CN110251406B - Sunscreen spray - Google Patents

Sunscreen spray Download PDF

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Publication number
CN110251406B
CN110251406B CN201910617578.4A CN201910617578A CN110251406B CN 110251406 B CN110251406 B CN 110251406B CN 201910617578 A CN201910617578 A CN 201910617578A CN 110251406 B CN110251406 B CN 110251406B
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sunscreen spray
mixture
sunscreen
alcohol
spray
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CN110251406A (en
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于寒
王丽辉
林锦雄
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Guangzhou Aibei Biological Technology Co Ltd
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Guangzhou Aibei Biological Technology Co Ltd
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04Dispersions; Emulsions
    • A61K8/046Aerosols; Foams
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29Titanium; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35Ketones, e.g. benzophenone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37Esters of carboxylic acids
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4953Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom containing pyrimidine ring derivatives, e.g. minoxidil
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/496Triazoles or their condensed derivatives, e.g. benzotriazoles
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/67Vitamins
    • A61K8/678Tocopherol, i.e. vitamin E
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783Angiosperms [Magnoliophyta]
    • A61K8/9789Magnoliopsida [dicotyledons]
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59Mixtures
    • A61K2800/592Mixtures of compounds complementing their respective functions

Abstract

The invention relates to a sunscreen spray which comprises the following components in percentage by weight: 1-9.5% of titanium dioxide, 2-10% of octyl methoxycinnamate, 0.5-7.5% of methylene bis-benzotriazolyl tetramethyl butyl phenol and 0.1-5% of butyl methoxy dibenzoyl methane. The sunscreen spray disclosed by the invention is prepared by compounding a physical sunscreen agent (titanium dioxide) and a chemical sunscreen agent (octyl methoxycinnamate, methylene bis-benzotriazolyl tetramethyl butylphenol and butyl methoxy dibenzoyl methane), so that the sunscreen spray has a good skin feel and a good sunscreen effect.

Description

Sunscreen spray
Technical Field
The invention belongs to the technical field of cosmetics, and particularly relates to sunscreen spray.
Background
The unitary spray, binary spray, adopted by the current common sunscreen spray package is a safer form, and has the following advantages compared with the unitary spray:
1. safety first, the propellant of the unitary spray is generally flammable and explosive components such as dimethyl ether, propane and butane, and is forbidden to take airplanes and high-speed rails. The propellant of the binary spray adopts compressed air or nitrogen, has higher safety, and can be used for carrying high-speed rails and airplanes.
2. Sealing property: a unitary package is poorly sealed, and is free of a pouch-protecting body package. The binary package has high sealing performance, and the multiple protection material body packaging system is formed by a valve, four layers of vacuum bags and an aluminum can.
3. Purity of the material body: the unitary package is a mixture of gas and materials, the material body is not pure enough, the product quality cannot be optimized, and the poor sealing property can cause other gas bacteria to enter the interior to pollute the interior, so that the material body deteriorates. And the propellant may cause irritation to the skin. The binary package is that the gas material is separated, and the material body is filled into food grade sacks by a vacuum aseptic technique.
4. The spraying effect is as follows: the unitary package has poor atomization effect of the sprayed material, large impact force and relatively unsatisfactory skin absorption. The material body sprayed by the binary package is in a uniform and continuous nano atomized state and is easier to be absorbed by skin.
5. The spraying convenience degree is as follows: the monadic bottle is packed with sediment, and needs to be shaken before use, and needs to be pressed for many times during use, and the bottle body can only keep a fixed angle of horizontal standing during spraying. The binary package has no sediment, and can be sprayed along with holding, and can be sprayed to the bottom once being pressed smoothly, so that the multi-pressing is not needed, and the all-round spraying can be carried out without any dead angle.
6. Utilization rate: the unitary package is wasted with residue. The utilization rate of the binary package is as high as 98 percent.
And the adoption of binary spraying sunscreen spraying is less and has poor effect.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide a sunscreen spray.
In order to achieve the purpose, the invention adopts the technical scheme that: a sunscreen spray comprises the following components in percentage by weight: 1-9.5% of titanium dioxide, 2-10% of octyl methoxycinnamate, 0.5-7.5% of methylene bis-benzotriazolyl tetramethyl butyl phenol and 0.1-5% of butyl methoxy dibenzoyl methane.
The sunscreen spray is suitable for being prepared into a spray formulation by reasonably blending a physical sunscreen agent (titanium dioxide) and a chemical sunscreen agent (octyl methoxycinnamate, methylene bis-benzotriazolyl tetramethyl butylphenol and butyl methoxydibenzoyl methane), and has good skin feel and a good sunscreen effect.
Preferably, the sunscreen spray comprises the following components in percentage by weight: 2.8% of titanium dioxide, 7.4% of octyl methoxycinnamate, 2.5-3.75% of methylene bis-benzotriazolyl tetramethyl butylphenol and 3% of butyl methoxy dibenzoyl methane. The inventor finds that the sun-screening effect and the skin feel of each sun-screening component are optimal in the above proportion through experiments.
Preferably, the sunscreen spray further comprises 0.1-5% of a VP/hexadecene copolymer. The addition of the VP/hexadecene copolymer can obviously improve the water resistance of the sunscreen spray and effectively improve the SPF value. More preferably, the VP/hexadecene copolymer is present in an amount of 2% by weight. Especially, when the additive amount is added, the water-resistant effect is good, the dosage is proper, and the skin feel is good.
Preferably, the sunscreen spray further comprises 0.025-0.14% of a mixture of a buddleja officinalis extract, a black mulberry extract, a lycium barbarum root extract, a strawberry fruit extract and a berberis europaea root extract 0.004-0.1%. The flos Buddlejae extract is a full-effect photoprotectant, and has strong effect on erythema and oxidation pressure caused by ultraviolet, blue light and infrared rays. The plant extracts such as black mulberry extract, Chinese wolfberry root extract, strawberry fruit extract and berberis europaea root extract can prevent cell damage caused by UVB, repair skin damaged by ultraviolet rays, resist oxidation, resist inflammation, resist wrinkle and preserve moisture.
Preferably, the sunscreen spray further comprises 0.1-2% of tetrahydro-methyl pyrimidine carboxylic acid and 0.1-2% of tocopherol acetate. The addition of the tetrahydro-methyl pyrimidine carboxylic acid can protect the immune system of the skin, trigger and improve the reaction speed of the heat shock protein, protect cell membranes and DNA, and stabilize and repair skin inflammation and allergy symptoms. The tetrahydromethylpyrimidine carboxylic acid and the tocopherol acetate can play a role in resisting oxidation together.
Preferably, the sunscreen spray further comprises emulsifiers, emollients, anti-inflammatory agents, thickeners, humectants, chelating agents and preservatives; the emulsifier comprises a mixture of C20-22 alcohol phosphate and C20-22 alcohol, a mixture of glyceryl stearate and PEG-100 stearate; the emollient comprises polydimethylsiloxane, C12-15 alcohol benzoate, a mixture of cyclopentadimethylsiloxane and cyclohexasiloxane, squalane; the anti-inflammatory agent comprises allantoin.
Preferably, the weight percentage of each component in the emulsifier, the emollient and the anti-inflammatory agent in the sunscreen spray is as follows: 0.5-5% of a mixture of C20-22 alcohol phosphate and C20-22 alcohol, 0.5-3% of glyceryl stearate and PEG-100 stearate, 1-5% of polydimethylsiloxane, 1-5% of C12-15 alcohol benzoate, 1-5% of a mixture of cyclopentadimethylsiloxane and cyclohexasiloxane, 1-6% of squalane and 0.01-0.5% of allantoin.
Preferably, the weight percentage of each component in the emulsifier, the emollient and the anti-inflammatory agent in the sunscreen spray is as follows: 3% of a mixture of C20-22 alcohol phosphate and C20-22 alcohol, 1% of glyceryl stearate and PEG-100 stearate, 3% of polydimethylsiloxane, 3% of C12-15 alcohol benzoate, 2% of a mixture of cyclopentadimethylsiloxane and cyclohexasiloxane, 3% of squalane and 0.1% of allantoin.
Preferably, the thickener comprises acrylic acid (ester)/behenyl polyether-25, methacrylate copolymer, xanthan gum, hydroxyethyl acrylate, sodium acryloyldimethyl taurate copolymer, squalane and polysorbate-60; the humectant comprises glycerin and butylene glycol; the chelating agent is disodium EDTA.
Preferably, the thickener and the humectant comprise the following components in percentage by weight in the sunscreen spray: 0.1-2.5% of acrylic acid (ester)/behenyl alcohol polyether-25 methacrylate copolymer, 0.01-0.3% of xanthan gum, 0.1-2% of hydroxyethyl acrylate, acryloyl dimethyl sodium taurate copolymer, squalane and polysorbate-60 mixture, 1-10% of glycerol, 1-5% of butanediol and 0.01-0.2% of EDTA disodium.
Preferably, the thickener, the humectant and the chelating agent are contained in the sunscreen spray in the following weight percentage: 0.8% of acrylic acid (ester)/behenyl alcohol polyether-25 methacrylate copolymer, 0.15% of xanthan gum, 0.8% of hydroxyethyl acrylate, acryloyl dimethyl taurate copolymer, 0.8% of a mixture of squalane and polysorbate-60, 5% of glycerin, 3% of butanediol and 0.05% of disodium EDTA.
The emulsifier, the emollient, the anti-inflammatory agent, the thickener, the humectant, the chelating agent and the like can be added into the sunscreen spray to prepare the sunscreen spray with uniform and stable properties, and the sunscreen spray is suitable for binary-packaged spray, and has soft skin feel and good moisturizing effect.
The invention has the beneficial effects that: the invention provides a sunscreen spray which is prepared by compounding a physical sunscreen agent (titanium dioxide) and a chemical sunscreen agent (octyl methoxycinnamate, methylene bis-benzotriazolyl tetramethyl butylphenol and butyl methoxy dibenzoyl methane), so that the sunscreen spray has good skin feel and a good sunscreen effect.
Detailed Description
In the examples of the present invention, titanium dioxide was purchased from HOMBITAN AC360, manufactured by Guangzhou aromatic garden cosmetics manufacturing Co., Ltd;
octyl methoxycinnamate available from Merck
Figure BDA0002122989440000041
Wherein the content of octyl methoxycinnamate is 37 percent;
methylene bis-benzotriazolyl tetramethylbutylphenol was purchased from TINOSORB M produced by Fitz Chem responsibility Co., Ltd., wherein the content of methylene bis-benzotriazolyl tetramethylbutylphenol was 50 to 75%;
butyl Methoxybenzoylmethane from Merck
Figure BDA0002122989440000042
Copolymerization of VP/hexadeceneFrom Ashland corporation
Figure BDA0002122989440000043
The flos Buddlejae extract is obtained from Baihabo Co Ltd of Guangzhou
Figure BDA0002122989440000044
(001169), wherein the content of the flos Buddlejae extract is 5-7%.
The mixture of black mulberry extract, wolfberry root extract, strawberry fruit extract and berberis europaea root extract was purchased from the korean BIOSPECTRUM company under model number vartierTMThe product comprises 0.4-2% of black mulberry extract, 0.4-2% of wolfberry root extract, 0.4-2% of strawberry fruit extract and 0.4-2% of berberis europaea root extract;
a mixture of C20-22 alcohol phosphate and C20-22 alcohol was obtained from Shanghai Saifu chemical engineering Co., Ltd under the trade designation SENSANOVTM WR;
The mixture of glyceryl stearate and PEG-100 stearate was purchased from SIMULSOL, available from Saybolt CorpTM165;
A mixture of cyclopentadimethylsiloxane and cyclohexasiloxane was purchased from Dow corporation, USA under the trade designation XIAME ETERTMMPMX-0345;
acrylic/behenyl polyether-25 methacrylate copolymer was obtained from volaserst FL, a product of daikon co ltd;
acryloyldimethyl sodium taurate copolymer, squalane and polysorbate-60 SIMULGEL from Saibox corporationTM NS;
Sumex K350, germany, is a mixture of phenoxyethanol, methylparaben, ethylparaben, and ethylhexylglycerol.
To better illustrate the objects, aspects and advantages of the present invention, the present invention will be further described with reference to specific examples.
Examples 1 to 8 and comparative examples 1 to 3
The formulations of the sunscreen sprays described in examples 1-8 and comparative examples 1-3 are shown in table 1, and the preparation methods of the sunscreen sprays described in examples 1-8 and comparative examples 1-3 include the following steps:
1. preparing powder slurry: mixing and stirring C12-15 alcohol benzoate, titanium dioxide (CI77891) and squalane uniformly, and then grinding three times by using a three-roll mill until the mixture is completely and uniformly dispersed;
2. adding C20-22 alcohol phosphate (and) C20-22 alcohol, glyceryl stearate (and) PEG-100 stearate, polydimethylsiloxane, cyclopentadimethylsiloxane (and) cyclohexasiloxane, tocopheryl acetate, butyl methoxydibenzoylmethane, VP/hexadecene copolymer, methylparaben and propylparaben into an oil phase pot in sequence, heating and stirring to 75-85 ℃;
3. adding the powder slurry prepared in the step 1, continuously stirring and heating to 75-85 ℃;
4. putting deionized water, glycerol, butanediol, allantoin, EDTA disodium, acrylic acid (ester)/behenyl alcohol polyether-25 methacrylate copolymer and xanthan gum into a main emulsifying pot, heating to 80-90 ℃, homogenizing at low speed to completely disperse and dissolve the materials, and stirring for 10-20 minutes while keeping the temperature;
5. vacuumizing the main emulsifying pot to 0.03MPa, slowly pumping the pre-oil phase prepared in the step (2) into the emulsifying pot, uniformly mixing and stirring, and homogenizing at medium speed for 3 minutes;
6. mixing SIMULGELTMPutting NS into an emulsifying pot, vacuumizing, homogenizing at high speed for 5-8 minutes, and stirring for 10-20 minutes under heat preservation;
7. cooling to 55 deg.C, adding triethanolamine, and stirring;
8. cooling to 45 deg.C, and sequentially adding
Figure BDA0002122989440000061
TINOSORB M、
Figure BDA0002122989440000062
(001169)、VarrierTMStirring the tetrahydromethyl pyrimidine carboxylic acid uniformly;
9. cooling to 40 deg.C, adding
Figure BDA0002122989440000063
K350, stirring uniformly, and discharging after the inspection is qualified to obtain the sunscreen spray.
TABLE 1 formulations of sunscreen sprays as described in examples 1-8 and comparative examples 1-3
Figure BDA0002122989440000064
Figure BDA0002122989440000071
Example 9
In order to verify the skin feeling and the atomization effect of each group of sunscreen spray, 88 volunteers with oily or mixed skin are selected, the volunteers are 18-35 years old and divided into 11 groups, 8 people in each group are tried out respectively from the sunscreen spray described in the embodiments 1-8 and the comparative examples 1-3, the skin feeling and the atomization effect are sequentially graded into 5 grades, 4 grades, 3 grades, 2 grades, 1 grade and 0 grade from good to poor, and the average value of the test is counted. The test results are shown in Table 2.
TABLE 2 skin feel and fogging Effect test results of examples 1 to 8 and comparative examples 1 to 3
Figure BDA0002122989440000072
The test data show that the skin feel of the examples 1-8 is better than that of the comparative examples 1-3, and the skin feel and the atomization effect of the example 1 are the best.
Example 10
The performance of the sunscreen sprays of examples 1-8 and comparative examples 1-3 was tested, and the specific test method was as follows:
1. accurately weigh 100mg per sunscreen spray sample in a 50ml capacity bottle, add absolute ethanol and absolute ether at a ratio of 1: the mixed solution with the proportion of 1 is used as a solvent to prepare a solution. And pouring the prepared solution into a quartz cuvette with the wavelength of 1cm multiplied by 5cm, and measuring the ultraviolet light transmittance in the wavelength range of 290-400 nm in a well-adjusted ultraviolet spectrophotometer.
2. The test pen is used for testing the water and oil content of the skin without the sunscreen cream, and after the sunscreen cream is used, the test pen is used again for testing the water and oil content.
3. Specific detection results are shown in table 3.
TABLE 3 product Performance test results
Figure BDA0002122989440000081
According to the test results, the sunscreen spray prepared in the examples 1 to 8 and the sunscreen spray prepared in the comparative examples 1 to 3 have the light absorbing capability and certain moisturizing effect, and comprehensive comparison shows that the sunscreen spray prepared in the examples 1 to 8 has the light absorbing capability superior to that of the sunscreen spray prepared in the comparative examples 1 to 3, wherein the sunscreen spray prepared in the example 1 has the strongest light absorbing capability and the moisturizing effect is the best.
Finally, it should be noted that the above embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the protection scope of the present invention, and although the present invention is described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions can be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention.

Claims (11)

1. A sunscreen spray is characterized by comprising the following components in percentage by weight: 2.8% of titanium dioxide, 7.4% of octyl methoxycinnamate, 2.5-3.75% of methylene bis-benzotriazolyl tetramethyl butylphenol and 3% of butyl methoxy dibenzoyl methane.
2. The sunscreen spray of claim 1, further comprising 0.1 to 5% VP hexadecene copolymer.
3. The sunscreen spray of claim 2 wherein the VP hexadecene copolymer is present in an amount of 2% by weight.
4. The sunscreen spray of claim 1, further comprising from 0.025 to 0.14% of a buddleja officinalis extract, from 0.004 to 0.1% of a mixture of black mulberry extract, wolfberry root extract, strawberry fruit extract and berberis europaea extract.
5. The sunscreen spray of claim 1 further comprising 0.1-2% of a tetrahydro methyl pyrimidine carboxylic acid and 0.1-2% of a tocopherol acetate.
6. The sunscreen spray of any of claims 1-5, further comprising an emulsifier, emollient, anti-inflammatory agent, thickener, humectant, chelating agent, and preservative; the emulsifier comprises a mixture of C20-22 alcohol phosphate and C20-22 alcohol, a mixture of glyceryl stearate and PEG-100 stearate; the emollient comprises polydimethylsiloxane, C12-15 alcohol benzoate, a mixture of cyclopentadimethylsiloxane and cyclohexasiloxane, squalane; the anti-inflammatory agent comprises allantoin.
7. The sunscreen spray of claim 6, wherein the emulsifier, emollient, and anti-inflammatory agent are present in the sunscreen spray in the following weight percentages: 0.5-5% of a mixture of C20-22 alcohol phosphate and C20-22 alcohol, 0.5-3% of glyceryl stearate and PEG-100 stearate, 1-5% of polydimethylsiloxane, 1-5% of C12-15 alcohol benzoate, 1-5% of a mixture of cyclopentadimethylsiloxane and cyclohexasiloxane, 1-6% of squalane and 0.01-0.5% of allantoin.
8. The sunscreen spray of claim 6, wherein the emulsifier, emollient, and anti-inflammatory agent are present in the sunscreen spray in the following weight percentages: 3% of a mixture of C20-22 alcohol phosphate and C20-22 alcohol, 1% of glyceryl stearate and PEG-100 stearate, 3% of polydimethylsiloxane, 3% of C12-15 alcohol benzoate, 2% of a mixture of cyclopentadimethylsiloxane and cyclohexasiloxane, 3% of squalane and 0.1% of allantoin.
9. The sunscreen spray of claim 6 wherein said thickening agent comprises acrylates/beheneth-25, methacrylate copolymers, xanthan gum, hydroxyethyl acrylate, sodium acryloyldimethyl taurate copolymers, squalane and polysorbate-60; the humectant comprises glycerin and butylene glycol; the chelating agent is disodium EDTA.
10. The sunscreen spray of claim 9, wherein the thickening agent, humectant and chelating agent are present in the sunscreen spray in the following weight percentages: 0.1-2.5% of acrylic acid (ester)/behenyl alcohol polyether-25 methacrylate copolymer, 0.01-0.3% of xanthan gum, 0.1-2% of hydroxyethyl acrylate, acryloyl dimethyl sodium taurate copolymer, squalane and polysorbate-60 mixture, 1-10% of glycerol, 1-5% of butanediol and 0.01-0.2% of EDTA disodium.
11. The sunscreen spray of claim 10, wherein the thickening agent, humectant and chelating agent are present in the sunscreen spray in the following weight percentages: 0.8% of acrylic acid (ester)/behenyl alcohol polyether-25 methacrylate copolymer, 0.15% of xanthan gum, 0.8% of hydroxyethyl acrylate, acryloyl dimethyl taurate copolymer, 0.8% of a mixture of squalane and polysorbate-60, 5% of glycerin, 3% of butanediol and 0.05% of disodium EDTA.
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