CN110295410A - One kind plus hydrophilic easy contaminate of bullet imitate cotton fiber and its manufacturing method - Google Patents

One kind plus hydrophilic easy contaminate of bullet imitate cotton fiber and its manufacturing method Download PDF

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Publication number
CN110295410A
CN110295410A CN201910545083.5A CN201910545083A CN110295410A CN 110295410 A CN110295410 A CN 110295410A CN 201910545083 A CN201910545083 A CN 201910545083A CN 110295410 A CN110295410 A CN 110295410A
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CN
China
Prior art keywords
hydrophilic
roller
polyester
cotton
easy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910545083.5A
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Chinese (zh)
Inventor
孙德荣
孙德明
张堂标
朱延伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XUZHOU SILK FIBER TECHNOLOGY Co Ltd
Original Assignee
XUZHOU SILK FIBER TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XUZHOU SILK FIBER TECHNOLOGY Co Ltd filed Critical XUZHOU SILK FIBER TECHNOLOGY Co Ltd
Priority to CN201910545083.5A priority Critical patent/CN110295410A/en
Publication of CN110295410A publication Critical patent/CN110295410A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/688Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
    • C08G63/6884Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6886Dicarboxylic acids and dihydroxy compounds
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G1/00Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics
    • D02G1/02Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist
    • D02G1/0206Producing crimped or curled fibres, filaments, yarns, or threads, giving them latent characteristics by twisting, fixing the twist and backtwisting, i.e. by imparting false twist by false-twisting
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/08Interlacing constituent filaments without breakage thereof, e.g. by use of turbulent air streams
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J1/00Modifying the structure or properties resulting from a particular structure; Modifying, retaining, or restoring the physical form or cross-sectional shape, e.g. by use of dies or squeeze rollers
    • D02J1/22Stretching or tensioning, shrinking or relaxing, e.g. by use of overfeed and underfeed apparatus, or preventing stretch
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J13/00Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass
    • D02J13/001Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass in a tube or vessel

Abstract

The invention discloses one kind plus play the hydrophilic imitative cotton fiber of easy dye, polyester POY long filament is used to be made for raw material, it is characterized in that, the polyester POY long filament is that hydrophilic easy contaminate of polyester imitates cotton POY, the polyester imitates cotton POY and generates the hydrophilic imitative cotton polyester fondant of easy dye by chemical reaction by polypropylene glycol, 5-sodium sulfo isophthalate, antimony glycol, cobalt acetate, stabilizer Irganox1010, triphenyl phosphite, titanium dioxide and p-phthalic acid, ethylene glycol, then is directly spun.Because the hydrophilic easy imitative cotton POY of dye of polyester is with preferable cotton sense, the gloss of cotton, regain, chromatophilia, the hydrophilic imitative cotton fiber of easy dye is played with good imitative cotton effect by adding bullet production technology that polyester can be made to add.

Description

One kind plus hydrophilic easy contaminate of bullet imitate cotton fiber and its manufacturing method
Technical field
The present invention relates to one kind, and elastic fibre, more particularly to a kind of hydrophilic easy contaminate of plus bullet to be added to imitate cotton fiber and its manufacturer Method.
Background technique
The preoriented yarn (POY) that spinning is produced generally is not directly used for weaving, it is necessary to can after post-processing is handled It uses.The work for adding bullet is exactly, by stretching and deformation process, so that POY is transformed into physical property more steady using POY as raw material It is fixed, it can be directly used for woven draw textured yarn (DTY).It is inquired in presently disclosed data, functional form adds elater mainly and have anti- Electrostatic, noctilucence, resistant to lodging, uvioresistant etc., but have no that the relevant functional form polyester of imitative cotton adds elater.
Summary of the invention
The one kind for adding product function in elater incomplete the purpose of the present invention is to solve existing capability type and designing adds bullet The hydrophilic easy product function type for contaminating imitative cotton fiber, increase plus elater.It is a further object to provide one kind plus bullet parents Water easily contaminates the manufacturing method of imitative cotton fiber.Method of the invention is the advantages of keeping polyester texturing craft stream, if process is short, the energy Consume it is low, other than quality is stablized etc., additionally it is possible to the effective imitative cotton effect for embodying polyester and adding elater.Technology solution party of the invention Case is:
One kind plus hydrophilic easy contaminate of bullet imitate cotton fiber, use polyester POY long filament to be made for raw material, which is characterized in that described Polyester POY long filament is that hydrophilic easy contaminate of polyester imitates cotton POY.Because of the hydrophilic easy light for contaminating imitative cotton POY and there is preferable cotton sense, cotton of polyester Pool, regain, chromatophilia play the hydrophilic imitative cotton fiber of easy dye with good imitative by adding bullet production technology that polyester can be made to add Cotton effect.
Further explanation of the invention:
The polyester it is hydrophilic it is easy contaminate imitative cotton POY by polypropylene glycol, 5-sodium sulfo isophthalate, antimony glycol, cobalt acetate, Stabilizer Irganox1010, triphenyl phosphite, titanium dioxide and p-phthalic acid, ethylene glycol are generated by chemical reaction Hydrophilic easy contaminate imitates cotton polyester fondant, then is directly spun, in which: the polypropylene glycol additive amount is that the hydrophilic easy imitative cotton of dye of gained gathers 2.5%-the 10% of ester gross mass, the 5-sodium sulfo isophthalate are that hydrophilic easy contaminate of gained imitates cotton polyester gross mass 2.5% -5%, the antimony glycol additive amount is that hydrophilic easy contaminate of gained imitates 0.02%-the 0.03% of cotton polyester gross mass, acetic acid Cobalt additive amount is that hydrophilic easy contaminate of gained imitates 0.004%-the 0.006% of cotton polyester gross mass, stabilizer Irganox1010 additive amount 0.03%-the 0.05% of cotton polyester gross mass is imitated for hydrophilic easy contaminate of gained, triphenyl phosphite additive amount is that the hydrophilic easy dye of gained is imitative 0.01%-the 0.02% of cotton polyester gross mass, titanium dioxide additive amount are that hydrophilic easy contaminate of gained imitates the 0%-of cotton polyester gross mass 5%。
The technical solution for completing the 2nd invention task of the application is: the above plus the system for playing the hydrophilic imitative cotton fiber of easy dye Make method, which is characterized in that the method are as follows: polyester is hydrophilic easy to contaminate imitative cotton POY through yarn cutter, the 0th roller, pre- network, the One roller, threading end bar, twist arrester, deformation hot box, coldplate, scroll tube, the second roller, master network device, shaping heat box, third sieve Drawing, oil tanker and winding form plus play the hydrophilic imitative cotton fiber of easy dye.
More optimized and more specifically, each step operation of manufacturing method of the present invention is as follows: the pressure of pre- Network device is 0.1-0.3MPa, the pressure of master network device are 0.1-0.3MPa, and the second roller speed is 350-550m/min, the second roller and the The draw ratio ratio of zero roller is 1.0-1.1, and the draw ratio ratio of the second roller and first roller is 1.0-1.1, third roller and the The draw ratio of two rollers is -5.0%- -4%, and it is -5.0%--4% that the winding of winding speed and the second roller, which compares, false twisting orientation For " S " type or " Z " type, deformation hot box temperature is 140-160 DEG C, and shaping heat box temperature is 130-150 DEG C, oil level 2-3cm.
It optimizes and most in detail, the detailed steps operation of manufacturing method of the present invention is as follows:
The pressure of pre- Network device is 0.2MPa, and the pressure of master network device is 0.15MPa, and the second roller speed is 400m/min, the The draw ratio ratio of two rollers and the 0th roller is 1.03, and the draw ratio ratio of the second roller and first roller is 1.04, third roller Draw ratio with the second roller is -4.5%, and it is -3.5% that the winding of winding speed and the second roller, which compares, and false twisting orientation is " S " type, Deformation hot box temperature is 150 DEG C, and shaping heat box temperature is 135 DEG C, oil level 2.5cm.
Detailed description of the invention
Fig. 1 is that of the invention adding plays the hydrophilic imitative cotton fiber process flow schematic diagram of easy dye.
Specific embodiment
The present invention will add the case study on implementation for playing the hydrophilic imitative cotton fiber of easy dye to further illustrate this hair with following production 80S It is bright, but protection scope of the present invention is not limited to case study on implementation.
Polyester is hydrophilic easy to contaminate imitative cotton POY by polypropylene glycol, 5-sodium sulfo isophthalate, antimony glycol, cobalt acetate, steady Determine agent Irganox1010, triphenyl phosphite, titanium dioxide and p-phthalic acid, ethylene glycol and parent is generated by chemical reaction Water easily contaminates imitative cotton polyester fondant, then is directly spun, in which: the polypropylene glycol additive amount is that hydrophilic easy contaminate of gained imitates cotton polyester 2.5%-the 10% of gross mass, the 5-sodium sulfo isophthalate are that hydrophilic easy contaminate of gained imitates cotton polyester gross mass 2.5% -5%, the antimony glycol additive amount is that hydrophilic easy contaminate of gained imitates 0.02%-the 0.03% of cotton polyester gross mass, acetic acid Cobalt additive amount is that hydrophilic easy contaminate of gained imitates 0.004%-the 0.006% of cotton polyester gross mass, stabilizer Irganox1010 additive amount 0.03%-the 0.05% of cotton polyester gross mass is imitated for hydrophilic easy contaminate of gained, triphenyl phosphite additive amount is that the hydrophilic easy dye of gained is imitative 0.01%-the 0.02% of cotton polyester gross mass, titanium dioxide additive amount are that hydrophilic easy contaminate of gained imitates the 0%-of cotton polyester gross mass 5%。
Use specification for the polyester of 83dtex/62F it is hydrophilic it is easy contaminate imitative cotton POY, through yarn cutter, the 0th roller, pre- network, the One roller, threading end bar, twist arrester, deformation hot box, coldplate, scroll tube, the second roller, master network device, shaping heat box, third sieve Drawing, oil tanker and winding form plus play the hydrophilic imitative cotton fiber of easy dye.Wherein: the pressure of pre- Network device is 0.2MPa, master network device Pressure is 0.15MPa, and the second roller speed is 400m/min, and the draw ratio ratio of the second roller and the 0th roller is 1.03, second The draw ratio of roller and first roller ratio is 1.04, and the draw ratio of third roller and the second roller is -4.5%, winding speed and the It is -3.5% that the winding of two rollers, which compares, and false twisting orientation is " S " type, and deformation hot box temperature is 150 DEG C, and shaping heat box temperature is 135 DEG C, oil level 2.5cm.
80S made from this method adds the hydrophilic easy physical property for contaminating imitative cotton fiber of bullet to be fiber number: 84.78dtex;Internet pricing: 127/meter, elongation at break: 21.91%;Oil content: 2.52%;Crimp shrinkage: 5.11%, curling stability: -3.99%;Boiling water Shrinking percentage: 5.06%;Intensity: 1.88cN/dtex.This adds the hydrophilic easy imitative cotton fiber of dye of bullet to can be widely applied to water spray, jet, circle The weaving process such as machine, for the cloth being made into after ionic dye dyeing and finishing, feel is soft, and color is low and deep, room temperature colouring, high regain, With good imitative cotton effect.
When present invention combination above embodiments are to be illustrated, those skilled in the art should be noted that can be to this Invention carries out various change and is replaced to component.It is, therefore, to be understood that the present invention is not limited only to best mould disclosed herein The specific embodiment of formula implements the present invention.Under the premise of without departing substantially from present inventive concept, all changes and modification each fall within institute In attached scope of protection of the claims.

Claims (5)

1. one kind plus hydrophilic easy contaminate of bullet imitate cotton fiber, polyester POY long filament is used to be made for raw material, which is characterized in that described Polyester POY long filament to be that polyester is hydrophilic easy contaminate imitative cotton POY.
2. according to claim 1 plus play and hydrophilic easy contaminate imitative cotton fiber, which is characterized in that the polyester imitate cotton POY by Polypropylene glycol, 5-sodium sulfo isophthalate, antimony glycol, cobalt acetate, stabilizer Irganox1010, triphenyl phosphite, Titanium dioxide and p-phthalic acid, ethylene glycol by chemical reaction generate it is hydrophilic it is easy contaminate imitative cotton polyester fondant, then directly spun and At, in which: the polypropylene glycol additive amount is that hydrophilic easy contaminate of gained imitates 2.5%-the 10% of cotton polyester gross mass, the isophthalic Dioctyl phthalate -5- sodium sulfonate is that hydrophilic easy contaminate of gained imitates 2.5%-the 5% of cotton polyester gross mass, and the antimony glycol additive amount is Hydrophilic easy contaminate of gained imitates 0.02%-the 0.03% of cotton polyester gross mass, and cobalt acetate additive amount is that the hydrophilic easy imitative cotton polyester of dye of gained is total 0.004%-the 0.006% of quality, stabilizer Irganox1010 additive amount are that hydrophilic easy contaminate of gained imitates cotton polyester gross mass 0.03% -0.05%, triphenyl phosphite additive amount is that hydrophilic easy contaminate of gained imitates 0.01%-the 0.02% of cotton polyester gross mass, two Titanium oxide additive amount is that hydrophilic easy contaminate of gained imitates 0%-the 5% of cotton polyester gross mass.
3. the hydrophilic easy imitative cotton fiber of dye of according to claim 1 plus bullet, which is characterized in that described adding plays hydrophilic easy contaminate and imitate Cotton fiber uses following manufacturing process to obtain plus plays the hydrophilic imitative cotton fiber of easy dye: the hydrophilic easy imitative cotton POY of dye of polyester is through chopping Device, the 0th roller, pre- network, first roller, threading end bar, twist arrester, deformation hot box, coldplate, scroll tube, the second roller, master Network device, shaping heat box, third roller, oil tanker and winding form plus play the hydrophilic imitative cotton fiber of easy dye.
4. manufacturing method that is according to claim 3 plus playing the hydrophilic imitative cotton fiber of easy dye, which is characterized in that pre- Network device Pressure is 0.1-0.3MPa, and the pressure of master network device is 0.1-0.3MPa, and the second roller speed is 350-550m/min, second sieve Drawing with the draw ratio ratio of the 0th roller is 1.0-1.1, and the draw ratio ratio of the second roller and first roller is 1.0-1.1, third sieve Drawing with the draw ratio of the second roller is -5.0%- -4%, and it is -5.0%--4% that the winding of winding speed and the second roller, which compares, vacation Twisting orientation is " S " type or " Z " type, and deformation hot box temperature is 140-160 DEG C, and shaping heat box temperature is 130-150 DEG C, oil level 2- 3cm。
5. manufacturing method that is according to claim 4 plus playing the hydrophilic imitative cotton fiber of easy dye, which is characterized in that pre- Network device Pressure is 0.2MPa, and the pressure of master network device is 0.15MPa, and the second roller speed is 400m/min, the second roller and the 0th sieve The draw ratio ratio of drawing is 1.03, and the draw ratio ratio of the second roller and first roller is 1.04, and third roller is led with the second roller It stretches than being -4.5%, it is -3.5% that the winding of winding speed and the second roller, which compares, and false twisting orientation is " S " type, and deformation hot box temperature is 150 DEG C, shaping heat box temperature is 135 DEG C, oil level 2.5cm.
CN201910545083.5A 2019-06-21 2019-06-21 One kind plus hydrophilic easy contaminate of bullet imitate cotton fiber and its manufacturing method Pending CN110295410A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116254629A (en) * 2022-12-10 2023-06-13 桐昆集团股份有限公司 Preparation method of elastic fiber easy to dye at normal temperature

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101020743A (en) * 2007-03-24 2007-08-22 施建强 Prepn process of copolyester capable of being dyed deeply with cationic dye
CN102321934A (en) * 2011-08-29 2012-01-18 苏州金辉纤维新材料有限公司 Cotton imitation polyester filament with high hygroscopicity and preparation method thereof
CN102558526A (en) * 2011-12-09 2012-07-11 东华大学 Hydrophilic copolyester chip and preparation method thereof
CN103710782A (en) * 2013-10-30 2014-04-09 上海德福伦化纤有限公司 High-moisture-absorption easy-dying cotton-imitating polyester short fiber and preparation method thereof
CN107201567A (en) * 2017-06-22 2017-09-26 江苏三房巷集团有限公司 A kind of preparation method of the super imitative cotton polyester fiber of continuous polymerization fused mass directly spinning
CN109023616A (en) * 2018-09-10 2018-12-18 江苏德力化纤有限公司 It is a kind of for producing the preparation method of super fine denier pro-skin type polyester filament
CN109281009A (en) * 2018-08-28 2019-01-29 桐乡市恒基差别化纤维有限公司 A kind of production technology of crystal cotton

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101020743A (en) * 2007-03-24 2007-08-22 施建强 Prepn process of copolyester capable of being dyed deeply with cationic dye
CN102321934A (en) * 2011-08-29 2012-01-18 苏州金辉纤维新材料有限公司 Cotton imitation polyester filament with high hygroscopicity and preparation method thereof
CN102558526A (en) * 2011-12-09 2012-07-11 东华大学 Hydrophilic copolyester chip and preparation method thereof
CN103710782A (en) * 2013-10-30 2014-04-09 上海德福伦化纤有限公司 High-moisture-absorption easy-dying cotton-imitating polyester short fiber and preparation method thereof
CN107201567A (en) * 2017-06-22 2017-09-26 江苏三房巷集团有限公司 A kind of preparation method of the super imitative cotton polyester fiber of continuous polymerization fused mass directly spinning
CN109281009A (en) * 2018-08-28 2019-01-29 桐乡市恒基差别化纤维有限公司 A kind of production technology of crystal cotton
CN109023616A (en) * 2018-09-10 2018-12-18 江苏德力化纤有限公司 It is a kind of for producing the preparation method of super fine denier pro-skin type polyester filament

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116254629A (en) * 2022-12-10 2023-06-13 桐昆集团股份有限公司 Preparation method of elastic fiber easy to dye at normal temperature

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Application publication date: 20191001