyzate volume=2: 1, temperature is 35 DEG C, time 60min, pH 4.0, and percent of decolourization with this condition is 88.11%, also Raw sugar loss late is 48.54%, and the removal rate of furfural reaches 74.91%, and phenolic compound can be removed all, again passes by baking Dry step dries wheat-straw;
It crushes: after the wheat-straw of drying is air-cooled, putting into pulverizer, cross 80~100 mesh when wheat-straw exports after crushing Sieve, unsifted stalk foam grind and crossed 16~20 meshes again;
Macromolecule mixing: the stalk foam of sieving, calcium carbonate, dioctyl sebacate, reactive assistant, resists aldehyde crosslinking agent Oxygen agent, lubricant, ultraviolet absorbing agent, light stabilizer, water and microbial deodorant mixing are 80~90 DEG C in temperature, and lead to It crosses High-efficient Stirrer and stirs 20~30min, reach mixed uniformly purpose, degradable thick mixture is transferred to spiral In formula cooler, it is stirred cooling;
Granulation: degradable granular materials is squeezed out by twin-screw extrusion granulator;
Blown film: high speed inflation film manufacturing machine is used, degradable granular materials is blow molded into the full degradable mulch of controllable biological base.
As a preferred technical solution of the present invention, the biomass fiber 200--1500 mesh micro mist of the mulch can be One of wheat-straw, stalk, rice straw, animal hair etc. or several mixture.
As a preferred technical solution of the present invention, the exhaust gas generated in the baking step, extremely by pipeline The input terminal of stalk dryer, preheats wheat-straw, final exhaust gas by purify it is up to standard after, be discharged into atmosphere.
As a preferred technical solution of the present invention, the ultraviolet absorbing agent selects UVP-327.
As a preferred technical solution of the present invention, the degradable granular materials in the granulation step is irregular Shape.
As a preferred technical solution of the present invention, the mulch in the blown film step is wound using winder, packaging, Storage.
Compared with prior art, the beneficial effects of the present invention are: a kind of addition biomass fiber controllable biological base of the present invention Full degradable mulch, by the way that biomass fiber is added, biomass fiber 200--1500 mesh micro mist includes wheat-straw, stalk, rice One of bar, animal hair etc. or several mixture make full use of resource, and more environmentally friendly, the mulch produced is degradable, raw Production method is simple, at low cost, has the application prospect being widely popularized to promotion China's soil pollution treatment, the aspect that develops eco-agriculture.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
Embodiment, the present invention provides a kind of full degradable mulch of addition biomass fiber controllable biological base, the systems of mulch The processing step of Preparation Method is as follows:
Pretreatment: the wheat-straw of collection is cleaned using clear water, cleans the sewage of generation, passes through the mistake layer by layer of filter screen Filter, Reusability, environmental protection and energy saving;
Drying: the wheat-straw after cleaning passes through after stalk drying machine drying;
Decoloration detoxification: the wheat-straw of drying is put into hydrolytic tank, and the ratio of solution is activated carbon dosage in hydrolytic tank: Hydrolyzate volume=2: 1, temperature is 35 DEG C, time 60min, pH 4.0, and percent of decolourization with this condition is 88.11%, also Raw sugar loss late is 48.54%, and the removal rate of furfural reaches 74.91%, and phenolic compound can be removed all, again passes by baking Dry step dries wheat-straw;
It crushes: after the wheat-straw of drying is air-cooled, putting into pulverizer, cross 80~100 mesh when wheat-straw exports after crushing Sieve, unsifted stalk foam grind and crossed 16~20 meshes again;
Macromolecule mixing: the stalk foam of sieving, calcium carbonate, dioctyl sebacate, reactive assistant, resists aldehyde crosslinking agent Oxygen agent, lubricant, ultraviolet absorbing agent, light stabilizer, water and microbial deodorant mixing are 80~90 DEG C in temperature, and lead to It crosses High-efficient Stirrer and stirs 20~30min, reach mixed uniformly purpose, degradable thick mixture is transferred to spiral In formula cooler, it is stirred cooling;
Granulation: degradable granular materials is squeezed out by twin-screw extrusion granulator;
Blown film: high speed inflation film manufacturing machine is used, degradable granular materials is blow molded into the full degradable mulch of controllable biological base.
Preferably, the biomass fiber 200--1500 mesh micro mist of mulch can be wheat-straw, stalk, rice straw, animal hair etc. One of or several mixture;The exhaust gas generated in baking step, it is right by pipeline to the input terminal of stalk dryer Wheat-straw is preheated, final exhaust gas by purify it is up to standard after, be discharged into atmosphere, environmental protection;Ultraviolet absorbing agent is selected UVP-327;Degradable granular materials in granulation step is irregular shape;Mulch in blown film step is received using winder Volume is packed, and storage is convenient for collecting, is easy to transport.
When specifically used, a kind of full degradable mulch of addition biomass fiber controllable biological base of the invention is passed sequentially through It states step and produces mulch, by the way that biomass fiber is added, biomass fiber degradable mulch is crosslinked by biomass fiber, aldehydes Agent, calcium carbonate, dioctyl sebacate, reactive assistant, antioxidant, lubricant, ultraviolet absorbing agent, light stabilizer, water and micro- It is made up after biological deodorant mixing of multiple tracks technique, the mulch the produced oxygen after exposing to the weather drenches with rain in use Change very fast, the destruction by machinery after use, causes mulch can be degradable at 6-9 a month, therefore in daily agro-farming process In, using degradable mulch, predetermined quantity in advance is needed, facilitates and carries out plantation crops, crops is made to reach preferable growth, Biomass fiber 200--1500 mesh micro mist in degradable mulch include one of wheat-straw, stalk, rice straw, animal hair etc. or Several mixture makes full use of resource, and more environmentally friendly, the mulch produced is degradable, and production method is simple, at low cost, There is the application prospect being widely popularized in terms of to pushing the pollution treatment of China's soil, developing eco-agriculture.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with A variety of variations, modification, replacement can be carried out to these embodiments without departing from the principles and spirit of the present invention by understanding And modification, the scope of the present invention is defined by the appended.

Claims (6)

1. a kind of full degradable mulch of addition biomass fiber controllable biological base, which is characterized in that the work of the preparation method of mulch Steps are as follows for skill:
Pretreatment: the wheat-straw of collection is cleaned using clear water, cleans the sewage of generation, by the layering of filter screen, instead It is multiple to use, environmental protection and energy saving;
Drying: the wheat-straw after cleaning passes through after stalk drying machine drying;
Decoloration detoxification: the wheat-straw of drying is put into hydrolytic tank, and the ratio of solution is activated carbon dosage in hydrolytic tank: hydrolysis Liquid product=2: 1, temperature are 35 DEG C, time 60min, pH 4.0, and percent of decolourization with this condition is 88.11%, reduced sugar Loss late is 48.54%, and the removal rate of furfural reaches 74.91%, and phenolic compound can be removed all, again passes by drying step Suddenly wheat-straw is dried;
It crushes: after the wheat-straw of drying is air-cooled, putting into pulverizer, cross 80~100 meshes when wheat-straw exports after crushing, not The stalk foam of sieving grinds and crossed 16~20 meshes again;
Macromolecule mixing: the stalk foam of sieving, aldehyde crosslinking agent, calcium carbonate, dioctyl sebacate, reactive assistant, antioxidant, Lubricant, ultraviolet absorbing agent, light stabilizer, water and microbial deodorant mixing are 80~90 DEG C in temperature, and by efficient Blender stirs 20~30min, reaches mixed uniformly purpose, degradable thick mixture is transferred to spiral cooling In machine, it is stirred cooling;
Granulation: degradable granular materials is squeezed out by twin-screw extrusion granulator;
Blown film: high speed inflation film manufacturing machine is used, degradable granular materials is blow molded into the full degradable mulch of controllable biological base.
2. a kind of full degradable mulch of addition biomass fiber controllable biological base according to claim 1, it is characterised in that: The biomass fiber 200--1500 mesh micro mist of the mulch can be one of wheat-straw, stalk, rice straw, animal hair etc. or several The mixture of kind.
3. a kind of full degradable mulch of addition biomass fiber controllable biological base according to claim 1, it is characterised in that: The exhaust gas generated in the baking step preheats wheat-straw, most by pipeline to the input terminal of stalk dryer Whole exhaust gas by purify it is up to standard after, be discharged into atmosphere.
4. a kind of full degradable mulch of addition biomass fiber controllable biological base according to claim 1, it is characterised in that: The ultraviolet absorbing agent selects UVP-327.
5. a kind of full degradable mulch of addition biomass fiber controllable biological base according to claim 1, it is characterised in that: Degradable granular materials in the granulation step is irregular shape.
6. a kind of full degradable mulch of addition biomass fiber controllable biological base according to claim 1, it is characterised in that: Mulch in the blown film step is wound using winder, is packed, storage.
CN201910588058.5A 2019-07-02 2019-07-02 A kind of full degradable mulch of addition biomass fiber controllable biological base Pending CN110330804A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113214844A (en) * 2021-04-29 2021-08-06 杭州绿兴环保材料有限公司 Full-degradable mulching film for planting mountain rice and preparation method thereof
CN113512217A (en) * 2021-07-22 2021-10-19 东华大学 Clean production method of straw-based mulching film

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1036140C (en) * 1992-12-18 1997-10-15 中国国际科技促进会 Vegetable fibre film product and its process
US20110073008A1 (en) * 2009-09-29 2011-03-31 Young Kwan Lee Biodegradable thermoplastic resin composition comprising cellulose derivatives and surface-treated natural fiber
CN106566261A (en) * 2016-10-25 2017-04-19 刘岱晨 Crop waste degradable mulching film and preparing method thereof
CN109096786A (en) * 2018-08-23 2018-12-28 中国热带农业科学院农产品加工研究所 A kind of degradable composite mulching film and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1036140C (en) * 1992-12-18 1997-10-15 中国国际科技促进会 Vegetable fibre film product and its process
US20110073008A1 (en) * 2009-09-29 2011-03-31 Young Kwan Lee Biodegradable thermoplastic resin composition comprising cellulose derivatives and surface-treated natural fiber
CN106566261A (en) * 2016-10-25 2017-04-19 刘岱晨 Crop waste degradable mulching film and preparing method thereof
CN109096786A (en) * 2018-08-23 2018-12-28 中国热带农业科学院农产品加工研究所 A kind of degradable composite mulching film and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113214844A (en) * 2021-04-29 2021-08-06 杭州绿兴环保材料有限公司 Full-degradable mulching film for planting mountain rice and preparation method thereof
CN113512217A (en) * 2021-07-22 2021-10-19 东华大学 Clean production method of straw-based mulching film

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Application publication date: 20191015