CN106619159A - Method for improving viscosity stability of water-in-oil type cream - Google Patents
Method for improving viscosity stability of water-in-oil type cream Download PDFInfo
- Publication number
- CN106619159A CN106619159A CN201710016782.1A CN201710016782A CN106619159A CN 106619159 A CN106619159 A CN 106619159A CN 201710016782 A CN201710016782 A CN 201710016782A CN 106619159 A CN106619159 A CN 106619159A
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- CN
- China
- Prior art keywords
- water
- oil type
- modifying agent
- type creams
- viscosity stability
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/064—Water-in-oil emulsions, e.g. Water-in-silicone emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/25—Silicon; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Abstract
The invention discloses a method for improving the viscosity stability of water-in-oil type cream. According to the method for improving the viscosity stability of the water-in-oil type cream, a hydrophilic montmorillonite modifier and an oleophylic organic clay modifier are added into the water-in-oil type cream, wherein the use amount of the montmorillonite modifier accounts for 0.01-5% of the total mass of the water-in-oil type cream, and the use amount of the organic clay modifier accounts for 0.01-5% of the total mass of the water-in-oil type cream. Compared with the prior art, the method provided by the invention for improving the viscosity stability of the water-in-oil type cream can remarkably improve the viscosity stability of the water-in-oil type cream by adding the hydrophilic montmorillonite modifier and the oleophylic organic clay modifier into the water-in-oil type cream; the prepared cream is stable in performance and good in rheological property.
Description
Technical field
The present invention relates to technical field of skin care, and in particular to a kind of side of raising water-in-oil type creams viscosity stability
Method.
Background technology
Water-in-oil type (W/O) system refers to grease etc. as foreign minister or decentralized medium that hydroaropic substance is interior phase or dispersion
Phase, hydroaropic substance is dispersed in the system in oil in forms such as drops；It is relatively broad in products applications such as BB frosts, but open in formula
Send out and technique productions in, be frequently encountered the problem of dispensing viscosity stability, be mainly reflected between batch that the differences in viscosity opposite sex is big, resistance to
Situations such as viscosity B coefficent is obvious after heat is cold-resistant, quality risk is higher.Jing is analyzed, it is believed that be the rheology modifier product due to oil phase
Plant relative aqueous phase stream change modifying agent not enough to enrich, and it is strong without aqueous phase stream change modifying agent in terms of the effect of interior phase aggregation is prevented.
The content of the invention
The purpose of the present invention is to overcome above-mentioned technical problem, there is provided a kind of side of raising water-in-oil type creams viscosity stability
Method, can keep the viscosity stabilization between batch, and the cold and hot stability examinations of product Jing itself in the production process of water-in-oil type creams
Test rear viscosity relatively stable.
Technical scheme is as follows：
A kind of method for improving water-in-oil type creams viscosity stability, by adding hydrophilic in the water-in-oil type creams
The smectites modifying agent and oil loving organic clay class modifying agent of property, wherein the consumption of the smectites modifying agent accounts for institute
State the 0.01-5% of water-in-oil type creams gross mass, it is total that the consumption of the organic clay class modifying agent accounts for the water-in-oil type creams
The 0.01-5% of quality.
Preferably, the consumption of the smectites modifying agent accounts for the 0.5% of the water-in-oil type creams gross mass, described to have
The consumption of machine clay class modifying agent accounts for the 0.5% of the water-in-oil type creams gross mass.
Preferably, the smectites modifying agent is included in lithium magnesium silicate, aluminium-magnesium silicate, hectorite or bentonite at least
It is a kind of.
Preferably, the organic clay class modifying agent includes distearyl dimethylammonium hectorite or the bentonite of quaternary ammonium salt -18
In at least one.
Preferably, the water-in-oil type creams are also including the component of following mass percent：
A phases：Lauryl KF-6028
0.5-2%
The diisopstearate 0.5-1.5% of polyglycereol -3
Titanium dioxide 7-8%
The 0.05-0.6% of CI 77492
The 0.02-0.2% of CI 77491
Polyricinoleate 0.1-1% of polyglycereol -6
Carbonic acid dioctyl ester 2-4%
Ring five dimethyl silicone polymer 10-18%
Caprylic/capric triglyceride 4-6%；
B phases：Glycerine 5-10%
EDETATE SODIUM 0.01-1%
Niacinamide 0.1-3%
Sodium chloride 0.1-1.5%；
C phases：Phenoxyethanol, Chlorphenesin and glycerine 0.1-0.5%；
D phases：Essence 0.01-1%；
E phases：1,3-PD 2-4%
Deionized water surplus.
Wherein CI 77492 and CI 77491 is colouring agent.
Compared to prior art, the method for the raising water-in-oil type creams viscosity stability that the present invention is provided is by described
Add hydrophilic smectites modifying agent and oil loving organic clay class modifying agent in water-in-oil type creams, can significantly carry
High water-in-oil type creams viscosity stability, prepared creams stable performance, rheological property is good.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but embodiments of the present invention not limited to this.
The method of the raising water-in-oil type creams viscosity stability that the present invention is provided is by the water-in-oil type creams
Add hydrophilic smectites modifying agent and oil loving organic clay class modifying agent, wherein the smectites modifying agent
Consumption accounts for the 0.01-5% of the water-in-oil type creams gross mass, and the consumption of the organic clay class modifying agent accounts for the Water-In-Oil
The 0.01-5% of type creams gross mass.
Embodiment 1-3, its formula is shown in Table 1.
Table 1
The smectites modifying agent is distinguished as the component of E phases, the organic clay class modifying agent as the component of A phases
Add in the preparation process of the water-in-oil type creams, the smectites modifying agent of wherein embodiment 1 is：Hectorite, it is organic
Clay class modifying agent is：Distearyl dimethylammonium hectorite；The smectites modifying agent of embodiment 2 is：Lithium magnesium silicate, it is organic glutinous
Great soil group modifying agent is：The bentonite of quaternary ammonium salt -18；The smectites modifying agent of embodiment 3 is：Bentonite, organic clay class is modified
Agent is：Distearyl dimethylammonium hectorite.Comparative example 1 only add organic clay class modifying agent distearyl dimethylammonium hectorite and
Without smectites modifying agent, comparative example 2 is only added smectites modifying agent hectorite and is modified without organic clay class
Agent.The preparation method of embodiment 1-3 and comparative example 1-2 is as follows：
Step S1, mill A phase each component high speed homogenizations 30min, is warming up to 80 DEG C, insulation；
Step S2, E phase is pre-mixed, and is warming up to 80 DEG C, high speed homogenization 20 minutes；
Step S3, B phases each component is put under agitation in E phases, high speed homogenization 2 minutes；
Step S4, under agitation E phases are slowly added into A phases, high speed homogenization 10 minutes；
Step S5, addition C phases, stirring is cooled to 40 DEG C, adds D phases, is stirred until homogeneous, and detection is qualified can to discharge.
Water-in-oil type creams viscosity stability is tested
By the creams of preparation be divided into three parts be individually positioned in -15 DEG C, 25 DEG C, carry out viscosity tracking and testing within 6 months at 45 DEG C.
Method of testing adopts BROOKFIELD DV2T RVT JO type digital display viscosity apparatus, in 04# rotors, 12rpm, carries out under the conditions of 25 DEG C
Test, concrete test result is shown in Table 2.
Table 2
From table 2 it can be seen that by adding hydrophilic smectites modifying agent and oil loving organic glutinous in creams
After great soil group modifying agent, at each temperature storage viscosity B coefficent is little, has good stability, and only adds hydrophilic smectites modifying agent
Or oil loving organic clay class modifying agent, then viscosity stability differ greatly, the viscosity error scope of comparative example 1 has exceeded
± 30%, even there is layering equistability exception in comparative example 2, and illustrate present invention offer adds parent in water-in-oil type creams
Aqueous smectites modifying agent and the method for oil loving organic clay class modifying agent is stablized to improving water-in-oil type creams
Property has very great help.
Compared to prior art, the method for the raising water-in-oil type creams viscosity stability that the present invention is provided is by described
Add hydrophilic smectites modifying agent and oil loving organic clay class modifying agent in water-in-oil type creams, can significantly carry
High water-in-oil type creams viscosity stability, prepared creams stable performance, rheological property is good.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, it is every using this
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (5)
1. it is a kind of improve water-in-oil type creams viscosity stability method, it is characterised in that by the water-in-oil type creams
The hydrophilic smectites modifying agent of middle addition and oil loving organic clay class modifying agent, wherein the smectites modifying agent
Consumption account for the 0.01-5% of the water-in-oil type creams gross mass, the consumption of the organic clay class modifying agent accounts for the oil bag
The 0.01-5% of water type creams gross mass.
2. it is according to claim 1 improve water-in-oil type creams viscosity stability method, it is characterised in that the illiteracy take off
The consumption of stone class modifying agent accounts for the 0.5% of the water-in-oil type creams gross mass, and the consumption of the organic clay class modifying agent is accounted for
The 0.5% of the water-in-oil type creams gross mass.
3. it is according to claim 1 improve water-in-oil type creams viscosity stability method, it is characterised in that the illiteracy take off
Stone class modifying agent includes at least one in lithium magnesium silicate, aluminium-magnesium silicate, hectorite or bentonite.
4. according to claim 1 or 3 raising water-in-oil type creams viscosity stability method, it is characterised in that it is described
Organic clay class modifying agent includes distearyl dimethylammonium hectorite or at least one in the bentonite of quaternary ammonium salt -18.
5. it is according to claim 1 improve water-in-oil type creams viscosity stability method, it is characterised in that it is described oil bag
Water type creams are also including the component of following mass percent：
A phases：Lauryl KF-6028 0.5-2%
Polyglyceryl-3 diisostearate 0.5-1.5%
Titanium dioxide 7-8%
The 0.05-0.6% of CI 77492
The 0.02-0.2% of CI 77491
Polyricinoleate 0.1-1% of polyglycereol -6
Carbonic acid dioctyl ester 2-4%
Ring five dimethyl silicone polymer 10-18%
Caprylic/capric triglyceride 4-6%；
B phases：Glycerine 5-10%
EDETATE SODIUM 0.01-1%
Niacinamide 0.1-3%
Sodium chloride 0.1-1.5%；
C phases：Phenoxyethanol, Chlorphenesin and glycerine 0.1-0.5%；
D phases：Essence 0.01-1%；
E phases：1,3-PD 2-4%
Deionized water surplus.
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| CN201710016782.1A CN106619159B (en) | 2017-01-10 | 2017-01-10 | The method for improving water-in-oil type creams viscosity stability |
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| CN201710016782.1A CN106619159B (en) | 2017-01-10 | 2017-01-10 | The method for improving water-in-oil type creams viscosity stability |
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| CN106619159B CN106619159B (en) | 2019-10-11 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107308012A (en) * | 2017-06-30 | 2017-11-03 | 广州澳希亚实业有限公司 | A kind of water-in-oil type sunscreen breast good with low viscosity suspending power and preparation method thereof |
| CN108550767A (en) * | 2018-04-28 | 2018-09-18 | 丹阳克帕斯特能源科技有限公司 | A kind of zinc load battery diagram modification method |
| CN110227040A (en) * | 2018-06-14 | 2019-09-13 | 广州雅纯化妆品制造有限公司 | A cerul bar-like cosmetic that can be out of the water and preparation method |
| CN111467274A (en) * | 2020-04-30 | 2020-07-31 | 深圳市垂纶远翔科技有限责任公司 | Eye cream for quickly removing wrinkles and bags under eyes |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107308012A (en) * | 2017-06-30 | 2017-11-03 | 广州澳希亚实业有限公司 | A kind of water-in-oil type sunscreen breast good with low viscosity suspending power and preparation method thereof |
| CN108550767A (en) * | 2018-04-28 | 2018-09-18 | 丹阳克帕斯特能源科技有限公司 | A kind of zinc load battery diagram modification method |
| CN110227040A (en) * | 2018-06-14 | 2019-09-13 | 广州雅纯化妆品制造有限公司 | A cerul bar-like cosmetic that can be out of the water and preparation method |
| CN110227040B (en) * | 2018-06-14 | 2022-09-06 | 广州雅纯化妆品制造有限公司 | Wax-based stick-shaped cosmetic capable of discharging water and preparation method thereof |
| CN111467274A (en) * | 2020-04-30 | 2020-07-31 | 深圳市垂纶远翔科技有限责任公司 | Eye cream for quickly removing wrinkles and bags under eyes |
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| Publication number | Publication date |
|---|---|
| CN106619159B (en) | 2019-10-11 |
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Address after: Room 3007, 888 Yuncheng West Road, Baiyun District, Guangzhou, Guangdong 510420 Patentee after: Guangzhou Anxin Cosmetics Co.,Ltd. Address before: Room 3007, 888 Yuncheng West Road, Baiyun District, Guangzhou, Guangdong 510420 Patentee before: HANHOO COSMETICS CO.,LTD. |
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Effective date of registration: 20220617 Address after: Room 189, first floor, No. 2429, Xingang East Road, Haizhu District, Guangzhou, Guangdong 510000 Patentee after: Guangzhou Zhongzhuang Meiye Cosmetics Co.,Ltd. Address before: Room 3007, 888 Yuncheng West Road, Baiyun District, Guangzhou, Guangdong 510420 Patentee before: Guangzhou Anxin Cosmetics Co.,Ltd. |
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