CN110227040A - A cerul bar-like cosmetic that can be out of the water and preparation method - Google Patents
A cerul bar-like cosmetic that can be out of the water and preparation method Download PDFInfo
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- CN110227040A CN110227040A CN201910170511.0A CN201910170511A CN110227040A CN 110227040 A CN110227040 A CN 110227040A CN 201910170511 A CN201910170511 A CN 201910170511A CN 110227040 A CN110227040 A CN 110227040A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0229—Sticks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/001—Preparations for care of the lips
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Abstract
The invention discloses a cerul bar-like cosmetics that can be out of the water, the characteristics of oil phase part of the cerul bar-like cosmetic that can be out of the water point or oil, which mix portion envelops water, makes the releasing of its moisture provide a kind of composition of emulsifier, and the composition of the emulsifier of the laminated structure of compounding wraps up moisture particle；The present invention can be out of the water during solving cerul bar-like cosmetic in smearing in original technology, a large amount of moisture can provide water profit, the problem of refrigerant skin sense directly to skin, the cerul bar-like cosmetic that can be out of the water made of the present invention not only can directly provide a large amount of moisture content, also there is good hardness, and state stability is outstanding, smear that sense is outstanding, and storage stability is outstanding, the features such as outstanding coloring effect.
Description
Technical field
The present invention relates to a kind of cosmetics, relate generally to a kind of cerul stick-shaped cosmetic that can be out of the water in use
Product can moisten, refrigerant, moist skin sense with water, the product formula stability is good, hardness is good, skin sense is good, color is painted,
Storage stability is good, and the preparation method for the cerul bar-like cosmetic that can be out of the water.
Background technique
Bar-like cosmetic, because state is solid, uses and takes care of all more convenient, bar-like cosmetic than ordinary cosmetics
The characteristics of be directly to use, the hardness that when smearing has needed will not encounter hand.The cosmetics for being surrounded by moisture are easy directly
There is provided sufficient moisture to skin, when makeup can let us have refrigerant feeling, so the progress that such trial can be steady, but
When being bar-like cosmetics and be surrounded by moisture content, its stability is poor.
This publication in order to supplement Republic of Korea the 1999-0069366th, it is -2 isostearate of polyglycereol, poly-
- 2 diisopstearate of glycerol, the three isostearate composition of polyglycereol -2 include the moisture of 5-20%, and Shui Run, clear is not achieved
Cool skin sense will not be discharged during smearing.
Korean Patent discloses the oil components that volatility in No. 10-2016-0139042 flows, which can be with
It changes wax, silicone elastomer and silicone oil surfactant into, a large amount of moisture content can be added in this way, reach refrigerant sense but stablize
Property is bad.
The explanation of the cosmetics of moisture is provided for lip, generally first smears after common lipstick the smearing moisture above again
The composition of the scattered component materials containing Sodium Polyacrylate graft starch, but containing for common lipstick collocation water dispersion is poly-
The mixture of sodium acrylate graft starch uses uncomfortable, it has not been convenient to, so needing to do a lipstick rodlikeization that can be out of the water
Cosmetic.
Summary of the invention
The present invention can be out of the water during solving cerul bar-like cosmetic in smearing in original technology, a large amount of water
Water profit, the problem of refrigerant skin sense can be provided directly to skin by dividing.The first object of the present invention is that providing one kind can go out
Cerul bar-like cosmetic of water and preparation method thereof, can satisfy the good hardness of cerul bar-like cosmetic, the stability of state,
The purpose of skin sense, the stability of storage, upper coloration；The present invention is as above in order to solve the problems, such as, second object of the present invention is wax
The oil phase part of base bar-like cosmetic point or oil, which mix portion envelops water, makes the releasing of its moisture provide a kind of group of emulsifier
Synthesis point.The composition of the emulsifier of the laminated structure of compounding wraps up the characteristics of moisture particle.
To solve the above-mentioned problems, the present invention adopts the following technical scheme:
A cerul bar-like cosmetic that can be out of the water, including oil phase part point or oily phase derivative moiety；The oil phase part
Point or oily phase derivative moiety package water so that the releasing of its moisture is provided a kind of composition of emulsifier, above moisture release at
The composition of the emulsifier of the laminated structure for the compounding divided has the characteristics that wrap up moisture particle.
Further, the flaky substance of the composition of the emulsifier of the laminated structure of the compounding is with the shape of multi-panel complex
State wraps up moisture particle；Cosmetics are made to enter the shape that can be out of the water since smearing deforms multi-panel complex structure when use
State；The multi-panel complex wraps up several flaky substance structures near moisture content particle and has the characteristics that thixotropic.
Further, the surface of the flaky substance is lipophilic speciality, and corner angle have hydroxy functional group, or to sheet
The stirring of substance montmorillonite carries out surface treatment and makes it have lipophilicity.
Further, the lipophilicity substance of the flaky substance is not particularly limited, and specifically can be the rouge of carbon number 5-22
The alkyl species of fat race；The aliphatic alkyl species of carbon number 5-22 above more specifically can be 4 grades of ammonium salts.
Further, the flaky substance montmorillonite is not particularly limited, and specifically can be lithium magnesium silicate or bentonite,
Lithium magnesium silicate can be better, and the cerul bar-like cosmetic that state stability is best water outlet in this case can be made；
Certainly better can be distearyl dimethylammonium hectorite.
Further, the model of the flaky substance is not particularly limited, round, the object of 3-5 angle-style or irregular type
Matter can be above-mentioned compounding substances of more than two kinds and be used in mixed way.
Further, the thickness of the flaky substance and long and short degree can be randomly selected, and specifically can be thickness
0.0005-0.005um, length can be 0.5-1.5um, are also possible to above-mentioned compounding substances of more than two kinds and are used in mixed way, and use
Outstanding stable cosmetics can be made when wrapping up large quantity of moisture in range above.
Further, the multi-panel complex substance can be the face 5-500 body, can be same Fig. 1 polyhedron of 2 dimensions, can
Be one in three-dimensional same Fig. 3 polyhedron above multi-panel complex be that can be closed to have hole such as 1-1 to the 1-10 of Fig. 3
The structure of gap, can be has faceted portions that can compare cunning such as 2-1 to 2-4 in the structure for having hole, and it is prominent to can be flaky substance
The structure of a part；Above the hole single side size of maximum pore be moisture content particle maximum single side size 50% within be ratio
Preferably, the single side size of more preferably maximum pore be moisture content particle maximum single side size 10% within；It can in range above
To wrap up a large amount of moisture, the outstanding water outlet cerul bar-like cosmetic of stability can be made.
Further, the diameter of the moisture particle size in the cerul bar-like cosmetic that can be out of the water can be 1-
100um, preferably 10-60um, such cosmetics Material are easy water outlet, the state of such cosmetics Material when smearing
Stability is more outstanding, if the size of moisture content particle be it is extra small if package do not live a large amount of moisture content, when may use less
It is easy water outlet, if the size of moisture content particle is super large, cosmetics Material state stability is almost.
Further, the rodlike emulsifying agent for cosmetics of cerul that can be out of the water is not particularly limited, more preferably carbon number
The alkyl emulsifier of 9-22, package moisture in this way is more, and the outstanding water outlet cerul bar-like cosmetic of stability is made.
Further, the emulsifier can be one 4 isostearate of polyglycereol, -3 polyricinoleate of polyglycereol, gather
- 3 diisopstearate of glycerol, -4 oleate of polyglycereol, polyglyceryl-3 diisostearate, poly- hydroxy stearic acid ester, decanedioic acid
Ester, anhydrous sorbitol isostearate, glycerol monolaurate, sorbitan monooleate, sorbitan sesquioleate, lauryl
PEG-9 Polydimethylsiloxyethyl Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone, PEG-
10 dimethyl silicone polymers etc. are individually or two or more is used in mixed way.
Further, the flaky substance and emulsifier weight ratio are 0.9-10 parts: 0.1-10 parts of weight, above model
Enclose it is interior can wrap up a large amount of moisture, the outstanding water outlet cerul bar-like cosmetic of stability can be made；The emulsifier structure
Plurality of sheet-like substance and moisture content can adjust at random, weight ratio be 80-99 parts: 1-20 parts of weight, above
A large amount of moisture can be wrapped up in range, and the outstanding water outlet cerul bar-like cosmetic of stability can be made.
Further, the cerul bar-like cosmetic that can be out of the water further includes water-phase component, and the water-phase component is specific
It can be water ,if needed it is soluble in water that raw material of the cosmetics with functional component can be used.
Further, the ion that specifically can be using cosmetics Material of the functional component, fragrant, extract, nutrition
Ingredient, one of moisturizer or other functional components or a variety of, the usage amount of usual additive are total weight
0.001-10%.
Further, the addition composition of effect can be used in the cerul bar-like cosmetic that can be out of the water；Specifically add
Addition part is, for example, powder, and thickener, fungicide, preservative, vitamin, effect medicament etc. can be with used aloned.
Further, the cerul bar-like cosmetic that can be out of the water is not particularly limited using position, specific to be, for example,
Lipstick, lip gloss, lipstick, BB frost or suncream.
Further, the cerul bar-like cosmetic that can be out of the water of the invention will include the oil having effects that and coordinate
Point, specific is, for example, the oil suitable for bar-like cosmetic Material, suitable for the wax of bar-like cosmetic Material, is suitable for stick-shaped cosmetic
The polymer resin of product Material, the vegetable oil suitable for bar-like cosmetic Material；Oily above, wax, polymer resin or vegetable oil can
To be single or two or more is used in mixed way；Oily phase composition in the cerul bar-like cosmetic that can be out of the water and addition at
The content that part is used can adjust at random.
Further, the cerul bar-like cosmetic moisture content that can be out of the water can be 20-60%, spy of the invention
Point is can to wrap up large quantity of moisture, and general moisture content is in 20-60%.Preferably moisture content is in 30-57%, such words shape
State stability, storage stability or use feeling all can satisfy.
Further, the cerul bar-like cosmetic that can be out of the water is the hardness having had, specially rheometer hardness
It is 2-120 all right, such words state stability or use feeling can meet.
Another technical problem to be solved by the invention is to provide the preparation side of a cerul bar-like cosmetic that can be out of the water
Method, comprising the following steps:
S1) emulsifier of flaky substance uses the tubule of 1-50um mixing jetting under the pressure of 100-600bar；
S2) S1 above) mixture mixes with oil；
S3) S2 above) mixture is mixed with water；
S4) S3 above) mixture is put into cooling procedure after the filling of rodlike molding die, the wax-based stick that can be out of the water
Shape cosmetics manufacturing method.
The beneficial effects of the present invention are: the present invention is the cerul bar-like cosmetic that can be out of the water, it is straightforward to provide a large amount of
Moisture content, the cerul bar-like cosmetic that can be out of the water has good hardness, so state stability is outstanding, it is outstanding to smear sense,
The features such as storage stability is outstanding, outstanding coloring effect.
Detailed description of the invention
Fig. 1 is two showed in water-phase component in cerul bar-like cosmetic when flaky substance and emulsifier are simply mixed
Tie up simulation drawing.
Fig. 2 is the two-dimensional analog figure of the water outlet for the cerul bar-like cosmetic that the present invention can be out of the water.
Fig. 3 is the display of the three-dimensional simulation figure of multi-panel complex in the cerul bar-like cosmetic of the invention that can be out of the water
Fig. 4 is cerul bar-like cosmetic such as 1 lipstick and contrast test 1 that the present invention can be out of the water under the conditions of 45 degree
Variation after placing 7 days compares picture.
Fig. 5 is the 2 suncream series 45 of cerul bar-like cosmetic such as 2 suncreams and contrast test that the present invention can be out of the water
Viscosity test contrast curve chart after being placed 7 days under the conditions of degree.
Fig. 6 is the cerul bar-like cosmetic such as suncream of 2 suncreams and contrast test 3 series that the present invention can be out of the water
Variation after placing 7 days under the conditions of 45 degree compares picture.
Fig. 7 is 45 degree of series of the cerul bar-like cosmetic such as 3BB frost that the present invention can be out of the water and contrast test 4-5BB frost
Under the conditions of place 7 days after observation variation comparison picture.
Fig. 8 is 45 degree of series of the cerul bar-like cosmetic such as 3BB frost that the present invention can be out of the water and contrast test 4-5BB frost
Under the conditions of place 7 days after viscosity test contrast curve chart.
Specific embodiment
Below in conjunction with attached drawing, a specific embodiment of the invention is described in further detail, so that technical solution of the present invention is more
It should be readily appreciated that and grasp.
The S1 in preparation method of the present invention) a plurality of flaky substance emulsifier using the tubule of 1-50um in 100-
Mixing is sprayed under the pressure of 600bar, it is characteristic of the invention that moisture component can be wrapped in cosmetics Material, is originally general
Logical hybrid machine such as Fig. 1, that invented originally does not form multi-panel complex and S1) emulsifiers of a plurality of flaky substances of process
Mixture, S2) or S4) process carries out when in thixotropy property and structure, such as Fig. 2 form multi-panel complex above；The present invention
The upper surface of S1) during can add mixed vegetable oil, above content of vegetable oil it is adjustable, but the emulsifier of flaky substance
It is that 100 parts of weight can be with the upper surface of 10-100 parts of mixed weight of vegetable oil, the cerul stick-shaped cosmetic that in this case can be out of the water
The state stability of product can be better；S2 of the invention) be S1 above) mixed process of mixture process and oily phase is not
Use S1) mixed process, the mixed process of oil-phase component can be used in the mixed process of the rodlike type cosmetics Material of effect；
Such as mixed process can be using homogenizer or three-roll grinder above；Above when the present invention contains powdered ingredients
S2 mixed-powder ingredient can be added during)；S3 above the present invention) mixing process can be used effect hybrid machine mixing
Oil-phase component and water-phase component, such as using being mixed in homogenizer or blender whipping process；It is controlled when mixing above
1800-2500 mixing speed mixing be it is best, the size of such words moisture content particle be the present invention to the cerul that can be out of the water
Bar-like cosmetic Material is wrapped up preferably, is made to the outstanding cerul bar-like cosmetic that can be out of the water of state stability；
S3 above when also in need) process mixture can add fragrance mixing after the cosmetics Material of fragrance can be provided；
S4 of the present invention) S3 above) process mixture be filled into it is cooling after mold after available effect bar-like cosmetic Material.
Multi-panel complex substance in the present invention can be the face 5-500 body, can be same Fig. 2 polyhedron of 2 dimensions, can be
One in three-dimensional same Fig. 3 polyhedron；Multi-panel complex is to can be closed to have hole such as 1-1 to the 1-10 of Fig. 3 above
Structure, can be has faceted portions that can compare cunning such as 2-1 to 2-4 in the structure for having hole, can be flaky substance prominent one
Partial structure；Above the hole single side size of maximum pore be moisture content particle maximum single side size 50% within be to compare
Alright, the single side size of more preferably maximum pore be moisture content particle maximum single side size 10% within；It can be in range above
A large amount of moisture is wrapped up, the outstanding water outlet cerul bar-like cosmetic of stability can be made.
Embodiment 1
A cerul bar-like cosmetic that can be out of the water is specially lipstick, the lipstick by following weight material
Be made: 1 part of -4 isostearate of polyglycereol, lauric alcohol -1 part of caprylate/decylate, 1 part of -3 polyricinoleate of polyglycereol are lost
1 part of water sorbierite isostearate, 1 part of stearyl alcohol heptanoate, 2 parts of distearyl dimethylammonium hectorite, 4 parts of butter fruit, cocounut oil
Alcohol -8 parts of caprylate/decylate, 1.5 parts of microwax, 8.5 parts of ceresin, No. 5 0.8 part of toner yellow, carmine (No. 102 colors of redness of the skin or complexion
Powder) 0.8 part, 0.6 part of pigment of phloxine (redness of the skin or complexion 104), 56.2 parts of water, 6.5 parts of butanediol, 3.0 parts of glycerol, 1,2- oneself two
2.0 parts of alcohol, 0.5 part of sodium chloride.
Another technical problem to be solved by the invention is to provide the preparation method of the lipstick, comprising the following steps:
S1) 1 part of -4 isostearate of polyglycereol, lauric alcohol -1 part of caprylate/decylate, -3 polyricinoleate of polyglycereol
1 part, 1 part of anhydrous sorbitol isostearate, 1 part of stearyl alcohol heptanoate, 2 parts of distearyl dimethylammonium hectorite, butter fruit 4
Part, using 1-50um tubule, the pressure injection of 100-600bar is mixed；
S2) oil-phase component adds lauric alcohol -8 parts of caprylate/decylate in mixture above, and 1.5 parts of microwax, purely
It is 8.5 parts of wax, No. 5 0.8 part of toner yellow, carmine (0.8 part of the toner of redness of the skin or complexion 102, phloxine (redness of the skin or complexion 104) pigment 0.6
Part, it is warming up to 70-75 degree and is ground using three-roll grinder, oil mixture is made；
S3) 56.2 parts of water, 6.5 parts of butanediol, 3.0 parts of glycerol, 1,2- 2.0 parts of hexylene glycol, is warming up to by 0.5 part of sodium chloride
40 degree are made water-phase component mixture；
S4 after) oil mixture manufactured above and aqueous mixture are stirred using blender 1800-2500rpm,
0.6 part of flavoring essence weight is stirred obtained lipstick Material；Lipstick Material uses lipstick obtained after the filling cooling of mold above.
Embodiment 2
A cerul bar-like cosmetic that can be out of the water is specially suncream, and the suncream is by following weight
Material is made: 16.0 parts of ring five dimethyl silicone polymer, 2.0 parts of PEG-10 Polydimethylsiloxane, distearyl dimethylammonium lithium covers
De- 2.0 parts of stone, 6 parts of diethyl hexylcarbonate, 3.0 parts of carbonic acid dioctyl ester, 7.5 parts of ethylhexyl methoxy cinnamate, salicylic acid
2.5 parts of ethylhexyl, 5.0 parts of the silylated dimethyl silicone polymer of titanium dioxide & silica &, zinc oxide & triethoxy octyl
5.0 parts of silane, 2.0 parts of methyl methacrylate cross-linked polymer, 39.2 parts of water, 5.0 parts of propylene glycol, 1.0 parts of sodium chloride, benzene oxygen
0.5 part of ethyl alcohol, 0.3 part of essence.
Another technical problem to be solved by the invention is to provide the preparation method of the suncream, comprising the following steps:
S1) 1.0 parts of ring five dimethyl silicone polymer, 2.0 parts of PEG-10 Polydimethylsiloxane, distearyl dimethylammonium lithium covers
De- 2.0 parts of stone is mixed using the tubule of 1-50um using the pressure injection of 100-600；
S2 15.0 parts of ring five dimethyl silicone polymer) are added in the oil-phase component of mixture above, carbonic acid diethyl
6 parts of own ester, 3.0 parts of carbonic acid dioctyl ester, 7.5 parts of ethylhexyl methoxy cinnamate, 2.5 parts of ethylhexyl salicylate, titanium dioxide
5.0 parts of the silylated dimethyl silicone polymer of titanium & silica &, 5.0 parts of silane of zinc oxide & triethoxy octyl, methacrylic acid
It 2.0 parts of methyl esters cross-linked polymer, is warming up to 70-75 degree and is ground using three-roll grinder, oil mixture is made；
S3) 39.2 parts of water, 1.0 parts of sodium chloride, 0.5 part of Phenoxyethanol, are warming up to 40 degree and water phase are made by 5.0 parts of propylene glycol
Constituents mixt；
S4 after) oil mixture manufactured above and aqueous mixture are stirred using blender 1800-2500rpm,
0.3 part of flavoring essence weight, which is stirred, is made sun-proof cream cosmetic Material, above sun-proof cream cosmetic Material using mold it is filling
Rodlike suncream is made after cooling.
Embodiment 3
A cerul bar-like cosmetic that can be out of the water specifically can be BB frost, and the BB frost is by following weight
Material is made: 11.0 parts of ring five dimethyl silicone polymer, 2 parts of PEG-10 Polydimethylsiloxane, distearyl dimethylammonium lithium covers de-
2 parts of stone, 4.0 parts of diethyl hexylcarbonate, 5.0 parts of ethylhexyl methoxy cinnamate, 3.0 parts of dimethyl silicone polymer, different nonyl
Different 5.5 parts of nonyl ester of acid, dimethyl silicone polymer & Dimethicone/Vinyl Dimethicone cross-linked polymer 3
Part, 7.1 parts of the silylated dimethyl silicone polymer of titanium dioxide & silica &, silica & titanium dioxide & triethoxy octyl silane
7.1 parts, 0.2 part of silane of iron oxide & triethoxy octyl, 1.7 parts of silane of talcum & triethoxy octyl, tri- ethoxy of titanium dioxide &
1.7 parts of base octyl silane, 37 parts of water, 7.0 parts of propylene glycol, 1.0 parts of sodium chloride.
Another technical problem to be solved by the invention is to provide the BB preparation method of frost, comprising the following steps:
S1) 1.0 parts of ring five dimethyl silicone polymer, 2 parts of PEG-10 Polydimethylsiloxane, distearyl dimethylammonium lithium covers de-
It 2 parts of stone, using the tubule of 1-50um, is mixed using the pressure injection of 100-600bar；
S2) in the oily phase composition of mixture above be added 10.0 parts of ring five dimethyl silicone polymer, carbonic acid diethyl oneself
4.0 parts of ester, 5.0 parts of ethylhexyl methoxy cinnamate, 3.0 parts of dimethyl silicone polymer, 5.5 parts of isononyl isononanoate, poly- two
3 parts of cross-linked polymer of methylsiloxane & Dimethicone/Vinyl Dimethicone, titanium dioxide & silica & first
7.1 parts of silylation dimethyl silicone polymer, 7.1 parts of silane of & triethoxy octyl of silica & titanium dioxide, tri- ethoxy of iron oxide &
0.2 part of base octyl silane, 1.7 parts of silane of talcum & triethoxy octyl, 1.7 parts of silane of titanium dioxide & triethoxy octyl rise
Temperature is ground to 70-75 degree using three-roll grinder, and oil mixture is made；
S3) 37 parts of water weight, 1.0 parts of weight sodium chloride, are warming up to 40 degree and water-phase component are made by 7.0 parts of propylene glycol weight
Mixture；
S4 after) oil mixture manufactured above and aqueous mixture are stirred using blender 1800-2500rpm,
BB cream cosmetic Material is made, above BB cream cosmetic Material using rodlike BB frost is made after the filling cooling of mold.
Experimental example:
Contrast test 1
2 parts of hectorite of example 1 above oil-phase component distearyl dimethylammonium is not added, without using the tubule of 1-50um,
It is mixed without using the pressure injection of 100-600, obtains oil mixture and mixed without using three-roll grinder, other and above example
Lipstick is made in 1 same method；Embodiment 1 and the stability of contrast test 1 compare test-example 1 above lipstick and comparison
It is placed 7 days under the conditions of 45 degree of lipstick of test 1, then compares the lipstick state under normal temperature condition, as a result such as Fig. 4；Fig. 4 is this hair
Bright 1 sample state of embodiment does not change, and largely scatters and disappears and volatilizees comprising moisture content in 1 sample of contrast test, it is therefore seen that of the invention
Lipstick state stability it is obviously more outstanding.
Contrast test 2
Oily 2 parts of hectorite of composition distearyl dimethylammonium of phase is not added in example 2 above, without using the thin of 1-50um
Pipe is mixed without using the pressure injection of 100-600, is obtained oil mixture and is mixed without using three-roll grinder, other and real above
It applies 2 same manner of example and suncream is made；The stability test of embodiment 2 and contrast test 2 compares, example 2 above it is sun-proof
7 days, suncream viscosity test such as Fig. 5 are placed under the conditions of 45 degree of suncream white and contrast test 2, Fig. 5 the embodiment of the present invention 2
With 2 viscosity of contrast test compare, embodiment 2 change it is small, it is therefore seen that suncream state stability of the invention is more outstanding.
Contrast test 3
0.5 part of hectorite of composition distearyl dimethylammonium of example 2 above oil phase addition, ring five dimethyl silicone polymer
17.5 parts of additions mix without using the pressure injection of 100-600 without using the tubule of 1-50um, obtain oil mixture and do not use
Three-roll grinder mixing.Suncream is made in other and example 2 above same manner；The suncream of example 2 above and comparison
It is placed under the conditions of 45 degree of suncream of test 37 days, then compares the suncream form under normal temperature condition, as a result observation such as Fig. 6,
Fig. 6 the embodiment of the present invention 2 does not change with comparing under normal temperature condition, and contrast test 3 is with comparison under normal temperature condition comprising a large amount of
Moisture evaporation scatter and disappear；It is therefore seen that suncream state stability of the invention is more outstanding.
Contrast test 4
2.0 parts of raw material distearyl dimethylammonium hectorite is not added in example 3 above, without using the tubule of 1-50um, no
It is mixed using the pressure injection of 100-600bar；Gained oil mixture is mixed without using three-roll grinder；It is other and real above
It applies 3 same method of example and BB frost is made.
Contrast test 5
0.5 part of raw material distearyl dimethylammonium hectorite, ring five dimethyl silicone polymer 12.5 are added in example 3 above
Part, without using the tubule of 1-50um, mixed without using the pressure injection of 100-600bar；Gained oil mixture does not use three rollers
Grinder mixing；It is other and above such as 3 with same method be made BB frost.
Embodiment 3 and contrast test 4-5 stability test compare；The BB frost of example 3 above and the BB of contrast test 4-5
It is placed under the conditions of 45 degree of frost 7 days, then compares form with normal temperature condition BB frost, as a result observation such as Fig. 7；Fig. 7 it is of the invention such as 3
It is not find out variation phenomenon with room temperature comparison, comparison room temperature observation moisture evaporation scatters and disappears tight when contrast test 4-5 the 4th day
Weight, it is therefore seen that BB frost state stability of the invention is more outstanding；The BB frost of example 3 above and the BB of contrast test 4-5
Frost 45 degree under the conditions of place 7 days, viscosity test results such as Fig. 8: Fig. 8 it is of the invention such as 3 with contrast test 4-5 viscosity comparison,
Such as 3 variation it is small, it is therefore seen that BB frost state stability of the invention is more outstanding.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any
The change or replacement expected without creative work, should be covered by the scope of protection of the present invention.
Claims (12)
1. a cerul bar-like cosmetic that can be out of the water, it is characterised in that: including oil phase part point or oily phase derivative moiety；Institute
Stating oil phase part point or oily phase derivative moiety package water makes the releasing of its moisture provide a kind of composition of emulsifier, above water
The composition of the emulsifier of the laminated structure for the compounding for releasing ingredient is divided to have the characteristics that wrap up moisture particle.
2. a cerul bar-like cosmetic that can be out of the water as described in claim 1, it is characterised in that: the sheet of the compounding
The flaky substance of the composition of the emulsifier of structure wraps up moisture particle with the state of multi-panel complex；Make when use due to smearing
Multi-panel complex structure deforms and cosmetics is made to enter the state that can be out of the water.
3. a cerul bar-like cosmetic that can be out of the water as claimed in claim 2, it is characterised in that: the flaky substance
Surface is lipophilic speciality, and corner angle have hydroxy functional group, or carries out surface treatment to the stirring of flaky substance montmorillonite and make it
With lipophilicity.
4. a cerul bar-like cosmetic that can be out of the water as claimed in claim 3, it is characterised in that: the flaky substance
Lipophilicity substance is not particularly limited, and specifically can be the aliphatic alkyl species of carbon number 5-22；More specifically above
The aliphatic alkyl species of carbon number 5-22 can be 4 grades of ammonium salts.
5. a cerul bar-like cosmetic that can be out of the water as claimed in claim 3, it is characterised in that: the flaky substance covers
De- stone is not particularly limited, and specifically can be lithium magnesium silicate or bentonite, and lithium magnesium silicate can be better, in this case may be used
The cerul bar-like cosmetic that state stability is best water outlet is made；Certainly better can be distearyl diformazan
Ammonium hectorite.
6. a cerul bar-like cosmetic that can be out of the water as claimed in claim 2, it is characterised in that: the flaky substance
Model is not particularly limited, round, the substance of 3-5 angle-style or irregular type, and it is mixed to can be above-mentioned compounding substances of more than two kinds
It closes and uses.
7. a cerul bar-like cosmetic that can be out of the water as claimed in claim 2, it is characterised in that: the flaky substance
Thickness and long and short degree can be randomly selected, and specifically can be thickness 0.0005-0.005um, and length can be 0.5-1.5um,
It can be above-mentioned compounding substances of more than two kinds to be used in mixed way.
8. a cerul bar-like cosmetic that can be out of the water as described in claim 1, it is characterised in that: described to can be out of the water
The rodlike emulsifying agent for cosmetics of cerul is not particularly limited, more preferably the alkyl emulsifier of carbon number 9-22, wraps up moisture more in this way
It is more, the outstanding water outlet cerul bar-like cosmetic of stability is made.
9. a cerul bar-like cosmetic that can be out of the water as claimed in claim 8, it is characterised in that: the emulsifier can be with
For -4 isostearate of polyglycereol, -3 polyricinoleate of polyglycereol, polyglyceryl-3 diisostearate, -4 oleic acid of polyglycereol
Ester, polyglyceryl-3 diisostearate, poly- hydroxy stearic acid ester, sebacate, anhydrous sorbitol isostearate, glycerol laurel
Acid esters, sorbitan monooleate, sorbitan sesquioleate, lauryl PEG-9 polydimethylsiloxanes ethyl poly dimethyl silicon
Oxygen alkane, PEG-9 Polydimethylsiloxyethyl Dimethicone, PEG-10 Polydimethylsiloxane etc. individually or 2 kinds with
On be used in mixed way.
10. a cerul bar-like cosmetic that can be out of the water as described in claim 1, it is characterised in that: described to can be out of the water
Cerul bar-like cosmetic further include water-phase component, the water-phase component specifically can be water ,if needed makeup can be used
Product have the raw material of functional component soluble in water.
11. a cerul bar-like cosmetic that can be out of the water as claimed in claim 11, it is characterised in that: the functional component
Specifically can be ion using cosmetics Material, fragrant, extract, nutritional ingredient, moisturizer or other functional components
One of or it is a variety of, the usage amount of usual additive is the 0.001-10% of total weight.
12. a cerul bar-like cosmetic that can be out of the water as described in claim 1, it is characterised in that: described to can be out of the water
Cerul bar-like cosmetic be not particularly limited using position, specific e.g. lipstick, lip gloss, lipstick, BB frost or suncream.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020180067948A KR102091324B1 (en) | 2018-03-19 | 2018-06-14 | Water-release stick type cosmetics |
| KR10-2018-0067948 | 2018-06-14 |
Publications (2)
| Publication Number | Publication Date |
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| CN110227040A true CN110227040A (en) | 2019-09-13 |
| CN110227040B CN110227040B (en) | 2022-09-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910170511.0A Active CN110227040B (en) | 2018-06-14 | 2019-03-06 | Wax-based stick-shaped cosmetic capable of discharging water and preparation method thereof |
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| Country | Link |
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| CN (1) | CN110227040B (en) |
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| CN113318009A (en) * | 2021-05-17 | 2021-08-31 | 科丝美诗(中国)化妆品有限公司 | Oil-dispersed mousse paste composition and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN110227040B (en) | 2022-09-06 |
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