CN110237709A - Silicon chip surface based on solar cell manufacture process inhibits method for oxidation - Google Patents

Silicon chip surface based on solar cell manufacture process inhibits method for oxidation Download PDF

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Publication number
CN110237709A
CN110237709A CN201910621992.2A CN201910621992A CN110237709A CN 110237709 A CN110237709 A CN 110237709A CN 201910621992 A CN201910621992 A CN 201910621992A CN 110237709 A CN110237709 A CN 110237709A
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CN
China
Prior art keywords
filter
drying
air
ozone
high efficiency
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910621992.2A
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Chinese (zh)
Inventor
杜俊霖
刘正新
谢毅
孟凡英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongwei Solar Chengdu Co Ltd
Original Assignee
Zhongwei New Energy (chengdu) Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhongwei New Energy (chengdu) Co Ltd filed Critical Zhongwei New Energy (chengdu) Co Ltd
Priority to CN201910621992.2A priority Critical patent/CN110237709A/en
Publication of CN110237709A publication Critical patent/CN110237709A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8671Removing components of defined structure not provided for in B01D53/8603 - B01D53/8668
    • B01D53/8675Ozone
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B21/00Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
    • F26B21/003Supply-air or gas filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26DRYING
    • F26BDRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B21/00Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
    • F26B21/004Nozzle assemblies; Air knives; Air distributors; Blow boxes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention discloses the silicon chip surfaces based on solar cell manufacture process to inhibit method for oxidation, the following steps are included: S1 device is chosen, the processing of S2 device, the connection of S3 drying tank, S4 ventilation test, the beneficial effects of the present invention are: fully ensuring that silicon chip surface not by ozone oxidation by ozone filter;It is connected by multiple gas transmission pipe ends with workshop, while ozone filter is set, improves ozone removal efficiency;By air-conditioning system, the stabilization of temperature in workshop is realized.

Description

Silicon chip surface based on solar cell manufacture process inhibits method for oxidation
Technical field
The present invention relates to the anti-oxidation fields of ozone, and the silicon chip surface specifically based on solar cell manufacture process inhibits oxidation Method.
Background technique
In solar cell manufacturing process, silicon wafer after making herbs into wool is cleaned is entering next step chemical vapor deposition (CVD) it before technique, is usually saved in air environment, the oxygen and ozone in air can aoxidize silicon chip surface, be formed Layer of oxide layer.Ozone concentration changes, the various electrical equipments in workshop with the variation of Ozone in Atmosphere concentration in workshop Ozone may also be generated, causes the ozone concentration in workshop to fluctuate very big.Since the oxidability of ozone is eager to excel much than oxygen, The degree of oxidation that the fluctuation of ozone concentration directly results in silicon chip surface generates fluctuation, and when carrying out CVD technique, silicon chip surface is aoxidized The thickness and consistency of layer change with the variation of ozone concentration, therefore between the amorphous silicon of CVD deposition and silicon wafer crystalline silicon Interface state be not able to maintain stabilization, final battery efficiency can generate larger fluctuation.
Existing solar cell workshop does not control the concentration of ozone in workshop condition, cleaned silicon wafer In air, the ozone concentration variation in the length and air of exposure duration can all lead to silicon for exposure before entering CVD equipment The degree of oxidation of piece is non-constant.In addition, silicon chip drying equipment is usually using the air or compressed air in workshop, by heating Hot-air recycles in drying tank afterwards, and the silicon wafer after cleaning is dried, the change for the ozone concentration that this process silicon wafer touches Change but also the degree of oxidation of silicon wafer changes.Lack in prior art to ozone concentration in workshop and silicon chip drying equipment Control, increases the fluctuation range of battery efficiency, influences the stability of product quality.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide the silicon chip surfaces based on solar cell manufacture process Inhibit method for oxidation, to steady removal ozone, control drying tank ozone concentration.
The purpose of the present invention is achieved through the following technical solutions: the silicon chip surface based on solar cell manufacture process Inhibit method for oxidation, comprising the following steps:
S1 device is chosen: selecting and is successively arranged primary filter, air-conditioning system, medium effeciency filter along air delivery direction Fresh air system selects end to have the appendix of high efficiency particulate air filter, sets CVD chamber and making herbs into wool cleaning equipment in selection The ozone filter of solid Ozone Absorption agent or ozone catalyst is selected in the workshop of equipment;
The processing of S2 device: welding fresh air system and appendix along air delivery direction, the appendix end with high efficiency particulate air filter End is welded on workshop top, and workshop two sides are welded with vent, at the same by ozone filter be fixed on medium effeciency filter with Between high efficiency particulate air filter and abut high efficiency particulate air filter.
The connection of S3 drying tank: exhaust outlet will be dried in the welding of drying tank side in making herbs into wool cleaning equipment, while dries exhaust Blower is dried in the welding of mouth end;It is welded with drying air inlet below drying blower, top is welded with drying appendix, dries simultaneously Dry appendix end bend setting, and be equipped with drying high efficiency particulate air filter, the drying appendix pass through drying high efficiency particulate air filter and It is communicated at the top of drying tank.
S4 ventilation test: air is passed through before fresh air system, air ozone content in sequentially determining workshop, drying tank.
Preferably, the ozone filter is before the also optional primary filter in air delivery direction, primarily efficient filter Between device and medium effeciency filter, between high efficiency particulate air filter and workshop in one or more in three positions, and then can sufficiently go Except the ozone in air used.
Preferably, it is additionally provided with drying ozone filter between the drying high efficiency particulate air filter and drying appendix, it is described Drying ozone filter may be also secured between drying tank high efficiency particulate air filter and drying tank, and then guarantee drying silicon chip surface Ozone content is low in air.
Preferably, the fresh air system is provided with several ventilation holes along conveying direction, and then it is same to improve air flow rate When sufficiently allow air to come into full contact with primary filter, medium effeciency filter, remove air in impurity.
Preferably, the appendix is connected by multiple ends equipped with high efficiency particulate air filter with workshop, and then is improved empty The removal efficiency of ozone in gas.
Preferably, the air-conditioning system is equipped with heating plate, air-conditioning draught fan, cold plate along air delivery direction, passes through sky Adjust blower that air circulation, heating plate or cold plate is accelerated to need to heat air or freezed for different.
Preferably, the drying tank air inlet pipe is equipped with drying layer along air delivery direction front end, and then prevents drying tank Influence of the moisture in air used to silicon chip surface oxidizing and depressing.
Preferably, the primary filter uses aperture for 5-10 μm of strainer;The medium effeciency filter use aperture for 1-5 μm of strainer;The high efficiency particulate air filter uses aperture for 0.1-0.5 μm of strainer.
The beneficial effects of the present invention are:
1. by installing ozone filtering in the drying tank of making herbs into wool cleaning equipment, the fresh air system equipped with multiple ventilation holes Device fully ensures that after silicon chip surface cleans in workshop not by ozone oxidation, while improving the transfer efficiency of air.
2. being connected by multiple gas transmission pipe ends equipped with high efficiency particulate air filter with workshop, workshop air intake efficiency is improved, Ozone filter is set between high efficiency particulate air filter and medium effeciency filter simultaneously, and then improves the removal efficiency of ozone in air.
3. utilizing air-conditioning draught fan by being equipped with heating plate, the air-conditioning system of air-conditioning draught fan, cold plate along air delivery direction Accelerate air circulation, heating plate or cold plate to need to heat air or freezed for different, and then realizes temperature in workshop The stabilization of degree, while also can guarantee the constant of air velocity.
4. drying layer is equipped with along air delivery direction front end by drying tank air inlet pipe, the dry air for entering drying tank And then prevent influence of the moisture in air used in drying tank to silicon chip surface oxidizing and depressing.
5. by using the graphene primary filter of plate-type filtering mode, the nylon medium air filtration of modular filter mode The ultra-fine fibre glass paper high efficiency particulate air filter of device, plate-type filtering mode, and then filter impurity in air sufficiently, while using and dividing Grade filter type improves device and crosses air filtering efficiency.
Detailed description of the invention
Fig. 1 is the schematic device that silicon chip surface oxidizing and depressing method of the invention is chosen;
Fig. 2 is the air-conditioning system schematic diagram of silicon chip surface oxidizing and depressing method of the present invention;
Fig. 3 is the drying tank air inlet pipe schematic diagram of silicon chip surface oxidizing and depressing method of the present invention;
Fig. 4 is the fresh air system schematic diagram of silicon chip surface oxidizing and depressing method of the present invention.
Specific embodiment
Technical solution of the present invention is described in further detail with reference to the accompanying drawing, but protection scope of the present invention is not limited to It is as described below.
As shown in Figure 1, the silicon chip surface based on solar cell manufacture process inhibits method for oxidation, comprising the following steps:
S1 device is chosen: selecting and is successively arranged primary filter 2, air-conditioning system 4, medium effeciency filter along air delivery direction 3 fresh air system 1 selects end to have the appendix 5 of high efficiency particulate air filter 6, sets CVD chamber 10 and making herbs into wool in selection The ozone filter 7 of solid Ozone Absorption agent or ozone catalyst is selected in the workshop 8 of cleaning equipment equipment 9;
S2 device processing: along air delivery direction welding fresh air system 1 and appendix 5, with the multiple defeated of high efficiency particulate air filter 6 5 end of tracheae is welded on 8 top of workshop, and 8 two sides of workshop are welded with the exhaust of exhaust outlet 12, while ozone filter 7 being fixed on Between medium effeciency filter 3 and high efficiency particulate air filter 6 and high efficiency particulate air filter 6 is abutted, and then sufficiently reduces ozone content in workshop 8.
The connection of S3 drying tank: exhaust outlet 93 will be dried in the welding of 91 side of drying tank in making herbs into wool cleaning equipment 9, dried simultaneously Blower 95 is dried in the welding of 93 end of exhaust outlet;Drying air inlet 94 is welded with below drying blower 95, top is welded with drying Appendix 92, while the setting of 92 end bend of appendix is dried, and be equipped with drying high efficiency particulate air filter 96, the drying appendix 92 It is communicated at the top of drying high efficiency particulate air filter 96 and drying tank 91, and then realizes " returning " shape structure of 91 gas transmission route of drying tank, Simultaneously dry ozone filter 97 be fixed on drying appendix 92 and drying tank high efficiency particulate air filter 96 between, and then fully absorb into Enter the air of drying tank.
S4 ventilation test: air, air ozone content in sequentially determining workshop 8, drying tank 9 are passed through before fresh air system 1.
As shown in Fig. 2, the air-conditioning system 4 is equipped with heating plate 41, air-conditioning draught fan 42, cold plate along air delivery direction 43, accelerate air circulation, heating plate or cold plate to need to heat air or freezed for different using air-conditioning draught fan, into And realize the stabilization of temperature in workshop, while also can guarantee the constant of air velocity.
As shown in figure 3, the drying air inlet pipe 94 of the drying tank 91 is equipped with drying layer along air delivery direction front end 941, and then prevent influence of the moisture in air used in drying tank to silicon chip surface oxidizing and depressing.
As shown in figure 4, the fresh air system is equipped with several ventilation holes 11, by the ventilation hole 11 of setting, cooperate air-conditioning Blower 42, accelerating air velocity contacts air sufficiently with primary filter 2, medium effeciency filter 3 simultaneously.
Further, the primary filter 2 uses aperture for 5 μm of strainer;The medium effeciency filter 3 uses hole The strainer that diameter is 1 μm;The high efficiency particulate air filter 4 uses aperture sufficiently to filter off for 0.5 μm of strainer by filters at different levels Except impurity in air, while classified filtering mode is used, improves device filter efficiency.
Embodiment 1
Silicon chip surface through the invention inhibits method for oxidation, does not use the ozone filter 7 in S1 and S2, together When S3 in also do not use drying ozone filter 97, measure respectively in workshop 8 in making herbs into wool cleaning equipment 9 in drying tank 91 Ozone concentration when 16:00 is 10ppb, 8ppb.
Embodiment 2
Silicon chip surface through the invention inhibits oxidative system, does not use the ozone filter 7 in S1 and S2, but Drying ozone filter 97 described in S3 selects between drying appendix 92 and drying tank high efficiency particulate air filter 96 and abuts drying tank High efficiency particulate air filter 96 measures in workshop 8 respectively and divides with the ozone concentration in drying tank 91 in making herbs into wool cleaning equipment 9 in 16:00 It Wei not 2ppb, 4ppb.
Embodiment 3
Silicon chip surface through the invention inhibits oxidative system, and the ozone filter 7 described in S1 and S2 is defeated along air Direction is sent to select between medium effeciency filter 3 and high efficiency particulate air filter 6 and against high efficiency particulate air filter 6, while the drying described in S3 is smelly Drying tank high efficiency particulate air filter 96 is selected between drying appendix 92 and drying tank high efficiency particulate air filter 96 and abutted to oxygen filter 97, point It Ce Ding not be respectively 2ppb, 1ppb with the ozone concentration in drying tank 91 in making herbs into wool cleaning equipment 9 in 16:00 in workshop 8.
By embodiment 1,2,3 it is found that inhibiting method for oxidation that can effectively drop by using silicon chip surface of the invention Ozone concentration in the gas of low latitude, while being set between the medium effeciency filter in workshop 83 and high efficiency particulate air filter 6 and against high efficiency particulate air filter 6 It sets between the drying appendix 92 and drying tank high efficiency particulate air filter 96 of ozone filter 7, drying tank 91 and efficient against drying tank The setting drying ozone filter 97 of filter 96 can effectively reduce the ozone content during silicon wafer surface cleaning, and then reach Silicon chip surface inhibits the purpose of oxidation.
The above is only a preferred embodiment of the present invention, it should be understood that the present invention is not limited to described herein Form should not be regarded as an exclusion of other examples, and can be used for other combinations, modifications, and environments, and can be at this In the text contemplated scope, modifications can be made through the above teachings or related fields of technology or knowledge.And those skilled in the art institute into Capable modifications and changes do not depart from the spirit and scope of the present invention, then all should be in the protection scope of appended claims of the present invention It is interior.

Claims (9)

1. the silicon chip surface based on solar cell manufacture process inhibits method for oxidation, it is characterised in that: the following steps are included:
S1 device is chosen: selecting the fresh air that primary filter, air-conditioning system, medium effeciency filter are successively arranged along air delivery direction System selects end to have the appendix of high efficiency particulate air filter, sets CVD chamber and making herbs into wool cleaning equipment equipment in selection Workshop, select the ozone filter of solid Ozone Absorption agent or ozone catalyst;
The processing of S2 device: welding fresh air system and appendix along air delivery direction, the gas transmission pipe end weldering with high efficiency particulate air filter It connects in workshop top, workshop two sides are welded with vent, while ozone filter is fixed on medium effeciency filter and efficiently Between filter and abut high efficiency particulate air filter;
The connection of S3 drying tank: exhaust outlet will be dried in the welding of drying tank side in making herbs into wool cleaning equipment, while dries exhaust outlet end Blower is dried in the welding of end;It is welded with drying air inlet below drying blower, top is welded with drying appendix, while drying defeated The setting of tracheae end bend, and it is equipped with drying high efficiency particulate air filter, the drying appendix passes through drying high efficiency particulate air filter and drying Groove top portion communicates;
S4 ventilation test: air is passed through before fresh air system, air ozone content in sequentially determining workshop, drying tank.
2. the silicon chip surface according to claim 1 based on solar cell manufacture process inhibits method for oxidation, feature exists Before primary filter also can be selected along air delivery direction in: the ozone filter, primary filter and medium air filtration Between device, between high efficiency particulate air filter and workshop in one or more in three positions.
3. the silicon chip surface according to claim 1 based on solar cell manufacture process inhibits method for oxidation, feature exists In: drying ozone filter, the drying ozone filtering are additionally provided between the drying high efficiency particulate air filter and drying appendix Device is against drying high efficiency particulate air filter.
4. the silicon chip surface according to claim 3 based on solar cell manufacture process inhibits method for oxidation, feature exists In: the drying ozone filter may be also secured between drying tank high efficiency particulate air filter and drying tank.
5. the silicon chip surface according to claim 1 based on solar cell manufacture process inhibits method for oxidation, feature exists In: the fresh air system is provided with several ventilation holes along conveying direction.
6. the silicon chip surface according to claim 1 based on solar cell manufacture process inhibits method for oxidation, feature exists In: the appendix is communicated by multiple ends equipped with high efficiency particulate air filter with workshop.
7. the silicon chip surface according to claim 1 based on solar cell manufacture process inhibits method for oxidation, feature exists In: the air-conditioning system is equipped with heating plate, air-conditioning draught fan, cold plate along air delivery direction.
8. the silicon chip surface according to claim 1 based on solar cell manufacture process inhibits method for oxidation, feature exists In: the drying tank air inlet pipe is equipped with drying layer along air delivery direction front end.
9. the silicon chip surface according to claim 1 based on solar cell manufacture process inhibits method for oxidation, feature exists Use aperture for 5-10 μm of strainer in: the primary filter;The medium effeciency filter uses aperture for 1-5 μm of filter Net;The high efficiency particulate air filter uses aperture for 0.1-0.5 μm of strainer.
CN201910621992.2A 2019-07-10 2019-07-10 Silicon chip surface based on solar cell manufacture process inhibits method for oxidation Pending CN110237709A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114993028A (en) * 2022-06-17 2022-09-02 广东高景太阳能科技有限公司 Silicon wafer drying treatment method and system

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CN114993028B (en) * 2022-06-17 2023-05-30 高景太阳能股份有限公司 Silicon wafer drying treatment method and system

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